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By Bingguo Liu, Daifu Huang, Jinhui Peng

"The conditions to prepare U3O8 by calcination from ammonium diuranate were optimized, and the response surface design method was applied to analyze the influence on the total uranium and U+4 of calcination temperature, calcination time and mass of sample. A quadratic equation model for the total uranium and U+4 of U3O8 was built and the effects of main factors and their corresponding relationships were obtained. The analysis of variance shows that calcination temperature and calcination time significantly affected the value of total uranium and U+4 of U3O8. The optimal calcination conditions were as follows: calcination temperature 931.83 K, calcination time 24.32 min and 43.89 g. Under these conditions the value of total uranium and U+4 of U3O8 was 84.78% and 28.02%, respectively. The validity of the model was confirmed experimentally and the results were satisfactory.IntroductionNuclear energy is clean, effective, and a sustainable from of energy. It plays an important role in overcoming the impending global energy crisis, and in reducing energy vulnerability. In addition, nuclear energy is a possible cheaper and cleaner source of energy compared to fossil fuels, with no not really, mining of uranium produces CO2 contribution to green house gases [1]. Uranium dioxide, one of the most important fuel pellets used as nuclear fuel in light water reactors, is manufactured by calcining ammonium diuranate to triuranium octaoxide, followed by its reduction to uranium dioxide using cracked ammonia at 700°C [2]. Earlier attempts to optimize the important calcination process through several common techniques have not yielded desirable results [3]. These techniques either rely on the classical one parameter at a time approach that ignores the combined interactions between physicochemical parameters, or are theoretical in nature. Furthermore, these techniques also require large number of experimental data to be generated [4]. In order to produce triuranium octaoxide in an optimized manner, which considers the interaction of different process parameters [5], there is a need to adopt a multivariate statistical technique."

Jan 1, 2011

1. What Is a Rock Burst? . . . . 569 Jack Spalding . . 569 A. F. Robertson . 569 W. R. Crane . 569 G. S. Rice......569 P. J. Shenon........... 569 L. C. Graton........... 569 2. What Are the Causes of Rock Bursts? 573 Jack Spalding..........573 A. B. Yates and P. J. Shenon 574, 578, 592, 596 A. F. Robertson . . . . . 575, 595 W. R. Crane. ... 579 G. S. Rice.........582 Oscar Weiss .........582 P. B. Bucky..........582 P. H. Bird.....588, 592, 593, 595 M. K. Hubbert.........593 G. Wheeler.......... .593 B. F. Tillson........593, 595 T. T. Read............594 3. How Can Rock Bursts Be Prevented?. 597 Jack Spalding..........597 A. B. Yates and P. J. Shenon ... 598 A. F. Robertson.......599 W. R. Crane....... .602 G. S. Rice............602 Page 4. How Can Rock Bursts Be Predicted?. 602 Jack Spalding.........602 A. F. Robertson.......602, 603 A. B. Yates and P. J. Shenon ... 602 W. R. Crane......602 G. S. Rice......602 B. F. Tillson...........603 5. How Can Rock Bursts Be Controlled? 603 Jack Spalding..........603 A. F. Robertson.......603 W. R. Crane...........604 A. B. Yates and P. J. Shenon 604 Oscar Weiss........605 G. S. Rice......- 604, 609 R.D.Hoffman..609, 610 R. D. Hall..........609 R. H. Cromwell . . 609 P. J. Shenon...........609 P. B. Bucky......609, 611 B. F. Tillson.........609, 611 A. B. Yates...610, 611 P. H. Bird.......610 6. General Discussion........ 611 Jack Spalding.......... 611 R. D. Parker....... . 616 C. Baring Horwood........ 618 P. B. Bucky........... 619 Foreword This symposium brings together points of view, experiences and ideas on rock bursts from a goodly portion of the globe. Some conceptions, particularly those regarding the necessity of depth, have been fairly well shattered, as we find that they are present in the water tunnels of New York, on the surface at marble quarries in Vermont, and in the coal mines of the United States, as well as in the deep mines of the South African and Kolar gold fields, and in the nickel, copper and gold mines of Canada. Their occurrence under such a variety of conditions is, therefore, a challenge, which, if successfully met and overcome,

Jan 1, 1946

"In this paper, a mobile heat treatment furnace from Akkermans Gloeitechniek, a Dutch company, was simulated with Computational Fluid Dynamics (CFD). The furnace is cylindrical with four oil burners, and large metal products such as dredging pumps and impellers can be flexibly heat treated to obtain required microstructure and mechanical properties through stress relief, annealing, hardening and tempering. The furnaces are exposed to the open air, and thus the heat loss becomes significant and varies from day to day and from season to season. Since the temperature of the metal products to be heat treated can only be measured on the surface, the temperature evolution inside the metal could not be tracked in practice. CFD simulation provides a useful tool to predict the temperature evolution within the metal pieces and within the combustion space of the furnace. Energy distribution and heat loss can be subsequently estimated. An overall energy balance through temperature measurement indicted relatively low energy efficiency. Especially during the soaking period, the high energy supplied is barely used to compensate the heat loss of the furnace to maintain a constant temperature of the metal piece. The current CFD modeling aims to give advice on how to modify the design and optimize the operation to reach higher energy efficiency and low heat loss. The CFD model consists of turbulent combustion model, radiation model in participating media, and conjugate heat transfer between the combustion space and solid metal. Temperature measurement was carried out to provide thermal boundary conditions and overall energy balance of the operation. After the model validation with temperature measurement within the combustion space and metal surfaces, furnace optimization will be conducted.IntroductionHeat treatment is a common practice in metal production and manufacturing industries. Through heat treatment at certain temperatures with special patterns, unique mechanical properties of the metals and the metallic products could be obtained. ""Akkermans Gloeitechniek"" is a company situated in K.inderdijk, at location of LHC-Holland (www.ihccaland.com), the Netherlands. Heat treatment of metals is its core business. Various type of heat treatment are applied, such as stress relieving, soft annealing and hardening (quenching), tempering, transformation and precipitation. At the company 6 furnaces are in operation and the 7th is being built"

Jan 1, 2004

By Joseph Licavoli, Paul Sanders, Yang Yang

"Al-Sc-Zr alloys form thermally stable L12 precipitates which provide high temperature strength. Although the overall fraction of L12 Al3Sc and Al3Zr may be increased by increasing scandium (Sc) and zirconium (Zr) content, such additions may increase primary phase fractions and do not produce desirable secondary phase morphologies. Rapid solidification techniques, such as melt spinning, increase solute atom concentration within the matrix. When the supersaturated matrix is aged, higher precipitate volume fractions at low Sc and Zr levels can be achieved improving high temperature strength. Melt spinning was used to rapidly solidify (107 k/s) a thin ribbon of Al-0.5Sc-0.4Zr at. %. The ribbon was compacted and extruded into 99.8% dense rods, and then aged using multi-step isochronal heat treatment up to 600°C. Precipitation strengthening was evaluated by ambient hardness measurement. The ambient hardness of melt-spun ribbon after precipitation hardening increased by 450 MPa (~67% increment) during isochronal heat treatment.INTRODUCTION Small Sc and Zr additions to aluminum improve strength and creep resistance above 300°C due to tri-aluminide precipitation of Al3(Sc,Zr) in L12 structures similar to ??, Ni3(Al,Ti) in nickel superalloy, but the Al3(Sc,Zr) particles have a Sc-rich core surrounded by Zr-rich shell (Figure 1). The Al3Zr shell limits atomic transport between the Al3Sc core and the matrix and reduces coherency strain. These factors reduce precipitate coarsening rate at elevated temperature (Bergner & Van Chi, 1977; Fujikawa, 1997; Knipling et al., 2011; Clouet et al., 2006).Figure 1. Simplified schematic model of precipitate Al(Sc,Zr) in Al-Sc-Zr alloy. Shell is rich of Al(Zr) intermetallic phase, particle core is rich of Al(Sc) intermetallic phase (after Voorhees, 2006). Numerous Al3(Sc,Zr) particles increase alloy strength and creep resistance as the precipitates impede dislocation glide and to a lesser extent climb. Previous work on ternary Al-Sc-Zr alloys show large strength increases versus binary Al-Sc, and Al-Zr alloys in Table 1."

Jan 1, 2018

By Takeshi Yoshikawa, Kazuki Morita, Yuichi Kato

"A composite composed of carbon fiber and a Cu-Si alloy is a promising candidate for next generation brake disc materials used in high-speed trains. The composite can be prepared by vacuum infiltration of the Cu-Si alloy into the fibrous carbon matrix. The activity of Si in the alloy plays an important role in controlling the formation of SiC; this formation is attributed to the reaction between the Si in the alloy and the carbon fiber during the infiltration process. Because Fe has strong affinity with Si, the addition of Fe is expected to decrease the activity of Si in the alloy. In the present work, the variation in the activity of Si in the alloy with the addition of Fe has been investigated by equilibrating a Cu-Fe-Si alloy with solid SiO2 and graphite under controlled CO partial pressure. The first-order and second-order interaction parameter of Fe on Si in molten Cu was determined to be -16 and 160, respectively. The negative value of the first-order interaction parameter clarified the addition of Fe to the Cu-Si alloy is effective in decreasing the activity of Si in the alloy.IntroductionIron-based materials have been commonly used for brake discs in high-speed trains. It becomes critical for brake disc materials to withstand high thermal loads with an increase in the maximum speed of high-speed trains. The fabrication of high heat-resistant, light-weight brake disc materials is then crucial for their use in next-generation high-speed trains. Carbon fiber is known to be a light-weight, high-strength material, and is considered to be a promising matrix material for use in brake discs. The Cu-Si alloy exhibits high thermal conductivity. The composite in which the Cu-Si alloy is added to the carbon fiber matrix is expected to be a high performance material for brake discs. The composite can be prepared by the infiltration of the Cu-Si alloy into the carbon fiber matrix at a temperature higher than 1700 K."

Jan 1, 2012

By B Crompton, A Berghorst, G Knox

Laboratory-based dynamic testing provides an invaluable tool in the development of rock bolts for use in highly stressed, burst prone rock masses. While in most cases the laboratory-based test method is not a direct comparison to an in-situ installation due to the purely axial loading and variations in boundary conditions, it does provide an indication of the performance of the tendon system under dynamic loading. The aim of the research described in this paper is to provide an understanding of the effect of the impact velocity of the impact mass during a laboratory-based dynamic test. Understanding the effect of boundary conditions of laboratory testing will improve Geotechnical Engineers understanding of the performance in an in-situ installation. In addition, due to the limited number of dynamic test facilities, an understanding of the effects of the boundary conditions will aid in the comparison of test results for different products from different test facilities. The research was conducted using an impact tester, whereby a known mass is raised to a known height defining the kinetic energy and velocity of the mass at the point of impact with the test sample after release. The impact velocity was varied between 2.7 m/s and 5.4 m/s, while the kinetic energy of the mass was maintained at 11.5 kJ. While a correlation between the impact velocity and strain rate of the system tested was established, due to the properties of the system tested, the range of impact velocity on which dynamic tests were conducted was insufficient to result in a considerable change in the average impact load, the cumulative proximal displacement and the cumulative maximum energy absorbed over multiple impulse. However, due to the reduction in the momentum of the impact mass the impact duration and displacement during each impulse in the series of impulses reduced. CITATION:Knox, G, Berghorst, A and Crompton, B, 2018. The relationship between the magnitude of impact velocity per impulse and cumulative absorbed energy capacity of a rock bolt, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 160–169 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By J. M. Cases

Study of the normal interaction between flotation collectors and the silicates through measurement of the electrokinetic potential carried out by the streaming potential and flotation recovery methods indicates that the interaction is wholly 07 partly of electrostatic origin. In some cases, it partly consists of the chemical affinity of the polar head of the collector for the active surface sites. Reagents composed of a polar head and a paraffinic chain and forming micelles in solution were used as flotation collectors. They are sodium dodecylsulfate (anionic collector) and dode-cylammonium chloride (cationic collector). The adsorption isotherms on biotite of alkylamine chloride having 10 to 18 carbon atoms in their chain all show a sharp change in slope relevant to the condensation of alkylammonium ions into bidimensional phase.1-1 Condensation is possible because of the relative homogeneity of the adsorbing surface and of the very strong lateral binding forces through Van der Waals type bonds in the adsorption layer. The different isotherms are seen to coincide when, instead of the equilibrium concentration, the under-saturation ?µ = kT In C/C, is plotted in abscissa, C representing the concentration of the solution with which the adsorbed layer is in equilibrium and C, the saturation concentration of micelles in solution or. critical micellar concentration. More particularly, the undersaturation ?,u1*, corresponding to a surface coverage 6 of 0.5, is equal to Since silicates immersed in aqueous solutions show a surface charge which is a function of pH, it is of primary importance to study the influence of this parameter on the adsorption of collector ions acting as Strong electrolytes in the pH range where they are utilized. The aim of this present paper is to determine by studying electrokinetic phenomena and recovery curves effectuated with a cationic collector and a anionic collector, the nature of the normal adsorbate-adsorbent interaction. Tables 1 and 2 sum up part of the results previously obtained'H11 for the determination of the point of zero charge of the silicate studied by the streaming potential method. Throughout the remainder of this paper, the surface charge will be considered positive for all values of pH below the point

Jan 1, 1971

By Philip B. Bucky

CONTENTS [PACEPACE r. What Is a Rock Burst?2 4. How Can Rock Bursts Be Predicted? . 35 Jack Spalding2Jack Spalding35 A. F. Robertson 2, 5A. F. Robertson35 W. R. Crane 2A. B. Yates and P. J. Shenon. . . . 35 G. S. Rice 2W. R. Crane 35 P. J. Shenon 2G. S. Rice 35 L. C. Graton 2B. F. Tillson 36 2. What Are the Causes of Rock Bursts? 6 5. How Can Rock Bursts Be Controlled?. 36 Jack Spalding6Jack Spalding36 A. B. Yates and P. J. Shenon . 7, 12, 29A. F. Robertson 36 A. F. Robertson 12, 28W. R. Crane37 W. R. Crane 15A. B. Yates and P. J. Shenon. . . . 37 G. S. Rice 15Oscar Weiss38 Oscar Weiss15G. S. Rice37, 42 P. B. Bucky21R. D. Hoffman42, 43 P. H. Bird 21, 26, 28R. D. Hall 42 M. K. Hubbert26R. H. Cromwell42 G. Wheeler 26. J. Shenon 42 B. F. Tillson26, 28P. B. Bucky42, 44 T. T. Read 27B. F. Tillson 42, 44 A. B. Yates 43, 44 3. How Can Rock Bursts Be Prevented? . 30P. H. Bird 43 Jack Spalding. . . . • . • • • • . 306. General Discussion . A. B. Yates and P. J. Shenon. . . . 31Jack Spalding44 A. F. Robertson32R. D. Parker49 W. R. Crane 35C. Baring Horwood 51 G. S. Rice 35P. B. Bucky 52] FOREWORD THIS symposium brings together points of view, experiences and ideas on rock bursts from a goodly portion of the globe. Some conceptions, particularly those regarding the necessity of depth, have been fairly well shattered, as we find that they are present in the water tunnels of New York, on the surface at marble quarries in Vermont, and in the coal mines of the United States, as well as in the deep mines of the South African and Kolar gold fields, and in the nickel, copper and gold mines of Canada. Their occurrence under such a variety of conditions is, therefore, a challenge,

Jan 1, 1942

By J. O. Brittain, E. P. Lautenschlager, F. Felberbauer

This investigation was undertaken to evaluate the effect of a dispersed phase in a iron upon the strain hardening and the stress dependency of dislocation velocity as inferred from the strain-rate sensitivitv. Experiments were made in a-iron specimens with controlled amounts of carbon and/or A12O3. They were tested at various temperatures between 195' and 373 'K under a variety of conditions oj-concentration, strain rate, and quench aging. The resulting yield strength, flow strength, and strain hardening increased with addition of Al2O3. The parameter m, measured from changes in strain rate, was xsed to describe the stress dependency of the dislocation velocity. m was found to increase with additions of A12O3, increasing carbon in solution, and with increasing temperature. When applied to a recent model for yielding based upon dislocation multiplication and velocity characteristics, the values of m alone did not successfully predict yielding for the materials of this investigalion, but had to be adjusted with a consideration of the number of unlocked dislocations nucleated heterogeneously at discontinuities or inclusions. The change of yield strength with Al2O3 Interpar-ticle spacing appeared to obey a theory of Orowan. EVER since the concept of dislocations has been introduced to explain plastic deformation in crystalline materials, the origin of dislocations and the source of the number of dislocations required to account for plastic deformation have been persistent questions. Ruling out the possibility of homogeneous nucleation,' Gilman2 drew attention to the various cases of heterogeneous nucleation as the source of dislocations, whereas Frank and Read3 introduced the Frank-Read source. However, Gil-man found that the Frank-Read sources did not play a dominant role in the deformation of LiF crystals, but that small precipitates are often, if not always, associated with the nucleation of dislocations. In LiF crystals, however, most of the dislocations arose through the multiplication of moving dislocations in a mechanism described by Koehler4 and Orowan,5 Thus, relatively few precipitates could account for a large number of dislocations. A similar observation of dislocation nucleation at inclusions of precipitates was made by Stein and LOW' on Si-Fe crystals. Their crystals contained

Jan 1, 1964

By N. Snyders, I. Mwandawande, S. M. Bradshaw, M. Karimi

"Computational fluid dynamics (CFD) was applied to predict the average gas holdup and the axial gas holdup variation in a 13.5 m high cylindrical column 0.91 m diameter. The column was operating in batch mode. A Eulerian-Eulerian multiphase approach with appropriate interphase momentum exchange terms was applied to simulate the gas-liquid flow inside the column. Turbulence in the continuous phase was modelled using the k-_ realizable turbulence model. The predicted average gas holdup values were in good agreement with experimental data. The axial gas holdup prediction was generally good for the middle and top parts of the column, but was over-predicted for the bottom part of the column. Bubble velocity profiles were observed in which the axial velocity of the air bubbles decreased with height in the column. This may be related to the upward increase in gas holdup in the column. Simulations were also conducted to compare the gas holdup predicted with the universal, the Schiller-Naumann, and the Morsi-Alexander drag models. The gas holdup predictions for the three drag models were not significantly different. IntroductionColumn flotation is an important concentration technology that is used in the mineral processing and coal beneficiation industries. The growing interest in the use of column flotation in mineral processing has been attributed to the simpler flotation circuits and improved metallurgical performance compared to conventional flotation cells (Finch and Dobby, 1990). Flotation columns have also found other applications outside mineral processing, such as de-inking of recycled paper (Finch and Hardie, 1999).In column flotation, a rising swarm of air bubbles generated by means of air spargers is employed to collect the valuable mineral particles and separate them from the gangue minerals in a countercurrent process. Wash water, which is continuously fed at the top of the column, is used to eliminate entrained particles and stabilize the froth. The column volume can be divided into two sections – the collection zone in which the bubbles collect the floatable mineral particles, and the cleaning zone (or froth zone) where product upgrading is enhanced through the removal of unwanted particles entrained in the water mixed with bubbles from the collection zone."

Jan 1, 2019

By Gerhard Derge, J. Warren Stewart

Extrusion processes are used in the commercial production of a wide variety of products, as indicated by the review presented a few years ago by D. K. Crampton.' Most writers have confined themselves to a general description of the equipment and products and the engineering aspects of the process. The few studies that have dealt with the metallurgical side of extrusion have been concerned primarily with an examination of the mode of flow of the metal during extrusion. This has been accomplished by the use of composite billets, by scribing grids on symmetrical sections of billets and observing the change of dimensions in the gridwork, or by examining microstructures in extruded sections.2"8 Ariotlier limitation of these original studies is that they were confined to the extrusion of very simple shapes, usually rods having a diameter of about one-fourth that of the billet. Tin is particularly well suited to the extrusion of collapsible tubes and similar shapes in which the extruded section is very small in comparison to the diameter of the billet or slug. In modern production, impact extrusion methods are generally employed, therefore the thickness of the slug is small compared to its diameter. Under these conditions the process differs considerably from the processes that have been most fully described in the literature, and it is known that the quality of the product is very sensitive to slight variations in any one of the many variable factors involved, such as coinposition and structure of the alloy, rate of extrusion, temperature, shape of punch and die. An exhaustive examination of all of the above-mentioned problems promises to produce so many data that it seems advisable to initiate the reports at this time, even though all of the factors outlined have not been examined fully, and to confine this paper to a description of the apparatus and method. Only tin and its alloys with small amounts of copper have been considered. These are the alloys most commonly used in this country for the production of the type of articles already described.

Jan 1, 1940

By Gerhard Derge, J. Warren Stewart

Extrusion processes are used in the commercial production of a wide variety of products, as indicated by the review presented a few years ago by D. K. Crampton.' Most writers have confined themselves to a general description of the equipment and products and the engineering aspects of the process. The few studies that have dealt with the metallurgical side of extrusion have been concerned primarily with an examination of the mode of flow of the metal during extrusion. This has been accomplished by the use of composite billets, by scribing grids on symmetrical sections of billets and observing the change of dimensions in the gridwork, or by examining microstructures in extruded sections.2"8 Ariotlier limitation of these original studies is that they were confined to the extrusion of very simple shapes, usually rods having a diameter of about one-fourth that of the billet. Tin is particularly well suited to the extrusion of collapsible tubes and similar shapes in which the extruded section is very small in comparison to the diameter of the billet or slug. In modern production, impact extrusion methods are generally employed, therefore the thickness of the slug is small compared to its diameter. Under these conditions the process differs considerably from the processes that have been most fully described in the literature, and it is known that the quality of the product is very sensitive to slight variations in any one of the many variable factors involved, such as coinposition and structure of the alloy, rate of extrusion, temperature, shape of punch and die. An exhaustive examination of all of the above-mentioned problems promises to produce so many data that it seems advisable to initiate the reports at this time, even though all of the factors outlined have not been examined fully, and to confine this paper to a description of the apparatus and method. Only tin and its alloys with small amounts of copper have been considered. These are the alloys most commonly used in this country for the production of the type of articles already described.

Jan 1, 1940

By Akira Yazawa

The continuous converting has attractive advantages, but further experimental studies on the slag are required, when the process is considered thermodynamically. The summarized experimental results, obtained with iron silicate slag and with ferrite slag and results relating to actual operation are described and discussed in this paper. At first, equilibrium relations at controlled oxygen potentials among three melts of silica-saturated iron silicate slag, white metal and copper are investigated. The results obtained for slag agreed with the thermo-dynamical predictions. Namely, to suppress a magnetite separation, the system should be at high temperature; in the case of the S02 gas of 10 kPa, for example, magnetite did not separate from the slag at 1300°C, but at 1250 and 1200°C the slag was saturated with magnetite even at lower SO2 pressure. Copper losses caused by dissolution of its oxide increased with increasing 5O2 pressure, and were slightly lower than those reported in previous papers without the matte phase. When the continuous converting slag does not contain any appreciable amount of silica - in contrast to the conventional smelting slag ferrite slag would form, but there was no published fundamental work on-ferrite slags. Hence, the melting behavior and activities of the system CaO-Cu2O-Fe2O3 have been investigated. The liquidus diagram in nitrogen atmosphere was, constructed using both thermal analysis and quenching method. The low liquidus temperature region without magnetite separation was found in the part of low content of Cu2O in the section Cu2O-CaO-Fe2O3 and Cu2O?Fe2O3¬CaO?Fe2O3. The activity of Cu2O in the system was also measured. Slags, composed-of CaO, Cu2O and Fe2O3, in platinum crucibles were equilibrated at 1250°C and controlled oxygen pressures. After quenching, the-composition of slag and platinum crucible were determined qualitatively. On the thermo-dynamic analysis of the results, iso-activity lines were drawn, and it was shown that the slag in the converting furnace of the Mitsubishi process exists in an adequate region of the composition triangle.

Jan 1, 1976

By Mark Jolly, Xiaojun Dai

"Foundry engineers in the traditional foundry usually regard the quality of casting component as the most important issue and leave the energy saving or energy efficiency as the subsidiary one. This frequently causes disproportionate energy consumption as a result of the inefficient casting processes used and increases the production costs. This paper presents the novel CRIMSON aluminium casting process and compares its facility and melting process with traditional melt furnaces and aluminium alloy melting process. A real example is investigated to demonstrate quantitatively how the traditional foundry wastes energy and what the improvement of energy efficiency can be achieved using the new CRIMSON method. The results of this investigation will help the foundry engineer recognize the importance of energy saving and demonstrate how to use this new technology to reduce production costs and carbon footprint without decreasing the quality of the cast component.IntroductionAluminium melting in metal casting industry is an energy intensive process where it is estimated that the energy consumption is in the order of 1,700 ~ 4,700 kWh tonne-1 in using crucible and natural gas [1]. Different countries may use different energy resources for aluminium melting: in US the main energy resources are natural gas, electricity and coke [2] and in UK most of the foundry use electricity, gas and oil as energy resources [3]. Due to the pressure of rising energy price and the strict environment law, it is anticipated that under the right socioeconomic conditions, the efficiency optimisation of industrial process can be an important step toward increased industrial sustainability [4]. In metal casting industry the energy efficiency of a casting facility depends largely on the efficiency of its melting and heat treating performance. In association with the two performances, over 60 % of the total process energy costs are represented in a typical casting facility [5] where there are huge opportunities for metal casting industry to adopt the best energy practices for potential energy saving. How to ameliorate the current processes for increasing energy efficiency will have a vital effect on reducing the production costs and increasing the competitiveness. For instance, by implementing some state of the art technologies such as the CRIMSON method in aluminium alloy casting will make use of such opportunities."

Jan 1, 2011

By K C. Runge, E Tabosa, A Jankovic

Flotation recovery in geometallurgical modelling is usually predicted based on relationships developed from batch flotation testing of different ore types. These batch flotation tests are usually performed at a constant set of operating conditions and at a fixed feed grind size P80. Usually the laboratory feed grind P80 is that which is expected to be produced in the full-scale flotation circuit for that particular ore type.Flotation recovery will be a strong function of the valuable mineral particle size distribution, with lower recovery of ultra-fines due to poor flotation kinetics, optimum recovery for the intermediate sized particles and lower recovery for the coarser particles due to poorer liberation of this fraction. This valuable mineral particle size distribution is not characterised by the solids P80 parameter alone. The proportion of material in each class will also be a function of the slope of the size distribution and the degree of preferential grinding of the valuable mineral in comparison to the total mass of the ore.This paper will demonstrate (through example) how these other size distribution parameters can change with a change in grinding technology, the size and operating conditions used in a grinding unit and the characteristics of the classification technology used in conjunction with the grinding unit. Case studies will be presented that demonstrate how this can result in these parameters being very different in laboratory testing to that produced in the full-scale comminution circuit. A rule of thumb that laboratory rod milling rather than ball milling produces a size distribution most similar to that of the full-scale grinding circuit will be challenged. These differences can result in a significant change in flotation recovery. It is therefore important to consider these parameters when developing a laboratory geometallurgical program, to enable more accurate prediction of the flotation recoveries that will be achieved in the full-scale process.CITATION:Runge, K C, Tabosa, E and Jankovic, A, 2013. Particle size distribution effects that should be considered when performing flotation geometallurgical testing, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 335-344 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By S. Carsten, S. Subramanian, R. Vasant Kumar, S. Vimalnath

"The effect of EPS components namely protein, polysaccharide and biosurfactant purified from Pseudomonas fluorescens was investigated for the bioremediation of Pb(II) ions in aqueous solution. Two parameters, namely the amount of EPS component and the concentration of Pb(II) ions were optimized for maximum Pb(II) ions uptake. The EPS components interacted with Pb(II) ions were characterized using energy dispersive X-ray analysis (EDAX) to ascertain the presence of Pb and by attenuated total reflection-Fourier transform infrared spectroscopy (ATR–FTIR) to reveal the functional groups involved in Pb(II) binding. The maximum Pb(II) binding capacities of protein, polysaccharide and biosurfactant were found to be 11.4, 0.55 and 0.11 mg mg-1 respectively. The biosorption processes followed the Langmuir model. The Gibbs free energy (?G0) values of -23.6, -20.9 and -23.2 kJ mol-1 for Pb(II) biosorption by protein, polysaccharide and biosurfactant respectively, attested to spontaneous, chemisorption processes. The ATR–FTIR results revealed the presence and involvement of amino, hydroxyl, carboxyl, phosphate, and methyl functional groups in Pb(II) binding and EDAX analysis confirmed the interaction of Pb with EPS components. The Pb(II) binding mechanisms of EPS have been discussed. The results demonstrate the potential of the purified EPS components of P. fluorescens for removal of Pb(II) ions from aqueous solution INTRODUCTION Waste water containing toxic metals from various industries pose a serious threat to human health and ecosystem. For treating such waste water, conventional methods like chemical precipitation, coagulation, evaporative recovery, electrodialysis, floatation, flocculation, ion exchange, reverse osmosis, nanofiltration, ultrafiltration are used (Lakherwal et al., 2014). These methods have some disadvantages like toxic sludge generation, incomplete metal removal and high cost (Singh and Gadi, 2012), necessitating the search for cheaper and efficient alternative methods. Bioremediation is one of the emerging alternatives where bacteria, fungi, yeast, algae and other biological substances are used as sorbents to remove toxic heavy metals (Vijayaraghavan, et al., 2015). Recently, the bioremediation potential of extracellular polymeric substances (EPS) of microbial origin has attracted attention. However, for Pb(II) removal, there is a paucity of literature focusing on EPS."

Jan 1, 2018

By Binbin He, Baiwei Lei, Rehamutula·Rouzi, Zheng Wang, Chao Li

Methane explosions are highly destructive and constitute a primary hazard affecting mine safety. Seals are commonly employed to obstruct the propagation of methane explosions within tunnels, with the aim of reducing the damage caused by methane explosions. In order to study the influence of the seals’ position on the parameters of methane explosion damage, this study takes the Lake Lynn Experimental Mine No. 501 in the United States as a background case. It investigates the methane/air explosion damage parameters at different positions of seals in a fully sized roadway using the GASFLOWMPI code. The coupling mechanism between methane explosion gas expansion and reflected waves is analyzed. Finally, the variation patterns of explosion damage parameters are analyzed based on explosion damage criteria. The results show that as the distance increases between the seal and the explosion source, the maximum overpressure and impulse at the seal decrease exponentially, and the decrease is more significant when the seal is closer to the explosion source. The maximum velocity and maximum dynamic pressure increase first and then decrease, reaching their maximum values at approximately 115 m. They are approximately 163.355 m/s and 30.485 kPa, respectively. According to the analysis of explosion damage criteria, it is found that overpressure damage is the main form of methane explosion damage. But the damage of impulse and dynamic pressure is not be ignored. The relative position between the seal and the gas expansion area significantly impacts the parameters of methane explosion damage due to the coupling effect of gas expansion and the overpressure reflected wave from the seal. When the seal is set in the gas expansion zone, the further the seal is from the explosion source, the greater the dynamic pressure damage and the more minor the overpressure and impulse damage. The closer to the explosion source, the more significant overpressure and impulse damage changes. When the seal is set outside the gas expansion zone, the further the seal is from the explosion source, the more minor the overpressure and impulse damage to the seal, and the dynamic pressure damage increases first and then decreases.

Apr 24, 2024

By B. Barry, M. S. Klima

"Testing was conducted to evaluate the effects of hydroacoustic cavitation (HAC) treatment on two bituminous coal slurries and the subsequent separation of each slurry in a classifying hydrocyclone. HAC treatment was performed using a pilot-scale circuit fabricated by Furness-Newburge Inc. The circuit was designed to induce cavitation by means of flow through an ultrasonic resonator chamber or enhanced cavitation by initial flow through a cavitation chamber followed by flow through the ultrasonic chamber. The test materials were nominal -1,500-micron and -150-micron Illinois-basin bituminous coal slurries, which were obtained from an operating coal preparation facility. After 5 sec of HAC treatment, the median size of the -1,500-micron material was reduced, with ash values for certain size fractions decreasing more than 5 percent compared with untreated samples. Extending treatment time led to greater degradation of the +1,180-micron material and an increase in the -25-micron material, with ash reductions occurring for material in the -850+150-micron size range. Size degradation was less for the -150-micron material. Subsequent separation of the treated slurries was carried out in a hydrocyclone with diameter of 102 mm. HAC treatment led to a decrease in the ash value and an increase in the heating value of the underflow stream compared with the feed material. For example, the ash value was reduced by about 16 percent for the -1,500-micron material and 25 percent for the -150-micron material with heating value increases of 7 and 33 percent, respectively, after HAC treatment. Overall, HAC treatment appeared to have a slight effect on the size selectivity curves.IntroductionUltrasound in the range of 20 to 1,000 kHz, referred to as power ultrasound, consists of high energy waves that can create zones of compression and expansion when used to irradiate liquids (Frederick, 1965; Leighton, 1994; Mason and Lorimer, 1988). This action generates varying pressure regions leading to cavitation or the formation, growth and near-immediate collapse of microscopic voids or bubbles (Frederick 1965; Leighton 1994; Mason and Lorimer 1988). Collapse occurs when the bubble reaches critical size and cannot absorb additional sound field energy, and the critical size is governed by the ultrasound frequency (Shchukin et al., 2011)."

Jan 1, 2015

The Teutonic Bore deposit lies in a major greenstone belt within the Archaean Yilgarn craton of Western Australia. It occurs towards the base of a suite of tholeiitic basalts, some 100 m above a felsic volcanic pile of rhyolitic composition. Sediments comprise a minor, albeit important, percentage of the mine stratigraphy.The deposit consists of a single, steeply dipping lens of massive sulphides totalling 1.4 million tonnes grading 4.16 per cent Cu, 16.4 per cent Zn, 1.22 per cent Pb and 203 g/t Ag. In addition, cross cutting "stringer" mineralisation in the footwall contributes a further 0.75 million tonnes at 2.38 per cent Cu, 1.92 per cent Zn and 52 g/t Ag to the mining reserves. Principal primary sulphides in massive and disseminated mineralisation are sphalerite, pyrite, chalcopyrite and galena, while minor amounts of arsenopyrite and argentiferous tetrahedrite are also present. Weathering has affected the primary mineralogy down to at least 90 m, resulting in a strongly leached oxide profile to about 85 m, overlying a thin, erratic zone of chalcocite supergene enrichment.Lateral metal zoning is marked both in massive sulphide and stringer mineralisation, with Cu/Zn ratios decreasing away from the centre of the orebody. Alteration is well developed in association with footwall stringer mineralisation, changing from a central Fe-Mg carbonate, chlorite and silica alteration zone below the massive sulphides to an outer halo of sericitisation. The spatial distribution of these minerals is patchy. Geochemically, the footwall alteration zone is characterised by central Cao, Na20 and Sr depletion (with less regular enrichment of SiO2 , Fe and MgO), surrounded by a peripheral zone of K20 enrichment.Evidence supports a classic volcanic-exhalative origin, involving submarine discharge on the flanks of a rhyolitic dome and accumulation of the massive sulphides in a local palaeotopographic depression. The sulphides overlie their feeder zone as shown by alteration and stringer mineralisation. Tholeiitic wallrocks are thought to be genetically unrelated to the mineralising solutions, although their presence as a cap over the felsic volcanics may have permitted the build up of a circulating metalliferous brine system prior to sulphide deposition.

Jan 1, 1984

By Henry M. Howe, W. P. Barba

When this country went into the war, but two concerns, The Bethlehem Steel Co. and The Midvale Steel and Ordnance Co., knew how to make steel fit for great cannons and at these concerns there were relatively few men who knew the whole art. Fortunately, certain of these men put their knowledge at the service of the Government, and proceeded to instruct the metallurgists at the arsenals and at various steel works. Doctor Howe, then chairman of the Engineering Division of the National Research Council, suggested that this work might be facilitated, and the number of effective gun-steel makers thereby increased, if a detailed description of the best practice could be written, giving the reasons for the various steps, and issued with the endorsement of a committee composed of those who were evidently the most competent authorities. It was thought that something would be gained by clarification of the subject, and something by the eminent authority of the members of the committee. To that end, the Engineering Division appointed a committee, consisting of the gentlemen whose names follow, to mention on1y those who retained their connection with it. At this time there were serious difficulties in the manufacture, for the Government. of aircraft and high-speed engine crankshafts, of certain ordnance forgings, and of shells for both the Army and Navy. This Committee was asked to study and report upon these, with a view to betterment of practice. There were indications that the source of some of the difficulties went back to the melting of the steel and the production of the ingot. Hence, the committee first studied steel melting and ingot production, in order to guide the wartime manufacturers to an even larger percentage of useful production from the steel initially melted. Committee on Steel Ingots W. P. Barba, chairman, Ordnance Dept., U. S. A. (formerly Vice Pres. & Gen. Mgr., Midvale Steel Co., Philadelphia). George K. Burgess, Chief of Division of Metallurgy, U. S. Bureau of Standards, Washington, D. C. Henry M. Howe, Then Chairman Engineering Division, National Research Council.

Jan 1, 1922