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By L. Filip

The roast-leach-electrowinning (RLE) process for zinc was modified to treat two typical complex concentrates containing zinc, lead, copper, gold and silver. Laboratory testwork results indicated that the optimum roasting temperature ranged from 700 to 800°C, in order to produce acceptable residual sulfur levels. The calcined concentrate was subjected to a three-stage leach sequence. The resulting leach solution was purified by hematitic precipitation and directed to the recovery of copper and zinc by solvent extraction and electrolysis. Alkaline smelting and subsequent electrolytic purification recovered the lead and precious metals from the leach residue. A flowsheet was developed based on the laboratory testwork results, and demonstrated in a large-scale pilot plant. The recoveries produced during the pilot plant operation ranged from 90 to 92% for zinc and copper, 85% for lead and 90% for gold and silver, respectively.

Jan 1, 1999

By Thierry Bernard

Since the signature hole method principle has been described in the 80's, there has always been a lot of controversy about it. The theory is easy to understand but when it comes to apply it for predicting vibration level, optimizing timing to reduce PPV or shifting frequencies, it’s not always working as expected. Simulations show waveforms that don't make any sense or predictions that are far away from actual results.

Jan 1, 2012

By Beverly W. Dunning

The effect of vacuum melting on the elimination of gases and nonmetallic inclusions for six low-alloy steels was investigated. The purpose of these studies was the analysis and comparison of differences in gas content and inclusions in air-melted and vacuum-melted steel. Data obtained from melts of 1-1/4 to 20 pounds indicate that vacuum melting decreases the number and size of nonmetallic inclusions and at the same time increases the degree of dispersion of the remaining inclusions. These improvements are undoubtedly related to the elimination of approximately 80 percent of the nitrogen and 90 percent of the oxygen as well as most of the undesirable metallic trace impurities.

Jan 1, 1961

By E. R. Dotson

Kaolin is an important industrial mineral. It has unique properties, which combined with its low cost, make it suitable for use in a wide variety of products. Kaolin is defined as "any of a group of clay minerals, including kaolinite, nacrite, dickite, and anauxite, with a two-layer crystal in which silicon-oxygen and aluminum-hydroxyl sheets alternate; approximate composition is AlZ03-ZSiOZ-1/ ZHZO".-The kaolin discussed here is composed chiefly of the mineral kaolinite. Kaolin is also commonly referred to as "china clay". Approximately 4.9 kkg (5.4 million short tons) of kaolin was sold or used in the United States, and .8 million kkg (.9 million short tons) was -exported in 1974. In domestic usage, paper coating and filling accounted for 43% of the total, fol-2/ lowed by refractories, rubber, and ceramics.-Figure 1 shows the amount of kaolin sold or used by domestic producers for specified uses for the years 1963-3/ 1973.- Kaolin was produced at mines in 14 states, but Georgia accounted for 75% of the 1974 domestic production. The average value for all grades was $36.00/kkg 4/ ($32. 67/ton) .-

Jan 1, 1977

By D. Warkentin, M. Tomlinson, A. Nacu

"This study focuses on comparing the “blinding” effectiveness of various organic additives as part of a general review of using organic additives to mitigate preg-robbing and improve gold recovery during cyanide leaching of carbonaceous gold ores. The laboratory results compared the impact of various organic additives on the prevention of gold adsorption using both activated carbon and ore samples containing carbonaceous matter, generally referred to as total carbonaceous matter (TCM). Although several organic reagents were found to have a significant blinding effect on activated carbon, these results did not translate into increased gold leaching efficiencies with actual ore samples.INTRODUCTION Preg-robbing refractory ores, which contain carbonaceous matter, have been problematic in cyanide plants for many years. In industry, preg-robbing by carbonaceous matter may be mitigated using various techniques including flotation, to remove the carbonaceous matter; addition of blinding agents, to passivate the carbon surface and prevent adsorption of gold cyanide complex; roasting, to partially or fully destroy the carbonaceous matter; chemical oxidation (Abotsi & Osseo-Asare, 1986); pressure oxidation; or microbial deactivation (Dunne, Staunton, & Afewu, 2013). Carbon-in-Leach and Resin-in-Leach are also used as process alternatives in which activated carbon or resins are used to compete with the carbonaceous matter for gold cyanide adsorption. For highly preg-robbing ores, thiosulphate leaching may be considered as an alternative to conventional cyanide chemistry (Baláz, et al., 2000). Natural carbonaceous matter is composed mainly of hydrocarbons, organic acids, and graphitic/amorphous elemental carbon. Natural elemental carbon that behaves as activated carbon is considered to be the main reason for preg-robbing, although the true nature of this phenomenon is not fully understood (Tan, Feng, Lukey, & van Deventer, 2005). In general, the hydrocarbon fraction is assumed to have negligible interaction with gold, while organic acids, such as humic acids, may form complexes with gold, inhibiting its extraction in cyanide solutions. Organic reagents have been used for blinding carbonaceous matter in gold ores prior to cyanidation. Abotsi & Osseo-Asare (1987) tested various organic compounds, with two possible effects in mind. First, the organic compounds were expected to adsorb onto the surface of the solids as anionic/cationic species; the resulting electrostatic interactions between the Au(CN)2- anion and the negatively/positively charged surface would inhibit/enhance the gold uptake. Second, the organic reagents were expected to coat the surface of the carbonaceous component in the ore, limiting the available adsorption sites and reducing gold losses. Optimal reagent dosage depends on ore mineralogy, maturity and surface area of the carbo"

Jan 1, 2019

By D. R. Schmitt, N. Ong, R. S. Kofman

Shales and mudstones comprise about 75% of all the sedimentary rocks. In, particular, organic rich shales are considered as a petroleum source rock and more recently with the advent of hydraulic fracturing technology to be a reservoir in their own right. In this sense, the aforesaid motivates our work with laboratory measurements of elastic properties of these geologic materials, which are known to be anisotropic. As such, assuming Vertical Transverse Isotropy (VTI) symmetry, the dynamic and static moduli of a series of cores from various geological formations in Alberta, Canada are simultaneously investigated as a function of confining pressure using the ultrasonic pulse transmission method and strain gages. Dynamic moduli were obtained from ultrasonic P- and S-wave velocities measured on a prism cut with faces perpendicular, parallel and oblique to the assumed vertical axis of symmetry. Static moduli were calculated from strain-stress curves obtained along the directions perpendicular and parallel to the assumed axis of symmetry as well. Velocity measurements show that samples are highly anisotropic, but that the pressure-dependent behaviour of the wave speeds differs. VP(90°) and VSH(90°) both with layer parallel propagation and polarizations change little with pressure while VP(0°) and VS(0°) (both with layer perpendicular propagation) display significant nonlinear responses particularly at pressures < 25 MPa. These characters transfer to the derived full set of elastic constants. In order to effect a proper comparison of the dynamic and static moduli, we convert the dynamic elastic constanst to linear compressibilities pependicular (Kdyn1) and parallel (Kdyn3) which are directly comparable to the static tangent compressibiities obtained by differentiation of the observed strains. Both sets highlight the anisotorpic nature of the material but most interestingly Kdyn1 _ Ksta1 but Kdyn3 > Ksta3 by nearly 40% for one of the samples. The other samples measured respond similarly suggesting that conceptually the structure of such materials could be considered to be constructed of alternating stiff or compliant layers. This finding has implications in the response of the formation to stress particularly during hydraulic fracturing and the interpreation of acoustic logs in providing appropriate measures of elastic properties for engineering purposes.

Jan 1, 2015

By M. M. Fine

"Button" type ore from the Cason mine, Batesville, Ark., can be up-graded to plus-40-percent manganese by mineral-dressing procedures. A simple process including gravity concentration and. magnetic separation yielded more than 50-percent recovery of concentrates containing 38.1 to 40.6 percent manganese. These values in turn could be raised to 41.4 and 42.8 percent, respectively, upon sintering to conform to size specifications. The Bureau of Mines in the past has surveyed and tested many manganese ores and prospects in an endeavor to alleviate the shortage of manganese. The present period of emergency again emphasizes the strategic position of the metal, and manganese investigative work is being stressed to find new ore bodies and to apply newer beneficiation techniques to the known deposits.

Jan 1, 1953

By Lizelle Glaner

An investigation was carried out by Mintek to investigate the influence of additions of gold to ?Fecraloy?, alloys based on Fe-Cr-Al. The aim was to try and improve the oxidation resistance of the ?Fecraloy? alloys at elevated temperatures over extended periods of time. The ?Fecraloy? alloys are very oxidation resistant alloys already employed in industry as substrates for metallic catalysts in auto-catalyst systems for high performance cars. Since their life and durability is limited by the slow, but steady, oxidation of the substrates, any change in the growth or stability of the oxides could be an improvement.

Oct 1, 2003

By W. Miola, R. V. Ramaoi

"The MSHA prescribed method for the determination of quartz in airborne respirable-dust samples from underground coal mines is the P-7 method, a combination of /ow-temperature, radio-frequency ashing (LTA) and infra7 red analysis (IR). There is no prescribed procedure for quartz analysis in bulk samples of coal and host rock. Dispersive infrared (IR), Fourier-transform infrared (FTIR) and X-ray diffraction (XRD) methods are most commonly used for the analysis of quartz in powders. Several aspects of the experimental procedures, such as the preparation of the analysis sample from bulk samples, ashing techniques, scanning procedures, peak measurement location, calibration techniques, sample amounts, size consist and data interpretation, affect the results from each of the methods differently. Significant differences in analytical results obtained from X-ray diffraction (XRD) and infrared spectroscopy (IR) on the same samples are reported. All studies point to the need for reliable quartz analysis methods.In a recent research program, a procedure for preparing bulk-coal and host-rock samples for quantitative quartz analysis was developed. Further, the results from X-ray diffractometry and infrared spectroscopy for quartz content on identical samples were compared. Calibrations with pure and mixed standards were used to assess the influence of particle-size distribution, matrix and calibration on the analytical results. In this paper, several issues concerning the measurement of quartz in the samples of coal, host-rock and airborne respirable dust from mines are outlined and quantified. IntroductionThe literature on coal-mine airborne-dust control has identified a need for a better understanding of the sources, mechanisms and amounts of quartz in mine airborne respirable dust (Althouse, 1984; Jankowski, Nesbit and Kissel, 1985; Ramani 1988; Qin, 1988; Bhaskar and Xu, 1990; Bhaskar and Li, 1992; Ramani, Qin and Miola, 1991 ). To understand the quartz content in the source materials, bulk samples of coal and host rock must be analyzed. Establishing an analysis procedure for determining the quartz content in bulk-coal and host-rock samples is necessary for identifying the sources of quartz in mines; for establishing the relationships between the quartz contained in the source and in the airborne dust; and for controlling the content of quartz in the mined product and in the airborne respirable dust."

Dec 1, 1996

By Gregory Harbort, Sarah K. DeBono, Alan J. Monaghan, Emmanual V. Manlapig

"The Jameson Cell is a type of flotation machine in which air and pulp are brought together in a vertical tube called a downcomer. Within the downcomer the air and pulp are dispersed into a dense foam of fine bubbles, which creates a favourable environment for bubble-particle collision and subsequent collection of hydrophobic particles. The intense collection zone within the downcomer can be considered similar to the zone between the rotor and stator in mechanical flotation cells.Research into the bubble-particle collision and fluid dynamics of mechanical cells rotor-stator zone has been limited by the difficulty of achieving accurate measurements in production sized machines. With the Jameson Cell the downcomer is largely external and separated from the flotation tank, allowing ready access to the primary contacting zone for measurement and analysis.An investigation has been undertaken into the operating characteristics of the downcomer relating to bubble-particle collision. An effective mapping of the downcomer has been made through measurements of void fraction and bubble size taken across cross sections of the downcomer. Analysis of these measurements has provided an interpretation of the variations in the air and fluid dynamics, bubble size and distribution throughout the downcomer chamber.Existing models of bubble-particle collision efficiency are reviewed in respect to the collected information and refinements conducted. The area of maximum bubble-particle collision efficiency is defined. Findings are related to operation within the rotor-stator zone of mechanical flotation cells."

Jan 1, 2003

By Y. Luo

The rock breakage process in drilling is a main source of noise in roof bolting operations, especially when hard rocks are encountered. Proper control of drilling operation can provide an opportunity to improve energy efficiency of drilling and to reduce noise and heat generated from bit-rock friction. Drilling tests have been conducted in laboratory settings to confirm this noise-reduction strategy. Preliminary results show that the drilling parameters, penetration and rotational rates can be controlled to achieve in a desirable range in drilling medium hard rock. Based on the theoretical and experimental studies, rational drilling control strategy is developed for noise control while maintaining a safe and productive roof bolting operation. Applying this strategy in underground roof bolting operation, the noise exposure of roof bolter operators will be significantly reduced.

Aug 1, 2013

By Eulogio Velasco, Jose Nino, Marcos Cardoso

"Recycling of aluminum scrap for production of secondary alloys used for automotive applications is increasing continuously. Automotive alloys require a strict control to remove alloy impurities, inclusions and excess of magnesium. The advantage of aluminum is its recyclability with large energy and emission savings with minimal loss in material properties. The aim of this work is to study the magnesium removal from recycled aluminum by chlorine injection in a reverberatory furnace, and removal by an oxidation process at high temperature in an industrial rotary furnace.The magnesium removal by gas injection is carried out by the reaction between chlorine and magnesium, with its efficiency associated to kinetic factors. In the rotary rapid oxidation of aluminum and magnesium elements at high temperature is characterized by the formation of surface films composed of magnesium oxide. Additionally this work reviews the benefits of an efficient demagging process.IntroductionThe advantages of using light alloys for automotive applications include fuel economy improvement, greenhouse gas reductions and polluting emissions. These characteristics makes the aluminum alloys an attractive option for automotive components such as powertrain products and other critical parts like cylinder heads and blocks. [1]Aluminum alloys coming from recycled automotive components, used beverage cans (UBC) and wrought alloys have positive effects in the energy savings and current environmental trends. Producing a scrap recycled aluminum ingot consumes approximately 5% of the energy required to produce a primary aluminum ingot from bauxite ore. [2]"

Jan 1, 2011

The major components of sylvinite ores, sylvite (KCl) and halite (NaCl), are separated by flotation. Since both these minerals are water-soluble, the process is carried out in a saturated brine, 6~7 mol/L aqueous solution of NaCl and KCl. C16~C22 primary amines, utilized as a collector, are practically insoluble in water. In commercial potash ore flotation operations these amines are melted by heating up to 70~90°C. They are then neutralized with hydrochloric or acetic acids, and such a hot emulsion/dispersion is introduced to the flotation pulp (which is at room temperature). This is immediately accompanied by the appearance of a white precipitate in the system. As our measurements indicate, the Krafft point of dodecylammonium chloride in concentrated electrolyte solutions is much higher than 80°C, and the Krafft point of C16~C22 amines is substantially higher than that. Introduction of a hot amine emulsion into a pulp, at temperature much lower than the Krafft point for the utilized amines, must cause precipitation of the amines. Some of these species are obviously flotation-active. It is interesting to observe that in summertime, when temperatures are high-er, longer chain amines perform better. It demonstrates that the colloidal amine species that precipitate serve as active species in the potash flotation. Therefore, at higher pulp temperatures, when the temperature difference between the pulp temperature and the Krafft temperature of the utilized amine is not sufficiently large, a longer chain amine, the amine with a higher Krafft point, is more efficient. The results reveal that premixing of an alcohol such as MIBC (common frother) with the amine significantly improves flotation performance of the amine. In the presence of such an alcohol the amine disperse system becomes less turbid, and the rheology of the system less non-Newtonian. All this indicates that MIBC, which does not operate as a frother in a potash flotation system, when used as a co-surfactant, enhances the dispersion of the amine colloidal system. The appearing colloidal species perform as an active form of the collector.

Jan 1, 2014

By R. D. Govier

The U.S. Bureau of Mines has developed a thin-film X-ray fluorescence technique to rapidly determine Cu, Ni, Co, Fe, and Cr in super alloy leach liquors. Total analysis time per sample was less than 15 min, as opposed to several hours for traditional wet chemical methods. Precision and accuracy were checked by replicate analyses of solutions similar in composition to leach liquors, whose analyte concentrations were well known. Coefficients of variation for all elements were found to be less than 2 pet. With the exception of the results for Fe, all relative errors of estimation were also found to be less than 2 pet. Bulk liquids are not introduced into the spectrometer; thus, the potential for damage to the instrument by leakage of corrosive liquids is eliminated.

Jan 1, 1989

By Michael A. Markowitz, Alok Singh

"Molecular self-assembly of phospholipids and other amphipathic molecules offers a versatile approach to form self-organized microstructures in various morphologies. Stabilization of microstructures in specific morphologies by polymerization renders them useful for practical applications in areas ranging from controlled release technology to template mediated synthesis of metals. Our efforts are focussed on the development of polymerizable biomembranes derived from phospholipids, their properties and utility e.g., as stable templates for studying chemistry at the lipid interface. Polymerized vesicles formed from mixtures of 1,2-bis(tricosa-1 O,12-diynoyl)-sn-glycero-3-phosphocholine, 1, with corresponding lipids having phosphohydroxyethanol,2, or -hydroxypropanol,3, headgroups have been used in electroless metal plating of vesicle surface with gold utilizing selective binding of Pd(NH3)4 2 + to 2 or 3. The surface bound palladium ion served as catalyst for metalization. Metalization of polymerized vesicles constructed from charge neutral diacetylenic phosphocholine,1, did not occur using this process. The headgroup structure of the negatively charged phospholipids and the degree of vesicle polymerization had an effect on the stability of the vesicles after metalization. Vesicles formed from a mixture of 1 with polymerizable diacetylenic phosphatidic acid, nonpolymerizable 1,2- dipalmitoyl phosphohydroxyethanol or 1,2-diacyl phosphohydroxyethanol (from soy lecithin) were not stable to metalization process. The metal coating of the vesicles was examined by electron diffraction and revealed that the gold metal on vesicles was polycrystalline and face centered cubic. The results demonstrate the utility of polymerized synthetic membranes as template for easy and efficient synthesis of nanoparticles. IntroductionPhospholipids, synthetic or natural, provide a simple and straight forward route to construct membranes in a variety of morphologies due to their inherent property of selforganization in the presence of water[1]. Vesicles are closed spherical structures comprised of concentric walls made from lipid bilayers. Vesicles are morphologically simple structures with enormous technological potential. Polymerizable phospholipids prepared by incorporating a polymerizable group in the molecules demonstrate physical properties comparable to their non-polymerizable counterparts and have the added virtue of providing enhanced physical and chemical stability to the membranes[2,3]. The size, shape and properties of the organized assemblies are dependent on the lipid structure and the nature of the aqueous environment[4,5]. The headgroup geometry, surface charge density, and spatial arrangement of the phospholipids are known to affect the surface behavior of the lipid membranes, which is evident through their interaction with other molecular (hormones, antigens, antibodies etc) or lomc species. Since phospholipid headgroup structure and charge can be modified either synthetically or by chemical perturbation of the aqueous medium (e.g., pH or ionic strength), phospholipid membrane surfaces offer a potential for developing novel strategies in those areas which involve the use of molecular reactive sites. One such strategy which could be envisioned explores the use of molecularly engineered phospholipid assemblies to design and prepare template structures to regulate formation of ordered materials [6]."

Jan 1, 1994

By S. J. Zagula

Improved desulfurization of Illinois coals is a widely Shared research goal. The development of a physical cleaning strategy and the results of a project to demonstrate technical and economic feasibility of producing a low sulfur compliance coal from the Illinois Basin are reported. Processing flowsheets to extend or retrofit existing preparation plants are considered. Comminution, conventional and micro-bubble flotation, and selective agglomeration technologies were investigated to maximize pyrite rejection while maintaining high product yield. Batch bench scale testing was followed by continuous pilot plant studies. Parameters included grind size, flow rates, pulp density, aeration, agitation, and reagent dose. An economic evaluation of targeted processes is included.

Jan 1, 1987

By A. B. Coates

During the last three years the use of ethylene glycol dinitrate4 (E.G.D.) as at low-freeze (L.F.) agent in place of nitropolyglycerin has become common in the manufacture of explosives of the dynamite type. The usual proportion of D. G. D. in the explosive "oil" is 25 per cent; the remainder, 75 per cant, is regular nitroglycerin. These proportions were probably selected as a continuation of the practice of 25 per cent nitropolyglycerin and 75 per cent regular nitroglycerin.

Jan 1, 1929

By Andrew L. Puwis

Methodologies were presented for computing the thermal gradient associated with single crystal solidification in macroscopic computer modeling. The. heat transfer, and solidification of a shaped investment casting model were simulated using properties from three different alloys. Following the simulation of solidification, the resultant thermal gradients (G) and rates of solidification (R) from representative points were extracted in various ways and compared: It was discovered that alloy properties have a strong influence on the computed thermal gradient and rate of solidification for the three methods investigated. Data also showed that the computed gradient for each model was very different depending on the temperature range used to compute these values.

Jan 1, 1994

During incineration of municipal solid waste (MSW), some heavy metals and other environmentally harmful elements are liberated into bottom ash. The stricter environmental regulations require a higher immobilization efficiency of the ash before its safe disposal and application. Vitrification is one of the promising options, and has the advantages of high destruction efficiency of organics, high immobilization of heavy metals, and large volume reduction. The main components of the vitrified slag are SiO2, CaO, Al2O3, Fe2O3, Na2O and MgO, and the compositions have direct effect on the glass formation during vitrification, and further on the physical and mechanical properties of the slag. To provide essential data for the utilization of bottom ash as vitrified slag, the phase relations and thermodynamic properties of the oxide system need to be systematically investigated. In the present study, the liquidus temperature of the typical vitrified bottom ash slag was determined by using differential scanning calorimetry (DSC) measurement. High temperature equilibrium experiments were conducted to investigate the phase relations of the sub oxide system of CaO-SiO2-Na2O by means of Scanning Electron Microscopy (SEM), Electron Microprobe Analysis (EMPA) and X-ray Diffraction (XRD). The results show that the melting temperature of the vitrified bottom ash is around 930°C. In the CaO-SiO2-Na2O system with less than 50 mol% SiO2, the liquidus temperature de-creases with increasing amounts of Na2O along the tie-line of Na2O-Ca3Si2O7. Two compounds Na2Ca3Si2O8 and Na4Ca8Si5O20 are identified in the oxide system.

Jan 1, 2014

By M. E. Tyrrell

Mixtures of zirconium diboride and iron, cobalt, and nickel were resistance sintered to high-density compacts using modified electric welding equipment. To evaluate the use of iron, cobalt, or nickel as binders for zirconium diboride, the sintered compacts were examined in polished section and tested for crushing strength, hardness, microhardness, oxidation rate, and resistance to mechanical shock. Each of the zirconium diboride-metal mixtures produced brittle cermets, but the hardness was generally satisfactory. The iron- and cobalt-bonded cermets exhibited rather poor oxidation resistance. Cobalt provided the least brittle bond, and nickel, the hardest and most resistant to oxidation. Iron tended to form chalky compacts with low resistance to mechanical shock.

Jan 1, 1963