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By Vianey Garcia-Osorio

One of the problems in the carbothermic aluminum process is the substantial loss of aluminum compounds as vapors due to the high temperatures in the process. In order to solve this problem a Vapor Recovery Unit (VRU) is proposed. In this unit operation the aluminum vapor undergoes a series of heterogeneous non-catalytic reactions forming solid, liquid and gas products. In this work a model for the simulation of this unit was developed which includes heat and material balances as well as heterogeneous non-catalytic reactions. The model leads to a system of differential equations; its solution was implemented in Matlab giving as a result a stage-by- stage solid-fluid reaction model.

Jan 1, 2001

By Henk L. C. Meuzelaar

Most of us are aware of the relationship between the golden-yellow resin spots on Upper Cretaceous Wasatch Plateau coals and fossil tree resins (?amber?). Nevertheless, confusion remains about the exact chemical composition and structure of commercial coal resin preparations as well as their observed heterogeneity. In order to arrive at a more detailed chemical description we need to distinguish between micropetrographic, organic geochemical and process technological definitions of coal resins, which may include substantial quantities of constituents unrelated to fossil tree resins. New information on composition and origin obtained by Curie-point pyrolysis/evaporation in combination with isobutane chemical ionization mass spectrometry, as presented in this paper, points to the presence of four more or less distinct resin components: (1) a sesquiterpenoid polymer; (2) sesqui-and triterpenoid monomers and dimers; (3) a suite of triterpenoid alcohols, ketones and acids; and (4) a series of increasingly aromatized hydrocarbons with naphthalene and picene type skeletons. Moreover, a strong similarity is found between the composition of recent Dammar resin and fossil Wasatch Plateau coal resins. Some of the technological implications of these findings and the consequent need for a more precise chemical definition and nomenclature are discussed.

Jan 1, 1990

By P. Zhang, W. D. Xiao

"A process mineralogy study was conducted to guide the development of a process for the extraction of vanadic oxide (V2O5) and aluminum compounds from bone coal and its ash as well as the production of byproducts. Results show that to extract the targeted metals at higher recovery rates, one must find a suitable agent capable of destroying the structure of the mica and breaking down the lattices in which these metal-bearing minerals occur. For such minerals, metal extraction efficiency is usually low if the approach is simply adding an oxidant that cannot destroy the structure. In this research, a byproduct fluosilicic acid (H2SiF6) at 20 percent concentration from an operating phosphate fertilizer plant was found to be powerful and effective for the leaching of vanadium-bearing minerals such as mica. This environmentally friendly process improved the leachability of valuable constituents in the bone coal significantly, with the leaching rate of V2O5 increased to 94 percent, from 83 percent, and that of aluminum oxide (Al2O3) increased to 75 percent, from 40 percent. X-ray diffraction and chemical analyses showed that the structure of mica can be destroyed using fluosilicic acid either alone or in combination with sulfuric acid. Based on the process mineralogy study, a processing flowsheet was tested, which resulted in a final V2O5 powder product with purity of 99.2 percent and an overall recovery rate of higher than 85 percent. The flowsheet consists of leaching, ion exchange and ammonium precipitation. With this process, various byproducts could also be generated, including aluminum fluoride, cryolite, aluminum sulfate, calcium sulfate, ammonium chloride, sodium chloride and cement admixtures.IntroductionVanadium is an important rare metal broadly used in the production of steel alloys and nonferrous alloys as well as in the chemical field as a catalyst. Vanadium-bearing bone coal and clays are abundant in China, and they contain other valuable metals such as aluminum. Bone coal is a type of carbonaceous shale. The vanadium-bearing minerals mainly exist in mica, kaolin, iron oxides, tourmaline and garnet. According to previous studies (Xiao, 2007; Xu, 1989; Xu and Chen, 1991; Ji and Xu, 1991; Chen and Xu, 1992; Xu and Heng, 1992), vanadium occurs from the isomorphous substitution of V3+ for Al3+ or Fe3 + in the crystal lattices of mica, tourmaline, garnet, dolomite and aluminosilicate minerals. In iron oxide and kaolin minerals, vanadium appears as an adsorption form. The isomorphous substitution of vanadium is more stable in tourmaline, garnet and silicate minerals. Therefore, vanadium in bone coal may exist in three phases: vanadium-containing kaolin and oxides, vanadium-containing mica, and tourmaline and garnet (Xu and Chen, 1993; Xu and Zhang, 1993; Xu and Wang, 1994; Feng, et al., 2005; Lin and Fan, 2001)."

Jan 1, 2015

By Maciej Wrobel, Joerg Hammerschmidt, Dana Nurgaliyeva, Alexandros Charitos, Jochen Guentner

"Smelting of copper concentrates in the flash smelter generates a flue dust stream that contains a substantial amount of copper and accumulates more than half of the arsenic input to the smelter. In view of its high copper content flue dust recirculation to the flash smelter is common practice. Globally traded copper concentrates are affected by ever increasing arsenic contents and cause an increasing circulating arsenic load in flash smelter operation. Control of the arsenic level in the smelter slag becomes a challenge. This interaction of arsenic loaded copper feedstock, need for flue dust recirculation and slag quality control call for possibilities to reduce the arsenic load of the recirculated flue dust stream.The technology of partial roasting is known from pre-treatment of copper concentrates before smelting, and gold concentrates before cyanide leaching, to remove the harmful element arsenic. The partial roasting technology can be adapted for use in the purification of the flue dust. A major challenge for flue dust treatment is its extremely fine particle size compared to usual concentrates. For this reason Outotec developed a new process, which allows handling of such fine flue dust. This process solution provides an efficient possibility to reduce the arsenic burden in copper smelter operations.The suggested process aims at reducing the arsenic load to the smelter by treating the flue dust prior to recirculation to the smelter. The presented results are based on test work in the Outotec R&D-centre in Frankfurt. It is possible to remove 80-85% of the contained arsenic and to collect it in an arsenic trioxide residue with a concentration above 90%. The final off gas contains SO2 from decomposition of sulphates that are contained in the flue dust. The off gas stream is relatively small. We assume that it is possible to combine the off gas stream with other smelter process gas streams and to treat it in an existing sulphuric acid plant. Coal is used as fuel and as reductant to reduce pentavalent arsenate to trivalent arsenite. Arsenite can be kept in gas form at temperatures above 450°C. This permits separation of a calcine stream with arsenic levels of 0.2 – 0.3%, which is recirculated to the furnace.Outotec has a wide range of roasting testing facilities from lab-scale to pilot-scale. Outotec has both capability to modify and adapt technology to specific ore or concentrate requirements, but also the necessary infrastructure in its research centers in Frankfurt and Pori to do appropriate validation tests in lab and pilot scale size plants."

Jan 1, 2016

By Mahmood Alemrajabi, Ake Rasmuson, Kerstin Forsberg, Kivanc Korkmaz

"In the present study, the recovery of rare earth elements (REE) in the nitrophosphate process of fertilizer production is investigated. The apatite has been recovered from iron ore tailings by flotation. After digestion of apatite in concentrated nitric acid, Ca(NO3)2.4H2O is first separated by cooling crystallization and then the REEs are recovered by precipitation. Optimum conditions in these steps have been determined in a previous study. The precipitate mainly consists of CaHPO4.2H2O and REE phosphates.In the present study, selective dissolution and re-precipitation have been studied in order to obtain a precipitate that is more concentrated in REEs. The precipitate was selectively dissolved in nitric and phosphoric acid at different acidities (pH 6 to 0) with the liquid /solid ratio of 100 mL/g. It is shown that most of the CaHPO4.2H2O and other calcium containing compounds will be dissolved at pH 2 while the REE phosphates are not dissolved above a pH of approximately 2. Thus, by partial dissolution of the REE precipitate at pH 2.5 most of the solid calcium phosphates will be dissolved and the remaining solid phase, which is more concentrated in REEs, can be filtered off as a fairly concentrated REE solid mass and the liquor can be recycled back to recover more P nutrients. Alternatively, the REE enriched precipitate was dissolved completely in nitric acid and re-precipitated again by addition of ammonium hydroxide to pH 1.2. A chemical equilibrium software, MEDUSA (Puigdomenech, 2013) has been used to evaluate the experimental results and to estimate the optimum conditions for selectively dissolving the precipitate."

Jan 1, 2016

By Klaus M. Hahn, Kurt Aasly, Jutta Lennartz, Hermann Wotruba, Ben Snook, Przemyslaw B. Kowalczuk, Rolf Arne Kleiv

"Seafloor massive sulphide (SMS) deposits have been identified as important marine metal resources for the future. However, literature on mineral processing of SMS is currently limited, and to date, no research has been published on processing of SMS from either active or inactive hydrothermal vent fields on the Arctic Mid-Ocean Ridge. In this paper, individual SMS rock samples from the Loki’s Castle area were tested. Chalcopyrite, isocubanite and sphalerite represented the main copper and zinc bearing minerals in the SMS samples, whereas the gangue consisted of barite and silica. Based on the X-ray transmission response (XRT), i.e. differences in the atomic number of elements in tested samples, and using portable XRF (PXRF) values of elemental composition, individual particles were classified as a either product (low barium / high to low silicon / high copper and zinc) or waste (high barium / high silicon / low copper and zinc). The classification was based on the elemental composition of the samples with the cut-off grade equal to 0.5% for copper. It was shown that the XRT discrimination analysis correlated well with elemental (PXRF) data classification. The results clearly indicate that X-ray transmission sensor-based sorting can be used a useful technique for preconcentration of SMS rock samples. INTRODUCTION Due to different compositions of investigated samples, sensor-based sorting is a useful technique for preconcentration of different materials. The aim of using sensor-based sorting is to upgrade an ore by reducing the quantity of overall waste material reporting to the next processing stage. This can be achieved by eliminating (reducing) the waste fraction. By applying sensor-based sorting, the energy consumption for particle comminution as well as the required process water and reagents can be decreased. The total volume of the waste rejection leads to a proportional reduction in the total energy costs (Lessard et al., 2014, 2016)."

Jan 1, 2018

By K. S. Coley, M. A. Rhamdhani, G. A. Brooks

Interfacial phenomena in high temperature reactions such as between iron alloy and slag is well documented but not fully understood. It is believed that a gradient of oxygen concentration plays an important role to the occurrence of such phenomena. This article describes the results from the continuation of the study of interfacial phenomena between Fe-Al alloy droplets and CaO-SiO2-Al2O3 slag. Materials characterization techniques involving microscopic observations, depth profiling, bulk, point analysis and were carried out. The roles of oxygen as well as other factors that contribute to the interfacial phenomena were evaluated. The results and their implications to steelmaking will be discussed.

Jan 1, 2004

By James C. Cawley

This report presents results of recent Bureau of Mines research to establish the probability of spark ignition as a function of current (or voltage, for capacitor circuits) for resistive, inductive, and ca-pacitive circuits in 8.3% methane-air atmospheres. The data presented quantify the explosion hazard created when low-power electronic devices catastrophically fail in an explosive mine atmosphere. Previous litera-ture dealt with levels of probability between 10-3 and 10-4. This re-port extends the probability data to levels as low as 10-7. This study has verified that when the probability of ignition, PI, is plotted on a log-log coordinate system versus the current (or voltage), a continuous, straight-line relationship is formed. An interesting result that can be statistically hypothesized is that at some low level of igniting current the ignition process ceases altogether.

Jan 1, 1988

By Robert H. Merrill

In 1960, the Kennecott Copper Corp. and the U.S. Bureau of Mines entered into a joint research program to determine the changes in stress, strain, and displacement created by changes in slope angles. The field site was the Kimbley Pit, located near Ely, Nevada; the supporting laboratory investigations were made at the Bureau's Denver Mining Research Center. Following a study to determine the rock stresses in the mining district, the strike and dip of geologic defects (fractures) in the rock, and the laboratory-determined strength of the rock, a new slope angle and pit configuration was selected, and instruments were installed to measure changes in stress, strain, displacement, microseismic noise rate, and sonic velocities at several points in the west wall of the pit. Between February and November 1966, the west slope was changed from an average angle of 45° to a new slope angle that started at 45° on the south wall, gradually increased to 57 ½ at the center of the west wall, and to 61° on the north wall. The pit was deepened from about 500 feet to about 550 feet. About 2.55 million tons of waste and ore were removed by stripping and mining.

Jan 1, 1968

By K J. Davey, J T. Woodcock

Australian steelmakers produce up to 30 000 t/yr of electric arc furnace (EAF) dust. Current disposal techniques include sending EAF dust to landfill, stockpiling, and paying zinc smelters or registered waste removalists/processors to take the dust. Many of the complex overseas pyrometallurgical and hydrometallurgical treatment routes cited in the literature are not considered economic. Governmental, environmental and social pressures on producers to consider more sustainable disposal options are mounting, and there is now a strong push to consider recovering potentially valuable or recyclable components, such as zinc and iron units, from EAF dust. As well, there remain strong economic drivers for producers to find lower cost disposal solutions. Characterisation studies undertaken at CSIRO Minerals have revealed important physical differences in the nature of the zinc- and iron-bearing phases contained in domestic EAF dusts. These differences have been exploited using simple and cheap mineral processing techniques such as water washing, wet cycloning and wet magnetic separation. This has allowed a significant upgrade in the zinc content of EAF dust to be achieved, together with a reduction in the levels of key smelter penalty elements, such as chlorides and fluorides. The zinc-rich portion of the dust is now a more attractive smelter feed while the iron-rich part of the dust could potentially be briquetted or pelletised with a reductant and recycled to recover iron, and thus close the loop on dust processing. The basis of the separations tested together with laboratory results from several Australian dust samples are presented and discussed in this paper.

Jan 1, 2006

By Donna Wallace

Past EPA groundwater monitoring programs required that contamination not leave the boundaries of a disposal facility. New regulations under the Resource Conservation and Recovery Act (RCRA) require that once hazardous waste constituents are detected beyond the limits of the disposal area, a program to define the rate and extent of contaminant migration must be instituted. Future regulations are likely to include even more stringent groundwater protection criteria. The implications of both the existing and probable future groundwater protection and monitoring requirements in terms of using geologic containment as a means of disposing of hazardous waste are explored in this paper.

Jan 1, 1981

By C. O. Aksoy, P. M. Ozfirat, M. K. Ozfirat, C. Tatar, C. Pamukcu

"Temporal and other factors contributing to the occurrence of occupational accidents at an underground coal mine in Turkey between 1992 and 2000 have been analyzed. The time period of the study spanned the transition from hand-worked mining methods (1992 to 1996) to hand-worked mining methods and mechanized mining methods (1997 to 2000).The mine selected for the study employed an average of 5,835 men per year on three separate eight-hour production shifts for 302 d/y (Sundays are not worked, and there are 11 holiday days per year). Production on an annual basis averaged 190,000 tons per year between 1992 and 1996, and 300,000 tons per year between 1997 and 2000.The purpose of the study was to determine which, if any, of the factors studied contributed to the occurrence of accidents so that the mine could take the necessary steps to reduce the risk to the workforce. Regression analysis was used to determine the strength of the relationship between each factor studied and the number of occupational accidents.The strongest relationships observed were between the age of the employee, the day of the week, and the total yearly labour."

Jan 1, 2006

By S. Kelebek, B. Ingram, C. Gibson, T. MacNeil, M. Aghamirian

"The beneficiation and upgrading of pyrochlore from its ores is carried out through flotation. In industrial practice, upgrading is conducted in a two-stage flotation process in which pyrochlore flotation is carried out after gangue mineral pre-flotation (carbonate, silicate, sulphide or phosphate reverse flotation). In this study, the flotation of pyrochlore from a low grade carbonatite ore was performed at the laboratory scale following a two-stage flotation process in which carbonate minerals were floated in advance of niobium minerals. In parallel, a simplified flotation process was developed in which pyrochlore was floated directly from gangue minerals at increasingly acidic pH. Laboratory results indicated that both two-stage and direct flotation provided similar results in terms of niobium grade-recovery. Based on these results, a large scale, integrated pilot plant was conducted using a direct flotation flowsheet. While the elimination of reverse gangue flotation resulted in flowsheet simplification, the dissolution of carbonate minerals and the subsequent effect of dissolved cations on the floatability of pyrochlore added an element of complexity. A comparison of results from locked-cycle laboratory testing and pilot plant testing highlights the challenges of scaling up a complex flowsheet. A case is made for the direct flotation process and the key parameters to achieving success in large scale direct flotation of pyrochlore are discussed.INTRODUCTIONPyrochlore (Ca,Na)2Nb2O6(OH,F) is a niobium bearing mineral which has been the primary global source of niobium since the first pyrochlore mine commenced operations in the late 1960s (Gibson et al., 2015a). Preceding the discovery and development of high grade pyrochlore deposits in North and South America, the majority of global niobium supply came from gravity concentration operations of columbite (Fe,Mn)Nb2O6, across Africa (Perrault and Manker, 1981)."

Jan 1, 2016

By Anthony J. Deevy

"Abstract -The Magino gold mine is located 45 km northeast of Wawa, Ontario. There was limit­ ed gold production in the Iate thirties. The present operation was officially opened in October 1988 and produced gold until September 1992. It was a 635 tonnes per day, decline-accessed mine, with ore coming from several small blast hole and shrinkage stopes.The host for the gold is the Webb Lake granodiorite stock which was intruded into the Goudreau Lake Deformation Zone. This east-northeast-striking deformation zone overprints the generally east­ west-striking isoclinally folded metavolcanic and metasedimentary rocks, which make up the east end of the Michipicoten greenstone belt. The ore-shoots are controlled by dextral delatancy associated with the Goudreau Lake Deformation Zone. Shearing, bleaching and silicification accompanied the gold emplacement."

Jan 1, 1994

By Shimeni Baptista Ribeiro Daer, Patrícia Freitas Rodrigues, Edir Neves Teixeira, Naiara Vieira Le Sénéchal, Andersan dos Santos Paula, Francisco Manuel Braz Fernandes

Este trabalho visou em compreender as características microestruturais de uma liga de NiTi rica em Ni deformada a quente por meio do processo de forjamento rotativo, que foram submetidas ao processo com temperaturas distintas de pré-aquecimento (800 e 950 ºC) sem e com tratamento térmico de recozimento prévio (950 ºC por 2 horas) para homogeneização do lingote. Por meio dos aspectos da evolução microestrutural verificados com auxílio das técnicas de Microscopia Óptica, Microscopia Eletrônica de Varredura e difração de Raios X pôde-se observar que a adoção do recozimento prévio para homogeneização e incremento da temperatura de pré-aquecimento as etapas de forjamento rotativo a quente, conduziu a resultados mais satisfatório ao processamento termomecânico a ser aplicado nesta liga, a fim de seguir para as etapas de deformação a frio.

Nov 14, 2019

By Richard K. Komarek, Antonios Zavaliangos, Roman T. Dec

Roller presses are widely utilized in mineral industry for fine milling and compaction. Recently used models are providing only limited information about the material behavior in the roll bite. This paper introduces a 2-dimensional finite element model for analyzing those two basic processes. A pressure-dependent plasticity model with linear elasticity was used as a constitutive model for the particular material. Coulomb friction law was used to describe phenomena on the material/roller surface interface. Two basic roller geometries are considered: smooth (used for milling and compaction) and with cavities, commonly used for briquetting. Comparison of the results obtained from the model with experiment indicates that they are following the general trends of experimental values recorded with laboratory roller presses. It is shown, that the model is suitable to analyze material behavior through all stages of the rolling process: feeding zone, nip region, neutral plane and release section. It can predict pressure, shear stress, slip of the material over the roller surface, material velocity field, failure of the compact during release and the course of other important process variables. This allows the process engineer to gain an improved understanding, leading to a better process and equipment design and control.

Jan 1, 2003

By D. F. Malan, P. M. Couto

We propose a layout design for the UG2 Reef where weak geological alteration layers are present. The collapse of the Everest platinum mine in South Africa indicated that these layers substantially weaken the pillars. The popular Hedley and Grant pillar strength formula cannot be used where these alteration layers are present. Underground investigations at Everest mine and numerical modelling of the layout were conducted using the TEXAN code and a limit equilibrium model. Simulations of a collapsed area and an intact area allowed for a preliminary calibration of the model. This was subsequently used to explore modified layouts for these ground conditions. An alternative is to compartmentalize the blocks of ore using barrier pillars. The numerical modelling predicted that the barrier pillars appear to remain stable even in the case of large-scale collapses, provided their width exceeds 25 m. Main access routes into the mine can be protected by a double row of pillars at least 15 m wide to provide a safe travelling way. As a cautionary note, these conclusions are based on the model calibration and this needs to be refined in future. Calibration of the limit equilibrium model remains a challenge owing to the large number of parameters involved.

May 3, 2023

By Dilermando Nagle Travessa

High strength-light weight materials are very attractive for the transportation sector, particularly to the aerospace industry. High strength-age hardenable aluminium alloys are widely used in airframes due to their unique combination of strength, density, toughness, corrosion resistance, cost and easy processing. However, the hardening capacity of such alloys is somehow saturated due to thermodynamic issues related to the conventional processing. The production of aluminum-matrix composites is a promising strategy to overcome this limitation, resulting in strength levels that cannot be reached by actual commercial aluminum alloys. In the present work, multiwall carbon nanotubes were used to reinforce the AA6061 aluminium alloy. 1 and 2% weight percent of MWCNT were mixed to the alloy powder by high-energy ball-milling process. The blended powder was consolidated by hot extrusion. The obtained composite bars were submitted to heat treatment for the T6 condition in order to combine both CNT dispersion and precipitation hardening effects. Optical and scanning electron microscopy, as well as hardeness testing, was used to characterize the bars. Typical wrought microstructure, free of defects, was observed on the extruded bars. Hardness of the composites was observed to increase by 20, 28 and 68% for 1% MWCNT 6 h milling, 2% MWCNT 6 h milling and 2% MWCNT 10 h milling, respectively, in the as-extruded condition. The better performance for the composites blended at higher milling time was attributed to a better nanotubes dispersion. Subsequent heat treatment to the T6 condition did not result in additional hardening.

Aug 8, 2018

By Y. Nara, N. Aramaki, M. Maruyama

Evaluation of three dimensionally non-uniform strain distribution in rocks under various conditions such as in water or under freeze-thaw cycles is of significant importance to understand their complex deformations and fracturing mechanisms. For this purpose, we developed an image analysis method which can evaluate or “measure” the three dimensional (3-D) strain distribution in rocks. The proposed method utilizes the 3-D images of rock under initial and deformed configurations, which are obtained by some imaging techniques such as X-ray computed tomography (X-rayCT). In the proposed method, the obtained 3-D images are divided into multiple sub-regions of interest. For each sub-region, the strain is evaluated utilizing 3-D affine transform with unknown coefficients to be determined. In the first step, 3-D voxel level displacements at multiple representative points in each sub-region are computed by 3- D digital volume correlation technique between the comparison images and the initial-guess of the transform coefficients are obtained. In the second step, referring to the initial-guess of unknown transform coefficient, they were optimized in sub-voxel level by finding optimum digital volume correlation between the comparison images, which can evaluate the transform coefficients with higher precision. From the calculated transform coefficients, the strain was directly obtained through the spatial derivative of displacement based on affine transform. In this paper, along with the description of the proposed method, the evaluation of deformation in a lignite specimen due to immersion in water was presented as an application example. As the 3-D imaging technique, micro-focus X-rayCT was applied. The result showed that the induced dilatational strain field due to the initiation and extension of cracks in the specimen was clearly captured. Therefore, authors believe that the proposed method can be applicable to various problems in rock mechanics.

Jan 1, 2015

By J. J. DeMull, B. A. Boster

Amax's Sleeper mine uses conventional cyanidation milling and heap leaching techniques to produce gold. Since milling operations commenced in March 1986, average ore processing rates have improved from the design rate of 455 t/d (500 stpd) to more than 720 t/d (795 stpd). Heap leaching was added to the process facilities in September 1986 at a design rate of 1.5 kt/d (1650 stpd) and current heap leaching rates exceed 2.7 kt/d (2950 stpd). Presented are descriptions of the Sleeper processing facilities with emphasis on the crushing and grinding circuits, a review of the selection of crushing and grinding equipment, and a summary of operating performance during the first 16 months of operations.

Jan 1, 1990