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By Henry A. Stiff, and Lawrence E. Davis

The authors previously presented a method for predicting the tendency of oil field waters to deposit calcium sulfate. The present paper gives a similar method for calcium carbonate. Methods for predicting calcium carbonate scaling tendencies in fresh waters have been available for some time, but these could not be used for brines. By experimentally deriving the value of the K term in the Langelier equation, a method has been developed which applies to waters of high salt content. A statistical study is included which shows that the experimentally derived values of K are in good agreement with actual conditions. Several applications of the final equation to production practice are given. INTRODUCTION The authors previously presented a method for predicting the formation of calcium sulfate scale in oil field waters.' Although calcium sulfate deposition is important in production operations, the majority of scale problems involve calcium carbonate. The present communication discusses a method by which the formation of this type of scale in oil field waters can be predicted. Calcium carbonate precipitation is caused by a shift toward carbonate in the carbonate-bicarbonate-carbon dioxide equilibrium. When equilibrium shifts in the other direction, the precipitate goes back into solution. Since there is usually considerable delay between the establishment of an equilibrium and the precipitation or solution of calcium carbonate, unstable conditions exist in which a water will precipitate or dissolve calcium carbonate on standing. Tillmans? who did a major part of the early work on carbonate scaling, pointed out that the condition of equilibrium not only indicates the tendency of a water to scale but also is an indication of its corrosive properties. Previously precipitated calcium carbonate combines with iron to form a dense crust which inhibits corrosion. If the water tends to dissolve carbonate, the scale becomes porous, and electrolytic corrosion takes place. Tillmans1 work was extended by several investigators until in 1934 Langeliers developed an equation setting forth the conditions of carbonate equilibrium. By the use of this equation the pH of a water at equilibrium can be calculated. If the actual pH is higher than the calculated pH, the water has a tendency to form scale. If it is lower. the water has a tendency to be corrosive. Langelier's equation can be expressed in a simple form as follows: SI = pH-pCa-pA lk-K where: SI is the stability index. A positive index indicates scale formation. A negative index indicates corrosion. pH is the pH of the water sample, as actually determined. pCa is the negative logarithm of the calcium concentration. pAlk is the negative logarithm of the total alkalinity. K is a constant, the value of which depends on the total salt concentration and the temperature. This equation has been shown to apply to waters with totaI solid concentrations as high as 4.000 ppm. In fact, control of fresh water treatment by means of this equation has been standard text-book practice for a number of years. Nomographs have been worked out so that the stability index of a fresh water sample can be determined in a matter of minutes. Most oil field waters, however, contain well over 4,000 ppm of salts and for this reason the usual application of Langelier's equation can not be made. By an empirical method we have extended the application of the Langelier equation to waters of high salt concentration. By the use of this equation the tendency of oil field waters to deposit calcium carbonate can be predicted.

Jan 1, 1952

By E. I. Organick, B. H. Golding

A simple correlation is presented for the prediction of saturation pressures in condensate-gas and volatile-oil mixtures. Saturation pressure is related directly to the composition of the mixture with the aid of two generalized composition characteristics, B, the molal average boiling point, and W, the modified weight average equivalent molecular weight. The need for hydrocarbon equilibrium constants is entirely eliminated. Only the values of the two conlposition parameters need be obtained, and these are calculated in a simple and reproducible manner from the stream analysis of the mixture and the ASTM distillation for the heavy ends. The correlation is given .in the form of a set of 14 working charts in which saturation pressures, either retrograde dew points or bubble points, are plotted cs temperature, forming partial phase envelopes for mixtures having discrete values of the composition parameters, B and Wul. A locus of critical states on each chart intersects the partial phase envelopes, distinguishing retrograde dew point pressures from bubble pressures. A comparison Between experimental and predicted saturation pressures reveals that: the probable error of the predicted values, when considering the data as a whole (214 experimental points), is five per cent; for high gasjoil ratio condensate fluids (approximately 40.000 or more cu ft/bbl) the probable error is about 8 per cent. In either case, however, the probable error is comparable with the overall uncertainty of the data from which the correlation is derived. INTRODUCTION There is a present need for a simplified, yet reasonably accurate method for predicting upper phase boundaries of reservoir fluids. In the case of high gas/oil ratio fluids, namely the so-called highly volatile oils and the condensate gases, no simple method, accurate within 5 to 10 per cent, is now available by which bubble point and retrograde dew point pressures may be predicted. In order to calculate the upper phase boundary of a volatile reservoir fluid, using correlations now available, it is necessary to find and employ the proper K-values (equilibrium volatility ratios of the hydrocarbons in that fluid). This process of finding the Proper K-values usually involves a double trial and error computation. Since the K-values are in themselves dependent upon the composition of the fluid, their use in the calculation of a saturation pressure actually represents an unnecessary complication. The correlation described in this paper relates saturation pressure directly to the stream composition, entirely eliminating the need for K-values. The only data required to calculate the Stream composition are obtained from the customary low temperature fractional analyses of separator gas and liquidt and from the ASTM distillation of the c,+ fraction of the separator liquid. A considerable simplification in the procedure for predicting saturation pressures is thereby effected without significant loss in accuracy. BASIS FOR A CORRELATION Empirical relationships between the saturation pressure and the composition of the fluid in question have already been partially explored by one of the authors.V n particular, a relationship between the critical pressure for a hydrocarbon mixture and its composition was developed. The critical pressure is in reality a saturation pressure, as it repregents a limiting case either of a dew point or of a buhhle point pressure for any given mixture. It was found that the critical pressure may be correlated as a function of two generalized composition characteristics or variables. One characteristic expressed a molal average prop-erty, the other a weight average property of the mixture. Specifically, the molal average boiling point (MABP, or B as it

Jan 1, 1952

By G W. Heyes, P J. Guy

Investigations were undertaken to assess the suitability of CSIROflotation methods for improving the efficiency of separation of heavyminerals in the monazite circuit at the Westralian Sands Limitedoperations at Capel, Western Australia. Flotation work was conducted on two plant samples. The first was a high-titanium product containing considerable amounts of zircon and silica as quartz and aluminosilicates, and the second was a low monazite/zircon material containing high levels of silica. A three-stage process including reverse flotation was developed totreat the first sample. In this process monazite, zircon, quartz, andaluminosilicates were selectively concentrated by flotation and screening to produce a titanium-rich product. In the first stage, an acid amine float, monazite, zircon, and some non-zircon silica were recovered and in the second stage, an alkaline amine float using a fluoride activator, more quartz and staurolite were floated. The titanium minerals were thus concentrated in the unfloated fraction. In the third stage, the titanium-rich flotation tail was screened at 250 ¦m to remove the remaining coarse aluminosilicates. In a single pass, the three-stage process yielded a TiO2 recovery of 64.0 per cent with the titanium-rich product assaying 70.3 per cent TiO2.

Jan 1, 2001

By Djavid Mohammad

Over the next several years, the storage capacity of the Metropolitan Water Reclamation District of Greater Chicago?s Tunnel and Reservoir Plan will be increased by 14.8 billion gallons through the addition of two large off-line reservoirs: the McCook and Thornton Reservoirs. The Thornton Reservoir will be constructed at the terminus of Calumet TARP System. The constructed TARP system will be connected to the Thornton Reservoir via connecting tunnels and gates systems. The connecting tunnels will comprise of: an upgradient transition tunnel, steel lined bifurcated tunnel for conveyance and control of flow, downdradient transition tunnel, and energy diffuser at tunnel portal. A large, approximately 250-foot-long, 69-foot-wide, and 40-foot-high, rock cavern will be excavated at an average depth of 320 feet to house the bifurcated tunnel system and associated six large control gates, each 12.5-ft by 28-ft wheel gate. Presented in this article are discussions about the TARP system, the Connecting Tunnels and gates Project, regional rock conditions, evaluation of reservoir?s wall stability for evaluation of tunnel penetration, and design challenges facing during design of the: rock cavern hosting the bifurcated tunnel system and gates and associated tunnels and shaft.

Jan 1, 2008

By Y. Nien Wang

The Devil?s Slide portion of Highway 1 between Pacifica and Montara is often closed due to the instability of the adjacent slopes. Following many years of public input and careful evaluation of alternatives, Devil?s Slide will be by-passed via two inland tunnels, providing a safe, dependable highway between Pacifica and Montara. For the twin tunnels, each 9m diameter tube will accommodate only one traffic lane. Each tunnel tube will accommodate a 3.6 meter roadway, 0.6 meter and 2.4 meter inside and outside shoulders respectively, and 1.2 meter walkways on each side. Cross passages will connect the bores at about 120 meter intervals and jet fans will provide tunnel ventilation. The twin tunnels are approximately 1,250 meter long and 9 meter wide. Excavation will progress from south to north using tunneling techniques that rely on inherent rock strength for support known as the New Austrian Tunneling Method (NATM). Both tunnels will be excavated at the same time, one tunnel face approximately 40 meters ahead of the other. Staggering the tunnels reduces the likelihood of damage from blasting in alternate tunnels. The work schedule is 24 hours a day, 7 days a week resulting in a 24-month timetable to break through to the north portal.

Jan 1, 2008

By William R. Yernberg

Santa Fe Pacific Gold, headquartered in Albuquerque, NM is expanding its operation at the Twin Creeks Mine in Nevada. The $250-million sulfide expansion project, including the Sage Mill, is under construction and is 80% complete. Also, additional mining equipment has been purchased to haul the sulfide ore to the mill. With the expansion, employment at Twin Creeks is expected to reach approximately 970 people by the end of 1996. Santa Fe Pacific Gold now owns and operates three gold mines in the United States and is involved in several other gold projects. The three currently operating mines are the Twin Creeks, Mesquite and Lone Tree mines. The Mesquite Mine is located in California’s Imperial Valley. Lone Tree is located 55 km (34 miles) southeast of Winnemucca, NV. The company’s total gold production from these operations is expected to be in the range of 26.3 to 26.6 t (845,000 to 855,000 oz) in 1996. This compares to a total production of about 124 kg (4,000 oz) for the company in 1989. Production costs range from $6.90to $7.25/g ($215 to $225/oz). At the end of 1995, the company reported proven and probable reserves of 556.7 t(17.9 million oz) of gold.

Jan 1, 1996

By Abolfazl Eslami, Fatemeh Rostami, Sara Heidarie Golafzani, Mohammad Arabameri

Collapsible loess is classified as problematic soil found in most continents. The loess immediately collapses under stresses induced by axial compressive loading or the soil weight when exposed to moisture. In Iran, vast areas of the Golestan province are covered with aeolian loess deposits. This paper investigates whether the simultaneous effect of inundation and pre-loading in helical pile installation are operative and effective in improvement of Golestan loess. The effect of installation conditions on loess collapsibility is studied via two main approaches, i.e., field investigations and physical modelling. The experimental studies include installation of eight single helix piles in the Amirkabir University of Technology Frustum Confining Vessel, i.e., FCV-AUT. Also, four single helix piles with embedment depth of 3 m and diameter of 250 mm were installed in Golestan province and full-scale pile static loading tests were performed. The results indicated that the simultaneous application of crowd loading and water pressure during installation of helical piles results in better soil shear strength parameters. Moreover, high crowd stresses or low crowd stresses accompanied by water pressure during pile installation brings about similar load-displacement behavior of model piles installed in FCV-AUT and full-scale helical piles.

Oct 1, 2022

By J. Jávor

The response of the air/water interfaces to deformation in presence of surfactants is affected by the adsorption/desorption rate, re-orientation and exchange rate of surfactant. These surface properties can be observed using equilibrium and dynamic surface tension and surface elasticity measurements. However, the effect of these parameters on bubble size in dynamic conditions has not been studied due to the difficulty in capturing freshly formed bubbles in dynamic conditions. The paper presents a new experimental set-up designed and built at the Aalto University, called Shear Force Observation Chamber(SOC). The setupallows the monitoring and analysisof freshly formed air/liquid interfaces in dynamic conditions and facilitates the study of the effect of dynamic surface tension and surface elasticityon freshly formed air bubblesin presence of surfactants. The method helps to establish correlation between bubble size and dynamic interfacial properties and bubble-bubble interaction in turbulent flow. Dowfroth 200, Nasfroth 240 and Dowfroth 250 commercial flotation frothers were tested in this study. The results show a marked difference between results obtained in dynamic conditions compared to the static conditions. The results are presented and the reasons and implication to flotation modelling are discussed in the paper. Keywords: shear force observation chamber, flotation frothers, flotation bubbles, critical coalescence concentration

Sep 1, 2012

By Jasinder S. Jaspal

Most of the underground coal in the United States is mined via room-and-pillar mining methods with continuous miners. These machines operate intermittently because they have to wait for shuttle cars to interchange positions. To overcome this discontinuity in shuttle car haulage and to realize the full production potential of continuous miners, the U.S. Bureau of Mines developed a multiple-unit continuous haulage (MUCH) system through a research contract with Jeffrey Mining Machinery Div. (JMMD). The MUCH system consists of 12 rubber-tired vehicles and a bridge conveyor. The rubber-tired vehicles are connected by a unique mechanical linkage system to form a 250-ft train. The mechanical linkage permits the vehicles to track-retrack the preceding vehicle in both inby and outby directions. The cut coal cascades from one vehicle to another until it is discharged on the section conveyor belt. The MUCH system provides continuous haulage to the continuous miner. The MUCH system was initially surface tested by JMMD. Subsequent extensive testing was conducted by the Bureau at its test facilities at Bruceton, P A. Deficiencies found during testing were corrected. This report summarizes initial tests by JMMD and subsequent extensive tests and evaluation by the Bureau.

Jan 1, 1989

By Muhammad Hashim Rasa, Ali Aras

Recovering valuable metals from tailings not only provides a source of income but also helps conserve natural resources, thus reducing the environmental impact of mining activities. This study aimed to recover cobalt using tailings of the Küre flotation plant, which were determined to contain 0.17% Co. Flotation tests were conducted on samples taken from the tailings to investigate the effects of pH and pH conditioning time, as well as types and amounts of depressant, collector, and frother on the grade and recovery of Co in rougher flotation tests. Optimal flotation conditions were determined to be pH 6, a pH conditioning time of 7 min, and dosages of 50 g/t, 100 g/t, and 20 g/t of sodium hexametaphosphate, X-231, and DF250, respectively. According to the rougher flotation test results, a concentrate with a Co grade of 0.46% and a Co recovery of 84.15% was obtained. In the concentrate obtained using cleaner flotation tests, the Co grade increased to 0.49% and Co recovery increased to 90.56%. These results show that froth flotation, carried out with the appropriate reagents, is a successful method for recovering Co by enriching the flotation plant tailings.

May 17, 2023

By Ana E. Bohé, Georgina De Micco, Juan P. Gaviría, FEDERICO J. POMIRO, Gastón G. Fouga

Chlorination and carbochlorination processes have industrial applications in metallurgical activity for extraction and purification of uncommon metals such as rare earth elements (REE). This study reviews the chlorination and carbochlorination reactions of light REE (LREE) oxides with chlorine considering the thermodynamic, stoichiometric, and kinetic aspects of the reactions. Lanthanides between lanthanum to gadolinium were considered as LREE, in agreement with previous literature, and the results were detailed in this review. LREE were analyzed taking into account their oxidation states and were divided into three groups accordingly. The results presented show that, although the LREE are chemically similar, their behaviors during the reactions with Cl2 and Cl2–C, and the different LREE-O–Cl compounds formed, have particularities. It was observed that gadolinium, in both thermodynamic calculations and experimental results, presents some differences, and it can be considered intermediate between light and heavy REE; i.e., reactions between LREE2O3 and Cl2(g) begin at approximately 250 °C, except for Gd2O3 that begins at 327 °C. The present work will contribute to a better understanding of the chemistry of LREE oxides and Cl2 under different conditions and the products obtained in the LREE–O––Cl2(g) and LREE–O–C–Cl2(g) systems.

Oct 15, 2021

By X. M. Yu

A large amount of polluted sludge is produced by a nonferrous metal factory after treating waste water with lime/ferrous salt. The concentration of arsenic in the dried sludge is high to 5.84%, a toxicity test is taken on the sludge according to GB5085.3-2007 and the extraction content is 15.75mg/L, which surpasses the arsenic extraction standard [As]=5mg/L, the sludge is categorized as hazardous waste. If put outside without disposal, it would be very harmful to environments. Here we report an optimum protocol to extract arsenic; S2- alkaline liquor is utilized to treat the arsenic sludge. At 85?, 10L 7% S2- liquor is added into 1kg dried sludge and the resulting mixture is stirred for 120min at 250r/min, then separated by centrifugation and the compressed waste residue dried naturally. The average arsenic content is 1.40mg/L, lower than GB5085.3-2007 Standard and arsenic-free residue is consistent with GB18598-2001 Standard, which can be bury safely. The extracted arsenic is transferred into copper arsensite for use as addictive in copper electrolysis and the waste water can be recycle after calcium is removed.

Jan 1, 2014

By J. H. Field

The sulfur dioxide emitted in low concentrations in flue gases from the combustion of sulfur-containing coals and fuel oils is a significant factor in contamination of the atmosphere with sulfur dioxide. A review of methods for treating gases containing high concentrations of sulfur dioxide shows that they are seldom satisfactory for purifying flue gases. Processes developed specifically for treating flue gases using liquid absorbents are costly and may cause localized pollution, because the cooled flue gases can settle in the vicinity of the stack. Bench-scale research is being conducted to investigate the use of dry absorbents for sulfur dioxide removal at temperature levels of about 250°- 300° F. and 600°-650° F. Alkalized alumina has been found effective for treating simulated flue gas and Is regenerable by hydrogen, carbon monoxide, or producer gas. Other metallic oxides have been tested as absorbents also. Chemically impregnated activated carbons removed sulfur dioxide from the gas at 265° F. Vanadium pentoxide is effective as a catalyst for oxidizing of sulfur dioxide in the simulated flue gas at temperatures lower than have been used commercially for gases with higher concentrations of sulfur dioxide. Conversions of sulfur dioxide to trioxide wore studied as a function of temp- erature over a range of about 570° to 750° F.

Jan 1, 1959

By P. M. Dranchuk

"""PLANET EARTH seen from space appears as a fragile and limited life-supporting system in a vast emptiness. That such a view is, in fact, an accurate one is now more widely accepted than it was not long ago, before Earth's problems of over-population, overconsumption, limited resources and environmental degradation attained the limelight. The danger is that a government and public now deluged by doomsday prophecies and bemused by equally confident reiterations that technology will cure all may hesitate in coming to grips with the problem, in the hope that, given time, it will go away."" With these words, Preston Cloud begins a recent editorial, in Science(l), in which he presents a brief resume of some of the findings of the Committee on Resources and Man of the National Academy of Science-National Research Council(20.Their report, which is based on a two-year study by an extremely competent group and consists of some 250 pages of text, is even more far-reaching and sobering than the report on Energy Resources(3). It begins by quoting Sir Macfarlane Burnet as follows:""There are three imperatives: to reduce war to a minimum; to stabilize human population, and to pre-vent the progressive destruction of the earth's irreplaceable resources.(4)"

Jan 1, 1971

By J Euston

In the 1990s round flotation tanks were introduced as a result of the lower fabrication costs for larger cells. It was soon observed that round tanks held a number of further advantages over the traditional rectangular cells, such as better hydrodynamics, lower costs and reduced footprint per unit volume.In the last twenty years flotation cell sizes have increased almost exponentially and designs of 250 to 300m3 are a well established standard with plans for full scale pilot installations of 500m3. The option to install these large cells gives flexibility in circuit arrangements and allows efficient and economic matching of flotation lines with modern mill designs. The benefits of scale up are well known with reduced numbers of cells required, lower power costs per unit volume, etc. These benefits will be briefly reviewed with specific reference to the installation of 300m3 to 350m3 flotation cells at the Copperton Concentrator of Kennecott Copper in Utah, USA.The sophisticated techniques required to model these ‘supercells’ have led to a critical review of the fundamentals of flotation science and engineering. In addition to outlining the advantages of large flotation cells, this paper will review the science which supports, and occasionally challenges, the ongoing trend to larger flotation cells.

Aug 8, 2011

By P. W. Jensen

Gold deposits in Interior Alaska are commonly coincident in time and space with reduced, mid-Cretaceous granitoids. The True North deposit of the Fairbanks district is several km from such granitoids, but yields mineralization ages indistinguishable from the Fort Knox granite-hosted deposit. True North, however, resembles sediment-hosted epithermal Au, demonstrating the variability of intrusion-related Au deposits in metamorphic rocks. The True North deposit (14M tons at 1.5 gpt) is hosted within a carbonaceous thrust complex separating eclogite facies from amphibolite facies rocks, located > 5 km from mineralized granite outcrops. The ores contain anomalous Sb, As, and Hg (stibnite is the most common sulfide) with ankerite-sericite alteration in steep NE-striking ?feeder? shears and low angle thrust shears. Nearest hornfelsed rocks are located > 1 km away, and across several high-angle faults. Fluid inclusion data indicates trapping temperatures of ~250C from low-density, low-salinity fluids at P < 0.5 kb. Au was originally present as solid solution in sulfides; minable ores are restricted to the oxidized upper 100 m of the deposit. The considerable differences between this deposit and the temporally equivalent Fort Knox intrusion-hosted deposit indicate no one description adequately characterizes this deposit type.

May 1, 2003

By Robert B. Scott

The Dents Run Demonstration Project near Morgantown, West Virginia, was a cooperative venture involving the U.S. Environmental Protection Agency (EPA), the Water Resources Division (WRD)(1) of the West Virginia Department of Natural Resources (DNR), and the Christopher Division of the Consolidation Coal Company (CONSOL). The object of this project was to demonstrate pollution control methods and to clean up a 37.8 sq km (14.6 sq mi) watershed severely polluted by coal mine drainage. A study entitled, "Water Infiltration Control to Achieve Mine Water Pollution Control" (EPA-R-2-73-142),(2) was conducted by the Cyrus Wm. Rico Division of NUS Corporation for the grantee to determine the feasibility of utilizing remedial techniques to improve the Dents Run water¬shed. This study showed that the Dents Run watershed was discharging as much as 6,870 kg/day (15,100 lb/day) of acid; 1620 kg/day (3,560 lb/day) of iron 17,250 kg/day (38,000 lb/day) of sulfates; and 29,500 kg/day (64,900 lb/day) of total dissolved solids into the Monongahela River near Morgantown, West Virginia. This pollution was caused by the combination of borehole pump discharges from active underground mines, runoff from abandoned strip mines, and runoff from refuse dumps.

Jan 1, 1977

By I. M. Arbuthnot

Over the last five years, a large number of small to medium sized carbon-in-pulp gold treatment plants have been built in Australia, most designed to treat between 250,000 -1,500,000 tpa of ore. In many cases, the primary requirement was to get a plant built and operating in a short period of time and at minimal capital cost, relating to the limited capital resources and tight cash flow positions of these relatively small mining companies. Since the inclusion of both pre-leach and tailings thickeners resulted in an obvious and significant capital cost, most plants were built without thickeners, without doing a detailed cost-benefit analysis on their inclusion, However, the increasing use of High Rate Thickener?s (HRT s) in the mineral processing industries resulted in a reassessment, in some cases, because of their considerably lower cost. This reassessment was triggered primarily by the need to conserve water in arid mining areas, where borefields were costly to install and water was limited. It has become apparent, though, since startup and operation of these installations, that the savings in cyanide consumption is also a very significant factor and can be used as a primary justification for the installation of a HRT in many cases.

Jan 1, 1991

By R. D. Smith

The Bureau of Mines (BOM) evaluated the technology, capital investment, and annual operating costs of emission control for further reductions of lead in ambient air at the East Helena, Montana, smelter, and the Glover, Herculaneum, and Buick smelter-refineries in Missouri. This study seeks to analyze the technology available to the domestic primary lead industry for attempting to further reduce lead emissions below 1985 levels. Through enclosure of concentrate unloading and handling areas and all lead-processing buildings, followed by venting these enclosures to the atmosphere through baghouses and the application of appropriate local controls, emissions can theoretically be reduced by a total of 2,424 pounds of lead per day from 1985 levels at the three Missouri operations. Using conventional technology, aggregated additional capital costs of $250,014,000 and annual operating costs of $18,507,800 are estimated for the four operations, resulting in a total cost of $0.063 per pound of refined lead. Continuous drossing techniques would assist in meeting OSHA standards in process areas. Continuous drossing would change capital and operating costs to $258,344,800 and $16,104,700, respectively, for a total cost of $0.062 per pound of refined lead. First quarter, 1986 open market price for refined lead was $0.184 per pound.

Jan 1, 1986

By J. van der Merwe, C. Phetolo, V. Matjeke

The mechanical properties and microstructure of AlSi10Mg alloy samples that were printed by selective laser melting (SLM) were studied to determine the effect of processing parameters and building orientation. After printing, the alloy was stress relieved at 250°C for 2 hours. The microstructures were analysed by optical microscopy and scanning electron microscopy (SEM) to determine the alloy phases and distribution. Phase transformation characteristics of the material were evaluated using differential scanning calorimetry (DSC). Mechanical properties were determined by subjecting the XY- and Z-built samples to tensile and nano-indentation testing. The samples from the tensile tests were then used to perform fractographic analysis by SEM. The microstructural properties in each orientation revealed a non-homogeneous microstructure which was characterized by a semi-elliptical tract and fine silicon precipitates, which were found to be softer along the fusion zone. The DSC thermograms revealed that the material underwent two phase transformations during the first heating cycle. The mechanical properties revealed a higher UTS, higher yield strength, and a lower percentage elongation in the Z orientation than in the XY orientation. Fractographic analysis showed that crack initiation in both orientations started from the surface in a brittle manner due to surface flows, and then propagated via microvoid coalescence.

Jul 1, 2021