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By Frame Ritzert, Dennis Keller, Vijay Vasudevan, David Arenas

"An investigation was conducted to describe topologically close packed (TCP) phase instability as' a function of composition in the advanced ·Ni-base superalloy Rene N6. TCP phases are detrimental to overfill high-temperature performance of Ni-base superalloys because of their brittle nature and because they deplete the Ni-rich matrix of potent solid solution strengthening elements. Thirty-four variations of polycrystalline .Rene N6 determined from a design-of-experiments approach were cast and homogenized at 13 l5°C for 80 hours followed by exposure at 1093°C for 400 hours to promote TCP formation. The alloys had the following composition ranges in atomic percent: cobalt 10.61 to 16.73, Mo 0.32 to 1.34%, W 1.85 to 2.52%, Re 1.80 to 2.11%, Ta 2.36 to 3.02%, Al 11.90 to 14.75%, and Cr 3.57 to 6.23%. Physical and chemical characteristics of all microstructures obtained were described using various analytical techniques. From these observations, a mathematical description of TCP occurrence (s and P phase) was generated for polycrystalline Rene N6.IntroductionNi-base superalloy single crystals represent the state-of-the-art for turbine engine airfoil application as they offer the best balance of properties to allow for the high operating temperatures required: for efficient engine operation.1 Current trends in alloy design take advantage of improved creep rupture strength with the addition .of higher levels of refractory elements. 2 In .particular, the addition of significantly higher levels of Re in third generation superalloys is key for both microstructural stability and creep rupture strength. 3 While the presence of the refractories is thought to provide strength benefits from solid solution hardening, a tendency for alloy instability in the form of topologically-close-packed (TCP) phases or secondary reaction· zone (SRZ) ·phenomena accompanies the high refractory content. 3 The formation of these phases in sufficient amount is detrimental to the overall high temperature performance of Ni-base superalloys because of their brittle nature and because they deplete the Ni-rich matrix of potent solid solution strengthening elements.4 The tendency for a particular composition to form TCP may not be immediately known since the precipitation of TCP phases in Ni-base superalloys is nucleation controlled, thereby requiring long times at elevated temperatures to precipitate. 5 They preferentially nucleate along the octahedral planes of the Ni-base superalloys, usually in areas of refractory metal enrichment at grain boundaries or inside dendrites.5-6 In Rene N6, two closely related TCP phases, a and P, have been observed.2"

Jan 1, 1998

By M. Paul

"INTRODUCTION In 1990, the uranium production of SDAG Wismut in East Germany was stopped. 45 years of inconsiderate destructive exploitation had scarred both landscape and nature. With the “Wismut law” which came into force in December 1991, the Federal Republic took responsibility of the remediation of the legacies from former uranium ore mining and milling in Saxony and Thuringia. A unique opportunity turned out in order to remove environmental damage, to enhance the life quality of the local population, to shape new landscapes and to advance the economic restart. (1) The results of nearly 25 years of remediation activity are evidence that this opportunity was used at all former SDAG (Sowjetisch-Deutsche Aktien-gesellschaft) Wismut sites. The reference project “Wismut“ has evolved into a joint project of all parties involved and radiates beyond the affected regions. This is particularly reflected by the Know-how transfer starting from Wismut and the increasing activities for third parties abroad.WATER MANAGEMENT AT WISMUT REHABILITATION Within the Wismut project, water management and conventional technical water treatment are by far the most cost-intensive long-term tasks of the remediation programme. Over the medium term, there is no viable alternative to the operation of active systems to catch and treat contaminated mine waters at the Ronneburg, Schlema, Königstein, Pöhla, Seelingstädt and Helmsdorf sites. Based on the status quo, this paper outlines the key issues of the Wismut GmbH water management strategy over the medium and long term. It is focused primarily on achieving protection goals for potentially impacted water bodies in the surroundings of Wismut sites and on optimising associated remediation expenditures as well as on creating the prerequisites for achieving low post-remedial care and maintenance or walk-away system status over the long term. (2) The applied mining practices during the active SDAG Wismut period have not been up to the high standards of modern mining operations and their requirement to leave former production premises and deposited residues in a condition that was not only physically but also chemically stable. Rather the emission of mine and seepage waters laden with high acidity, metal and salt content is a frequent corollary and difficult legacy of historic mining and processing operations (4, 5). As a consequence, the control or mitigation, respectively, of environmental impacts associated with contaminated mine waters ties up enormous public resources worldwide (6, 7)."

Jan 1, 2016

By J. M. Skeaff

As much as 100% of the gold and 67% of the silver in a sulphur-bearing hydrometallurgical leach residue have been transferred to copper metal at copper smelting temperatures by dissolving the partially calcined residue in an iron-bearing slag maintained in equilibrium with the liquid copper metal and matte phases. The precious metals can then be recovered by conventional refining techniques. Copper can be recycled at least four times without any detrimental effects on gold and silver transfers and recoveries. Apparent copper recovery in the .process can be over 100% because of the copper content of the residue. Based on slag analys.es, the overal1 recovery of gold in the copper metal and matte phases varies from 94% to 100% under all conditions investigated. On the? same basis, silver recovery varies .from 9S% ?to 99% under optimum conditions, but is only 4S% to 73% under other, less attractive conditions. Unaccounted for silver losses of' about 30% make it difficult to determine the major factors affecting ?silver transfer and recovery. A method for implementing the technology on a commercial scale at a Canadian copper/zinc smelter has been proposed. A preliminary economic assessment and comparison of the proposed pyrometallurgical process with conventional cyanidation indicates that either process is economically attractive for recovering gold and silver from leach residues. Although the capital costs are higher, the pyrometallurgical process is simpler, has higher recoveries, lower operating costs and no .potential environmental problems related to cyanide disposal.

Jan 1, 1989

By L. J. Barnes, R. O. Koch, J. H. Versteegh, P. J. H. Scheeren, F. J. Janssen

Following two years of laboratory research with bench scale reactors, a 9 m3 experimental process demonstration reactor was installed at Budelco's zinc refinery to treat their underlying groundwater. A 600-fold scale-up was successfully achieved. It has demonstrated that this anaerobic microbial process can remove a wide range of heavy metals and sulphate to the required levels. Extended operation of the demonstration unit has shown that the process is robust, can withstand wide variations in feed composition, rapidly recovers from operational upsets and is easy to start up and shut down. The metal sludge produced can be processed in a metal refinery to recover both metals and sulphur.

Jan 12, 1992

By Claudio Asioli

"The project’s goal was to construct the Al Ghazala Intercontinental, a multi-use development in the bay area of Tripoli overlooking the Mediterranean Sea. The site of the project is located approximately 500 ft (150 m) from the Mediterranean coast, near the Al Ghazala roundabout in the town center of Tripoli, Libya. The investor of the project was Magna Properties Group, Ltd. – Libya, the main contractor was Man Enterprise S.A.L., and the design and construction management was performed by Dar Al-Handasah Engineering. Trevi S.p.A. was contracted to perform the design and construction of the anchored diaphragm walls and dewatering systems for the excavation of a two-level basement car park, which extends across the full footprint of the site.The site was approximately 640 ft by 230 ft (195 m by 70 m) in plan and nearly flat. The groundwater level typically varies from about 11 ft to 23 ft (3.4 m to 7.0 m) above mean sea level. To construct the required raft foundation, it was necessary to excavate the area down to El. -15.7 ft to -26.3 ft (-4.8 m to -8.0 m), which resulted in an excavation depth ranging from about 27 ft to 39 ft (8.3 m to 12.0 m) below the existing ground surface. Subsurface ConditionsThe subsurface site investigation was performed in three phases by Al-Tamier Engineering Consulting Bureau. During Phase 1, a preliminary investigation was undertaken during the early stages of the project to obtain information about the general stratigraphy and groundwater level at the site. Phase 2 was performed to obtain subsurface information and design parameters, and Phase 3 was performed as a supplementary ground investigation to investigate unexpected ground conditions identified during Phase 2. In total, 14 boreholes were drilled to depths ranging from about 80 ft to 180 ft (24 to 55 m). The generalized subsurface profile is quite heterogeneous, and is predominantly composed of sand with silt and gravel that is underlain by limestone, calcarenite and claystone."

Jan 1, 2017

By J Say, M Hawtin, L Carlon, P Cann

Historically, production from sublevels of the Ernest Henry Mine (EHM) started from blind uphole rises at the end of slot drives. Where previous investigations considered removing these slot drives and starting production with independent ore drives, any development savings were consumed when drives were extended to minimise ore loss. Since 2017, EHM and Orica have been investigating opportunities to optimise drill and blast practices by implementing Orica’s Wireless Electronic Blasting System (WEBS). To reduce ore drive development metres, a novel design was proposed utilising the WebGen™ 100 system to combine a rise with pre-charged widening firings. Initially these new rise and widening firings achieved results similar to previous EHM designs, achieving on average 81 per cent of design height and width. Due to poor performance of the fourth trial a significant re-design was required. Modifications included drill hole re-positioning, in-hole primer relocation and initiation delay adjustments. Since the re-design a step change in rise performance has been observed with rise and pre-charged widening shots averaging 95 per cent of design height and width. With rise and widening performance exceeding expectations, the removal of slot drives has allowed a substantial reduction in lateral development. Development savings of 165 m and 169 m from the RL1325 and RL1300 levels have been achieved. Primary draw and ore recovery has also increased due to the later addition of pre charged forward stripping rings. Level design changes have also significantly improved the mining cycle by allowing for a reduction in required ground support, improved secondary ventilation, a reduction of critical path development, simpler production scheduling and less wear and tear on machinery. Future mine level designs now incorporate key learnings and are proving beneficial to a variety of scenarios including changing orebody boundaries at depth.

Mar 15, 2021

By R. W. Hiteshue, R. W. Fridy, W. Kawa

A study of the production of coronene , a high - melting ( 440 ° C ) , highboiling ( 525 ° C) , polynuclear hydrocarbon , was made by the Bureau of Mines to determine the maximum yield obtainable by the hydrogenation of coal and coalderived materials . Experiments were made with anthracite and bituminous coals and with asphaltenes and centrifuged residue obtained from heavy oil produced in a pilot plant by the hydrogenation of a bituminous coal at 2,000 psi and 480 ° C. With anthracite , yields of coronene of 0.5 to 0.7 wt pct of moistureand ash - free coal were obtained at 6,000 to 8,000 psi , 700 ° to 750 ° C , and a residence time of 30 minutes . With bituminous coal , yields averaging 0.4 wt pct of maf coal were obtained at 6,000 psi , 800 ° C , and 30 minutes ' residence time . With asphaltene and centrifuged residue , yields of less than 0.02 wt pct of maf coal were obtained at 6,000 psi , 700 ° C , and 60 minutes ' residence time .

Jan 1, 1964

By Yisa Liu, Lili Xu, Shina Li, Kang Li, Jiong Dong, Zichen Yin, Ruixin Ma

With the evolving landscape of gold mineral resource development and utilization, the easily treatable gold resources are continuously decreasing, while refractory gold minerals are becoming the most important resources in the field of gold extraction. In these original ores, most of the gold is encapsulated in the lattice of pyrite and arsenopyrite, resulting in difficulty of gold transfer into the solution during the leaching process. The most effective method to solve the problem of insufficient contact between gold particles and leaching reagent is oxidation pretreatment before leaching. Different from traditional high-temperature roasting, concentrated sulfuric acid was used as both an oxidant and leaching agent in a sulfideencapsulated refractory gold ore to decompose the pyrite in the curing environment to expose the gold and improve the leaching efficiency. The experimental results showed that under the conditions of liquid solid ratio 3:1, curing temperature 240 °C and the reaction time 1.5 h, the weight loss rate and iron removal rate of the ore sample reached the highest value of 60.01% and 99.68%, respectively. The main phase of curing residue was Fe2( SO4)3, and silica was nearly the only phase after washing. At the same time, by combining the sodium thiosulfate system gold leaching method, the gold leaching rate increased from 3.67% to 81.30% before and after pretreatment with concentrated sulfuric acid.

Feb 19, 2024

By Robert C. Dyni

The use of techniques and equipment designed to pneumatically place backfill into an underground mine opening through boreholes for subsidence abatement has historically met with limited success, largely due to the inability to directly monitor the placement of the backfill in the opening. The success of a backfilling project cannot be guaranteed if it is not known whether the underground opening has been completely filled with backfill material. To overcome the inability to directly monitor backfill placement, the U.S. Bureau of Mines developed a pneumatic backfilling system that allows for direct viewing of the backfill as it is placed in an underground mine opening. This system utilizes a recently developed pneumatic nozzle coupled with an instrumentation package that allows for real-time observations and measurements of backfill placed in an underground opening through a borehole. The nozzle utilizes a high-velocity airstream to redirect backfill falling through a pipe in the borehole and directly in front of the nozzle; the airstream redirects and propels the backfill horizontally into the .mine opening at over 100 ft/s. The instrumentation package, mounted directly to the nozzle, contains a video camera, high-intensity lamps, laser-rangefinder, electronic compass, and water sensor.

Jan 1, 2010

By A. Khodadadi, M. Abdolahi, P. Taimory

Cyanide is used by the mining and chemical industries in tremendous quantities without attention being given to its hazardous properties. The use of cyanide compounds in mining is one of the most important environmental issues for the mining industry due to the acutely toxic properties of many cyanide compounds to humans and aquatic life. Cyanide tends to react readily with most other chemical elements, producing a wide variety of toxic, cyanide-related compounds and because cyanide is carbon based an organic compound it reacts readily with other carbon-based matter, including living organisms. This research is aimed at investigating a feasible and economical technique for the removal of cyanide from tailing wastewater of Muteh gold mine. In this research, removal from Muteh factory's waste water, was achieved at Tarbiat Modares University's mineral processing laboratory through the oxidation of cyanide by calcium hypochlorite. Cyanide oxidizes and changes to cyanide (CNO-) which is 1000 times less environmentally hazards than cyanide. Cyanide titration was accomplished using Rhodanine solution and silver Nitrate. Cyanide concentration in the wastewater, was 270 mg/L. Cyanide removal was achieved at an optimum pH of 12.3. However, at higher temperatures, cyanide removal was complete at this pH level. Optimum Dosage for complete removal of cyanide using calcium hypochlorite was 1.43g/L.

Jan 1, 2005

By Xavier B. Starnes

The Dike and Eaton veins in Crittenden County, Ky. (fig. 1), are along northwesterly trending relief fractures that lie between two northeastward striking major faults - the Moore Hill and- the Levias, in Crittenden County, Ky. The veins contain small, narrow, irregular ore bodies of fluorspar with subordinate quantities of sphalerite and galena. Gravel fluorspar was found on the surface in the Eaton vein, and open-cut mining was in progress on the W. M. Conyer property about 1900. Discovery of fluorspar in the Dike vein came much later, about 1933, on the W. H. LaRue tract, but the principal production on the Dike vein started after the discovery of gravel spar in 1938 on the land of the P. J. Gilless estate. Production from the Eaton vein was estimated at 9,400 tons and that from the Dike vein at 15,700 tons, a total of 25,100 tons. A large part of this production was gravel fluorspar from within 50 foot of the surface. Beneath the gravel spar the veins are very narrow, averaging 2 to 2.5 feet in width, and the ore shoots are small. The deepest mine level was 140 feet below the surface, and the deepest shaft 150 foot. Orb was concentrated by log washer or sent unwashed to custom mills at Marion, Ky. about 6 miles distant.

Jan 1, 1950

By Jr. Kauffman

The data contained in this report were obtained incidental to the Bureau of Mine's investigation of the lime-soda sinter process as applied to the recovery of alumina from siliceous bauxite, kaolin, and other high aluminous materials. The Bureau of Mines was charged by Congress to investigate processes for the production of aluminum from domestic low-grade ores. The Eastern Experiment Station at College Park, Md., conducted laboratory and pilot-plant investigations of the recover-y of alumina by the lime-soda sinter process. Reports by the College Park staff covering the recovery of alumina from these sources have been published. The lime-soda sinter process involves the sintering of the finely ground siliceous bauxite or clay with limestone and soda ash in a rotary kiln. During the sintering the alumina supposedly reacts with the soda ash to form soluble sodium aluminate and the silica combines with the lime to form the insoluble orthosilicate. In the early stages of the investigation it was considered desirable to know the temperatures at which the phase changes occurred during the sintering operation. The total time involved in the passage of any given portion of the charge through the kiln was 28 minutes. The exposure time of the charge to temperatures above 600° C. (decomposition temperature of kaolinite) was, roughly, half the total. The exposure to the full temperature of the kiln, 1,100° C was only 3 minutes. (Subsequently, the maximum kiln temperature and retention time were increased.)

Jan 1, 1949

By N B. McCaffrey, V Glenn, C Johns, P D. Erskine, A T. Fletcher

"Underground coal mining is the dominant method of extracting thermal and coking coal in the southern and western coalfields of New South Wales. Monitoring mining-related subsidence forms an important component of environmental impact assessments and subsidence management plans, particularly when there are conflicts between the interests and requirements of mining and environment and community groups. However, there are few specific guidelines for monitoring the impacts of subsidence on terrestrial and aquatic ecosystems, leading to inconsistent policy approaches and highly variable abilities of monitoring programs to accurately detect biological change.This paper highlights the use of a conceptual framework to guide the development of a long-term ecological monitoring program at an underground coalmine in the Western Blue Mountains, New South Wales. Two pilot studies are described: determining the level of observer agreement to assess the condition of a vulnerable tree species (Capertee Stringybark) comparing field sampling methods for detecting a rare heath shrub, Epacris muelleri, using a power analysis to determine sampling intensity requirements.These examples demonstrate that investment in initial pilot studies to test different monitoring approaches can have long-term benefits for stakeholders by more confidently being able to detect potential impacts.CITATION:McCaffrey, N?B,?Glenn, V, Erskine, P?D, Johns,?C?and Fletcher, A?T, 2014. Detecting long-term ecological impacts of subsidence from underground coal mining – a tale of two pilot tests, in Proceedings Life-of-Mine 2014, pp 139–152 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 16, 2014

By M. L. Joy

The heat pipe is a self-contained, passive structure that uses a liquid-vapour fluid cycle to provide high thermal conductance . Through the proper selection of working fluids and container materials, heat pipes have been operated at temperatures ranging from less than -300°F to more than 3,000 °F. The passive nature, high efficiency and configuration flexibility of the heat pipe are presented. The application of McDonnell Douglas Astronautics Company Cryo-Anchor® heat pipes for foundation and support stabilization in permafrost regions is discussed. Using the proven Cryo-Anchor technology base. a proposed application of heat pipes in a cold -region mine ventilation system heat recovery heat exchanger is presented. Information obtained from the development of an air-cooled heat pipe steam condenser provides the technical basis for large -scale heat pipe applications.

Jan 1, 1978

By T. Iwasaki

This paper points out two key elements in resource trade in general and the Canada-Japan relationship in particular. The first is that the advanced countries have a more important role than one would expect in the supply of resources in world trade. Canada 's dual role as a major resource supplier in conjunction with an advanced economy will continue to increase. The second point is the heavy reliance on foreign resource supplies in some advanced economies, particularly in Japan. Finally, as regard the future of the Canada-Japan economic relationship, particularly .in resource development, it is suggested that trade could be enhanced by an accelerated exchange of various types of resources between the two countries. These include natural resource commodities as well as the more abstract capital, technological and human resources.

Jan 1, 1978

By H. P. Hermance

Preliminary examinations of the Parker and Webb deposits were made by E. E. Maillott, Bureau of Mines engineer in July 1942. The chemical and spectrographic analyses included in this report wore made at the Eastern Experiment Station of the Bureau of Mines at College Park, Md., under the general supervision successively of S. M. Shelton and of Paul M. Tyler, formerly regional engineer, Eastern Region. Beneficiation tests were conducted under the supervision of Frank D. Lamb. The mineral exploration was under the general supervision of J. D. Bardill, formerly district engineer. Acknowledgment is gratefully made to the St. Joseph Lead Co., in particular to John S. Brown and P. J. Mechin for their assistance. Special acknowledgment is made to the American Metal Co., Ltd., ,Ind to T. C. Moore for furnishing core-drill and assay data; to the Universal Exploration Co. and P. B. Jennings; and to the Northern New York Mining Corp. and C. H. Sprague for their permission to publish the core-drill dta. Excellent cooperation was given by Dr. W; M. Agar and C, L. Rogers of the Geological Survey.

Jan 1, 1949

By P. R. Tisot

Knowledge acquired from this research contributes to a better understanding of the physical structure of Green River oil shale and provides fundamental data and concepts that may serve to improve oil-shale technology. This study by the Bureau of Mines indicates that oil shale is a highly consolidated organic-inorganic system with no significant micropore structure, pore volume, or internal surface. This system is a form of physical structure that precludes rapid diffusion of either gases or liquids. The mineral matter consists essentially of nonspherical particles that tend to follow a log-normal size distribution. An excess of 99 weight-percent of these particles have equivalent spherical diameters of less than 44 microns--75 weight-percent are from 2 to 20 microns, and 15 weight-percent are less than 2 microns. The surface area (3 to 5 square meters per gram) of these mineral constituents is mainly external surface. The mineral constituents contain some micropore structure--pore radii ranging from 10 to 100 Angstrom--with the pore sizes randomly distributed. Distribution of the organic matter within the inorganic matrix is essentially interparticle and not intraparticle. The organic matter within the micropores of the mineral constituents is less than 4 percent of the total. Estimates made from surface area data suggest that perhaps only a small amount of the organic matter is bonded either physically or chemically to the mineral constituents.

Jan 1, 1963

By N. L. Kozlinsky, B. W. Gandrud

"The Marvel mines 1 and 3 of the Roden Coal Co. are located in the Cahaba field in Bibb County, Ala., nearly southwest from Birmingham, an airline distance of roughly 30 miles. The coal of the Clark seam at this point has some coking properties, but at present it is sold exclusively as a domestic and steaming coal.This paper, which is the second of a series on the washability of Alabama coals, like its predecessor dealing with the Mary Lee seam,5 contains screen-sizing and float-and-sink tests of a representative sample of the raw slack, and slotted-screen tests showing the proportions of flaky particles in certain selected sizes; inasmuch as this coal is not used for coke manufacture, no crushing tests have been made. These data have been obtained in connection with an exhaustive study of coal preparation in Alabama, now being conducted by the United States Bureau of Mines and the University of Alabama with the cooperation of the different coal operators. As the work progresses, other papers will follow containing further data on Alabama coals and giving results obtained in preparing these coals by various methods.The only published investigative work on the Clark seam is that of Forbes,6 who gives a number of sections of this seam in Marvel No. 3 mine with proximate and ultimate analyses of face samples taken in the mine and also some analyses of delivered coal.The available information on this coal indicated that the preparation problem was one of ash reduction. In order to substantiate this information a complete analysis of the 3/4 by 3/16 inch size, and sulphur determinations and ash-fusibility tests of the float-and-sink fractions have been made; these results are given in Tables 1 and 2. As these results also indicate that the preparation problem is one of ash reduction, the tests and discussion have been devoted to that subject."

Jun 1, 1930

By Gary P. Sames

This U.S. Bureau of Mines study was conducted in eastern Kentucky drift mines as part of an ongoing research program to characterize the outcrop barrier zone. "Hillseams" were identified as the dominant geologic cause of roof instability unique to the outcrop barrier zone, with many roof fall injuries and fatalities attributed to them. Hillseam is the eastern Kentucky miners term for weather-enlarged tension joints that occur in shallow mine overburden where surface slopes are steep. Hillseams are most conspicuous within 200 ft laterally of a coalbed outcrop and under 300 ft or less of overburden. Hillseams form by stress relief, and therefore tend to parallel topographic contours and ridges. They can intersect at various angles, especially under the nose of a ridge, and create massive blocks or wedges of roof prone to failure. Examples of hillseams are described in both outcrop and in coal mine roof to establish their geologic character and contribution to roof failure.

Jan 1, 1989

By R. E. Zimmerman

Wide attention is being placed upon various methods for cleaning the fine sizes of bituminous coals. The author describes and analyzes the results achieved on wet concentrating .tables of modern design on unclassified feeds of - 1/2 in. particle sizes, including tests on high-sulphur coals.

Jan 1, 1950