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By W. G. Wu

More and more researches and applications of organic chelating agents as depressors or activators are carried out in the course of research and application of modern flotation. The paper puts forward the necessary condition of organic chelating agents as depressors or activators by analyzing the chelating chemical performance of organic chelating agents with metal ions and the stability of chelates formed by them; at the same time, puts forward four sufficient conditions of organic chelating agents as depressors or activators according to different hydrophilic capability of the chelates and different performance of depression and activation of organic chelating agents for minerals. Namely, the ?1+1/4? necessary and sufficient conditions of organic chelating agents as depressors or activators are put forward.

Jan 1, 2014

By Anna Franzkowiak, Dean Gregurek, Alfred Spanring, Angelika Ressler

In order to determine the most suitable refractory products and improve the lining lifetime for the diverse furnaces used in the nonferrous metal industry, corrosion tests are performed at RHI’s Technology Center. The practical facilities include the cup test, induction furnace, rotary kiln, and drip slag test described in this paper, which enable a comprehensive understanding of the chemo-thermal brick wear on a pilot scale. The corrosion trials are performed with actual slags generated during operations at a customer’s plant. To determine the highest influencing wear parameter, every single test is combined with a detailed mineralogical investigation and thermochemical calculations performed using FactSage. Based on the results, tailored refractory solutions for the nonferrous metal industry can be provided in combination with trials conducted at the customer’s site.

Jan 1, 2014

By Alessandro Bertero, Stefano Valagussa, Filippo Maria, Wesley Schmutzler, Leoni

"Abstract The Deep Mixing Method (DMM) represents a viable solution to improve the adverse geotechnical properties of foundation soils. Differences and the importance of performing pre-construction laboratory and field tests will be highlighted. Comparative analyses and interpretations between the various lab and field stages, along with accumulated information about soil properties and QC results, allowed fine-tuning of the production parameters throughout almost the entire project.Two projects where the US Army Corps of Engineers selected the Deep Mixing Method (DMM) for the required stabilizations, and a third project completed in Italy, will be illustrated:•,?the LPV 111 Project (New Orleans - LA – USA); DMM was used for groundimprovement/foundation strengthening and consequently stabilize and support the burden of the new levee.•,the Rio Puerto Nuevo Project (San Juan - PR - USA); DMM was applied to improve the soils adjacent to a 90” forced sewer main relocation and to improve the soils for the base of a new drainage channel•,the new Italian high speed railway project (Florence Italy); DMM technology was applied to realize a a TBM break in/break out, foreseen originally by jet-grouting.IntroductionThe Deep Mixing Method (DMM) represents a viable solution to improve the adverse geotechnical properties of foundation soils. The effectiveness of working parameters depends largely on the physical and mechanical properties of the soil to be treated. Therefore, well designed laboratory and field test programs, aimed to disclose the interaction between the site-specific soils and the mixing parameters, are essential to achieve the desired end product."

Jan 1, 2014

By Robert F. Stevens, Robin Givet, Kenneth Viking

"Summary This paper describes a case of a directional pile installation conducted from an existing oil platform in the Caspian Sea, offshore Baku. Results are presented for 660 mm outer diameter (660 mm OD) conductor piles. Each conductor was equipped with a beveled aluminum toe for directional impact driving and was driven through a 710 mm casing using a Delmag 100–13 diesel hammer and a chaser pile. The 710 mm casings were preinstalled to a depth of 75 m below mud line (75 m BML). The longest impact driven conductor pile on the project was 456 m at end of drive, and reached the terminal depth of 295 m BML.Soil conditions consisted of soft to stiff silty clay to a depth of 30 m BML, underlain by stiff clay to 96 m BML, very stiff silty clay to 200 m BML, and very stiff to hard clay down to 300 m BML.In order to assess the maximum stresses in the conductors and check the performance of the hammer, the driving of each conductor was monitored using a Pile Driving Analyzer (PDA). The hammer fuel setting was adjusted based on the PDA outputs to ensure the conductors were not overstressed during installation. All driving and monitoring operations were carried out from the drill floor.The conductor piles drove easier than anticipated but in the direction predefined by the pre-cut angle of the beveled aluminum toe. The driving system performance was good. Post driving, the SRD were analyzed by either the global method analysis, using WEAP, or by the CAPWAP program.To detect any collision between the conductor being driven and the adjacent wells in production, the well heads were monitored in real time with high sensitivity accelerometers. These accelerometers were connected to an alarm system on the drill floor, triggering a siren and a strobe light should a collision be detected by an abnormal increase of the peak acceleration.IntroductionThe world longest directional impact driven pile was installed in year 2005. The operation was carried out from an offshore production, drilling, and quarters (PDQ) platform located about 120 km east of Baku, in the Caspian Sea.The platform foundation consists of driven piles and 24 slots were available for drilling the wells to the reservoir, located about 3800 m below sea floor. Each slot was fitted with a casing, 710 mm in diameter, running from the top of the jacket to a depth of about 75 m BML (Figure 1). Oil production started in 1997 and by the end of 2003, 14 wells were in operation; 10 slots were therefore still available, either for oil production or for water injection. However, due to larger than expected settlement of the platform, drilling of additional wells was put on hold. After further investigation, experts concluded the settlement was due to an alteration in the mechanical properties of the bearing strata supporting the foundation piles. This alteration was due to either excess soil material transportation, or soil fracture by the drilling fluids (mud), when drilling the first wells. With only 14 wells in production, out of 24 possible, the owner faced a new dilemma: to drill, or not to drill new wells?"

Jan 1, 2014

By Sean Masse

New Gold?s New Afton Mine, located 8 km (5 miles) west of Kamloops, British Columbia, is a 4.5-Mt/a (5-million stpy) block cave mine, making it the highest tonnage underground hard rock mine in Canada. The reserve is estimated at 52.5 Mt (55.9 million st) with grades of 0.65 g/t (0.02 oz/st) gold and 0.93 percent copper (2012). Commercial production was achieved in July 2012 and nameplate production was achieved ahead of schedule in September 2012, with the cave breaching to surface in 2013. The mill has a SAG and a ball mill with a froth flotation circuit.

Jan 1, 2014

By Dena Morgan, Emre Biringen

"Abstract This paper discusses the execution of pile installation and design issues at two environmentally challenging industrial sites in North America. Environmental regulations set constraints on the design and require versatility in choice of technology.For a proposed bridge, due to protected fish habitat, performing soil borings within 30 m of the creek embankment was prohibited. The limited subsurface profile indicated a thick upper layer of granular material, thus driving H-piles was considered. However, to limit generation of vibration and noise in the protected area, drilled piles had to be used. During execution, the subsurface profile differed from that in the borings 30 m away. Very soft, saturated silt was encountered at the bottom of the caisson and the length had to be redesigned very quickly while the contractor waited for instruction. For a new structure in uncontrolled fill area, performing soil borings was not allowed. It was known that a layer of peat was present in the area, but no information regarding the thickness and extent. The subsurface profile generally consisted of granular material overlying a thick compressible silt layer. Somewhere within the granular layer peat would likely be encountered. Franki piles were chosen to penetrate the peat and bear in the underlying granular material. During environmental sampling in the area, methane gas was encountered and Franki piles were no longer a viable option due to safety concerns. The foundation system was changed to steel H-piles driven to bedrock, which was more than 50 m below the ground surface and sloping. Rock shoes that would work to significant slopes had to be used in order to increase the likelihood of good embedment within the bedrock. Also, due to obstruction of an approximately 3 m thick debris field that was encountered in the upper granular soils, some of the piles had to be relocated and extra piling needed to compensate for such differences. The results of PDA testing to estimate compressive capacity and a series of lateral load tests are presented.INTRODUCTIONThe design issues that are encountered during construction can be quite problematic and have a significant impact on schedule. In order to avoid such impact on the project, a thorough subsurface investigation should be considered prior to design and construction. Better understanding of environmental regulations also prevents costly changes to the foundation design. This paper discusses the execution of pile installation and the design issues at two environmentally challenging sites in North America.BRIDGEDuring the subsurface investigation for a proposed industrial building complex, several boreholes were drilled within the footprint or in close proximity of various structures, with Standard Penetration (SPT) sampling of the upper coarse-grained soils (sand/gravel) and undisturbed sampling of the lower fine-grained soils (silt/clay). The SPT blow counts (N60) were corrected by a factor of 1.35 in order to incorporate the SPT automatic energy transfer ratio. When Modified California Sampler was used, a correction factor of 0.44 to 0.64 was also applied. N60 values were further corrected for gravel to avoid artificially high blow counts during the analyses due to spoon samples contact with gravel and cobbles, and the corrected values of (NG)60 (limited to a maximum value of 50 blows/300 mm) were used for design. The information from the SPT boreholes was then used to assess the subsurface conditions beneath the structures, as well as for a nearby bridge that was designed to cross over a creek. Since performing soil borings within 30 m of the creek embankment was prohibited due to the protected fish habitat, the investigation with regard to the bridge abutments was limited to two deep boreholes (B10-33 and B10-34) at the bridge location and two additional boreholes (B10-35 and B10- 36) located approximately 200 m upstream. The bridge location and two sets of boreholes are"

Jan 1, 2014

By Shahriar Vahdani, Andy Herlache, Andrew Bro, Wei-Yu Chen

"The Presidio Parkway Project will reconstruct approximately 1.6 miles of highway, including seven bridges, three cut-and-cover tunnels, and an undercrossing connecting the Golden Gate Bridge to the City of San Francisco, California. The project site is approximately 5.6 miles from the San Andreas Fault, which is capable of producing magnitude 8 earthquakes. Seismic hazards include strong ground shaking, soil liquefaction, ground settlement, and lateral spreading. At the Tennessee Hollow bridge section up to 30 feet of loose sands and soft clays are present. Concerns are raised that standalone drilled piers will experience excessive lateral soil loads from liquefaction-induced lateral spreading pressure resulting in excessive pier head displacement of up to 8 inches. Ground improvement by Cement Deep Soil Mixing (CDSM) is proposed to provide additional foundation stiffness. This paper presents the methodology to: 1) assess the effectiveness of the ground improvement in resisting lateral spreading, and 2) optimize ground improvement design at individual bridge bents based on local site condition. A series of 3-D numerical analyses are conducted and the results show that drilled piers with CDSM ground improvement are capable of withstanding seismic demands from lateral spreading and the lateral pier head displacement is reduced to less than 2 inches. The adopted analytical approach is efficient at modifying design for individual bents and can be considered for future pier foundation design in seismically active areas. IntroductionThe Tennessee Hollow bridge section (Low Viaduct) is an integral component of the Presidio Parkway project which will replace the existing facility with a new multi-lane roadway between the Golden Gate Bridge and the City of San Francisco. As shown on Figure 1, the project site is located about 5.6 miles east of the San Andreas Fault and 12.5 miles west of the Hayward Fault. The Low Viaduct will span over a future wetland habitat subject to tidal fluctuations and potential scouring."

Jan 1, 2014

By L. Chunpongtong

The mining limit in oil sands is regulated by the ratio of total mining volume (ore, interburden, and overburden) one has to mine per volume of bitumen in place (TV/BIP). This paper presents a mathematical solution for creating the most economical pit outline where the TV/BIP ratio upper limit is 12, by combining mining economic theory and the Lerchs-Grossmann (LG) algorithm.

Jan 1, 2014

By D. Sprott, P. A. Kirsch, J. Harris, D. Cliff

This paper details the work of RISKGATE, the largest Australian Coal Association Research Program (ACARP) occupational health and safety initiative to date. The program is an interactive online risk management system developed to maximize health and safety performance in the coal mining industry by implementing continuous improvement in managing major unwanted events. The comprehensive knowledge base covers tires, collisions, fires, isolation, strata control underground, ground control open cut, explosions, explosives, manual tasks, and slips/trips/falls. All major Australian coal mining companies contributed topic experts to this broad industry initiative: nine coal mining companies, more than 80 experts, and more than 400 days of individual time for knowledge-capture workshops.

Jan 1, 2014

By B. R. Conard

Copper refining at Vale Canada (previously known as Inco) has been associated with Ni production. Because Cu and Ni carry risks for adverse health endpoints through inhalation exposure, it is critical that their aerosol levels, and the metallurgical processes through which they enter the air, are understood. Because certain Ni substances have been linked to respiratory cancers, it is also important to characterize the amounts and types of Ni compounds in occupational settings. This paper describes electrorefining and electrowinning operations near Sudbury, Ontario (1930–present), and gives aerosol measurements (1978–present).

Jan 1, 2014

By A. Sokolov, E. Hasikova, V. Gostilo, V. Titov

Introducing online X-ray fluorescence (XRF) analyzers in the mining and processing industries can lower costs and improve the representativeness and speed of analysis. The applicability of the CON-XTM industrial conveyor XRF analyzer for continuous measurement of potassium content in process materials was demonstrated at various stages of potassium muriate (MOP) production. The CON-X analyzer produced reliable and accurate results for sylvinite ore (27–36% KCl), MOP cake after flotation (88–97% KCl), and NaCl residue (1.5–5% KCl). Tests of the analyzer at an MOP-producing plant showed a < 0.5% difference between online and laboratory results.

Jan 1, 2014

By A. M. Ramadan

The composition of phosphate rocks, mainly used in manufacturing fertilizers, varies among deposits; therefore, phosphate rocks from different sources are expected to behave differently in acidulation processes. This paper examines the effect of preconcentration of phosphate ore from El-Sebaiya East, Egypt, using flotation on uranium leaching. A high-grade ore sample (27.3% P2O5, 168 mg/kg U) supplied by the Al-Nasr Mining Company, was subjected to reverse single-stage flotation to separate carbonate from the phosphate sample. Subsequently, P2O5 and U concentrations were 32.2% (92.1% recovery) and 225 mg/kg, respectively. After the leach process, the U concentration in the liquor was 319 mg/L.

Jan 1, 2014

By Ri McCrindle

"Analytical Chemistry is moving rapidly towards a concept where technicians have to do no more than press a button and print the result from an instrument that is a featureless ""black box"". In this environment we must ask how much traditional &apos;&apos;wet chemistry"" is still required for undergraduate students.Methods that can be fully automated will become increasingly important. An example of such a method is that of the slurry nebulisation and ICP-OES analysis of precious metal concentrate. Grinding the sample and adding Triton X100 as dispersant, complete analysis time is in the order of 90 min as apposed to the traditional Carius tube method which could take as long as 24 h. For most of the elements studied, the results using ""in-house"" reference material for calibration and as samples as well were within the 95% confidence level. Elements of low concentration in the sample (As, Bi and Se) were not within that level."

Jan 1, 2014

By Yasuhiro Konishi, Norizoh Saitoh

"We have developed new recycling technologies, based upon an eco-friendly biotechnology, in order to extract precious and rare metals sourced from post-consumer products. Recently we have been focusing on the metal ion-reducing bacteria, Shewanella algae and Shewanella oneidensis, which are able to reduce and deposit the precious metal ions (gold (III), platinum (IV), palladium (II), and rhodium (Ill)) into metal nanoparticles at room temperature within 120 min. When targeting the leachates from printed circuit boards, the Shewanella bacteria were able to allow selective reduction and deposition of gold (III) ions under acidic conditions in the presence of heavy metal ions, proposing a new bio-recovery system for gold. We also found that the Shewanella bacteria can separate and concentrate soluble rare metal ions (dysprosium (III), indium (Ill), and gallium (Ill)) from dilute solutions. Using this biomass adsorbent, the effectiveness of system for the novel recovery of indium from the leachate of used LCD (liquid crystal display) panels has been demonstrated.IntroductionMany high-tech manufacturing industries are highly dependent upon the use of critical raw materials that are the rare metals (e.g. rare earth elements/indium) and precious metals (e.g. gold/platinum group metals). There are now serious global concerns over the short term and long term availability of critical raw materials for high-tech manufacturing. This highlights the paramount importance of sustainable component reuse and material recycling technologies for recovery of critical raw materials. We believe that the most important domestic source of precious metals is through more recycling, and this will require more research and further development for the recycling of precious and rare metals. In general, chemical/thermal recycling is deemed to be the most appropriate means to extract the precious and rare metals from postconsumer products. However, there are issues related to the heavy use of toxic and hazardous chemicals, and the release of toxic emissions.Biological recovery methods provide an attractive alternative strategy and use microorganisms to separate and concentrate soluble precious and rare metals from dilute solutions into microbial cells via biosorption [1-3] and biomineralization [ 4, 5]. Biological systems generally operate at ambient temperature and near-neutral pH. Consequently, microbial recovery of metals would be an environmentally friendly method for recycling precious and rare metals from end-of-use products."

Jan 1, 2014

By D. Chakravarty, B. Samanta, D. Ghosh

Autonomous robots are useful for 3D underground mine mapping to avoid human exposure to hazardous spaces. To prepare a precise mine map, a self-navigating robot must navigate an arduous path, avoiding obstacles and sensing the environment. A prototype laboratory-scale robot was built and evaluated through a mock-up in a test mine gallery. It was outfitted with a 2D laser scanner, a stereo camera for obstacle avoidance, and a high-precision, laser-based imaging and digitizing system for collecting 3D point cloud data. Various algorithms were used for scan matching to facilitate simultaneous localization of the robot for mapping.

Jan 1, 2014

By N. R. Thote, J. L. Porathur, C. P. Verma

Highwall mining is a highly mechanized coal mining method associated with several advantages, such as a very high production rate (approximately 3,000 t/d) and low production costs. There is no requirement for underground support, ventilation, or blasting. Production leads to added recovery, which is otherwise lost in the ultimate pit. The use of highwall mining can bridge the gap that exists between supply and demand in the energy sector. This paper presents a brief review of highwall mining technology, including current status, analysis tools, and design techniques. In addition, it identifies important parameters from the analysis of failure case studies.

Jan 1, 2014

By C. V. Deutsch, O. Babak, J. G. Manchuk

High levels of geological heterogeneity occurring over relatively short distances pose a challenge to the unconventional open-pit techniques used in oil sands mining. There is strong motivation to mine selectively and minimize dilution and loss; however, the large equipment and high mining rate used to meet production targets tend to reduce selectivity. A numerical model is developed to account for geological complexity, mining equipment, regulatory criteria, and other operational parameters. This framework is used for more accurate forecasts, optimization of equipment, and other operational decisions. An example demonstrates the approach in light of Alberta Energy Regulator criteria.

Jan 1, 2014

By A. Rodriguez-Prado, P. Kuschk, R. L. Legge, W. C. Lennox

Using constructed wetlands to chemically reduce hexavalent chromium Cr(VI) to Cr(III) from industrial and mining wastewater has proven to be feasible and efficient. Applying first-order kinetics to describe the process is simple, but in some cases a more accurate model is required to reflect the process. This paper studies the feasibility of using non–first-order kinetics to describe the reduction process. Results indicate that half- and second-order kinetics adequately described Cr(VI) reduction in laboratory wetland mesocosms. The organic carbon content played a relevant role, whether it was built up by plant growth or spiked into the feed water.

Jan 1, 2014

By Chonghe Li, Xionggang Lu, Wei Xiao, Xingli Zou, Weizhong Ding

The reduction degree and rate of the initial ilmenite concentrate and pre-oxidation samples by hydrogen were investigated by using thermogravimetric analysis system. H2-TPR was used to detected reduction properties of the pre-oxidation products which were oxidized at different temperatures. The phase transformations and micromorphology changes during pre-oxidation and hydrogen reduction were identified by XRD and SEM. The FeTiO3 was decomposed into TiO2 and Fe2O3 at the temperature below 900 oC. With the temperature rising, Fe2TiO5 was the only stable phase in high temperatures. The reduction of pre-oxidation ilmenite concentrate was faster than the natural sample, which was attributed to the micropores generated on the surface of ilmenite concentrate during oxidation. The main phases of the reduction product were metallic iron, ferrous pseuodbrookite.

Jan 1, 2014

By Ramana. G. Reddy, Haoxing Yang

The electrodeposition of zinc from zinc oxide using urea and choline chloride mixture in a molar ratio 2:1 is investigated in different experimental variables, namely, the concentration of added [BMIM]HSO4, temperature, and applied cell voltage. The additive, [BMIM]HSO4, was determined to have beneficial effect on the current efficiency, energy consumed in the process and surface morphology of the deposits. The highest current efficiency (92.6%) and lowest energy consumption (2.92kWh/kg) was obtained for solution with 20mg/mL [BMIM]HSO4. The morphology showed the formation of absorbed additive layer on the cathode at higher concentration of additives. Experiments were conducted at different temperatures between 343K and 388K and at various applied cell voltages between 2.7V to 3.6V to determine the best experimental conditions. By varying temperature, highest current efficiency (91.3%) and lowest energy consumption (2.69 kWh/kg) was obtained at 373K. The electrodeposition process is enhanced between the applied voltage 3.0-3.3V by achieving lower energy consumption (2.75~3.06kWh/kg) and higher current efficiency (88.4~89.7%). SEM images showed grain size is significantly increased in higher applied voltages. While at higher temperatures, it seemed to generate particle growth as clusters at the outer deposit layer.

Jan 1, 2014