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By Norman O. Lotter, Virginia Lawson, Mika Muinonen, Dominic Fragomeni, Jorge F. Oliveira

Development of metallurgical flowsheets from drill core to production of finished metal involves two main domains: process mineralogy to sample the ore and develop a successful flowsheet producing saleable concentrate; and extractive metallurgy to convert that saleable concentrate to finished metal. Effective flowsheet development for a new or brown-field concentrator and processing facility is essential to project schedule and return on investment. Over the last decade in particular, the integration of geology, mineralogy, sampling, and mineral processing have empowered the development of an improved practice in flowsheet development. The use of geometallurgical units as a basis for best-practice sampling delivers representative study material to the laboratory. Modern automated mineralogy characterises the whole rock assembly and paymetal mineral hosting, to address downstream process implications. Batch scale flotation testing then uses this information to design and perform well-focused strategies. At early stages of the project, the Extractive Metallurgy team is engaged to determine processing constraints or other economic drivers in conversion of the saleable concentrate into finished metal. The team evaluates available technologies, assesses the impurities and key properties of the given concentrate. In many cases, changes to mineral processing flowsheet are required to maximize value per tonne of concentrate. Site conditions, availability of infrastructure, energy and power all play an important role. Modern metallurgical simulation tools such as FactSage™ and METSIM™ can quickly define the appropriate test program for each process. Bench scale testing and appropriate scale of piloting can confirm simulations and provide design criteria. A case study demonstrates how effective use of these tools and a multidisciplinary team can accelerate flowsheet development, while reducing costs and ensuring that the designed processing facilities maximize project value with minimum risk.

Jan 1, 2014

Cokriging uses a sparsely sampled, but accurate and precise primary dataset, together with a more abundant secondary data-set, for example grades in a polymetallic orebody, containing both error and bias, to provide improved results compared to estimation with the primary data alone, as well as filtering the error and mitigating the effects of conditional bias. The method described here may also be applied in polymetallic orebodies and in other cases where the primary and secondary data could be collocated, and one of the data-sets need not be biased, unreliable, etc. An artificially created reference data-set of 512 lognormally distributed precious metal grades sampled at 25×25 m intervals constitutes the primary data-set. A secondary data-set on a 10×10 m grid comprising 3200 samples drawn from the reference data-set includes 30 per cent error and 1.5 multiplicative bias on each measurement. The primary and secondary non-collocated data-sets are statistically described and compared to the reference data-set. Variograms based on the primary data-set are modelled and used in the kriging of 10×10 m blocks using the 25×25 m and 50×50 m data grids for comparison against the results of the cokriged estimation. A linear model of coregionalization (LMC) is established using the primary and secondary data-sets and cokriging using both data-sets is shown to be a significant improvement over kriging with the primary data-set alone. The effects of the error and bias are filtered and removed during the cokriging estimation procedure. Thus cokriging using the more abundant secondary data, even though it contains error and bias, significantly improves the estimation of recoverable reserves.

Jan 1, 2014

By S. McCarthy, K. E. Waters, A. Jordens

The beneficiation of rare earth (RE) element bearing minerals has become an active area of research as applications for these elements grow while the supply to non-Chinese consumers is restricted by export quotas. One of the most interesting beneficiation techniques for RE minerals is froth flotation as their unique chemistry suggests that collectors with a specific affinity for RE cations should be able to selectively recover these minerals. Existing literature, focusing mainly on bastnäsite flotation, identifies hydroxamic acids as excellent collectors for RE minerals. The high stability of hydroxamate-RE cation complexes is the explanation most often offered for the observed selectivity of these reagents in bastnäsite flotation however some research has also suggested that mineral solubility plays a crucial role in the success of hydroxamic acid flotation of RE minerals. This work investigates the interaction of allanite, a relatively insoluble RE-silicate mineral, with benzohydroxamic acid using zeta potential measurements and microflotation. The effects of Fe(III) and Fe(II) ions as potential activating ions (cations that form stable hydroxamate complexes) on benzohydroxamic adsorption to the allanite surface are investigated as a potential solution to promote hydroxamic acid adsorption. The results indicate that the optimum conditions for separation of allanite from quartz occur at pH 4 using FeCl2 as an activator for benzohydroxamic acid adsorption.

Jan 1, 2014

By H. Powell

"This paper discusses how elemental analysis of conveyed bulk flows in real time using PGNAA (Prompt Gamma Neutron Activation Analysis) technology has resulted in significant improvements in advancing plant control in mineral processing operations. PGNAA through belt, full stream, continuous, multi-elemental, real time analysis technology is explained. Capabilities and limitations in plant operating environments are discussed including comparison with other real time, on-line technologies through review of published information available for on-conveyor minerals applications. Case studies include an iron ore and copper-gold company, both of which consider the technology an essential component in advanced plant control necessary in new process flow sheet designs, rather than an optimisation tool.INTRODUCTION Process operators rely on supply of a reasonable ore quality and consistency from the mine. Unfortunately neither the mining nor process operators have much control over the ore quality once it has been put into the crusher. Grade control typically stops once the material is designated as ore and the process plant operator needs to process it irrespective of quality. Plant control is most effective when technologies measure process streams directly and preferably in real time. Measuring sampling streams that are not representative of the primary flow will result in incorrect plant control decisions. Sampling coarse conveyed flows is expensive and impractical at many operations, however, this does not mean those flows cannot be measured. Investigations to find techniques suitable for real time elemental analysis have focussed on the application of known laboratory techniques to process streams. For conveyed applications, development of neutron irradiation techniques were most promising and early studies indicated potential success for bauxite measurement (Beurton et al, 1995). Tran & Evans (2001) concluded there was no equivalent technology to PGNAA in terms of material penetration power and that the technology was eminently suitable for basic industries such as cement. Nelson and Riddle (2003) evaluated PGNAA for possible use in the phosphate industry by using a unit installed in a cement plant to test performance on phosphate samples and ultimately recommended its use for further characterisation of the mine’s various ore types to improve stockpile allocation and grade control"

Jan 1, 2014

By A. N. Zagorodnyaya

The results of research on recovery of ammonium perrhenate from by-products of lead production are presented in the article. For the first time in the world, rhenium marketable products were produced on lead plant of Kazakhstan. Distribution of rhenium in lead production has been studied. During oxidative agglomeration of lead charge, 67.43% rhenium is sublimated and at that, 67.27% rhenium is trapped by the dusts of a system of gas purification, out of them 6.21% is transferred into different solutions, 1.89% into slime and only 0.09% into exhaust. During agglomerate smelting, up to 72% of its rhenium is sublimated and condensed in the dusts also. At leaching stage of sulphate product under dusts processing by the method of sulphatization, 15% of its content in the dusts is transferred into solution. The sorption method on the ionite ?N-21 has been proposed for recovery of rhenium from the solutions of sulphatization. At the same time, rhenium recovery from the dusts into commodity was 13%. The method of direct hydrometallurgy - leaching the dusts by solutions of sulphuric acid under presence of manganous concentrates, has been proposed as alternative method of recovery. This method has allowed increasing recovery of rhenium and other metals from the dusts into solution up to 90%~95%. Rhenium solvent extraction by ??? has been proposed for recovery of rhenium from the leaching solutions. At that, extraction of rhenium into marketable product from the dusts is above 75%.

Jan 1, 2014

By M. Saghaeian, R. Hejazi, L. Hosseini

The specific surface area (Blain value) of iron ore concentrate entering the pelletizing plant is one of the characteristics most effective on the overall performance of the plant such as producing harder pellets, decreasing additives consumption, and decreasing energy consumption. Therefore, preparing the feed entering pelletizing plant is required. The iron concentrate entering Ardakan pelletizing plant located in Yazd province, Iran bears relatively low Blain value (approx. 1600 cm2/g) which necessitates one stage of regrinding so as to increase the Blain value to more than 1800 cm2/g. Studies were conducted and results showed that HPGR is the best regrinding equipment for increasing specific surface area. Conducting pilot plant tests on the concentrate sample revealed that specific throughput is 181 to 263 ts/hm3 and specific energy consumption is 1.6kWh to 2.2 kWh. Pilot tests also showed that one stage of grinding results in 407 cm2/g to 553 cm2/g increase in specific surface area. Based on these results, diameter of rolls, length of rolls, power consumption and grinding force were calculated to be 1.3 m, 0.9 m, 1276 kW and 13800 kN, respectively. Therefore, an HPGR with a roll diameter of 1.52 m, roll width of 1.1 m, power of 1660 kWh and a capacity of 500 t/h has been selected and implemented in Ardakan pelletizing plant. Industrial performance of HPGR and its effects on the plant study results show that limestone and bentonite consumption has reduced about 60% and 30%, respectively. Total Fe of the final pellet has increased from 65.5-65.7% to 66.2%. Cold compressive strength (CCS) and porosity of final pellets are approximately 292 kg/pl and 20.4, which are in the acceptable range.

Jan 1, 2014

By M. S. Eygi

This study covers the investigations based on the electrokinetic and rheological properties to explain the interactions between kaolin minerals and commercially available polyelectrolyte in anionic character. Additional adsorption test were also conducted to support the interaction mechanism. Adsorption tests showed that adsorption densities decrease by increasing the solid content. In-creasing the solids contents from 1% to 30% by weight resulted in the decrease on adsorption from 2.14 mg/g to 1.85 mg/g. Because of its difficulty, the solids ratio at 70% was not studied. However, following to trend of the curve plotted adsorption density-solid ratio, an estimation was made and adsorption density at 70% solid content was extracted from the curve as 1.75~1.80 mg/g. The electrokinetic studies pointed out that the presence of polyelectrolyte increase the zeta potential of kaolin from 40 mV to 60 mV which is reasonable conditions to disperse and stabilize the kaolin slurry and lower the viscosity. When these result of the different tests are combined and considered together, 2 mg/g polyelectrolyte concentration was noted as optimal concentration where adsorption density, viscosity and zeta potential of the slurries give maxima and remain constant after this concentration.

Jan 1, 2014

By ChuanJie Cai, Zemin Zhuang, Jing Chen, Xuebin Hao, Shaobo Zheng

"Carbon which was used as heating and reducing agent in traditional iron and steel making process at present brought us large amounts of greenhouse gas harmful gases and dust seriously leading to the fog and haze condition. As one of ideal global new energies, Hydrogen has good features such as rich resource, high heat efficiency, cleanness, renewable and transportation. With the commercialization of hydrogen energy, the world energy structure will be changed greatly. Although many scholars have done a lot of researches and long-term exploration on hydrogen metallurgy, researches on the formation of metal iron phase in the process of hydrogen reduction of iron oxides in slag was rarely reported, which had important theoretical significance on the development of hydrogen smelting reduction process. Based on the thermodynamics and kinetics calculation, A laboratory experiment has been designed to research the iron phase formation during hydrogen reduction of iron oxides in the molten slag in this paper. SEM and EDS techniques were also used to observe and analyze the iron morphology. According to detection results, the influence of temperature, reaction time and surface tension on the morphology of the iron phase reduced were showed.IntroductionWith the increasingly severe global warming greenhouse effect, governments are paying more attention to no-carbon and low-carbon energy development and utilization. Hydrogen has received widespread attention around the world, which has rich resources, high thermal efficiency, large energy density, use clean, transportation, storage, renewable etc [1].The development of the hydrogen economy is new competition areas of the world economy for the 21st century. China should assess the situation, and achieve the important strategy of peaceful development as the realization of new industrialization, by establishing a ""hydrogen economy"" industry revolution which replaces fossil energy. The current hydrogen metallurgy process includes hydrogen direct reduction, smelting reduction and direct steelmaking process. Hydrogen plasma hydrogen metallurgy is the use of hydrogen as a reducing agent to replace carbon reductant, to reduce carbon dioxide emissions, and to ensure the sustainable development of ironmaking industry."

Jan 1, 2014

By N. L. Ayres

Tendon support systems have been successfully used to stabilize excavations. Tendon support systems are routinely designed using the axial load-bearing capacity of tendons, namely the tensile strength. To attain tensile strength the tendon must be loaded along its length, which often does not occur in practice. Tendons should optimally be installed at 90° to the surface of the excavation to achieve maximum penetration depth, yet this is often not physically or practically possible, and installations at angles less than 90° occur. Furthermore, the intersection of geological features within the rock mass frequently results in complex loading situations on tendons. The position and angle at which loading occurs results in different combinations of tensile and shear forces acting on the tendon, which can impact on the support performance of each unit and ultimately the whole system. All factors that influence the support system should be understood and taken into account to ensure a sound support design. Combination loading situations are further investigated and tested to obtain a better understanding of the mechanisms involved and the effects on tendon load-bearing capacity. Tendon support units were tested at different installation angles to establish the tendon performance, mechanical behaviour, and load capacity during these loading situations. The results and outcomes are aimed at providing rock engineers with additional data and improved understanding of how tendons could perform under certain conditions.

Jan 1, 2014

By S. Klingmann

ABSTRACT In this paper, we used data collected from the Gibraltar mine to analyze the effect of the TyreSense tire monitoring system on tire performance by reducing tire wear and preventing premature tire failure or damage. We analyzed the relationship between tire temperature, tire pressure, and tire failure or damage to help better understand the importance of controlling high tire temperature and pressure. The results enhance and expand the knowledge of the management of tire operational pressure and temperature.

Jan 1, 2014

By Hamid-Reza Manouchehri, Hassna Aitahmed-Ali, Stellan Sundberg

"In flotation practices as the particle size becomes fine, e.g., p<20µm, the process efficiency declines markedly. When flotation of fine particles is necessary, one method to improve the recovery is selective agglomeration of fines. Different agglomerating methods have been introduced and tested; however, one method which has recently received great attention is to aggregate fine particles by magnetic force. A selective aggregation of the fine paramagnetic particles, e.g., sulfide minerals, can be achieved by applying a high intensity magnetic field during flotation conditioning. The method is simple, selective and effective for fines, and has a low operation cost. However, a minimum magnetic susceptibility of fine grains is required for this process. This method has been demonstrated in different sulfide minerals flotation plants. The implementation of the magnetic conditioning device, ProFlote, in both the Cu-Pb and the Zn circuit of Boliden’s Garpenberg plant in Sweden, where a complex massive sulfide ore is treated, is discussed herein. The preliminary results have shown an increase in the recovery of value minerals, in particular Zn and Ag and considerable reduction in Zn deportment to the final tail. Increases in Cu grade and decreases in Pb grade in Cu-con have been achieved as well."

Jan 1, 2014

By R. Shiva Kumar, G. Sreedhar, S. Sharma

Some of the Indian origin iron ore deposits located in Bellary, Karnataka province are having peculiar characteristics of Iron ore deposits (Hematite) having Iron above 64% and 30-40% lump (-30+6mm) recovery which are not suitable to use in blast furnace due to not meeting the specification of Tumbler Index and Abrasion Index. In general for high grade Iron ores, process flow sheet involves crushing and screening (dry/wet). In the contest of high grade Iron ores located at Bellary sector of Karnataka state in India, lump generated from this process could not attain the required physical properties (Tumbler Index, Abrasion Index) and metallurgical properties , even though the grade of the lump ore is above 64% Fe. Washing techniques like Drum scrubber and Log washer play major role in improving the metallurgical properties of Iron ore lumps by removing the light and hard layers of clay, silica coated over the lumps. In this study the effects were compared of drum scrubbing and log washing on iron ore lumps. It is found that by incorporating simple washing technique i.e. drum scrubbing or log washing, Tumbler Index of Iron ore Lumps could be increased from 74% to 78% which is acceptable for use in Blast furnace. From the Drum scrubber and Log washer tests, it is clear that Log washers have an edge over Drum scrubber in removing hard coated clay on surface of Lumps. This simple washing technique facilitate us to utilize the lumps directly in blast furnace and eliminate the unnecessary crushing and grinding of the ore so as to meet the specifications of Sinter fines and pellet feed.

Jan 1, 2014

By Charles Zdazinsky

Back-break induced from blasting is a concern in open pit metal mining because it compromises the conditions of the pit’s final walls. Final walls that have excessive blast induced damage commonly require extra attention and can often lead to increased cycle times. Most importantly however, the safety conditions of a back-broken region can be significantly compromised and it must be addressed to prevent injury and/or damage to equipment. This occasionally results in the necessity to alter mine plans to prevent an incident from occurring in a back-broken region which can be costly to the mine.

Jan 1, 2014

By Érica Linhares, Anderson Silveira Lopes, Aline Costa

In the production units of ferromanganese alloys wastewater are generated. They mainly arise from gutters of drainage water from warehouse of raw material (manganese ore, reducing agents and other), product and slag. This wastewater, in general, may contain particles that will suffer difficulty to naturally decant, giving the water turbidity and color characteristics. Thus, this study aims to characterize the effluent, the treated water and the sludge from the sedimentation tank from the one main Brazilian plant. The investigated characteristics were: turbidity, total solids (TS), suspended solids (SS), dissolved solids (DS), pH, Eh, COD (chemical oxygen demand), residue classification and chemical analysis by ICP - OES. The turbidity before treatment was 417 NTU and after passing through the tank, 44 NTU, a figure slightly higher than the emission standards for Class 1 regulated by the Brazilian environmental legislation in force. The values for TS, SS and DS of the effluent were 225, 114.3 and 110 mg/L, respectively. For the treated water the values were 93, 48.3 and 45 mg/L for TS, SS and DS, respectively. The sedimentation process was able to reduce by 21 % of the COD. In the test of loss on ignition (LOI) from the tank bottom sludge were observed losses of 29.35 %, while the volatile analysis found 20.70 % of volatiles in the sample. It was determined that the concentrations of Al, Fe, Mn and S are, respectively, 0.1875 mg.L-1, 0.3071 mg.L-1, 0,789 mg l-1 and 0.00828 mg.L-1, values above the maximum allowed by law. Based on the analysis of X-ray diffraction, the identified minerals in the sludge were quartz, muscovite, kaolinite, calcite and albite.

Jan 1, 2014

By L. Xia, B. Hart, K. Douglas

In the flotation of Rare Earth Element (REE) bearing minerals, oxalic acid is reportedly acting both as a depressant and pH modifier. Testing has established the significance of oxalic acid in the flotation process however its specific role in either the recovery or selectivity of REE over their gangue minerals is not well understood. Pulp pH reduction trials with alternative acids have not shown the same effect on the REE mineral recovery or the depression of gangue phases. This work examines the effect of oxalic acid on the surface of gangue minerals (quartz and carbonates (dolomite and calcite)) in a series of conditioning tests. Gangue surface analyses by TOF-SIMS indicate that oxalic acid inhibits the transfer of secondary ions generated during the conditioning process from one mineral phase to another. In this regard, the oxalate anion acts to fix ions in solution through chelation, limiting their participation in surface adsorption.

Jan 1, 2014

By Gabsoo Kim, Rulin Yang, Dave Kay

Blast vibration data, such as PPV are usually scattered. In many cases, plots of PPV versus the charge weight scaled distance are so scattered that useful trends from different blast designs cannot be identified. The scattering of the data may be attributed to the inaccuracy of the PPV measurement, the definition of the scaled distance from a multiple-hole production blast, and the measurement of distances and charge weights. The error from vibration measurements is one of the major contributors to the scattering of the plots. If accurate monitoring is conducted, improved design options may be identified. This paper documents two case examples that compare different vibration sensor couplings. The first case shows mounting accelerometers at spots that protrude from the ground, compared with the sensors that were mounted on a flat ground surface. The second case compares data from loose-sand buried geophone with that from sensors coupled to the ground using concrete blocks.

Jan 1, 2014

By Cathy Aimone-Martin, Kristin Dunlap Kolden

Blasting was conducted for the Army Corps of Engineers (Corps) in the Columbia River near Saint Helens, Oregon during 2009 and 2010 to deepen the navigation channel as a final phase of a dredging project to accommodate larger container ships. The Columbia River Channel Improvement Project (CRCI) required 4 months to blast and dredge 300,000 yd3 (229,366 m3) of basalt from the bottom of the channel to allow Post-Panamax vessels with drafts up to 50 ft (15.2 m) access to the Ports along the River. Explosives charges were limited to 90 lbs (40.8 kg) per delay for the protection of fish and marine life in the area. A fish mortality study and marine mammal monitoring program was also required by the Corps. Underwater overpressure monitoring was required for each blast and peak overpressures measured 10 ft (3.1 m) above the river bottom 140 ft (42.7 m) from the closest blast hole were not to exceed 70 psi (483 kPa) with a cautionary level of 40 psi (276 kPa). Specifications required sampling rates of 500k S/s and PCB Peizotronics tourmaline pressure sensors. The Corps granted permission to co-locate additional ceramic-type sensors at different sampling rates to design redundant monitoring systems 140 and 300 ft (42.7 and 91.4 m) from blasting and develop a site-specific overpressure attenuation model for the project. This paper presents the correlations of overpressure with cube-root scaled distance factors, a comparison of measurements using three different pressure sensor systems, and a discussion of blast design influence on overpressure measurements.

Jan 1, 2014

By Kari Niiranen, Andreas Fredriksson

LKAB (Luossavaara-Kiirunavaara AB) is operating iron ore mines, concentration plants and pelletizing plants in Northern Sweden. Geometallurgy, which combines geological and metallurgical information is not a new way of thinking at LKAB, but rather a revised and updated version of an old working process. A project called "Silica in the Mine" which started in 2007, was an important reason to set a new focus at the geometallurgy. The target of the project was to develop a simplified method in laboratory scale to predict SiO2 grade in the magnetite concentrate in Kiruna and further predict the physical properties of the crude ore with respect to processing characteristics. The connection between mineralogy and products properties have started to be even more vital and necessary to examine due to the future exploiting new iron ore deposits. Geometallurgy at LKAB can be described as a mental and strategic framework where the Research and Development department (R&D), and others within the organization of LKAB, aims towards the connection of the minerals-production-products. It could in its basics be called "research & development", but it must be clarified that changes have been made, mainly due to the development on the instrumental analysis side. LKAB’s idea is to work quite broad, with internal educations, an active working process in ongoing projects, together with external parties (such as universities), with several PhD-projects and an upgrading on the instrumental side at the LKAB Research & Development department. This paper is a summary about the concept Geometallurgy at LKAB and some of the actions within its framework.

Jan 1, 2014

By X. Cao, B. S. Naik, D. L. Chen, P. Wanjara

AZ31B-H24 Mg alloy sheets with a thickness of 2 mm were friction stir lap welded (FSLWed) at two tool rotational rates of 1000 and 1500 rpm and two welding speeds of 10 and 20 mm/s. The tensile behavior of the FSLWed AZ31B-H24 Mg alloy was then evaluated at low (-40°C), room (25°C), and high (180°C) temperatures. It was observed that the failure load increased with decreasing tool rotational rate and increasing welding speed. The maximum failure load occurred at a tool rotational speed of 1000 rpm and a welding speed of 20 mm/s at all temperatures tested. It was also noticed that at the high test temperature, the samples failed along the sheet interface, i.e. shear fracture. At the low and room temperatures, the samples failed on the advancing side (AS) of the top sheet near the interface between thermo-mechanically affected zone (TMAZ) and stir zone (SZ). The different modes of fracture observed are associated with the hooking defect.

Jan 1, 2014

By Markus Dammers, Christopher Robben, Hermann Wotruba, Christian Schropp

"In most underground mining processes the entire extracted ore is transported from underground workings to surface processing plants for separation of valuable minerals and gangue material. Most of the transported material consists of barren rock with negligible metal content, especially for low grade deposits, such as in the copper or gold metal ore mining. Increasing mining depths result in higher costs for transportation and hoisting. Therefore, rejecting waste rock as soon as possible from the material stream gains importance. The concept of resource to product integration in the form of earliest waste rejection in combination with subsequent backfilling follows the philosophy of ‚leaving waste underground?. Implementing mineral processing underground can lead to less required mass movement to surface, hence reducing transportation and hoisting costs. At the same time, rejected waste can be used as backfill to increase extraction rates by reducing pillar volumes. In the mill, a stable high grade feed leads to decreased specific operating and investment costs as well as increased productivity and recovery. These effects as a whole have a large potential to reduce cut-off grades so that resources can be turned into reserves. Within the I²Mine (Innovative Technologies and Concepts for the Intelligent Deep Mine of the Future) project of the European FP7, investigations are carried out by the Unit of Mineral Processing of RWTH Aachen University, the Institute of Mining Engineering I and TOMRA Sorting Solutions | Mining. One aim of the cooperation is to develop new concepts for a comprehensive integration of near-to-face processing in combination with backfill into the overall underground mining process. Effects on up-, down- and side-streams are investigated to prove the potential of resource to product integration in comparison to common underground mining systems and processing methods."

Jan 1, 2014