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By B. H. Zhao

A low grade Pt-Pd ores, with 1g/t Pt and 0.13g/t Pd, and 8.70% Fe and 2.50% P2O5 is experimented to recover of Pt and Pd. The flowsheet is proposed which consists of Pt-Pd selective flotation, apatite flotation from tailings of Pt-Pd flotation, magnetic separation of magnetite from apatite flotation tailing. With butyl xanthate, N-ally group-O-isobuturyl-thioanimoformate and Sodium y-89 xanthate as collectors, sodium silicate as depressant, and sodium carbonate as pH regulator, a concentrate, assaying 324.52 g/t Pt and 45.62 g/t Pd, is obtained with recoveries of 87.23% Pt and 76.89% Pd from surface ore. A concentrate, assaying 1693.53 g/t Pt and 64.12 g/t Pd, is obtained with recoveries of 88.54% Pt and 83.78% Pd from primary ore. At same time, A iron concentrate assaying 64.12% Fe with a recovery of 24.94%, and a apatite concentrate assying 30.32% P2O5 with a recovery of 80.12% are obtained.

Jan 1, 2014

By G. Y. Zhou

During Zijinshan copper heap bioleaching, pyrite was leached in plenty resulting in high ferric concentration in solution. It has affected bioleaching and extraction processing greatly. It results much acid and iron in solution and bad effect to extraction processing. The paper studied the influence factors in the course of pyrite leaching and ferric ion chemical oxidation, especially studied the redox potential for copper bioleaching so as to find key factors affecting the dissolution difference between chalcocite and pyrite. The results show that the redox potential is important factor. Copper and pyrite leaching rates are 95% and 11% respectively and there is great dissolution difference between them at redox potential 700 mV (SHE). During pyrite bioleaching, the indirect action of bacteria gives priority to bioleaching cooperating with the direct attack of microbial cells attached to the mineral surface. Redox potential is determined by ratio of ferric and ferrous, ferric in solution was supplied by the way of oxidation of T. f bacteria, sufficient bacteria concentration and active character were two vial factors of controlling redox potential. It is indicated that copper can be selectively bioleached during copper bioleaching by controlling redox potential of bioleaching. The conclusion will provide theoretic foundation on balance of acid and iron during bioleaching for copper of higher S/Cu ratio. The experinment proved that bacteria activation was decreased on condition of both low pH value and intermittent aeratation during bioleaching. It resulted that the oxidation velocity of ferrous ion was decreased and redox potential was controlled. The dissolution of pyrite was depressed. It would be possible to actualize selective leaching of secondary sulfide copper ore during bioleaching process.

Jan 1, 2014

By Gülay Bulut, Ünzile Yenial

"Water composition has a significant effect on flotation. A better understand the role of water composition in flotation is very important for process quality and performance. Based on source of process water, the concentrations of the dissolved ions, hardness, contaminants and residual composition of reagents can varied in the process water. The various water resources employed during lead and zinc flotation caused activation, depression or selectivity effects on minerals due to the presence of different ions in solution. Metal ions in these water resources were adsorbed on the ore, whilst ions associated with gangue minerals were released into the flotation pulp.This paper includes a research for the effect of different water compositions on lead and zinc sulphide flotation. Experiments were carried out five types of water such as tap water, recycling water, tailing dam water, underground mine water and sea water. The ore sample was obtained from Esan Balikesir-Balya mine. The mineralogical study of ore sample shows that it contains mainly galena, sphalerite, pyrite, hematite, quartz, diopside, epidote, calcite, and chlorite. It is found that recycling water and tailing dam water has a positive effect on recovery of lead and zinc minerals and detrimental effect on content of both minerals. This result may explain with remaining reagents in these waters. Underground mine water and tap water gave nearly the same recoveries of zinc. Sea water affects the recovery lead and zinc negatively."

Jan 1, 2014

By Z. Halifa, P. G. Geyer

Tapping a blast furnace is necessary not only to deliver the product, but is also essential for the safety of the furnace and workers in the cast-house. This paper will highlight the practices at ArcelorMittal’s blast furnaces in the Vanderbijlpark Works, with specific focus on tap-hole design and monitoring as well as casting practice. Extension of the tap-hole life and hearth campaign will be illustrated with reference to the methods of maintenance of the tap-holes, troughs, runners, and cast-house equipment. The importance of proper cooling, good thermocouple installation, and temperature monitoring will be explained.

Jan 1, 2014

By Wei Sun, Xue-feng Cao, Lei Sun, Run-qing Liu

The flotation performance of kaolinite in laboratory micro-flotation was investigated with 3- (dodecyloxy) propan-1-amine (ON12) as the collector. Compared with dode cylamine (DDA), which is commonly used as the bauxite reverse flotation collector, ON12 shows stronger collecting ability for kaolinite than using the same amounts of DDA, when experimental pH value reaches more than 6. With the addition of ON12, the isoelectric point of kaolinite shifts to 6.1 from 3.6, which suggests a strong adsorption between kaolinite and ON12. Infrared spectra analysis indicates that the type of ON12 adsorbed on the kaolinite surface is mainly of electrostatic adsorption. Molecular dynamics simulation further indicate that electrostatic adsorption of ON12 cation on kaolinite (001) surface based on electrostatic interaction between NH4+ and O atoms. ON12 will be suitable for bauxite reverse flotation with the efficiency depressors of the diaspora.

Jan 1, 2014

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014

By Diana Drinkwater, Tim Napier-Munn

"This paper argues that, although specialist mineral engineering expertise is essential for the efficient design and operation of mineral processing plants, the environment in which these skills are supplied to the industry has changed forever, and not for the better. Most of the mineral engineering programmes in western universities have died or are dying. The long-service mine site mentors have gone, operations are run on a staffing shoestring so that there is no longer the time (or inclination) for considered decision-making, and the FIFO model has discouraged continuity of optimisation projects and communication between professionals. At the same time the technical challenges of designing and operating effective process plants are increasing. These trends are not going to be reversed any time soon, if ever. The ability to run efficient mineral processing operations has been materially compromised as a consequence. We propose that well-designed professional development can help to recover this situation, and it can be done easily and cheaply. The workplace is the best environment for such skills development. Professional development training should be integrated with normal duties throughout the early years of a graduate’s service (and probably beyond), and the cost should be regarded as non-discretionary expenditure for the business. If such programmes are properly resourced and managed and extended over longer time periods, there will be a measureable rise in the level of technical understanding and competence within companies and a resulting beneficial impact on resource utilisation and thus shareholder value. The paper outlines some of the approaches that we believe will work, and the benefits that we expect will accrue."

Jan 1, 2014

By D. B. Dreisinger, M. R. Tavakoli

Vanadium has been produced from a variety of sources. This metal is known to make aqueous solutions of complex speciation as a function of vanadium concentration and pH. Considering the method of leaching, the impurities in the PLS and the planned vanadium product, different extractants and flowsheets can be applied for solution purification. In this paper, purification of vanadium leaching solution using organophosphorus, solvating and amine extractants will be reviewed. This review will be focused on vanadium separation from iron, molybdenum and uranium which are often present in vanadium resources including primary ores, fly ashes and spent catalysts.

Jan 1, 2014

By Zach G. Agioutantis

The Illinois Basin has an extensive history with the use of mechanized longwall mining dating back to the early 1970?s. In recent times, technological advances have resulted in increased panel widths from 800 feet to over 1400 feet and daily panel advance rates have also increased significant l. The prediction and control of subsidence and surface deformation due to underground mining are important considerations in the permitting, planning, and monitoring of these coal mining operations. The prediction of mining-induced ground movements using the influence function method is a mature technology, well utilized in the Illinois basin, and widely used by researchers and planning engineers around the world. This paper utilizes subsidence data, recently measured in longwall operations in Illinois, to develop an updated ground movement prediction capability implemented by the Surface Deformation Prediction System (SDPS) software package.

Jan 1, 2014

By G. Unland

The sizing of crushers depends on the expected crushing forces. However, the crushing forces develop differently with every individual rock while it is compressed by the working surfaces of the crusher. For sizing, this compression process has to be characterized by the maximum crushing force. The maximum crushing force depends on the strength, shape and size of the rock, the amount and velocity of the imposed displacement of the working surfaces of the crusher on the rock and the conditions of the contact surfaces. From experience it is known that the strength of the material and, therefore, the crushing forces depend on the size of the specimen. This dependence is the so called size effect. The determination is based on compression tests. The force development is recorded during the compression of the specimen and for every individual test the maximum force is determined. The occurring maximum crushing forces of several rocks with the same diameter comminuted under the same conditions can be assessed by a mean value and a variance. The relationship between the mean values of the cross section related maximum crushing forces FAmax and the corresponding sizes d of the specimens can then be described by mathematical functions. They are derived from different approaches (phenomenological, statistical and statistical-physical methods). The phenomenological methods are subjective and yield functions depending on the assumptions of a person, whereas the statistical and statistical-physical methods are based on an evaluated function and the optimization of the parameters.

Jan 1, 2014

By I. Nolet

Matte tapping is one of the most critical operations of a matte smelter. Every smelter has developed particular matte tapping practices and tap-hole repair strategies that are often based on the experience of the smelter personnel. As a result, very little information has been published on these critical topics. This paper aims at providing the information gathered from a survey conducted in the PGM and Ni industries on matte tapping practices and tap-hole maintenance strategies for different PGM-Ni matte smelting operations.

Jan 1, 2014

By M. Bryson, S. Broom-Fendley, A. E. Brady, W. Dawes, G. Beer, N. Sehlotho, S. Al-Ali, F. Wall

The Songwe Hill Rare Earth Element (REE) Project in Malawi is a near surface carbonatite-hosted deposit with synchysite and apatite as the key REE bearing minerals. A strong focus has been placed on understanding the REE mineralogy of the Songwe Hill carbonatite as REE mineralogical characterization is a crucial component at all steps, ranging from exploration to production, in the development of REE deposits. Extensive mineralogical work has been completed at Camborne School of Mines (CSM), Natural History Museum (NHM) London, British Geological Survey (BGS), Nottingham, Aberystwyth University, Wales, Mintek, South Africa, and SGS Inc. Canada (SGS). The following analytical techniques were used: scanning electron microscopy (SEM), electron microprobe analysis (EMPA), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and QEMSCAN®. The detailed studies have demonstrated that while synchysite is light-REE enriched as expected, apatite, abundant in all stages of carbonatite emplacement at Songwe, is anomalously enriched in mid- to heavy-REE relative to apatite in other carbonatite deposits. The distribution of REE within synchysite and apatite at Songwe has had important implications for the direction of the metallurgical work with respect to the behaviour of light and heavy REE through the flotation and hydrometallurgical stages of the flow sheet.

Jan 1, 2014

By N. A. Jabit

The dissolution behaviour of ilmenite in acid solutions has been studied by many researchers to improve the leaching efficiency. Most studies which utilized natural ilmenite from different origins resulted in different reactivity due to the alteration caused by the weathering process. Previous researchers have suggested that the greater reactivity shown by some ilmenite samples towards sulphuric acid may be a result of the mineral being relatively unaltered. In the present study a rotating synthetic ilmenite disc of 2.2 cm diameter was subjected to leaching studies in hydrochloric acid. The dissolution rates of iron and titanium from synthetic ilmenite were determined in hydrochloric acid solutions (4 M to 9 M) over a temperature range of 50 to 80°C. Results show that the rate of dissolution of both iron and titanium increased with the increase in acid concentration. However, the rates decreased with time and obeyed a parabolic rate law indicating the blockage of the surface by an insoluble product. The rates of dissolution of both iron and titanium were higher in the presence of SnCl2 and remained unaffected with time indicating the reductive role of SnCl2 which inhibits the formation of surface blocking solids. Application to natural ilmenite is also discussed.

Jan 1, 2014

By Z. G. Guan

The tungsten ore in Xingluokeng belongs to a symbiotic deposit containing granite and fine vein-type wolframite and scheelite. The tungsten (WO3wolframite) accounts for only 0.233% of the raw ore, 49.60% of the , 49.60% of the scheelite and 0.8% of the tungstite. The dissemination size of the tungsten ore is extremely uneven, with 0.02~1.28 mm for scheelite and 0.01~1.28 mm for wolframite. The dissemination size of scheelite is coarser than that of wolframite. The size of 83% of scheelite and 60% of wolframite is greater than 0.04 mm. The composition of minerals in the ore is quite complex. The major metallic minerals include wolframite, scheelite and pyrite, which are followed by molybdenite, chalcopyrite, arsenopyrite, limonite, magnetite, hematite and siderite. The major gangue minerals include quartz, feldspar, muscovite, biotite and sericite, which are followed by chlorite, fluorite, apatite, dolomite, etc. According to the dissemination features and liberation degree of the tungsten minerals, the technology flowsheet of gravity concentration for coarse particles and flotation for fine particles to re-cover the low-grade and fine vein-type tungsten minerals is adopted, and -0.7 mm is selected as the processing size. The closed-circuit grinding procedure, with the combination of the rod mill and high-frequency vibration screen, is adopted. The grinding product is classified into three products of -0.7 +0.2 mm, -0.2 +0.04 mm and -0.04 mm. The gravity separation is adopted for the former two to recover tungsten minerals and the flotation is adopted for the last one. Under the condition that the raw ore contains 0.23% WO3, some technology indexes of beneficiation have been achieved. The gravity tungsten concentrate contains 63.54% WO3 with the recovery 70.11%. The slime flotation tungsten concentrate contains 35.22% WO3 with the recovery 10.48%. The composite tungsten concentrate contains 57.53% WO3 with the recovery 80.59%. Thus, the tungsten minerals are re-covered effectively.

Jan 1, 2014

By Guanghui Li

Nickel pig iron (NPI), used as a substitute for electrolytic nickel, is able to reduce the production cost of stainless steel greatly. Aiming for preparing NPI from nickeliferous laterite ore, a pilot-plant scale test of coal-based rotary kiln direct reduction of laterite ore was performed and reported in this study. In this process, the ground laterite sample (18.85% TFe and 1.52% Ni) mixed with additives, pulverized coal and binder was briquetted into briquettes with the size of 40mm×40mm×31mm, laterite ore briquettes and reducing coal were charged into a rotary kiln with the diameter of 1.6 m and the length of 16 m, for a retention period of 6~7 hours, in which reduction section temperature was ranging from 950~1050 oC. The reduced briquettes were water quenched, ball mill ground and beneficated via low intensity magnetic separation. A magnetic concentrate, Ferronickel powder, with 86.9% TFe and 8.0% Ni was obtained, and the corresponding magnetic recovery of iron and nickel are 75% and 96.3%, respectively.

Jan 1, 2014

By Yuanyuan Wang, Hong Li, Xueting Liu, Hao Bai, Kang Zhou

"Phase change materials are widely used in efficient utilization of energy and new energy technology. Especially, more attention has been paid to composite phase material, which is applied on architectural energy-saving and efficient working fluid. In this paper, stearic acid-silicon dioxide composite material was prepared by sol-gel process from tetraethyl orthosilicate (TEOS) and stearic acid (SA). The material was investigated by Field emission scanning electron microscopy (FE-SEM), Fourier transform infrared spectroscopy (FT-IR) and Differential scanning calorimeter (DSC). The FE-SEM results show that 3D-grids of silicon dioxide were formed clearly and SA was encapsulated in the silicon dioxide shell. The FT-IR results show that there were no chemical reactions between silicon dioxide and SA, which is the chemical property of the composite material, is stable. The DSC results show that the composite phase change material has favorable heat capacity. This material is expected to be used to make a cooling working fluid.1. IntroductionEnergy thermal storage becomes increasingly prominent issue in recent years, because thermal storage has been used in many aspects, for example, it can be added into building materials to improve heat conditioning. Another potential application of thermal storage materials is that the intermittent waste heat can be collected and recycled effectively by using the thermal storage facility. Thus, energy thermal storage plays a significant role in conserving available energy and improving its utilization [1]. Energy thermal storage includes sensible heat storage and latent heat storage. The latent heat storage has great heat density with a constant temperature during the phase change process [2-5]. Large quantities of latent heat storage will be absorbed and released when phase change takes place. Based on the former researches, some phase change material (PCM), such as fatty acid and paraffin waxes, has been proved to have high latent heat storage capacity and appropriate thermal properties [5-6]. However, using the PCM in energy storage systems directly is restricted, e.g. some properties of organic PCM, like form-stability and thermal conductivity, are not good enough to use. Meanwhile, almost all the inorganic PCMs are corrosive and most materials may cause sub cooling and segregation [7-9].The other problem is that the leakage when the temperature reaches the phase change point. Therefore, encapsulated composite phase change material (CPCM) emerged in order to solve the problem of leaking out, minimize the sub cooling and prevent phase segregation. [10-13] However, the easy flammability of fatty acid also has hindered the development of PCM. Accordingly, it has been found out that silicon compounds are environmentally friendly promising substitutes for halogen-containing flame retardants. Especially, silsesquioxanes are excellent in the flame retardancy. So CPCM can be encapsulated with SiO2 acting supporting material."

Jan 1, 2014

By Z. C. Zhen

Basing on character of fine ores, and employing all the advantage of dissolved-air flotation, the study within the dissertation put forth the methods of superfine metal mineral flotation with dissolved-air flotation equipment, and constructed a full set of laboratory flotation system. Experiments both in water and in slurry were respectively carried out by means of this flotation equipment. Further study was also fulfilled on mechanism of air-dissolved released devices, and the key components of system including ejector, releaser and saturator were designed. Optimizing devices parameters were chosen by taking ideal performance of the devices into consideration, according to orthogonal experiments and tests on bubbles factors, those performance factors were called air release rate, air release efficiency. The results with some minerals are better than JJF flotation machine with 30 litres bulk. The Dissolved-air Flotation(DAF) machine shows great potentiality in treating super-fine metal mineral concentration. The research indicates the Dissolved-air Flotation(DAF) system has superiority over mechanical flotation machine in fine flotation. Air-dissolved released bubbles appear on the surface of hydrophobic minerals in priority, solving collision probability less in the tradition fine mineral separation, such that the metallurgy technology of fine metallic minerals are improved. The exploratory research is a foundation for industrial pilot, commercial test and equipment maturity in the future.

Jan 1, 2014

By N. P. Mahumapelo

This paper is based on a study to determine the potential beneficiation opportunities for marble from Griekwastad in the Northern Cape Province. The marble was characterized mineralogically by X-ray diffraction. Major and trace elements were determined using inductively coupled plasma-optical emission spectroscopy. The sample was crushed, and the crushed material beneficiated by tumbling and polishing. The resulting beads were incorporated into a variety of jewellery and other decorative items. It is concluded that the beneficiation of Griekwastad marble presents a good opportunity for value addition and job creation, provided that an effective marketing strategy for the products can be developed..

Jan 1, 2014

By Leopoldo Gutierrez, Esau Arinaitwe, Marek Pawlik

"The effect of various polymers, including: anionic carboxymethyl cellulose (CMC), polystyrene sulfonate (PSS), humic acids (HA) and non-ionic hydroxypropyl cellulose, on the wettability of Athabasca bitumen was evaluated through dynamic contact angle measurements using the captive bubble technique. The tests were carried out as a function of pH at a constant ionic strength (0.01 mol/L sodium chloride). The evolution of the three-phase contact angle between the solution, bitumen and an air bubble was followed as a function of time over a period of ~6 minutes. The contact angle data were modelled using a first-order kinetic equation. The results were analyzed in terms of the initial contact angle, the evolution rate constant, and the steady-state contact angle value. In the case of anionic polymers, a pronounced decrease in the initial contact angle value was observed at pH 3. Under acidic conditions, there was no significant effect of CMC observed on the steady-state contact angle value but PSS and HA significantly decreased the steady-state contact angle value. At pH 8.5. the anionic polymers did not affect the wettability of the bitumen surface but they significantly decreased the contact angle evolution rate. These results suggested that CMC is not capable of permanently lowering the hydrophobicity of bitumen, and the polymer only slowed down the evolution of the contact angle to the steady-state value. The results also showed that polystyrene sulfonate and humic acids were capable of making bitumen hydrophilic but only under acidic conditions. Only hydroxypropyl cellulose (HPC) produced a large decrease in the steady-state contact angle under alkaline conditions (pH 8.5). The kinetics of contact angle evolution in the presence of HPC was also drastically lowered. The results were discussed in terms of the chemical composition of the polymers and their different affinities towards the bitumen surface."

Jan 1, 2014

By Renato Oliveira, Walter Valery, Alex Jankovic, Birol Sönmez

"The ball mill is the most common ore grinding technology today, and probably more than 50% of the total world energy consumption for ore grinding is consumed in ball mills. On the other hand, high pressure grinding roll (HPGR) technology is relatively new to the mining industry, with significant application only since the beginning of the 21st century. Both ball mills and HPGRs are typically used in closed circuit with classifiers. There is a general consensus within the industry that classification efficiency and circulating load both have a major effect on the efficiency of closed circuit ball mills. Metso Process Technology & Innovation (PTI) conducted a laboratory test program to understand the relationship between classification efficiency and circulating load, and the impact on the performance and capacity of ball mill circuits. However, the effects on HPGR performance are significantly different. Metso PTI has initiated a pilot scale test program to evaluate the size reduction performance of the HPGR under different circuit configurations. A series of pilot scale HPGR locked cycle tests were performed to simulate the following circuit configurations: including closed circuit with a screen, partial product recycle and edge recycle. This paper discusses the results from the pilot scale HPGR and laboratory scale ball mill test programs. The effect of circulating load and classification efficiency on the performance of ball mill circuits is compared to the effect on HPGR circuits. The fundamentals of grinding behavior are also discussed in order to explain the difference."

Jan 1, 2014