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By Chang Wei, Fan Zhang, Zhigan Deng, Minting Li, Cunxiong Li, Gang Fan, Xingbin Li

Marmatite is an important resource of zinc, which exist in forms of high iron and high indium. In order to recycle the valuable metal from these ores, the testwork of simultaneous leaching on neutral residue mixed with zinc concentrate of high iron and high indium has been conducted. The primary objectives are to leach the zinc and indium remaining in the neutral leach residue as ferrite using acid, and to reduce the ferric iron in solution to the ferrous by zinc concentrate, thereby extracting the zinc and indium in the zinc concentrate. The results indicated that in the following conditions, mass ratio of neutral residue to zinc concentrate of 1:0.25, particle size of 74-58 μm, initial sulfuric acid concentration of 150 g/L, liquid to solid ratio of 8 L/kg, temperature of 90°C, reaction time of 4h, the leaching efficiency of zinc and indium were over 95%, nearly 90% Fe was Ferrous in the leaching solution. This process effectively extracted zinc and indium and converted Fe3+ into Fe2+ in solution, and simplified the traditional process of reduction after leaching.

Jan 1, 2016

By Michael Rehbock-Sander, Romed Insam

"INTRODUCTIONThe idea of building a summit tunnel under the Brenner occurred to the Italian engineer Giovanni Qualizza as far back as 1847. But it was to be another 160 years to pass before a base tunnel was to be built.In 1971 the idea of a tunnel at the Brenner was dusted off again. The UIC, the International Union of Railways, commissioned a study for a new Brenner railway with a base tunnel. By 1989 three feasibility studies had been drawn up which formed the basis for further planning of the Brenner Base Tunnel.This was the start of the planning activities. In 1994, the European Union included the Berlin-Naples corridor in the list of priority projects. Ten years later, Austria and Italy signed a State Treaty to build the Brenner Base Tunnel. In that same year, what is today the BBT SE was established.PROJECT DESCRIPTIONThe Brenner Base Tunnel (BBT) with a length of 55 km is the centrepiece of the Helsinki-Valletta Transeuropean Traffic Corridor from Finland to Southern Italy. The BBT tunnel system connects in the north with the Innsbruck station (Austria) as well as to the feeder routes in the Lower Inn Valley, and opens to the south with the projected new line in the direction of Verona (Italy). The tangible design efforts have been underway since 1999; the start of construction of the first section was in the year 2007. The project is financed by the Italian and Austrian governments (each 30 %), as well as by the European Union (40 %).From 2027 onwards the Brenner base tunnel, including the existing lines connected with it, will carry a daily average of 330 trains (approx. 80% cargo trains and 20% passenger trains)."

Jan 1, 2016

By Maurizio Siepi, Bruno Vingiani, Claudio Asioli

"The article describes an emergency rehabilitation intervention executed at Buyo Dam, in Ivory Coast, to intercept a significant water seepage occurring through the foundation of this zoned earthfill retaining structure constructed in the late Seventies. To solve the problem, a 800 mm thick, 400 m long impervious cut-off wall (COW) was constructed on the right side of the embankment, operating from the dam crest and with the reservoir almost at its maximum level. The use of an innovative pre-mixed self-hardening grout, with a target hydraulic conductivity coefficient (k) lower than 10-9 m/s, was considered the only way to match the tight working schedule and the strict requirements for the filling material of the COW.Presentation of the Hydroelectric Scheme of BuyoThe hydroelectric scheme of Buyo, located at 6°14’28” N 7°20’45 W on the Sassandra River, in Ivory Coast (Figure 1), was built in the late Seventies for agriculture and power generation. With a reservoir of 8.3 billion m3 and an installed power capacity of 165 MW, enough to supply electricity to 111,000 homes, it represents an installation of great significance for this West African country."

Jan 1, 2016

By Fatima-Zahra Houmymid, Elena Chiriotti, Mahdi, Samy

"The Greater Paris projects involves the creation of a 200km extension of the actual public transport network on the close outskirt of Paris. In 2011, SYSTRA has been awarded the Engineering studies of a 20km underground section in the densely urbanized southeast quarter of the Parisian suburb. In order to both guide the TBM technology choice and identify and mitigate the risk due to soil settlement during tunnel boring, several analysis have been carried out and integrated into a Geographical Information System to share and manage this risk during the successive design phases of the project. The geological context‘s complexity and the Owner‘ requirements have led to the necessity of using an innovative analysis approach, leveraging both the numerical modelling analysis’s accuracy and the analytical method‘s ease of programming and implementation in a GIS, by the mean of the calibration of the analytical approach’ parameters on the FEM results.INTRODUCTIONThe Greater Paris Transport Project foresees the extension of the actual public transport network to the close outskirt of Paris through the extension lines 11 and 14, the creation of a circular new line around Paris - line 15 completed by lines 16 and 18 linking developing territories - and line 17 to Roissy-Charlesde- Gaulle airport.The SOCIETE DU GRAND PARIS (SGP) is the public institution that promotes this project and awards SYSTRA as Engineering for the 15th Line southeast section.Line 15th – South-East sectionIn 2011, the Owner SGP (SOCIÉTÉ DU GRAND PARIS) awarded to SYSTRA the preliminary and detailed design of a 20km-long underground section of Line 15, between the stations of Villejuif-Louis-Aragon and Noisy-Champs. The double-track, single-tube tunnel has an inner diameter of 8.5m (about 9.8m excavated diameter, 75m2 excavated cross-section). The tunnel is inserted in a densely urbanized context."

Jan 1, 2016

By Jens Classen, Martino Gatti

"GENERAL PROJECT DATAThe Sparvo Tunnel is part of the “Variante di Valico” project, a new 65km (40mi) highway link between Bologna and Florence, designed to renew the existing A1 route which connects Bologna and Florence. It is composed of 2 x 2,5km (1,55mi) twin tunnels excavated inside a complex geological context, characterized by the presence of a series of surface landslides and methane gas.The inclination is 2,6 % and the minimum radius is 1.400m (4.600ft). The two tunnel tubes were excavated by a 15,6m (51ft) diameter EPB-TBM from summer 2011 to summer 2013. The internal diameter of the concrete lining is 13,6m (44,5ft), made up of precast concrete segments 2m (6,5ft) long and 70cm (28”) thick, being the largest and heaviest segments ever produced. Excavation went smooth apart from initial problems concerning clogging problems and a main bearing damage of the TBM, which are discussed in a further paper during the congress. No structural damage was observed until the end of the TBM drives.SITE OBSERVATIONS DURING THE POST-EXCAVATION PHASEThe first evidence of the stress state of the segmental lining appeared on November 20, 2013 inside the northern tube (1st drive). Ring No. 884 showed obvious signs of overstress, resulting in spalling and crushing of the concrete, and the subsequent bending of the reinforcement, as visible in figure 1.At this time the tunnel invert was already partially backfilled, and construction traffic was running through the tunnel. First safety measures included closing of the tunnel, and initial measurements of the displacements."

Jan 1, 2016

By Frank Haehnig, Harald Krenn, Harm-Christoph Claassen

"The Wadi Dayqah Dam Water Supply Scheme represents one of the most important projects implemented by the Sultanate of Oman to ensure sustainability of water resources. The principal components of the project comprise two dams to impound the Wadi Dayqah, to store and supply drinking water to the local area and to Muscat, the capital city of the Sultanate.The Main Dam with a central spillway is a RCC Gravity Dam with a maximum height above foundations of 75m, crest length 400m; the Saddle Dam is a rockfill dam with central clay core, max height above foundations is 49m and crest length 360m. During construction of the Saddle Dam a key trench was excavated to 10m depth and filled with compacted clay connected to the central core of the embankment. Grouting utilizing cement grout was performed as a single line grout curtain prior to each filling operations. Both Dams are founded on soft Siltstone, Claystone, Sandstone and inter-bedded harder limestone.After construction of the Saddle Dam, once water was in the reservoir it became evident in early 2010 that some seepage was occurring apparently from the right abutment. This seepage became more marked when the reservoir first filled to discharge over the spillway in June 2010. In order to reduce the seepage, additional sealing works by drilling and grouting of a three row curtain up to 80 meter target depth were initiated to supplement the existing single row curtain. Part of this project for the sealing works has also been to drill additional investigation holes to provide more information and confirm extend of the additional sealing works and its limits.Züblin Ground Engineering was awarded the Additional Sealing Works Contract. Whilst Equipment was on Site, the opportunity was taken to carry out drilling and grouting on the Left Abutment of the Main Dam to reduce seepage through that abutment and to install additional standpipe piezometer for future monitoring of seepage patterns.Work on this Contract started on site in January 2013 and was substantially completed in January 2015.At the time of Tender Züblin Ground Engineering propose and Alternative Design in the form of a Secant PileCut-Off Wall, 85m long to a depth of 40m with additional drilling and grouting below the foot of the cut-off which was then included in the contractual scope."

Jan 1, 2016

By Lisa R. Papandrea, David Chen, Walter E. Kaeck

"Construction of the University at Buffalo’s new School of Medicine and Biomedical Sciences (UB-SMBS) required excavation in variable ground to a depth of more than 40 ft adjacent to the NFTA Metro subway and Allen Street Station. Complicating the building design and construction, the new medical facility incorporates the at grade Station entrance building, requiring a combination of temporary and permanent excavation support structures, a complex sequence of ground support installation, and a mix of shallow and deep foundations to accommodate the large floor spans and concentrated column loads introduced by building over and adjacent to the Station entrance. Excavation and foundation construction was challenged by a stratified soil profile with interlayered and sensitive sands, silts and clays and complicated groundwater regime with perched and regional water tables. Efficient construction required ongoing coordination between the design team and contractor, careful field observation, and construction monitoring in several facets of below grade construction. This paper describes the design and construction of excavation support structures and foundations to manage the variable ground, congested site conditions, and complications of building adjacent and above an active subway station. Use of site instrumentation and monitoring data to provide guidance in construction when unanticipated field conditions arise is illustrated. Lessons learned in installation and sequencing of excavation support, groundwater control and foundation construction are also discussed.INTRODUCTIONUniversity at Buffalo President Satish K. Tripathi heralded the new School of Medicine and Biomedical Sciences (UB-SMBS) as a future linchpin of UB’s downtown campus that will revitalize the area and enhance western New York’s emerging bio-sciences corridor. The $375 Million, 628,000 square foot, eight story building with two basements is expected to house 2,000 faculty, student and staff allowing UB to increase class size from 140 to 180 students. It will be constructed above the Niagara Frontier Transportation Authority’s (NFTA) Allen Street Station, creating a direct connection to Buffalo’s light rail system. The 200 ft x 400 ft site is bounded by Main Street, High Street, Washington Street and the Roosevelt Apartments and adjoining parking lot at the west, north, east and south respectively, as shown in Figure 2. Groundbreaking for the new building was in October 2013 with the facility scheduled to open in early 2017."

Jan 1, 2016

By John P. Turner, Steven S. Dapp, Dan A. Brown

"The Goethals Bridge Replacement (GBR) spanning the Arthur Kill Waterway between Elizabeth, NJ and Staten Island, NY consists of a dual-span 1,982.5-ft long cable-stayed bridge with approach spans of 2,545 ft on the NJ side and 2,788 ft on the NY side. The bridge is supported on over 200 drilled shaft foundations ranging in diameter from 4.5 ft to 10 ft and socketed into Passaic Formation siltstone. Drilled shaft resistances for design were based on load tests as described in a companion paper (Dapp et al. 2016). This paper presents the main foundation design considerations and challenges. The approach to construction of the rock sockets, with a focus on quality in order to support the use of high nominal values of side and base resistance, is described. Lessons learned from this project and their application to future similar projects are presented.INTRODUCTION AND BACKGROUNDThe Goethals Bridge Replacement (GBR) project is a Public-Private Partnership (P3) that represents a major milestone for the Port Authority of New York and New Jersey (PANYNJ) in its distinguished history of bridge building in the greater New York City metropolitan area. The new bridge will replace the existing Goethals Bridge, named after Major General George W. Goethals, Chief Engineer of the Panama Canal and the first consulting engineer for the Port Authority. The existing Goethals Bridge along with the Outerbridge Crossing and the Bayonne Bridge comprise the three Port Authority bridges connecting Staten Island with New Jersey. The existing Goethals Bridge and the Outerbridge Crossing are cantilever truss structures and both opened on the same day in 1928. They were designed by J.A.L. Waddell under the supervision of the eminent engineer Othmar H. Ammann (1879-1965), who was the designer of many other iconic bridges in the NY City area including the Bayonne Bridge (1931), the George Washington Bridge (1931), and the Verrazano Narrows Bridge (1964). The designer of record for the replacement Goethals Bridge is Parsons Corporation, which is the successor firm of Robinson & Steinman, whose principal David B. Steinman was also a notable NY area bridge designer and a contemporary and rival of O.H. Ammann.The replacement Goethals Bridge is supported on over 200 rock-socketed drilled shaft foundations. Each main pylon tower is supported on a group of six 9-ft diameter drilled shafts and each anchor pier is supported by two 10-ft diameter shafts. Each approach pier consists of a two-column bent with each column supported on a rock-socketed drilled shaft. A rendering of the Main Bridge crossing the Arthur Kill is shown in Fig. 1."

Jan 1, 2016

By Adnan A. Malik, Tadashi Maejima, Jiro Kuwano, Shinya Tachibana

"The helical piling system provides solution to many geotechnical related problems due to its quick installation, higher compressive and pullout resistance, no wastage of material, workable in limited areas and reusability. However, its use as a foundation for bridges and high-rise buildings is still limited as compared to other piling methods. In the present study, the performance and load settlement behavior of screw and straight pile is investigated under cyclic compressive load in dense ground conditions. To achieve the set objectives, pile load tests were conducted in a cylindrical steel container. The model ground was compacted with dry sand at relative density of 80%. It is observed from the test results that screw and straight pile resistance reduced when the cyclic load is applied at allowable pile resistance state. The reduction in the ultimate pile capacity is more in straight pile than in screw pile. However, straight pile showed higher ultimate pile capacity than screw pile under similar pile tip diameter. The effect of helix bending deflection on load settlement behavior and ultimate pile capacity increases under cyclic loading.INTRODUCTIONScrew pile is one of the new developments in deep foundation, which is growing tremendously fast because of its quick installation technique, less noisy operation, no wastage of material and involvement of minimum manpower. Screw piles have an edge on straight pipe piles due to its high bearing capacity and uplift resistance. The installation mechanism of screw pile is different from straight pile. Torque and pressure is required to install the screw pile whereas hammering, pressure and vibration is required to install straight pile. As the installation mechanism is different between screw and straight pile, therefore, the ground disturbance that is produced during their installation is also different. The ground disturbance produced during the installation also depends upon the pile tip condition i.e. open or closed ended. Sakr, (2009) stated that the compressive capacity of screw pile in 3 to 5 times higher than driven piles having the same shaft diameter and length. The reason for this increase in pile capacity is due to helix, which is generally 2 to 2.5 times the pile shaft diameter. Larger helices can give higher end bearing capacity but it requires very powerful machinery to install in dense grounds. For instance, if large helix screw pile is installed in a dense ground then helix-bending deflection will start affecting the end bearing capacity (Yttrup and Abramsson, 2003; Malik et al. 2013 and 2015). According to Malik (2015), the equations of thin plate (Young and Budynas, 2002) with uniformly distributed load on the plate can give reasonable estimation of helix deflection due to dense ground conditions."

Jan 1, 2016

By Mohamed Elgouhary, Carol L. Tasillo, Daniel Koziol

"The Bolivar Dam, located near the Village of Bolivar, Ohio is one of a system of dams designed to provide flood control and water conservation in the Muskingum Watershed. The Bolivar Dam is a “dry dam” that only impounds water during flood events. In order to address problematic seepage, which negatively affects the structural stability of the dam, the U.S. Army Corps of Engineers (USACE) designed a partial-depth and partial-length Seepage Barrier Wall (SBW) through the upstream slope of the dam. For this project, TREVIICOS constructed a 36 in (914 mm) positive SBW by plastic concrete panel wall method and excavated using hydromill and clamshell equipment. The plastic concrete was manufactured on-site, which allowed for enhanced quality control and prompt service. This required the installation, commissioning and operation of a concrete batch plant on-site. This paper presents the challenging aspects of the design, manufacture and placement of the plastic concrete for the SBW in order to meet contract strength and permeability requirements as well as workability requirements necessary for tremie concrete placement.Project General InformationBolivar Dam is located in Northeast Ohio (Fig. 1). It is one of a system of sixteen dam projects designed to provide flood control and water conservation in the Muskingum Basin, which covers 20 percent of the State of Ohio (Fig. 2). Bolivar Dam is on Sandy Creek, a tributary of the Tuscarawas River.The Dam has been constructed, operated and maintained by the USACE, for the Muskingum Watershed Conservancy District. Its construction was completed in 1937 and it has been in operation for flood control since 1939.Bolivar Dam is a rolled earth fill dam, with a typical embankment section made of a central impervious core flanked upstream and downstream by a pervious outer shell with downstream rock toe. The embankment has a maximum height of 87 ft (26.5 m) and a crest length of 6,300 ft (1,920 m), and is comprised of the main embankment starting on the left abutment of about 1,500 ft (457 m) heading to the Northeast, followed by the terrace embankment of 4,800 ft (1,463 m) heading to the North. An upstream impervious blanket extends up to 500 ft (152 m) upstream of the dam along the majority of its length. The outlet works are to the left of the embankment, and consist of an intake structure with six gates, followed by two outlet conduits that finish in a stilling basin. To the left of the outlet works is the uncontrolled emergency spillway, which was doubled in width to 540 ft (165 m) in 1989, and excavated material utilized for construction of a stability berm against the upstream face of the main embankment. A concrete parapet wall was also installed along the upstream side of the crest during this work. In 1982, a toe drain, downstream filter berm and line of 35 relief wells were installed. The filter berm was recently extended an additional 200 ft (61.0 m) downstream and granular filters were placed over an approximate 2000 linear ft (610 m) reach of the lower terrace slope. (Fig. 3)."

Jan 1, 2016

By George W. Little, John Councilman

"The selection, evaluation, and modification of contractor mix designs for self-hardening seepage barriers, completed by the slurry trench excavation method, can be one of the most critical and challenging tasks to ensure the cutoff wall meets the design performance criteria. Contractor mix designs should incorporate all available geotechnical data, including subsurface soil characteristics, groundwater information, and potential site contaminates. However, the pre-construction mix design can have limitations if subsurface data is limited or shows variability from initial investigations. Placement of the seepage barrier material needs to be evaluated during construction to identify in-situ performance. In one particular case study, the self-hardening cutoff wall mix design was evaluated over a one year period followed by a year and a half installation period, in which, a number of adjustments were made to the laboratory mix design during construction due to performance in the field. Installation for the selected mix was monitored on a real-time basis, using quality control data, as well as early strength and permeability results to determine if adjustments to the self-hardening mix were necessary. Evaluation of early results and relationships between strength and permeability were used to make adjustments prior to achieving the final test results for 28-day strength and permeability. Test results of the installed mix illustrated a direct correlation between strength and permeability. Achieving a minimum unconfined compressive strength was necessary to meet the minimum permeability of the seepage barrier. Other determinations conclude that the thorough development of a pre-construction mix design can have limitations even when all geotechnical data and site conditions are taken into account. Understanding early indicators and key strength and permeability relationships are necessary to determine seepage barrier performance and limitations.IntroductionThe evaluation of contractor mix designs for self-hardening seepage barriers was reviewed for one particular case study where a mix was developed using available geotechnical background information, including considerations for impacted groundwater. Following development of the laboratory mix design, the seepage barrier wall was installed over a one and a half year period, where the contractor mix design was evaluated and modified to accommodate field conditions affecting performance. The objective of the project was to cutoff and collect impacted groundwater and prevent the migration of contaminants to the creek running adjacent to the project. The self-hardening seepage barrier wall was installed using the slurry trench excavation method along 4700 ft of alignment and extended to depths ranging from 20 to 85 ft below ground surface, where it tied in with a low permeability stratum or competent bedrock."

Jan 1, 2016

By Saverio Agresti, Giuseppe Lunardi, Donato Basta, Roberto Trapasso

"At a distance of 10 years from the first application of the Nazzano Method, the widening under traffic of a tube of an existing motorway tunnel was realized near Ancona, along the A14 Motorway in Italy. This paper describes the works for the enlargement with conventional method of the second tube, very close to that already widened under traffic.This enlargement was realized very fast, taking into account the advantages of some interesting technological improvements of the Final Design proved in the first tube.INTRODUCTION TO THE WIDENING OF EXISTING MOTORWAY TUNNELSThe widening of a twin-bore motorway tunnel usually considers the double option of creating a third bore as an alternative or closure to traffic of one of the two bores with the resulting reduction in the level of service for users.On the contrary, the extension in situ of a road, motorway, railway or underground tunnel in the presence of traffic, made possible by an inspired idea of Prof. Pietro Lunardi, enables the level of service of the infrastructure to be maintained without the need to resort to alternative routes to create new permanent or temporary bores, not always feasible because of the lack of the necessary space.This construction technique, known as the ‘Nazzano Method’, is part of the technologies refined and offered by the ADECO-RS approach to tunnel design and construction (Lunardi P., 2008) which is increasingly used in the world, leading to the industrialisation of tunnelling (meaning respect for the times and costs set out during detailed design) both in conventional and mechanised (through TBM) excavations.The first true experimentation of the ‘Nazzano Method’ was carried out between 2004 and 2007 to enlarge the two-bore ‘Nazzano’ tunnel (Italy, Milan-Rome A1 motorway) in the presence of traffic, widening it to house from two to four lanes in each direction (Lunardi P. et al., 2007). Following the success achieved in this first application, the Nazzano Method was strengthened considering all the possible suggestions arising from the previous experience and then taken up to enlarge the north bore of the ‘Montedomini’ two-bore tunnel (Italy, Bologna-Taranto A14 motorway), in situ and the presence of traffic."

Jan 1, 2016

By Tina Živec, Žibertm Marko

"Civil design has changed in many ways using BIM (Building Information Modelling) technology in its most recent form. Such a technological breakthrough has not been successful so far in traditional oriented Engineering Geology, except in the Mining and oil exploration markets with budgets on much different scales. The fact is that paper, pencil and hand drawn sketches are still state of the art and a perfectly acceptable way of producing subjective geological interpretations.Using the technology available, we have developed a set of procedures and techniques to combine the latest surveying and remote sensing technology, GIS based tools to manage large data sets and BIM modelling techniques in a 3D geological environment.To demonstrate the concept, the forthcoming Karavanke tunnel project (Slovenia) has been chosen for testing techniques. The project, with its rich documentation from previous phases and new data available, represented a good basis for testing the possibility of digitizing geological data while communicating with Leapfrog Geo 3D modelling algorithms. This type of procedure would then allow engineers at the construction site to use the 3D model for prognosis and evaluation, while upgrading it daily with new information.INTRODUCTIONThe Karavanke tunnel crosses the mountain range on the border between Slovenia and Austria. As the geology is very complex due to its imbricate fan structure, a series of geological – geotechnical and hydrogeological investigations have been performed since the 1970s, resulting in extensive project documentation. The construction of the 7864 m long single-tube two-lane tunnel took place in the late 1980s. Currently, the tunnel represents a critical point on Pan-European Transport Corridor X (Salzburg, Austria – Thessaloniki, Greece), with insufficient safety measures. The need for improved traffic flow and enhanced road safety led the Slovenian government in 2013 to a decision to continue with activities regarding the construction of the second tunnel tube 70 m east of the existing tunnel.The extensive project documentation from previous investigation phases and construction of a new tunnel tube presented a good base for a pilot project, in order to test the emerging new technologies for data acquisition, processing and analysis in a 3D environment. Several products are available on the market for data acquisition and 3D geological modelling, but only a few can be applied in the civil design, as well. Developing a standard format and procedure for implementing the 3D geological model using new remote sensing techniques, 3D geological modelling tools, such as Leapfrog Geo and BIM (Building Information Modelling) modelling techniques would move the Engineering Geology, Geotechnics and Tunneling to a more advanced level. 3D modelling tools would therefore not only be used as a visualization tool, but would also contribute to in a more efficient communication and workflow between the professionals involved in the project."

Jan 1, 2016

By Yunhua Gan, Xiaowen Chen, Yang Tong

Experimental studies of electro-spraying were carried out using ethanol as fuel in a microcombustor under combined electric field. And the effects of different electro-spraying modes on the combustion efficiency were analyzed. Results showed that when ring electrode potential was invariant, there were four different electro-spraying modes with the variations of nozzle potentials, which were varying with the flow of ethanol. The cone-jet mode was the stablest one during the whole experimental process. The atomized ethanol was ignited and combusted stably near the steel mesh, the combustion efficiency increased firstly and then decreased along with the increasing of the equivalent ratios, reached the maximum values when the equivalent ratio equal to 1.0. And the maximum values were the highest at the cone-jet mode, and the lowest at the pulsed-jet mode.

Jan 1, 2016

By Mao Chen, Baojun Zhao, Zhixiang Cui, Leonel Contreras, Chuanbing Wei

Bottom blown oxygen copper smelting process developed at Dongying Fangyuan Nonferrous Metals shows many advantages such as flexible feed requirement, high productivity, low energy consumption and high direct copper recovery. However, the weak acid generated during the process is not stable which influences the waste management and continuous operation. The amount of the weak acid is determined by SO3 formed in copper smelting process. SO3 can be formed inside copper smelting furnace and boiler at different conditions. Effects of temperature and oxygen partial pressure on the formation of SO3 during copper smelting process have been discussed thermodynamically. Understanding of the mechanisms for SO3 formation will enable the operation of bottom blown copper smelting furnace to be optimized and generation of the weak acid in the process can be managed. The fundamentals developed in this study can also be applied to other copper smelting processes.

Jan 1, 2016

By Dianyuan Dang, Guihong Han, Wenjuan Wang, Tao Jiang, Yanfang Huang

In this study reduction kinetics and swelling behaviors in "two-step process” were investigated by weight-loss technique and visualizing physical changes of pellet. Results showed that reduction degree (r) increased with increasing temperature and time. According to the dynamic calculation, when reduction temperature was lower than 1000°C the reduction process was controlled by chemical reaction with apparent activation energy of 72.27 kJ/mol. When reduction temperature was higher than 1000 , the equation of t/[1-(1-r)1/3] against [1+2(1-r)-3(1-r)2/3]/[1-(1-r)1/3] followed straight lines, demonstrating that reduction was mixed-controlled. Swelling experiments indicated that the maximum swelling index increased with the increase of reduction temperature and CO content.

Jan 1, 2016

By Bo Jiang, Jiusan Xiao, Hongmin Zhu, Kai Huang, Shuqiang Jiao

Carbothermal selective reduction of simulative titanium slag and various titanium raw materials were presented and SiO2 was found to be partially reduced, forming a series of Fe-Si alloys during the process. Thermodynamic analysis of the selective reduction between TiO2 and SiO2 was performed using HSC 6.0 software, then a series of equilibrium experiments were designed and presented. The activity of Si reduced from SiO2 was affected by the presence of Fe reduced from FeOx and the generation of Fe-Si alloys, promoting the reduction of SiO2 in the whole process. The results of experiment are in great accordance with the calculated data obtained from thermodynamic analysis.

Jan 1, 2016

By Guo Chen, Xuefeng Liao, Tu Hu, Shengzhou Zhang, Hongying Xia, Jinhui Peng, Libo Zhang

Pine nut shell is as raw material for preparation of high surface area activated carbon (HSAAC) by microwave induced KOH activation. The effects of microwave power, activation duration and KOH/C mass rate (R) on the iodine adsorption capability and activated carbon yield were investigated. Additionally the surface characteristics of HSAAC were characterized by nitrogen adsorption isotherms and SEM. The operating variables were optimized utilizing the response surface methodology and were identified microwave power 738W, activation duration 17 min, and R 4, corresponding to a yield of 46.28 % and an iodine number of 2154 mg/g. The key pore structure parameters of HSAAC such as the Brunauer–Emmett–Teller (BET) surface area and total pore volume were estimated to be 3819 m2/g and 2.09 mL/g, respectively. The findings strongly support the feasibility of microwave heating for preparation of HSAAC from spent pine nut shell by microwave induced KOH activation.

Jan 1, 2016

By Sedef Pinar Basag, Onuralp Yucel, Ahmet Turan

Niederschlag process is commonly used to produce metallic antimony. The process is a metallothermic process which is conducted in one step for metallic antimony production. Using this method Sb2S3 is mixed with coal and metallic iron and subjected to reduction. During heating, antimony sulfide is decomposed and sulphur combines with iron to form the matte phase. Metallic antimony is collected at the bottom of the crucible. In this study, evaluation of Sb2S3 concentrate, extracted and obtained from West Anatolian Region of Turkey was investigated by using Niederschlag process. The reductant stoichiometry, reduction temperature and duration were carried out in the experiments. Chemical analysis methods by using atomic absorption spectrometry (AAS) and X-ray diffraction spectrometry (XRD) techniques were used for the characterization of the concentrate, metallic nuggets and matte phases.

Jan 1, 2016

By Yuanbo Zhang, Ruijun Wang, Qian Li, Zhao Jing, Guanghui Li, Zhengwei Yu, Chen Liu

The high content of sodium and potassium in sinter is harmful for blast furnace ironmaking. Reductive sintering technology can remove more alkali metals than conventional sintering process. In order to improve the removal ratios of Na and K, reductive sintering with both CO-containing flue gas circulation and carbon-bearing pellet was conducted in this study. Experimental results show that all indexes except the VSV and P were improved in reductive sintering with CO circulation. Flue gas circulation technique combined with carbon-bearing pellets were beneficial to reductive sintering, because it could maintain good sintering indexes and enhance the removal of Na, K. The best removal ratios of Na, K and reduction degree of iron oxides were 20.37%, 63.73% and 23.76%. In reductive finished sinter, silicate mineral becomes the important binder phase, and main iron mineral phases are wustite (FexO) and magnetite (Fe3O4).

Jan 1, 2016