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By Åke C. Rasmuson, Mahmood Alemrajabi, Kerstin M. Forsberg, Kivanc Korkmaz

"In the present study the recovery of a Panasonic Prismatic Module 6.5 Ah NiMH 7.2 V plastic casing hybrid electric vehicle (HEV) battery was investigated, separately processing the anode and cathode electrodes. The composition of the electrode materials was determined by total dissolution and analysis using ICP-OES. Nickel is the dominant metal in the active materials (65% by mass in the anode and 70% by mass in the cathode). Most of the rare earth elements (La, Ce, Nd, Pr and Y) are located in the anode active material, whereas only a small amount of Y is found in the cathode material. The electrode materials were further characterized by SEM-EDS and powder XRD. The electrodes were leached in sulfuric acid and in hydrochloric acid under different conditions. The dissolution was followed by taking out samples and analyzing the concentration of REE, Co, and Ni using ICP-OES. The results indicate that the dissolution of nickel could be limited by slow dissolution kinetics of nickel oxide. Further, it was found that light rare earths are lost through precipitation during sulfuric acid leaching with increasing extent as the temperature and sulfuric acid concentration increases. The separation of REE from the sulfuric acid leach liquor by precipitation as NaREE(SO4)2.H2O and from the hydrochloric acid leach solution as REE2(C2O4)3.xH2O have been studied by performing experiments using battery leach liquors. INTRODUCTIONIt is well known that the Hybrid Electric Vehicle (HEV) is becoming more common due to economic and environmental reasons. Batteries are widely used in HEVs’ such as automobiles or larger trucks for transportation purposes. The most common type of battery in these vehicles is nickel metal hydride (NiMH), largely due to Toyota's decision to use them in their popular Prius. More than two million hybrid cars worldwide are running with NiMH batteries, such as the Prius, Lexus (Toyota), Civic, Insight (Honda), and Fusion (Ford). Panasonic manufactures HEV prismatic NiMH batteries that have been used by Toyota and GM (among others), while Sanyo manufactures HEV cylindrical cell NiMH batteries, which have been used by Honda and Ford."

Jan 1, 2016

By A. K. Fallaw, G. Wang, L. R. Moore, S. Dobson, Y. Xiong, J. Gu

"As ores degrade, mining techniques and chemistries change to meet market demand and maintain product quality. The balance of recovery and grade is a significant challenge in the Crago Process where an anionic collector is used to float phosphate, followed by acid scrubbing, then an amine float to improve product grade. As the grade is a requirement for DAP and MAP production, recovery is the criteria to suffer. Phosphate losses in the amine float can bring overall recovery down by as much as 18%, creating a growing need to think outside the box to improve recovery. This paper will focus on the theory of amine tail recycling and the best methods to optimize the overall phosphate recovery by recycling the tails from the cleaner flotation step. INTRODUCTION In 2014 the total US phosphate production was down 13% over the prior year, from 31.9 to 27.1 Mt, which accounts for 12.32% of the world’s phosphate rock production. Florida and North Carolina phosphate production accounted for 80% of total US phosphate production, which was down from 85% the previous year. This decline is due in part to the closing of the last phosphate mine in Polk County, FL - which had an operating phosphate mine for over 100 years (Gurr, 2015). Another factor contributing to the reduction in contribution from FL & NC is the increasing challenges in beneficiating the remaining ore deposits. The Central Florida mining district has historically been in the Bone Valley deposit, where raw apatite was abundant with P2O5 values as high as 15%. The Bone Valley ore also had characteristics favorable to beneficiation to 27.5-29.7 %P2O5 while achieving recoveries above 86%. The move southward into the Hawthorne Formation has seen the ore feed grade hit some historic lows, and the matrix characteristics pose more challenges to phosphate producers. The Hawthorne Formation experienced lateritic weathering after the Bone Valley formation which altered the apatite to aluminum phosphate minerals, and alteration of montmorillonite to kaolinite, releasing MgO that caused the dolomitization of the top of the Hawthorne limestone (Cathcart, 1966). Elevated levels of dolomite can yield an increase in slurry viscosities, reduce production rates, and increase energy costs in the wet-acid fertilizer process. The MgO will also act to dilute grade, making it more difficult to achieve a standard 18-46-0 product (McHardy, 1981)."

Jan 1, 2016

By E. Garab, M. Pillalamarry, E. Develo

"Recent geological exploration at Rosh Pinah mine revealed that the mine’s major production is shifting towards the western orefield, which will increase the demand for air flow to be supplied to this area. A snapshot of the ventilation survey carried out in December 2014 at the western orefield drill drive B (WOF-DDRB) showed that the air flow was well below the required standards. In order to improve the existing conditions, possible options were considered and simulated using Ventsim™ software.The best option found was to replace the existing western orefield fans with the larger fans from the inactive southern orefield workings, to increase the air flow in the DDRB district. Simulation showed that as much as 20 m3/s of air can be received at the working faces of WOF 30, compared to the previously received amount of 1.37 m3/s. The economic analysis indicated that the above option can reduce the ventilation cost by N$1.9 million annually. It was also noticed that after implementing this option together with other projects, the ventilation conditions in the mine were greatly improved and currently give no cause for concern. IntroductionA good mine ventilation system should be capable of providing adequate quantity and quality of air to all working faces, and is critical to the occupational health, safety, and comfort of underground employees (Luxbacher and Ramani, 1977; Exikis and Kapageridis, 2006). No ventilation system can remain adequate indefinitely; as the mine workings are extended, the ventilation characteristics such as system pressures, air volumes, leakages, and airway resistances change considerably. Continuous improvement of the ventilation system is needed to ensure compliance with health and safety regulations (Lovejoy, 2010). It also ensures that the right quality and quantity of air is delivered to all the necessary areas at the lowest possible cost. This can be achieved by identifying inefficient airways and poorly ventilated areas in the mine and planning how best to upgrade them.The latest geological exploration shows that the focus of production at Rosh Pinah mine is shifting towards the western orefield (WOF). As mining progressed, the working areas have advanced away from the main fans, which increased the resistance to air flow drastically and resulted in increasing demands being imposed on the main fan in order to supply an adequate air flow. This process also created more leakage paths between the fan and the working areas, which has caused the air to short-circuit before it can reach the faces. Consequently, a much larger quantity of air has to be circulated by the fan so that the stipulated quantity reaches the face, which increases operating costs (Singh et al., 2004)."

Jan 1, 2016

By P. T. Bissert, L. Yan, M. D. Klein

"Federal regulations require the installation of refuge alternatives (RAs) in underground coal mines. Mobile RAs have a limited ability to dissipate heat, and heat buildup can lead to a life-threatening condition as the RA internal air temperature and relative humidity increase. The National Institute for Occupational Safety and Health Office of Mine Safety and Health Research performed heat testing on a 10-person tent-type training RA and contracted ThermoAnalytics, Inc. to develop a validated thermal simulation model (TSM) of the tested RA. The TSM was used to examine the effects of the constant mine strata temperature assumption, initial mine air temperature (MAT), initial mine strata surface temperature (MSST), initial mine strata temperature at depth (MSTD), and mine strata thermal behavior on RA internal air temperature using 117 W of sensible heat input per simulated miner. For the studied RA, when the mine strata temperature was treated as a constant, the final predicted RA internal air temperature was 12.8°F lower than it was when the mine strata thermal behavior was included in the model. A 10°F increase in the initial MSST resulted in a 7.1°F increase in the final RA internal air temperature, whereas a 10°F increase in the initial MSTD yielded a 2.5°F increase in the final RA internal air temperature. INTRODUCTION Since 2008, the Mine Safety and Health Administration (MSHA) has required the installation of refuge alternatives (RAs) in underground coal mines (1). MSHA requires that RAs provide an environment with breathable air for entrapped miners for a 96-hour period. Heat buildup inside an occupied RA is a serious concern. Without a means to dissipate the heat and humidity generated by the occupants and the carbon dioxide scrubbing system, the temperature and humidity inside RAs could lead to severe discomfort or heat stress depending on the mine ambient temperature before and during occupation of the RA. NIOSH recommended an apparent temperature limit of 95°F in its 2007 report to Congress (2). In 30 CFR 7.504, MSHA has specified a maximum apparent temperature of 95°F inside an occupied RA (3). The apparent temperature is calculated using both air temperature and relative humidity (4). Calculations could be used to determine if the air within an occupied RA will reach the apparent temperature limit. In these calculations, in order to simplify the problem, the mine temperature could be assumed to remain constant. With this assumption, the effects of the mine strata thermal mass and thermal conductivity on the heat buildup in an RA are ignored. OMSHR research has shown that the mine air and strata temperatures surrounding an RA increase when subjected to the heat of an occupied RA (5). Thus, calculations performed with the assumption that the mine temperature is constant would under-predict the resulting dry-bulb temperature and apparent temperature for a given RA occupancy. The mine air temperature has been used as the basis for RA temperature calculations. However, research has not been used to confirm that the mine air temperature is the appropriate basis."

Jan 1, 2016

By Y. M. Zhao, C. L. Duan, Z. F. Luo, X. L. Yang

"Fine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. In this study, a continuous vibrated gas-fluidized bed separator was established and developed based on the results of laboratory batch separation results. The fluidization behavior and the effects of several main parameters including superficial air velocity, vibrational parameters, bed height and separating time were systematically investigated. The results showed that the bed expansion increased linearly with the superficial air velocity and theoretically, higher bed expansion benefited the hindered settling process of fine coal particles. However, larger superficial air velocity would induce intense fluctuation in bed surface and a poor performance of density segregation. The conveying velocity of particles was mainly determined by the vibration angle and a predicted model was established by the nonlinear regression analysis. A theoretical model of bed height distribution was established and this model fitted the measured value well. The beneficiation performance of this separator was evaluated by separating -3+1 mm Wuhai fine coal. The results showed that the probable error, E, is 0.225, indicating a continuous vibrated gas-fluidized bed separator could achieve a satisfactory performance.INTRODUCTIONFine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. Meanwhile, it is also conducive to environment protect and low-carbon, green development of coal sector. In recent years, the increasing academic interest in the field of fine coal dry beneficiation has been aroused in most of big coal countries. In summary, recent processes of fine coal dry beneficiation are, according to their processing principles, mainly classified into two categories: dense medium beneficiation (Dong et al., 2015; Fan, Chen, Zhao, & Luo, 2001; Luo et al., 2008; Macpherson, Iveson, & Galvin, 2011) and improved pneumatic beneficiation (Patil & Parekh, 2011; Yang, Zhao, Luo, Song, & Chen, 2013; Yang, Zhao, Luo, Song, Duan, et al., 2013; Zhao, Zhao, Chen, & Luo, 2015). The former deploys artificial dense medium, such as magnetite powder and fine sand, to form a stable gas-solid suspension with certain density under the function of the upward fluidizing air flow and in some case, the external force field like vibration and magnetic field. Generally, it is believed that the process of air dense medium fluidized bed (ADMFB) is suitable for separation of coarse coal (-50+6 mm) and can't obtain a satisfactory result for fine coal separation (Luo, Chen, & Zhao, 2002; Luo et al., 2008). However, some recent laboratory efforts (Patil & Parekh, 2011; Zhang et al., 2014) attempt to find an improved performance for fine coal beneficiation in ADMFB with some modifications. The point of these works is to use a comparatively shallow bed and finer magnetite powder with appropriate size distribution. It is known that fluidization of finer magnetite powder is prone to arouse adverse fluidization properties such as channeling and slugging. Thus, the external force is introduced to an ADMFB in order to improve the fluidization quality of a magnetite powder bed. Some recent literature on air dense medium magnetically stabilized fluidized beds (Fan et al., 2001; Luo, Zhao, Chen, Fan, & Tao, 2002; Song, Zhao, Luo, & Tang, 2012), air dense medium vibrated fluidized beds (Luo et al., 2008) and Reflux Classifier (Macpherson, Iveson, & Galvin, 2010) reports that the separation efficiency, namely the probably error E value, of dense medium separation of fine coal ranges from 0.066 to 0.07, indicating a good separation performance. But, the main unresolved problems of dense medium beneficiation are located in the processes of product purification and medium recovery and are urgent to be solved befor"

Jan 1, 2016

By M. Gaumont, F. Robichaud

"Agnico Eagle Mines Limited (AEM) is a Canadian-based gold producer with operations in Canada, Finland and Mexico. In 2010, AEM produced its first gold bar in Nunavut, Canada as it started its Meadowbank operation. It is also in 2010 that AEM acquired the Meliadine property, which is located 25 Km North of Rankin Inlet, Nunavut, Canada. The Meliadine gold project is an advanced exploration and development project, comprising of workers camp, underground and open mines, a processing plant and all the services facilities and infrastructures required to sustain operation in a remote arctic environment.Pending formal board approval, production start-up is planned for Q3 2019 and the process flowsheet is based on an ore processing rate of 1.1 million dry tonnes per year (3,000 dry tonnes per day from underground mining) for the first three years, and 1.98 million dry tonnes per year (5,000 dry tonnes per day from both underground and open pit mining) for the remaining years at 92% process plant availability.To the end of 2015, more than 45 metallurgical test programs have been conducted on the Meliadine deposits. Based on the results of these programs, an optimal gold circuit was designed, comprising of crushing, grinding, gravity separation and cyanide leaching with a carbon-in-leach circuit (CIL), followed by cyanide destruction and filtration of the tails for dry stacking. The assumed gold recovery for the reserves averages 96.0% at a 7.44-g/t gold average mill feed grade."

Jan 1, 2016

By Xuexin Ding, Weijie Wei, Jinwang Zhang, Yi Chen, Shengli Yang

"Many ultra-thick coal seams exist in Xinjiang and the northern part of the Inner Mongolia. These coal seams are more than 30-40m thick. This kind of the thick coal seam is too difficult to extract in one slice, so the top-coal caving longwall mining method was designed for this purpose. In order to study the movement characteristics of the overburden strata and the development of the ""three zones"" in ultra-thick coal seams, the physical and numerical simulations were carried out based on the in-site condition of Baiyinhua coal mine. The result shows that, when extracting the upper part of the l 5m thick coal seams, the first weighting interval was 50-58m and the periodic weighting interval was I 8-20m. The caving zone, fractured zone and bending and sinking zone were 38m, 92m, and 50m respectively in height. The fractured zone height increased with the advancing distance of the face, but in some localities, a ladder-like distribution due to the periodic weighting existed. When extracting the lower part of the 25m thick coal seams, the roof was extremely broken and the collapse range of overlying strata continued to increase in irregular form.INTRODUCTIONThe thick coal seams occupy 44 percent of coal reserves in China and account for 45 percent of the gross domestic coal production. There are three main methods for extracting the thick coal seams: sublevel mining, large height mining, and longwall top-coal caving (LTCC) (Wang, 2009). Due to the rapid development of LTCC in the past two decades, it has become the most extensively used mining method. It possesses the advantages of high-production, high-efficiency, low development ratio, and low-cost (Yang, Zhang, Chen, and Zhengyang, 2016; Wang and Zhang, 2015). Baiyinhua coal mine's coal reserves are full of uniformly distributed thick coal seams, with the minable thickness of the main coal seam between 25 to 40m, i.e. the main coal seam is an ultra-thick coal seam. Sublevel longwall top-coal caving (SLTCC) which is an efficient method for extracting the ultrathick coal seams has led to multiple disturbances Xie, Chen, and Wang, 1999; Singh and Singh, 1999; Xie, Chang, and Yang, 2009. Therefore, using the case of Baiyinhua coal mine, the movement features of overburden strata and development characteristics of the three zones in ultra-thick coal seams were studied by physical and numerical simulations (Qian, et al, 2003; Qian, 1994)."

Jan 1, 2016

By Philippe Ribagnac, Bruno Courtaud, Jean-Marie Lambert, Valérie Weigel

Mabounié is a polymetallic deposit in Gabon containing niobium (1.2 wt.%), tantalum (0.03 wt.%), rare earth elements (REE) (1.4 wt.%) and uranium (0.03 wt.%) that are mostly carried by pyrochlore minerals. The classical route for niobium recovery is a pyrometallurgical process that consists of pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF. ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore (Donati, Courtaud, & Weigel, 2014). As for most of the oxidized ore processes, the major impurity is iron (~30 wt.%). Thus, in this hydrometallurgical process, the question arises of the elimination and stabilization of the iron as residue. The iron in solution is ferrous; goethite precipitation seems the most adapted crystalline form. Lab and pilot tests have shown kinetics of precipitation of 6 g.L-1.h-1 at pH 4.5. To reduce the salt discharge, sodium-jarosite form is more adapted, but at pH 2, 95°C only 30% of iron is precipitated in 5 hours, compared to 100% in goethite form at the same time and pH 2, 80°C. Different ways of oxidation were tested, air, pure O2, activated carbon, without drastic effect. The more efficient was ozone use, at room temperature; the kinetics of oxidation is five time faster than the other ways with 30% of sodium removed from the solution.

Jan 1, 2016

By M. Poirier, J. H. Mbouche

"The research question of the present work is the following: at which speed should a rotary sample divider operate in order to produce representative samples of iron ore concentrate? In order to solve this problem, the representativity of a rotary sample divider treating iron ore concentrate from Iron Ore Compagny (IOC) Carol Lake mine in Labrador City was studied in the laboratory of mineral processing of “CEGEP de Sept-Îles”. The rotary sample divider speeds tested are: 20, 40, 50, 60, 80 and 100%. The results show differences in both weight and particles sizes distributions with respect to the various rotation speed used. 20% has shown to be the speed that generates an almost normally distributed samples for both weight and particle size. As the speed of the rotary sample divider increases, the polygon of frequency for weight distribution progressively becomes a two modal distribution curve. 40, 50 and 100% speeds generate normal samples distribution curves with respect to particles size only. 60 and 80% are the speed to be avoided since they generate multiple modal distribution curves for both weight and particles size.IntroductionIn the mining industry, samples representativity is part of the key elements for management decisions. In fact, “Sampling provides vital information to plant operators, clients and geologists to profitably run and operate iron ore mines and plants” (Kevin Thorne et al. 2007). At the laboratory scale, several types of techniques’ are currently used to perform sampling. This include: grapping, alternate spading, quartering, riffles divider and rotating divider etc.. Among all these instruments, rotary divider is the most commonly used. Nevertheless, the usage of a rotary divider is not a guaranty for samples representativity since the results have shown to be related to running speed of this instrument. For the present research work, the idea is to use iron ore concentrate to quantify the representativity of a rotary sample divider. In other words, the research idea is to determine the speed at which a rotary sample divider produces representative samples while treating iron ore concentrate from Carol Lake mine. The present report will give an overview of the methodology used and the principal results obtained."

Jan 1, 2016

By G. Wang, L. R. Moore, Y. Xiong, A. Gorken

"Mining is a very water intensive industry. As such, the industry has become dependent on applying alternate sources in efforts to minimize the impact on the locally available fresh water. Sources such as recycled water, sea water, and even acid mine drainage have been applied at some limited applications, while other mines may not even have the option of fresh water available in their region. However, the different sources of water will have varying concentrations and types of soluble salts and suspended solids, which can lead to dramatic differences in mineral processing when comparing these types of waters. Water quality is known to affect bubble generation and strength, mineral surface charge, and even reagent coordination properties. This paper focuses on the exploration of how water quality and soluble salts affect the flotation of iron and titanium containing minerals from feldspar, and the design of flotation collectors for optimal performance in this water.INTRODUCTIONFeldspar is defined as a tectosilicate mineral with the generic structure of MAlxSixO8, where M represents the cation (Celik, 2001). Feldspar is most often found naturally occurring with quartz, iron containing minerals (i.e mica), and titanium containing minerals (i.e. rutile). The alumina component of feldspar is of interest to glass making, while the alkali metal component is of interest to ceramics (Vidyadhar, 2002). In glass making, the alumina is known to improve product hardness, durability, and resistance to chemical corrosion. In ceramics, the alkalis act as a flux; a flux lowers the melting temperature of the mineral mixture, and assists in connecting the other components present in ceramics. Quartz is stated as having a negative effect on the melting point of the feldspar. Although quartz is typically not removed during the feldspar applications in the glass industry, it needs to be reduced for the ceramics industry. Iron and titanium based minerals are known to have negative effects on color and quality of the products in both glass and ceramics. Thus, these “contaminants” must be reduced to a certain product specification via feldspar beneficiation (Table 1)."

Jan 1, 2016

By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016

By A. A. Lavrinenko, N. I. Gluhova, L. M. Sarkisova, D. V. Makarov

"The investigated sulfide Cu-Ni ores are characterized by low PGE contents and emulgated impregnations of pentlandite and palladium minerals in the main ore-forming mineral pyrrhotite, which hinders their selective separation, requiring a collective flotation of sulfides to concentrate, and hydrometallurgical processing. As revealed by studies of floatability of Pt-Cu-Ni ore in a mixture of butyl xanthate and chelating phosphorus containing reagents, the most effective additive is Aerophine 3416 (a phosphinates mixture) manufactured by Cytec. Using collective flotation with a butyl xanthate – Aerophine 3416 composite in the ratio of 1:3 has afforded to enhance the Pt, Pd, and Ni recovery by 13.6 %, 9.2 %, and 9.4 %, respectively. The optimal ratios of Aerophine 3416 to butyl collector for the collective flotation are the following: 1:1 for Pt and Pd and 3:1 for Ni. The effect of these reagents on the electrode potential and surface hydrophobicity of pyrrhotite, pentlandite, and platinum black has been investigated. The extraction UV spectrophotometry experiments demonstrate that DIBDTPI exists on the pyrrhotite surface mainly in the form of disulfide in weak acid medium and in the form of compounds with Fe on the mineral surface in minute amounts. There appears some disulfide and few amount of (DIBDTPI)2Ni on the surface after interaction of DIBDTPI and pentlanditeINTRODUCTIONXanthates are widely used in flotation of copper-nickel ores containing platinum group metals (PGM) as sulfides collectors which can concentrate the most part of PGM connected with the sulfides. Though xanthates are hardly efficient for flotation of free PGM, the latter are floated more slowly compared to the sulfides of base metals. The reasons for poor floatation of free (mineral) forms of PGM are under-researched, however the key accepted reasons are: fine disseminations of free PGM, insufficient interaction with xanthate and negative influence of blue copperas and sulfur-containing ions which are sulfides oxidation products (Penberthy et al. 1999; Shackleton et al., 2007). That’s why an additional collector, normally dialkyldithiophosphates, is used during flotation of PGM-containing copper-nickel ores. A reagent DP-4 is used for recovery of PGM at Norilsk mining and metallurgical plant. The reagent represents a slightly-soluble organic calcium sulfonate which is given to flotation pulp in the form of water emulsion of 5% - solution in automotive diesel oil."

Jan 1, 2016

By Mostafa Benzaazoua, Emilie Ré, Raphaël Mermillod-Blondin, Hassan Bouzahzah, Jean-François Wilhelmy, University of Québec in Abitibi-Témiscamingue

"We analyzed two copper and lead flotation concentrates from the LaRonde mill using MLA technology (Mineral Liberation Analyzer) to identify the contaminants and to quantify their size and liberation. The MLA mineral quantification was compared with traditional mineralogical techniques (Scanning Electron Microscopy, Optical Microscopy, X-Ray Diffraction and Chemistry). The accuracy of MLA data was then quantify in application to metallurgical decision (mineral identification, mineral quantification, particle sizing and liberation quantification). We prepared five well-known materials from pure minerals and analysed them by MLA. MLA concentrates analyses showed the lead concentrate is mainly contaminated by pyrite and sphalerite. These minerals are liberated above 70 % and present a floatable size around 15 to 35 µm. Surface activation by dissolved lead from galena is therefore assumed for these contaminants. The analyses of the known samples show that mineral quantification and size distribution given by the MLA are consistent with the chemical analyses and the laser particle sizer. The liberation measurement is affected by the stereological effect. Modelling quantifies the overestimation of the particle liberation. Based on the modelling, the stereological shift on liberation should not impact metallurgical conclusions on the concentrate contaminations.INTRODUCTIONTo face the diversity of mineral processing challenges, the process mineralogy includes phase quantification, measurement of mineral size, liberation by exposure and by grade, association, surface contact proportion and texture. In the last decades, two SEM commercial tools emerged: MLA and QEMSCAN R. Both are based on specific combinations of backscattered electrons and X-ray images as well as image analysis routines developed at CANMET (Petruk & Pinard, 1976, Petruk, 1989), CSIRO (Frost, O'Hara, Suddaby, Grant, Reid, Wilson & Zuiderwyk, 1977, Reid, Gottlieb, MacDonald, & Miller, 1984) and JKMRC (Hall, 1977, Gu & Sugden, 1995). Recently, TIMA (TESCAN) and Mineralogic MiningR (ZEISS) supplied automated mineralogy for mining industry (Bouzahzah, Benzaazoua, Graham & Cropp, 2015, Gottlieb & Dosbaba, 2015a). In parallel, home-made routine were developped to resolve mineralogy challenges in mineral process but also in geometallurgy and mining environment (Kahn, Mano, & Tassinari, 2002, Knight, Klassen & Hunt, 2002, Mermillod-Blondin, Benzaazoua, Kongolo, de Donato, Bussiere & Marion, 2011, Hunt & Bradshaw, 2015). SEM mineralogy become essential to operation by setting units on mine sites (MacDonald, Latti, Adair, Bradshaw, & Dunn, 2011, Goergen et al., 2013, Dobbe et al., 2014, Gottlieb & Dosbaba, 2015b)."

Jan 1, 2016

By Masashige Makifuchi, Hiroki Kumakura, Kota Nagai, Takahiro Kikuchi

"A large amount of platinum group metals (PGM) are used in automobile catalyst. It is important to recover the metals from wasted catalyst. Nomura and Kageyama (2013) suggested recovery process that PGM oxides were absorbed to perovskite-type oxide based on LaScO3. In their process, the PGM in wasted catalyst as absorbed to the perovskite-type oxide as PGM oxide. It has potential to each element in the process if the perovskite-type oxide is selected properly. In this study, the PGM oxide absorption properties of various perovskite-type oxides are investigated to develop a new recovery and separation process. The various perovskite-type oxide were synthesized with metallic platinum, palladium, rhodium at high temperature in air atmosphere. And the PGM contents in the perovskite-type oxide after the experiment are determined by chemical analysis. Some of them have the properties to absorb specific PGM oxide selectively. In addition, in order to increase the amount of absorption of PGM oxide and composition of the perovskite-type oxide experimental temperature was investigated. Then it is also found that doping another specific element to the perovskite-type oxide is effective to increase the amount of absorption of PGM oxide. Then a new recovery process of PGM from wasted automobile catalyst, in which PGM can be separate to each element, was designed.INTRODUCTIONA large amount of Platinum (Pt), Palladium (Pd), and Rhodium (Rh) are used in automobile catalysis (Figure 1) (Platinum, 2013). Natural supplies for these metals are limited and PGM mining can detrimental environmental impact. Therefore, the recycling of PGMs from wasted automobile catalysis is very important. The Rose process (Figure 2) was developed as a process to recover PGM from wasted automobile catalysis. In this process, the automobile catalysis is first crushed mechanically, and then extracting agent, copper (Cu), and flux are melted at high temperature. The mixture separates into a metal phase, (Cu alloy containing PGM) and slag. The PGM is enriched by oxidizing. Cu to Cu oxide. The PGM are then recovered and separated to each element in a wet process. However, it is hard to dissolve the PGM with acid because they are chemically stable and strong oxidation agent such as aqua regia is used. Moreover, to separate the PGM to each individual element, a solvent extraction process is required."

Jan 1, 2016

By Curtin University Western Australian School Mines

"Curtin University’s Gold Technology Group has developed an online CIP/CIL simulation model called SIMCIL which has been used since 1999 to model and simulate industrial leach-adsorption circuits. Recently the model has been upgraded to include an integrated liberation-leach modelling (ILLM) approach which can be used to evaluate the impact of various process parameters (such as grind size, bleed to gravity etc.) and circuit configurations on leach-adsorption circuit behaviour and overall plant gold recovery. A new time-efficient ore characterisation methodology has been researched and developed to provide the required liberation-leach data used in the ILLM approach, which is implemented online for the modelling of gold operations. The model structure, modelling approach, and some scenarios are discussed.INTRODUCTIONCurtin University’s Gold Technology Group has developed an online CIP/CIL simulation model called SIMCIL which has been used since 1999 to model and simulate industrial leach-adsorption circuits. The model has recently been upgraded to include an integrated liberation-leach modelling (ILLM) approach. The ILLM approach provides the means to evaluate the impact of the gravity recoverable gold (GRG) characteristics of the ore (GRG content and liberation behaviour), various process parameters (such as grind size, bleed to gravity, etc.) and circuit configurations on the gravity gold recovery, leachadsorption circuit behaviour and overall plant gold recovery.A new time-efficient ore characterisation methodology has been researched and developed to provide the required liberation-leach data used in the ILLM approach. The data required for the ILLM calibration can be obtained directly from the 3 stage GRG test, leach tests and size-by-assay analysis of the 3 stage GRG test products, and leach test products.This paper describes the ore characterisation methodology, model structure, modelling approach, and the application of the ILLM."

Jan 1, 2016

By Jun Ho Lee, Dae Young Kim, Ebrahim Farrokh, Ki Chang Hyun

"The Jinhae Geoje gas pipeline tunnel project is the largest (7.8 km) and the deepest (90 m) subsea tunnel in South Korea. This tunnel will house a pipeline to carry natural gas from the mainland to Geoje Island southeast of the country to alleviate the increased demands for natural gas, especially in the winter season. Tunneling is currently underway using two slurry shield TBMs of 3.5 m diameter. This paper describes the major design elements of the tunneling machines and their performance evaluation. For this purpose, a thorough analysis of geotechnical information was performed to evaluate the tunnel elevation to reduce the risk of tunneling under high water pressure in unstable and permeable rock mass under 9 bar water pressure. TBM specification and TBM performance were also analyzed using different methods, including well-known models as well as a rotary cutting machine test developed in house in Hyundai Engineering and Construction Company. INTRODUCTION High demand for natural gas, especially in winter season was the primary driving factor for the design of the Jinhae Geoje gas pipeline project. This project is located southeast of South Korea between Jinhae district and Geoje Island and runs for over 50 km length. The mid part of this project includes a 3.5 m diameter subsea tunnel consisting of two sections of Geoje to Jiri Island (4.3 km) and Jinhae to Jiri Island (3.5 km). Figure 1 shows the tunnel project location and its layout. Figure 2 shows the geological profile along the tunnel. As can be seen, the tunnel passes mainly through three rock types: granite, tuff breccia, and andesite tuff. This tunnel was planned to be constructed by two face pressurized shielded TBMs and to be lined with a segmental lining of 2.8 m internal diameter. The major challenge for this tunnel is its maximum expected water pressure at the tunnel invert (8.83 bar). At such a high water pressure, the TBMs required special design to ensure they can handle unexpected water pressure and to ensure the risks for the TBM maintenance intervention are minimal. In this regard, a thorough analysis was conducted on the TBM design parameters and geotechnical information to define required TBMs’ design parameters and to identify the safest tunnel elevation. This paper provides a brief overview of the project geotechnical information, TBM selection and its design specification, tunnel elevation selection, and TBM penetration rate evaluation. In this regard, a rotary cutting machine testing equipment was used to perform trial tests on a similar rock type encountered along the tunnel for performance evaluation and optimization."

Jan 1, 2016

By David Brown, Adrian St. John, John Comins, Mike King

"INTRODUCTION The Crossrail project provides an East-West link across London enabling an additional 200 million journeys each year linking up major business centres and existing transportation interchanges, while reducing congestion at street level and within the current underground system. The project has built major structures in Sprayed Concrete Linings (SCL), including 5 new stations, 6 crossover caverns and numerous passages, adits and ventilation tunnels. Construction has taken approximately 4 years, and has involved the spraying of over 200,000m3 of concrete. At the start of the project there was a lack of available records from previous projects concerning concrete falls, which hindered risk assessments and the ability to make meaningful comparisons around spraying or material performance. This paper redresses this lack of data by providing information on falls experienced on this project and makes recommendations to assist future projects. Construction Methods Table 1 below summarises the main contracts with elements of permanent SCL. The listed primary lining lengths include pilot tunnels, side drift tunnels and enlargements as separate tunnels.A range of construction sequences were used in order to deal with the design requirements, geometry, and the ground and ground water conditions. The following briefly summarises the build up by layers, with typical design dimensions provided for a platform sized tunnel (approximately 9m internal diameter), excluding tolerance allowances. Some linings were sprayed in more than one layer to allow for inclusion of reinforcement layers or to avoid a too aggressive build-up of thickness: •,Initial shotcrete, or sealing, layer (ISL) of 75mm followed by a Primary Lining (PL) of 300mm. •,Regulating layer of 40mm followed by a Waterproof membrane (Sprayed membrane, 3-6mm). •,Secondary lining (SL) of 250mm with a separate sprayed fire protection layer (FPL) of 50mm."

Jan 1, 2016

By Wei Huang, Anh V. Nguyen

"Potash flotation is an industrially proven success of flotation of soluble salts, but its collector adsorption mechanism remains elusive. In this paper, specific ion effects in NaCl-KCl flotation with carboxylate collectors were investigated. Flotation recovery and contact angle were determined as a function of brine composition of NaCl and KCl. The experimental results have shown that wettability of KCl and flotation of the soluble salts with laurate collectors were dependent on brine ion composition. Specifically, adding Na+ to brines decreased hydrophobicity of KCl crystals and their flotation recovery. Both KCl and NaCl could be floated with laurate collectors. However, flotation of NaCl was greatly enhanced by adding K+ to brine whereas flotation of KCl was significantly suppressed by the presence of Na ions. The decrease in KCl recovery upon adding Na+ is attributed to the counter-ion binding in the pulp. The flotation recovery enhancement of NaCl in the presence of K+ is explained by two effects: 1) increasing K+ concentration leads to a better dispersion of collector colloids in the pulp and 2) K+ enhances the collector adsorption at NaCl crystal surfaces. The water affinity matching rule can explain the specific ion binding behaviors and supported by the SFG spectroscopic results.INTRODUCTIONPotassium is an important fertilizer. Its primary source comes from potash ores, which are a mixture of sylvite (KCl), halite (NaCl) and many other complex double salts such as carnallite (KCl·MgCl·6H2O), alkali nitrates such as KNO3 and NaNO3, and sulfates-langbeinite (2MgSO4·K2SO4) with water-insoluble minerals such as clay and carbonate minerals. Previously, these salts were recovered with a lengthy hot leaching method, with further crystallization of potassium salts from saturated saline solutions. Selective flotation has been preferred since 1940s. Various collector adsorption mechanisms have been proposed soon after the industrial introduction of potash flotation. These include the formation of the insoluble compound model (Halbich, 1933; Singewald, 1961), an ion exchange model (Fuerstenau and Fuerstenau, 1956), a heat of solution model (Rogers, 1957), the surface hydration model (Schubert, 1988), the surface charge model (Roman, 1966; Miller et al., 1992), the interfacial water structure model (Hancer and Miller, 2000) and the colloid adsorption model (Leja, 1983; Burdukova and Laskowski, 2009). Most of the early exercises attempting to propose a unified rule on collector adsorption mechanisms can be seen as heroic endeavors due to the consideration of a vast number of salts in the pulp including alkali halides, nitrates, and sulfates, even the practically insoluble heavy earth metals. Additionally, several types of surfactants with different polarization features and alkyl chain length have been employed. As for the recent models, due probably to the preferential application of long chain amines as collectors in industrial potash flotation, most researchers are only devoted to collectors with low polarization features like amines and sulfonates (Hancer and Miller, 2000; Du et al., 2014). Collector adsorption mechanisms are therefore proposed based largely on a neglect of carboxylates as collectors. However, carboxylates remain an important collector type in soluble salt flotation systems where both salt minerals can be floated using anionic collectors and cationic collectors. Fatty acid type collectors are still one of the widely used collectors for soluble salt flotation and also one of the first to be applied on an industrial scale for the separation of potash ore (Hernáinz et al., 2003; Titkov, 2004). Here we examine some recent models that are relevant to our study to reveal a long neglected specific ion binding effects in potash flotation."

Jan 1, 2016

By L C. Taylor

Both the U. S. Navy and the U. S. Army are interested in knowing more about the loading applied to vehicles which are unfortunate enough to encounter a detonation of a buried mine in the course of performing their normal duties. The Dynamic Effects Laboratory at the University of Maryland has been involved in small scale testing for ten years to assist the Navy and the Army in understanding the loads that are applied to personnel carriers when a buried explosive detonates beneath them. This paper describes results from small scale tests conducted to determine the loading mechanisms on target plates when subjected to loading due to the detonation of a buried mine in saturated sand, dry sand, and water. Transparent target plates were utilized in order to determine the loading process beneath a floor board on armored vehicles. Various charge sizes were scaled in the laboratory accordingly to a standardized full size threat encountered in the battlefield. Tests were conducted in saturated sand, dry sand, and water keeping the stand-off distance of the target and the depth of burial of the charge constant. In the case of water impacting a transparent PMMA plate the crack propagation was recorded and the crack velocity is determined. Additional tests were performed in saturated sand by varying the stand-off distance of the target but keeping the depth of burial of the charge constant. The small-scale test results could be scaled to full scale by using verified scaling laws.

Jan 1, 2016

By J. Shibata, K. Manabe, A. Fuji, N. Matsunaga, D. Murakami, Yamaguchi University, T. Suzuki

"Spent hydrodesulphurization (HDS) catalyst contains rare metals such as cobalt, nickel (Ni), molybdenum (Mo), and vanadium (V). The overall objective of this project is to develop a hydrometallurgical process that provides a degree of high recovery and selectivity of these rare metals from spent HDS catalyst. As a part of this project, this study focused on (i) development of a solvent extraction-precipitation stripping process for separation of Mo and V from solutions and (ii) optimization of grinding conditions of alkaline leaching residue for selective Ni sulfuric acid leaching against aluminum (Al). Experimental results showed that effective separation between Mo and V can be achieved by the two-stage process; solvent extraction of Mo and V with TOA (tri-n-octylamine) and precipitation stripping of V with ammonium salt at pH above 8.0. Regarding grinding conditions of alkaline leaching residue for selective Ni leaching against Al, it was found that Ni leaching efficiencies increased by providing higher grinding intensity, while the Al leaching efficiency increased and then decreased with increasing grinding intensity.INTRODUCTIONHydrodesulphurisation (HDS) catalysts account for about one third of the total worldwide catalyst consumption and are extensively used for sulphur removal in petroleum refineries (Zeng & Cheng, 2009). Fresh HDS catalysts generally contain molybdenum (Mo) and nickel (Ni) on an alumina carrier, but various elements included in the crude oil such as sulphur, carbon, silica, arsenic, cobalt, and vanadium (V) deactivates HDS catalysts during HDS reactions. As a result, spent HDS catalysts contain high concentration of rare metals. For example, regarding to Mo and V, it has been reported in the literature that the concentrations of Mo and V in the general spend HDS catalysts are generally 10-30% and 1-12%, respectively (Zeng & Cheng, 2009), which makes it economically viable to recover these rare metals (Biswas et al., 1986).Among a number of processes proposed for the recycling of rare metals from spent HDS catalysts, alkaline leaching is often used for selective Mo and V leaching (Zeng & Cheng, 2009). However, the process which provides a high degree of separation between Mo and V from a leaching solution had not been developed. Therefore, the first objective of this study was set to develop a solvent extraction-precipitation stripping process for the separation of Mo and V from solutions. More specifically, using artificial aqueous solutions of Mo and V, a series of experiments was performed to optimize the extraction pH, stripping agent, and the stripping pH."

Jan 1, 2016