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By Rainer Antretter

"THE CHALLENGE The 14km long, Arlbergtunnel, closed for public traffic during summer 2015, receiving a comprehensive and substantial renovation from 2015 to 2017. The main works discussed here, carried out during 2015, comprise 37 drill and blast SEM/NATM emergency escape tunnels from road level to the ventilation duct plenum have to be constructed as well as eight additional lay-by niches and three transformer tunnels. This presentation comprises the construction ventilation design, designed according to national regulations, suitable for 150 employees working 24/7 simultaneously at more than 40 single working sites lined up along the tunnel. The ventilation-system chosen was utilising two existing shafts for intake/discharge and a cross passage to surface, to handle a total fan power of 1.600kW. DESCRIPTION OF RENOVATION WORKS Linking Tyrol and Vorarlberg, two Federal States of Austria, the Arlbergtunnel is a single tube two-way road tunnel with vent duct plenum, constructed in the mid-1970s. According to latest EU legislation, additional escape exits have become obligatory. The existing seven cross passage links to the adjacent Arlberg Railway Tunnel, with average spacing of about 1.500m constructed in 2007, an additional upgrade to shorter escape spaces of approx. 400m was now required to comply with the updated legislation. Additional transformer tunnels, lay-by niches and small niches for emergency maintenance use, cleaning and other purposes, as well as a the installation of a new fire main in the invert, coupled with the simultaneous replacement of virtually the entire power and signaling cables, generated several dozen small and large single sites distributed along the 14km of tunnel.Purpose of the 37 walkable emergency escape tunnels is to reach the “upper deck” of the Arlbergtunnel, the vent duct plenum. These have an 180deg curve in plan, inclined at 10% and approx. 60m (65yd) long tunnels, excavated using drill and blast method starting from road level and working upwards to the level of an “intermediate soffit”, the vent duct plenum in the crown of the tunnel. The vent duct plenum is separated into a fresh air part and an exhaust air part, shown in Figure 1. The escape tunnels end with a pressure door in the fresh air section of the ventilation duct plenum. From there illuminated signs show the shortest escape route to the safe area between the road tunnel and the railway tunnel, as shown in Figure 2."

Jan 1, 2016

By M. Raffaldi, J. Johnson, M. Stepan, D. Benton

"The Office of Mine Safety and Health Research (OMSHR), Spokane Mining Research Division (SMRD), is continuing its High-Energy High-Displacement (HEHD) testing of field-scale shotcrete panels. A test program was developed to determine the relationship between applied force, displacement, and energy for both unreinforced and reinforced shotcrete panels. Reinforcement options consisted of synthetic macro-fibers, sprayed polyurea liners, chain-link fence, welded-wire mesh, and combinations of these products. During testing, photogrammetry was used to measure the geometric changes of the panels, including volume changes and panel cracking. These measurements were correlated with the load and displacement data, allowing visual observation to be related to the applied force and displacement. The test results provide a comparison of the mechanical performance of the various panel types and can be used by the practicing engineer to evaluate installed support based on visual observation of cracking and deformation. Visual assessment of the loading cycle and strength capacity of shotcrete in underground excavations will improve mine safety by providing a means to quantify the stability of installed shotcrete support. INTRODUCTION The National Institute for Occupational Safety and Health (NIOSH), Office of Mine Safety and Health Research (OMSHR), Spokane Mining Research Division (SMRD) is continuing research on the behavior of shotcrete when used as the surface support component in mining ground support systems. Ground control safety often depends on supporting, or at least containing, the ground between the rockbolts. Shotcrete and mesh, in various combinations and with other components, are often used to accomplish this (see Figure 1). Maintaining support pressure during ground deformation is key to the performance of these systems, and to ensuring miner safety. However, the toughness of a ground support system–the ability to maintain strength over large deformations–is difficult to quantify. Researchers at SMRD have responded to this deficiency by designing a full-scale test device, described previously by Martin et al. [2015a], and beginning a testing program to assess the behavior of shotcrete surface support reinforced with a variety of products including: fibers, chain-link mesh, welded-wire mesh, spray-on polyurea liners, and combinations of these products. This paper presents the findings of these tests."

Jan 1, 2016

By Christoph Schulte-Schrepping, Bou-Young Youn, Rolf Breitenbücher

"The main requirements of two-component grouts are a high workability and sufficient stability against sedimentation with a retention time of more than 72 hours, as well as a rapid strength development im-mediately after grouting. Component A usually consists of OPC, water, bentonite, and retarding agent. Component B, a liquid accelerator, is added to Component A during grouting at the end of the shield tail. Current investigations on different compositions of Component A showed a high workability lasting for at least 72 hours. The workability could be extended with increasing amount of the retarding agent to a certain degree. An increase of the bentonite content improved the stability of the mix, but had a negative impact on the flowability respectively the workability of Component A. High compressive strengths could be rather achieved by an adapted mixing ratio of Component A and B than by increasing the amount of the accelerator. Thereby, the interactions and compatibility of the selected constituents play an essential role. INTRODUCTION In mechanized tunneling with segment linings, the annular gap between segment ring and soil must be filled instantaneously with an adequate grouting mortar. The main functions of the annular gap grouting are to stabilize the tunnel lining and to minimize settlements of the ground surface at the same time. Thereby, two contradictory requirements are demanded on annular gap grouts: On the one hand a high workability and sufficient stability against sedimentation, on the other hand a rapid strength develop-ment immediately after grouting. Besides single-component grouts, which achieve the necessary stiffen-ing by dewatering into the surrounding soil, two-component grouts are used, especially in cohesive soils with a very low permeability. Basically, annular gap grouts are almost exclusively defined on empirical basis. Fundamental studies about the constituents and composition of the grout as well as the related achievable properties are still missing so far. Therefore, it is necessary to investigate the material-specific correlations regarding the relevant parameters of annular gap grouts – workability and flowability, stability of the mix as well as strength development – in comprehensive experiments. Based on the knowledge gained from the investigations, it should also be possible, to perform the grouting material according to a real design concept and thus, to ensure an adequate grouting in prac-tice considering the geological and hydro-geological conditions."

Jan 1, 2016

By M. Maccagni, J. Nielsen

"Engitec developed the EZINEX® Technology some years ago to recover zinc from oxidized secondary sources. This process works at neutral pH and can take into solution any kind of metal, but iron is rejected and remains in the leach residue. Engitec has also developed the FLUOBORATE System, which is able to recover lead and copper from relevant concentrates. Some iron is leached into solution, but it is controlled through a solution purification bleed treatment. In this paper, we present the two above mentioned technologies. They are very different with regards to the chemical environments and the methods used to control the build-up of iron in solution, but both systems are suitable to treat iron bearing feeds.INTRODUCTIONIn the design of hydrometallurgical processes, the most important issues are the water balance, the filtration and the control of impurities. This is particularly important when the process includes an electrowinning unit. Iron has been one of the most problematic elements to remove, especially in acidic environments.Engitec Technologies has developed several hydrometallurgical processes divided in two different electrolyte lines: the Fluoborate Technology for the recovery of lead and copper from primary and secondary sources and the Ammonium Chloride System based on a chloride electrolyte for the recovery of different non-ferrous metals, among which zinc and lead are the most important. In both cases, iron is present in the feed and needs to be eliminated from the solution. It is not a problem for the quality of the metal produced, but when present in solution, it consumes the basic electrolyte reducing its free concentration which is very important both for both the leaching and electrowinning unit operations. Both process systems are very peculiar, the fluoborate case being much more intriguing."

Jan 1, 2016

By Verya Nasri, Kevin Akbarpour, Hiva Mahdavi

"The Sheppard East Light Rail Transit (SELRT) project comprises approximately 13 km of new light rail, which will be constructed along Sheppard Avenue East in Toronto. There is a 380 metre long section of the route that will be constructed as tunnel below Highway 404, which is owned by the Ministry of Transportation Ontario (MTO). MTO has published guidelines for tunneling under its highways. An impact analysis was undertaken to predict the surface settlement and angular distortion of Highway 404 resulting from the construction of the twin tunnels. The results were then compared to the performance criteria defined in MTO’s guidelines. As a result of this analysis, it was necessary to request an adjustment to MTO’s current performance criteria. This paper presents details and results of the impact assessment, approaches taken to satisfy the requirements defined by MTO, and provides details of the adjustment permitted by MTO. INTRODUCTION Several major rapid transit projects are planned for the Greater Toronto and Hamilton Area (GTHA) located in southern Ontario, Canada. These projects are part of The Big Move (Metrolinx 2008) initiative, a 25-year, and $50 billion plan aimed at improving regional transportation. Metrolinx, an agency of the Government of Ontario, is now working collaboratively across the region to deliver major Toronto rapid transit projects to the GTHA. One such project is the SELRT. The line will largely run along Sheppard Avenue East on the surface, except for a crossing of Highway 404 where it will be constructed using a combination of open cut and bored tunneling methods. AECOM has been retained by Metrolinx as the Technical Advisor (TA) to develop the Reference Conceptual Design (RCD) and Project Specific Output Specifications (PSOS) for the project. Also, Infrastructure Ontario (IO) is the Co-Sponsor and CH2M HILL is Metrolinx’s Owner’s Engineer (OE) & Project Management Support (PMS) for the new LRT lines. This paper presents information on the tunneling settlement analysis and further work undertaken to satisfy the MTO’s requirements."

Jan 1, 2016

By L. J. Bryson, C. A. Biley

"Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) produces Ni and Cu cathode from slow cooled converter matte after Platinum Group Metals (PGMs) are magnetically separated for further processing. In 2010, execution of the RBMR expansion project was commenced to increase the production capacity to 33 ktpa Ni. The expansion, which is currently still in a ramp-up stage, brought about several fundamental changes to the circuit chemistry, including the installation of a dedicated Pressure Iron Removal (PIR) autoclave. This provided an independent outlet for iron from the refinery, which previously deported to the residue from the leach circuit and was toll refined. At the same time as changes in the circuit associated with the RBMR expansion were being made, the plant experienced a significant increase in iron and copper units per nickel unit in the feed. The decoupling of the leaching and iron removal process steps has had significant advantages for the robustness and control of the overall circuit, in particular pertaining to the preparation of a nickel electrolyte of sufficient purity to produce LME grade nickel. This paper details the primary changes to the RBMR circuit chemistry with a particular focus on iron deportment and the benefits derived from the installation of the PIR autoclave.INTRODUCTIONAnglo American Platinum mines and refines Platinum Group Metals (PGMs) through a complex processing pipeline in its South African operations. Mined ore is first treated through several mineral processing stages, geared to the recovery of base metals and associated PGMs, followed by smelting and refining operations that aim to separate base metals from PGMs and recover the value components to purified, saleable products. The focus of this paper is the Rustenburg Base Metals Refiners (RBMR) complex which receives a PGM-containing converter matte, then physically separates PGMs and base metals, and recovers nickel and copper to cathode by utilising leaching, precipitation and electrowinning processes.With new mining operations coming online and the continued increase in PGM ore arisings, it was necessary to undertake an expansion project at the Base Metal Refinery (BMR) to increase production capacity from 21 ktpa to 33 ktpa Ni. Complicating the expansion project was the requirement of continued production through all stages of design, construction and implementation and, due to stringent capital constraints, the utilisation of all existing equipment installed during a previous expansion in 1981. Against this backdrop, the expanded BMR flow sheet involved significant changes to the chemistry, especially iron management. These changes in iron management allowed for the separation of iron and copper residues and significantly increased the robustness of the plant to changes in feed mineralogy as well as the potential to increase production duties of the existing equipment."

Jan 1, 2016

By C. Birch

"A mineral resource royalty is payment to the holder of mineral rights for the utilization of the mineral resource. In South Africa, this payment is made to the State as holder of the mineral rights (The Mineral and Petroleum Resources Royalty Act of 2008). The principle purpose of this research paper is to identify if the State is benefitting from the mineral resource royalty by considering its impact on seven individual Witwatersrand gold mines.For this study, a simple financial optimiser model was created in Microsoft Excel that links the ore flow, block listing and the cash flow (excluding or including the cost of the mineral resource royalty). Mixed integer linear programing (the Excel Solver function) is utilised to optimise either profit or NPV (at 9% and 12%) by adjusting the cut-off grade.The impact on each of the seven mines mine was different but overall R7.9 billion is estimated to be paid in mineral resource royalty over their expected remaining lives. Due to the cost of the mineral resource royalty and increasing the cut-off grades, the total revenue decreases by R10 billion. A significant portion of this lost revenue would have been paid to the State in the forms of other taxation including company income tax which decreases by R2.8 billion. It is recommended that an industry wide investigation be conducted to determine if the resource royalty is adding to the State’s revenue, or destroying value including premature job losses. IntroductionTaxation of mining companies has become a very topical subject in the context of the postapartheid South African economy. There have been increasing calls for equitable re-distribution of mineral asset wealth for the benefit of all South African citizens and not just to an elite few. As part of the Mineral and Petroleum Resources Development Act (MRDPA) of 2002, the Mineral and Petroleum Resources Royalty Act of 2008 was introduced and came into effect in 2010 (South African Revenue Services, 2008). A mineral royalty is payment to the holder of mineral rights for the utilization of the mineral resource. In the case where the holder of the mineral right is the State, then this payment is made to the State (Cawood, 1999). Studies on the potential impact of the mineral resource royalty on the minerals industry have been conducted during the formulation of the Act and subesquently. These include Cawood and Macfarlane (2003), who suggested a cap of no more than 3% (Cawood and Macfarlane, 2003), as well as Cawood (2011), who predicted rising cut-off grades and thus reducing mineral reserves. In 2013, Grobler completed a Masters in the Faculty of Economic and Management Sciences at the University of Pretoria and concluded that the impact of the mineral resource royalty on the economy is positive. She stated that the royalty has caused operating expenses to increase, but this does not appear to be significant. Furthermore, she stated that the royalty has not affected the way the mining industry operates (Grobler, 2014)."

Jan 1, 2016

By Uli Leiste

Two papers are presented which examine Air Deck Blasting, one from a computational aspect and the other from a shock aspect.

Jan 1, 2016

By Troy Williams, Chris Preston, Ian Lipchak

"Underground blasting operations are challenging from the standpoint of the distribution of explosivesenergy representative of ring blasting. Energy from both shock and pressure regimes of commercialexplosives may appear concentrated in the collar region of a typical ring blast and diluted at the toes of holes due to the oblique geometries of blastholes. The non-homogenous nature of ore in whichexplosives are distributed via drillholes, adds to the complexities of generating particulate profiles from fragmented material with consistencies that are predictable from blast pattern to blast pattern - well suited for specific underground handling equipment and mill processing. In an ideal world, it would be the blasting operations themselves that represent the primary crushing mechanism, or at least mitigate mechanical crushing that can comprise a large component of the cost in generating suitable muck. This paper presents a dynamic break view in 3D that allows a planner to visualize the potential break zone around a blasthole generated by an explosive load using a Kleine field. Simple as it sounds, this methodology provides information that can be used in conjunction with cavity monitoring surveys (CMS) to potentially judge dilution due to overbreak as well as recovery for a typical blast. As examples, there are two break geometries that are examined regarding circular breaks and elliptical breaks around blastholes. Using a Kleine field to define break, a planner generated isosurface can be generated and compared to CMS data for calibration and prediction, using AEGIS 3D ring design software."

Jan 1, 2016

By R. C. Gilmore, S. A. Lolon, G. E. Bogin, S. A. Saki, J. F. Brune, J. W. Grubb

"Gob ventilation boreholes (GVBs) are widely used in underground coal mines for longwall gob degasification purposes. GVBs are often drilled within 10 to 30 m above the top of the coal bed into the fractured zone, completed with 20 cm (8 in.) diameter casing and 60 m of slotted pipe at the bottom. The purpose of this completion strategy is to create a pressure sink to capture the emissions before they can enter into the underground workplace. For GVBs to work effectively, they must be drilled close enough to the working areas to capture methane from the fractured zone while the setting depth must be kept above the caved zone to minimize the amount of ventilation air that is drawn into the GVBs. Well completion parameters are important for creating safe working conditions. In this paper, computational fluid dynamics (CFD) studies will be presented to analyze the effect of different practices for GVBs completion parameters for methane extraction, formation of explosive gas zones in the gob and methane concentrations at the longwall face and tailgate. Authors have identified the optimum completion parameters for GVBs, which can maximize the benefit and minimize fire and explosion risk. INTRODUCTION Coal mines may be considered gassy based on the presence of CH4. Gas from the mined coalbed or from rider seams above or below the mined coalbed can migrate into the gob and then potentially move towards the working areas. In longwall coal mines with high methane emissions, sufficient ventilation and additional methane control measures are usually required to reduce the methane concentration in working areas to below statutory levels. Several techniques or combinations of techniques are available to control the methane hazard. These may include mine face ventilation to dilute methane, coal bed degasification, nitrogen injection into the gob to render a methane atmosphere inert and the use of gob ventilation boreholes (GVBs). Longwall face ventilation and dilution alone can only handle methane emissions up to a certain amount. When methane emissions exceed the face ventilation capacity, additional control measures are required. Drilling horizontal or vertical methane drainage holes into the coal seams as well as gob ventilation boreholes from the surface into the gob area to extract methane are common practices. GVBs are usually drilled from the surface above the longwall panel ahead of mining. When the face moves outby the GVBs and the gob begins to form, methane production starts from the boreholes. It is important to control the performance of GVBs to maintain a safe working environment in the mine. The performance of GVBs depends on multiple factors, including borehole location, length and diameter of slotted casing, setting depth of casing above the coal seam being mined, wellhead vacuum pressure, and permeability of caved-fractured zones."

Jan 1, 2016

By C. Dodds, R. S. Ferrari-John, The University of Nottingham, G. Dimitrakis, J. Katrib, A. R. Batchelor

"Sorting technologies have the potential to reduce energy use in comminution by rejecting uneconomic ore before feed material enters the mill. However, a major challenge for sorting porphyry copper ores is providing a basis of discrimination between valuable and non-valuable fragments, due to their complex mineralogies and textural features. Microwave heating in combination with infra-red detection (MW-IR) has been shown to provide upgraded feedstock for certain ores at bench scale. Selective heating of copper sulphide minerals compared to the gangue leads to an increased thermal response for valuable fragments, providing the basis for sorting.Rapid scale up of MW-IR from bench scale to a 100 t/h continuous pilot plant facility has been facilitated by the design of microwave choking structures to allow continuous operation at industrially meaningful throughputs, whilst meeting health and safety and electromagnetic compliance standards, and the integration of materials handling with electromagnetic systems.Laboratory batch testing on a pilot scale microwave system has been undertaken to investigate the thermal response of copper ores under industrial conditions, at microwave energy inputs up to 1 kWh/t. These results provided the operating window and recommended test conditions for the continuous pilot plant. Sortability curves predicted in the laboratory are in good agreement with separations achieved during continuous pilot plant operations. The potential microwave sortability of a number of ores has been studied, allowing informed decisions to be made about potential ore candidates based on mineralogy. Future development of the technology will be underpinned by the creation and validation of scale up concepts for 1000 t/h operations. Understanding the value proposition for individual sites/applications will be central to unlocking the potential economic and environmental benefits of microwave sorting."

Jan 1, 2016

By T. Qiu

"The purpose of this study is to investigate the effect of the dosage of sodium hypochlorite as activator on the flotations of depressed marmatite and depressed chalcopyrite, with a focus on activation-flotation kinetics. Four flotation kinetic models were applied to test data using 1stOpt statistical analysis software to estimate the relationships between the maximum flotation recovery rates for the depressed marmatite and depressed chalcopyrite, the flotation rate constants and the sodium hypochlorite dosages. Within the range investigated, the highest flotation performances of depressed marmatite and depressed chalcopyrite were obtained at 2.5 mL/L sodium hypochlorite with zinc recovery rate of 93.8 percent and 3 mL/L sodium hypochlorite with copper recovery rate of 94.6 percent, respectively, after four minutes of flotation. A second-order model with rectangular distribution of flotabilities gave the best fit to test data collected at various sodium hypochlorite dosages. For the highest flotation performances of depressed marmatite and depressed chalcopyrite, the respective equations of their flotation models were derived and presented.IntroductionCyanidation tailings are the solid residues generated by gold plants that use cyanide to extract gold (Lv, Ding and Qian, 2015; Zhang, Li and Yu, 2013). Because of increasing demand for gold, the Chinese gold industry has developed rapidly, with production amounting to 451.799 tons in 2014, an increase of 5.5 percent from 2013. Chinese gold production has been the highest in the world for eight consecutive years. As a result, more than 2.45 million tons of cyanidation tailings are estimated to be discharged into tailings ponds every year (Li et al., 2010; Lv, Ding and Qian et al., 2015; Wang et al., 2015; Zhang, Li and Yu, 2013; Zhang, Li and Yu, 2012), and approximately 300 million tons of cyanide tailings are stockpiled in China, with the potential to cause serious environmental pollution as well as death to wildlife (Adams and Lloyd, 2008; Donato et al., 2007; Hewitt, Breuer and Jeffery, 2012; Velasquez-Lopez et al., 2011; Stephen et al., 2009; Zagury, Oudjehani and Deschenes, 2004). Concerns over cyanidation tailings are not exclusively environmental but also economic, as tailings occupy considerable land area, and tailings storage facilities increase the production costs of gold enterprises (Donato et al., 2007). Tailings often contain other valuable metals such as zinc, lead and copper. For example, the cyanidation tailings of Gaoyao Hetai Gold Plant in Guangdong Province contain 2.5 percent copper (Cu), 0.31 percent lead (Pb), 0.23 percent zinc (Zn) and 15.36 percent iron (Fe) (Shi, 2008), and the tailings of Tianshui Gold Plant in Gansu Province contain 1.94 percent Cu, 5.96 percent Pb, 0.27 percent Zn and 24.62 percent Fe. Cyanidation tailings have therefore been increasingly viewed as a secondary resource rather than waste."

Jan 1, 2016

By Sepulvedam Jaime E., Levi Guzmán Rivera

"Grinding media consumption rates and their dependence on key operating conditions in semiautogenous grinding mills is analyzed on the basis of a detailed mathematical model recently developed by Moly-Cop´s specialists which describes and takes into account the three primary media consumption mechanisms, namely: abrasion/corrosion, surface spalling and impact ball breakage. The influence of key mill operating conditions – such as ball filling, discharge grate opening, mill speed, lifter profile, and ball quality – on their corresponding grinding media consumption rates is explored via a variety of model simulations, discussing in every case the independent contribution of each of the indicated consumption mechanisms to the estimated total ball consumption rate.INTRODUCTIONA thorough understanding of the independent contribution of each grinding media wear mechanism is extremely important, especially in semi-autogenous grinding (SAG) operations where macrowear (spalling) and ball breakage cannot be ignored or neglected. The high impact conditions imposed in modern SAG milling environments has created serious challenges for grinding media manufacturers since their products must be able to perform with minimal breakage and surface spalling.GRINDING MEDIA WEAR MECHANISMFor SAG milling operations, at least 3 different mechanisms have been identified as the main contributors to the observed overall grinding media consumption, here referred to as: abrasion / corrosion, ball breakage and surface spalling.Wear by Abrasion/CorrosionThe abrasive/corrosive wear mechanism has been discussed in depth in previous publications (Benavente Hector, 2007; Guzman Levi, 2014; Sepulveda and Morrow, 2014). The most widely accepted approach to mathematically characterize the consumption (wear) kinetics of grinding media in rotary tumbling mills is known as the Linear Wear Theory (Prentice, 1943; Norquist, 1950; Sepulveda, 2004) which claims that—at each instant 't' after a grinding body enters the mill load—the rate at which the body loses weight is directly proportional to its surface area exposed."

Jan 1, 2016

By Ye Chen, Jianhua Chen, Xianhao Long, Qingxia Liu, Zhenghe Xu

"It is crucial to understand the mechanism of the collector interacting with the mineral surface in the presence of water molecules, which could influence the relaxation and electronic properties of sulphide mineral surface due to the proximity effect for narrow band gap of semiconductors. The adsorptions of three typical collector molecules (xanthate, dithiocarbamate and dithiophosphate) on the sulphide mineral surfaces in the absence and presence of water molecule have been simulated by density-functional theory (DFT). The calculated results show that the adsorptions of collectors on clean mineral surface in vacuum are not in agreement with the observed flotation behaviours. The presence of water molecules has a great influence on the adsorption of collectors. The analysis of density of states of the mineral surface atom suggests that the adsorption of water molecules could influence the electronic properties of mineral surface and consequently influence the adsorption between the surface and the collector molecule.INTRODUCTIONIn the separation of multi-metal sulphide ores, the selectivity of a collector is a key factor for the efficient recovery of the aimed mineral. Xanthate, dithiocarbamate (DTC) and dithiophosphate (DTP) are the most common collectors used in the flotation of sulfide minerals. Generally, xanthate exhibits powerful collecting property but lack of selectivity. While dithiophosphate and dithiocarbamate show the good selectivity in the lead and copper sulphide mineral flotation. The mechanisms of these collectors interacting with the sulphide mineral had been attracted many attentions and several mechanism based on experimental results had been reported (Chander & Fuerstenau, 1974; Fuerstenau, 1990; Raju & Forsling, 1991; Crozier, 1991; Bradshaw, Cruywagen & O’Connor, 1995; Guler, Hicyilmaz, Gokagac & Emekci, 2006). However, the micro-mechanisms of the selectivity of these three thiol collectors on different sulphide mineral surfaces are not fully understood."

Jan 1, 2016

By R. Al-Hent, M. Aissa, J. Asfahani

"This paper presents regional radiometric gamma-ray spectrometry maps of Syria for total radioactivity (Ur) and surficial concentrations of equivalent uranium (eU). The maps were created by merging airborne and ground-based gamma-ray spectrometric survey datasets. On the regional radiometric eU map, eU anomalies are closely related to either phosphate and/or glauconite deposits. The Ur and eU maps delineate the boundaries of three phosphate deposits, close to the Palmyrides ridge, in the northern part of the Coastal Range and Syrian Desert. Scattered occurrences of uranium mineralization in other phosphate formations are attributed to secondary chemical and physical processes, rather than primary accumulation.RÉSUMÉ Cet article presente des cartes regionales radiometriques de spectrometrie gamma de la Syrie pour la radioactivite totale (Ur) et les concentrations en surface de l’equivalent en uranium (eU). Les cartes ont ete creees en combinant des ensembles de donnees, aeroportees et au sol, de releves de spectrometrie gamma. Sur la carte regionale radiometrique eU, les anomalies eU sont etroitement reliees aux gisements de phosphate et(ou) de glauconite. Les cartes Ur et eU delimitent les limites de trois gisements de phosphate, a proximite de la crete des Palmyrides, dans la partie nord de la chaine cotiere et du desert de Syrie. Des dispersions de mineralisation d’uranium dans d’autres formations de phosphate sont attribuees a des procedes chimiques et physiques secondaires, plutot qu’a une accumulation primaire."

Jan 1, 2016

"One of the major issues that the Rare Earth Elements Mining Industry has to deal with is the legislation vacuum that exists in many countries around the world. Among these, are countries which have long history and tradition in mining. In many cases the lack of direct legislation for REE mine management as well as for other potentially polluting industries can be a barrier to sustainable development. Moreover, the case of lax legislation in China has led to environmental pollution problems and extended smuggling of rare earth elements. This paper looks into the current regulatory status on the mining of REEs, identifies the loopholes and suggests some elements for a new global legislation framework for sustainable development in the REE mining industry. The setting of this regulatory framework will be in line with the present and future challenges of the rare earths market as well as with the policy strategies that are defined internationally. The aim of such a legislative framework will be to strengthen the global rare earth elements supply chain, appease social concerns and ensure the preservation and conservation of the environment. INTRODUCTION The general public received their first introduction to rare earth elements (REEs) in 2010, when the previously inconspicuous commodities became the subjects of front-page headlines. It was when China created a furore in global high-tech markets after imposing an embargo on Japan following a minor marine dispute (Barakos et al. 2015b). Soon enough the Chinese embargo was extended on REE export restrictions all over the world and thus aroused concerns to many countries over potential supply disruptions. The world had suddenly realized that these wonder materials underpin products that they care about. Governmental and industry executives, policymakers and material scientists voiced concerns and conducted numerous reports stating the situation and the risks of a supply crisis. The price spike of 2011 intensified the crisis and the public turmoil, yet the drama did not last for long as the prices declined significantly in 2012. Nevertheless, the world was nonplussed by the fact that China has the total control of the market with more or less the 90% of the global production. More potential entrants became interested, thus initiating an exploration boom during the recent years that has resulted in a significant increase in known global REE reserves that could have potentials for exploitation."

Jan 1, 2016

By D. D. Gertenbach

"The successful commercialization of a pressure oxidation (POX) process for recovering metal values, including gold, copper, zinc, nickel and molybdenum, is the result of a carefully planned development program. The initial task involves developing one or more conceptual flowsheets, including the POX autoclave and downstream purification and recovery steps. A laboratory program is completed to determine the technical viability of the flowsheets, define the operating parameters for each step and provide information for an initial economic assessment of the process. The process is then confirmed during a continuous pilot plant program, providing engineering design data and other information for the commercial design. A well-thought-out development program has been shown to be critical for reducing the risk of commercializing POX processes. Experiences developing POX processes for refractory gold ores and copper concentrates are briefly discussed. IntroductionPressure oxidation (POX) has become a common commercial operation for processing sulfide-bearing feedstocks. These feedstocks include gold ores and concentrates; copper concentrates; nickel concentrates and mattes; zinc concentrates; and molybdenum concentrates. Drivers for the development and commercialization of POX processes include:• The high cost for pyrometallurgical processing of sulfide ores, much of which is attributed to environmental controls.• The motivation to implement safe and more environmentally attractive alternatives for sulfide ores.• The need to process increasingly difficult ores with complex mineralogy.• Improvements made over the last 25 years in POX equipment design and experience operating commercial POX plants.Although the capital and operating costs for commercial POX processing can be high, this technology is capable of rapid oxidation of most sulfides and arsenic minerals in the feed, with little noxious gases and environmentally stable iron arsenate and other iron compounds in the POX residue (Marsden and House, 2006).In POX operations, sulfides are oxidized to either sulfates or elemental sulfur in an autoclave at elevated temperature and pressure with oxygen gas. An example is the overall oxidation reactions of chalcopyrite when sufficient oxygen is present, shown in the following reactions:"

Jan 1, 2016

By A. A. Rogozhin, E. G. Likhnikevich, S. I. Anufrieva, A. V. Kurkov

The Beloziminskoe deposit in Siberia is a large, potentially productive deposit of rare metals contained in ochreous apatite pyrochlore ores formed by weathering of a carbonatite. The ores are composed of pyrochlore, columbitized pyrochlore, monazite, apatite, magnetite, ferric and manganese hydroxide, titanic iron ore, zircon, hydromica, quartz, feldspar, and carbonates. A gravity-flotation enrichment flowsheet with application of cationic and anionic collectors has been developed. This flowsheet allows for obtaining a pyrochlore concentrate containing 44.3% Nb2O5 and 1.89% P2O5 with recovery of 55.83% Nb2O5 as well as an apatite concentrate containing 39.2% P2O5 and 1.05% TR2O3 with recovery of 62% P2O5 and 43.23% TR2O3 from ores containing 0.92% Nb2O5, 16.9% P2O5 and 0.6% TR2O3. Rare-earth concentrate containing 40% TR2O3 with recovery of approximately 10% TR2O3 was obtained at the same time. Major losses of valuable elements are related to slimes, which make up more than 50% of the ground ore. The niobium concentrate does not meet the phosphorus and radionuclide concentrations needed for the production of ferro-niobium. Acid leaching and sulfatization provided a high level of phosphorous and radionuclide removal. Conditions include hydrochloric acid pre-leaching at 75- 80°C with an 18% HCl solution for four hours and low-temperature sulfatization of acid-leached concentrate at 160-180°C for one hour followed by water leaching of the residue. The apatite concentrate could potentially be processed using nitric acid leaching. This technology is based on decomposition of apatite concentrate with 55-57% strength nitric acid with transfer of rare-earth metals into solution in the form of ammonium phosphate. This technology recovers a rare-earth concentrate containing 95% TR2O3 with extraction of 86%, and highly concentrated polynutrient fertilizer (ammophos) with phosphorus extraction of 95%. The completed research shows how complex multicomponent ores of residual soil may be processed for the extraction of niobium, phosphorus, and rare-earth products.

Jan 1, 2016

By Daniel Mallette, Richard Goodridge, C M. Lownds

Despite a world of mobile devices that has many of us taking the ability to communicate wirelessly for granted, an in-hole wireless initiation system was thought to be not viable. The known and common wireless communication techniques are not suited to this application. To overcome this, we have developed cutting edge technology to communicate to our initiating devices more than 1km through solid rock.

Jan 1, 2016

By G. Viggiani, J. Bel, H. Wong, N. Losacco, D. Branque

"Within the framework of the European project NeTTUN, the Laboratory of Civil Engineering and Building Sciences of ENTPE in Lyon (France) is in charge of a large experimental campaign to investigate the impact of tunneling on neighbouring piled structures. For this study, an original reduced-scale (around 1:10) physical model of EPBS is used. This ""1g"" laboratory model is able to reproduce the main features of the excavation method. For this new experimental program, the miniature EPBS advances inside a large tank filled with a model soil (dry sand), in which instrumented piles were pre-installed. In this paper, the authors describe briefly the original 3D device and present results concerning the impact of tunneling on a single pile located above the tunnel. Different tunneling face pressure are studied in connection with the practice. Machine parameters, pile solicitations and stress-strain behavior of the soil mass monitored under real time conditions are discussed. INTRODUCTION When tunnels are constructed in urban areas, they often come close to pre-existing structures, such as pile foundations. Perturbations of tunnel construction on these neighbouring structures must be considered during design and construction of the tunnel. Ground movements due to tunnelling may induce bending moments, lateral and vertical loads, settlements and lateral deflections in the piles, which may lead to structural damage or failure of the piles or the supported structure. The interaction between piles and a tunnel in construction is a complex three dimensional problem. To date, several experimental approaches have been carried out to analyse the effects of tunnelling on piled foundations (Bezuijen et al., 1994, Loganathan et al., 2000, Jacobsz et al. 2004, Lee and Basset, 2006, Marshall and Mair, 2011, ). These different studies carried out in the laboratory on 1 g or centrifuged models aim at a better understanding of tunnel - piles interaction and a quantification of the influence of each dominating parameter on the structural responses. Parameters like foundation type (single pile, group of piles) and geometry, relative tunnel – pile position, volume loss induced by tunnelling, ground characteristics, pile loading history were considered. However, most of these experiments were carried out under plane strain conditions by modelling the volume loss due to tunnel excavation by decreasing the tunnel diameter or the radial support pressure. As a result, these models do not adequately account for the variations of settlements both in the longitudinal and the transverse direction, which can induce significant flexional and torsional effects on the structures. These effects are particularly critical and detrimental in the case of historical monuments."

Jan 1, 2016