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By Gus Van Weert

The cost of oxygen is a major and common factor in the hydrometallurgical processes developed or proposed tor the oxidation of refractory pyrites. This cost involves charges for the generation and the transfer of the 02 to the mineral slurry. Bio-oxidation faces considerable design demands which require large scale equipment to be resolved. Nitric acid assisted oxidation offers low cost oxygen units; this method of pyrite oxidation deserves a closer look for large scale plants treating pyritic gold ores and concentrates.

Jan 1, 1990

By G. Bräuner

The methods of burst control treated in the authors' very informative paper have been applied in the Ruhr Coalfield, Germany, for more than 20 years and have proved to be highly effective. It might be interesting here to mention a few experiences: The symptoms of critical stresses when drilling with small diameters ("test drilling") are essentially the same as described. However, we consider the situation safe if these symptoms occur beyond a certain distance ahead of the face. That safety distance equals three times the seam thickness plus the daily advance. It is the total seam thickness that counts, not merely the mined portion. Critical stresses within the safety distance are dissolved by so-called destressing measures: drilling with heavier equipment, blasting, or water infusion. To avoid bump initiation, the destressing operations should begin at the sides of the stressed zone rather than in the middle. As to water injection, there are two different principles. If the situation is critical already, high pressures are applied for hydraulic fracturing. If the stresses still allow to drill deep holes, the fluid pressure is kept low and acts for a longer time. This is to make the coal break successively instead of violently - a long-term precaution. When the stresses are very high, destressing is the most appropriate means. We mostly drill with 95 mm-diam (3.7 in.- diam). The techniques in detail are somewhat complex and subject to modifications. But the general idea is to accomplish burst prevention by controlling the potential burst situations.

Jan 1, 1990

By M. M. Kim

As-electrogalvanized coatings of pure Zn, Zn-11% Fe, and Zn-18% Fe coatings were characterized in terms of initial crystal structure and surface morphology. Samples were then subjected to heat treatments simulating the paint bake cycle of automobile manufacturers. Surface morphology changes were correlated with the process variables, and crystallo.graphic changes were interpreted by mapping heat treatment routes on the Fe-Zn phase diagram. The morphology of pure zinc electrogalvanized coatings with heat treatment from platelets to smeared platelets. The zn-11% Fe coating changes with heat treatment from tetrahedral nodules to a mixture of round and tetrahedral nodules, with the Zn-:18% Fe coating always having round nodules. Regarding crystal structure, a critical transformation time can be defined at any selected temperature, below which the crystal structure does not change. This temperature is related to iron content.

Jan 1, 1990

By Tapponnier P

In North Vietnam, large ductile shear zones are observed along the Red river fault and the Dienbien fault. Left-lateral sense of the Red river shear zone is related to the direction of shortening E-W. NE dipping foliation planes is subvertical. Stretching lineation is subhorizontal ( 25¦). Left-lateral slip observed in the Oligocene Yansun granites demonstrates the major tectonic phase in Neogene, The stress field established from microfaults observed in triassic limestones, Oligocene granites and Neogene Conglomerates. Measurements of striations on fault mirors are used for calculating the stress tensor and for separating tectonic phases. Two tectonic phases in tertiary are separated : first tectonic phase related to the compressive direction E-W corresponds to the major tectonic phase represented by NW left-lateral shear zone. Second phase having the compressive direction N-S associated with the right-lateral movement of the Red-river fault zone opening of the Eastern sea and the Red-river and the Red-river delta is associated with the left-lateral movement along the Red-river.

Jan 1, 1990

By Wan-Kyu Choi, Arpad E. Torma

The electrochemical reactions involved in a zinc sulfide flotation concentrate leaching with sulfuric acid in presence and absence of Thiobacillus ferrooxidans, as well as with ferric chloride - hydrochloric acid containing media, have been investigated. The cyclic voltammetric measurements revealed that many intermediate electrochemical reactions are involved in the zinc sulfide leaching. Using chronoamperometric and chronopotentiometric techniques, it was found that the leaching process is controlled by solid - state diffusion. The activation energy of solid - state diffusion process was determined by the Price's approach to be 21.3 kJ. The leaching mechanism is discussed in terms of solid - state properties (energy bondings) of the high energy gap solid zinc sulfide semiconductor and energy density states of redox systems of acidic leach media. A generalized model for the mechanism of zinc sulfide oxidation is present.

Jan 1, 1990

The mining industry is generally regarded as a high risk industry, mainly because of the difficulties in estimating the tonnage and grade of mineral resources, the fluctuations in metal prices, mining problems and other problems which occur with mining in offshore and remote locations, such as appropriation or disruption to supply. As a consequence, finance providers require a high reward from mining projects. In the past two decades, the development of "mega" projects has led to the packaging of the finance becoming more sophisticated. Some would see this move as a measure of the evolution of banking rather than an intrinsic facet of mining finance itself. Project financial managers now require a thorough knowledge of all the financial tools which are available and have to be aware of the funding options so that they can put together a finance package which minimises the cost of the financing with the risk spread adequately between the partners of the financing. The different sources and types of finance for mining projects are described herein along with the factors which determine their costs. To understand the ramifications of financing mining projects, it is essential to appreciate the fundamental difference between debt and equity, which illustrates the importance of gearing. Costs of finance are determined by the interaction of supply and demand forces. Bankers and other financiers have become more adept at isolating a wide selection of risk elements and have devised a formidable range of insurance mechanisms. There is still a lot of money looking for good project risks and if a good project is properly presented and structured, financing can be obtained in today's market.

Jan 1, 1990

By S. C. Tadolini

"Roof bolts are the primary means of roof support in underground mines in the United States. Presently, post installation loads are measured on about 10% of the expansion anchor and combination bolts by using standard torque wrenches that Unit the accuracy of the measurements to about ±30%. No system has been available for measuring the loads generated on full-column resin grouted bolts. Mine roof bolts are long, slender, non-uniformly sized, roughly forged, and placed in a corrosive environment, creating obstacles for researchers trying to utilize ultrasonic reflection techniques to measure strain. A complete measurement system has now been developed by the U.S. Bureau of Mines, Denver Research Center. This system is being used successfully in determining loads measured on expansion anchor and combination bolting systems, examining the transfer mechanics of full-column, resin-grouted bolts, and measuring loads generated on bolts in an underground roadway support system.IntroductionMillions of roof bolts are used each year to provide structural support in underground U.S. metal, non-metal, and coal mines. Approximately 45% of the bolts used are expansion anchor, 45% are resin-assisted combination or full-column resin-grouted, and 10% are friction anchored. The effectiveness of these bolting types is dependent on a number of factors including rock density, bolt length, in situ stresses, rock properties, bolt pattern, installation tension, etc. When implementing expansion anchor and resin assisted combination bolts , installation and post-installation tension, or load, is a major determinant of support quality and subsequent behaviour of the reinforced roof. The method by which these systems carry roof loads is well understood and documented(1,2).The importance of these installation and long-term bolt tension measurements is well recognized and are required in the federal government regulations(3). A statistical sample of the bolts, lout of 4 during installation and lout of 10 inby the last open crosscut, is required to be measured using current torque wrench technology. The disadvantages of this system are the disturbance and weakening of the anchorage and limitations of accuracy to approximately ± 30%. The method by which resin-grouted bolting systems carry roof loads is much less understood, mainly because testing procedures used to evaluate point-anchor systems are not effective on resin-grouted bolts.Due to these problems, the U.S. Bureau of Mines designed a measurement technique that provided a highly accurate, low cost-per- bolt system that led to the development of ultrasonic pulse echo instrumentation. The original system was designed to measure the tension only on expansion anchor bolts. Recent developments and system modifications have permitted measurements on resin-assisted and full-column resin-grouted bolts. The use of these types of support systems has been increasing steadily in underground coal mines.The development of this instrumentation has provided laboratory and field results that help to explain the mechanics and relationships between the applied loads and the interaction between the grouted bolt system consisting of the bolt tendon, grout, and rock."

Jan 1, 1990

By A. J. W. Law

"This paper deals with the organization of the central office technical areas and the role played during the feasibility studies, construction and operating phases of Les Mines Selbaie.HistoryThe Engineering Department was originally formed as a part of the Exploration Department, to examine the feasibility of advanced exploration prospects being brought to the company. In 1968, with the discovery of the South Bay property in northwestern Ontario, the department became part of a Mining Division and was expanded, so that it could provide more advanced mine feasibility studies, control of construction engineering and procurement and initial mine design. As is generally the case, the mine design function was handled with in-house capability, while plant, mill and const ruction functions used outside consultants.The 1974 discovery of the Selbaie deposits, started a period o f growth in the capabilities o f the department. The complex nature of these deposits, required that skills were added in the mining, metallurgical and plant areas. During the early feasibility study period these skills were provided by the engineering company of the parent group, but when it was realized that production from the deposits was likely, permanent staff was added."

Jan 1, 1990

By A. L. Wilder, S. N. Dixon

Introduction Coeur d'Alene Mines Corp.'s largest precious metals property is located in the historic Rochester Mining District 40 km (25 miles) northeast of Lovelock, NV. The property encountered cold weather operational problems soon after its fall start-up in 1986 due to its elevation of over 1830 m (6000 ft). The problem of ice buildup on the heaps because of sprayed solution application was faced immediately. It was felt that allowing ice to build up all winter long until a spring thaw was impractical due to the large area under leach. Further, the operating cost and delivery schedule for a solution heating system was unacceptable. The development and installation of a leach solution distribution system using drip emitters made efficient, cost-effective winter operation possible. Other benefits of this system have also been observed and are discussed here. General process description 15,422 kt/day (17,000 stpd) of - 1.27-cm (-1 /2-in) crushed ore from the three-stage crushing plant are delivered to the leach pad using 77.1 t (85 st) rear dump haul trucks. The ore is drifted into place with a D-9 bulldozer. Leach panels are contiguous and are approximately 8861 m'(90,000 square ft) in area built in 6-m (20-ft) lifts. New panels are built on top of older areas to a final height of 61 m (200 ft). Each panel is ripped and cross-ripped prior to leaching. Barren solution is distributed to the heap using drip emitters at rates of 0.02 to 0.41 L/min/m2 (0.0005 to 0.01 gpm per sq ft), depending on the age of the panels. The pH of the leach solution is 10.7 with a cyanide concentration of 0.75 kg/t (1.5 lb per st). Approximately 50% of the silver and 80% of the gold are finally recovered. Pregnant solution percolates though the heap and flows by gravity into one of two 9.46 ML (2.5 million gal) pregnant solution ponds. The solution is then pumped to a conventional Merrill-Crowe process plant. Clarification takes place in three 9464 L/min (2,500 gpm) capacity filters. The solution is then pumped to a packed vacuum deareation tower for the removal of dissolved oxygen. Typical deareated solution contains 0.7 parts per million dissolved oxygen. Precipitation of gold and silver is accomplished by adding a zinc dust slurry to the deareated solution at the suction of the filter press feed pump. Precipitated gold and silver are recovered in three recessed plate and frame filter presses. Barren solution is discharged into a 11.7 ML (3.1 million gal) pond where cyanide makeup occurs. This solution is pumped back to the heap for further leaching. The precipitate filter cake, containing approximately 75% dore (Ag + Au), is then fluxed with anhydrous borax, soda ash, sodium nitrate and fluorspar to yield a neutral, bisilicate slag. The fluxed precipitate is then charged into a propane-fired melting furnace and heated to 1150° C (2100° F) for 3 1/2 hours. Slag and dore bullion are poured into conical cast iron pots yielding buttons of 800 to 1000 troy oz. The dore typically contains 98.5% silver and 1 % gold. Slag is crushed and tabled to recover the trapped dore blebs and beads. Concentrate from the table is returned to the furnace. Table tails are sent to the crushing circuit and out to the leach pad. Solution application The area kept under leach at Rochester is approximately 130 000 m2 (1.4 million sq ft). Barren solution is delivered to the pad at 21.2 kL/min (5600 gpm) for a resultant application rate of 0.16 L/min/m2 (0.004 gpm per sq ft). A traditional solution sprinkling system using No. 12 Senninger Wobblers with individual pressure regulators was installed at the onset of leaching activities. The Wobblers were placed at 9.1-m (30¬ft) staggered centers and were fed off of a gridwork of Yellowmine plastic piping. Solution flow rates were moni¬tored to each panel. The onset of cold weather with an average nighttime temperature of -12° C (10° F) made it apparent that continual operation would not be possible with the sprinklers. A significant amount of ice was built up on top of the heap, making maintenance and pipe removal dangerous, if not impossible. Leach solution application was restricted to daylight hours to inhibit ice formation. Process plant flow rates were reduced to maintain steady-state operating conditions. However, as daylight temperatures dropped below freezing, ice continued to accumulate due to the sprays. Besides the obvious operating hazards brought on by the growing icefield, there was also the potential environmental hazard associated with an early thaw melting the ice too rapidly for the solution containment facilities. One other option for preventing ice formation was heating of the barren solution prior to spraying. Initial plant design allowed for expansion of the propane storage and distribution system as well as modification of the barren piping for a solution heater. This option was not exercised because the operating costs for an adequate system would have been prohibitive, and timely delivery of a system was not available. An investigation was conducted on the various drip irriga¬tion products available, since subsurface solution applicators would eliminate ice formation altogether. Systems utilizing external flow emitters were ruled out because of their ten¬dency to clog when buried. Emitter systems using perforated tubing were also eliminated from consideration due to their inability to adequately control flow over required lengths of tubing. An in-line emitter system was finally selected which demonstrated clog resistance and adequate flow control, enabling direct burial.

Jan 1, 1990

By S. E. James

EAF dust has been listed as a "hazardous waste" due to the presence of lead and cadmium, and at times chromium. The 550,00 tpy production of . .EA]' dust, estimated for the United States alone, contains more than 10,000 tpy of lead and about 250 tpy of cadmium in addition to nearly 1'00,000 tpy zinc. Even though the listing of .EAF dust as a hazardous material stimulated extractive metallurgical work worldwide, process development efforts have focused only on the recycle of the potentially-valuable zinc units. However, the recycle of the lead and cadmium, while not lucrative, is the more critical effort. Horsehead Resource Development Company, Inc. (HRD), in conjunction with its sister company, Zinc Corporation of America (ZCA), has taken a unique approach to total recycle of the toxic heavy metals found in the EAF dust. Impure oxide, produced by either a Waelz kiln or FLAME REACTOR Process and containing the lead and cadmium, is calcined in a rotary kiln at Palmerton, Pennsylvania, to produce a refined zinc-rich intermediate for ZCA's electrothermic zinc plant at Monaca, Pennsylvania. During the calcining operation, lead and cadmium are concentrated in a fume product and shipped to ZCA's electrolytic plant at Bartlesville, Oklahoma. At Bartlesville, a new hydrometallurgical circuit has been constructed and the existing cadmium plant expanded. The combined facilities permit the total recovery of cadmium to refined metal and the lead to .a silver-rich intermediate, which is sold to lead smelters. In this paper the Waelzing, calcining and new leaching facilities will be described.

Jan 1, 1990

By Thomas J. Albin

U.S. Bureau of Mines research has found that maintenance of surface mining equipment is involved in slightly more than one-third (34.1 pct) of all surface mining accidents. Two groups of machines, haulage trucks and power shovels, accounted for over one-half of all surface mining mobile equipment maintenance accidents in 1978-84. Maintenance work-time histories for these machines were compared with accident records to identify the most hazardous-to-maintain systems within the machines. Recommendations to reduce the accident risk associated with maintenance of these hazardous systems are presented.

Jan 1, 1990

By W. Dan Hausel

Archean supracrustal rocks of the South Pass greenstone belt of western Wyoming have been an important source of gold and iron ore. Actual gold production statistics are incom- plete although gold production estimates for the South Pass- Atlantic City district range from a low of 2.0 Mg (70,000 oz) (Koschmann and Bergendal, 1968) to a high of 9.8 Mg (327,000 oz) (Hausel, 1980). From 1962 to 1983 iron ore was also mined from the greenstone belt and production totaled more than 91 Mt (90 million It). The supracrustal rocks of the South Pass greenstone belt occur in a tightly folded synform bounded by Late Archean granite and granodiorite. The youngest of the Archean successions has a reported Rb-Sr isochron age of 2.8 b.y. (Stuckess, et al., 1985). Metamorphism of the supracrustals increases towards the flanks of the belt and is amphibolite-grade enclosing a small island of greenschist facies rocks. The supracrustal sequence consists of metasedimentary and metaigneous rocks that are divisible into four mappable units. The metasediments include metagraywacke, quartzite, pelitic schist, banded iron formation, metaconglomerate, and graphitic schist. Metavolcanics include metabasalt, meta-andesite, and ultramafic schist. These supracrustals have been intruded by mafic sills and dikes and tonalitic stocks and dikes. Two granite plutons and associated pegmatites intrude the supracrustals in the western portion of the belt, and the supracrustals exhibit both fault and intrusive contacts with granitic batholiths along the western and eastern margins. The northeastern flank of the Archean belt is unconformably over- lain by Paleozoic sediments, and the southern portion of the belt is onlaped by Tertiary sediments.

Jan 1, 1990

Here, in what is partly a review and partly a personal viewpoint, I take stock of changes in emphasis and comprehension on the subject of basaltic volcanism in the decade that has passed since the completion of the landmark Basaltic Volcanism Study Project (1981). I concentrate attention on the relatively neglected physical-volcanology aspects (in 1988 it was still possible to publish a 340-page book on flood basalts with barely any mention of physical mechanisms).I adopt the useful unifying concept of "volcanic system" to embrace the invariably-present intrusions as well as the volcano; I consider controls exercised by magma-supply rate and modulator-mechanisms on the nature of the system;I emphasize that sheeted-intrusion complexes, consisting either of dikes or inclined sheets (depending on the ability of the system to expand laterally) occur in all eroded major systems and fuel geothermal systems; I show how constraints set by cooling of narrow intrusions cause such complexes to be wedge-like and produce considerable rotations; I consider the role of the level of neutral buoyancy in making magma chambers possible, causing lateral subsurface magma flow and localizing intrusions, while the LNB itself can be accentuated by intrusions; and I examine the possibility that underwater systems could have very different internal structures from systems on land.

Jan 1, 1990

By Little T. N

The Western Australian School of Mines is continuing to investigate the blasting techniques and mining strategies that are used for ore/waste separation (or high grade/low grade ore separation) or to prevent ore and waste mixing. The aim of all the mining strategies is to produce an optimum product. The optimum product is one which contains no diluent and undergoes no mixing of the various identified ore and waste blocks and is fully recovered at the minimum overall operating cost. The current study includes the use of computerised Knowledge Based Systems (KBS) technology to assist the user with the blast technique selection and blast design process. These aspects are highly dependent on the geology. (geometry, rock mass properties, grade distribution), explosive performance and the expectations of the mining company in terms of production rates and equipment utilisation. Most of these factors are not well defined and nor are they easy to quantify. However, a large amount of knowledge does exist and is available in the following forms: rules of thumb, empirical formulae, engineering judgement and past experience. KBS techniques are well adapted to handle such"forms of knowledge. The primary objective of this paper is to illustrate an approach for the use of Knowledge Based Systems during the analysis and interpretation stages of the blast design process. In particular, the components and methodology of the developed system are described for selective open pit gold mining. The Knowledge Based System developed was written using the declarative programming language PROLOG.

Jan 1, 1990

By Michael Wieland

Sharp transient stress waves generated during the delay blasting of underground coal can damage unfired borehole charges remaining in the delay pattern. These tremendous stress pulses in coal bear a strong resemblance to underwater shock waves, despite differences in rise times, damping rates, and scaling relations. "Shock wave" terminology is adopted to distinguish the sharp transient waveforms propagating through the coal from the gas-driven stresses that rift the coal. Reported waveform characteristics of shock waves through underground coal were utilized to design a simulator test for rating the impact resistance of cap-sensitive explosives. Theoretical minimum borehole separations were determined for each cap-sensitive explosive from the requirement that worst-case waves hitting an unfired charge would not exceed its impact resistance rating. Rugged explosives have higher impact resistance and will function properly at smaller borehole separations. Additional work is required to verify the findings from the simulator technique and modeling relations reported here.

Jan 1, 1990

By Lownds C. M

Several classes of commercial explosives and blasting agents behave non-ideally, especially in diameters near their critical diameter. A direct and convenient measure of non-ideal behavior is the detonation velocity (VOD); if the VOD is less than the ideal value, usually obtained by calculation, then the explosive is detonating in the non-ideal mode. Such lowering of the VOD is usually due to both lateral loss of energy and post-CJ release of energy. The second of these factors, namely slow release of chemical energy, is of most interest in blasting. While the observation of a low VOD clearly suggests slow reaction of part of the explosive composition, it does not necessarily mean that the energy is lost to the overall rock-breaking process. The partition of the energy of the explosive into various useful and wasteful categories is considered. Simple models of energy partition in blasting, and of explosive reaction kinetics, are presented. The models consider the effect of explosive type and rock type, the explosive being described in terms of the most common phases namely liquid, air bubbles, porous ammonium nitrate, dense or crystalline ammonium nitrate, and aluminum. Over a range of combinations of the above phases, the model predicts reasonable critical diameters and VOD's. Results are presented which show the effects of non-ideal detonation on fragmentation and heave in different rock types. Conclusions are drawn about those blasting conditions in which ideal behavior is beneficial, or Disadvantageous.

Jan 1, 1990

The word `environment' may have many different meanings but, for the purposes of this paper, I have assumed the definition included in the Environmental Protection Act 1986 (Western Australia). This Act defines `environment' as `... living things, their physical, biological and social surroundings, and interactions between all of these'. The Act further defines the `social surroundings of man' as `... his aesthetic, cultural, economic and social surroundings to the extent that those surroundings directly affect or are affected by his physical or biological surroundings'. This gives a very broad meaning to the idea of environment and environmental issues, and it is therefore understandable that the influence that environmental issues have on mining activity can vary so much from state to state, and even within states, and why the degree of influence can change so much with time.

Jan 1, 1990

By Keith A. Heasley

Pillar recovery in deep coal mines with competent roof and floor can concentrate stresses and generate hazardous bumps. Actual calculation of the geologic strain energy released in association with these coal bumps has been rare, although energy release values have been utilized successfully for indicating burst potential in numerous hard- rock mines. This paper advances the current knowledge of energy release calculations as applied to coal bumps through an extensive analysis of an actual bump occurrence. The U.S.B.M, displacement- discontinuity code, MULSIM/NL, is used to produce a numerical model which generates stress, displacements and energy values associated with a pillar retreat section. This model is calibrated with actual field data, and then dissipated energy values from the model are examined as to their suit- ability for indicating bump potential. Ultimately, it is determined that prudent application of dissipated energy calculations can be used as a tool to investigate the coal bump potential of a mining plan or cut sequence.

Jan 1, 1990

By Jaki Wilson, Les Armstrong, Neville T. Moxon

Low shock energy ANFO (ANFO) mixtures have been developed for use in fragmenting weak overburden materials and reducing damage.outside the blast zone in dry conditions. These mixtures can be readily produced on a minesite using conventional equipment and are formed by mixing low density additives such as polystyrene, bagasse and sawdust with ANFO.

Jan 1, 1990

By Batric Pesic

Gold dissolution with bromine was studied by using the rotating disc technique. Geobram TM 3400 was used as a source of bromine. The parameters studied were: rotating speed, Geobrom 3400 concentration, pH, temperature, sulfuric and hydrochloric acid concentration, and the concentration of various cations (copper, iron, zinc, aluminum, manganese, potassium and sodium) and anions (chloride, bromide, sulfate, nitrate, and iodide) According to the Levich plot and activation energy, gold dissolution was controlled by a chemical reaction rate. Copper, iron, and manganese in their highest oxidation states, aluminum, zinc, sodium and potassium did not have any effect on gold dissolution rate. The presence of manganous ion dramatically decreased the gold dissolution rate. Kinetic performance of bromine, in the form of Geobram TM 3400, was compared with performance of cyanide and thiourea.

Jan 1, 1990