Search Documents

By Liu Zhonghua

Hydrogen reduction of cobalt sulfide (Co9S8) was experimentally investigated in the temperature range 813-1053 K. The results revealed that the reaction kinetics can be described by the shrinking core mod¬el in chemical control regime at low temperatures, it is of first order with respect to hydrogen concentration, and the reaction activation energy is 67.4 kJ/mol. The SEM second electron images of the samples before and after experiments showed that the swelling of the sample above 973 K is due to the formation of metallic cobalt whiskers.

Jan 1, 1992

By C. E. Jordan

The Bureau of Mines investigated a simultaneous elutriation and flotation technique for separating polyethylene terephthalate (PET) from polyvinylchloride (PVC). The Tuscaloosa Research Center, through a cooperative agreement with a recycling company, devised an elutriation-flotation method for beneficiating the mixed heavy plastics portion of municipal solid wastes which is composed of polystyrene (PS), PET, and PVC. A sodium carbonate brine was used to remove the lighter PS from the heavier PET and PVC. Over 98 pct of the PS was recovered in a high purity PS concentrate containing 99.7 pct PS, The remaining PET and PVC mixture was washed to remove the brine salts that would be harmful to the flotation process. The clean PET and PVC mixture was conditioned in a solution of 45 g/t gelatine and floated in a short (l-m) column flotation cell in an upward flow of water. In a single flotation step, over 75 pct of the PET was recovered in a high purity product containing 99.8 pct PET. The bubbles attached to the PET lowered the effective density of the PET-bubble agglomerate and allowed successful separation of these agglomerates from the PVC plastic pieces. This method separated two-thirds of the mixed plastics fraction into high purity PS and PET products suitable for recycling and left only one-third of the plastics in the mixed plastics product.

Jan 1, 1992

By A. Dadgar

The adsorption kinetics of AuBr4 on Dowex ® -21K ion-exchange resin were studied and found to be independent of the initial gold, bromine, and base metals concentrations. A commercially-available undivided hypochlorite generating cell was used to generate bromine from simulated mixed halide (Br-/CI-) solutions. Electrolyses were performed with solutions containing very low Br' ion concentrations. The current efficiencies were 80-90%, and Br- ion utilization was maximized. A detailed economic assessment was made considering the capital and the operating costs for a 1000 mtpd gold ore processing plant. The toxicity and discharge levels of bromide, bromine, and cyanide were compared from a detailed analysis of the published literature data. Comparing bromine vapor with hydrogen cyanide gas for a given length of exposure, the lethal concentration of bromine is about 3 times less than hydrogen cyanide. The toxicity of sodium bromide is similar to that of sodium chloride. Acute poisoning to bromides and chlorides is rare because of their low toxicities. The allowed discharge levels of Br-, Br2, and CN- in fresh water are 250, 0.1, and 0.005 mg dm-3, respectively.

Jan 1, 1992

By Joseph J. Wojcik

INTRODUCTION A great deal more is involved in a sampling effort directed at a placer deposit than physically capturing a quantity of representative material and extracting the desired component. The distribution and dimensions of the sample sites must be chosen after consideration has been given to the type of deposit and the concentrating mechanism. Interpretation of the sampling results is likewise an extremely important part of the sampling program. SAMPLE SPACING The interpretation begins with the selection and design of the sampling program. A decision regarding genesis of the deposits and their geometry must be made in order to select a suitable technique and sampling pattern. Deposits differing genetically will have differing distributions and degrees of concentration.

Jan 1, 1992

By R. R. Oder, R. J. Gray

We report measurements of the effects of rank, type, and grade of coal on grinding energy and grinding media consumption in a Pitt Mill. The rank of coal has a greater effect on grinding energy than does coal type. The effect of coal grade on grinding energy depends upon the relative grindability of the mineral matter and of the hydrocarbon components of the coal. The mineral matter is primarily responsible for abrasive media wear in a Pitt Mill. The widely recognized HGI test for coal breakage may yield misleading results, particularly for multiple-banded bright and dull coal where the screening procedure used in sample preparation favors the testing of the hardest coal fraction. The work reported here indicates that the Pitt Mill, which grinds the whole coal in a single stage and which yields easily interpreted results, is an excellent candidate for testing coal pulverization characteristics including energy requirements and equipment wear. The measurements of the effects of coal characteristics on grinding energy and on media consumption have been used to estimate the cost of fine grinding in a Pitt Mill. The results, based on a conceptual level evaluation of grinding at the rate of 1 TPH, show that there are trade-offs possible between the cost of energy and cost of media consumption which involve choice of grinding media size. The use of fine-size grinding media to lower grinding energy and to increase throughput can be deceptive because the total cost of grinding must consider both energy and media consumption.

Jan 1, 1992

By G. L. Mowrey

One critical element of the US Bureau of Mimes computer- assisted mining research program is the development of a reliable coal interface detection (CID) system. Several promising CID concepts currently being investigated by the Bureau include natural gamma radiation (NGR), vibration and passive infrared. To help establish which CID sensor technologies need to be developed for a given seam, coal and adjacent rock samples (immediate roof and floor) are being collected from selected major coal seams in the US and are being analyzed in terms of NGR and other geophysical measurements. This paper provides a brief overview of the Bureau's work in these CID areas.

Jan 1, 1992

By Hans G. Machel

In low-temperature diagenetic environments (0 c T c 60 - 80°C), elemental sulfur forms by six common processes: via (1) inorganic oxidation of H2S by molecular oxygen, (2) inorganic oxidation of H2S by ferric iron compounds, (3) polysulfide disproportion- ation; and via the microbial metabolic actions of (4) colorless sulfur bacteria, (5) colored sulfur bacteria, and (6) some types of thiobacilli. Economically viable deposits of native sulfur usually are formed by only one process: inorganic oxidation of H2S by molecular oxygen. The amount of elemental sulfur is also limited by three common processes that destroy it in low- temperature diagenetic environments: bacterial reduction, bacterial oxidation, and inorganic oxidation. In high-temperature diagenetic environments (80 - 10o°C c T c 150 - 200°C), particularly in sour gas reservoirs, there are seven common processes forming elemental sulfur: (1) SOdH2S reaction, (2) H2S- hydrocarbon reaction, (3) polysulfide disproportionation, (4) catalytic H2S decomposition, (5) C02-H2S reaction, (6) chlorinification, and (7) exsolution of physically dissolved elemental sulfur. Natural processes that destroy or remove elemental sulfur in such settings are hydrocarbon sulfurization, polysulfide formation, and advection. In most sour gas reservoirs, relatively small quantities of elemental sulfur occur as a free phase (solid or liquid). However, elemental sulfur often precipitates in copious amounts from the reservoir fluids via exsolution and polysulfide disproportionation during production of sour gas reservoirs. By extension, elemental sulfur may precipitate from reservoir fluids in relatively large quantities upon uplift and erosion of deep sour gas reservoirs, or from advection of sulfurous fluids into shallower settings via faults or other high-permeability pathways.

Jan 1, 1992

By Zvonimir Jam?ek

In Rudarski Institut Ljubljana (RIL), i.e. Ljubljana Mining Institute, we have developed CADRIL, a smaller CAD package which purpose is to overcome the difficulties by introducing Computer Aided Design in our mines. Program CADRIL is a graphics shell for several computer applications in mining. With the basic version of CADRIL all 2D working maps for daily use can be produced. Inserting different program blocks into CADRIL we get versions MAPRIL, TAHRIL, SECRIL and so on. The main purpose of all versions is graphics design. The main and most innovative feature of CADRIL is the screen four-word command menu. Not having pull-down or tablet menus is the speciality of this program. CADRIL contains 500 achievable commands. Each of them can be composed by choosing two to four expressions stored and shown in a specific four- column menu, sorted as objects functions, parameters and modes. Thus all commands are immediately accessible. As a result of its plainness and adaptability to the present working methods of mining engineers, CADRIL quickly attained a good reputation in our mines.

Jan 1, 1992

By C. A. Roberts

What are the benefits and limitations of financial analysis software as a decision making tool in the mining industry? Traditionally, the assumptions and simplifications imposed by complex and uncertain information have been viewed as the main obstacle to reaching an optimum decision. Recently, however, phenomena such as corporate culture and power structure have received increasing attention as significant influences on organizational decision making processes. Studies of these phenomena have suggested an alternative way of understanding decision making processes and an alternative view of the role played by computer analysis in such processes. This paper presents these two views of decision making, and examines what each implies about the role of financial analysis software as a decision making tool in the mining industry.

Jan 1, 1992

By C. P. Lazzara, Y. Miron, A. C. Smith

This report presents a U.S. Bureau of Mines study to identify the causes of self-heating events beneath the floor of a deep underground coal mine. Mine samples from both heated and unheated areas were examined by various techniques, including visual, microscopic, thermal, chemical, and instrumental tests. The combined results led to the conclusion that pyrite (FeS2) oxidation was the prime cause of the beatings. However, adiabatic oven tests of selected samples did not indicate the effect of the pyrite on the self-heating process, probably because of the experimental conditions. A fast, simple procedure to assess the concentration of pyrite in the mine samples was developed, utilizing the reactivity of the sample with an aqueous solution of hydrogen peroxide (H2O2)

Jan 1, 1992

By P D. Katsabanis

"This chapter describes the principles for the derivation of the equations for a detonation wave.. Theimportance of the equation of state for the detonation products is demonstrated and commonly used equations of state are discussed. Furthermore a brief introduction to the TIGER code is presented."

Jan 1, 1992

Because surface mining removes the original plant cover from the land and exposes the soil, special care is needed. Until the mined land is stabilized by revegetation, snowmelt and rainfall can pick up sediment and erode mined lands much faster than undisturbed areas. Sediment control is an important aspect of protecting the environment during mining and reclamation because without it, large amounts of sediment can clog streams, increase the risk of flooding, damage irrigation systems, harm aquatic habitat, and limit the use of water for other purposes. Stream quality can be affected many miles downstream from the mine. Before SMCRA was implemented many streams were degraded by uncontrolled sediment from mining. Sediment is controlled through careful planning and a design that incorporates a variety of measures that work together to reduce soil erosion at the mine. Disturbed areas are graded, and some areas terraced, to achieve stable slopes, reduce runoff water velocity, increase infiltration, and divert runoff into drainage channels so that it flows away from unvegetated, erodible areas. Grading along the slope contour and scarify in gun vegetated slopes with bulldozer track marks help prevent erosion by slowing down the flow of water. Runoff from haul roads is controlled by culverts and roadside ditches. Sedimentation ponds or other forms of sediment control are required at all mines to minimize the amount of sediment leaving the site.

Jan 1, 1992

By Distin P. A

The extraction of platinum and rhodium from scrapped honeycomb autocatalyst into hydrochloric acid/aluminum chloride/nitric acid solutions is described. Results are given for the effects of leachant composition, temperature and catalyst pre-reduction using hydrogen. Data are also presented for the recovery, by hydrogen reduction, of platinum and rhodium dissolved in the leach solution. Parameters studied include solution composition and temperature, hydrogen pressure, and platinum seed addition.

Jan 1, 1992

By R. J. Reuss

Mina Maria is a high-grade, underground copper mine located in the Cananea district of Sonora, Mexico. The ore body is a massive sulfide breccia located in mountainous terrain. A major highway and an electric transmission line pass directly over the near-surface ore body. The mine is operated by Minera Maria SA de CV, a joint venture company that is 51 % owned by Empresas Frisco SA de CV and 49% by Cominco Resources International Ltd. Empresas Frisco is the operating partner. Production began in October 1990. The mining method used is undercut and fill. A continuous miner and a single-boom, hydraulic jumbo mine the ore. Backfill is a weakly cemented sand-gravel mixture that is pneumatically placed. The ore is treated by conventional crushing, milling and flotation. The Maria deposit is located about 40 km (25 miles) south of the Sonora-Arizona border and 11km (7 miles) northwest the city of Cananea and the Cananea Mine. The mine portal, at an elevation of 1780m (5840 ft), is on the east side of an important drainage divide. The mill site is situated about 800 m (2625 ft) northwest of the mine on the northwest side of the drainage divide where the drainage is more favorable. Its elevation is 1860 m (6100 ft) (Fig. 1).

Jan 1, 1992

By Art Hamilton

The Zn-Pb-Cu-Ag ore deposits of the Boundary and N-5 zones near Bathurst, New Brunswick, occur in a polydeforrned volcano-sedimentary sequence that is part of the Ordovician Tetagouche Group. Massive and disseminated sulfides are hosted by an argillaceous to cherty sedimentary sequence that is stratigraphically Wlderlain by a siliceous fragmental unit and is overlain by a feldspar-rich crystal tuff and related tuffaceous rocks. The deposits have a low iron sulfide content relative to that of most stratabound sulfide deposits of the Bathurst-Newcastle mining district. The ore is commonly associated with chlorite- and talc-rich sediments. The N-5 deposit is considered to be the fault-displaced extension of the Boundary deposit. The Boundary deposit is estimated to contain 891 000 t grading 3.31% Pb, 7.96% Zn, 0.32% Cu and 44 g/t Ag; the estimate for the N-5 zone is 330 000 t grading 3.24% Pb, 7.15% Zn, 0.33% Cu, and 37 g/t Ag. The ore is processed at 1000 tpd at the Heath Steele mill.

Jan 1, 1992

By André Vervoort

The roof behaviour in room and pillar panels during the development of roadways and the subsequent pillar extraction was monitored underground and numerical simulations were conducted. For several underground sites, a satisfactory, correlation was found between underground measurements and three-dimensional numerical simulations using a boundary element code in the linear elastic domain. However, to simulate bed separation, and roof block collapses more complex models were required, of which examples are presented.

Jan 1, 1992

By M. R. Peterson

The U.S. Bureau of Mines has investigated new methods for increasing the selectivity in flotation by creating and regulating reagent concentration gradients within flotation columns at steady-state operation. Gradients were generated and traced in a water-only system with the use of fluorescent dyes, and the effects of various operating parameters on these gradients were investigated. From this investigation, it was found that both gradual and steep gradients could be generated in the froth cleaning zone, and that these gradients could be changed through the manipulation of both physical and chemical operating parameters. The application of reagent-gradient control to mineral systems could improve both flotation grade and recovery in commercial flotation operations without the use of additional flotation circuitry.

Jan 1, 1992

By Tuncel M. Yegulalp

In this paper we revisit the well known "Ultimate Pit Limit Problem" and suggest an alternative approach for fast and efficient solution. We follow the approach originally proposed by Johnson and Barnes (1988), but utilize the "Excess Scaling Algorithm" in solving the equivalent maximum flow problem. This algorithm provides significant increases in speed and reduction in memory requirements over the well known Labeling Algorithm of Ford and Fulkerson (1956), enabling one to solve large problems with relatively small computers. We present results of a series: of benchmark tests using this approach against the well known Lerchs Grossman algorithm as well as a brief description of the new algorithm.

Jan 1, 1992

By P. R. Taylor

This investigation (Bowles, 1990) involves consideration of technology utilized by three separate fields of metallurgy and materials science: 1) The recovery of metals employing the use of solvent extraction, 2) The fabrication of materials using powder metallurgy, and 3) The use of composite materials in fabrication of engineering materials. The research considers each of the processes in order to realize the benefits of each. In light of the fact that materials have an intended use -it does seem plausible to simplify the process required between "mother earth" and final use. For instance, a primary copper producer that already employs a solvent extraction and electrowinning process could produce value added products directly. Part of the existing extractant flow could be diverted into a pressurized hydrogen stripping process in order to produce specialty composite powders. Innumerable methods have been employed for the recovery of metals; solvent extraction, the one considered in this study, was used due to the possibility of it providing a pure powdered metal. The use of solvent extraction in the recovery of metals has gained wide acceptance and its use proves beneficial in many applications (Ritchey and Ashbrook, 1984). Pressure hydrogen stripping of solvent extractants may provide the benefit of flowsheet simplification compared to conventional solvent extraction followed by electrowinning. It may also provide the benefit of direct production of high purity metal powder (Demopoulos and Distin, 1985).

Jan 1, 1992

By Anderson J. M, Gillies A. D S, Jones N

There are a number of current theories in relation to methane migration and emission into workings following underground coal mining activity and some controversies do exist. Mining causes changes in the stress regimes in surrounding strata and results in fracturing. Permeability increases and methane flows into workings under a pressure gradient. The effects of stress on permeability depend on the physical properties of the coal and surrounding strata. Methane emission also depends on the original methane content and the proportion which will be liberated. There are several methods for determining in situ methane content and desorption characteristics of coal samples and several methane prediction methods but clearly more research is necessary to achieve an adequate predictive model.

Jan 1, 1992