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By Michael S. Wieland

Charge malfunction problems result from rather universal damage mechanisms and are widespread throughout surface and underground delay blasting. Recent refinements in instrumentation technology reveal a range of charge performance difficulties, not just outright misfires. This report focuses on the U.S. Bureau of Mines research regarding desensitization and malfunction of delay detonators and cap-sensitive explosives, utilized in underground coal mining. Delay blasting generates tremendous shock waves and rifting forces that fracture and heave the surrounding stratum. The shock waves from charge explosions propagate outward in all directions through the coal, impacting neighboring charges with later delays. The impact phenomena have debilitating effects, causing degrees of reduced charge performance ranging from misfires or weak detonations to out-ofsequence detonations. Impaired charges react poorly. fracture less coal, and produce fumes with higher toxicity. Coal-mine, underwater, and simulator tests were conducted to m3re thoroughly understand the shock-wave and rift-compression damage mechanisms. Recently the U.S. Bureau of Mines partially resolved the malfunction problem by demonstrating the feasibility of formulating a rugged explosive, which could pass the requisite tests for certifying an underground coal-mine explosive. The charge formulation was not certified only because it lost initiation sensitivity too quickly from natural aging and had to be rebatched to finish the testing.

Jan 1, 1994

Background BHP Iron Ore Pty Ltd is one of the major iron ore producers in the Pilbara Region of North Western Australia. The company manages three separate joint ventures; the Newman, Goldsworthy and Yandi joint ventures and two 100 per cent owned operations, Yampi and Jimblebar. The Newman operations constitute a mine site at Newman and a 426 km railroad to Port Hedland where there is an ore processing/port site. The Goldsworthy operations currently constitute a mine site at Shay Gap/Nimingarra, a developing mine site at Yarrie, a decommissioned mine site at Goldsworthy and an ore processing/port site at Finucane Island (Port Hedland). The Yandi operations include mining and processing facilities at site and a spur line to join the Newman Hedland railroad. Jimblebar operations are scree and bedrock mining near Newman and include mining, processing and a spur line to Newman where it joins the Newman-Hedland railroad. The Yampi operations constitute a mine/port site at Koolan Island (which is presently being decommissioned). The combined BHP Iron Ore operations produce approximately 46 Mtpa of iron ore. This paper will concentrate on the processes developed and applied for the decommissioning of the Goldsworthy site. The Goldsworthy site is on the northern boundary of the Pilbara Region and adjacent to the western extremity of the Great Sandy Desert. It is located approximately 110 km east of Port Hedland (see Figure 1). The area is generally of low relief with isolated low ranges. The mine site being within the Mount Goldsworthy range area. The geology of the area is essentially Archaean granite with Archaean banded iron formation becoming dominant within the ranges. The chief soils are hard alkaline red soils. The vegetation is essentially shrub steppe with the main hummock grass species being spinifex (Triodia sp). The climate for the region is semi arid tropical. The temperature ranges from a mean low of 15¦C in winter to a mean high of 40¦ in summer. Rainfall is episodic, occurring mainly throughout the summer as a result of tropical depressions or cyclonic activity. The average annual rainfall is approximately 300 mm and annual evaporation may exceed rainfall by up to 2500 mm. Goldsworthy Mining Ltd commissioned the Goldsworthy site in 1965/66. Goldsworthy was the first iron ore operation and associated town site in the Pilbara region. The mine development peaked in 1977 with the town population reaching 1400 people. In 1982 mining ceased and the mining operations were relocated to Shay Gap, 80 km east of Goldsworthy. The Goldsworthy town continued as the base for the railing operations between Finucane Island and Shay Gap. BHP Minerals acquired Goldsworthy Mining Limited in 1990. The population for the town of Goldsworthy at this stage was around 450 people. An assessment of the Goldsworthy site operations concluded that it was uneconomic to continue the operation of the site. The decision was made to transfer the base for railing operations to Port

Jan 1, 1994

By R. F. Hammen

Copper is one of the most widely used metals in industrial processes and is also present in most mining operations. Extraction of copper from solutions often proves difficult due to the presence of complexing agents. ChromatoChem, Inc. has developed a Solid Phase Extraction (SPE) support (HiPAC) for removal and recovery of metals from wastewater. The HiPAC SPE support employs chelating agents covalently coupled to a long linker molecule. Several solutions containing copper and complexing agents were tested including 1) copper and carbonate, pH 9.8, 2) mixed metals and anions with copper and cyanide, pH 11, and 3) copper and the chelating agent EDTA, pH 11. The copper was extracted from solutions one and two at high pH, but the EDTA containing solution needed the pH lowered to make the copper available for capture. In each example, the copper concentration was significantly reduced by HiPAC SPE treatment.

Jan 1, 1994

By L. A. Taylor, R. O. Colson, D. S. McKay

The production of oxygen on the Moon utilizing indigenous materials will be essential for successful lunar colonization. Several processes have been put forth to accomplish Lunar Liquid Oxygen (LLOX) generation. The schemes that have received the most study to date involve: 1) Reduction of ilmenite (FeTi03) by H2, CO, CH4, CO-Cl2 and Cl2, plasma. 2) Molten silicate electrolysis, both unadulterated and fluoride fluxed. 3) Several others, including H, reduction of glass, carbo-chlorination, HF acid leaching, fluorine extraction, magma oxidation, and vapor pyrolysis. The H2 reduction of ilmenite and molten silicate electrolysis processes have received the most study to date. They are both feasible schemes and have various pros and cons, including their feedstock requirements. However, all processes should be addressed at the onset of LLOX research. This paper reviews several of the most studied and feasible processes for winning oxygen front lunar materials. There is an obvious need for more experimentation and study.

Jan 1, 1994

By V. A. Shea-Albin

Sandstone escarpments surrounding western coal-bearing plateaus serve as critical habitat for animal species. Effects of mining subsidence on escarpment stability are not well documented; therefore, regulatory agencies may limit extraction of coal reserves underlying escarpments. Because millions of tons of this coal exist on Federal Lands, associated public revenues from Federal royalties, and valuable coal reserves, risk being lost. The U. S. Bureau of Mines is using numerical modeling techniques to analyze effects of subsidence on escarpment stability. Finite element models that incorporate bedding plane slip, gob formation, and movement along joints simulate escarpment subsidence observed in the field.

Jan 1, 1994

By David K. Ingram

The objective of this U.S. Bureau of Mines (USBM) investigation was to characterize overburden response due to longwall mining. Subsurface strata and surface deformations were monitored at two sites in southeastern Ohio. Site A included two adjacent longwall panels. Site B consisted of one longwall panel. Both sites had similar mine geometries and overburden thicknesses. The major difference between the two sites was the rock strata within the overburden. Multipoint borehole extensometers (MPBX) were employed to measure subsurface displacements. Survey monuments were installed above the centerline and profile of each panel to measure surface deformations. Subsidence of the surface was observed before and after movement was detected in the MPBX units. Initial and final displacement of the MPBX units occurred at the same time at both sites. No deformation was detected outside the panel area. The development of overburden deformation was different over each panel. The final subsurface failure characteristics also varied between panels.

Jan 1, 1994

Provide the National Park Service (NPS) with guidelines for closing abandoned mine openings such as shafts and adits. Approach The NPS needed alternative methods of closing a variety of abandoned mine openings on National Park lands. Because the U.S. Bureau of Mines (USBM) has a long history of mining-related experience, the NPS requested that the Bureau provide them with technical mine closure information. USBM engineers compiled information on various types of mine closures and prepared technical illustrations of those closure techniques. Multiple closure options, by type of opening, were prepared as one-page field guides to assist NPS field personnel in determining the most appropriate closure method for a given situation and detailing the construction of the closure method. Results Guidelines provided to the NPS included a description of the method, use applications, construction techniques, technical illustrations, and technical support information. The following provides a brief description of 11 mine closure techniques identified for use by NPS personnel. Most of the closure methods, except the backfill methods, allow for construction that can provide access to the mine. However, providing access makes the closure susceptible to vandalism. Most closure methods require periodic monitoring for subsidence and corrosion or deterioration of construction materials.

Jan 1, 1994

By Pesic. Batric

A novel chitosan-pyridoxal-epichlorohydrin was synthesized and evaluated in our laboratories. The evaluation was achieved by performing kinetic and equilibrium studies of copper sorption. The parameters examined were pH, temperature, concentration of copper, particle size and selectivity of copper sorption against iron, zinc, cadmium and cobalt. It was found that pH was the most important parameter, and sorption of copper increased with pH increase in the range pH 2.5-6.0. The low activation energy of the sorption reaction, 1 1.13 kJ/mole (2.66 Kcal/mole), showed that temperature was not an important parameter. The synthesized chitosan was selective against iron, zinc, cadmium and cobalt. The selectivity with respect to last three metals was achieved by the kinetic difference of sorption, as sorption of copper was much faster than for other metals. Iron (Fe2+) does not adsorb on chitosan. The mechanism governing the sorption of copper is intraparticle diffusion. This finding was supported by the dependance of copper sorption on the square root of time, the low activation energy, and the fit of experimental data in the diffusion through the product layer equation.

Jan 1, 1994

By Laxman M. Amaratunga

"The fine fraction of tailings is usually excluded from the backfill process and generally disposed on the surface in tailings ponds. Because of the ever increasing demand for fine grinding in the extraction process for improved liberation of valuables in the ore, increased production of fines in the tailings has resulted. The negative impact of surface impoundment of tailings on the environment is well known. Amaratunga and Annor (1989) first presented a concept of fine tailings agglomeration for backfill.This paper presents the development of the novel cold-bond tailings agglomeration (CBTA) technology for non-reactive fine gold mill tailings. For cold-bond agglomeration regular portland cement was used as a binder. In order to cut costs, alternate binders such as lime, and blast furnace slag cement were examined. The effects of binder dosage, curing time, and agglomerate size on the fracture load strength of the agglomerate were studied.Fine tailings agglomerates are mixed with coarse tailings or non-agglomerated fine tailings to make high density fill compositions to be used as underground backfill. Alternatively, the agglomerates can be used as aggregates for surface applications. The paper discusses the environmental and operational benefits of this total tailings utilization and disposal technology.IntroductionIn Canadian mines, mill tailings are probably the most commonly used material for backfill. However, only the coarse fraction of tailings is desirable for use as hydraulic fill or high density fills. The fines are disposed on the surface in tailings ponds since they are unsuitable for underground backfilling owing to the following factors:i) slow settling ratesii) longer percolation timeiii) excessive consumption of binder due to drainageiv) poor compactionFor improved value liberation more milling operations have resolved to fine grinding in their comminution circuits. Gold milling operations driven by down stream leaching processes grind their ores excessively fine. In general, gold mines use hardly any tailings for backfilling. This can result in periodic short falls and the need to search for alternate backfill material from other sources. Apparently, the gold producers are the most identifiable sector which suffer from a shortage of backfill materials ( Amaratunga and Annor, 1989)."

Jan 1, 1994

By M. W. Wadsley

Despite the convenient subdivision of extractive metallurgy into hydro- and pyro- divisions, many flowsheets contain both types of process. When complex materials are used as feed, combinations of hydro- and pyro-metallurgical processes are even more common. Hydrometallurgy is used to treat many by-products and waste-products. (Bio-metallurgical processes may be considered to be a sub-set of hydro-metallurgical processes.) Combinations of the different processes in the Australian metallurgical industry are described. Selected international examples demonstrate that the use of combked processes is not a unique. Antipodean phenomenon. The motives for selection of combined pyre- and hydro-metallurgical processes in a flowsheet are examined.

Jan 1, 1994

By Lynn B. Hales

There is a large economic opportunity associated with improving metallurgical performance in mineral processing plants that use process control. Thus, future control systems will be developed towards more sophisticated user friendly, computer-based systems that use powerful software analysis and control techniques. Auto-tuning, adaptive control and process models will gain expanded use because of their transparent availability to the system designer. Control of individual unit operations will be optimized and coordinated through expert systems that monitor economic conditions and management directives and direct operations accordingly. Plant areas, once considered cost centers, will be integrated into plant-wide control systems for economic control and optimization. This article looks at new control hardware, process sensors, control strategies and software development tools. It also looks at the economics driving the continued development of advanced process control systems. Process control systems routinely used in the mining industry were born when the microprocessor was invented. They have continued along an evolutionary path from vendor specific processing hardware and proprietary operating systems to computer industry standard "open architecture" systems. The many economic forces that drive the development and functionality of these process control systems will cause this evolutionary process to continue. Two of the broadest categories are the needs of the end users and the desire of the system manufacturers to distinguish their products from one another. More

Jan 1, 1994

By J. G. Groppo, B. K. Parekh

Eastern US oil shale contains approximately 10 to 12 gallons of oil per ton and 7 to 10% pyritic sulfur. Physical beneficiation of these low grade shales using froth flotation provides a high grade material that makes extraction of oil more economically attractive. The Alabama oil shale used in the present study contained 16.46% organic carbon and 14.5 gallons of oil per ton as determined by Fischer assay. Liberation size of the kerogen was estimated at 10 µm. `Ken-Flote' column flotation technology provided a high grade concentrate containing as much as 60% organic carbon. However, carbon recovery was about 60%. Carbon recovery was improved to 75-85% while maintaining concentrate grades in excess of 40% carbon by providing longer retention time in the column, which facilitated effective bubble-particle collision and attachment.

Jan 1, 1994

By D. J. Brennan

A techno-economic study is in progress, examining process and product options for treating smelter gases containing various concentrations of sulphur dioxide. Key contenders have been examined within an Australian context using the following criteria: * Markets for products * Capital Costs * Operating Costs * Waste streams generated Product options considered thus far are sulphuric acid, sulphur, calcium sulphite and gypsum. The development of an appropriate overall framework for evaluating process and product options is discussed and findings thus far presented. The emerging techno-economic study offers promise as a constructive guide to future policy decisions by industry and government.

Jan 1, 1994

By H. J. Brown

Pluess-Staufer (California) Inc. Lucerne Valley California operation is one of the largest producers of high brightness high purity fme grind limestone products in western North America. The San Bernardino Mountains area of southern California contains the largest high brightness, high purity limestone mining operations and undeveloped reserves in western North America (Fig. 1, Brown 1987). Combined annual production of high brightness limestone products from several operations is approximately 1.5 million tons, with an estimated gross value of $75 million dollars per year (Fig. 2). An additional 5.0 million tons of cement grade limestone is mined by several large cement producers in the nearby Mojave area (Brown, in press). The purpose of this paper is to summarize the geologic setting, genesis and mining of white, high purity crystalline limestone by Pluess-Staufer (California) Inc.

Jan 1, 1994

By Serguei A. Diatchkov

The principles of classification of reserves and resources in the Soviet Union were developed in 1960. Mineral reserve calculations were reviewed by the State Committee on Reserves for approval, then registered in the State List of Mineral Deposits and included in the State Balance of the Reserves. In 1981, however, a new "System of Classification of Reserves and Resources of Mineral Deposits" was adopted. This classification system (Table 1) is still used today in the Commonwealth of Independent States (CIS). It subdivides mineral concentrations into seven categories in three major groups, based on the level of exploration performed: explored reserves (A, B, C,), evaluated reserves (C) and prognostic resources (P1, P2, P3). Explored reserves Explored reserves are calculated within exploration contours. Category A The A category is the highest level of classification for any given mineral deposit and requires comprehensive exploration. First, the ore body's position, shape and structure must be accurately delineated (Fig. 1). Next, the mineralogy of the ore body must be studied to determine its composition and properties as well as the distribution of both ore and detrimental components. It is also necessary to outline the blocks of barren rocks and limits of subeconomic ores and to distinguish between the different types, grades and physical-chemical properties (mineral texture and structure) of the ore, the

Jan 1, 1994

By Turgut Yalcin

"Recent years have seen a resurgence of interest in flotation cell design, and one of the areas where attention is being focused is flotation in centrifugal fields which aims at increasing the flotation rates by forced bubble-particle contact.A new cycloflotation device was developed at Laurentian University and tested on the nickel ore of Falconbridge Limited in Sudbury. In comparison with conventional flotation, cycloflotation yielded at least seven times faster flotation rates in terms of the mass of solids floated per unit time per unit flotation volume, while producing concentrate grades similar to those of conventional flotation. These results, which were obtained with a bench-scale ""cyclofloat cell,"" suggest that cycloflotation has the potential of setting a new direction in flotation technology.IntroductionFroth flotation is no doubt the dominant separation technique in the mineral processing industry. Since its inception early in this century, much research effort has been and is still being expended on this process. Until recent years, emphasis seems to have been placed on the chemical aspects of flotation, but there is now an increased awareness for the need to improve flotation machine performance and more and more attention is being directed towards this area. In a 1982 article on ""Flotation Machines"" (Young 1982) it is stated that "" ... by now the design of the machines used would have reached a high level of perfection, ... In fact, this is not the case ... "".The process of flotation in a flotation device may be considered to take place in several distinct stages as follows:"

Jan 1, 1994

By Anthony J. Deevy

"Abstract -The Magino gold mine is located 45 km northeast of Wawa, Ontario. There was limit­ ed gold production in the Iate thirties. The present operation was officially opened in October 1988 and produced gold until September 1992. It was a 635 tonnes per day, decline-accessed mine, with ore coming from several small blast hole and shrinkage stopes.The host for the gold is the Webb Lake granodiorite stock which was intruded into the Goudreau Lake Deformation Zone. This east-northeast-striking deformation zone overprints the generally east­ west-striking isoclinally folded metavolcanic and metasedimentary rocks, which make up the east end of the Michipicoten greenstone belt. The ore-shoots are controlled by dextral delatancy associated with the Goudreau Lake Deformation Zone. Shearing, bleaching and silicification accompanied the gold emplacement."

Jan 1, 1994

The Northwest Territories (NWT) of Canada has emerged as a major new province for diamond mineralisation in less than three years. This is primarily the product of a diligent search in the form of a scientifically based exploration effort. However other factors, including positive aspects of the business and the legal environment have also been identified as assisting the exploration process. In my view these have increased the likelihood of diamond mining becoming a major new industry for Canada. The supportive role of various government agencies has been important. In addition, the character of many of the joint venture deals that have been done has provided an attractive setting for the capital intensive evaluation and development work that is now required to bring the diamond discoveries into production. Perhaps of equal importance is that with the recognition that is being given to the success of the NWT diamond ventures, Canadian explorers are continuing to attract new risk capital for further exploration. This paper attempts to model and quantify the probability of exploration success translating into successful mine development.

Jan 1, 1994

By J. P. Mogan, E. D. Dainty

Polynuclear aromatic hydrocarbon (PAH) levels were measured in underground mines in the vicinity of diesel vehicles equipped with several types of emission control hardware. In general, the emission control devices appeared to reduce PAH levels, but the companion mutagen study suggested that the reduction might not always be beneficial. All underground PAH concentrations were below the threshold at which a significant impact on health might be expected, but recent animal exposure studies have indicated that PAHs may not be the primary hazard from chronic diesel fume exposure.

Jan 1, 1994

By Sam Oaks, David A. Smith

The new Corridor "G" Federal Highway Project in Logan County, West Virginia is the largest mass excavation highway project currently being built in the United States. Seven sections covering 14 miles of four lane highway and two connector roads will require over 30 million cubic yards of excavation. Construction is on a fast track schedule requiring the contractors to complete excavation and pavement placement in a little over 19 months. The two different general contractors have implemented several innovative Blasting and Excavation Programs to complete this project within the tight completion schedule. The paper expands on some of these unique programs that made the project a reality.

Jan 1, 1994