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By A. F. Alsobrook

Specialty silica materials, as defined in this chapter, are rocks that consist predominantly of silica (SiO2) and are produced as chunks, round pebbles, and sawed or trimmed blocks and other shapes for nonconstruction applications. The rock types include quartzite, sandstone, novaculite, flint, chert, and vein quartz. Other terms used commercially include jasper, silex, lascas, and rock crystal. In its publication, Minerals Yearbook, the US Bureau of Mines (USBM) reports the production and consumption of some specialty silica materials under several headings. Quartzite, sandstone, and novaculite used in abrasive applications are addressed by the USBM under Abrasive Materials. Lascas, a type of vein quartz used in growing synthetic quartz crystals and in fusing applications, is discussed under Quartz Crystal. Silica gravel used in manufacturing silicon metal and ferrosilicon, as metallurgical fluxstone, and as a filtration medium is covered under Industrial Sand and Gravel. Information on

Jan 1, 1994

By Howard K. Worner

Several features of smelting and refining operations make them appropriate technology to adapt to the processing of "wastes" not only from the minerals Industry itself, but for wastes in general. These features include significantly higher temperatures than are achieved in conventional Incinerators and also good thermal stability derived from the mass of molten metal and slag in the furnace. This paper expands on Information contributed to the Mervyn Willis Symposium in July 1992 and includes knowledge generated in the last two years of waste processing R&D in a sealed 100kg capacity DC arc furnace specially constructed for the "Environment" process being developed in Wollongong. As one product of-the process is a foundry-type iron, the feed always contained ferruginous dusts or heavily contaminated scrap. For the dusts, sewage sludge has been used as a binder and also as a proportion of the fuel-reductant. To achieve the necessary bath carburisation, It is beneficial to add other lower reactivity carbons such as "kish' graphite, carbon from electrode butts, dusts from coke ovens, carbon from aluminium pot line residues, dry cell batteries etc. Metallurgical factors involved In process control, Including metal and slag, compositions, are discussed.

Jan 1, 1994

By Timothy J. Rohrbacher

This report presents a U.S. Bureau of Mines study that incorporates coal mining factors, coal recovery factors, and economic factors into the definition of an economically recoverable coal resource. The relationship between these factors to the Energy Information Administration's estimate of U.S. coal resources-the "Demonstrated Reserve Base"-is discussed. The Boltsfork 7 1/2-minute quadrangle in eastern Kentucky was selected as the study area. Results indicate that of the original 280.2 M tons of resource in the quadrangle, only 99.8 M tons (35.6%) is recoverable at a mining cost of $25 per ton or less.

Jan 1, 1994

A technical exhibition was held in conjunction with the 4th DFI International Conference on Piling and Deep Foundations, Stresa. The exhibition was located in the ground floor of the Conference Hall. It was open from 15.30 on Monday April 8 till 16.30 Thursday April 11, 1991. The following is an alphabetical list of firms who took part. 1) A.P. VAN DEN BERG MACHINENFABRIEK B.V. P.O. BOX 68 8440 AB HEERENVEEN The Netherlands Tel: +31 5130 31355 Fax: +31 5130 31212 Stand Executive: A. Duyfjies

Jan 1, 1994

By Alan J. Hurd

"New insights into the development of microstructure in sol-gel films have recently been revealed by several diagnostic techniques, including imaging ellipsometry, ""chemical imaging"" by fluorescent tracers, light scattering from capillary waves, and finite-element modeling. The evolution of porosity during the continuous transition from dilute sol to porous solid in restricted geometries such as films and fibers is becoming clearer through fundamental understanding of evaporation dynamics and capillarity.IntroductionWith sol-gel processing, the full flexibility of solution chemistry can be exploited to make ceramic films and fibers with well controlled compositional characteristics. No less important is the ability to tune porosity and connectivity for specific applications such as optical and electrical coatings and membranes. Since the chemical and physical factors that determine the microstructure are not entirely understood, new diagnostics applied to sol-gel processing are welcome.Sol-gel films and fibers are distinguished by processing that takes a sol through continuous stages of increasing concentration and connectivity of a solid precursor. The liquid carrier is usually volatile or, at least, volatilizable through heat treatment. During deposition through states of increasing solids concentration, this sol might gel, as in bulk sol-gel processing, however, the gel state may be a fleeting transient that quickly empties of liquid. Nevertheless, the structures formed in solution during this stage influence the structure of the final solid. In particular, porosity is likely to be a remnant of networks formed in the sol-to-gel transition. Here we report on experiments whose goal is to discover the factors involved with porosity development."

Jan 1, 1994

By E. M. Yates, H. M. Hamilton

"For the assent of any new mining project it is essential to determine a realistic value of revenue from the sale of concentrates.A description of the market factors influencing the concentrate terms will be presented along with a detailed review of historical terms of a smelter contract for zinc concentrates. OverviewFor the assessment of any new mining project it is essential todetermine a realistic value of revenue from the sale of concentrates.This applies at all stages of assessment through to the final feasibilitystudy. In forecasting revenue for a zinc mine the followingfactors must be considered:(a) mill recovery and zinc concentrate grade;(b) metal price forecast for all payable metals;(c) smelter terms; and(d) other selling costs.Normally, data from test work are used to determine mill recovery and concentrate grade.Market forecasting, and indeed all economic prediction is an inexact science and probably will always remain so. We have our econometric models our input/output models and a lot of other tools. But they are of no help in predicting the unpredictable. OPEC's huge increase in the price of oil was certainly the most dramatic example of this. It had a tremendous effect on the cost of producing most products world wide and on the price of these products. Any forecasts made prior to the OPEC action were obviously proven wrong."

Jan 1, 1994

By Eric Konigsmann

"Omai Gold Mines is a large scale open pit gold mining operation located in central Guyana, South America with a 12,000 tonne per day milling facility. Mill operations were initiated in December 1992 with commercial production beginning in January 1993. The entire operation employs approximately 120 expatriates and some 800 Guyanese nationals and is expected to produce in excess of 250,000 ounces of gold per year. The total mineable reserves contain 2.5 million ounces of gold with a projected mine life of twelve years.The milling circuits feature an SABC grinding circuit, gravity concentration and a conventional CIP gold recovery circuit. This paper will review the mill start up and ""run-in"" phase during the first year of operation. Emphasis will be placed on descriptions of start up problems and circuit modifications, mill performance trends in 1993, and personnel training and development. An outlook for 1994 is also given.IntroductionOmai Gold Mines is a large scale, open pit gold mining operation located in the Potaro district of Guyana, South America, some 160 kilometers south of the capital city Georgetown. Although there are numerous small scale gold mining ventures in Guyana, particularly with the dredging operations on the rivers, Omai is the first hard rock, open pit mine to be developed in the country. At present, this mining operation is one of the largest gold mines in South America.The Omai gold deposit has been exploited for over one hundred years. In the late 1800's, a German syndicate used hydraulicing with subsequent gravimetric separators such as sluice boxes and trommel screens to recover gold from saprolite, a soft, oxidized, claylike mineral which covers much of the claim area. Through the early 1900's and up until the 1950's, numerous mining companies including Anaconda Mining Co. Ltd. explored and drilled the Omai deposit but the technology and low gold price of the day made the reserve uneconomic to develop."

Jan 1, 1994

By Saskia Duyvesteyn

Ion flotation is a technique applicable to the removal of metal ions from dilute solutions, using ionic surfactants.- While there are a number of physical and chemical parameters that influence the ion flotation process, this paper focuses on two of the important chemical ones, namely frother concentration and ionic strength. The effect of several frothers, including ethanol, iso-propanol and MIBC at concentrations ranging from 0% to 0.4%, was studied for the model Cd-dodecylsulfate and Cu-dodecylsulfate systems. The ionic strength, as well as the effect of monovalent and multivalent counter ions, was also studied in the range of 1@3 - 1 M, at constant pH. The results are discussed in terms of applicability to a range of effluents from minerals and materials processing operations.

Jan 1, 1994

By Satian Niltawach

Iron sulphate jarosite through which iron in zinc sulphide concentrate feed is removed from the production circuit of conventional roast-leach-electrowin process, is chemically unstable and environmentally hazardous even if it is mixed with lime. If zinc silicate ore is used at similar chemical conditions in place of calcine in the jarosite precipitation, the resultant silico-jarosite residue having been mixed with lime is chemically stable and environmentally friendly. The recovery of zinc from silicate ore is also higher than that from calcine.

Jan 1, 1994

The effect of change in slag composition upon metal losses to the slag and the relationship between slag composition and slag matte separation was investigated at 1400°C. The synthetic slags containing CaO, MgO, SiO2,, A1,0, and FeO were similar to those employed in the electric furnace smelting of sulphide Cu-Ni concentrates containing PGM (Precious Group Metals) from the Merensky Reef of South Africa. The matte with a grade of 9.3% Cu and 16.0% Ni was a typical electric furnace product. The results indicated that the Cu and Ni solubility in the slag increases with the increase of the basicity ratio and CaO and MgO contents of the slag. At constant CaO/MgO ratios the rise in basicity decreases the metal losses. When FeO and SiO2 contents of the slag are kept constant, the substitution of MgO with CaO decreases the metal losses. The relationship between slag composition and matte-slag separation was found to depend primarily on the basicity ratio and the FeO content of the slag. The net effect comes from a strong interaction of the two in such a way that increasing basicity and decreasing FeO contents deteriorate the clean separation of the two phases.

Jan 1, 1994

By Lewis L. Oriard

This paper describes the process of developing blasting specifications for 850 miles of new pipe trench running parallel to an existing high-pressure gas pipeline, often with as little as 14 ft to the existing pipeline trench. The primary method of preventing damage to the existing pipeline was the use of fracture (overbreak) control.

Jan 1, 1994

Pictured on these pages are seven of the eight RMCMI Scholarship Award Winners for the 1993- 94 year followed by a brief profile. Seven of the eight winners were present as guests of the Institute at the June convention in Snowmass Village, Colorado to receive recognition at the Institute Awards Luncheon Monday, June 27, 1994. Due to another conflict. Jason T. Dale of Wyoming was unable to attend. Each state vice president sewed as the host for the collegiate winner. In addition to receiving a plaque from the Scholarship Chairman. Alan Czarnowsky, each winner receives $750 tuition credit for the coming academic year, as well as transportation, hotel lodging and meals at convention as guests of the Institute. Because this is a continuing award, the winners from the previous year will receive another $750 for tuition credit in their senior year if they have maintained good academic standing and are recommended by their university. A resident from each of the eight RMCMI member states is selected from among Board approved institutions. Criteria for these awards to be made in the spring annually is (1) That the award be made to a sophomore student and used as tuition during the junior year. (2) That the recipient be both a U.S. citizen and a resident of the member state. (3) That the recipient have good academic standing, be pursing a degree in a mining related field and have an expressed interest in Western coal as a possible career path. The scholarship program includes curricula other than those in the mining departments, but in engineering disciplines, such as geology, mineral processing and metallurgy. Contributions to this worthy project are tax deductible to each individual RMCMI member or his firm. Through annual donations of $100 or more, the Patrons of the Institute fund the scholarship program and the various vice presidents contribute the travel expenses to convention for these outstanding young collegiates. Donations to this worthwhile program may be made payable to RMCMI Scholarship and mailed to the RMCMI Office. 3000 Youngfield Street, Suite 324, Lakewood, CO 80215. Profiles of the 1994 Scholarship Winners follow. [ ] ARIZONA WINNER Christy L. Brandt University of Arizona Tucson. Arizona Christy Brandt is the 1994 RMCMI scholarship winner from Arizona. She is majoring in Mining Engineering at the University of Arizona in Tucson, Arizona, but recently is considering switching to Environmental Engineering with emphasis on mining. She told the Scholarship Chairman that if she wasn't part of the solution, she was part of the problem. Christy has received numerous awards during school including being on the honor roll and university chapters of Society of Mining Engineers. Besides her academic activities, which includes being a member of Student Council, Christy is quite an athlete and enjoys basketball, softball, tennis, golf, and soccer. Last summer, she worked as a safety assistant/laborer for the Magma Copper Company. This summer, Christy is working in the safety department at Magma Copper Company's Pinto Valley Mine in Arizona. [ ] COLORADO WINNER Jason P. Markle Colorado School of Mines Golden, Colorado Jason Markle is the 1994 RMCMI

Jan 1, 1994

By Romano J. Micciche

One of the largest scale uses of a multiple, high-strength steel bar tiedown system is described. Tiedowns were installed to resist hydrostatic uplift forces acting on a section of the Interstate Highway Route I-90 southern approach roadway to the Third Harbor Tunnel, in Boston, Massachusetts. Site specific information is discussed regarding design, testing, and installation of Tiedowns. Conclusions are presented regarding the overall performance of this system and the application of this type of tiedown system on future projects.

Jan 1, 1994

By Aïda Espinola

This work is part of a research program concerning the study of heavy metal removal and selective recovery from electroplating waste waters in the Guanabara Bay ecosystem, preventing the potential noxious retarded effect of landfill, specially in a country of heavy rainfall. A flow-throw cell was employed to adapt to the limits established by the local legislation for disposal in rivers and seas. The cell design is presented and preliminary results show that this cell may be applicable for the decontamination from copper.

Jan 1, 1994

By Alan Weakly

The Powder River Basin (PRB) of northeastern Wyoming and south-central Montana is the largest strippable reserve of compliant coal (0.6 or less lb of sulfur per million Btu) in the United States. In mining parlance, it is the Mother Lode! Wyoming’s portion of the Basin provides one fifth of the coal produced in the United States annually, and the state has been the nation’s top coal producer for the past six years. Based on 1993 production statistics and estimated strippable compliance coal reserves, Wyoming may remain the nation’s top producer for the next 76 plus years. Past articles on the PRB have focused mainly on production. After living and working in the Basin for the past five years, I have developed an appreciation for the area and its major industry that transcends size and production data. In the fall of 1993, MINING ENGINEERING’s publisher and I decided to present a series of articles that would cover many other aspects of the Basin. Ten topics were outlined, and specific individuals, selected for their knowledge and experience, were asked to contribute articles about their specialties. Although Montana has four large mines producing coal from the PRB, this series of articles will concentrate on the Wyoming portion of the Basin.

Jan 1, 1994

By Andrew B. Cecala

This U.S. Bureau of Mines report provides a detailed description of the Bureau-designed modified shearer clearer system. Engineering drawings are provided for all major components of this system. The modified shearer clearer system is a revised version of the original system and is intended to improve the ventilation around both cutting drums. The original shearer clearer technique was solely a dust control technique that has been effective in lowering shearer operators' dust exposures. The technique uses a series of water sprays that not only knock down a portion of the dust cloud but also act as small fans that move a substantial amount of air and keep the dust cloud from dispersing over the shearer body. The modified version is composed of two additional spray blocks for improved air movement around both cutting drums, thus lowering methane levels and the likelihood of an ignition. A laboratory study performed with the modified version in a full-scale longwall gallery resulted in a 73-pet reduction in methane concentrations at the shearer machine for both cut directions. The air-moving capabilities of the system provide more turbulence at the cutting drums and reduce methane levels.

Jan 1, 1994

By R. Bhaskar, H. Xie

Fractal theory was horn in the mid-1970s. Since then, its application has been spreading day by day, from mathematics and geology to areas such as geophysics, physics and material sciences. In this paper, fractal models are developed to characterize particle size distribution and surface area. Theoretical formulas are derived for the computation of fractal dimensions D (size) and D[s] (surface area). The models developed are applied using experimental data of particle size distribution and surface area obtained from the Microtrac Particle Size Analyzer for dust processed by several size reduction devices. The theoretical models and the experimental data are found in good agreement. The fractal dimensions obtained are D = 1.350 to 1.770 and D[s] = 2.058 to 2.584 for fine coal dust particles (< 15 µm) produced by various size reduction mechanisms. The physical meaning of these fractal dimensions is also related to the dust generation processes.

Jan 1, 1994

By B. Q. Li, S. P. Song

"This paper describes an on-going research on developing coupled boundary element and finite element algorithms for the solution of thermal and electrodynamic problems relating to materials processing. The coupled methods are uniquely suitable for field problems involving composite regions, in which detailed information on field distributions within one particular region is of more interest and yet the solution can be obtained only if the effects of other regions are all considered. Problems of this type include heat transfer in multiple regions and also magnetic induction involving an infinite boundary. The hybrid boundary and finite element formulation, algorithm development and the applications are discussed. Two examples are given to demonstrate the capability and accuracy of the coupled algorithm for heat transfer problems. Various treatments of corner discontinuity are discussed. It is found that the double flux treatment is an ideal choice amongst those tested as it is easy to implement and also gives the most accurate solution. 1. INTRODUCTIONElectrodynamic and transport problems occur frequently in materials processing systems. Accurate solution of these problems is of great importance not only for our fundamental understanding of physical principles governing these phenomena in the processing systems but also for optimization of the existing processes as well as development of new processes. For this purpose, many numerical algorithms have been developed. These computational schemes in general can be classified into three categories, that is, the finite element and finite difference schemes and the boundary element scheme. The former two are domain based numerical algorithms while the latter the boundary-based algorithm.The finite element method, which is based on the variational calculus, is a very useful and yet popular engineering numerical method for boundary value problems defined over irregular boundaries. The use of the method requires the discretization of the entire domain. It can be applied to solve both linear and nonlinear problems, but is particularly powerful for nonlinear problems that involve the field variables defined within the computational domain. On the other hand, the boundary element method, with its root in the Green's function method, is very efficient for linear boundary value problems or nonlinear problems that involve field variables only along the boundaries. The primary advantage of the boundary element method lies in the fact that only the boundaries of the computational domain need to be discretized, and hence the dimension of the problem is reduced by one, compared with the finite element method."

Jan 1, 1994

By Robert B. Fulton

The objective of this chapter is to discuss the interrelationship between industrial minerals and chemical manufacturing. It is intended to supplement rather than duplicate the commodity chapters. Particular emphasis is given to the pertinent chemical element and to market factors. Condensing this broad subject into a few pages of this handbook permits treating only the most important elements derived from industrial minerals. Hydrocarbons, which quantitatively dominate as raw materials for the chemical industry, are omitted, as are the metallic elements and the minerals covered in other "use" chapters such as phosphorous, potassium, and nitrogen for fertilizers, and titanium dioxide for pigments. The remaining six elements of major importance are: boron, bromine, chlorine, fluorine, sodium, and sulfur. These elements are treated individually under separate headings. [Table 1] affords an overview of the main industrial minerals, the chemical products derived from them, and end uses of the products. Salt brines have particular importance as raw material sources for the chemical industry. Table 2 is a chart of the chemical compounds derived from four types of brines: (1) Owens Lake-type brines, which are sources of boron and sodium compounds; (2) Midland-type brines, from which bromine, iodine, and chlorides of calcium, magnesium, potassium, and sodium are derived; (3) Searles Lake-type brines, yielding boron, bromine, lithium, magnesium, potassium, and sodium compounds; and (4) Silver Peak- type brines, produced mainly for lithium. MARKET ATTRIBUTES Some of the important market traits common to industrial minerals used by the chemical industry are: 1. They are international commodities, such as fluorspar and sulfur, which largely move to foreign consumers. 2. Grade, and freedom from deleterious elements are important factors affecting their usability in chemical processes. An example is salt (NaCl) used in electrolysis where ultrapure evaporated salt is required to meet rigid specifications. 3. Purified products take on the characteristics of specialty items and command a distinctly higher price than the basic commodity from which they are derived. 4. In practically all cases, chemical users require some sort of cleaning or beneficiation of the naturally-occurring mineral to bring it to specification, and individual specifications may vary from user to user for essentially the same use. 5. In some instances it is necessary to strike a balance between what the vendor can supply and what the buyer requires, with the result that specifications have to be eased to afford the needed materials in marginal cases. 6. Because they tend to be bulk commodities, low cost for handling and transportation are important and such costs may limit the area from which a chemical user can draw his supply. 7. Shipments are usually in bulk and frequently in multiple-car, full-trainload or full-shipload lots to reduce transport costs, which in turn may require large terminal investment facilities. 8. Purchases are generally by contract of one year or longer term, with spot buying playing only a minor role. 9. Contract prices are usually fixed in short term commitments, but may vary according to assay, with premiums and penalties for content above or below the norm; however, general practice is for specifications to be fixed in the contract with minimums being set for the desired material and maximums for undesired elements. In longer term contracts, prices are often escalated on labor, fuel, and other vendor processing costs. 10. Suppliers of individual commodities to the chemical industry tend to be limited in number and are generally medium- to large-size producers that supply a few major consumers. 11. The bulk of the mineral volume is for basic chemical uses, sulfur suppliers to sulfuric acid producers and fluorspar for hydrofluoric acid producers being typical examples. These basic chemical products then are used for the production of other products. 12. Shortage of a supply of adequate quality leads consumers to seek substitutes. In the case of fluorspar, much work is being done on recovery of fluorine from phosphate rock. Success in the form of fluorosilicic acid and/or hydrofluoric acid production could, in time, affect the hydrofluoric acid chemical industry. 13. Markets tend to be characterized by cycles of shortage followed by oversupply, with attendant wide price fluctuations. 14. Baniers to trade can have an adverse effect on the necessary movement of industrial minerals used by the chemical industry in international trade. Antidumping laws, quotas, and tariffs can disrupt or dislocate normal markets. 15. Chemical industry consumers may back-integrate for security of supply or for favorable economics, sometimes by joint ownership and often with experienced mining partners.

Jan 1, 1994

By Ivette E. Torres

Of the 15 selected non fuel mineral commodities detailed in table 12, only 3 indicated increases in worldwide consumption in 1992. As in 1991, decline in consumption levels of the selected commodities can be attributed to reduced levels of use in the former U.S.S.R. and Eastern Europe. Of the remaining 12 commodities, 2 magnesium and cadmium, stayed relatively the same, while the other 10, including iron and steel, all recorded decreases. Global consumption of iron ore is estimated to have fallen about 3.5 % or about 30 million tons. This is a greater decline than what was estimated for production of iron ore, which is down only 2.7% or nearly 26.5 million tons, suggesting an addition to stocks. The consumption trend for iron and steel has been declining since 1989. This has mainly been due to the continued drops in use in the former U.S.S.R. and Eastern Europe. Even as the European economy begins to turn upward, there may only be a slight increase in consumption of iron, steel, and cement, considering the high cost of construction needed to modernize factories and buildings in Eastern Europe. Many feel that the economies of these countries are limited by the current status of their industries.

Jan 1, 1994