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By F. J. Reichhardt

Abstract -The Molopo Farms Complex is a major, layered ultramafic/mafic, early Proterozoic intrusion which is totally covered by sediments of the Karoo and Kalahari Formations and situated in southern Botswana and northeastern South Africa. The approximately 3000 m thick, generally fine- to medium-grained ultramafic and mafic cumulates are intrusive into equivalents of Transvaal Supergroup sediments and lavas. Multiphase deformation resulted in tilting and segmentation of the Complex into individual tectonic blocks. Sr isotopes document at least two chemically distinct parental liquids which interacted in a complex manner to form an approximately 1000 m thick rhythmically layered succession which straddles the ultramafic/mafic boundary. Repeated mixing resulted in a complex cryptic layering pattern and numerous sulfide-enriched layers which contain significant PGE +Au concentrations.

Jan 1, 1994

By J. Y. Kim, Kenneth Stowe, Stephen Chryssoulis

"A series of flotation tests was carried out on Brunswick Mining ore with various pH modifiers (soda ash, lime, KOH) and added ions (ferric, nitrate, sulphate) in the copper lead rougher circuit. The main objective was to identify downstream effects on sphalerite activation and subsequent zinc rougher flotation. Some significant differences in zinc flotation were obtained. Most notably, soda ash and nitrate ions had a positive impact and ferric ions a pronounced negative effect on selectivity.Selected products from the flotation tests were deslimed at 400 mesh, washed with methanol, air dried, placed in teflon vials purged with nitrogen and stored at -15 degrees C. Numerous liberated sphalerite and pyrite particles were selected under a stereoscope and placed in rows on indium foil. The surface compositions of the particles were analyzed with an innovative laser probe (LIMS). The very small analysis area of the LIMS enables the surfaces of individual grains to be characterized. In addition, the rapid analysis time allows a statistically significant number of grains to be analyzed quickly.Surface lead appears to play a major role in zinc activation/flotation. Possible mechanisms are proposed to explain the variations in metallurgical performance at the different test conditions.IntroductionAlthough the bulk composition of mineral grains is an important consideration for the mineral processor it is ultimately surface composition and topography (edges and dislocations preferred sites for reactions) that control reactivity in flotation and cyanidation (passivation, encapsulation and preg-robbing). Determination of the surface properties of particles from process streams poses a particular challenge for the surface chemist for a variety of reasons, including:"

Jan 1, 1994

By P. J. Arps

Cyanide (CN) is used to recover gold from its ores in many locations worldwide. In spite of the established history of gold mining in Alaska, modern cyanidation methods have been used at only one location, the Ryan Lode Mine at Ester Dome, near Fairbanks. Ore was processed by heap leaching between 1987 and 1989, when permitting issues caused operations to be terminated. Those issues have since been resolved, and plans to reopen the mine are currently being discussed. Plans are also proceeding to develop several other ore deposits in the state, all of which include the use of cyanide for gold recovery [6]. Since tailings and effluent water produced from these mines will require treatment, it is important to develop detoxification methods suitable for the Arctic and sub-Arctic conditions found in Alaska. Several methods exist for removing cyanide from mining wastewater. However, most industrial users prefer chemical treatment systems, and typically use sodium hypochlorite, hydrogen peroxide, or sulfur dioxide/air/copper to oxidize free and complexed cyanides [9]. Biological treatment has been used successfully at two sites in the United States [30,32] and field tested at several others [20,27,28]. In addition, one mine uses "natural processes", which include natural oxidation, photodegradation, and degradation by naturally occurring bacteria [33].

Jan 1, 1994

By J. J. McClelland

The face area of a continuous mining section of an underground coal mine is the most dangerous area in the mine. Workers there are at nearly twice the risk of death or disabling injury than those in other parts of the mine. Despite extensive training of miners and improved equipment and mining methods, fatality and injury rates have remained constant during the past few years. It is clear that advanced research is necessary to apply new technologies or modify work procedures to solve the continuing problem of the loss of lives and the numerous injuries at the mine face. A U.S. Bureau of Mines research program is developing a Reduced-Exposure Mining System (REMS) that relocates personnel operating the mining machinery at the face away from the hazards to a nearby haven of relative safety. REMS uses proven technologies of computer automation and robotics to help control the operation of the mining machines at the face, while personnel are moved away to a nearby, safe control room. In this protected, well-ventilated environment, they can supervise or control the operation of the machines while viewing what the machine is doing using video and graphic display monitors.

Jan 1, 1994

By P. R. Taylor

Recent research by the investigators has evaluated the oxidation roasting of refractory gold concentrates in the presence of hydrated lime. (Taylor, 1990, 1991, 1992, 1993). These results have indicated that it may be possible to roast concentrates in such a way as to contain nearly all of the sulfur and arsenic in the roaster calcine and that cyanidation may be possible. To further evaluate the behavior of this type of roasting system a laboratory cyclone reactor was built and operated using pyrite and hydrated lime as a .model system. Approximately 50 years ago, the principle of cyclone firing entered practical boiler construction. The appeal of the cyclone configuration was that it afforded the flash combustion process greater efficiency due to turbulence-induced increased mass transfer, heat exchange, and combustion rates.

Jan 1, 1994

By R. De Ruiter

"In times when mines are emphasizing cost reductions, a properly rebuilt shall conveyance can be more cost-effective than building a new unit. Awareness of the safety aspects of conveyance design along with proper maintenance playa large part in reducing operating costs. A knowledgeable operator can maintain a high level of safety and significantly lengthen the service life of a conveyance. Such an operator is also in a better position to determine when a major overhaul is necessary.After the decision has been made to rebuild, operators must decide who will do the overhaul. Whether the work is to be done in-house or contracted out, the goal is to achieve a conveyance recertified to ""as new"" condition. By dealing with conveyance rebuilds as an engineered product, operators can be certain they are getting a top quality product for their money.This paper deals with the engineering aspects of conveyance rebuilds. Actual examples of typical problems are discussed and corrective action outlined. Design considerations such as proper material selection, component fatigue due to cyclic loading, effects of stress concentrations and corrosion are all part of the initial design considerations that must carryover into the rebuild process. All too often equipment overhauls are done by people who are not experienced in conveyance design.As a manufacturer of mining equipment, Wabi has gained expertise over the past 70 years. By sharing this knowledge the company hopes to create a safer work environment and help to reduce operating costs."

Jan 1, 1994

By F. G. Miller, M. Polat, S. Chander

Flotation was used to achieve improved separation of magnetite from the float and sink products obtained from heavy medium separation and to reduce the load of the medium cleaning circuit. The investigation was carried out in two successive phases. In the first phase, tests were performed on in-plant samples from the Homer City Coal Perdition plant to determine what effects variables such as medium density, particle size and magnetite source had on the efficiency of the process. In the second phase, the optimum conditions determined in the first phase were used to determine the applicability of the process to other selected coals from central Pennsylvania. It was observed that flotation was very effective in the separation of magnetite from coal. In most of the cases investigated, the magnetite recovery was approximately 99% with a magnetite grade ranging from 95 to 99%. The grade of the magnetite decreased as the ash content of the coal increased and the particle size of the magnetite decreased.

Jan 1, 1994

By Pradip

The development of highly selective mineral processing reagents, which are not merely metal-ion specific, but specific to the particular mineral surface structure, is essential for the exploitation of relatively more difficult-to-process ore deposits, in particular for the separation amongst minerals having the same constituent ion. Both the choice of the functional group as well as the molecular architecture of the reagent determine its selectivity. Several examples are presented in this paper to illustrate the concepts of structure specificity and molecular recognition at mineral surfaces - the concepts crucial to the advancement of the emerging science of reagents design. Recent advances made in the understanding of molecular interactions involved in the synthesis of biomineralized materials are discussed so as to delineate the utility of this approach in the design of selective reagents for mineral separation.

Jan 1, 1994

By F. N. Kissell, C. D. Litton

This study ranks the factors impacting survival during a coal mine fire. It has already been established that reducing time delays is the most important factor in saving lives. Consequently, every event during afire is measured in terms of its duration, and the effectiveness of any action taken to improve survival is measured in terms of the time it saves. By ranking actions according to time saved, these authors found that a combination of actions was most effective. This combination was: •installing lifelines, •moderately decreasing air leakage and •decreasing the fire growth rate. Changing ventilation leakage alone was much less effective, as was altering the CO (carbon monoxide), sensor alarm threshold. These results confirm an earlier fault-tree study on escape from mine fires. The fault-tree study had shown that, with the exception of delays, single-factor changes have minimal impact. Significant reductions in fire fatalities only take place with multiple factor changes.

Jan 1, 1994

By Ann M. Hagni

Electric arc furnace (EAF) dust from the secondary steel industry contains lead, cadmium, and chromium that causes it to be classified as a hazardous waste. Pyrometallurgical treatment of EAF dust is directed at recovering zinc and simultaneously rendering the dust non-hazardous. The mineralogy of the EAF dust is important in determining the occurrence and phase relationships of the zinc, lead, cadmium, and chromium contents. The principle phases in EAF dust as determined by reflected light microscopy, SEM-EDS, and XRD are solid solutions of the iron spinels (franklinite, magnetite, and jacobsite), zincite, hematite, and Ca-Fe-Si glass. Chromium is present in small amounts in solid solution in the spinels. Cyclone sizing of the minus 53 pm particles shows that more than 50% of this size fraction are less than 10 pm in diameter. The <I0 pm particles contain zinc as both franklinite in solid solution with magnetite and jacobsite, and zincite as determined by transmission electron microscopy and XRD. Auger electron spectroscopy did not detect coatings of volatile phases on the surfaces of EAF dust particles.

Jan 1, 1994

By Olusegun J. Ilegbusi

"A two-fluid model is used to calculate flow and heat transfer characteristics of a plasma jet. This model accounts for both gradient-diffusion mixing and unmixing that may result from pressure-gradient-body-force imbalance in the system. The unmixedness is considered to be essentially a Rayleigh-Taylor kind instability. Separate transport equations are solved for the plasma and ambient gas velocities, temperatures and volume fractions. The two fluids allowed to exchange mass, momentum and energy through empirical interaction parameters. The empirical coefficients are first established by comparison of predictions with available experimental data for shear flows. The model is then applied to an Argon plasma jet ejecting into stagnant air. The predicted results show the significant build-up of unmixed air within the plasma gas, even relatively far downstream of the plasma torch. By adjusting the inlet condition, the model adequately reproduces the available experimental data on the temperature profile.IntroductionPlasma jets have important applications in materials processing, some of which include spray deposition, melting and refining, heat treatment and materials synthesis. In a typical reactor, the hot plasma stream entrains a surrounding gas and the resulting heat and mass transfer and the condition of operation of the torch, determines to a large extent, the performance of the unit. The entrainment may prevent uniform mixing and produce regions of unmixed hot/cold gases and non-uniform deposits as a result of insufficient melting of deposit in cold regions. This phenomenon may also affect chemical reaction rate in plasma systems for NOx reduction in exhaust gases.The study of plasma phenomena is often conveniently divided into three parts namely, the plasma torch, the plasma jet and analysis of the particles carried in the jet. The present work concerns processes occuring in the near-field of the plasma jet i.e. just downstream of the torch."

Jan 1, 1994

By G. Bonifazi

In the present work the possibility to utilize the morphometrical and morphological characteristics of an articulate solids system in a slurry flow to monitorate and to control a continuous process is considered. This goal has been reached by mean of an optical system able to acquire, to handle and to process the pictorial information derived by a suitable hardware architecture designed to realize the best lighting, focusing and sampling conditions for the examined flow stream domain. The procedure has been tested using different flow stream slurries coming from different sections of a beneficiation plant. A suitable strategy and a consequent software architecture has been set up in order to assure to the system the necessary speed and the stability to achieve correct on-line measurements and control.

Jan 1, 1994

By P. K. Berger, G. T. Lineberry, H. P. Cole, J. V. Haley

Sixty-five simulation exercises were developed for teaching and testing problem solving and decision making skills to miners and mining engineers. The exercises focused on judgment and decision making for preventing and controlling mine emergencies. The structure and field testing of the exercises are described, and sample frames of individual exercises are presented. Empirical data are summarized about the effectiveness of these simulations based on the performance scores of a national sample of miners and mining engineers.

Jan 1, 1994

By R. M. Westcott

A two-electrode, direct current, slag resistance furnace (SRF) has been constructed and operated to selectively reduce the zinc and lead contents of non-ferrous slags. The experimental SRF is equipped with multiple methods of gas/solids injection for both mixing and reaction. A computer is used to position the electrodes and for data acquisition. A geometric factor correlation was previously developed at Columbia University for calculating the electrical resistance on the basis of furnace geometry and slag conductivity. The experimental SRF was used to test this correlation.

Jan 1, 1994

Nine case studies are presented to illustrate how risks can be, minimised or quantified during pit optimisation, utilising Whittle Four-D software. Each case study covers a specific problem that has been encountered from a wide variety of pit optimisations. Case A: Maximising profits when the tenement owner is paid a royalty on tonnes processed. Case B: Allocating product prices, rather than a single commodity price during optimisation. Case C: Quantifying processing costs that are affected by penalty elements in the ore. Case D: Exploration expenditures below current pits can be quantified through the use of simulation techniques. Case E: Alternative strategies can be quantified when pits are restricted by tenement boundaries. Case F: Relocation of mine infrastructure that requires large capital expenditures, can be simulated by allocating costs to an area during optimisation. Case G: Evaluating alternative corporate strategies during pit optimisation. Case H: Sensitivity analysis for price, processing cost and mining cost. Case I: Quantifying the advantages of using additional mining capacity during the early periods of mining.

Jan 1, 1994

By Ivette E. Torres

The final 26 tables of this chapter, tables 24-49, extend and expand the statistical series on production that was started in the 1963 edition of the Area Reports: International volume of the Minerals Yearbook and that was subsequently updated and expanded in the 1965 and 1967-90 editions. Mainly because of the separation of the countries that formed the U.S.S.R., the column that provided a 5-year average, was deleted. The listing order of major producers, however, continued to be, as in past years, in descending order of rank in the year of review, 1992. This group of tables now includes each of the top 19 crude minerals in 1983 in terms of value of their output plus 3 others of lesser rank. These 22 crude mineral commodities accounted for more than 98 % of the estimated value of world crude mineral production in 1983. Coal production, included in the 1983 value of production table as two separated entries, is combined in one table in this chapter. World output of five key downstream products-aluminum, steel, cement, nitrogen in ammonia, and refined oil-is included because of their significance as products.

Jan 1, 1994

By S. Zakaria

"Inco&apos;s Automated Haulage Truck System (AHT) is a revolutionary automatic guided vehicle that performs all load, haul and dump operations without human intervention. The high level of sophistication and the short period it has been in operation has only allowed a select few Inco personnel to become familiar with the ART operation and maintenance. As an aid to operations an expert system using the knowledge gained from the experienced specialists was implemented in the field.The AHT operating and maintenance assistance expert system will reason through the information given, arrive at conclusions and give advice to operations, technical and management personnel. It will provide comprehensive real-time troubleshooting assistance for the hydraulic, electrical and mechanical subsystems of the ART. The ART expert system has many benefits to Inco which include increased skill levels of ART operations and maintenance personnel, reduction in ART downtime, standardization of troubleshooting procedures and reduction in ART operating and maintenance costs. In the future, the expert system application will be linked to SCADA (Supervisory Control and Data Acquisition), maintenance and statistical software to display current and historical trends of variables from a centralized historical database. As well, a wide variety of features will be integrated into the system including AutoCad drawings, graphics, photographs, voice and video capabilities."

Jan 1, 1994

By Letz H

An investigation of earthquake hazard in Papua New Guinea (PNG) by a yearly extreme magnitude method using the magnitude 7 earthquake record since 1900 shows that the Bougain-ville Island seismic zone is by far the most active, followed by the New Britain and northern mainland PNG regions. Return period for magnitude 7.0 earthquakes occurring in normalized 10,000km2 areas of the Bougainville Island, New Britain, Huon, West Bismarck, North Sepik and Ramu seismic zones is 37, 60, 81, 88, 125 and 125 years respectively. These areas are much more active than the California Seismic Zone 4 region including the San Andreas Fault, which has a normalized magnitude 7.0 return period of 299 years, calcul-ated here by the same method.Only southern PNG, including the Papuan Fold Belt and most of the Bismarck Sea, are less active than California Zone 4. The Papuan Fold Belt is only marginally less active than California Zone 4, but more active than the State of California taken as a whole.

Jan 1, 1994

By L. R. Duncan, W. H. McCracken

Magnesium is the eighth most abundant element in the earth&apos;s crust and the third most plentiful element in seawater. It is found in more than sixty minerals and in brines and seawater as a magnesium salt. One of the more important magnesium minerals is magnesium carbonate, MgCO3, with a theoretical maximum magnesia, MgO, content of 47.6%; this carbonate form represents the world&apos;s largest source of magnesia. The next most used sources for magnesia are magnesia-rich brines and seawater, where it occurs as magnesium sulfate and magnesium chloride. Other commercially important magnesium-bearing minerals are dolomite, CaMg(CO3)2, which serves the aggregate industry as well as the chemical industry; brucite, Mg(OH)2, which is used in the production of both caustic and sintered magnesia; olivine, ([MgFe]2-SiO2), which serves the refractory and heat storage industries; talc, (H2Mg3(SiO3)4), which serves several industries as a filler and as an ingredient in cosmetics; and serpentine, (H4Mg3SiO9). All these minerals are of commercial value because of the desirable characteristics given to them by magnesia and by its placement in the crystal structure. These minerals are the starting raw materials for a wide range of products. These include the production of magnesium metal, and several grades of magnesia used for the production of both sintered magnesia for refractory manufacture and lighter fired caustic magnesia, the latter is used in fluxes, fillers, insulation, cements, decolorants, fertilizers, chemicals, in the treatment of waste water including pH control, and in the removal of sulfur compounds from exhaust stacks. Magnesite is one of several major minerals possessing a dual character, i.e., non-metallic industrial mineral because of its principal end use as a calcined/dead burned raw material in non-metallic end products and magnesium metal. A large percentage of the magnesia used to produce magnesium metal comes from seawater1 brines. The total primary metal production worldwide is about 350 ktpy. This report reviews magnesite solely as an industrial non- metallic raw material. Magnesite for most refractory purposes must have a content of sintered magnesia above 85%, with a preference for those sources that have the potential for 90 to 98% magnesia values. Dolomite, used in large tonnages because of its physical properties in the construction industry, also has a use in the chemical and the refractory industry. In its calcined form, dolomite is used as a slag addition in the making of steel, and it is used in a high-purity calcine to precipitate magnesium hydroxide from brines or seawater. The precipitated magnesium hydroxide is intermediate for the production of deadburned clinker for refractories and the production of magnesium metal. In many cases the high-purity magnesium hydroxide obtained by precipitation with calcined dolomite, or in some cases limestone, has supplanted much of the world&apos;s production of magnesia from the natural mineral magnesite. This is especially true of the United States and in major industrialized areas of Europe and Japan. The best known of the minerals directly and widely exploited for its magnesia content is magnesite (MgCO3), one of the calcite group of rhombohedra1 carbonates, which includes calcite (CaCO3), siderite (Fe2CO3), and rhodocrosite (MnCO3), among others. The members of this group enter into a wide range of substitutional solid solutions when the positive ions have similar radii. The radii of magnesium and iron ions are within 6% of each other; hence magnesite and siderite form a complete series, of which the mineral breunnerite (ferroan magnesite) is a well known end member. The radii of calcium ion is 36% larger than that of magnesium ion and only limited substitution exists at each end of the MgC03-CaCO3 series. Dolomite is not a member of the calcite group, but it occurs when calcium and magnesium ions alternate in equal number in an ordered structure among carbonate ions. The result of this relationship is that calcite and dolomite are commonly found intermixed with magnesite. They occur, commonly, as identifiable crystal entities, which can be separated to a varying degree from the magnesite by benefication techniques. Magnesite, when pure, contains 47.8% MgO and 52.2% CO,. The pure mineral is found occasionally as transparent crystals resembling calcite. Magnesite principally contains variable amounts of the carbonates, oxides, and the silicates of iron, calcium, manganese, and aluminum. Although the genesis of natural magnesite deposits can be complex, it is distinguished in nature in two distinct physical forms, namely crystalline, (with a wide range of visible crystal sizes) and cryptocrystalline, sometimes referred to as amorphous, where the crystal size is not detectable to the eye and will range from 1 to 10 pm. The two types not only differ in crystal structure but in the sizes of the deposits and in modes of formations. The crystalline form has a Mohs hardness of 3.5 to 4.0. The color range is from white to black with shades of yellow, blue, red, or gray. The color is not a significant indicator of purity but in a given deposit an experienced person can often roughly grade the magnesite by observing color and crystallinity. Macrocrystalline deposits occur in relatively few, but generally large, deposits on the order of several million tons. The ore shows a marble-like crystal structure and belongs to the sedimentary or metasomatic groups of origin. The cryptocrystalline variety of magnesite frequently occurs in many small deposits, although there are exceptions. Cryptocrystalline magnesite is typically massive with no cleavage and is sometimes descriptively called bone magnesite. The fracture is usually conchoidal, with a hardness of 3.5 to 5.0. The color is mainly white, but it can have tints of yellow, orange, or buff. Accessory silaceous minerals such as serpentine, quartz, or chalcedony are usually present. Calcium minerals are normally absent or in low concentration, this contrasting with the macrocrystalline form where calcium minerals are almost invariably present and some- times in high concentration. The specific gravity of cryptocrystalline magnesite ranges between 2.90 and 3.00, whereas the value of pure crystalline magnesite is 3.02. In actuality, the normal specific

Jan 1, 1994

By J. J. Talja

An investigation of oxidation of various nickel concentrates was carried out using differential scanning calorimetry (DSC). The aim of this study was to determine the ignition temperature and investigate other oxidation behavior of various sulfide-based nickel concentrates. Variables in the experiments were mineralogy, particle size and partial pressure of oxygen with temperature increasing linearly at 25 K/min from 323 to 1023 K (50-750 °C). The igni¬tion temperature was determined to represent the starting point of rapid oxidation. The reac¬tion enthalpies of the concentrates were determined and the amount of heat generated up to various time were used to calculate the extent of reaction. Mineralogical changes at various stages of oxidation were also investigated. For this purpose a second set of DSC-experiments were carried out in which each experiment was interrupted at a desired temperature between 673-873 K. From these tests the weight loss of samples were determined and changes in the individual constituent of sulfide minerals were analyzed. For pentlandite-based Ni-concentrates the ignition temperature was 705-710 K (approximately 435 °C). Pyrite was the first sulfide to oxidize. Reactivity of the violarite-based concentrate was greater than those of the pentlandite-based concentrates. The stoi-chiometry of pentlandite changed before ignition because of preferential oxidation of iron. Rapid oxidation of the pentlandite mineral occurred at about 823 K (550 °C). By 900 K about 90 % of the iron in pentlandite was converted to hematite, and NiS containing some iron was formed.

Jan 1, 1994