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By E. D. Goddard, D. S. Murphy

Acid resistance, zeta potential and ESCA (electron spectroscopy. for chemical analysis) experiments were performed on emperador marble and four calcium carbonate samples (onyx calcite, travertine calcite, Iceland spar calcite and aragonite). Six fluorine-containing reagents were used to treat the surfaces of these materials: magnesium hexafluorosilicate, zinc hexafluorosilicate, sodium fluoride, zinc fluoride, strontium fluoride and stannous fluoride. The acid resistance of treated samples proved to be much higher than that of their untreated equivalents. The isoelectric point of treated samples approaches the isoelectric point of fluorite. Also, the fluorine content, as measured by ESCA, of a marble surface treated with magnesium hexafluorosilicate is much higher than that of an untreated sample. The binding energy off of fluorine and calcium the treated marble is consistent with the formation of calcium fluoride.

Jan 1, 1994

By Richard M. Crowell

"As thorough sampling is usually expensive, the cost of a complete job is often unwarranted, and a cheaper approximation must be substituted. The engineer should, however, weigh the situation thoroughly before subscribing to an alternative other than an accurate assay basis on which to build his conclusion." Examination and Valuation of Mineral Property. R. Parks, 1949

Jan 1, 1994

By S. Seetharaman

A mathematical model has been developed to evaluate the viscosities of melts at high temperatures. The viscous flow in liquid is described by the equation, {n = Aexp(AG*/RT)} based on the absolute reaction rate theory. The Gibbs energy of activation,{ AG* } is considered to be a function of the temperature as well as the composition of the melt. The model has been applied successfully to various metallic and slag systems from unary to quaternary. On the basis of this model, a relationship has been suggested to relate the Gibbs activation energy of viscosity to the Gibbs energy of mixing in binary metallic melts. The viscosities predicted from available thermodynamic data in the case of a number of binary metallic systems using this correlation show satisfactory agreement with the reported experimental values.

Jan 1, 1994

By Stella Sigler

This publication contains analyses and related source data for 153 natural gas samples from 16 States. Of the total samples, 149 were collected during calendar year 1993. The remainder were collected earlier, but releases granting permission to publish were not received until 1993. None of the analyses have been previously published in annual reports. All samples were obtained and analyzed as part of U.S. Department of the Interior, U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1994

By D. R. McMullin

The purpose of this paper is to provide a method for mine planners and engineers to evaluate on a conceptual basis if a shaft or a ramp is most suited for their particular underground access requirements. Mine planners and engineers are often raced with the decision of choosing which method of underground access is best suited for their particular requirement. Underground access can be provided by a shaft, ramp, adit, or slope for either exploration and/or actual production operations. This paper will focus on the construction cost and schedule differences between sinking a shaft and excavating a ramp which are currently the most typical access alternatives used in the western United States. It would be wrong to state that one method is superior to the other in every case. There are many variables to be addressed, and the degree of sensitivity of each of them will eventually dictate which method is the most suited to the particular circumstances. This paper compares the construction cost and schedule or sinking a shaft to excavating a ramp at different depths given different ground and hydrological conditions. This comparison provides mine planners with "rules or thumb" that may be applied to the access selection process.

Jan 1, 1994

By Steven R. Davis

Dear Interested Party: Subject: Notice of Intent to Solicit Outside Opinions Regarding Amendments to the Rules Concerning the Leasing of State Owned Lands for the Mining of Metallic Minerals The Department of Natural Resources, Division of Minerals, is seeking outside opinions concerning the leasing of state owned lands far the mining of metallic minerals. Enclosed for your information in a copy of the Notice of Intent to Solicit Outside Opinions Regarding Amendments to the Rules Concerning the Leasing of State Owned Lands for the Mining of Metallic Minerals.

Jan 1, 1994

The Lihir deposit in Papua New Guinea (PNG) contains an estimated mineable reserve of 454t (14.6M oz) of gold in refractory sulphide ore. The Lihir Joint Venture has submitted a proposal to the PNG Government to develop an open pit mine and to install a process plant and associated infrastructure facilities on Lihir Island. The proposed process plant will employ whole-ore pressure oxidation technology, has a design capacity of 2.825Mt/a of ore containing 7.20 sulphide sulphur, and is expected to average 19.3t/a (620,000 oz/a) in gold production during its first 12 years of operation.An extensive program of process development testwork and feasibility engineering was completed to establish the process plant design for the Lihir Project. Summary results of this test-work as well as key design criteria, the process flowsheet, and major equipment selected for the commercial plant are presented and discussed.

Jan 1, 1994

By Pefer F. Stacey

This paper considers some of the trends in slope design technology that are emerging as we approach the 21st Century. While the ability to design stable slopes has unproved greatly over the past 20 years, trends towards steep short-term slopes for small highgrade orebodies, and very high slopes for mega-pits centered on low grade deposits are starting to indicate limitations in available technology.

Jan 1, 1994

By R. W. Harnmack

Hydrogen sulfide generated by the anaerobic respiration of sulfate-reducing bacteria was used to treat pH 2.2 water from the abandoned Rio Tinto copper mine in Nevada. The untreated water contained 550 mg/L Fe, 140 mg/L Al, 90 mg/L Cu, 80 mg/L Mn, 60 mg/L Zn, 4 mg/L Co, and 2 mg/L Ni. The bench-scale treatment system examined consisted of a bioreactor for H2S generation and three precipitator/clarifier units for metal sulfide precipitation and recovery. The treatment system reduced the concentrations of all metals except Mn to less than 0.1 mg/L. Manganese concentrations were reduced by 96 percent to 3.3 mg/L. A CUS/SO concentrate (33 pct Cu) and a ZnS/5° concentrate (28 pct Zn) were produced that may be suitable for metal recovery at existing smelters

Jan 1, 1994

By R. Stefaniuk, T. Le, J-Y Huôt, H. Henein

"One of the most important process variables in gas atomization is the gas to metal (G/M) mass ratio as it has a direct effect on the mean particle size of the atomized powder. If this ratio can be controlled during the atomization process, the powder produced would be more uniform and the d50 more predictable. Thus, atomization using a tundish or gravity feed from a crucible would be more stable. In gas atomization, the gas flow rate can be easily monitored; while it is very difficult to determine the molten metal flow rate. This research paper presents a new method of recording the molten metal height with time using a conducting metal height detector. The metal height recorded in real time during atomization was used to characterize using a model the friction losses in the metal delivery system. It is found that the integrity of the metal delivery tube and the cleanliness of the melt play a key role in the maintaining a stable metal feed.IntroductionIn the gas atomization process, molten metal is normally fed to the system either continuously using a tundish or in most cases a certain amount of metal is melted in a crucible and flows into the atomizing chamber under gravity. In the first case, the metal flow rate is believed to be constant during the atomization process despite the presence of slag or dross on the molten metal surface. In the second case, the amount of molten metal is depleted with time and the rate at which the metal flow decreases with time varies from test to test in a seemingly unpredictable fashion.' Furthermore, most atomization systems are confined units and the metal level in the crucible cannot be detected by a visualization method. In industry as well as in laboratories, the metal flow rate is normally calculated on either the mass of input material or the mass of total production divided by the duration of the test. This figure is not accurate enough and obviously cannot be used as a control parameter for the gas to metal ratio as it is only determined after the completion of an atomization run. The need exists for a metal flow rate measurement and control methodology; thereby the d50 of the powder produced may be estimated and controlled in real time. Clearly, the smaller the variation of the G/M ratio during the atomization process the more uniform the powder produced and hence the size of the particles can be predicted."

Jan 1, 1994

By S. C. Suboleski, J. W. Oberholzer

This paper describes research being undertaken by the Chamber of Mines Research Organization (COMRO) to assist the continuous miner operator and section foreman in the performance of their jobs. The project will initially provide visual assistance to the miner operator, and later it will semiautomate the mining (cutting) process. Using a technique known as "RF tagging," the project will also provide the section foreman with real-time or near-real-time information about the performance of the loading and hauling units. This data will allow the section foreman to quickly detect problems and take action where appropriate. The project is based upon the application of currently available technology, and in-mine testing results from the first phase are now available.

Jan 1, 1994

By Corbett GJ

Comparisons between individual SW Pacific Rim gold deposits have facilit-ated proposal of a new classification of porphyry-related mesothermal gold deposit types. Carbonate base-metal gold systems form at relatively high crustal levels, peripheral to porphyry intrusions. There is a spatial assoc-iation with major structures which focus fluids from degassing porphyries at depth. Milled matrix intrusive breccias and extrusive maar volcano/ diatreme breccias form as a result of pre-mineralisation phreatomagmatic eruptions. These focus degassing magmatic fluids by the provision of fracture ground preparation, typically within competent host rocks, adjacent to the breccia bodies. Local dilational structures control the form of individual deposits which may contain bonanza gold grades at sites of fluid quenching and/or repeated mineral deposition.Early quartz veining and porphyry-related alteration is common and later gold mineralisation typically occurs in association with carbonate veining and Fe and base metal sulphides as Zn > Pb > Cu. The progressive cooling by mixing of the upwelling mineralised magmatic fluid with descending bicarbonate waters, produces characteristic zonations in carbonate compositions. These vary with distance from the porphyry source, from Ca through Mg, Mn and distal Fe types. Gold mineralisation is preferentially distributed within the Mn/Mg carbon-ates.

Jan 1, 1994

By Jae-Ho. Lee

Mercury is a toxic contaminant encountered in the extraction of gold from mercury-containing ores. It is found in the leach solution of CIP circuits and in the cathodes of the electrolyte cells used to electrodeposit the gold. The research conducted has examined the potential for selective removal of mercury from synthetic Au-Hg-CN electrolytes containing only gold, only mercury, and both gold and mercury. Cyclic voltammograms were obtained for mercury- coated copper electrodes with these cyanide electrolytes. Exchange current densities were determined from the voltammograms in the low overpotential region. Laboratory scale batch- electrolysis at constant current was also conducted for the electrolytes containing only mercury and both mercury and gold, at 20 and 50°C and from which the kinetic behavior associated with the process was analyzed. The surface of cathode before and after electrolysis was also characterized and a copper mercury intermetallic (CyHg,) was identified. Gold codeposited with mercury during the later stages of electrolysis. The results of this work corroborate that the mercury-amalgam copper electrode offers a viable electrochemical technique for the selective removal of mercury, however a high-surface-area cathode-cell would have to be utilized to provide for the desired selectivity.

Jan 1, 1994

By B. Towson, R. F. Dalton, G. W. Seward

This paper reviews the successful application of oxime reagents for the solvent extraction of copper and considers the role that well focussed research initiatives can play in bringing further radical change to the metallurgical industry. Particular reference is made to the Cuprex Metal Extraction Process (CMEP), for the treatment of low grade or difficult to treat sulfide concentrates, using the reagent Acorga CLX- 50 to recover the copper and the reagent Acorga ZNX-50 for the recovery of zinc from chloride solutions. Other new extractants, currently in development, are also referenced.

Jan 1, 1994

By James Watson Baxter

Fluxes are used to promote pyrometallurgical processes that rely on adhesion (soldering or brazing) or fusion (gas and arc welding) to join metallic surfaces. In the adhesive processes, the metal surfaces to be joined are not melted; the join is formed using a filler metal with lower melting point than the base metal. Fusion welding involves use of heat in excess of the melting point of the base metal. The fused joint may be achieved either by simply fusing together metal surfaces brought in contact with each other or by introducing additional molten metal of similar composition to form a fused joint. ADHESIVE PROCESSES--SOLDERING AND BRAZING In order for molten filler metal, solder or braze, to spread in a manner that creates a successful join; the work surfaces on the base metal must be thoroughly cleansed. Fluxes remove stubborn oxide films and other surface contaminants, promote wetting of the work surfaces, add fluidity to the solder or braze, and enhance workability and ease of spreading. Brazing processes involve higher temperatures than those reached in soldering. Brazing fluxes, which must remain active and effective at the higher temperatures, differ from those employed in soldering. Some common fluxes used in adhesive processes are rosin for soldering tin and electrical connections, hydrochloric acid for use in soldering galvanized iron and other zinc surfaces, and borax for brazing. Soldering and brazing are similar processes, the primary difference being the temperature at which the joining operation is carried out. Soldered joints, produced with low-melting-point fillers (solders) that melt and flow at temperature less that 450°C (Althouse et al., 1988) can sustain loads of 1 to 1.7 MPa for extended periods of time (Anon., 1966). Brazing involves the use of filler materials with melting points commonly above 500°C and generally provides stronger joints than those obtained with solder. Both processes require local application of heat to melt and spread the filler so that the molten filler can wet (adhere to) the base metals by alloying and diffusion. Soldering Soldering is a means of joining metals by adhesion using a metallic bonding alloy as the filler, commonly a mixture of lead and tin. However, the adhesion of solder depends more on its ability to be keyed into minute surface irregularities than on alloying. The most familiar application is to provide and secure electrical connections. Soft solders can range from 1 to 70% tin with the remainder mostly lead. However, for general-purpose, soft-solder work, the alloy is commonly 50% lead-50% tin. Higher lead contents provide a wider range in the melting temperature and, for this reason, a 60% lead-40% tin alloy, which yields a mushy mixture, is used for wiped joints in lead sheet and pipe work. Conversely, 40% lead-60% tin alloys are used in soldering tin and other low- melting-point materials for which a narrower range of melting temperature is required. There are numerous other solder compositions such as tin-silver, 95% tin-5% silver and antimony-tin, 95% tin and 5% antimony (Carlin, Jr., 1992). Heat needed to melt and spread the solders is commonly provided by electrically heated, copper-tipped soldering irons or by means of torches; the solder is applied by hand, usually face-fed by means of wire. For wiped joints in plumbing and lead-cable splicing, the solder is manipulated with cloth pads. The molten solder wets the joint surfaces and is drawn, by surface tension, into minute fissures and capillary openings. Other applications involve use of induction heaters and furnaces with pre-shaped solder appropriately placed prior to fluxing and heating. In some processes, the joints are immersed in molten solder. Constituents and Role of Soldering Fluxes: Soldering fluxes generally fall into one of three categories: highly corrosive fluxes, intermediate fluxes, and noncorrosive fluxes. These same categories are sometimes designated inorganic, organic and rosin-based respectively (Althouse et al., 1988). Common constituents of each group are discussed briefly below. Corrosive Fluxes (Inorganic). Work with aluminum, magnesium, stainless steel, high alloy steel, aluminum bronzes, and silicon bronzes is carried out at temperatures in the upper portion of the range for solder operations. Soldering these materials requires use of highly active, corrosive fluxes to remove and prevent the formation of the especially stubborn, hard, oxide films that form on these materials upon exposure to the atmosphere. The corrosive fluxes consist of inorganic acids and salts that are applied either as pastes or dry. They are active at elevated temperatures and, since they remain active after the soldering is completed, must be completely removed. The main constituent of most corrosive fluxes is zinc chloride with a melting temperature well above the solidus temperature of most commercial tin-lead solders. It is made by the action of hydrochloric acid on zinc. When zinc chloride is used alone, un- melted particles of this corrosive salt get caught up in the joint and weaken it. For this reason, other inorganic salts such as ammonium chloride (NH4Cl) or sodium chloride (NaCl) may be added to lower the melting temperature. A mixture of zinc chloride and ammonium chloride is very effective because the excellent oxide reducing properties of ammonium chloride and the protective action of the molten zinc chloride combine to produce a fluxing action superior to that achieved when either is used alone. In addition to zinc chloride, ammonium chloride, and sodium chloride; common con-

Jan 1, 1994

By Larry D. Lawrence, Gerald W. Greenway

Corrugated boxes have been the dominant shipping container for packaged commercial explosives for the past 3 decades. Recent changes in shipping regulations have dictated to the industry the adoption of enhanced standards dealing with the construction of fiberboard shipping containers for explosives. Effective October 1944, all shipping containers used for explosives will require individual certification verifying that the containers conform to the United Nations performance oriented packaging standards. The U.S. Department of Transportation will continue to enforce compliance to the new UN standards. A renewed emphasis on the design of corrugated shipping containers to insure industry compliance to the UN standards has been a joint development program between the explosive manufacturers, fiberboard container suppliers and the academic community. Along with drop strength, leakproofness, and vibration resistance, the individual stacking strength of corrugated shipping containers has come under tight scrutiny based on the new UN standards.

Jan 1, 1994

By Anna Marabini

This paper provides a summary of the studies performed over a period of more than fifteen years by the Italian National Research Council's Mineral Processing Institute in Rome to develop applications for the use of chelating reagents in the flotation of metallic minerals. A description is given of the various phases through which the studied progressed, starting with the combined use of commercial chelating reagents and a neutral oil and then moving on to the synthesis of new long-chain chelate collectors for the flotation of sulphide and oxidized Pb, Zn and Cu minerals. After a series of preliminary tests which confirmed the possibility of floating various metallic minerals with commercial reagents containing chelating groups exerting specific action on given cations, the studies were addressed to the development of a theoretical method of choosing chelating groups that exert selective action on one metallic mineral rather than others. The theoretical approach was based on thermodynamic data concerning the chemical equilibria in solution. The validity of the method has been proved in numerous cases by flotation tests on pure minerals. Subsequently the research was directed towards the design and synthesis of reagents with a mixed aliphatic-aromatic structure containing chelating groups for Pb and Zn and an alcoxyl chain of various length, position and configuration. The flotation results obtained on oxidized and mixed Zn-Pb ores provided interesting pointers for designing the nonpolar portion. The structural criteria identified via these studies were interpreted on the basis of chemical and steric considerations. A description is given of a new synthetic chelate collector which is effective in the selective flotation of Cu minerals from complex sulphides. The fact that this reagents is more selective than xanthate is demonstrated by comparative flotation tests on actual ores.

Jan 1, 1994

Production In 1993, it was estimated that United States mine production of barite increased 24%. Barite consumption, either sold or used by grinding plants, increased by 39% and imports increased 4%, according to the US Bureau of Mines (USBM). Nevada continued to be the leading producer of barite with 80% of the total, followed by Georgia. It is estimated that 83% of the domestically mined barite was used as a weighting agent in drilling fluids. The remaining 17% was used in barium chemicals, glass or as a filler. Most of the production from Missouri, Georgia and Tennessee was used in the non-oilfield sector. Prices The value of domestically produced barite, f.o.b. mine, decreased 1%, according to the USBM. The declared value c.i.f. US port of all imported crude barite during 1993 decreased from $40.09/t ($36.37/st) in 1992 to $37.72/t ($34.22/st). Uses Of the total barite used by grinding plants and chemical manufacturers, it is estimated that 90% was used in drilling fluids and 10% in the non-oilfield sector. This included barium chemicals, fillers in paper, plastics, brake shoes and glass. The tonnage consumed in the drilling fluids market increased due to the higher average rig count during 1993. The average number of rotary rigs operating in the United States was 754, 5% greater than the 1992 average of 717. Imports Crude barite imports in 1993 were 443 kt (488,000 st) greater than 1992, representing an increase of 137%. Imports accounted for 67% of the barite consumed (apparent) in the United States.

Jan 1, 1994

By Yael Miron

The presence of pyrite (FeS2) in coal can cause or contribute to several problems for the coal mining industry. These problems, which include spontaneous combustion, roof falls, floor heave, and accidental explosions in coal surface mining when ammonium nitrate fuel oil (ANFO) explosives are used, result from pyrite oxidation. Pyrite oxidizes exothermically in the presence of air and moisture to form a large variety of products, including hydrated ferrous and ferric sulfates, and sulfuric acid. Some of the products are reactive chemicals and strong oxidants. The volume of many of these oxidation products exceeds the original volume of the pyrite; as a result, the adjacent coal disintegrates and its surface increases, rendering it more susceptible to oxidation. The heat from pyrite oxidation raises the temperature of the adjacent coal, accelerating the oxidation and self-heating rates of the coal. These combined chemical, physical, and thermal effects are the cause of the aforementioned problems. When ANFO is used in surface coal mines and contacts ferrous sulfate, a highly exothermic reaction ensiles. Additional hazards are fires or explosions caused by the frictional ignition of methane when the pyrite in the coal is struck by a cutting bit during mining.

Jan 1, 1994

By Frank A. Vonesh

In order to reduce the amount of visible, airborne emissions in the Metals Industry, a new Industrial Gas Technology was developed by Air Liquide. This patented technique is called ALECT?, Air Liquide Emission Control Technology. Demonstrations have been conducted for many cutting and lancing operations as well as for hot metal transfer from vessel to vessel. Fume reductions of 90% and greater have been achieved in actual practice. Air Liquide continues to improve the process and the associated control equipment.

Jan 1, 1994