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By Zhengbin Cheng, Wenguang Lu, Baoqi Sun, Jiaying Tang

This paper studied the flotation separation of feldspar, zircon and kyanite from quartz with a mixture of cationic and anionic collectors. Tests show that collector mixture has specially good effect, using it, the separation of these three silicate minerals from quartz can be successfully achieved at the natural pH value of tap water in the absence of any acid, fluoride and other inorganic reagents. The properties and characteristics of collector mixture were analysed. By means of IR-spectra, ESCA and AES, the action mechanism between collector mixture and minerals was throughoutly studied.

Jan 1, 1995

By J. Drelick

Among the wide variety of modern surface chemistry analytical techniques, contact angle measurements still remain attractive for wetting characterization of solid surfaces. The captive-bubble and sessile-drop techniques are the most popular methods for the examination of flotation systems. Systematic measurements of advancing and receding contact angles for several three-phase systems using the captive-bubble and sessile-drop techniques show that the contact angle measurements depend on the technique used and may differ significantly for some heterogeneous and rough solid surfaces. Importantly, it was found that these discrepancies in contact angle measurements depend on the bubble (drop) size. Contact angles as measured with the static captive-bubble technique are compared with those measured with the dynamic captive-bubble technique, in which the capture of a bubble at the solid surface results after buoyant transport and attachment The dynamic captive-bubble technique allows for the formation of much smaller bubbles than is possible with the static placement technique in which a bubble is placed at the solid surface with a microsyringe. Although this dynamic technique cannot be recommended for the systematic wetting characterization of solid surfaces, its significant advantage is the ability to examine the contact angle/bubble size relationship over a wide range of bubble sizes, from several micrometers to several millimeters in diameter.

Jan 1, 1995

By Vanessa M. Torres, Renato S. Costa

This work presents the experience of Cia. Vale do Rio Doce in using Diagnostic Leaching tests to characterize refractory ores and CIP tailings. With the diagnostic leaching results of the highly refractory gold ore from Maria Preta Mine (Brazil), a process flowsheet was defined for a feasibility study of possible process modification on the existing plant. With CIP tailings from its Fazenda Brasileiro and Caué operations the amount of cyanidable gold was determined to aid plant optimization.

Jan 1, 1995

By Brian W. Stump

Seismic networks provide the primary technology for monitoring compliance with a comprehensive test ban treaty. The design goal of the network is the identification of possible clandestine explosions detonated below the earth’s surface and possible in the oceans. Complementary technologies such as infrasonic, hydroaccoustic and radionucleide (particulates and noble gases) monitoring supplement the seismic monitoring covering explosions in the atmosphere and oceans. Seismic sources that will produce detectable signals will be both natural and man made in origin. Naturally occurring events include earthquakes, many of which are beneath the oceans or deeper than it is possible to drill, and volcanic eruptions. Accurate locations of such events to depths of beyond 10 km precludes consideration of these events further.

Jan 1, 1995

The middle-Devonian Dulladerry Volcanics is a complex of A-type, predominantly rhyolitic ignimbrites, lavas and breccias. They form a NNW trending belt some 90 km long and 10-20 km wide, east of Parkes, NSW. The volcanics are dominated by widespread ignimbrite units with minor basalts, sediments and rarer andesites. The volcanics were deposited in a sub-aerial, possibly continental rift setting and are similar in chemistry and age to the Eden - Comerong - Yalwal Volcanic Zone (EVZ) on the NSW south coast. The volcanics exhibit an unusual Atype chemistry (high Zr, Y, Nb, REE, Ga). This distinctive composition illustrates that the volcanics are not comagmatic with the adjacent Yeoval Granite Complex or Eugowra Granite, which show typical I-type fractionation trends. Epithermal gold veins occur in basalt and andesite in the Dulladerry Volcanics at Mt Aubrey (Hopf, 1992), near Baldry. Alteration also occurs in the Glen Isla and Red Hill areas, with epithermal sinter recognised at Glen Isla. Copper and minor gold mineralisation occurs at the contact of rhyolite and andesite at Reedy Creek, but is not of epithermal origin. The analogous EVZ also contains several epithermal gold fields and it is this style of mineralisation which provides the most prospective targets in the Dulladerry Volcanics. Although the Dulladerry Volcanics also contain high background levels of REE and metals such as Zn and Pb, the general lack of fractionation and water-undersaturated character of A-type magmas does not lend itself to the development of significant concentrations of these elements into a fluid phase and mineralisation. The prospectivity of A-type volcanics in general could not be regarded as high. However, an indicator of some fractionation in the Dulladerry Volcanics is provided by the fairly low abundance (average 230 ppm) and wide range (

Jan 1, 1995

By J. M. Stewart

Mining fatality rates in many countries have not changed substantially over the past ten years. This demonstrates not only that there is an inherent risk in mining, but also that current approaches to improving safety need to be rethought. An analysis of productivity and fatality data in the United States, United Kingdom, and South 4frican coalmining industries shows that the impact of legislation on safety is overlain by other significant factors. Although improvements in safety and productivity usually occur together, the data warn that safety legislation can sometimes cause a significant reduction in productivity. Based on the data and experience considered, it is concluded that legislation should be aimed at creating a framework within which a positive attitude towards the implementation of more productive and safer mining methods, work practices, and technology can flourish, rather than attempting to enforce excessively prescriptive provisions. This later approach is even more problematic when safety standards and legislation are transferee from well developed to less developed countries. A legislative framework in which the mine manager is required to take al reasonably practicable measures to procure safe working conditions in accordance with mine-specific codes of practice is outlined. Within that framework, the value of adopting widely accepted standards is recognized. A performance-based external audit arrangement is outlined as a basis for ensuring that detailed attention is focused on those areas most needing improvement.

Jan 1, 1995

By Peter Godbehere, Christian Desroches, Viken Baboudjian

"Noranda Copper Smelting and Refining is a unit of Noranda Metallurgy Inc., comprising the Home smelter in Rouyn-Noranda, Quebec and the C.C.R. Refinery in Montreal East. The Home smelter provides custom smelting services for a wide variety of copper and precious metal bearing concentrates and recyclable materials, producing over 200 000 tonnes of anodes and 450 000 tonnes of sulphuric acid annually. The C.C.R. Refinery has an annual production of 360 000 tonnes of copper cathode, and is a major refiner of precious metals.Over the past twenty years, Noranda Copper has developed innovative processes and operating techniques to treat the ever increasing complexity of primary feed materials, while improving the quality of its final products, working conditions and reducing environmental emissions.This paper presents an overview of the operating practices of Noranda Copper with particular emphasis on the impact of impurities in the smelting and refining processes.IntroductionThe treatment of custom materials has been practiced by Noranda Copper since commencement of operations at the Home smelter in 1927 and the CCR refinery in 1931. Copper concentrates from a wide variety of regional, North American and overseas producers account for the bulk of the 800 000 tonnes treated annually, although recyclable and secondaries have increased in importance as feed sources in the past two decades. The geographical disadvantage of the Horne smelter compared with most custom smelters located on tidewater has provided an important incentive for Noranda Copper to develop the necessary technology and operating practices at its smelter and refinery to treat high value complex concentrates and other feeds containing significant concentrations of bismuth, antimony, arsenic, lead, tellurium, mercury, etc."

Jan 1, 1995

By Schofield D, Denby B, Stout F, Moli A

This paper documents the development of a user-friendly computational program, which has been constructed to assist the mine ventilation engineer in the optimal design and operation of methane drainage ranges. In the past, many computer tools for ventilation engineers led to the development of `research systems'. These computer systems, although developed with the needs of the industry in mind were due to a combination of inexperienced programming methods and the availability of suitable user interface software not easily accessible to the practising engineer. Recent developments in computer hardware and software (particularly windows based graphical user interfaces) mean that engineers no longer need to dedicate large amounts of valuable time to become familiar with often complex items of software. The authors of this paper intend to demonstrate a practical system which successfully integrates complex mathematical models, an easy to use interface and knowledge based techniques. The graphical interface guides the user to draw on the screen a mimic diagram representation of the methane drainage network. The user is prompted, during the construction of the drawing, to input the information and data required by the calculation and knowledge based procedures. The computer program then calculates all of the flows, purities and pressures throughout the network. Given reliable measured data from an existing range a comparative analysis can be performed between the predicted and measured network flow data. A knowledge-based system may utilise this analysis to either update the operational status of the network or suggest either a reasoned maintenance or remedial strategy to improve the performance of the drainage system. The development of the OMEN project has been carried out at the request of the Midlands Group, British Coal Corporation, Edwinstowe. The system is about to be field tested at a number of mines. It is hoped that when this paper is presented that the system will be used at both Group and mine level.

Jan 1, 1995

By Durao F

A multi-layer feed-forward neural network was trained (using the error back-propagation algorithm) to learn a subset of rules designed to stabilise the performances of the copper flotation section of a complex sulphide processing plant and then tested in order to evaluate its expert performances. Two types of neural networks were compared: the classical ones, fully connected between one layer and the adjacents (with different architectures), and entropy networks, partially connected and generated according to a methodology that simplifies its building up. The advantages and drawbacks of both were analysed and compared with classic (rule based) expert systems.

Jan 1, 1995

By T. A. Apelt, B. J. Elliot

"In September 1993, the flash furnace at Kalgoorlie Nickel Smelter, KNS, was brought off line after almost 12 years of operation. This is a record campaign life for a flash furnace. The furnace was' totally rebuilt and the capacity of the plant increased from 540 000 tpo to 750 000 tpa of concentrate throughput. The throughput increase was' achieved through the construction of a 525 t/day oxygen plant and upgrading of various plant ancillaries. A number of significant design modifications were also built into the flash furnace and oxygen enrichment was implemented in the operation of the Peirce-Smith converters.This paper discusses the rebuilding of the flash furnace and design modifications made to furnace equipment and ancillary plant. Some preliminary post-startup operating data are presented.IntroductionIn September 1993, Campaign 6 of the flash furnace was concluded and the furnace brought off line for rebuilding. The campaign length was almost 12 years and set a new record for campaign length. Planning for the rebuild took place over the last five years of the campaign. A number of modifications to the design of the furnace and the ancillary plant were planned to coincide with the furnace rebuild. The furnace was rebuilt and recommissioned in 70 days. The increased plant capacity of 750000 tpa has been achieved by the construction of a 525 t/day oxygen plant and modifications made to ancillary plant which centred around increased p~ control, efficiency and hygiene. This paper examines the development and implementation of the modifications made to the furnace and ancillary plant. Preliminary post-shutdown performance data are presented."

Jan 1, 1995

By S. K. Kawatra

Many mineral oxide and multi-component oxide (basalt) specimens break down into powders upon expo-sure to sodium vapor at elevated temperatures for extended times. This paper examines several possible mechanisms of oxide breakage by sodium vapor, both experimentally and from a thermodynamic viewpoint. The oxides for which reduction by sodium was thermo-dynamically favorable all exhibited some degree of fragmentation. The oxides which were not favorable for reduction by sodium did not exhibit fragmentation, with the exception of rutile, a titanium oxide. The rutile fragmentation was caused by the reduction of iron that was in solid solution in the rutile crystal structure.

Jan 1, 1995

By Fred N. Kissell

This U.S. Bureau of Mines report is a guide for the control of air contaminants during tunnel construction. Topics discussed are calculating air quantity requirements, types of ventilation systems, planning ventilation systems, control of methane gas, control of dust, control of diesel emission, ventilation to remove blasting fumes, measuring airflow, and measuring gases. This report does not provide detailed design information, but seeks to answer practical questions on air contamination issues.

Jan 1, 1995

By E. Burgos Cruz

The behaviour of S, N and P during refining of Fe-18 wt%Cr-10 wt%Ni with calcium carbide was investigated. The effects of the initial contents of C and N in the metal phase, as well as the supply method of calcium carbide to the melt on the removal degrees of S and P were evaluated. Heats were carried out at 1873K, in MgO crucibles, using a laboratory induction furnace. It was observed that simultaneously with S and P, N and O have also participated in the reactions. It seems that, in fact, O governs the behaviour of the other elements dissolved in the melt and that N is had to the removal of P with calcium carbide. It was also noticed that high C content in the metal phase have not altered the dephosphorization and desuffirization degrees, but that the supply of calcium carbide done by injection led to a lower dephosphorization degree than the one obtained by dumping it.

Jan 1, 1995

By A. Benchekroun

The phosphate mining industry is confronted everywhere in the world with financial difficulties and low prices which prohibit further investments and development of new mines even in regions with a comparative cost advantage (North America/ North Africa/ and Middle East). But old mines are being progressively exhausted/ and if no replacement mines come on stream in the near future/ we may soon find ourselves (around the year 2000) with a global annual production capacity of 160 million tonnes of marketable phosphate rock instead of the capacity of 200 million tonnes existing today. Unless prices improve/ phosphate rock/ a non-renewable resource and a vital commodity to world agriculture/ may turn to be in short supply to world fertilizer industry. Whatever the extent of recovery of fertilizer demand/ the expected decline of the production capacity during the 1990 I s is bound to cause the disappearance by the year 2000 of the important surplus characterizing today the supply/demand balance.

Jan 1, 1995

By E. R. Bauer

The ground control aspects and occupational safety concerns of extended depth-of-cut mining are presented in this U.S. Bureau of Mines (USBM) report. The scope of extended cut use and typical face operations while extracting extended cuts is reported. A comparative review of roof fall fatalities and a statistical analysis of accidents and injuries for both extended and nonextended cut mining is included. The views and opinions on extended cutting from a series of interviews with mine workers in five states are summarized. In addition, some of the problems and safety concerns of this extraction system are mentioned.

Jan 1, 1995

By M A. Etheridge

The evolution of economic precious metal and copper-gold deposits in high-level igneous terranes is dependent on very efficient fluid focussing. This is most readily achieved by contemporaneous deformation, igneous intrusion and hydrothermal activity. Mineralisation in these environments generally occurs in fault and fault-vein arrays developed in the cover sedimentary and volcanics sequences above older regional scale fault systems. Such reactivated fault systems are particularly prone to developing tile complex fracture arrays, extreme local dilation and dramatic increases in permeability that are necessary to efficiently focus hydrothermal fluid and produce large mineral deposits. The arc systems of tilePacific rim are typically structurally and tectonically complex. At any given period in the evolution of an arc system, it may be dominated by extensional, compressional or strike-slip deformation. Indeed, it is common for the tectonic environment to change repeatedly through the development of a single arc segment. As a result, structures formed in one tectonic environment are commonly complexly reactivated in quite different environments later in arc evolution. These complexly reactivated structures have greater potential to localise extreme fracturing, dilation and fluid flux than primary structures. Application of this knowledge to practical exploration requires an understanding of the primary geometry of the controlling fault systems, the fault movements during reactivation, intrusion and mineralisation, and the consequent location and geometry of dilational sites. Simple 2D lineament analysis and targeting on lineament intersections does not suffice. Chemical processes that results from structurally focussed fluid flow may also contribute to permeability enhancement and further enhance fluid flux. Two main types of chemical feedback are important. The first involves selective dissolution of minerals during alteration and tile consequent production of increased porosity and permeability. The second occurs where alteration changes the mechanical properties of tile rock mass, especially where it leads to a greater propensity for fracture (eg by silification). In near-surface environments (< ~1 km), geomorphic processes complement fault systems in focussing fluid flow to develop sub-horizontal bodies of mineralisation, such as the giant Ladolam gold deposit (>42 million ounces of gold).   Along with classification schemes which stress crustal level, host rocks and alteration assemblages, the styles of high level 'epithermal' and reated deposits must also be considered in respect of their controlling co-active fault structures. Such structural understanding, combined with understanding of tile chemical processes involved (eg host rock reactivity), provides a major tool for exploration particularly in terrains obscured by deep weathering. Geological interpretation based on integration of field mapping with magnetic, radiometric and other remotely sensed imagery provides a powerful complementary tool to the traditional geochemical and geophysical targeting techniques. Timely and effective geological input is capable of reducing exploration risk and providing a more cost-effective basis for drilling and development. Examples of deposits associated with fault reactivation in extensional, compressional and strike-slip settings within arc systems are discussed in this context.

Jan 1, 1995

By Guiseppe Bonifazi

This work applies the definition of "separation function" already introduced in the paper presented at the XVIII IMPC. This 'function" (defined for a certain size distribution after comminution of an ore) refers to the recovery distribution of a mineralogical species in a product made up of all the particles having at least a given content of that species. Many tests would be required to determine the liberation function for each mineralogical species, particularly for complex ores. Several stages of comminution would need to be examined and the mineralogical composition of the particles of each grain size class would need to be analyzed for each process step. A quick and dirty method is shown for obtaining the "separation function". It is based on the processing of data from topological maps of polished and/or thin representative sections of ore. By superimposing grids of different sizes over these maps and with appropriate combinations of mesh sizes, it is possible to simulate the grain size distributions linked to different stages of comminution and then evaluate the mineralogical composition of each grain. The procedure is carried out full automatically and can simulate a complete treatment circuit, imposing cut-off grades for the products at each separation phase. It is also possible to predict the results of treatment processes that involve grinding phases. The procedure has been successfully applied to complex ores containing several useful components.

Jan 1, 1995

By A. I. Kogut

Impurity minerals in fluorspar ores and concentrates from a deposit in Southern Africa have been studied by reflected light, transmitted light, and cathodoluminescence microscopy. The principal impurities are quartz, calcite, aegirine, apatite, ankerite, magnetite, goethite, and synchysite [Ca(La,Ce,Nd)(CO3)2F]. Cathodoluminescence microscopy was found to be very useful in studying the character of the fluorite and especially for recognizing the presence of apatite and calcite impurities. Fluorite exhibits blue, calcite shows yellow, and apatite has white, light purple, and pink cathodoluminescence. The cathodoluminescent character of apatite varies with its geological environment and position in the orebody. The results of this microscopic study show that phosphorus present in fluorite concentrates occurs principally in binary locked apatite-fluorite particles. Successive fluorite cleaner concentrates contain progressively smaller amounts of locked apatite-fluorite particles. Free apatite has been effectively partitioned to the final tailings.

Jan 1, 1995

By Y. C. Guan

The cementation of gold on to copper and zinc in ammoniacal solutions has been studied using rotating disc electrodes. The cathodic reduction of aurous ammine was studied on a gold rotating disc electrode and the anodic dissolution of copper and zinc was studied in the absence of aurous ammine. The cementation rate was found to be a first order with respect to the concentration of aurous ammine and to be proportional to the square root of the disc rotating speed. Based on the results obtained, it was concluded that the cementation reaction was controlled by mass transfer of aurous ammine to the reaction surface under the experimental conditions.

Jan 1, 1995

By Denby B

The ever increasing demand on land use has led to large areas of land being considered for development, which because of past mining activities are covered by substantial depths of fill materials. This paper examines the problem faced with the development of land infilled with open cast mining backfill, in predicting the behaviour of the fill upon development. To be able to design foundations suitable to withstand the movements that occur within open cast backfills or design a backfilling operation that produces land suitable for a proposed after development, a means of predicting backfill settlement is required. Factors critical to this prediction are the timing of backfilling operations, the compactive state of the backfill and the inundation of the backfill. The analysis of a considerable quantity of data collected from the monitoring of backfilling operations and backfill movement at a range of open cast coal sites located within the UK has given the authors a better understanding of how open cast backfills behave in terms of long-term creep settlement, collapse settlement and how these are effected by backfill scheduling. This knowledge has been encoded into a program running under Microsoft Windows that enables a user to make settlement predictions for a point, a given section or area or for the whole site. Differential settlements, critical to any development design, can also be determined between any two points taking into consideration the heterogeneous nature of open cast backfills. The program was tested with data from an open cast coal site in the UK. Compaction monitoring during the placement of the backfill material enabled a model of the backfill to be constructed taking into account backfill properties and scheduling. This model, taken as input into the program, enabled future backfill settlement predictions to be made. A comparison is given between these results and actual settlements obtained from a short-term settlement monitoring scheme.

Jan 1, 1995