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By J. A. Innes

"""The oxygen, next uniting with the carbon, sent up an ever-increasing stream of sparks and a voluminous white flame. Then followed a succession of mild explosions, throwing molten slags and splashes of metal high up into the air, the apparatus becoming a veritable volcano in a state of active eruption.""IntroductionHenry Bessemer F.R.S(An autobiography, 1905)Thank you Mr Chairman for the opportunity to speak: at this, the opening session of your International Symposium on the subject of ""Injection in Pyrometallurgy"". Judging from the list of papers to be presented over the next three days, the Symposium promises to provide a most valuable addition to our existing knowledge base in what is now an extremely active area of R&D investigations. Whilst we have obviously come a long way since Sir Henry Bessemer's pioneering experiments of the mid-19th century, there is still much for us to learn.Most importantly, the Symposium offers a further opportunity to acknowledge the many significant technical contributions made in this field by the Organising Committee's special guest, Professor Howard Worner - one of this country's most respected research leaders.When first approached to give this talk I had two areas of concern. Firstly, I was not entirely clear just what injection metallurgy was meant to cover. How should the overall scope of this particular subject be defined?My second concern related to Howard Worner himself - a man for whom I have the highest personal regard and who, in fact, played a most influential role in respect of shaping my own career. Having already spoken about Howard's achievements on earlier occasions, I wondered what I could sensibly add.Notwithstanding these personal reservations, I am delighted to be here with you this morning. If my thoughts on the meaning and scope of injection metallurgy appear to be slightly off-course, and if Howard should perhaps recognise some repetition in my remarks, then I hope I can be forgiven."

Jan 1, 1996

By Wright D. C

The operation of the cyanide-sensitive Mintek/TB1 kegold electrode was studied in the laboratory, with regard to equilibration time and drift, the effects of pH, stirring, salinity, dissolved oxygen, zinc and copper(I) ions. Methods for valid calibration in the range 20-600 mg(NaCN)/L and pH values in the range 9 - 12 in the absence of copper were also studied. Increasing the salinity beyond a threshold of 40 g(NaCI)/L improves calibration and measurement. The sensitivity is 91 mV per decade change in the concentration of ionic cyanide, and output is reproducible to within 10 mV with attention to the factors listed above. However, salinity of 40 g(NaCI)/L also sensitises the electrode to interference by copper(1) ions. This copper sensitivity seems capable of saturation, suggesting a research strategy for possible remedies.

Jan 1, 1996

By K. Rambha Devi

The paper is an attempt to co-relate the findings of pile capacity using a number of formula suggested by various authors with the actual field load test results. Five locations consisting of wholly sandy or clayey soils were selected for this purpose. The clayey soils are on a hilly area having clays of medium to stiff consistency upto a depth of 20 m The sandy soils are near the bank of a river having angle of internal friction 'Ø' value ranging from 30 to 35 Degree. The details of the soil properties are given in Table-1 Bored cast-in-situ piles of 30 cm diameter and a length varies from 6.5 m to 13 m were designed and cast for load test to be carried out. The load applied was twice the design load. The load vs settlement curves were obtained. The theoritical values obtained by formula suggested by various authors were superimposed on the curves. From the careful study of these curves it is seen that De Ruiter and Berigen values are close to the actual results for clayey soil. For sandy soil it is found that both the BIS method and Meyerhof method found to give conservative resuslts. A multiplication factor is suggested to theoritical values for obtaining satisfactory results.

Jan 1, 1996

By A. M. Richardson

The significance of a massive sandstone unit in the immediate roof to longwall support weighting is well known. If the unit lies in the main roof above the zone of caving, its influence becomes more difficult to calculate using traditional methods. Much of the reserves at Cyprus Plateau's new, multi-seam Willow Creek Mine are located in the A Seam. The massive Kenilworth Sandstone is typically situated 21.3 m (70 ft) above the A Seam in the main roof and is on average 14.6-m (48-ft) thick, ranging to 29.0-m (95-ft) thick. This paper describes the application of distinct-element modeling to determination of the appropriate yield capacity for supports at Willow Creek. The modeling was determined to be useful for understanding support loading mechanisms and as an aid to engineering judgment in selecting supports.

Jan 1, 1996

By M. J. Zdunczyk

The final 1995 figures on industrial sand and gravel have not yet been compiled by the US Geological Survey (USGS). There is usually about a nine-month lag time in receiving and compiling this information. However, USGS estimates that domestic production of industrial sand and gravel will increase about 4% to 28.2 Mt(31 million st). The average unit price is expected to increase as well. The top five producers during 1995 were Unimin, US Silica, Fairmount Minerals, Oglebay Norton and Morie Co. Glass manufacturing for containers, automobiles and buildings was mixed during 1995. Containers, the largest consumer of silica sand, remained steady, with regional increases. However, silica use in glass containers face increased competition from plastic and recycled glass (cullet). It was reported that the Pepsi Cola announced plans to replace glass containers with plastic during 1996.

Jan 1, 1996

By D. Michael Holloway

The realignment of Interstate 880 replaces the double-decked (Cypress) viaduct collapsed in Oakland, California during the 1989 Loma Prieta Earthquake. The California Department of Transportation (CALTRANS) evaluated several pile foundation schemes for supporting the proposed structures. Structural support demands led to the selection of steel pipe piles (16-, 24-, and 42-inch-(406-, 610- and 1067-mm-)diameter), filled with concrete and steel reinforcement. Deep penetrations required through layers of very dense/cemented sands in some locations, caused serious drivability and pile integrity concerns. The need for large pile driving hammers and large diameter steel pipe piles pushed the engineers and prospective contractors well beyond the limits of local experience. Such questions as the feasibility of driving the pipes closed-ended through dense upper strata, and quantifying the effects of installation on the long-term capacities of the piles, led CALTRANS to develop a comprehensive pile test program to address the design and construction issues effectively. The results were furnished to prospective bidders on the production stages of the ensuing contracts.

Jan 1, 1996

By R W. Thomas

This paper explores the possibilities of generating radical improvements in the drilling costs and productivity of blastholes through the efforts of integrated teams as opposed to traditional customer/vendor relationships.

Jan 1, 1996

By Helena Byrdziak

Polish Copper Industry, located in the Lepica-Glogów region and operated since the 1970's, includes four mines and two smelters, "Legnica" and "Glogów", the latter consisting of "Glogów" I" and "Glogów II" both having different technologies. The "Legnica" and the "Glogów I" smelters using shaft furnaces, so sulfur elimination largely takes place during batchwise converting, resulting in fluctuation SO2-concentration between less than 1% up to 10% in the converter pas W the sulfuric acid plants. The ensuing difficulties of the past have now largely been overcome. Introduction of flash smelting at "Glogów II" with subsequent acid making by double SO2-conversion from the stable process gas, contributed significantly to further reduction Of SO2-emission. In 1994 a new double conversion sulfuric acid plant was installed at "Glogów l" as well as a "Solinox" desulfurisation plant at "Legnica", further reducing SO2 emission considerably, The next step towards this goal under consideration is a semi-dry desulfurization system for the "Glogów I" power station, SO2- abatement measures by KGHM and the results thereby achieved are presented.

Jan 1, 1996

By Mehmet F. Taner

"Abstract - The East Sullivan Stock (ESS) is a small, composite felsic alkaline pluton of presumed late Archean age in the Val d’Or mining district. Three main facies have been distinguished: monzonite sensu stricto, porphyritic monzonite, and green trachytic porphyry. This monzonitic group of rocks is of relatively homogeneous composition with high abundances of Na2O, K2O, Ba, Sr, Rb, Zr, Mo and LREE. The alkaline ESS is distinguished from other igneous units in the Val d’Or mining district, such as the Bourlamaque Batholith, by relatively high concentrations of Ba, Sr, Rb, Mo, Cu and Au. The ESS hosts many base (Cu, Mo) and precious (Au) metal occurrences, including: (1) porphyry style Cu-Au-Mo disseminated sulfide deposits, (2) Cu-Au deposits in volcanic rocks near the ESS contact, and (3) pyritic gold mineralization in east-west trending shear zones. The ESS is well defined by concentrical zoning on the aeromagnetic vertical gradient color map, and displays four linear trends, which are assumed to be structural lineaments, at 035°-055°, 320°-300°, eastwest, and north-south. The main mineral occurrences related to the stock display a preferred spatial association with the east-west linear magnetic trends.The ESS is preferentially located along a major structure and was emplaced late in the evolution of the Abitibi subprovince like other felsic alkaline plutons. This stock is similar to late-tectonic mineralized felsic alkaline intrusions of the Kirkland Lake and Larder Lake mining districts in Ontario, and to the Allard stock in the U.S.A. which is associated with gold and base metal mineralization. Similarities also exist with younger alkaline plutons associated with Cu-Mo-Au porphyry deposits in the Canadian Cordillera, which formed in tensional tectonic environments. The felsic alkaline magma may have formed by partial melting of deeply buried supracrustal rocks, concomitant with the development of deep fractures such as the Cadillac Fault. In such an environment, hydrothermal solutions carrying remobilized metals from deep supracrustal rocks may have deposited gold and base metals in structural traps. Plutons similar to the ESS should be good targets for mineral exploration. Résumé - Le Stock de East Sullivan (SES) est une intrusion composite alcaline d’âge tardiarchéen, situé dans le camp minier de Val d’Or. Trois principaux faciès ont été identifiés: une monzonite sensu stricto, une monzonite porphyrique et un porphyre trachytique vert. Les données chimiques montrent que ce groupe des roches monzonitiques est relativement homogène en composition avec des concentrations élevées de Na2O, K2O, Ba, Sr, Rb, Zr, Mo et ETRL, définissant une suite alcaline typique. Cet alkalin stock peut être facilement distingué des autres unités géologiques de la région de Val d’Or, tel le batholite de Bourlamaque, par une concentration élevée de Ba, Sr, Rb, Mo, Cu et d’Au. Le SES contient plusieurs importants prospects de métal précieux (Au) et de métaux de base (Cu, Mo), incluant: (1) une minéralisation disséminée de type porphyre Cu-Mo-Au, (2) une minéralisation de Cu-Au dans les roches volcaniques encaissantes hôtesses près du contact et (3) une minéralisation d’or pyritique dans une zone de cisaillement de direction est-nordest. Le SES est bien défini sur la carte aéromagnétique en couleurs du gradient vertical par des zonages concentriques, où quatre linéaments structuraux ont été reconnus: 035°-55°, 320°-300°, est-ouest, et nord-sud. Les principales zones minéralisées spatialement associées au stock sont généralement situées soit près des linéaments magnétiques est-ouest, soit le long de ceux-ci.Le SES semble s’être mis en place le long d’une structure majeure, développée tardivement dans l’évolution de la Sous-province abitibienne, comme les autres plutons alcalins felsiques. Ce stock est similaire à la suite tardi-tectonique d’intrusions alcalines minéralisées des camps miniers de Kirkland Lake et de Larder Lake en Ontario, ou"

Jan 1, 1996

By Y. Z. Zhang

Electrochemical oxidation of arsenopyrite in ferric sulphate media in the absence and presence of bacteria T jerrooxidans has been investigated for the purpose of understanding the dissolution chemistry of arsenopyrite and the bacteria attack mechanism. Mixed potential, polarization resistance measurements, polarization curve, cyclic voltammetry experiments were conducted in a ferric sulphate medium of 10g/L FeH, temp.25-35°C, pH 1.5-2.5 in the absence and presence of bacteria Tjerrooxidans, respectively. For the anodic process, a two-step reaction sequence is suggested by the electrochemical measurements. The initial step at a low potential is described by:

Jan 1, 1996

By Peter Hornby, Maurice Craig, Franklin G. Horowitz, Don Bone

We have developed a high-performance, flexible scheme for interpolating multi-dimensional data. The technique can reproduce exactly the results obtained, for example, from Ordinary Kriging and related techniques in 3D, or from Thin-Plate Splines (Briggs' minimum-cuwature algorithm) in 2D. Moreover, com- pared to traditional implementations of these algorithms, our method enjoys large computational-cost savings. The new approach produces an interpolation that obeys a Partial Differential Equation (PDE). The PDE may arise from physically based arguments, but its form can vary widely. It might be specified only implicitly (as through a Model Variogram), or be nonlinear (although a performance penalty could then apply). While a formal equivalence between Kriging and Splines has been known for some time (Matheron, 1980), the present derivation, from radial basis functions, further illuminates this connection. Thus, for example, we can make explicit the PDEs that underlie some of the Model Variograms most often used in Geostatistics. Besides its practical utility, the work thereby ac- quires a theoretical interest.

Jan 1, 1996

By Rick Sarkisian, Albert D. Bonneau, David Keech

The Drummond Co. Inc.'s Shoal Creek Coal Mine Slope Belt Conveyor transports 5000 mtph (5500 tph) of material over a length of 1400 m (4600 ft.) and a lift of 3609 m (1180 ft.). Four 1500 kW (2000 hp) motors power the 1830 mm (72 in.) Goodyear Flexsteel 5800 steel cable belt. In May 1993, Dodge Manufacturing was selected to design and build the conveyor pulley assemblies for this conveyor. The conveyor includes five pulley assemblies. The 2135 mm (84 in.) diameter by 2135 mm (84 in.) face primary and secondary drive pulleys were designed for a resultant belt load of 3060 kN (688,000 Ib.) This paper describes the design and manufacture of the two drive pulley assemblies. Design details included are component evaluation, material selection, locking assembly selection, bearing selection and lagging selection. Manufacturing details include material procurement, welding process, lagging installation and component assembly. Quality control procedures are also discussed.

Jan 1, 1996

By V. M. Torres

An empirical correlation to detennine laboratory mill grinding time has been developed. Grinding samples to 90 ± 5# below 147 micrometers was required for a flotation testwork at Companhia Vale do Rio Doce (CVRD) Research Center. The initial samples were all below 1 mm in size with different size distributions and work indices (Wi) ranging from 13 to 23 kWh/st. Grinding curves were determined for some initial samples. A correlation was developed between percent retained on 147 micrometers at a standard time and the time required to grind each sample to the required size. This correlation was then used to grind all samples, based on the preliminary grinding model. Finally, a statistical analysis with the size distribution of all samples was performed. The success of using the correlation was confirmed and an equation was determined using the data set.

Jan 1, 1996

By Animesh Jha, Chris Dometakis

"Without the use of a flux, only a poor dispersion of ceramic phase can be achieved. A molten-flux-assisted ceramic phase dispersion technique for producing aluminium alloy metalmatrix composites has been developed. In this paper, we report the physical chemistry for the dispersion of TiB2 in molten aluminium. In particular, aspects of the interfacial energy and the thermodynamics of the dispersion reactions are briefly discussed for enhancing the volume of dispersion phase in the molten metal and for controlling their morphology. This investigation also addresses the role of molten flux in the fabrication of AI-alloy mmc using a casting technique. The morphological aspects of the dispersion are explained on the basis of the classical theory· of nucleation.IntroductionMetal matrix composites (MMCs), have long been recognised as an important class of material due to their greater wear resistance, specific stiffness and temperature capability when compared to conventional monolithic alloys. Particulate reinforced composites produced by melt casting techniques have been amongst the first MMCs to achieve commercial market viability. The advent of melt mixing techniques such as the Duralcan™ process have enabled low cost, easily fabricated composites based on the AI-SiC and AIAlz0 3 systems to be produced. In this process, uncoated ceramic particles with diameters 10ltm and larger, are incorporated into conventional monolithic alloys with reinforcement levels up to 25 volume percent. The AI-7Si-SiC metal-matrix composites have good wear resistance, high strength, low density and high thermal conductivity. The combination of these physical and mechanical properties has become a major attraction for the fabrication of light-alloy composite disc rotor brakes for the automotive sector2. However, in silicon-free alloys, SiC is thermodynamically unstable above the composite melting point and is extensively attacked by the melt to form aluminium carbide3 :"

Jan 1, 1996

By S. Behl, S. Mathur

It was previously reported that dolomite samples from different locations showed varying flocculation behavior with poly(ethylene oxide) (PEO). In this study, a Florida dolomite sample was examined, and it was determined that palygorskite associated with dolomite was responsible for its flocculation with PEO. A detailed characterization of dolomite samples from different locations was made by electrokinetic, XRD and FT-IR analyses, and the relevance of these characteristics to flocculation with PEO is discussed.

Jan 1, 1996

By Mark S. Stagg, David E. Siskind, Stephen V. Crun, Willard E. Pierce

The USBM is studying the impacts of low-frequency blast vibrations on residences to assess both response and cracking potential. Complementing coal mining sites monitored in the midwest and east, vibrations were analyzed at a major construction site in southern Florida where potentially serious low-frequency blast vibrations were believed to exist.

Jan 1, 1996

By J. A. Rose, A. S. Atkins

Environmental awareness has become a paramount consideration in the issue of planning and licensing arrangements for the disposal of wastes associated with mining operations. In this con- text the disposal of liquid tailings is a difficult and controversial problem with regard to environmental surface disposal. The paper outlines the use of Information Systems for decision support in the safe and environmental disposal of liquid tailings linked to conventional coarse refuse operations. This offers both an economic and an aesthetic approach to a historical perception of waste tipping in the underground coal extraction industry. The paper will demonstrate a prototype system that incorporates multimedia facilities which include data such as; voice comments, site photography, site plans and fluid flow circuits.

Jan 1, 1996

By Ernie Doell, Trung Nguyen

"In early 1995 Cluff Mining commissioned a newly constructed high density tailings thickener at its Cluff Lake uranium mill. The 85 ft diameter high density thickener is one of the first of its kind in North America, and incorporates the novel paste technology in its design to produce densified (in the range of 60 -65% solids) mill tailings suitable for stable deposition in the tailings management area. This paper discusses the impetus behind the installation of such an unconventional thickener, and the many trying experiences in making it operational.IntroductionCluff Mining, a wholly owned subsidiary of Cogema Resources Inc., is the operator of a uranium mine and mill complex at Cluff Lake which is located in northern Saskatchewan. Since 1980, the company has developed and mined out several different ore bodies within the Cluff Lake region for the production of uranium concentrates, commonly known as yellow cake. Based on the known ore reserves, the Cluff Lake operations are projected to last till the early 2000's.Tailings from the Cluff Lake mill have been discharged to a tailings management area consisting of a tailings pond and two facilities for primary and secondary treatment systems. The tailings pond has an impervious bentonite lined dam, and it is divided into a solids and a liquids holding areas. Until the beginning of 1995, the mill tailings were discharged in two separate lines to the solids pond; one line carried the slurry residue of 45-50% solids (w/w) from the CCD circuit, and the other discharged raffinate tails containing less than 1 % (w/w) gypsum precipitate. Supernatant in the solids pond is treated in the primary treatment system prior to discharging to the liquids pond. Figure 1 shows the site plan of Cluff Lake tailings management area.It has been estimated that by the end of 1995 the solids pond would be filled to about 60% of its design capacity, and probably would be full before the year 2000. Therefore, Cluff Mining had to consider a more efficient tailings disposal method that could extend the service life of the existing Cluff Lake tailings management area. A high density tailings thickener was believed to be the most practical and economical system for tailings disposal at Cluff Lake mine."

Jan 1, 1996

By Gao K, Wu C, Xia J, Burdett M

X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques have been adopted in this study, to investigate the structure of carbonaceous materials such as graphite, brown coal char as well as coke, in order to explain their dissolution performance during ironmaking. These materials have been selected for study since they are commonly used recarburizers in the metallurgical industry. It was concluded that the crystal structure in a carbonaceous material can have a significant influence on its dissolution into iron melts. The material with the highest degree of ordering, which is graphite, showed the best dissolution performance. In contrast, the material with the lowest degree of ordering, which is brown coal char, showed the worst dissolution performance.

Jan 1, 1996

By Robert Matusewicz

Ausmelt Technology has been applied to the recycling of spent pot liner (SPL) generated from primary alnminum production. The process is centered on the Ausmelt furnace, in which the SPL is converted under high temperature, oxidizing conditions to an HF containing gas stream and inert slag. fluorine is recovered from the SPL as HF gas and is concentrated and used to manufacture AIF) for recycle to the aluminum smelters. Approximately 87% of the fluorine can be recovered and converted to AIF), with the remainder being effectively tied up in the by product slag. Cost projections show that the recycling process will be competitive with other processes for SPL. The production and recycling of AIF) provides available credit that significantly offsets the operating cost of the facility. Ausmelt Technology for recycling of SPL is currently being marketed in North America by Ausmelt Technology Corporation in Denver, Colorado, and in the rest of the world by Ausmelt Limited of Dandenong, Australia.

Jan 1, 1996