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By Bailey S, Avraamides J

Laboratory-scale experiments were conducted in a mechanically stirred aeration vessel to determine the rusting abilities of aerated water in the presence of various catalysts compared to the industrially used ammonium chloride. The catalysts used were tartaric acid and citric acid, firstly by themselves, and then in later experiments mixed with ammonium chloride. From these experiments it was found that leaching of iron from reduced ilmenite in the presence of either tartaric acid or its sodium salt was much slower than in the presence of ammonium chloride. Citric acid or its sodium salt also give a slower rate of leaching than the ammonium chloride system, but citric acid and its sodium salt mixed in equal proportions produced a rate of leaching approximately twice as fast as the standard ammonium chloride system. When tartaric acid was mixed with ammonium chloride the leaching rate was found to be equivalent to the leaching rate of the same amount of ammonium chloride alone, thus indicating that tartaric acid made no contribution to the leaching in this svstem_

Jan 1, 1996

By Jorgen Elbrond, Xiaoli Tang

In this paper we apply continuous-time option pricing theory (Dixit 8 Pindyck 1994) to show how to obtain an optimal investment rule for a mining project which requires sequential in- vestments. The application per se is to some extent very simple. The main purpose of the paper, however, is to draw the attention of mining people to how the option pricing theory may be used to capital investment decisions. This topic in economics is quite new but is attracting a lot of attention.

Jan 1, 1996

By P. Tsang, S. S. Peng

The stability of longwall chain pillars depends not only on the mechanical properties of the coal and surrounding rocks but also on geological and mining conditions. To evaluate the effects of each variable, orthogonal experimental design was employed in a significance analysis. The study concluded that the stability of longwall chain pillars is mainly controlled by the ratio of pillar stress to pillar strength, the ratio of the Young's moduli of roof to coal and floor to coal, entry width, pillar width and the internal friction angle of coal. Additionally, horizontal stress, panel width and mining height also play a significant role.

Jan 1, 1996

By S. R. Reddy, R. G. Reddy

"The Margules equation is used for interpreting excess Gibbs energy of several ternary systems. In the present study activity coefficient of a dilute solute, 2, in a binary solvent 1-3 was derived. The derived expression is used to interpret logarithmic activity coefficient of oxygen and sulfur in several metallic systems. Self interaction parameter of the solute is derived from the partial function of solute using constant compositional path. An expression for logarithmic activity coefficient and self - interaction parameter of solute is also derived using Maclaurin infinite series. The derived equation is based on Maclaurin infinite series used successfully to deduce thermodynamics of self interaction of oxygen as a interstitial atom in two metallic systems. The predicted thermodynamic parameters values using Maclaurin infinite series and Margules equations, are in excellent agreement with the experimental data and also our predictions are far more accurate than the predictions made by other models.1 IntroductionIn most of the pyrometallurgical high temperatures processes, interactions of solutes such as oxygen, nitrogen and sulfur, with the solvent atoms are most important during refining processes. There are numerous theories are developed [1-25] to interpret the thermodynamics of solutes in multicomponent alloy systems. Which are mainly developed using statistical or Quasichemical equations.Wagner [4] developed one energy parameter ideal solvent model based on activity coefficient of solutes compositional dependency. He used one energy interaction term which is not able to account for interaction energy parameters for the same solute concentration at different solvent compositions and also it is ineffective model to predict for strong interacting systems."

Jan 1, 1996

By Paul Worsey, Ron Ecklecamp, Scott G. Giltner, Ronnie Inman, Terry Drechsler

A blast monitoring program conducted at Chemical Lie Company’s new lime calcining facility near Ste. Genevieve, Missouri is discussed. The purpose was to develop blasting criteria for the construction and operation of the lime plant within the quarry operated by Tower Rock Stone. Further, it was imperative to accommodate production requirements into the blasting criteria. The major concern was the effect of blasting on the curing of green concrete during the construction of the storage silos and kiln stacks. In addition to discussing the susceptibility of curing concrete to blast vibrations, the paper also details how this varies with time.

Jan 1, 1996

By E. Topuz, J. Mastoris

The problem of defining the optimum final limits of an open-pit mine has challenged the mining industry for the last three decades. The difficulty results mainly from the great number of variables involved and from the sheer computational effort required in real-life applications. An actual lignite deposit is used in this study to introduce and apply a new methodology that can be used as a basis for surface-mine design optimization. A geologic-reserves model of the deposit is first developed with the use of an integrated geostatistical-modeling package. The model is transformed into an economic one through the use of flexible objective function formulation(s). The final open-pit limits are then optimized using a competent commercial optimizer, and comparative-sensitivity analyses are performed to study the effect of some basic mining and economic parameters on the optimal pit design. The conclusions drawn can develop useful guidelines for decision making by the mine operator.

Jan 1, 1996

By P. D. Rao, D. E. Walsh, W. W. McClintock

A column flotation system was designed to conduct release analyses on a very finely disseminated, stratiform copper ore from the Denali Copper Prospect in Alaska. Chalcopyrite is finely disseminated in a carbonate matrix, and pyrite is disseminated in both the chalcopyrite and the gangue. Grinding to -20 µm is required for adequate liberation. A 25-mm x 2.4-m glass flotation column was designed. The ore and its flotation tailings were repeatedly floated to obtain a rougher concentrate. The rougher concentrate was then repeatedly floated to produce release fractions. These fractions were analyzed for copper, iron, calcium and magnesium, and release curves were plotted. The procedure was replicated at each of two grinds, i.e., 99% and 88% passing 37 µm (400 mesh). The procedure should find application for flotation characterization and process selection. Bond grindability testing was also conducted.

Jan 1, 1996

By J. Shahabpour

"Many porphyry copper deposits of the Kerman copper province in central Iran are associated with a consistent structurally con-trolled main drainage pattern, which is shown in this paper to be a useful regional prospecting tool in the search for new deposits. The main drainage trends also generally allow the distiction of high-grade (>0.2% Cu) from low-grade (<0.2% Cu) deposits. Topographic maps1:50 000 or geologic maps 1:100 000 have been found suitable for identification of promising drainages.IntroductionTrends of the main drainage systems transecting the high-grade porphyry copper deposits of the Kerman Region in Iran coincide with Quaternary age regional faults and fractures. Observation of such drainage trends can expedite regional evaluation prior to field examination. Thirty deposits located in the Kerman Region (Fig. 1) have been studied to identify common features that can be used for exploration purposes, especially for the first stage of regional exploration. A variety of field criteria are available for subsequent rapid field checking prior to trenching and more costly methods such as drilling, etc.Characteristic geomorphic features have been considered as aids in mineral exploration by many authors (e.g., Faniran, 1971; Piotrovski and Lubkashov, 1976; Verstappen, 1983). Clark et al. (1967) indicated the relationship between geomorphology and the supergene enrichment of copper in Atacama Desert, Chile, and correlated three periods of supergene enrichment with three periods of pediment disection. Seeland (1978) used fluvial drainage patterns for uranium and hydrocarbon exploration in the Wind River basin, Wyoming. Postolenko and Konopleva (1973) used the reconstruction of ancient valley systems for exploration of gold placers"

Jan 1, 1996

By R. C. Hubli

Copper (II) chloride has proven to be an efficient lixiviant for copper sulphide ores and secondary sources of copper such as scrap. Nickel sulphides are generally associated with copper ores and copper-nickel matte is an intermediate product of processing mixed sulphides. While the copper species in aqueous chloride media are present as chlorocomplexes, the presence of nickel as Ni++ offers effective separation between the two by solvent extraction techniques. Oxidation of millerite by cupric chloride in sodium chloride solutions has been studied as a function of rate of agitation, leaching time, temperature, acid concentration and total initial cupric concentration. The reaction has a 1/2 order of dependence on initial cupric concentration in the range of 0.0 to 0.5M. The activation energy for the temperature range 333 -363 K has been found to be 59.2 kJ/mol with chemical reaction at the unreacted mineral surface as the rate controlling step. The rate expression, according to the shrinking-core model, for initial cupric concentrations between 0.0 to O.5M, is evaluated as

Jan 1, 1996

By J. Bender

The objective of this research was to (1) Further develop cyanobacteria mats&apos; for metal-tolerance and cold-tolerance, (2) test them for durability in the field environment and (3) assess them for metal sequestering potential with actual and simulated field samples. Results show that mats performed well In the field and effectively sequestered metals from actual and simulated field samples. Metal uptake from Iron Mountain Hine samples was for Ins 87%, Cu and Cd 99%, Initial concentrations (mg/L) were Zn = 3,250, Cu , 279, Cd = 28. In solutions simulating the Gulf Tunnel drainage, Zn and Mn were effectively removed by mats immobilized on glass wool. Effluent water, after treatment, generally had a Ph of 7 .5-8.5. Al though the final metal concentrations in the mats &apos;harvested from the decontaminated water were only 1% or less, the actual mechanism of metal deposit was probably a mat-mediated alteration of the environmental conditions causing the metals to deposit outside the mat as oxides or carbonates. Bioflocculents, released by the mats, were likely involved in the metal-removal process.

Jan 1, 1996

By S. C. Torma

Sources of lead contaminated soils are numerous, i.e., the uses of leaded gasoline, lead-based paints, leaded pesticides, solders, smelting of lead concentrates, refining of lead products, automobile demolition, recycling of lead batteries, and so on. Conservative estimation by the US Environmental Protection Agency, EPA, indicated that several thousand lead contaminated sites are awaiting remediation. The current remediation technologies include immobilization, reclamation and soil washing. In this paper, the above remediation technologies will be reviewed, and where appropriate, the economics of processes discussed and future possibilities indicated.

Jan 1, 1996

By C. Bemelmans

Lead alloys function effectively as oxygen evolving anodes in copper SX-EW operations and are highly resistant to corrosion. The presence of organic from solvent extraction in the electrolyte seemed to enhance solution line attack. Laboratory tests showed that lead is soluble in D2EHPA, Acorga and LIX 984 to a limited, yet measurable degree. Lead alloys and various lead phases formed on the anode were tested to evaluate their effect on the corrosion process in organic media. Possible causes for anode corrosion and mechanisms responsible for their initiation will be discussed.

Jan 1, 1996

By Graham Farquharson, Jame Marshall

"Mining towns have always been an important part of Canadian geography. Many Canadians grew up in them. The frontiers of northern Canada would be a lot closer to the United States border but for the pioneering of new mines, new towns, and new transportation routes. Names such as Labrador City, Chibougamau, Val d’Or, Rouyn-Noranda, Kirkland Lake, Timmins, Sudbury, Red Lake, Thompson, Flin Flon, Yellowknife, Whitehorse,Trail and Kimberley are some of the better known larger communities that have grown to become major commercial and government centres, but which started as the base for a mining development.Many other smaller towns never grew beyond being small communities, dependent upon the local mine and many of these are still alive, but perhaps not quite what they used to be. In this list would be Buchans, Schefferville, Chapais, Cadillac, Virginia town, Lynn Lake, Uranium City, Pine Point, and Keno Hill.Nevertheless, all these towns and dozens more like them were residential communities where people lived and raised families and were quite accustomed to being days from the major centres of Montreal, Toronto, Edmonton and Vancouver, and not just hours away as wet end to measure travelling time today."

Jan 1, 1996

By Gordon A. Irons

"Powder injection for melt refining is widely practiced in the steel industry, and is gaining acceptance in the non-ferrous industries. In these commercially-important systems, the thermodynamics and kinetics may be very complicated. More than one element may be removed by refining, and often the refining agents are not just one compound. In this paper, the thermodynamic and kinetic aspects of these processes are reviewed. A number of examples are given, such as the desulphurization of iron with a variety of reagent mixtures, and selenium removal from copper with several different reagent combinations.IntroductionI am very pleased and honored to present a paper at this Symposium recognizing the many contributions of Professor Howard Womer. Even at the time I was an undergraduate student, the WORCRA process was part of the curriculum. I remember at the time that I was fascinated by the concept, and due to it and the many other rapid developments in Process Metallurgy, I chose it as my field of study. I think the Symposium is testimony that Professor Womer has touched the lives of many others as well.My original assignment was an overview of the basic aspects of gas and solids injection. However, I reviewed most of this material at the Savard/Lee Symposium [1]. In the present paper, I will present some of the basic issues related to refining with powder injection, using work that we have recently completed in both ferrous and non-ferrous systems."

Jan 1, 1996

By Baozhong Zhao

Experimental results have shown that fluxing with soda ash (Na:zC03) can remove As and Sb from molten copper at the rate of As>Sb, but is relatively ineffective in removing Hi. The rate of impurity removal is controlled by impurity mass transfer in the metal phase. In this paper, a mathematical model was developed to describe the impurity removal phenomena. The model incorporates the effects of molten bath mixing intensity, soda ash feeding rate, oxygen content in the molten copper and soda ash fluxing by surface addition and injection. The model predictions are in good agreement with experimental results and may be used in designing large scale tests.

Jan 1, 1996

By Mauro F. Dobran

The use of Slot Raises has been common for many years. The following presentation will compare various methods of developing these Slot Raises and introduce two new ones.

Jan 1, 1996

By D. Goossens

Quality control is a system which should guarantee that quality is achieved. It is the execution and verification of a project in an organised way, in order to obtain the maximum of certainty that the results meet the requirements. This concerns all stages of the project, from the soil investigation, over the design, to the execution. Quality control can and has been successfully realised for important projects by means of a quality plan. A quality plan is based on a number of general considerations, but should certainly be focussed on the particularities of a specific project. Practical examples of quality plans, which have been realised on sites in Belgium, are developed and the advantage of the system is shown by concrete case studies.

Jan 1, 1996

By Woodhouse M, Drew GJ, Andrews DL

The Honeymoon nickel sulphide deposits are located 45 km south of Wiluna in the 2.7 Ga old Agnew-Wiluna greenstone belt in the NE of the Yilgarn Craton (Figure 1). Both disseminated and massive nickel sulphide deposits are present within the deformed and metamorphosed Honeymoon Well ultramafic complex and are hosted by distinctly different komatiitic lithologies (Gole et al, 1996). The deposit styles and host rock lithologies reflect formation in markedly different volcanic settings. Metasomatism has affected parts of the ultramafic complex, including sections of the sulphide deposits, and has had a marked impact on mineralogy and bulk sulphide compositions. The present indicated resource is 158 Mt at 0.71 per cent Ni in four deposits (0.4 per cent Ni cut-off, resources above 300 m depth, December 1995). This includes a massive sulphide resource of 2.5 Mt at 3.36 per cent Ni.

Jan 1, 1996

By Mark Kramer

This paper is limited to treatment of bottom and fly ash waste resulting from WTE and RTE Cogeneration plants, commonly known as trash burners. The body of the paper defines waste generation and conventional treatment schemes. This paper does not identify a best treatment, however, it does offer a general perspective of the treatments to lead the reader to further investigation. Advantages and disadvantages of the ash treatments Is discussed in each treatment section.

Jan 1, 1996

By Dean R. Gehring

Creating projects to reach a goal is not new to American industry. In fact, all major construction projects, from skyscrapers to bridges, are completed using similar project management techniques. However, modern project management is relatively new. It was not formalized until 1962, when NASA and the US Department of Defense recognized the need to develop uniform project management procedures throughout the aerospace industry (Moder, Phillips and Davis, 1983). This management method was not introduced to the mining industry until the early 1970s (Britton, 1983). Project management typically follows an organized, four-stage process —definition, planning, implementation and control.

Jan 1, 1996