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Jan 1, 1996

By Animesh Jha, Catherine Davey

"Carbothermic reduction and nitridation reactions using synthetic kaolinite mineral were investigated for the formation of silicon based nitrogen ceramics. The temperature dependence of the reaction rate and its effect on phases formed are reported. The effect of the reactivity of carbon on the kinetics of formation of AIN and ShN4 is discussed. Using the standard Gibbs free energy values for the formation of nitrides and oxides of aluminium and silicon, a log po2 verses I/T diagram is constructed. The experimental data results are discussed and compared with the predicted phase equilibria. We also report the influence of sub-oxide gaseous species on the microstructure of the ceramic phases produced.IntroductionSynthetic kaolinite is a clay containing alumina, silica and water of crystallisation, and has a chemical formula 3(Al2O 3.2SiO2.2H2O). This mineral is relatively inexpensive and, is therefore an ideal candidate for use in the production of ceramic powder mixtures for example silicon nitride and aluminium nitride for composite material formation, When the mineral is heated, the water of crystallisation from the crystal lattice is lost via the 3(Al2O 3.2SiO2.2H2O) = 3(Al2O3.2SiO2) + 6H2O reaction. It has been shown [1·2j that on further heating to 1673K, the anhydrous kaolinite decomposes to a mixture of mulllte and silica, 3(Al2O3.2SiO2) = 3Al2O 3.2SiO2 + 4SiO2 which is consistent with the alumina-silica phase diagram, shown in figure 1.The binary alumina-silica phase diagram has a well-defined sub-eutectic immiscibility dome and this characteristic dernixing behaviour is reflected in the thermal decomposition of anhydrous kaolinite consequently the microstructural features resemble the spinodal decomposition process. It is well established that the spinodal decomposition process raises the nucleation frequency due to their low free energy barrier, (?G). The small magnitude of this barrier consequently promotes the evolution of a very fine microstructure. The process of spinodal decomposition is therefore expected to be influential during the reduction-nitridation of kaolinite minerals."

Jan 1, 1996

By J. C. Yingling, R. J. Sweigard, S. T. Mickleborough

The geostatistical technique of conditional simulation is applied to measure the uncertainty inherent in the factor-of-safety (FS) predictions for soil slopes in which there is an incomplete knowledge of the spatial distribution of soil properties. A case study that considers a natural clay slope in Canada is presented. The sequential-indicator simulation technique was used as a means of generating a series of spatial maps of the soil properties at the site. These maps approximate random draws from the conditional probability density function that characterizes existing uncertainty in the spatial distribution. FS determinations were made for each simulated map using the simplified-Janbu approach. In using this approach, computations are performed using a new computer program that can operate on irregular spatial profiles of soil properties specified on a discrete grid. A unique capability of this approach is the ability to generate the FS distribution conditional to the type, position and value of existing site-characterization measurements. This capability should reduce uncertainty in FS predictions.

Jan 1, 1996

By E. R. Torak

Custom Coals, International has installed and is presently testing a 225 kg/hr. (500 lb/hr.) micronized-magnetite, fine-coal cleaning circuit at PETC's Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program's High Efficiency Preparation Subprogram. The project includes design, construction and testing of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense-medium cycloning of the 300 by 30 micron feed coal using three different size micronized-magnetite mediums, and medium recovery circuits using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

Jan 1, 1996

By Richard P. Curtin, John M. Goris, Lewis A. Martin

Cable bolt supports are being recognized as an effective ground control system in under-ground coal mines in North America, and their use has increased considerably during the past few years. The U.S. Bureau of Mines personnel are conducting both laboratory and field tests to evaluate the performance of these supports under a variety of conditions and to establish realistic design guidelines. This paper describes efforts to evaluate the capability of cable bolts to resist the high shear forces often present in longwall operations. Shear tests were conducted on pairs of 0.025 m3 (0.88 cu. ft) concrete blocks having joint surfaces ranging from rough to smooth. Tests were conducted on blocks both with and without reinforcement with 15.2 mm (0.6 in.) diameter steel cables. During each shear test, the loads and displacements along the normal and shear axes, as well as loads on the cable, were monitored. Cableloads were determined using strain gauges attached to the outside surfaces of the barrel-and-wedge anchors used for pretensioning the cables. Test results show that a cable bolt placed across a joint more than doubled shear resistance of shear blocks having both smooth and rough joints.

Jan 1, 1996

By M. D. Johnson

Mina Santa Rosa, in west central Panama, is the first large-scale gold mine in Panama and will soon be the largest single-mine gold producer in central America (Fig. 1). At full production, the mine will process 1.8 Mt/a (2 million stpy) of ore and produce more than 1.8 t/a (60,000 oz/year) of gold and 9.3 t/a(300,000 oz/year) of silver. Mina Santa Rosa is a subsidiary of Greenstone Resources of Toronto, Ontario. Freeport-McMoRan geologists first visited the area in 1985. Their rock chip sampling adjacent to old shafts and adits confirmed widespread gold and trace element geochemistry anomalies. Surface mineralization appeared to be localized in and adjacent to narrow veinlets. However, they recognized astructural setting similar to the Nevada Tertiary volcanic-hosted epithermal gold systems.

Jan 1, 1996

By Abdullah Arik

An ore reserve block model is the basis for various decisions in mine development and production. The block model is initially built using the information from the drillhole data only. Once the mine is put in operation, the information from the blasthole data becomes available. Since the spacing of the blastholes are much closer than the exploration drillholes, the blasthole data gathered from the mine over the years become quite extensive containing valuable information about the deposit. In practice, the information from the blastholes is the basis of determining the ore and waste boundaries between and within mining blocks. In an ore reserve model, the valuation of blocks on and close to the pit face can obviously be improved by using blasthole data from neat by drilled and mined-out blocks in addition to using the widely spaced drillhole data. The ideal basis on which to integrate blasthole and drillhole data is to use cokriging.

Jan 1, 1996

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

By G. A. Campbell

This paper considers the international market trends of the rare earths and how they are strongly influenced by the by-product/co-product nature of their mining and processing. The two main economic minerals for the rare earths are bastnasite and monazite. Monazite is primarily a by-product of mining ilmenite and rutile and is affected by changes in these markets as well as the presence of thorium. Bastnasite is a by-product of mining iron ore in China and a stand-alone product in the USA. The paper will use conceptional relationships and empirical data to delineate the various by-products/co-products relationships and how they determine observed international market behavior.

Jan 1, 1996

This paper discusses the type of scaling operations presently in use in underground mines. It defines a scaling factor that is expressed as the area necessary to scale to extract 1 t (1.1 st) of ore. The problems associated with conventional scaling methods are discussed as well as recent developments in mechanized hand-held scaling de- vices and methods of loose detection. The elements of the scaling process are further analyzed. The conception and design of a mechanized scaling device, developed at Universite' Laval is also described. The results of field tests conducted in Quebec hard rock mines are presented. The experimental findings show that the mechanized hand-held scaling device shows potential in improving the productivity and safety of underground mining operations.

Jan 1, 1996

By G. A. Kordosky

The literature contains several references to the influence of copper solvent extraction reagents on crud formation, but, there is disagreement as to whether the reagent has an influence on crud generation. The results of three pilot plant campaigns, where crud generation was studied as a function of the copper solvent extraction reagent, are reported. These pilot plants were run at operating copper solvent extraction plants using the aqueous solutions being treated by the commercial copper solvent extraction plants. Two of the pilot plant studies showed that the copper solvent extraction reagent had a significant influence on the extent of crud formation while the other pilot plant study indicated the copper solvent extraction reagent had a lesser influence on crud generation.

Jan 1, 1996

By J. B. Rubinstein, V. J. Badenicov, S. T. Hall

A simulation technique of the flotation process and models for the solution of various problems are developed. A modular model of column flotation is constructed taking into account the kinetic relationship of the process and the hydrodynamic regime in the cell. Based on this, a technique of calculating the column parameters based on laboratory tests is developed (scaling-up), and applied for calcetest results is developed (scaling-up), and applied for calculating the design of commercial-scale columns.

Jan 1, 1996

By Xinghui Meng

The leaching behavior of platinum powder in .iodide solutions under oxygen pressure in an autoclave was investigated. Ammonium salts were added to the leaching solution at neutral pH as a key lixiviant for platinum. The effect of temperature, partial pressure of oxygen, concentration of iodide and of arttmonium salts on the dissolution rate of platinum was examined. Under experimental conditions, the leaching behavior of platinum powder exhibited a complex reaction mechanism. A precipitate was found during the leaching process and was identified to be platinum ammine iodide, Pt(NH3hI4. The dissolution rate was controlled by a series of chemical reactions, the equilibrium concentration of the platinum ammine iodide being responsible for the ultimate limit to the recovery.

Jan 1, 1996

By Liow Jong-Leng

A survey of the interactions of large gas bubbles formed from top and bottom injection of gases into melts was carried out. Spherical cap bubbles were found not to produce much splash when they break through the bath free surface except for that formed by plunging of the-spout at its edges. In contrast, the bursting of balloons produces cavities which give rise to liquid jets being ejected from the bath free surface. The position of the balloons relative to the bath free surface is an important parameter in the formation of the liquid jet. It is found that the interactions of multiple bubbles close to the free surface is important in determining the splash behaviour of gas injected systems.

Jan 1, 1996

Kalgoorlie Consolidated Gold Mines Pty Ltd (KCGM) is a management company, formed in 1989, to manage the assets and operate the Kalgoorlie joint venture for the owner companies Gold Mines of Kalgoorlie Limited (GMK) and Homestake Gold of Australia Limited (HGAL). Mining is still in progress on the 'Golden Mile' and surrounding areas more than 100 years after Paddy Hannan's discovery adjacent to the active Mt Charlotte mine. From 1893 until 30 June 1995 the Kalgoorlie Goldfields has produced approximately 45 million ounces (-1400 tonnes) of gold from mining and treating about 179 million tonnes of ore. This production equates to about 20 per cent of the total Australian gold production and about one per cent of the world's

Jan 1, 1996

By Rick Coleman

PT Freeport Indonesia’s (PTFI) latest expansion has increased total mill throughput to 125kt/d (137,700 stpd). The most recent expansion included the installation of a semiautogenous mill (SAG) designed to treat more ore than any other single SAG mill currently operating in the world. Also included in the expansion were two large ball mills, rougher and cleaner flotation, including conventional and column cells, and a regrind circuit. All equipment is supported by a modern distributed control system. PTFI’s operations are located in the Ertsberg mining district of Irian Jaya’s Jayawijaya Mountains, the eastern-most province of the republic of Indonesia on the Island of New Guinea. PTFI, the operator, is owned by Freeport McMoRan Copper and Gold (81.3%), the government of Indonesia (9.4%) and private Indonesian investors (9.3%).

Jan 1, 1996

By Alexander Malahoff

The new ship-submersible system with R/V Ka'imikai-o-Kanaloa as a mothership and the PISCES V as the submersible completed its first season of dives. The dives involved deployment of the PISCES V in the Hawaiian Islands between the months of July and October 1996. Submersible deployments up to depths of 2,000 meters in sea states up to a high three were made. The new hook and clasp deployment and retrieval connection for PISCES V to the telearm was shown to be an effective system for handling the PISCES V with the A-frame. The shipboard multibeam survey and seawater sampling capability proved to be especially effective in re-mapping the summit of the submarine volcano Loihi following a major volcano-tectonic event and for following the source and configuration of the new hydrothermal plume. Following the earthquake swarm of July 17 to August 18,1996, major changes in the geological setting of Loihi submarine volcano took place. Prior to the seismic event, the geology and structure of the summit of Loihi was represented by a platform-like area 8,100 meters long and 5,400 meters wide enclosed by the 1,200-meter depth contour. The summit was characterized by the presence of two prominent pit craters and eastern and western crater located at water depths of 1,100 and 1,370 meters, respectively. A hydrothermally active volcanic cone, named Pele's Vents, was located at a depth of 960 at the southern edge of the summit. The floor of the summit of Loihi was largely covered by prismatic talus, with interstitial hydrothermal clays. Pillow and tube lavas with volcanic cones 5 to 50 meters high were exposed along the axes of the southern and northern rift zones. The inner margin of the summit displayed fissures and normal faults with the downthrown component towards the center of the summit. The pre-earthquake structural data suggest a pre-caldera structural stage for Loihi. Maximum sustained hydrothermal activity observed on Loihi over the past 10 years existed at Pele's Vents with other sporadic venting occurs along the summit platform and along the south rift. Following the earthquake swarm, the hydrothermally saturated Pele's Vents cone gave way and slid into the inner pit crater. Subsequently, the observed above- bottom hydrothermal plume source deepened from 960 to 1,160 meters, possibly emanating from the same intrusive heat source as Pele's Vents. The observed inward collapse of the summit structures and subsequent opening of fissures gave rise to diffuse venting from the newly formed caldera-like depression with the bottom-hugging hydrothermal pool located at depth between 1,250 and 1,220 meters at the sites of the pit craters.

Jan 1, 1996

Microwave pretreatment can improve grindability by weakening brittle particulate material prior to size reduction. The differential thermal expansion experienced by multiphase materials during rapid heating can also promote damage in the grain-boundary region, which may ultimately translate into enhanced liberation. The effect of microwave pretreatment on the breakage characteristics of different ores has been studied using the Ultrafast Load Cell. The energy accumulated during impact (fracture energy) and the particle stiffness have been measured for untreated and microwaved ore samples. It has been observed that microwave pretreatment can weaken brittle multiphase particulate material, as observed by reductions in fracture energy and increase in damage.

Jan 1, 1996

By P. J. Ryan

Phelps Dodge’s Candelaria copper-gold mine is located 20 km (12miles) south of Copiapó in northern Chile’s Atacama province (Region III) (Fig. 1). The Candelaria Mine is about 800 km (500miles) north of Santiago and 75 km (47 miles) east of the Pacific Ocean. Its elevation is 600 m (1,970 ft) above sea level. The Copiapó River Valley is 6 km (4 miles) northeast of the mine site. It is the only major source of water in this arid region. The average rainfall is 14mm/a (0.5 in./year). During 1995, the mine produced 521.4 kt (574,800 st) of copper concentrate containing 150 kt (165,000 st) of salable copper and 3 t (98,800 oz) of gold. The 1995 unit cash cost was less than 50 cents/lb of copper. This makes Candelaria one the world’s lowest cost copper producers.

Jan 1, 1996

By Sergey Komarov, Manuela Diaz, Sano. Masamichi

"Mixing time, bubble behavior and absorption rate of gas injected into a liquid bath through rotary L-shaped lances have been studied by cold models with an effort to improve refining characteristics of metallurgical processes. Two kinds of the rotary lances were tested, namely the single-hole lance and the multi-hole lance. The effects of gas flow rate, bath depth and rotation speed were examined.It is found that when gas is injected through the rotary lances, the mixing intensity and the gas absorption rate are larger than that for the gas injection through stationary lances. The effect of rotation speed decreases as the bath depth and the gas flow rate increase.The multi-hole lance produces much smaller bubbles, which lead to an increase in the volumetric mass transfer coefficient by 3-4 times as compared with the single-hole lance. However, the effect of rotation speed is smaller for the multi-hole lance. The obtained results are explained in terms of the bubble coalescence and fragmentation, the rate of which depends on the departure bubble size and the power supplied to the liquid bath.IntroductionIn recent years, there has been a growing interest in the development of gas injector for metallurgical processes. The majority of the previous work was focused on modification to the injector design to improve mixing and to increase the of chemical reaction rate. These two goals can not be necessarily achieved by the same way. Bottom nozzles and stationary immersed top lances, which have been widely applied to steelmaking processes, are effective for the bath mixing, but have a limit to decrease in the bubble size. This results from a vigorous coalescence occurring between the bubbles when they rise in the molten bath as a bubble swarm.One of the ways to ensure the small bubble size and the effective bath stirring is the gas purging through rotary injectors. A number of studies have been undertaken to improve the refining characteristics by using rotary injectors. All of them are related to aluminum refining. The SNIF equipment (The Spinning Nozzle Inert Flotation) has significantly improved the quality of aluminum products at National Luxemburg Aluminum [1]. Rotary injectors made in the form of a disc have been applied to the Alcoa 622 [2] and the GBF processes [3]. A study of the gas injection by a rotary impeller has been carried out by C. Leroy and G. Pignacelt [4]. All researchers note the significant improvement in removal of sodium, calcium, hydrogen and non-metallic inclusion."

Jan 1, 1996