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By W. Jiao, Y. Yongqi, R. Shan

Soft rock mines are distributed through out P.R.C. And drilling and blasting is still the main method of driving a tunnel in these mines. Traditional smooth blasting has been widely and deeply studied and put into practice in P.C.R since 1970s. But the cartridge and blast hole are both columns, the stress field in the rock around blast hole at the beginning is symmetry around hole axis, and the original cracks in the rock can be activated randomly. So serious overbreak and underbreak at the boundary of an excavation occur often, especially when the excavation is in soft rockmass, and the rates of half-hole marks are generally about 50% in medium rock, and 20-30% in soft rock in Chinese coal mines. For the sake of overcoming the situation, we have been studying directed crack blasting since ten years, and have got some obvious achievements in this respect. Slotted cartridge control blasting in soft rock is studied in this paper. Through model experiments, reasonable decouple coefficient range and slot width are gotten, and unsymmetrical dynamic strain field is analyzed. Through underground test in soft rock with a strength lower than 1OMpa in Dayan Mining Bureau, The results of which the rates of half-hole marks and the nonsmooth grades of the cut contours are 83.3% and 1OOmm respectively have been achieved.

Jan 1, 2000

By M. Canty

This paper presents results from pilot-scale and field testing of an innovative technology that uses sulfate-reducing bacteria (SRB) to treat and control acid mine drainage (AMD). Sulfate-reducing bacteria, a common group of anaerobic bacteria, produce hydrogen sulfide and bicarbonate when supplied with sources of carbon and sulfate. Hydrogen sulfide reacts with metal ions in AMD, precipitating them as metal sulfides. The bicarbonate produced serves to help neutralize the drainage. Pilot-scale metal-removal efficiencies reached 99% for zinc, 99% for aluminum, 96% for manganese, 98% for cadmium and 96% for copper. However, the iron and arsenic removals were not as effective as the aforementioned metals. This was largely attributed to high levels of iron and arsenic that contaminating the organic substrate. There was evidence that both adsorption and sulfate reduction were occurring within the reactors. The SRB field demonstration involved using the flooded subsurface mine workings of the Lilly/Orphan Boy Mine near Elliston, MT, as an "in situ biological reactor." In the mine, high removal efficiencies were observed for aluminum, cadmium, copper and zinc (70% to near 100%) during the four years of monitoring. However, for reasons similar to the pilot scale testing, low removal efficiencies were observed for arsenic and iron. Sulfate reduction was evident by measured decreases in sulfate and the detection of soluble sulfide within the mine water.

Jan 1, 2000

By M. Okido, H. Yamamoto, T. Sakamoto, R. Ichino, K. Kuroda

"Hydrogen absorption alloy films have been produced by molten salt electrolysis. Lanthanum-Nickel alloy film can be formed on a nickel substrate in KCl-NaCl-LaCb molten salts by electrolysis diffusion process. LaNi5 alloy was formed by mutual diffusion between La ·and Ni after La deposition on Ni substrate. Though several kinds of La-Ni compound existed in deposits, the alloy compounds on Ni substrate changed by electrolysis condition. According to the open-circuit potential measurement in molten salts after La electrodeposition, the formed compounds had a relation to the potential. In the case of the substrate electroplated a cobalt thin film on nickel, LaNi4_5Co0.5 was formed by the electrolysis in the molten salts with lanthanum ions. This ternary alloy film showed better hydrogen absorption behavior in cyclic charge/discharge test in alkaline solution.IntroductionHydrogen storage alloys have attracted attention as the active materials for batteries with the charge/discharge property at ambient temperature. The alloy of nickel and misch metal, mainly consisting of La and Ce, has been commercially 'used as a metal hydride with rechargeable property. In recent years, researches have been developed many kind of new alloys with better hydrogen absorption properties. The hydrogen absorbing alloy ingots are commonly produced by melting method of both metals in furnace, otherwise, prepared by mechanical grinding and metallurgical sintering technique with metal powders. The film is also made by vapor-phase techniques such as sputtering method, ion plating method, etc. ·We have proposed a new method to produce hydrogen absorbing alloy films by molten salts electrolysis technique [1-3]. The hydrogen absorbing film, LaNi5, Mg2Ni and CaNi5, were obtained in this process through controlling the electrolytic condition. The active metals, La, Mg and Ca, are electrodeposited on Ni substrate, diffuse into the substrate and form various kinds of intermetallic compounds. This technique provides a direct process using metal chlorides as resources to produce functional films without using active metals such as La, Ca and Mg."

Jan 1, 2000

By Y. T. John Kwong

Modified after procedures for assessing acid-generating potential of coal spoils, most acid-base-accounting (ABA) analyses inadequately characterize highly varied metal deposits. Although mineralogy critically controls acid generation and metal leaching, acquisition of appropriate data and their interpretation are poorly developed. Metal loading rates are commonly determined by kinetic testing, which rarely duplicate actual field samples and conditions. Accurate predictions and reduced assessment costs can conceivably be achieved by (i) use of geochemical analyses to define surrogate indicators; (ii) intelligent acquisition and use of mineralogical data; and, (iii) compilation of geo-environmental ore-deposit models to validate inference based on detailed geology.

Jan 1, 2000

Modern mining and coal cleaning techniques lead to the generation of large quantities of fines which give rise to problems in their storage, handling, transportation and further processing. Pelletisation, a method of particle agglomeration, can alleviate such problems. This paper provides a brief overview of the principles of pelletisation and a survey of the coal pelletisation literature. Then it reports results from an experimental investigation of the effect of surface active reagents on coal pelletisation. Finally the paper is concluded with a few remarks on applying the results from the experimental study to practical coal agglomeration.

Jan 1, 2000

By J. H. Kempton, D. Atkins, W. Locke

The scrutiny given to model predictions of pit-lake water quality has focused attention on the uncertainty associated with long-term predictions. Although comparison of probabilistic predictive modeling of water quality in existing pit lakes suggest that short-term predictions can bracket most parameters, un¬certainties in wall-rock reactions and the stability of groundwater composition and climate remain unquantified This overview of the uncertainties associated with longer-term predictions is presented as support for those considering policy decisions that must be made in the absence of reliable estimates of future conditions.

Jan 1, 2000

By Entov Vladimir M., Gilmer R. Burgos, Andreas N. Alexandrou

"Processing of metal alloys in their mushy state represents a new trend in metal processing. As part of this process, known also as thixocasting, a specially prepared slurry at a temperature in the mushy region is injected into a die. Parts produced using this technology offer better mechanical properties than those produced by casting, and comparable to those of forged alloys.In thixocasting, semisolid slurries are highly concentrated suspensions of rounded rosette-like crystals in eutectic liquid. The mechanical behavior of the slurry is determined by the structure and properties of the skeleton formed by the alpha phase particles. The skeleton structure is almost never at equilibrium, and its evolution is, governed by a number of kinetic phenomena of different c11'aracteristic time-scales. Therefore, the skeleton structure depends on the mechanical and thermal history of the material. As a result of these kinetic processes, the rheological properties of the material, such as effective viscosity and yield stress, decrease with structure breakdown, and increase with its development. In the present investigation, the behavior of semisolid slurries during processing is modeled using the conservation equations, and a Herschel-Bulkley fluid model. The rheological parameters are assumed to be functions of the solid volume fraction, and of a structural parameter that changes with processing history. The evolution of the structural parameter is described by a first order kinetic differential equation that relates the rate of build-up and break-down of the solid"

Jan 1, 2000

By Eric G. Zahl

Researchers at the Spokane Research Laboratory of the National institute for Occupational Safety and health are evaluating stress and displacement measurements in a longwall coal mine. The objective is to determine the best indicators of coal bump hazards during operations so that mine foremen and technical stall can make more informed intervention decisions to protect miners from coal bumps. Instruments were clustered in two panels, a yield pillar, and the immediate roof and floor of a two-entry longwall coal mine. Data were gathered continuously from a variety of instruments as mining proceeded toward and past the instrument cluster. Researchers and the mine's technical staff evaluated these data with respect to coal bumps and bump mechanisms. Selected graphs were then presented to mine foremen on a periodic basis to test their usefulness in identifying hazards. Of particular interest was the use of horizontal stress data from the immediate roof. To measure changes in horizontal stress, a new technique was devel¬oped for installing a grouted biaxial stressmeter in the roof. An evaluation of the development of this stress monitoring system in producing data beneficial to mine foremen is presented.

Jan 1, 2000

By Michael T. Lambert

The purpose of the this paper is to demonstrate the benefits of using additional instrumentation during load tests of auger-cast-in-place piles. Traditionally, only load and butt displacement are determined during load tests. The results from and methods used to instrument 15 auger-cast-in-place (ACEP) piles as part of six projects are included herein. By instrumenting the piles, the distribution of load along the pile length and load transfer can be determined, allowing the pile capacity to be adjusted or the length/diameter of the pile to be adjusted for the a given required load. The majority of the piles tested were designed as end bearing piles on either shale or limestone bedrock. No discussion of Geotechnical Instrumentation can be started without acknowledgement of the "Red Book." The actual title of the book is Geotechnical Instrumentation for Monitoring Field Performance, by Mr. John Dunnicliff, John Wiley and Sons, 1993. Anyone undertaking an instrumentation program should thoroughly review the Red Book, paying particular attention to Chapters 3 and 4. Instrumentation should not be done just because it can be done. There must be an unanswered question or questions that can be answered with measured data before instrumentation should be considered.

Jan 1, 2000

By Noboru Masuko, Sachiko Ono

"The structure and composition of anodic films formed on aluminum in a borate solution have been investigated by using TEM and SIMS with respect to the effect of current density and electrolyte temperature. The film is composed of a boron-containing outer layer and a boron-free inner layer with disc-like crystals present at the interface. The thickness of the film formed at constant current density up to an identical voltage, decreases with increasing current density. The thickness increases remarkably with elevated temperature. The transport number of Al3+ estimated from the thickness ratio .of the cuter to the inner layers is 0.4 when the film is formed at the current density of 20 Am-2 at 60°C. It increases slightly with increasing current density and decreases significantly with increasing temperature. Content of boron in the outer layer increases 1.5 times when current density .increases 10 times. These changes in film structure and composition with electrolysis conditions must have a significant role in the determination of electric properties of anodic alumina films as a capacitor material.IntroductionThe growth of anodic alumina film in ·a neutral electrolyte proceeds at both film/electrolyte and film/substrate interfaces giving a duplex structure. The oxide layer formed at the former interface includes electrolyte anions while a-pure alumina layer is formed at the latter interface. The thickness ratios of each layer respectively represent transport numbers of Al3+ and 0 2 - (1). The film thickness and the incorporated anion content as well as transport numbers of both ions must affect the dielectric properties of the film as a capacitor material. However, the correlation between film structure and electrolytic conditions is not fully understood (2). For the further clarification of anodic film growth mechanism, more detailed characterization of anodic films in relation to electrolytic conditions is advantageous. In the present paper, therefore, the effect of current density and electrolyte temperature on the microstructure and composition of anodic barrier films formed in a neutral borate solution was studied. The films were characterized by direct observation using transmission electron microscopy (TEM) and depth profiles of constituent elements obtained by secondary ion mass spectroscopy (SIMS)."

Jan 1, 2000

By Takafumi Kondo, Satoshi Yamashita, Noboru Masuko

"Aqueous oxidation of phosphite ions to phosphate ions with dissolved oxygen was examined at 80° C and pH 4.5 mainly from the stichiometric point of view. Dissolved oxygen alone can not oxidize sodilim phosphite in aqueous solution, but when sulfur dioxide is coexistent, cooperative oxidation for both sulfite and phosphite can occur in aqueous solution. Sulfur dioxide itself is well known as a reducing agent, but it also reacts as an oxidation-promoting agent for other species under a certain condition. So sulfur dioxide is· a promising cheap reagent for waste phosphite processing.IntroductionIn a liquid-phase oxidation reaction using the dissolved oxygen gas, the eoexistence of a copper salt is required generally. Recently, it was reported that the oxidation reaction progressed by using mixed gas of sulfur dioxide and oxygen without the copper catalysis, and the attention has been collected1·3). The present authors also noticed the phenomenon since the early time and have been studying on the reaction mechanism of sulfur dioxide in liquid phase oxidation 4l. It was found that; by using the SO2-O2 mixed gas, the oxidation of phosphite ions to phosphate ions proceeded efficiently in sulfuric acid solutions. In the present report, the applicability of SO2-O2 mixed gas as a cheap oxidizing agent to the industrial processing of the waste solution of electroless nickel· plating is investigated. It is well known that the sulfur oxide dissolved in aqueous solution is oxidized ·by the oxygen in the air to sulfuric acid according to the following equation"

Jan 1, 2000

By R. C. Ford

The advent of solvent extraction-electrowinning (SX-EW) technology for recovery of copper from low grade oxide ores has extended the operational lives of many historic mines in the western United States, and made many other orebodies economically viable worldwide. Many of these operations are mature and face closure within the next decade, depending on market conditions. Closure of a large copper heap leach operation has not been undertaken, and differs in some important chemical respects from closure of gold leach pads. Challenges for closure include prediction of solution chemistry and draindown characteristics, determining the benefit of cover placement in semi-arid climates and evaluation of solution management strategies once the economics of copper recovery are no longer favorable. This paper discusses issues pertinent to copper heap closure in semi-arid and arid climates, and strategies for their management.

Jan 1, 2000

The ever-increasing power (and decreasing cost) of computers has opened up substantial oppor¬tunities for 'Vision'-based systems in both on-line and off-line control. This paper reviews image analysis applications in use at the Julius Kruttschnitt Mineral Research Centre (JKMRC) for: •blast and mill feed size monitoring; •AG/SAG mill model-based control; •mineral liberation; and •froth flotation control. The SPLIT™ image analysis system is being used to estimate muck pile and ROM feed sizings. AG/SAG mill feed sizing is being used in a dynamic model for mill control. A new generation mineral liberation analyzer has been developed with Philips Electron Optics. The Philips-JKMRC mineral liberation analyzer offers a substantial improvement in resolution and speed over previous developments. While on-line liberation control continues to be something of a pipe dream, measuring liberation "one shift behind" is now feasible. A robust instrument has been developed to measure flotation froth bubble size and velocity. The instrument also derives a parameter that allows different froth textures to be distinguished. The instrument has been used for on-line control in coal and sulfide flotation. For coal froth, an online ash estimate has been achieved at one site and is being tested at other sites. Overall, image analysis is finding many applications in mineral processing and control.

Jan 1, 2000

By Keizo Uematsu, Satoshi Tanaka, Nozomu Uchida, Anze Shui, Joaquin Lira, Cyril Lavelle, Midori Saito, Thierry Poirier

"Dispersed and flocculated alumina (non-spherical particles) slurries were prepared by pH controlling with HCL Spray-drying of these resulted in dimpled granules with a smooth surface and high density, and spherical granules with rough surface and low-density, respectively. Detailed characterization on granules and their compacts includes: SEM observation, density measuring (mercury porosimetry and Archimedes's Principle) and liquid immersion optical microscopy. Compaction of these granules originated a larger particles rearrangement in the samples made with the spherical granules than with the dimpled granules. This was verified through the orientation of alumina particles, which was pronounced in the compact made with the former granules.IntroductionOn immersing a ceramic powder in water, the surface usually acquires a charge by interaction with ionic species in solution. The charge is affected by pH and the electrolyte concentration of the water. 1 The dispersion in a slurry is achieved through the interaction of charges on the particle surface with the media. In the ceramic processing, especially in the process of casting, the dispersion of slurry has been one of the most important topics studied for many years. Recently the attention is paid on its role in the pressing. The granule characteristics are governed by the dispersion state of slurry. Takahashi et al2 , Tsubaki et al3 and Walker et al4 showed that the granules from dispersed slurry were dimpled and of high density, while granules from flocculated slurry were spherical and of low density. This variation in the granules characteristics should have a marked effect on the structure of compact.This paper presents the influence of the dispersion state of alumina slurry on the granules characteristics and also on the internal structure of compacts. Different dispersion states were elaborated by adjusting pH of the slurry. In this method, the particles are dispersed or flocculated only by the effect of surface charging, and thus some secondary effect such as the steric hindrance from an electrolyte dispersant is avoided. The characteristics of granules and compacts are examined with SEM, density measurements by mercury porosimetry and by Archimedes's Principle and liquid immersion optical microscopy. This novel microscopy provides various important information on packing structure of particles, such as their orientation. 5"

Jan 1, 2000

By S. Veeramasuneni, C. D. Dunbar

The rate of hydration influences many important physical properties of gypsum. Previous research examined the rate of gypsum hydration and related this to compressive strength and microstructure development using BET specific surface area analysis. The analysis of gypsum porosity in combination with BET surface area and rate of hydration remains to be done. In the present study, mesoporosity is analyzed using the numerical method of Barrett, Joyner and Halenda (BJH) to gain a greater understanding of gypsum hydration and microstructure development. The rate of hydration has a significant effect on mesoporosity of the gypsum matrix. The results reveal the effect of mesoporosity and hydration rate on some macro physical properties of gypsum.

Jan 1, 2000

By P. R. Desam, J. D. Miller, A. Datta

The flow behavior of bubble-particle aggregates in separation tanks is important for many flotation systems, particularly for wastewater treatment. These aggregates can be considered as the dispersed phase in a continuous liquid phase of water and the flow characteristics determine the efficiency of the bubble separation process. In this work, a general methodology for the computational fluid dynamics (CFD) simulation of a bubble separation tank is described. This system is analyzed by Eulerian-Lagrangian approach. The momentum transfer from the dispersed phase to the continuous phase is quantified using the Particle-Source-In Cell (PSI-Cell) method. With CFD simulations, the effectiveness of different tank design parameters are evaluated in terms of the extent of bubble separation.

Jan 1, 2000

Jan 1, 2000

By Nicholas Macrae Steven

Abstract - The Shaba-type Luamata Cu-Co(-Ni) deposit (11°50_S, 24°28_E) is located in a tectonic slice of Katangan Roan Supergroup (Mines Group) sedimentary rocks, surrounded by younger Kundelungu Supergroup lithologies in the external fold and thrust belt of the Lufilian Arc. Luamata is a classic central African copper clearing in dense woodland, visible as a tonal botanical anomaly on Landsat imagery. Supergene Cu-Co mineralization (especially malachite and subordinate chalcocite, digenite, covellite, and copper and cobalt oxides) and, probably hypogene, bornite, and chalcopyrite are hosted by altered, but essentially unmetamorphosed, moderately dipping, dolostones and dolomitic shales. Alteration products include talcose dolomite, sericite rocks and intense silicification and brecciation. Friable yellow shale is best mineralized with cobalt (up to 0.43 wt%), whereas, highest copper grades occur in brecciated, silicified shale (up to 13.5 wt% CuO). Soil copper and cobalt contents are up to 2.2 and 0.6 wt%, respectively. A newly identified nickel zone (where soil contents exceed 0.1 wt% Ni) fringes the Cu-Co deposit. Polymictic, matrix-supported breccias with a calcareous matrix that underlie the Cu-Co deposit are interpreted to be fluidization breccias related to thrust tectonics and the emplacement of the Mines Group slice. Although small compared to the Kolwezi district Shaba deposits in the Democratic Republic of the Congo, Luamata exhibits all the classic features of an ore deposit type (with low calcite contents), whose high metal concentrations could potentially be very profitably exploited by low-cost opencast mining and hydrometallurgical recovery methods.

Jan 1, 2000

By S. S. Peng, C. T. Holland

Mountain Top Removal (MTR) mining started in West Virginia nearly thirty years ago. This surface mining method can extract multiple coal seams as thin as a few inches thick with total recovery and minimum rock dilution in very steep mountainous terrain. It is highly efficient even if coal seams are in close proximity and small in aerial extent. Consequently, MTR has been widely used in the Central Appalachian Coalfield (mainly Kentucky, Tennessee, Virginia and West Virginia) for the past thirty years with great success. In that respect, there has been no demand for research and little scientific research has been performed to investigate its impacts on the surroundings in the history of MTR mining. However, in the past two years the debate over the MTR mining has grown quickly and in times become very intensely. This paper describes chronologically the issues raised by various parties, legal actions, its impacts on mining permit application and research projects developed to address the issues.

Jan 1, 2000

By T. G. Paradis, C. A. Mohns

"This paper summarizes the Wren CAT (Clarifier and Accelerated Thickener) deep bed thickener operation at the EKATITM Diamond Mine in Canada’s Northwest Territories. EKATITMs’ thickener project is presented in terms of initial design considerations and present day operating practices. A circuit description summarizes process equipment, reagent systems, and typical process conditions, and details of Wren CAT operating principles are provided. Operating strategies are discussed, with emphasis on process instrumentation and control and operating challenges.INTRODUCTIONThe EKATITM diamond mine, operated by BHP Diamonds, Inc., is located in the Northwest Territories near Lac De Gras, approximately 300 km NNE of Yellowknife, NT. 9000 dry metric tonnes of diamond-bearing kimberlite ore are processed daily. Processing operations commenced in October, 1998.The EKATITM process plant flowsheet features typical steps in diamond recovery plant design. Figure 1 shows the general plant flowsheet. Size reduction and feed preparation are accomplished by crushing, scrubbing, and high pressure grinding rolls (HPGR) through closed-circuit classification with vibratory screens. Heavy medium separation (HMS) is used as the initial stage of heavy mineral concentration. Secondary concentration is accomplished in the recovery plant by attrition milling; wet, high-intensity magnetic separation (both wet and dry); and X-ray sorting.The present budget throughput rate is 9000 dry tonnes per day. This will be increased to 18,000 tonnes during the first ten years of operation. Unlike most kimberlite treatment facilities, which process material from a single ore body, EKATITM’s process plant was designed to accommodate ore from five different kimberlite pipes, each with its own treatment characteristics.All processing, except for primary crushing, is carried out in a temperature-controlled environment in the main process plant building."

Jan 1, 2000