Search Documents

By Stanley J. Michalek

Good planning is critical to operating a safe and efficient mining operation. As the shallow coal scams become depleted, attention turns toward deeper mineable seams or remnant coal reserves. It is becoming more common to place a mine in a scam that is below or adjacent to existing mine workings. Significant research has been conducted regarding the ground control issues of multiple scam mining. However, safety aspects of the operation may not be fully considered. Safety issues include working below or adjacent to a flooded mine and controlling gas Communication between the active mine and the nearby mine. This paper will discuss the safety issues a mine operator should consider when working under or adjacent to mines that may be flooded with water.

Jan 1, 2000

By Ron L. Schmiermund

The Ferris-Haggarty underground mine was abandoned circa 1910, and portal discharge has since resulted in degradation of a trout fishery in the receiving waters of Haggarty Creek. Although tunnel discharge varies dramatically in volume throughout the year due to infiltration of snowmelt, compositionally it is a nearly constant low-TDS, pH-neutral, low-sulfate, copper-silicate dominated water. Between infiltration events, components of ARD accumulate in unsaturated, oxygenated environments within upper workings and are delivered to the main haulage level by the subsequent annual snowmelt flush. Mixing with non-ARD mine waters results in neutralization, dilution, and precipitation of amorphous copper carbonate and silicate phases. These mechanisms, combined with variations in the water balance, control the composition of the portal discharge. Understanding the chemical and hydrologic control mechanisms was critical to the design of a passive treatment system to decrease effluent copper concentrations.

Jan 1, 2000

By S. Mason

Many organizations are realizing that continual improvement in health and safety relies on addressing the potential for various forms of human error. Of these, rule violations are often the most frequent form associated with accidents. These occur when an individual (or individuals) deliberately contravenes established and known safety rules. They have been associated with up to 90% of the accidents and other incidents in some industries, and yet they rarely receive the systematic attention they deserve in the promotion of safety. This paper presents underlying motives that cause violations. These can vary significantly from mine to mine and from job to job. Managers need some measure of the attitudes of the violators to determine the underlying motives behind the violations if they are to determine effective strategies for promoting safe behavior. Questionnaires form the starting point to address attitudes and the motives behind rule violations. The choice of the most suitable questionnaire, how- ever, will vary from organization to organization. Guidelines on the choice of questionnaire are offered.

Jan 1, 2000

By David R. Hanson

Seismic tomographic imaging, based on the same principles as a medical CAT Scan (Computer-Aided-Tomography). has been used for many years in the oil industry for large-scale subsurface stratigraphic characterization. and has most recently been applied to various structure- and stress-related problems in the coal industry. New developments in signal processing have greatly enhanced the speed, resolution, and range of applications of topographic imaging in underground settings, and recent innovations in data acquisition hardware have further increased data reliability and repeatability. Whereas past structure mapping applications relied on Seismic velocity and/or attenuation tomopraphy within an enclosed seismic source gram receiver array, recent developments in "True Reflective Tomography- (TRT TM) have expanded the application of this technology considerably. For example, in-seam TRT TM seismic reflection tray now he used to image structure, and/or old workings from one general location in the mine face areas of mains and panel developments) well ahead of planned developments largely eliminating the need to probe-hole drill on regular intervals. This new reflective technology bas also been combined with traditional cross-hole seismic tomography-providing a comprehensive, powerful tool for velocity attenuation. and reflective imagine utilizing the same source/receiver array data sets (borehole-to-borehole. borehole-to-entry and entry-to-entry). These new developments in data acquisition and image processing have greatly expanded the variety of applications for tomographic site characterization allowing the mine operator considerable flexibility to cost-effectively characterize previously inaccessible areas of the property. This paper presents examples of 2-D and 3-D .seismic topographic imaging applied to (1) the location of old works in Appalachian room-and-pillar operations and (2) the identification of anomalous zones ahead of mining/tunneling developments these applications demonstrate the state-of-the-art in seismic ground imaging using velocity, attenuation. aril reflection techniques land combinations thereon, and further illustrate the flexibility of data acquisition from a variety of tinning arid tunneling settings. Recent examples are presented from projects in the United States and Europe.

Jan 1, 2000

By G. A. Irons, D. Guo, D. Angheiina

To produce low-carbon (<30 ppm) steel in the tank degassing process, a ladle of steel with an oxidizing slag is placed in a vacuum tank equipped with bottom bubbling. The kinetics of this process are slow compared to the more prevalent RH degassing process, providing the impetus for the present work. There are several aspects to this work: water models of the fluid flow in the ladle; simulation of the decarburization (CO evolution) with C02 desorption in water; pilot-plant (60 kg) studies of the decarburization kinetics; mathematical modelling of the fluid flow in the ladle; mathematical models for each of the kinetic sites (plume, top slag and auto-nucleation); and full-scale trials. The results show that during the refining cycle the contribution from each reaction site changes, suggesting avenues for reducing cycling time and final carbon contents.

Jan 1, 2000

By J. Fogarty, J. Sofra

The mobile telecommunications sector is one of the fastest growing industries worldwide. However, increasingly stringent environmental regulations are placing pressure on manufacturers to accept responsibility for end of life products. The companies are therefore exploring avenues to recover the valuable components contained within the mobile telecommunications devices thus reducing the quantities of toxic components going to landfill. Batteries used to power the devices, are typically based on either nickel-cadmium, nickel metal hydride, or lithium ion cells. They contain toxic metals including nickel, cadmium, lithium, potassium, lead, and cobalt in a complicated arrangement of battery cells surrounded by a metals then plastic casing. The Ausmelt Catalytic Waste Converter (CWC) for waste treatment and recycling is well suited to processing all three mobile phone battery types for the recovery of valuable metals in marketable products that can be recycled to industry without turning out harmful levels of toxic emissions. Ausmelt recently demonstrated the capabilities of its CWC by continuously processing 4.5 tonnes of nickel-cadmium batteries. Using Ausmelt's pilot plant facility in Australia, the nickel-cadmium batteries were processed to produce a nickel iron sulphide (matte), a cadmium fume and a final slag which satisfied CS toxicity leach test criteria and was safe f<~r disposal to landfill. This paper explores the commercial development of the Ausmelt CWC for treating each of the three battery types in light of (a) the outcomes of the recent demonstration, and (b) the current and expected future availability of batteries for processing.

Jan 1, 2000

By Takayuki Watanabe, Yoshiki Shimizu, Yusuke Moriyoshi

"B-C-N nanotubes prepared by a flush evaporation method using a de arc plasma were mainly characterized by transmission electron microscopy (TEM) and electron energy· loss spectroscopy (EELS). The nanotubes obtained· were divided into three types such as carbon boron nitride and carbon or carbon nanotubes surrounded with boron nitride nanotubes. These types of nanotubes were obtained at higher temperatures than about 3000 K, however, these were not formed at lower temperatures than about 3000K. On the other hand, 11anocapsules were· formed at all the experimental temperatures and nanocapsules with a homogeneous phase were obtained at lower temperatures than about 3000 K. The effect of additives on the formation of B-C-N nanotubes was not clear. Based on these experimental data depending on temperatures and corresponding microstructures, the formation mechanisms of both nanotubes and nanocapsules were briefly .discussed 1 Introduction As reported previously, nano tubes have unique electrical properties1, 3) The preparations of nallotupes have been usually carried out by flush evaporation methods using either a de arc plasma or a laser4 -5) By these methods the reaction rate is so rarid that we have no data of intermediate products between initial raw materials and. final products of nanotubes 6-9). So, the formation mechanisms of nanotubes have been mainly speculated only from the microstructures of resultant nanoiubes. In order to have more reliable formation mechanisms, it is particularly important to have the information of intermediate products at the corresponding temperatures. From the viewpoints, we have studied about the effects of temperatures on the preparation of nanolubes. Here we report mi firstly some problems on the preparation of B-C-N nanotubes 10), secondly the effects of temperatures on the preparation of B-C-N nanotubes, and finally the formation mechanisms of nanotubes."

Jan 1, 2000

By Hideki Yamamoto, Shigeno Matsumoto, Junji Shibata

"Some fundamental studies were carried out in order to produce composite powders comprising of two or three metal oxides ~y using liquid-liquid extraction and to develop the control technology of the particle size. The combination of samarium and cobalt was selected as the two component composite powders. Both stripping and crystallization occurred at the same time by emulsifying the organic phase loading the two metals extracted with Versatic Acid 10 and the aqueous solution containing oxalic acid. The effect of aqueous pH, oxalic acid concentration and agitation speed was examined on some properties such as crystallization percent, particle size and shape of each metal oxide powders obtained in this process. The analysis by using EDX showed that the two metal oxides were distributed uniformly.IntroductionComposite metal and metal oxide powders with high purity are indispensable as industrial materials in the fields of electrical engineering, electronics and metallurgy. It is difficult to mix metal powders or metal oxide powders uniformly for the production of alloy powders. If insoluble metal salts are allowed to collect as crystallization products in the crystallization-stripping process, the conventional melting and crushing process can be avoided. After mixing of the organic phase containing metals in fixed composition, fine metal and metal oxide powders of alloy composition are produced by using a crystallization-stripping method. Versatic Acid 10 and D2EHPA, both acidic extractants, were chosen in this experiment, and the metal oxide powders were produced by using oxalic acid as a crystallization reagent. Mixed metal oxalates containing samarium and cobalt were precipitated from the mixed organic phase containing these metals. Furthermore, the physical properties of the powders, such as particle size, shape and thermal decomposition, were measured in order to evaluate them for industrial purposes."

Jan 1, 2000

By G. Orhan, C. Arslan

The possibility of producing metallic chromium from Cr2O3 via the aluminothermic route, with no external energy supply, was the subject of this laboratory-scale research. The experimental study focused on investigating the individual effects and quantitative optimization of the charge contents, i.e., the additions of CrO3, Al powder and CaO (or BaO). The highest chromium recovery of 98% was attained with the additions of 12% CrO3 and 1.2 times the stoichiometrically required amount of Al powder. The optimum CaO addition giving the highest chromium recovery was found when the CaO/Al weight ratio in the charge was equal to 0.3. When BaO was used, however, 95% Cr extraction efficiency was obtained at a BaO/Al weight ratio of 0.15.

Jan 1, 2000

By E. A. Werner, W. Liebfahrt, J. Blaha

"The influence of the composition and the microstructure on the plane strain fracture toughness of five cold work tool steels all processed via the powder metallurgical route is investigated using 3-point bending specimens. The steels differ in composition and therefore possess different volume fractions of carbides. The amount, size and distribution of the carbides in the matrix are estimated by quantitative image analysis on a plane parallel to the fracture surface without discrimination of the carbide type, since the carbides are always much harder [1,2] than the matrix, irrespective of their composition. Due to the production of the steels via the powder metallurgical route almost all carbides are spherical in shape. The mechanical in-situ properties of the matrix are characterized by indentation tests performed with an ""UltraMicro"" -indenter in a scanning electron microscope.IntroductionCold work tool steels are used as tools in applications where excellent wear resistance and high hardness are required. Examples are cutting, woodworking, thread rolling, wire and deep drawing, cold extrusion and pressing of parts at process temperatures below 200°C. For such applications the steels must show an optimum combination of hardness, wear resistance and toughness while offering good machinability. Hardness and wear resistance are controlled by the amount of carbon and carbide forming elements such as molybdenum, tungsten, vanadium, chromium and niobium. These elements are present in the MC-, M6C and M7C3-carbides and are also responsible for the precepitation of secondary carbides during tempering. In this report attention is paid to the influence of the primary carbides only, while the very small ~~nm) secondary carbides will be treated as constituent of the homogeneous matrix. Increasing the amount of carbides (alloying elements) usually results in a decrease of the material's toughness which is caused by the presence of clusters and/or bands of carbides. To achieve an optimum combination of hardness, wear resistance and toughness many of the today's cold work tool steels are processed via the powder metallurgical (PM) route, which helps to prevent non-uniform element/carbide distribution because of the rapid solidification of the powders used. The resulting microstructure of the tool steel then consists of a tough matrix with uniformly distributed hard carbides· of globular shape. This shape of the carbides is also desirable instead of blocky carbides present in non-PM tool steels, since they improve the machinability of the steel. An additional advantage of PM-steels lies in the possibility to produce near net shaped tools thus lowering the costs of machining."

Jan 1, 2000

By S. R. S. Sastri, D. K. Senguta, S. K. Bhaumik, G. V. Rao

The amenability of a calcite-bearing ore to the reduction of silica to below 0.2% by physical beneficiation was studied. The objective was to use the ore as a raw material for seawater magnesia production. The ore contains complex gangue minerals such as diopside, forsterite, phlogopite, clinohumite, graphite and quartz. These contribute to around 25% acid insolubles with 6% SiO2. Reverse-flotation studies using various cationic collectors with tannin as a depressant indicated the possibility of reducing the acid insolubles to around 5%. Direct flotation of calcite with anionic sodium oleate in the presence of sodium silicate and lactic acid as a depressant indicated the possibility of reducing the acid insolubles to below 3% and the SiO2 to from 0.2% to 0.3%. Lactic acid was found to be an effective depressant of the complex gangue minerals in the ore.

Jan 1, 2000

By J. Paraszczak

High productivity of the equipment employed is one of the key factors in reducing production cost in mining. One of the best ways to achieve it is an increase in availability. In order to identify the most adverse factors affecting it, reliability and maintainability analysis ought to be done. If its results are to be conclusive, a sufficient amount of credible and consistent data is indispensable. Following the experience from field studies done in underground mines, this paper discusses the current status of failure and maintenance reporting, as well as problems encountered. It exposes the importance of adequate data collection on failures and downtime as well as it reviews the benefits of analysis based on such material. The question of benchmarking with regards to mining equipment performance is also addressed. The paper concludes with some recommendations on data collection and processing, as well as stresses the need to standardize the most important reliability/ maintenance notions throughout the mining industry and to conceive appropriate performance measures.

Jan 1, 2000

By R Lewis

Drill hole magnetometric resistivity (DHMMR) is a relatively recent addition to the explorationistsÆ suite of techniques for finding further resources in the vicinity of a drill hole. The method relies on gathering of an applied current into zones which are less resistive than the country rocks and it was first applied to exploration programs looking for weakly conductive sulphides, such as, for example, carbonate-hosted zinc deposits. More recently, it has been applied to a wider range of deposit styles, including highly conductive nickel sulphides. It has been found that the technique is capable of not only detecting mineralisation not seen by conventional electromagnetic (EM) techniques, but it can detect at a greater distance. Also, whilst EM is superior at defining tabular-shaped conductors, DHMMR may be more effective at finding cigar shaped sulphides. This paper presents a number of examples illustrating these findings.

Jan 1, 2000

By T. Asahina, M. Nakamura, M. Mabuchi, I. Shigematsu, M. Nakanishi, G. Yamauchi

"Commercial stainless steels (SUS304L and SUS430) were subjected to equal channel angular extrusion (ECAE) at room temperature to a total strain of 2.3 to 9.2. For each type of stainless steel, it was shown that the sample processed by ECAE showed higher room temperature strength than the as-quenched sample. This is probably due to the heavily worked structure. On the other hand, both strength and elongation of the ECAE processed SUS430 were increased by annealing at 773K. It is likely that higher strength is attributed to both the heavily worked structure and fine substructures. It is also likely that higher elongation is attributed to the fine substructures. It is concluded that ECAE is available for improving the room temperature strength of commercial stainless steels.INTRODUCTIONEqual channel angular extrusion ( ECAE ) is a technique that provides the repetitive deformation and allows to high intensity of deformation. With this procedure, a sample is pressed through a channel that has an equal cross section but bent at an angle of ?> [1-2]. Shear strain is introduced when a sample passes through the bending point of the channel. Repetitive processing is feasible because the cross-sectional dimension of a sample has no change during processing. To date, many reports have described that ECAE is available for the fabrication of fine-grained materials [3-14]. On the other hand, an ECAE processed sample can achieve high intensity of deformation through repetitive deformation. According to the equation given by Segal [ 2 ], a strain of about 1 is introduced in each pass through die if the angle ? is 90 deg.It is well known that high tensile strength can be achieved in metallic materials through work hardening [15]. It is also known that metallic materials with fine grain size show high strength [16]. Hence, it is expected that ECAE is available for strengthening method in metallic materials. In the present paper, we will report the mechanical properties of stainless steels processed by ECAE. As samples, SUS304L austenite stainless steel and SUS430 ferritic stainless steel were chosen. Each alloy has a single-phase structure (fee or bee) and shows no phase transformation, so that transformation strengthening cannot be applied. Hence, a heavy cold work such as ECAE may be effective for strengthening of this stainless steel. Annealing was conducted for the ECAE processed SUS430 to vary its microstructure. Then, the effect of annealing on the strength of the ECAE processed SUS430 was also investigated."

Jan 1, 2000

By Yoshifumi Abe, Akinori Toraiwa

"Nippon Mining & Metals started a new copper anode slime treatment plant that processes slimes in a chloride media. The basic plan of the process was proposed by Mr. James E. Hoffmann and Nippon Mining & Metals modified and advanced to produce precious metals in acceptable qualities for the company. The process has a wet chlorination stage of decopperized slimes, a solvent extraction and a reduction stages of gold, a silver chloride reduction stage and separative reduction stage of its gold extraction raffinate. The new plant of this process started in 1997 and has been operated in good condition.IntroductionThe old anode slime treatment plant of Nippon Mining & Metals, located in it's Hitachi Refinery, processed anode slimes through a combination of pyrometarllurgical processing and electrorefining. There was a need to plan a future of the plant because the maintenance cost increased year by year and a new selenium registration was going to be applied to the plant. Some plans were discussed and the result was that the process proposed by Mr. Hoffmann was superior among them.Nippon Mining & Metals started 'to examine the process and the experimental result showed that the process had an ability to be its new process but further research should be necessary to produce precious metals in acceptable qualities. The final process flow has some modified and additional stages to be suitable for its requirement. Silver processing stage is quite changed. Gold extraction stage has a new step to polish gold loading DBC. Gold extraction raffinate treatment stage is advanced to be able to recover precious metals, selenium and tellurium, separately. Aeration under atmospheric pressure is employed in decopperizing stage.The basic design of the new plant started in 1995 and finished in 1997. The construction of the new plant began in April 1997 and finished in October. The plant has been operating well after the four months test operation."

Jan 1, 2000

By Paul Worsey, Attila Szucs, Mark F. C. Schmidt

The use of water stemming with small explosive charges has been successfully developed at the University of Missouri-Rolla. Further study has been started to explore additional applications and uses for water stemming. Work has been focused in the areas of rock excavation and perimeter blasting techniques. This ongoing work is being conducted internally as graduate and undergraduate level research. A paper describing the general technique for use with boulder fragmentation was published in last year’s proceedings. The excavation work took place in the form of both small bench and trench shots while pre-split and trim shots comprised the perimeter-blasting portion. The excavation work was located in both the Roubidoux sandstone formation and the Jefferson City dolomite formation. Hole diameters ranged in size from 1.5” to 3” diameter and powder factors ranged from l/l 0 to l/3 of the conventional charge weight. The water was used to both couple the explosive charge with the surrounding borehole, as well as stemming. No other stemming material or products were used. The method of using water stemming in perimeter blasting was found to work well. However, when used for excavation purposes, adequate rock movement was not obtained. The rock was often split, but not fragmented. The airblast was surprisingly low, but the ground vibrations were excessive. This is not the case with trim shots, and therefore this method appears ideal for splitting purposes, especially in areas where people do not like to stem the tops of the holes, and where airblast and vibrations are of concern. Water coupling dramatically increases splitting and fracturing. However, fragmentation is not only fracturing but also the movement and swelling of the material. As the charge weights are reduced with this method, sufficient gas volume is not created to cause this necessary movement and swell, which is critical in rock excavation. This explains why its successful application was limited to perimeter blasting applications.

Jan 1, 2000

By Takamasa Ishigaki, Gervais Soucy, Mohamed Rahmane

"The induction plasma jets employed for the in-flight nitridation of molybdenum disilicide (MoSi2) powders were investigated in terms of their flow characteristics. The present study shows the effect of the operating parameters of the plasma torch, as used for this process, on the plasma jet properties. The enthalpy probe techniques, along with mass spectrometry, were employed for the measurement of the jet temperature, velocity and concentration fields. The measured values were compared to the results of a numerical simulation performed on the plasma flowing inside the torch-reactor system. The process operating conditions studied were the plasma plate power, chamber pressure and sheath gas composition. The optimal conditions for effecting the nitridation process using thermal plasma are obtained at moderate plasma plate power, at around atmospheric pressure and by using a mixture of argon and nitrogen as the plasma torch sheath gas.IntroductionMolybdenum disilicide (MoSi2) based composites are considered to be one of the most promising candidates for high temperature structural material applications [!], especially because of their high melting points, good oxidation resistance and relatively low cost. However, the wide application of these composite materials is still limited by some factors such as their brittleness at room temperature and lower strength at high temperature (> 1500 K). To overcome such limitations, a number of researchers [2-4] have earlier studied various kinds of reinforcements for MoSi2, e.g. oxides, silicides and nitrides. More recently, Fan and coworkers [5-9] have demonstrated the possibility of in-flight nitridation and carburization of MoSi2, using a thermal plasma process. This work has confirmed the plasma synthesis route as one of the most promising methods for creating an in-situ second phase structure. Properties of the plasma flow, such as its temperature, flow velocity and composition, are of crucial importance for the nitridation of MoSi2 powders during their flight in the plasma. Therefore, the optimization of such a process involving plasma· generated reactive species necessitates a thorough understanding of the plasma flow characteristics."

Jan 1, 2000

By Anders Lagerkvist, Agne Rustan, Tommy Edeskar

Landfills containing house hold waste produces methane gas during its decomposition. This gas can be recovered and used for heating purposes or as fuel for vehicles. Gas drainage pipes are installed in the landfill and connected to a central suction point. Methane gas is produced over several years until the slots in the drainage pipes are clogged by black mud. And the bottom of the vertical drainage pipe are filled with mud and water. The hypothesis tested in this paper is if blasting in the drainage pipes could activate the production and flow of methane. In the first part of the paper we have studied what maximum linear charge concentration could be used in different size of PE-pipes place vertical on surface and surrounded by air. The results show that the maximum linear charge concentration for single blasts varied between 5-10 g/m, depending on the diameter of the pipe (90, 100 and 160 mm). Maximum charge concentration for the repeated blast varied between 2-5 g/m. In the second part of the paper we study what maximum linear charge concentration could be used in situ for full scale blasting tests in a special prepared test area which later on was dug out after the blastings. Up to 40 g/m could be used without damaging the top of the 160 mm diameter pipes. The increase in methane flow was so low so it could not be measured c4.5 m3/h. The conclusion therefore is that the stimulation of methane flow by explosives is not enough.

Jan 1, 2000

By Lewis Stansfield

A rotary displacement method was used to install permanent steel casings for bored piles through an asbestos tip. This method was chosen in preference to alternative driven systems because it was quieter and more versatile if obstructions were encountered. New equipment was designed and made specifically for the project, and stringent health and safety regulations had to be observed.

Jan 1, 2000

By S. S. Chabot, S. E. James

A recent survey of major steel companies worldwide revealed the importance of recycling zinc units from electric arc furnace (EAF) dust, mill scale, blast furnace dust and other zinc containing streams within the steel industry. Many processes have been developed and installed in response to this challenge. The most successful approach involves the production of a crude zinc oxide and its sale to primary zinc producers to recover the metal values. The problem with this process is the high concentration of halides in the crude oxide. This type of material cannot be processed directly in an electrolytic zinc plant because of the corrosion problems it will cause in electrolysis. In 1999, Big River Zinc installed a zinc oxide receiving and washing plant to minimize the impact of halides in its electrolysis circuit. A description of the washing plant and the initial operating results are presented in this paper.

Jan 1, 2000