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By C. A. Young, R. G. Robins, E. J. Dahlgren

The formation of copper thio-complexes in sulfide solutions has been recognized for many years and the measured solubilities of certain copper sulfide minerals attributed to these complexes. Attempts to model this system have proposed either copper(I) or copper(II) thio-complexes, and these have been incorporated into computer programs for generating stability diagrams for the copper-sulfur-water system in order to delineate the region where the reductive dissolution of copper sulfide minerals is likely. In this paper it is proposed that the dissolution of copper from both ore bodies and sulfide tailings can be explained by the formation of the cupro-thio-complexes under anaerobic conditions. Stability diagrams are presented to depict the region and extent of the solubility.

Jan 1, 2001

By A Van Kersen, J Hodson

Waihi Gold Mining Co Ltd [WGM], operated by Normandy Mining, has been internationally recognised for its achievements in environmental management at the Martha Mine at Waihi. In a proactive approach to dealing with community concerns regarding blast vibrations on the North Wall cutback, trials were performed using the Cardox System [Cardox], to determine feasibility of achieving economic fragmentation of andesite overburden whilst bettering management levels of 5 mm/s peak particle velocity. Cardox is a non-explosive pressure breaking system which uses high pressure CO2, Results against conventional Ammonium Nitrate/Fuel Oil [ANFO] using a variety of delays showed that conventional blasting techniques could produce marginal fragmentation within the management levels with occasional excursions, whereas Cardox produced the required fragmentation while not registering on the vibration monitoring equipment. Fragmentation to enable normal excavation by a Hitachi EXII00 hydraulic excavator was achieved with a yield of 16m3 per round. The trails indicated that fragmentation with Cardox at the yields required of over 18m3 per round was possible with further product development. The trial demonstrated that non-explosive pressure breaking is feasible and its application warranted where environmental concerns affect the cost-benefit economics of production blasting in sensitive areas.

Jan 1, 2001

By T. Dlokweni, A. Z. Toper, A. P. Squelch, R. G. Gürtunca

A collaborative research programme called 'DEEPMINE' was established in 1998 to investigate and research the problems of mining below three and five kilometres depths. Backfill is considered as an important support strategy to alleviate rockburst and rockfall problems in current depths and it will even become a more crucial mining strategy at ultra-deep level mining. In this paper, the evaluation and the application of the current backfill design criteria to the ultra-deep level mining environment are studied and a new backfill design criteria is proposed. The new criteria suggests that backfill should still be placed 60 - 70% of the area mined with a maximum fill to face distance of three metres. Furthermore, the vertical stress generated in backfill should be between 2 - 3 MPa at maximum 25 metres from the face at a corresponding strain value of maximum 10%.

Jan 1, 2001

By Yoshikazu Hirosaki

How big or small is the Japanese explosive market? Who are the major explosive customers? Is there any big construction project in which a large amount of explosives is expected? What is the future of the explosives industry in Japan? Is it true that there are no ANFO trucks? What is the licensing system for blasters? Is there any education system for blasters?

Jan 1, 2001

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Jan 1, 2001

By Thomas Kovalchuk, Kenneth Eltschlager, William Shuss

In April of 2000, two adults and their newborn infant, were poisoned by carbon monoxide in their home and received medical treatment at a Pennsylvania hospital. Carboxyhemoglobin levels were; child - 3 1%, father - 28Oh, and mother - 17%. Initially the furnace was blamed but after further review, blasting at a nearby coal mine was determined to be the source. All other sources of carbon monoxide were ruled out. The blasting was about 400 feet from the house. The conditions that led to the migration of gas include: the blasts were highly confined, the geologic structure contained fractures that served as conduits for the carbon monoxide to reach a hand-dug well outside the house, and the well was atmospherically connected to the basement floor drains.

Jan 1, 2001

By John Frostiak, Don Welch, David Landriault

The use of paste technology for underground cemented backfill is widely accepted in the mining industry today as a potentially cost effective alternative to cemented rock and hydraulic slurry fill. While paste backfill is not the appropriate backfilling method for all mines, there are presently 23 operating tailings paste backfill plants throughout the world. This new technology has gained increasing acceptance as a backfill method over the last decade and its use is now expanding into the surface disposal of tailings using the stacked, thickened tailings disposal concept. Over the next 18 months there will be ten new paste plants commissioned in the world. Five of these ten plants will be used exclusively for surface tailings disposal or a combination of surface disposal and underground backfill production. The thickened tailings disposal concept, developed by Dr. Eli Robinsky in the early 1970's, has been in use for decades at several mine sites throughout the world (Kidd Creek Mine site in Northern Ontario), but always utilizing non segregating high density tailings slurry central discharge, stacked tailings placement. With the use of a higher solids content paste, the typical 2-degree beach angle can be increased to ten degrees or more with no runoff water and minimal shrinkage crack development through desiccation. This paper presents the design of the first mine to implement true surface paste disposal, Barrick Gold Corp's Bulyanhulu Mine in Tanzania. The paste system will be commissioned in the first quarter of 2001 allowing performance data to be collected to define the full potential of paste technology for surface tailings disposal.

Jan 1, 2001

By R. G. McLusky

This paper analyzes the opinion in Bragg v. Robertson, 72 F.Supp. 2d 642 (S.D. W.Va. 1999), a case which threatens the future of surface mining in West Virginia and which will almost certainly result in new policies or rules that will affect surface mining everywhere. This paper addresses: (1) the jurisdictional bases of the action which relies on the federal surface mining laws to enforce a state mining program; (2) settlement agreements reached in the case that threaten to alter federal policies beyond West Virginia borders; (3) a programmatic environmental impact statement on mountaintop mining being undertaken by the federal government; and (4) an opinion by the Court outlawing excess spoil disposal in intermittent and perennial streams.

Jan 1, 2001

By J. Drelich, J. Pletka

Lost foam casting patterns are foamed polystyrene shapes glued together into the shape of the part to be cast and are coated with a refractory material consisting of a mineral mixture and binders. Prior to casting, a significant number of the patterns are damaged and inevitably land-filled. In this study, a process is developed for the recovery of foamed polystyrene from the coating and glue contaminants. The process consists of shredding, impact comminution, size classification and density separation. It is successful in separating up to 97% of the contaminants, while recovering 95% of the polystyrene.

Jan 1, 2001

By John P. Hager

One possible approach for the recovery of mercury from acid plant blow-down sludge in smelters is the use of a vacuum retort reactor for the vaporization of the mercury with subsequent collection of metallic mercury in an attached condenser. An experimental study was undertaken to investigate the vaporization of mercury when present as a compound in the Hg-S-O and Hg-Se systems. A transpiration reactor was modified to operate under reduced pressure and with a continuous flow of inert sweep gas. A water-cooled cold finger was inserted into the exit end of the reactor to provide for the rapid quenching of the exit gases and the collection of the mercury. Rates of vaporization were measured at several temperatures for each compound and were generally found to be constant at a given temperature and reactor pressure. The results were used to determine the minimum operating temperature for 100% vaporization of the compound in 60 minutes. For Hg2SO4, HgSO4, and HgSO/2HgO the required temperatures. for a reactor pressure of 50 Torr. were determined to be 634°, 622°. and 603°C. respectively. For HgO, HgSe, and HgS the required temperatures were 557°. 451°. And 382°C. respectively. For HgS the rate of vaporization was also measured at a reactor pressure of 1 00 Torr. The rate of vaporization was found to be slower resulting in an increased vaporization temperature of 423°C. It was also determined that the mercury vapor present in the exit gas stream can back-react with the other gas species to a significant extent and can result in very little condensed metallic mercury. For the vaporization of both HgS and HgSe. the mercury vapor was found to have back-reacted to the extent that virtually none of the vaporized mercury was collected in metallic form. For the vaporization of Hg2S04? HgS04, and HgSO4*2HgO the amount of metallic mercury recovered varied from approximately 50% for HgS04*2HgO to approximately 10% for Hg2S04 and HgS04. Only for HgO was the recovered mercury in primarily elemental form. The application of the results to the operation of a vacuum retort and condenser system is discussed.

Jan 1, 2001

By Raj P. Singh

Lewatit TP207, a chelating resin with iminodiacetate functional group, is used for the purification of cobalt hexammine chloride solution for divalent cationic impurities (US Patent No. 5,154,757). The method is employed at commercial scale in OSRAM SYLVANIA Inc. cobalt chemical production since 1992. It is observed that after long use in the purification of cobalt hexammine chloride solution, a large number of resin beads tum black from their original beige color. The purpose of this paper was to characterize these black-colored resin beads for their ion exchange behavior. The resin sample used in this work was an exhausted production TP207 resin containing large number of black-colored beads. The results indicated that blackened resin beads can be regenerated to almost full capacity and' their ion exchange behavior for the purification of cobalt hexammine chloride solution was comparable to the new resin.

Jan 1, 2001

Deposits of the Reefton Goldfield, West Coast, New Zealand, are hosted on N-NE striking, upright folds of the Greenland Group. High-grade quartz lodes are hosted on axial planar shears, typically have short strike lengths, and form shoots that pitch steeply on the hosting shears. Deposits within the field area of a detailed structural study share these characteristics. Field mapping and microstructural analysis have demonstrated that the Greenland Group was affected by a multideformational sequence. Gold mineralisation is hosted on shears axial planar to the F2 folds, but occurred during a subsequent deformation event (D4). Deformation during D4 resulted from N-NE directed shortening, near parallel to the trend of the F2 folds. This event produced F4 kink folds that were accommodated by layer parallel slip on S2 parallel shears, gold mineralisation during D4 being confined to the dilational hinges of F4 kink folds. The semi-brittle nature of D4 allowed the formation of stockwork veining and disseminated mineralisation within the F4 hinge zones. Most deposits within the goldfield are similar to those within the field area, and are interpreted to have been mineralised during D4. The two largest known deposits within the goldfield, however, are distinct. The Blackwater Deposit, striking parallel to the hosting folds, has a combined strike length of 1 km. The Globe-Progress Deposit is hosted on an E-W striking discordant shear in which a brittle zone of disseminated mineralisation encompasses high-grade quartz lodes. The characteristics that distiguish the Globe and Blackwater deposits may be due to formation before and after D4 respectively. Detailed field mapping in the vicinity of known deposits throughout the goldfield will further refine the relationships between the F2 folds, later deformations and the localisation of ore deposits. Additional mapping may also help constrain the position, orientation and extent of additional orebodies.

Jan 1, 2001

By Mike Ounpuu

"Locked cycle testing has become more common practice in the last 10 years. Reasons vary from a desire to avoid pilot plant testing, demand for more variability testing within deposits, and perhaps most importantly, a request from the financial institutions who invariably finance many of the projects. Surprisingly, many people don’t understand locked cycle testing, analysis and balancing. This paper provides a brief overview of locked cycle testing, and then progresses into a more detailed discussion on the analysis and balancing of locked cycle test data. The paper endeavors to educate CMP personnel on how to determine if the test was good and if a reasonable metallurgical projection was made. The paper uses case studies to illustrate the key points.INTRODUCTIONA locked cycle test is a repetitive batch used to simulate a continuous circuit. The basic procedure has a complete batch test performed in the first cycle which is then followed by similar batch tests which have “intermediate” material from the previous cycle added to the appropriate location in the current cycle. These batch tests, or cycles, are continued in this iterative manner for an arbitrary number of cycles. The final products from each cycle, i.e. final concentrate and final tailings, are filtered and thus removed from further processing. At the end of the test, all the products, final and intermediate, are dried, weighed and subjected to chemical analysis. The test is balanced and a metallurgical projection is made.This description can be found in many of our classical textbooks for the mineral engineer 1, 2, 3,4. Unfortunately, none of these textbooks provide any discussion beyond the basic procedure. Often, they provide comments such as in Taggart’ where he states; “It is questionable whether in any case it approximates mill results any more closely than the standard batch test”. It is truly surprising that our classic textbooks promote that locked cycle tests are more art than science, and suggest that they can be of dubious value. None of the textbooks provide meaningful insight or discussion in how to assess:"

Jan 1, 2001

By Z. Xiao, A. R. Laplante

"The recovery of gold by gravity from grinding circuits differs from virtually all other gravity recovery approaches in that stage (or unit) recoveries are low, typically 1 to 5%, but overall recoveries are generally in the 25 to 60% range, because individual gold particles are presented many times to the primary recovery unit. Full-scale recovery is difficult to predict from benchscale tests. Further, maximizing metallurgical recovery is generally not the primary objective, because of the more efficient downstream recovery circuit (flotation or cyanidation). In this paper, a new concept, the gravity recovery effort, is presented to assist in the design and optimization of gold gravity circuits. It is defined as the product of the circulating load treated by the primary gravity unit, the recovery of this unit, and the gold room recovery. Predicted gold recovery is linked to the recovery effort, the size distribution of gravity recoverable gold (GRG), the dimensionless retention time in the mill and the partition curve of GRG. A case study of economic optimization of the gravity recovery effort is presented. INTRODUCTIONPredicting gold gravity recovery from grinding circuits has always been a hit-and-miss exercise. The problem can be traced to the highly variable gravity recoverable gold (GRG) content of ores, high GRG circulating load, fraction of the circulating load treated, and performance of primary gravity recovery and gold room. Typical values, highs and lows are shown in Table 1."

Jan 1, 2001

By David N. Hanlon

The effect of high-temperature plastic deformation of the austenitic phase (y) on the subsequent phase transformation to ferrite (a) has been experimentally investigated, and modelled using a physically-based model. The effect is of importance for steel sheet, in view of me significance of the phase transformation with respect to the eventual properties of the material. In this paper the kinetics of the y ? a phase transformation has been studied after different degrees of prior deformation. The degree of deformation is varied by applying different deformation temperatures and strain rates, and by allowing a varying extent of recovery and recrystallisation. Consequently, both dynamic and static recovery and recrystallisation have been involved. The dilatometric observations on the phase transformation have been modelled using an interface-mobility model, in which the effect of the dislocation structure is introduced as an additional driving-force term. The effect of the stored energy on the nucleation process, which appears to be affected more strongly than the growth of ferrite, is examined in terms of the classical nucleation theory.

Jan 1, 2001

By Douglas J. Uhren, Gary W. Gilbert

This paper describes the risk elements associated with difficult glacial geology, including boulders, heavy groundwater inflow, and potential running soils all coupled with a potentially corrosive service environment. The matrix workshop for the 168-inchfinished diameter sanitary sewer interceptor tunnel in Columbus, Ohio is assembled with the Design Team and the Owner’s design, operations, and fiscal staff. Corrosion protection alternatives are compared against cost and non-cost parameters with relative risk and weighting factors assigned. The Owner working in cooperation with the Design Team uses the matrix workshop to se

Jan 1, 2001

By W. G. Davenport

Smelting oxidizes Cu-Fe-S concentrate to matte. Converting oxidizes this matte to metallic copper. Smelting and converting are, therefore, part of the same oxidation process. It would seem natural, then, that smelting and converting should be combined to produce metallic copper in one step. This would: (a) maximize S02 capture by restricting S02 emission to a single, continuous source (b) minimize industrial oxygen and fuel requirements (c) minimize cost. This chapter discusses one step, direct-to-copper flash smelting as it is practiced in 2000. It then uses. the matrices of this book to determine: (a) the industrial oxygen and oil requirements of direct-to copper flash smelting (b) the distribution of Cu between metal and slag during direct-to-copper flash smelting. It concludes that direct-to-copper flash smelting: (a) captures?S02 efficiently from its single continuous stream of SO2 off gas (b) minimizes oxygen/oil consumption but: (c) sends -114 of its Cu-in-feed to slag.

Jan 1, 2001

By Christopher M. Kenney

Augered-cast-in-place (ACIP) piles have been utilized on commercial projects throughout many parts of the country for years, but are only beginning to be scrutinized for use on major infrastructure projects and other critical structures in some regions. Numerous engineers are aware that ACIP piles are an economical foundation alternative, and many technical papers have been presented that provide reliable methods of estimating ACIP pile load capacity. However, designers may not yet appreciate that the load-settlement behavior of ACIP piles is very similar to that of drilled shafts. This paper analyzes ACIP pile case histories from throughout the country and demonstrates that ACIP pile settlement under applied load is consistent, predictable, and very similar to the documented behavior of drilled shafts. This paper also presents a simple but accurate method of estimating ACIP pile settlement at the design load, and illustrates the need to estimate the equivalent diameter of the as-built ACIP pile when estimating pile behavior. Finally, this paper presents back-calculated values of the drained elastic modulus from the ACIP pile case histories that may be useful to those using more sophisticated methods of estimating ACIP pile settlement.

Jan 1, 2001

This paper describes the experiences with the application of the Coal Mining Roof Rating (CMRR) System to South African strata conditions. Roof classification studies using the CMRR system were undertaken as part of a SIMRAC investigation into falls of ground in South Mean collieries. Colliery roof rating exercises were undertaking in a range of geotechnical conditions from shallow level coal seams under flat topography to workings with cover depths of greater than 300m A comparison is made between the CMRR and other Rock Mass Rating systems used to classify different roof geotechnical conditions. The need for geological discontinuity orientation, blasting and rockmass stress adjustments to the CMRR is discussed. The effects of acid mine water on strata weatherability and the need to incorporate immersion tests using acid mine water are also detailed. In addition limited correlation is given between CMRR values and other geotechnical factors such as joint trace length, joint shear strength, joint orientation, weatherability and roof damage due to horizontal stress. Taking cognizance of these observations, a concept of stress induced roof damage triggering is discussed.

Jan 1, 2001

By Bob Rautenberg, Luminita Calin

The Tunnel and Reservoir Plan (TARP), commonly known as the Deep Tunnel Project, was developed by the Metropolitan Water Reclamation District of Greater Chicago as a two-phase solution to the problem of waterway pollution and basement flooding due to sewer system backups created by the combined sewer overflows. With only one contract left before completion of the Phase I tunnels—the 12.4 km(7.7 mi.) long Little Calumet leg—the pollution control phase of the 175.7 km(109.2 mi.) long system will be 93% complete, once the Torrence Avenue tunnel project comes to an end. This paper describes the Torrence Avenue tunnel project, currently under construction by the joint venture of Kenny (Sponsor) / Kiewit / Shea. Mining of the10.4 km (34,151 feet) long and 8.3 m (27'-4") diameter mainline tunnel was completed in a record thirty-one-weeks period and the concrete lining is nearing completion. Details on the complete muck handling system, numerous mining and concrete lining records will be given.

Jan 1, 2001