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By J. Budac, R. Kofluk, D. Belton, M. Sjogren

A series of tests were performed to determine the flammability limits of mixtures of oxygen, ammonia, steam and nitrogen, over a solution, in a sealed autoclave. The partial pressures of ammonia and oxygen in the vapour space were varied by adjusting the character of the solution and by adjusting the oxygen concentration in the oxidant gas respectively. The data shows that flammable conditions can be minimized by controlling the operating temperature, reducing the ammonia content in the solution, increasing the concentrations of Ni, Cu and Zn in solution and keeping the % oxygen in the gas phase less than 15.5. Observations were also made that suggest that the presence of an aerosol in the vapour space may hinder ignition.

Jan 1, 2004

By K. H. Brandt

A standard planning system for the development of roadways was adopted for German coal mines based on the results of geotechnical and rockmechanical investigations. Its goal is to provide for sufficient support systems under conditions of multiple seam mining at great depth. The report points out the required determination of geotechnical parameters and the basis for achieving a high level of planning reliability and resulting high performance in roadway development and longwall mining. The instrumentation and the planning procedure for selecting the support design most appropriate for the geotechnical conditions are described and demonstrated by examples.

Jan 1, 2004

Jan 1, 2004

By D. Fray

Electrochemical processing using molten electrolytes is undergoing a considerable renaissance due to several innovative ideas being explored both in the laboratory and also at the pilot scale. Several of these new ideas are related to developments in energy generation and storage and involve solid electrolytes. Sodium has been prepared by the electrolysis of sodium carbonate or sodium hydroxide with the transfer of sodium ions through a sodium beta" alumina membrane and magnesium oxide dissociated by the removal of the oxygen through a stabilized zirconiaelectrolyte incorporating a fuel cell electrode. By using halides with highly electropositive cations, such as molten calcium chloride, it has been found that the favoured cathodic reaction, when oxygen is present, is the ionization of oxygen and not the deposition of calcium. This approach has been applied to the reduction of many metal oxides including titanium, zirconium, niobium and rare earth oxides and, by using a mixture of oxides as the cathode, homogeneous alloys are produced. This concept can also be applied to deoxidation of solid and liquid metals. Refining of metals is possible using intercalation compounds and, in a completely different application, it has-been found that, by intercalating alkali metals by electrolysis of alkali halides into graphite, it is possible to produce carbon nanotubes and nanoparticles. The technological opportunities of these various concepts will be discussed.

Jan 1, 2004

By J. T. Kalala

Energy consumption and wear of grinding media and liners are the major cost factors in milling plants. Since the beginning of the last century, much effort has been directed at the prediction of the power draw as affected by the mill operating conditions. This paper explores the prediction of the liner wear using the discrete element method (DEM). A mathematical model taking into account adhesion, abrasion and impact wear which occur in dry mills is derived in order to predict the loss of material on liners. The mathematical model is implemented in the DEM code using an objective function in order to produce realistic simulated profiles. Our DEM simulated predictions are compared to published experimental and industrial data. Keywords: modelling; discrete element method; liner wear

Jan 1, 2004

By Frustino L. Prado

For more than a century, the AAC (ammonia I ammonium carbonate) process has been applied to the recovery of various metals. A variation of it, the Caron Process was first used in the early 1940's in Cuba for the extraction and recovery of nickel from laterites. The original Nicaro plant has been in continuous operation since then. Years later the Caron process was used again in Australia at the Greenvale (Yabulu) NickelICobalt plant, commissioned in 1974. Other projects (Sered, Niquelandia, Nonoc, Punta Gorda, Albania) as well as several studies have been carried out. The Caron Process is alive and still promising. Members of our organization have been working with AAC and the Caron Process since 1952. This paper will review current approaches and potential improvements (enhancement of recoveries of Ni and Co, reduced energy consumption and maintenance simplification). Keywords: Caron Process, Ammonia, Ammonium Carbonate, Laterites, Nickel, Cobalt

Jan 1, 2004

By M. Elmadagli

Wear mechanisms of two commercial aluminum alloys, namely a spray formed and extruded Al-25%Si alloy, and a sand cast A390 alloy (18.5 %Si) that are known to be successful in cylinder bore technology were studied to have a better understanding of the requirements for wear resistant aluminum alloy design. From durability point of view these alloys are known to be successful for engine bore applications. It is interesting to compare the wear mechanisms in these alloys because they have significantly different silicon content and microstructures, and were produced using different techniques. The wear tests were done using a block-on-ring configuration, in controlled air atmospheres (5 % relative humidity). In spite of the differences in silicon content and microstructure, the wear mechanisms were similar and consisted of formation and destruction of hard tribolayers that are either formed by either mechanical or chemical interactions on contact surfaces. The differences in the wear rates between the two alloys arose from the differences in the hardness of the worn surfaces, and the alloy's ability to sustain the tribolayers on the worn surfaces.

Jan 1, 2004

By D. G. Klaren, E. F. de Boer

Self-cleaning fluidized bed heat exchangers have demonstrated unparalleled performance internationally for the implementation of indirect heat transfer in severely fouling fluid environments. The ingenious configuration of recirculated cleaning particles through the tubes of vertical shell and tube heat exchangers provides the ability to solve any problems that arise as a consequence of tube-side fouling during indirect heat transfer to process fluids or slurries. In most cases, the cleaning particles consist of chopped metal wire, however other process-specific materials have been used. In addition to the mitigation of fouling effects, a number of other significant benefits for slurry heating are afforded by the mode of operation of the self-cleaning fluidized bed heat exchangers. Increased turbulence at the slurry/tube interface is imparted by the action of the fluidised particles, resulting in very high heat transfers at relatively low liquid velocities. Furthermore, given the thixotropic nature of most process slurries, the action of the fluidised particles imparts additional shear to the process slurry, resulting in shear thinning effects with a consequent reduction in pressure drop and enhancement of heat transfer across the heat exchanger. The benefits provided by the self-cleaning fluidized bed heat exchanger make it the ideal option for the indirect heating of laterite nickel slurry for High-Pressure-Acid-Leach (HPAL) plants. This article explains the principle and application of the self-cleaning fluidized bed heat exchanger technology for the processing of laterite nickel and cobalt slurries in HPAL plants. It also presents an elegant method to revamp existing direct heated laterite nickel and cobalt processing plants into an indirect heated configuration employing self-cleaning fluidized bed heat exchangers.

Jan 1, 2004

By Maria I. De Rosa

Table 37 and figure 13 show the number of fires and fire injuries for surface stone mines by state during 1990-2001. Table 37 also shows the injury risk rates, employees' working hours, and lost workdays. In all, 96 fires occurred in 31 states and 1 fire occurred in Puerto Rico. Sixty-eight of the fires caused 67 injuries and 1 fatality (including 6 fires and 5 injuries involving contractors). The yearly average was eight fires and 5.6 injuries. The Ewhr value was 689 x 106 hr (Irr = 0.02), and the LWD value was 7,399. Indiana had the most fires (eight fires and four injuries), followed by Georgia (seven fires and seven injuries) and Pennsylvania (seven fires and five injuries). Of these states, Georgia had the highest injury risk rate value (Irr = 0.058). Table 38, partly illustrated in figure 14, shows the number of fires, fire injuries, fire fatalities, risk rates, employees' working hours, and lost workdays by time period. The number of fires and fire injuries show an increase during the second period followed by a decrease during most of the remaining periods. Employees' working hours increased during most of the periods. The In values follow patterns similar to those shown by the injury values. Tables 39-44 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 15 shows the major variables related to fires for 1990-2001. Table 45 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By M. Görnerup, M. Hayashi, S. Seetharaman, C. -Å Däcker

The mould flux plays a crucial role in the continuous casting operation of steel due to its multi-functional assignment as lubricator and heat flux controller. In reality, the commercial fluxes can fall short of the expectations of the operator. In such cases, the performance of the mould flux reduces production throughput in the casting machine. This paper presents the results of a study of two different commercial mould fluxes in continuous casting of steels. The results of online sampling during casting, as well as off-line measurements in the laboratory, are presented. Mould flux powder and slag samples from the caster have been characterized with respect to melting behaviour, interfacial tension and thermal diffusivity, using various measuring techniques. An experimental technique has been developed in order to simulate the melting behaviour of a flux in the mould, which has been found to be useful for qualitative studies. A cross-sectional view of different powders reveals that up to four different material layers may exist in the bed: a loosely packed powder layer, sintered layer, semi-solid layer and liquid slag layer. It is found that the melting rate of the mould flux is dependent on the liquid slag layer thickness. Thus, in a continuous casting operation the melting rate is likely to be non-uniform with position in mould due to the difference in liquid slag layer thickness. Mould slag composition is found to be influenced by the starting powder for as long as 30 min, representing a large part of the first heat casting time. Observations of gas formation indicate that interfacial reactions between the steel and slag take place. Keywords: continuous sacting, mould flux, mould slag, properties

Jan 1, 2004

By G. D. Criswell, F. Palkovits, J. M. Johnson

A paste technology investigation was completed for non-pozzolanic fly ash from Units 3 & 4 of PPL Montana’s Colstrip Steam Electric Station. The purpose was to assess the feasibility of converting from dilute slurry deposition of ash products to a system using thickened or paste ash to reduce excess water storage in the impoundment, reduce seepage losses, and increase storage efficiency. The investigation included laboratory and field testing to characterize the rheological, geotechnical and dewatering properties of the ash products, an assessment of potential seepage reductions and an evaluation of potential for increased ash storage capacity by modifying impoundment operating procedures. The studies concluded that the conversion project was feasible, cost effective, and permittable. Critical facilities for the conversion project are currently under construction.

Jan 1, 2004

By Vic Sterner

As cities and towns continue to grow, the need to install sewer, water, gas and other utilities becomes a necessity and the blasting of trenches for these service lines probably constitutes one of the most important forms of blasting in built-up areas. There f o re, understanding how explosives can be safely used in the most efficient manner is of prime importance. The need for protection against flyrock must be emphasized. The first consideration is that all explosive c h a rges should be located well down in the blastholes. The golden rule is to ensure that the depth of top stemming is never less than the burden on the hole. In the case of shallow holes, the minimum depth of stemming should not be less than 18 times the charge diameter, if airblast and flyrock are to be controlled. If there is a doubt, then additional cover and/or blasting mats should be used. Putting too much burden on blastholes is another possible cause of flyrock and raising ground vibration levels. Overburdening of explosive charges will also result in the blastholes not breaking to grade. This in t u rn re q u i res additional drilling of shallow holes down in the trench to achieve grade, thus further increasing the h a z a rd of flyrock .

Jan 1, 2004

By K. Sun

The exothermic behavior of the intermetallic reactions inside an Al-Mn metallic powder compact and its assimilation fundamentals in molten aluminum were examined. In this study cylindrical compacts were manufactured and tested. The experimental work involved simultaneous temperature measurements of three thermocouples as well as detection of the apparent weight of the cylindrical specimen during its assimilation in liquid aluminum. The details of the intermetallic reactions prior to the compact complete disintegration were investigated by microscopically studying the morphology and local composition in a partially reacted compact. The variation of manganese concentration in the melt was determined by chemically analyzing the samples taken from the molten aluminum at specific time intervals. The exothermic reaction increases the compact's temperature above that of the liquid aluminum. In tandem with this exothermic reaction, the compact is suffering a swelling action. This swelling action disintegrates the cylindrical specimen, which is assimilated into the liquid aluminum. The intermetallic reactions proceed in a stepwise manner. Both the bath temperature and the compact composition impact on the exothermicity of the intermetallic reactions. However, when the amount of Mn in the compact is greater than 75-wt%, the maximum centerline temperature rise is slightly reduced as Mn amount increases.

Jan 1, 2004

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

It was determined by the authors that the water that remains in the filter cake after filtration in iron ore concentrators can contain several hundred times greater concentrations of calcium ions and other cations, due to surface chemical effects carrying the ions along with the water. Filter cake from two plants was analyzed. The water retained in samples of magnetite concentrate filter cake in Plant 1 contained 5088 ppm calcium and 5995 ppm magnesium, while the Plant 2 filter cake contained 231 ppm calcium and 119 ppm magnesium. These levels were dramatically elevated compared to the water that was removed from the concentrate by filtration for recycle to the plants (9 ppm calcium/15 ppm magnesium for Plant 1, and 11.9 ppm calcium/9.3 ppm magnesium in Plant 2). In addition to possible effects on agglomeration performance, the presence of these cations also affected the efficiency of filtration. In order to reduce the effects of these cations on filtration in Plant 2, carbon dioxide was injected into the slurry before it entered the filter press. This was found to increase filtration rates by up to 23.7%. Comparison of the results from the two plants shows that the concentrations of cations present in the filter cake will vary greatly from plant to plant, with correspondingly large variations in their effects on plant operations.

Jan 1, 2004

"In this paper, a mobile heat treatment furnace from Akkermans Gloeitechniek, a Dutch company, was simulated with Computational Fluid Dynamics (CFD). The furnace is cylindrical with four oil burners, and large metal products such as dredging pumps and impellers can be flexibly heat treated to obtain required microstructure and mechanical properties through stress relief, annealing, hardening and tempering. The furnaces are exposed to the open air, and thus the heat loss becomes significant and varies from day to day and from season to season. Since the temperature of the metal products to be heat treated can only be measured on the surface, the temperature evolution inside the metal could not be tracked in practice. CFD simulation provides a useful tool to predict the temperature evolution within the metal pieces and within the combustion space of the furnace. Energy distribution and heat loss can be subsequently estimated. An overall energy balance through temperature measurement indicted relatively low energy efficiency. Especially during the soaking period, the high energy supplied is barely used to compensate the heat loss of the furnace to maintain a constant temperature of the metal piece. The current CFD modeling aims to give advice on how to modify the design and optimize the operation to reach higher energy efficiency and low heat loss. The CFD model consists of turbulent combustion model, radiation model in participating media, and conjugate heat transfer between the combustion space and solid metal. Temperature measurement was carried out to provide thermal boundary conditions and overall energy balance of the operation. After the model validation with temperature measurement within the combustion space and metal surfaces, furnace optimization will be conducted.IntroductionHeat treatment is a common practice in metal production and manufacturing industries. Through heat treatment at certain temperatures with special patterns, unique mechanical properties of the metals and the metallic products could be obtained. ""Akkermans Gloeitechniek"" is a company situated in K.inderdijk, at location of LHC-Holland (www.ihccaland.com), the Netherlands. Heat treatment of metals is its core business. Various type of heat treatment are applied, such as stress relieving, soft annealing and hardening (quenching), tempering, transformation and precipitation. At the company 6 furnaces are in operation and the 7th is being built"

Jan 1, 2004

By David R. Skuse, Jacek A. Kostuch, Steven M. Fortier

"Particulate ground calcium carbonate (GCC) is used as a filler and coating pigment in a wide range of applications including papers, paints, plastics and films. In this paper we will overview the requirements for GCC used in both filling and coating applications in the paper industry and highlight the processes used in the production of these materials.INTRODUCTIONCalcium carbonate is both abundant and very widely distributed occurring most commonly as limestone, marble and chalk (Harben 2002). Given, the high purity, whiteness and relative inertness of these materials it is not surprising that they are heavily utilised in a range of industrial applications. Worldwide ground calcium carbonate (GCC) capacity is estimated at 50.5 million tonnes per year (Roskill, 2002). This usage is divided between relatively coarse materials that are used in applications such as landscaping, cultured marble and carpet backing and finer grades that find application in plastics, rubbers, inks, paints and paper. Given the usage of calcium carbonate products across a very wide range of consumer products, the outlook for GCC is very promising with growth expected in many markets. Growth is anticipated across many applications in the emerging nations and more specifically in paper applications on a global basis.Over the last several decades the GCC processing industry has evolved to be well adapted to both the cost effective production and delivery of standard products and the production of high performance speciality products. Many of the standard unit operations found in the metaliferous raw material processing industry are also used, albeit in some cases in modified form, in the processing of GCC. Coarse products (diameter > 3 - 10 µm) are typically produced by dry processing routes. Whereas, the finer products are typically produced by a combination of wet and dry processing."

Jan 1, 2004

By M. M. D. S. Vemba

Paper written on project work carried out in partial fulfilment of B.Sc. Eng (Mining Engineering) degree Engineering refers to the application of mathematics and other sciences to logically develop solutions to problems. However, in opencast mining, due to the randomness of operations, the use of mathematics is often neglected. Instead, practices that have proven successful elsewhere tend to apply. At the other end of the scale, mathematical models have been developed to identify and quantify all the operational parameters involved in the loading and haulage of ore. These are then used to optimize the operation. Optimization in this context, refers to the reduction of cost through effective utilization of the available time and resources. Considering these mathematical models, the loading and transport system at SMC (Catoca Mining Society) will be assessed with a view to its optimization. The discussion will be introduced by considering the mine background and other general information, which will highlight the main operational variables.

Jan 1, 2004

By W. Barthel, B. A. Dippenaar, J. Malan

In its most basic form, the process of sintering is very simple, and has been in use since the turn of the previous century. However, while the basic process is simple, control of the process relies on a number of extremely complex interdependent process parameters and requires a thorough understanding of the effect of these parameters on production capacity and product quality. Further, as with many other processes, the process parameters and hence design details of visually similar installations are highly dependant on the specific feed materials. While the industry trend has been towards an increase of capacity in order to lower unit production cost, typically in Iron ore sintering plants, this approach is not always possible for other commodities because of the scale of operation. This paper seeks firstly to describe some design considerations of sinter plants; secondly, to report on results from testwork performed with a specific series Manganese ore blends; and last, to relate these results to the design of new small-scale Manganese ore sinter plants.

Jan 1, 2004

[Dr. N.A. Barcza (Chairman) Mr. R.J. Linnell (Vice Chairman) Mr. J. Basson Dr. L.A. Cramer Mr. W.A. Gericke Dr. N.C. Machingawuta Mr. C.S. Mahony Dr. L.R. Nelson Mr. D. St J. Slater Mr. B.J. van der Walt INFACON X TECHNICAL PROGRAMME COMMITTEE Dr. L.R. Nelson (Chairman) Mr. W.A. Gericke (Vice Chairman) Mr. W. Barrett Mr. T.R. Curr Dr. O.F.R.A. Damm Prof. R.H. Eric Mr A.M. Hearn Mr. A.R. Jamieson Dr. N.C. Machingawuta Mrs. L. Mthombeni Mr. F.X. Prins Mr. J. van Tonder ]

Jan 1, 2004

By Dennis Nottingham

Increased interest in seismic soil liquefaction and preventative soil stabilization sets the stage for improved deep compaction methods using pile driving techniques. In 1971 L.B. Foster Company personnel patented a method of deep compaction using a vibratory pile hammer and pile probe. The technique had some success, but did not produce consistent results and thus found its way to obscurity. Other patents attempted to modify the technique by various probe modifications, but again without measurable improvement from a practical point of view. Solutions to economical deep compaction up to 100-foot depths particularly in saturated granular soils would have a great impact on the construction industry and new bulkhead structures being developed, thus PND was prompted into related research and development. The advent of higher horsepower vibratory hammers, coupled with PND engineers' experiments, observations and measurements, led to an "H" pile probe design which has produced measured soil density improvements up to 250% using SPT "N60" values as a measure. Case histories of two projects involving extensive SPT soil sampling comparative measurements will be discussed along with findings that led to the compaction success. Applications to numerous modern "Open Cell" bulkhead projects will be presented and discussed.

Jan 1, 2004