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By D. -P. Georgescu

A native sulfur mineralization associated with pyrite and iron oxides containing 20% iron was quarried in Calimani Mountains, Oriental Carpathians. The wastes resulted from this exploitation activity, with a volume of 33 millions m3, were stored in four dumps while the wastes resulted from ore processing using flotation and the subsequent treatment were disposed of in a settlement pond. The investigations carried out in the entire mining area focused on the following two aspects: - the impact of environmental factors mainly on the hydrographic network; - the characterization all pollution sources, namely dumps, leachates and the quarry and the assessment of acidic drainage generation. The total sulfur content of the excavated ore was 3.8% while in dumps it ranged between 0.54 and 1.06%. Analysis of samples collected along the hydrographic network, draining the mining area, resulted in pH values ranging between 1.7 and 2.83 as well as high concentration of iron (4525 mg/L to 1.6 mg/L), copper (1.87 mg/L to 0.04 mg/L) and zinc (13.13 mg/L to 0.3 mg/L). Samples from the quarry, the dumps and the tailings pond were analyzed in order to deter-mine: - the maximum potential acidity (MPA); - the acid neutralization capacity (ANC); - the net acid production potential (NAPP).

Jan 1, 2005

By D. J. Fourie

During the production of pure TiO2for the pigment industry, ilmenite, containing 35?60% TiO2, is reduced to high titania slag, containing 70?95% ?TiO2? and pig iron. The high titania slag produced, consists mainly of titanium in different oxidation states and FeO in equilibrium with liquid iron. To predict the phase and chemical reaction equilibria in a furnace, a suitable solution model is required with accurately determined binary interaction parameters, as slag melts tend to behave very non-ideally. This paper investigates two popular slag models, namely, modified quasi-Chemical (MQC) model and the cell model and provides the binary interaction parameters based on recently published data of the ternary system and critically assessed published unary and binary data. Very few modelling results have been published on the ternary Ti-Fe-O system pertaining to high titanium slags. The solution models, with their regressed interaction parameters, can subsequently be implemented in commercial software of the slag-metal phase equilibria to predict how much and which type of solids will precipitate for a given bulk slag chemistry and operating temperature or, alternatively, above which temperature should a furnace be operated to avoid excessive solids precipitation.

Jan 1, 2005

Although the mining industry has achieved record-low fatalities and injuries for each of the last three years, there are still too many miners injured or killed in this nation ís mining operations. Many mining injuries or deaths might have been prevented by using risk assessment to identify and control or eliminate the hazards associated with a task. To focus attention on the importance of conducting risk assessments in keeping mining workplaces safe and healthful, MSHA introduced this initiative on October 12, 2004. This initiative is called SLAM. SLAM is an acronym for Stop, Look, Analyze, and Manage. The steps involved in SLAM are: Stop ñ stop and consider the work involved Look ñ look for and identify the hazards Analyze ñ analyze what needs to be done Manage ñ manage safety by developing and implementing controls Everyone should be aware of the risks of an accident before beginning a task. It may not always be obvious that performing a seemingly routine task could result in an accident. That is why conducting a risk assessment is so important. Itís important to remember that over time a mining workplace seldom remains unchanged. Risks must be assessed whenever procedures or processes change, whenever new tasks are started, or non-routine tasks are performed.

Jan 1, 2005

By Shemek Oginski

The 5 km (16,194 lf) of 6.1m (20 ft) diameter TBM driven tunnel built by the J.F.Shea Co. will serve as sewage overflow storage. The TBM tunnel and four connecting tunnels excavated by drill and blast methods in hard granite will remain unlined. Based on the Geotechnical Baseline Report (GBR), the Contract documents provided a design with no required pattern of rock bolts, no probing, no pre-excavation or consolidation grouting, and lastly, no final lining of the tunnels was deemed necessary. This paper will provide a general overview of these topics with the emphasis on the actual ground conditions encountered versus the projected conditions provided in the GBR and how the GBR reflected the design of the project. Proposed modifications to the temporary and permanent ground support will be presented and the necessity of probing and pre-excavation grouting will be evaluated.

Jan 1, 2005

By F. N. Smith

Corrosion was observed on the aluminum pressure plates and dress-caps that hold the glazing in place on a curtain-walled building, The multi-storey building in question is situated in the downtown area of a busy Canadian city, For aesthetic reasons, the original design required the dress-caps (which have L-shaped cross-sections) to be externally clad with thin copper sheet. Since the aluminum was in direct contact with the copper trim, galvanic corrosion developed that resulted in damage to the aluminum components, Soluble corrosion products washing off the copper trim may also have contributed to the accelerated corrosion of the aluminum, The aluminum pressure plates and dress-caps are being systematically replaced with components made of fibre-reinforced plastic. The outsides of these new components will be clad with thin copper sheet in order to preserve the original appearance of the building.

Jan 1, 2005

By K. J. Stanaway

Major world ilmenite and rutile accumulations reveal similar regional geology and Proterozoic age deeper crustal source rocks. During crustal collision titanium crystallizes as ilmenite and rutile at buried sites of high pressure and temperature rock metamorphism. Hydrothermal activity can convert titanium minerals to rutile, but titanium migration and enrichment seem only local. Many melts crystallize rocks with iron-titanium oxides in solid solution, but titanium enrichment at economic scale takes place in basic intrusive melts often associated with anorthosites and charnokite. Sedimentary placer enrichments have formed since the Proterozoic with water-resistant ilmenite, and rutile segregating by gravity from quartz sands deposited from flowing water. Placers have residual, alluvial, strand and shallow marine variants. Time, organic acids, and sand permeability play lead roles in the leaching of iron from ilmenite during weathering and diagenesis.

Jan 1, 2005

For various reasons, the maintenance of shaft structures is becoming an increasingly important factor in the operation of underground mines. Deterioration mechanisms related to operation of the shaft are identified as corrosion, mechanical damage, fatigue damage and wear. Deterioration mechanisms related to rock movements are identified as vertical strain, ride vertical closure and squeezing. Analytical procedures for assessing this deterioration are discussed, and it is shown how acceptance criteria are developed and implemented. In order to track the deterioration of shaft structures, shaft inspections are undertaken, but the information is often not well documented. Formalised procedures for capturing and recording information, and then processing the information are presented. Finally, two case studies are briefly described to illustrate how these procedures have been implemented in practice, and what benefit has accrued to the mines concerned.

Jan 1, 2005

By P V. Savage, T Glück, RCA Minnitt, C Bothma

Manganese Metal Operations ?Manganese Metal Company (MMC), a subsidiary of Samancor BHP Billiton, has two production facilities for electrolytic manganese metal in South Africa and produces a range of about 44 Mn metal products. ?The company is accredited with ISO 9000 and uses Six SigmaTM for continuous improvement. ?The control of the process relies on the effective functioning of approximately 250 different control loops at 50% automation.. ?Approximately 50000 samples are analysed every month. ?There are pyro, hydro and physical unit operations for the production of electrolytic manganese metal flake and value added products ? [ ]

Jan 1, 2005

By J Masliyah, Z Xu

The largest oil sand deposit in the world is located in Alberta, Canada, with a total proven reserve of 2.5 trillion barrels of oil. The water based extraction process is currently being used in commercial operations to recover bitumen by flotation from oil sand ores. A recognised challenge in bitumen extraction is the reduced bitumen recovery when processing ores containing high fines content or æweatheredÆ oil sand ores, collectively known as poor processing ores. Inspired by demonstrated success of using kerosene as collectors in coal flotation, an innovative idea of using oily bubbles (air bubbles coated with a thin layer of oil or solvent) was tested to improve bitumen flotation recovery from poor processing ores. In this study, dynamic contact angle of air bubbles or oily bubbles on bitumen and induction time of bitumen-oily bubble attachment in water were measured to justify the use of oily bubbles in bitumen recovery from poor processing ores. The type of oil or solvents, including kerosene, toluene and naphtha, used in generating oily bubbles showed a marginal effect on the contact angle values, similar to the values measured with air bubbles. However, the spreading of an air bubble was found to be much slower than that of oily bubbles on a bitumen surface. The induction time for oily bubble-bitumen attachment was found to be much shorter than that for corresponding air bubble-bitumen attachment in the process water from poor processing ores. The reduced induction time for kerosene-coated air bubble-bitumen attachment correlates well with the improved bitumen recovery from poor processing ores using kerosene-coated oily bubble flotation technology.

Jan 1, 2005

By D C. Curry, M F. Young

Many flotation operations need to improve liberation to increase recovery, yet often plant operators are concerned that finer grinding will produce æslimesÆ with low flotation recovery. Yet simple circuits can be designed to give good liberation and excellent fines recovery. The economics of fine grinding has changed fundamentally with new stirred milling processes like the IsaMill. This has also transformed flotation design due to the clean surfaces produced in the inert grinding environment and the narrow size distribution produced by the IsaMill. Past poor experiences with æovergrindingÆ in flotation circuits was often due to the wide size distribution and the degradation of mineral surfaces produced by conventional devices using steel media, like ball mills and tower mills. The correct practice is to design both grinding and flotation together to suit the liberation characteristics of the ore. This may result in several stages of grinding and flotation, recovering mineral as soon as it is liberated, then applying further grinding energy only to those particles that still need liberation. Flotation then occurs in relatively narrow size bands and with minerals with similar liberation characteristics. Though the circuit may look more complex on paper, in reality it is far simpler to operate since each section performs predicably. Circuit design also needs to address materials handling. Finer particles affect froth handling and dewatering, but can still be easily handled by standard products with careful attention to design of launders, pumps and pumpboxes, and de-aeration before thickening and filtering. Excellent examples of designing circuits to include ultrafine grinding include Mt Isa and McArthur River (MRM). In the last decade these operations have produced over ten million tonnes of concentrate with an average grain size below 10 ¦m and above 80 per cent recovery. At Mt Isa, zinc recovery was increased by ten per cent by applying fine grinding to existing poorly liberated streams. In fact, grinding finer in the IsaMill actually improved the recovery of fine particles by ten per cent, and maximum particle flotation recovery occurs for 10 ¦m particles. A more recent example is the flotation of Platinum Group Metals (PGMs). The use of conventional ball or tower milling to improve liberation is severely limited by the impact of commonly associated chromite on classification, and degradation of flotation performance by the steel grinding environment. The ability of open circuit IsaMills to deliver a narrowly sized ultrafine product with clean mineral surfaces is transforming the design of platinum flotation circuits. The science and practice of fine-grained flotation is now thoroughly proven. The availability of the 2.6 MW IsaMill has made ultra fine grinding a practical tool for flotation plant design. It is expected to become a standard choice for future applications of both fine-grained ores and for minerals with difficult flotation characteristics.

Jan 1, 2005

By A Kamkar-Rouhani

The paper describes a mineral potential mapping of gold and other base metals in Mahneshan area, Iran, using geographical information system (GIS), in which, the method of weights of evidence is used to combine spatial data obtained from different sources to make prediction for mineral potential. This is a quantitative tool for mineral resource mapping that can be used to delineate and predict favorable areas for further exploration by using the characteristics of known and similar mineral deposits. In accord with the descriptive model for gold and other base metal deposits, the spatial distribution of 20 known mineral occurrences was used. In addition, digital evidential maps were used in this study. The maps include maps of lithological units, faults and first derivative of total aeromagnetic data, remotely-sensing data of alteration and also geochemical evidential maps produced on the basis of the results of chemical analyses of samples taken from the stream sediments in the area, and analysed for Cu, Pb, Zn, Sb, As, Ag, Au, Ba and Hg elements. The binary maps were produced and then combined with the model of weights of evidence using 20 known mineral occurrences to obtain a final map of the favourable areas for further exploration of gold and other base metals in the study area. The final map is a predictive GIS model of the mineral deposits in the area. An interesting matter about the final predictive GIS model is that the faults are mainly located in favorable areas which possesses the most probability of mineralisation. Therefore, the faults in these areas have priority for further exploration of gold and others base metals.

Jan 1, 2005

By Pengfu Tan

A thermodynamic model has been developed to predict the distribution behaviors of Cu, Fe, S, O, Pb, Zn, As, and heat balance in a lead blast furnace. The modeling results have been validated by the plant data of a lead smelter in Asia. The model can be used to predict for any set of controllable process parameters such as feed composition, smelting temperature, degree of oxygen enrichment and volume of oxygen-enriched air. The effects of the blast air, industrial oxygen, and coke charge on the distributions of Cu, Fe, S, O, Pb, Zn, As, and heat balance, and on the lead loss in slag have been presented and discussed.

Jan 1, 2005

By Michael S. Kucker, Stuart Warren, Robert A. Robinson, Michael J. Lehnen, David McAllister

Geotechnical conditions exposed by the phased exploration programs have had a major impact on the selection of excavation and support methods, dewatering requirements, size of openings, vertical alignment, and estimated cost of construction for the Beacon Hill Tunnel and Station section of the “Link” Light Rail. Beacon Hill is comprised of a very complex glacial geology, including numerous slickensided fractures, injected sand dikes, and multiple perched groundwater levels as revealed by a phased boring program and exposed in a test shaft. The Geotechnical Baseline Report (GBR) presents this complex geology along with a “tool box” of alternative additional support systems to accommodate the varying ground conditions during construction of the station excavation. Additional explorations will also be accomplished during construction to further refine the geotechnical interpretations and provide an opportunity to use pro-active ground improvement techniques to optimize the station excavation and support requirements.

Jan 1, 2005

By K. N. Santini, J. M. Barker

The perlite industry in the United States continued to undergo rapid change and increased competition last year as it did in 2002. U.S. production in 2004 was 510 kt (562,000 st),an increase following five consecutive years of decline (Table 1). Perlite is exported to Canada and to the Pacific Rim. These partially offset imports. Perlite imports from Greece to the eastern and Gulf Coasts of the United States declined by about 22 percent after reaching a record 240 kt (264,000 st) in 2003.But their market remains protected by high rail rates from western U.S. plants. Minor imports of perlite persist by Termolita from Mexico.

Jan 1, 2005

By T J. Sheer

The removal of airborne pollutants from underground ventilating air is discussed. The work concentrates on the removal of CO, CO2, NOx, SO2, radon gas and respirable carbon particles. The investigation combines techniques for multiple contaminant removal using forced chemical absorption and oxidation. Both dry and wet scrubbing techniques are employed. Mixed success has been achieved in the tests carried out and this paper is seen as a progress report on the work done to date. The interference and interaction of the gases on the individual removal efficiencies is a very important factor in the finalisation of a macro air conditioner (MAC) design for treating underground ventilating air. This necessitates a specific sequence of contaminant removal. Efficiencies are discussed and recommendations made. Wet forced chemical absorption and oxidation processes, though efficient in terms of removal efficiencies, cannot be employed in the confined underground environment due to safety and health risks. Impacts on the internal water reticulation systems of the mine have been analysed to determine the effect of future large-scale macro air conditioning practices, including blow-off liquids discharged into the water circuits. To engineer the safety and health risks out of such designs can be costly and it is for these reasons the research now concentrates on dry scrubbing of the contaminants from the underground ventilating air. The paper concludes with statements on the benefits of macro air conditioning in deep hot mines, in both recirculating and series air ventilation distribution strategies. These benefits include reduced re-entry times after blasting and increased production rate opportunities.

Jan 1, 2005

By Jim Nickerson, James McCleish, Tom Abkemeier, Nicholas Willig

The purpose of this project is to convey sanitary sewage from an existing pump station to a new waste water treatment plant. This paper will discuss the design and construction aspects of the project. The scope includes construction of three main shafts ranging from 34 to 100 feet in diameter at depths of 200 to 230 feet and 21,000feet of tunnel. Shaft construction consisted of slurry wall excavations keyed into claystone and limestone at depths ranging from 114 to 130 feet, followed by rock excavation utilizing drill and blast methods. The tunnel is being excavated in the Warsaw and Salem shale and limestone formations utilizing a 12'-6" diameter Wirth hard rock TBM.

Jan 1, 2005

By D Wiseman, R Dunne

Flash flotation is a process that is included in many new mineral processing plants as part of the grinding circuit. Some of the valuable minerals can often be liberated at coarse sizes and will remain in the recirculating loads of the mill until they are reground small enough to report to the cyclone overflow. In addition, minerals of high density report to the cyclone underflow despite being fine in size. This can lead to overgrinding and makes the recovery of valuable fines by flotation difficult. Flash flotation is used to remove the readily floated coarse particles as early as possible and can therefore prevent overgrinding. It thus has the added potential to improve materials handling of the concentrates in such processes as filtration. The merits of including flash flotation within an integrated comminution-conventional flotation circuit is not easy to determine experimentally. Simple batch flotation tests are unable to provide any measure of the possible or probable improvements that are likely to occur from this circuit configuration. As a consequence expensive pilot plant programs are resorted to, to provide the information that will justify the inclusion of flash flotation into a comminution-flotation circuit. Those who have been involved in such pilot plant programs will know of the difficulty in stabilising the circuit as well as selecting the appropriate operating parameters (eg amount of concentrate to be removed in both the flash flotation and conventional flotation circuits). The interactive nature of this circuit (grinding, classification and flotation) is the root cause of these difficulties. Computer simulation, based on information derived from laboratory batch test work or plant and laboratory data, offers an alternative means by which an initial assessment of the merits of a flash flotation circuit can be determined. It can also provide the basis and focus for pilot plant testwork. Recently MacKinnon, Yan and Dunne (2003) developed a model that allows the performance of a flash flotation to be obtained within a closed circuit grinding operation. This paper provides details of an extension of this model to incorporate the interaction of flash flotation on the downstream conventional flotation circuit and allows æwhat ifÆ scenarios to be explored. Details of the laboratory batch test work methodology and the pertinent data derived from these tests that are used in the models and simulation are provided.

Jan 1, 2005

By Terra Dinamica, Frank Lucca

This paper discusses blast design for vibration control in tight construction blasting. Topics include blast pattern geometry, blast design formulas, loading, explosives & initiation selection, and utilizing borehole deviation equipment and lasers, and rules of thumb. The paper will also explore vibration prediction, neighbor relations, and related topics, such as blast plan submittal. Various projects from metropolitan construction blasting operations will be used as examples. Examples include blasting in the inner city, next to pipelines, and in housing developments.

Jan 1, 2005

By S G. Hagemann, M E. Barley

The Mt Tom Price deposit is a world-class high-grade hematite deposit in the Hamersley Province of Western Australia with an original resource of 900 Mt of almost pure hematite, averaging 63.9 wt per cent Fe. Petrological and geochemical studies at both the Southern Ridge and the North deposit at Mt Tom Price have identified three hypogene alteration zones between unmineralised BIF and high-grade iron ore: distal magnetite-siderite-stilpnomelane; intermediate hematite-magnetite-ankerite-talc-chlorite; and proximal martite-microplaty hematite-magnetite-apatite alteration zones.Fluid inclusions trapped in siderite within the distal magnetite-siderite- stilpnomelane alteration zone at the North deposit revealed primary high salinity (25.5 eq wt per cent NaCl-CaCl2) inclusions that homogenised between 107¦ and 142¦C into liquid. Fluid inclusions trapped in ankerite within ankerite-microplaty hematite veins in the intermediate hematite-ankerite-magnetite-talc-chlorite alteration zone at the North deposit revealed mostly H2O-CaCl2 pseudosecondary and secondary inclusions with salinities of 22.4 - 25.4 eq wt per cent and 22.9 - 25.9 eq wt per cent CaCl2, respectively. Pseudosecondary inclusions homogenised between 153¦ and 449¦C and secondary inclusions homogenised between 103¦ and 157¦C. Fluid inclusions trapped in apatite within talc-microplaty hematite veins in the intermediate hematite-magnetite-talc-chlorite-apatite alteration zone at Southern Ridge revealed that primary, medium salinity (7.0 - 9.0 eq wt per cent NaCl) inclusions homogenised between 181¦ and 257¦C and primary high salinity (22.8 - 25.9 eq wt per cent CaCl2) fluid inclusions homogenised between 118¦ and 257¦C into liquid. Microthermometric analysis of quartz from quartz-hematite veins from the Southern Batter Fault, Southern Ridge show a complex fluid inclusion history. Primary fluid inclusions consist of: low- and high-salinity H2O-NaCI inclusions trapped at temperatures of approximately 140¦ to 230¦C; vapour-rich inclusions of unknown compositions; and æcomplexÆ salt-rich (Ca, Mg, K and Na inclusions).Secondary inclusions consist of medium-salinity fluid inclusions trapped at temperatures of about 140¦ to 280¦C.A two-stage hydrothermal model is proposed for the formation of both the Southern Ridge and North deposits. Early 1a hypogene alteration involved the release of hydrothermal NaCl-CaCl2-rich (25.5 eq wt per cent) basinal brines (110¦ - 150¦C) from the underlying Wittenoom Formation and directed upward along normal faults and focused within the silica-rich rocks of the Dales Gorge Member, by the shales of the underlying Mt McRae Shale Member and overlying Whaleback Formation. Within the Dales Gorge Member hydrothermal basinal brines migrated laterally within large-scale folds with permeability controlled by shale bands and the NW trending dolerite dyke sets. Fluid rock reactions transformed unmineralised BIF to magnetite-siderite-iron silicate BIF, with subsequent desilification of the chert bands. Stage 1b hypogene involved an increase in temperature of the hydrothermal, CaCl2-rich saline (24 eq wt per cent) basinal brines (250¦ - 300¦C) resulting in formation of hematite-ankerite-magnetite-talc-chlorite alteration and the crystallisation of microplaty hematite. Late stage 1c hypogene alteration involved the interaction of low-temperature (~120¦C) basinal brines with the hematite-ankerite-magnetite mineral assemblage. At the Southern Ridge deposit this process was very intense (ie high fluid flux), therefore resulting in the almost total removal of ankerite and resulting in the increased porosity of the ore. Stage 2 supergene enrichment in the Tertiary resulted in the removal of residual ankerite and apatite and the weathering of the shale bands to clay.

Jan 1, 2005

By C Yates, S Jobling, Z Y. Yang

The current trend in the UK towards the adoption of retreat longwall mining methods and the associated rapid development of the access drivages have exacerbated the environmental conditions experienced within these workings. There is a recognised need to improve the efficiency of the design and operation of mine ventilation systems in order to maintain an adequate environment and climate within these workings. Any improvement achieved in the quality, quantity and control of the delivered ventilation will assist in the provision of improved gas and dust dilution and climatic control. The paper presents an analysis of the psychrometric data recorded during the execution of a series of comprehensive climatic surveys conducted within two representative deep underground UK coal workings. The surveys were performed across two high production retreat longwall districts within UK Coal Ltd collieries. The surveys employed intrinsically safe psychrometric transducers and digital data-loggers to collect a continuous record of the mine climate over designated weekday production and weekend non-production periods. The transducers and data-logging units are capable of simultaneously measuring and digitally recording changes in the dry bulb temperature and the relative humidity at regular time intervals for extended periods of time.

Jan 1, 2005