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By Clara María Lamus Molina

The following minerals found in the residual black sands from gold mining in El Bagre Antioquia (Colombia) were identified as having major economic interest: Ilmenite (FeTiO3), with an average of 49% of TiO2, frequently altered presenting crowns; lamellaes of rutile and alteration textures; titanomagnetite with up to 25% of TiO2; magnetite (Fe3O4) in individual grains or associated with others minerals as hematite and ferromagnesian silicates rutile (TiO2) with considerable quantities of Nb2O5(0.1-3.7%Wt); zircon (ZrSiO4) with 66%Wt of ZrO2 and monazite with an average of 63.43%Wt of REE, this frequently associated to xenotime and thorite forming textures as little drops. Analysis in EPMA and SEM/EDS showed percentages of minor elements and traces, thereby clearly establishing the applications of these minerals in diverse industries. Furthermore, a detailed granumetric study of the different minerals and textural relationships among them also allowed for establishing the basis for possible processing and exploitation.

Jan 1, 2006

By M. A. Aziz

The electrochemical performance of a series of carbon materials produced from coconut shells, which are very cheap and readily available in Bangladesh was investigated for their viability as anode materials in rechargeable lithium-ion batteries. X-ray diffraction technique was used to measure the interlayer spacing (d002) of the produced carbon materials. A number of half-cells were prepared with the produced carbon materials from coconut shell as working electrode and metallic lithium as counter electrode with 1MLiPF6 electrolyte in a mixture of ethylene carbonate and dimethyl carbonate. The discharge-charge profiles were measured for the different half-cells by using Arbin 24-channel Cyler. The value of interlayer spacing of the coconut-based carbon material was found to be 0.397 nm at 900°C, which is most suitable for lithium-ion insertion into the carbon structure without any expansion. The specific discharge capacity of carbon material from coconut shell heat treated to 900°C was found to be 1015.65 mAh/g. The coconut carbon material heat treated to 900°C delivered 335.22 mAh/g reversible capacity, which is comparable to the commercial carbon/graphite presently used in lithium-ion battery systems. The irreversible capacity loss and coulombic efficiency in 25th cycle of half-cell made with coconut carbon material were found to be 0.16% and 99.83% respectively. The carbon material produced from coconut shell can, therefore, be used as a potential anode for rechargeable lithium-ion batteries.

Jan 1, 2006

By Peter B. Lilly

Thank you, Syd, for the kind introduction and for inviting me to give the Keynote Address at this very prestigious gathering of some of the finest intellect and talent in the domestic and international coal industry. CONSOL Energy has been a part of this conference for its entire 24-year existence. We have presented 27 papers over that time. CONSOL employees have also been members of the planning committee for the conference, and we have been pleased to support the event both financially and with many participants. So I am honored to be here with all of you this morning, especially during such a positive period for coal. You can just feel the enthusiasm in this room for our industry, and for this conference. I can tell you, there?s also a lot of enthusiasm and excitement in CONSOL Energy?s boardroom. And our enthusiasm is mirrored on Wall Street. But there remains an ironic twist to all of this attention. Even when times are good, the coal industry seems to go largely unnoticed by the mainstream. Outside of West Virginia and other coal-producing regions, the industry still seems to lack influence and support, at least here in America. As an example, last month, an ABC News crew visited our Blacksville 2 Mine, near here, to do a feature story on increased employment in the coal industry.

Jan 1, 2006

By Jan E. Nesset, Colin Hardie, Peter Radziszewski, Donald P. Leroux

"The successful introduction of new high intensity stirred milling technologies (e.g. IsaMill, SMDetritor) to the mining industry in recent years prompted Noranda-Falconbridge to initiate a study comparing these technologies to the conventional technologies of ball milling and existing vertical stirred mills (e.g. VertiMill). The study was unique in that it utilized the same material (Brunswick Mine zinc cleaner regrind mill feed), the same sizing instrument (a Malvern laser difractometer) and sampling protocol, and media size and type (for the high intensity stirred mills). The paper compares the net energy efficiency (kWh/t) of the various technologies, their power intensity (kW/m3) and product size distribution spread (P80/P20). A key finding is that media size is critical to achieving optimal performance. As part of the performance comparison, an analysis of the four methods of power measurement was made (Prony brake, shaft torque, grinding chamber reaction torque, “no-load” correction) and followed-up with an experimental test procedure using three of these methods. The findings include divergent results for power measurements and some explanations based on the observations are proposed. The direct shaft torque and Prony brake calibration methods are shown to be the methods most suitable for stirred mills.INTRODUCTIONThe motivation for the investigation reported here was the lack of a suitable comparison within the available literature of relative grinding efficiency for the emerging crop of new industrial fine grinding technologies. Such comparisons are potentially fraught with inconsistency, from ore samples and grinding media used, to testing methodology, to size measurement techniques, to the power measurements themselves. The collaboration of the industrial suppliers (at the time MIM Technologies and Svedala, now Xstrada Technologies and Metso Minerals) and McGill University (P. Radsiszewski) were sought in order to ensure as valid a comparison as possible. The work was performed between October 2000 and November 2002, led by the mineral processing group at the Noranda Technology Centre (NTC) in Pointe-Claire, Quebec. The paper is presented in two sections; Part A considers the different power measurement methods and a comparison of the results for the SMDetritor (SMD) technology, while Part B reviews the grinding performance of the 5 technologies investigated using the selected performance criteria."

Jan 1, 2006

By Frik Badenhorst, René Roux, Peter Terbrugge

This paper presents a case study where economics dictated an aggressive slope angle and where an appropriate slope management programme allowed successful completion of mining to 190m below surface. The Navachab Gold Mine is located in Namibia and is one of the few gold mines in that country. Mining by open pit methods commenced in 1990 with economics dictating an aggressive slope design to minimise waste stripping and make the mine viable. With steep slope angles in the design, and a steeply dipping footwall geology, it was necessary to introduce a comprehensive slope management programme. This required good mining practice in limit blast techniques with pre-splits and trims, and good housekeeping to effect a safe and economical operation. The slope management programme in addition required in pit mapping and logging procedures, regular survey monitoring evolving to a robotic Geomos system, as well as slope instrumentation to monitor stability. Two relatively large scale failures occurred at the mine, the second of which impacted on the east wall access ramp, while the first was confined to an operating stack. The paper describes the design and slope management techniques developed for the east wall.

Jan 1, 2006

By Steve Kral

For a state whose roots are in mining, most Colorado residents probably do not realize that the industry still contributes heavily to the state’s economy. In 2005, the industry contributed, directly and indirectly, about $8 billion to the state’s economy, according to the Colorado Mining Association (CMA). It employed nearly 10,000 people at mines and support businesses. And the mining industry in Colorado is one of the highest paying occupations in the state, averaging about $80,000 a year in wages and benefits. The state’s coal mining industry produced nearly 36 Mt (40 million st) of coal in 2005, valued at $800 million, the CMA said. That was seventh in the nation. And Colorado’s only major gold mine produced 10.2 t (329,000 oz) last year, valued at $124 million. That was third in the nation. And Phelps Dodge’s Henderson Mine produced about 12.7 kt (28 million lbs) of molybdenum, valued at $350 million. Colorado is the largest molybdenum producing state in the nation.

Jan 1, 2006

By Gregory M. Molinda

Historically, miners have known that roof rocks originally composed largely of mud were prone to slaking and deterioration when exposed to water and humidity. Mine Safety and Health Administration (MSHA) records show that roof falls are more prevalent in summer and late fall. Field data shows higher bolt loads and increased room convergence in summer months. Laboratory data shows that very high internal pressures can be generated by significant strain in clay-rich rocks. In summer months humidities ranging from 70-100% can cause rock strains up to 7%, and rock pressures of 14,000 psi, more than enough to break apart weak shales and fireclays. The National Institute for Occupational Safety and Health (NIOSH) conducted wet/dry immersion cycling of clay-rich rocks. Results show that the rocks most prone to moisture deterioration are fireclays, claystones, and sandy shales, all of which have disrupted bedding. Of the 7 mudrocks with a weatherability index above 40%, none showed consistent fissile bedding. Black shales were surprisingly resistant to wet/dry water immersion cycling. Generally, mixed rocks (stackrock), typically susceptible to horizontal stress, are more resistant to moisture-deterioration. Mine roof rocks tested with moisture sensitivity ratings above 50% (moisture sensitivity index ranges from 0-100 with 100 being the most sensitive) all came from mines which had roof skin problems and used supplemental support to prevent rock fall injuries. Some roof rocks showed lateral variability of moisture sensitivity values, suggesting the need for more samples in highly varying roof rocks. Swelling strains of mudrocks showed that almost all of the swelling occurred in the first 24 hours after immersion. The wet/dry immersion cycling test used provides an accurate, quick and inexpensive method for estimating the moisture sensitivity of mudrocks. With this information mine operators can begin to anticipate hazardous ground and prepare appropriate roof support.

Jan 1, 2006

By Timo Niitti, Antti Rinne, Janne Turunen, Sami Grönstrand

"This paper describes novel methods to enhance the flow dynamics of a mechanical flotation cell that can be applied to an existing installation. There are several reasons to alter the flow dynamics. The most common motivation is to improve the metallurgical performance of the cell, for instance, to improve the flotation recovery in particle size ranges that are normally difficult to recover.The flow dynamics enhancements are associated with the geometry of the rotor-stator area and additional features in the tank. The rotor-stator area has been modified to provide more concentrated turbulent kinetic energy or respectively more pumping efficiency with less attrition to the slurry. The tank can be fitted with various geometrical features, aimed to create a desired particle suspension profile. Depending on the targeted particle size range and application, badly selected or designed features can also have a negative effect on the metallurgical results.Besides new flotation equipment, the enhancements can be applied to existing flotation cell installations, thus enabling improvements in the mixing profiles, solids suspension, tank sanding and metallurgical performance of operating flotation circuits. Results of several tests carried out in existing plant operations are presented, concerning both flow variables and metallurgy.The common factor to above-mentioned enhancements is the use of modern computational fluid dynamics tools in the design phase, as well as the validation of the obtained CFD results in laboratory and production scale. Validated variables include mixing profile, power draw and local air hold-up.The paper demonstrates the effects of various flow geometries on the mixing profiles and metallurgical results of existing mechanical flotation cells. It shows how modern computational fluid dynamics analysis can be used to screen and select different approaches before carrying out costly trial-and-error experiments in plant scale."

Jan 1, 2006

Reverse sensitivity is a critical issue for all extractive activities. Extractive industries can only establish in the location of the particular resource sought to be extracted. Avoiding a location near sensitive activities (such as residential activities) may, therefore, be more difficult for extractive industries, than for other industry (such as dairy factories).   This paper focuses on the following matters: +        principles to be derived from case law, +       district and regional council approaches managing reverse sensitivity effects, and +        avoiding, remedying or mitigating reverse sensitivity effects in the future.

Jan 1, 2006

By G. Anger, J. Enser, H. Antrekowitsch, S. Koch

Homogeneous chemical composition and microstructure are always necessary, but not always attained in practice. As-cast aluminium alloys tend to have a segregation microstructure. Features of the cast structure, which affect subsequent processing or properties, can be altered by the homogenization. The main task of the Department of Nonferrous Metallurgy was to investigate the effect of homogenization treatment on precipitation hardening of aluminium alloys 6061 and 6082. The effect of the solution heat treatment (SHT) temperature on the mechanical properties was also analyzed. The homogenized and non-homogenized rolling slabs were produced according to the usual conditions and methods. The metallographic investigations were carried out on the as-cast samples, after homogenization, after the hot and the cold rolling mill, and after natural and artificial ageing. Then, Brinell hardness measurements and tensile tests were conducted on both alloys in order to examine the influence of the homogenization.

Jan 1, 2006

By M Haydon

How do you portray a large structurally and stratigraphically complex deposit to return a meaningful resource estimation, and produce a geological model that is useable for planning on a daily basis? The George Fisher Mine is located 22 km north of Mount Isa and forms part of XstrataÆs Zinc Group operations. It is currently a major producer of zinc, lead and silver in the region with an estimated total resource for all categories of 127 Mt at 100g/t Ag, 5.3 per cent Pb and 9.2 per cent Zn (June 2005). Production in 2005 totalled 2 647 492 wet tonnes for 317 699 kg Ag, 140 317 tonnes Pb and 230 331 tonnes Zn from underground operations. George Fisher (GF) consists of two deposits that are structurally complex on a mine scale, George Fisher North (GFN) and George Fisher South (GFS). Regional faulting has resulted in a 2 km long package of variably pyritic shale and siltstone that separates the deposits. This paper looks specifically at GFN. Distinct correlations exist between the two deposits based on stratigraphic matches; however, orebody characteristics, geometry and fault architectures differ significantly between the two. The deposits consist of multiple, sedimentary-hosted, stratiform orebodies from 2 to 25 m wide, separated by waste intervals of variable width. Each ore-waste interval is modelled as an individual geological domain. Structurally, George Fisher North (GFN) contains a series of major late-stage NE faults with dextral offset(s) of up to 130 m. Further complexity is added by NS, NW and NNE striking fault orientations that can produce either a loss or repeat of stratigraphy, local drag folding, orebody attenuation and block rotation. Due to this structural complexity and orebody offsets, domains at GFN are further divided into fault blocks (FB). The GFN model comprises eight FBs over a strike length of 1 km, all of which are modelled independently. As drilling progresses and additional resources are converted, further FBs will be added at major fault offsets to accommodate orebody and model expansion. This will be in addition to what is already a large and time-consuming data set to manage and update. For example, each FB has 18 domains each with two constraining wireframes (hanging wall and footwall). Each wireframe has several sets of point data depending on the type of data available, ie diamond drilling, mapping or interpretation points. This equates to over 1100 separate files to manage. Additional wireframes and files are also required for major structures, daily planning requirements and block model runs. In total some 1500 files are managed, updated and maintained for GFN alone. The ongoing need to expand as a business and optimise production in the current economic climate where there is a global demand for metal has led to an increase in production at GF. This has resulted in a rapidly growing data set and highlights the importance of practical and efficient modelling to achieve a meaningful resource estimate. This paper focuses on the geological modelling, modelling approaches and techniques employed for the GFN deposit.

Jan 1, 2006

By N Meadows, M Rodriguez

A 200 000 tpa heap leach demonstration plant was approved by the Murrin Murrin Joint Venture (MMJV) in December 2005 and engineering commenced in January 2006. The demonstration plant will utilise stockpiled ore reject material (æscatsÆ) and extract nickel and cobalt. Limited production from the demonstration plant is expected by the end of 2006. The demonstration plant will enable the company to fully investigate and understand all associated technical issues over the next 12 to 18 months, including the potential to expand the heap leaching operation to a commercial scale. In parallel, the MMJV will continue a research and development program to improve and expand the application of its heap leaching technology.

Jan 1, 2006

By P. Coulombe, J-F. Riverin, A. Gaboury

Cavity cleaning during anode change generates a material that consists of anode cover material and cryolite melts. This material is scooped and placed in bins for transport and further processing and recycling as fresh anode cover material. Typical processing methods in use involve cooling of the hot cavity bath in bins, with or without emission treatment systems, until it is adequate to be processed and grinded to the required particle size distribution. Handling of the hot and cooled cavity bath material can be labour intensive. It also generates significant air emissions which contain particulate and gaseous fluorides. With the advent of the Aluminerie Alouette smelter Phase II expansion, the hot cavity bath tonnage to be processed increased to 700 t/day and maintaining existing practices was not satisfactory. This article presents a novel process implemented at the Alouette smelter where cavity bath is processed as a hot material directly from the potlines ( 600-800°C range), sized, cooled and then processed in the existing cold bath treatment plant. The system is designed to process 36 t/h, is fully automated and requires limited monitoring from operations. Implementing this new system in a Browrifield environment imposed numerous constraints for space, interfaces with existing operations, commissioning and ramp-up. It is presently operating at approximately 80% availability and is easily meeting the requirements of the potlines. This system has significantly improved the workplace environment in the bath treatment area and reduced the overall particulate and gaseous fluorides emissions at Alouette. Aluminium 2006 45th Annual Conference of Metallurgists ofCIM Montreal, Quebec, Canada Edited by

Jan 1, 2006

By M. Mabuza

Two Rivers Platinum Mine (TRP) is a 55:45 joint venture between African Rainbow Minerals and Impala Platinum, respectively. TRP is situated on the farm Dwarsrivier 372KT, in the southernsector of the eastern limb of the Bushveld Complex. Dwarsrivier is underlain by rock formations of the Critical Zone (Winterveld norite-anorthosite) and the Main Zone (Winnarshoek norite-anorthosite). Two economically significant PGE-bearing layers namely the Merensky Reef and the UG2chromitite are found within the upper Critical Zone. These are approximately 140 m vertically apart, separated by a series of barren norites and anorthosites. At Two Rivers Platinum, only theUG2 chromitite layer is currently being mined for PGEs. The UG2 sub-outcrops north/south along the Klein Dwarsrivier river valley with a very gentle dip to the west of 7º?10º. At Two Rivers the UG2 averages about 120 cm in thickness, overlain by a waste pyroxenite parting about 20 cm thick, above which is a leader seam about 20 cm in thickness. The mineable cut consists of the leader seam, the waste pyroxenite parting, the UG2chromitite layer including 25 cm of pegmatoidal pyroxenite footwall, below the UG2 reef to a minimum of 185 cm trackless mining cut. The mining method is a mechanized bord and pillar layout, which will yield a total of 185 000tons at full run of mine production from the underground UG2 mine.

Jan 1, 2006

By Ludovic Charpentier

Production of metallic wires directly from liquid jets would avoid drawbacks of extrusion (space needed, damaging, cost?) and enable recycling. But liquid jets tend to break, due to capillary instabilities, unless a solid layer (coating or start of solidification) surrounds it. We recently developed a process to produce tin wires, cooled by water flow parallel to the jet. Superficial oxidization of tin produces a glass coating around the jet. Studies showed the length of wires increased when increasing speed of tin jets, and that water average speed should be the closest possible to the jet one to have smooth fibers. Producing 1 mm diameter wires is possible. The length of wires is limited by the experimental setup, which does not provide possibilities to coil the wire. Most of other metals do not generate glass-like oxides. The lack of coatings makes it necessary to reduce the capillary instabilities to obtain fibers.

Jan 1, 2006

By R R. Lovel

In this paper, life cycle assessment methodology has been used to assess the variations in water use associated with different metal production and processing routes and provide insights into the value derived from water usage in the minerals sector. Using water consumption data derived from the literature it has been shown that the æcradle-to-gateÆ water consumption (or embodied water) for production of the various metals considered in the study ranged from 2.9 m3/t for steel up to 252 087 m3/t for gold. The results largely reflect the grade of the initial ore used to produce each metal, and can be approximated by the following equation:W = 167.7 G - 0.9039 where: W = embodied water (m3/t refined metal) G = grade of ore used to produce metal (per cent metal) The study showed that indirect water consumption in the metal production life cycle, in particular that due to electricity generation, can make a significant contribution to the embodied water value, eg aluminium production. When expressed in terms of m3/t ore, the results for all metals considered indicated that the embodied water is roughly, on average, three times the water consumption of the mining and concentration stage. It was also shown that the economic value per m3 of water consumed for the minerals industry exceeds that for the agricultural and industrial sectors, supporting the view that allocating water resources to the minerals industry has a strong underlying economic basis. Water reforms currently taking place in Australia aim to address issues such as competition for water access, reduced security of supply and increase in cost. Consequently the minerals industry, along with others, can be expected to come under increasing pressure to reduce fresh or raw water use and to integrate water use across sectors. While water recycling is an obvious candidate to help reduce water consumption in the minerals industry, issues such as water quality, among others, will influence the extent to which this can be achieved. In addition, wastewater volumes can be minimised using techniques such as pinch analysis to establish and use the minimum water requirement for the process. The use of dry or near-dry processing technologies, for which the demand for water is small or zero, may be a more radical solution to the water consumption problem; however, it is possible that the introduction of dry processing would bring with it a new set of problems, including dust.

Jan 1, 2006

By Kwang-suk You

This paper describes the characteristics of electric arc furnace slag (EAF slag) as an aggregate of concrete along with the chemical composition, leaching concentration of heavy metals, the soundness of EAF slag and compressive strength of mortar with 20% and 50% replacements of sand. The results showed that leaching of heavy metals and soundness of EAF slag satisfied Korean environmental limit and Korean Industrial Standard for aggregates. The compressive strength of mortar increased as the replacement ratio of EAF slag for sand increased.

Jan 1, 2006

Accurate hematite solubility data are required to construct predictive solution chemistry models for complex hydrometallurgical solutions. These data are useful in understanding Fe(III) speciation and precipitation in a variety of hydrometallurgical processes. Hematite solubility data were generated in 10 to 70 g/L H2SO4 solutions and at temperatures from 130 to 270°C, using specially modified titanium autoclaves. These measurements represent an improvement over previous experimental data because of better in-situ filtration of the sample aliquots, the approach to equilibrium via hematite dissolution, and the inhibition of Fe(III) reduction on titanium surfaces. Fe(III) reduction was particularly studied to evaluate the inflationary effect of Fe(II) on hematite solubility measurements. Chromate was found to reliably inhibit Fe(III) reduction on titanium. Finally, the generated hematite solubility data were used to construct a solution chemistry model using the OLI software.

Jan 1, 2006

By N Slade, D Kennedy

Optimal throughput is a key objective for the successful operation of any manufacturing or processing business. In the mining industry in particular, in order to obtain maximum return on the significant capital investment in the physical assets involved, ensuring continuous throughput is a major focus for the complete leadership team. Failure to meet throughput objectives becomes a major source of distraction for management which too often attempts to solve shortfalls by æforcingÆ and æenforcingÆ production targets. This focus on the short term and the lack of attention to addressing root causes frustrates operators who attempt to satisfy unattainable short-term targets and lose sight of the long-term goal. Mount Isa Copper Operations, Xstrata Copper, North Queensland, had ambitious plans to increase throughput volume by ten per cent within a four month period to allow budgets to be achieved within the financial year. To achieve this, the process had to overcome the interplay of a multi-node (æsiloedÆ) production system and its associated inventories, each node, of which on the face of it at least, had more than enough ænameplateÆ capacity to meet these plans. However, the actual volume achieved at the end point of the system was well below this nameplate capacity and the system operated with an extraordinarily high standard deviation. The key issues in terms of making or exceeding plan were: how to substantially reduce the variability of the system and managing the inventories between nodes, how to synchronise throughput between the production nodes, and how to improve the decision-making ability within the process. In this paper, the implementation team has shown that a revolutionary process view of the operation together with appropriate planning decisions allowed increased throughput to be achieved without further capital investment.

Jan 1, 2006

By Georgene Renner, William R. Yernberg, Steve Kral

Agapito Associates (AAI) provides consulting services in geo-engineering, mining engineering and related disciplines. Founded in 1978, the firm operates out of offices in Grand Junction, CO, Golden, CO and Lombard, IL. Members of the staff include mining, civil and geological engineers, physicists, geologists, numerical analysts, computer specialists, instrumentation specialists, plus administration and technical support personnel. AAI has provided consulting and engineering services to mining companies producing base metals, precious metals, coal, potash, trona, limestone, oil shale and salt, and to defense and nuclear-waste disposal industries. AAI also provides services for measuring in situ horizontal stresses using an advanced biaxial overcore stress downhole measurement system developed by Sigra of Australia. Since 1978, AAI has measured in situ stress in copper, oil shale, molybdenum, trona, limestone and coal mines, and in tunnels and concrete structures. Since 1994, the staff has completed 527 overcore stress determinations. AAI has the equipment and personnel for overcoring, sample coring and instrumentation installation in limited access, surface and underground mines. Portable Longyear CP-65 drills, borehole deformation gauges and strain indicators are used for difficult-access overcoring and are permissible for use in gassy mines.

Jan 1, 2006