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By S. Neogy, M. Gupta, D. Srivastava, V. Kain, S. Roychowdhury, R. C. Prasad, G. K. Dey

"Austenitic stainless steels are an important material of construction for Boiling Water Reactors (BWR). These stainless steels are amenable to strengthening by strain hardening. Various deformation modes at different test temperatures and strain become active. In the present investigation type 304LN stainless steel was used in the annealed and strain hardened condition. Thin foils were prepared from gauge section for transmission electron microscope (TEM) investigation after tensile testing at room temperature and at 288°C. TEM investigation reveals that twinning is the major mode of deformation for the tests done at room temperature while dislocation cross-slip is the major mode of deformation at higher temperature. Stacking faults were also observed to a limited extent. The extent of twinning was much higher for the tests done using the rolled material. The formation of martensite in the stainless steel due to straining was investigated by the analysis of selected area diffraction patterns.IntroductionAustenitic stainless steels (type 300 series) are an important material of construction in Boiling Water Reactors (BWR). These stainless steels cannot be heat treated but can be strengthened by cold working [1]. Nitrogen alloying of these stainless steels result in high strain hardening rates and higher strength without any loss in toughness [1]. Stress Corrosion Cracking (SCC) in BWR of these types of stainless steels have been attributed to surface strain hardening and strain hardening ofregions adjacent to constrained weldment [2].The test temperature [3, 4], prestrain [5] and nitrogen level [5] has been reported to affect the deformation mechanism during tensile testing. Byun et al. [3] have reported the formation of martensite, dislocations, stacking faults and twinning during tensile deformation, the extent of each depending on the test temperature. Strain localisation has been reported to occur during tensile deformation in irradiated stainless steels [ 6]. The behaviour of rolled material during tensile testing is similar to that of irradiated material to a large extent [3]. Austenitic stainless steels are low stacking fault energy (SFE) materials in which various types of microstructures have been reported to form during tensile deformation and the strain is also highly heterogeneous in nature in these stainless steels which aides SCC in BWR environment to a large extent [7]. During cold working of austenitic stainless steels second order twinning has also been reported [8]. Knowledge about the deformation mechanisms operative in the strain hardened austenitic stainless steels during tensile testing at different temperatures is essential to understand the material deformation behavior and the present study aims at enhancing the existing understanding."

Jan 1, 2011

By Wang Jia, Chai Li-yuan, Zhang Jin-Long, Peng Bing, Zhang Qiang

"Electrolytic manganese dioxide (EMD) residue was mixed with shale and fly ash as the main materials to make solidification/sintering brick for the utilization of the residue from EMD production. The effects of sintering temperature, sintering time, solid waste content and cooling process on its mechanical properties and toxic elements solidification were investigated according to compressive strength and leaching toxicity. The results showed that the calcined residue had capability of solidifying toxic metals and exhibited perfect strength after treated in the optimal parameters of EMD residue below 50%, temperature at 1000-1100°C, time3-5h, and semi-quenched at 600°C1 InstructionSolid clay-brick holds the leading position among building materials for a very long time in China. The traditional technique of making clay-brick has the drawbacks of backward process, simple facilities and single product. Since Chinese Reform and Opening-up, urban-rural construction and real estate have been booming with the rapidly development of national economy and science technology. The problems of ruining fertile land, environment contamination and high energy consumption in the traditional technique of clay-brick making have not been solved yet. On the other hand, more than 7 billion tons of industrial wastes are accumulated over years which occupies over 6.7 million hectares filed and causes serious environmental problems[1-31. Strategy present in ""The Chinese Agenda of the 21st Century"" required the production of wall materials less energy conservation, land saving and waste recycling.Coal gangue[4-9l, fly ash[I0- 13l, sludge from waste water treatment and tailings of gypsum, pyrite, copper mine, high silicon containing iron, asbestos and ects [l4-lSJ are the solid wastes used for brick making around the world. There are two kinds of process for brick making, high temperature sintering and low temperature steam curing[19•201. Although the technology of two brick making made great progress and got widely application in construction field, no precedent for preparing sintering-bricks with EMD residue as materials occurred in China because of its complicated processing technics and lack of sufficient practical experience to guarantee the bricks' quality.In this study, EMD residue was mixed with shale and fly ash as the main materials to make solidification/sintering brick. The effects of sintering temperature, sintering time, solid waste content and cooling process on its mechanical properties and toxic elements solidification were investigated according to compressive strength and leaching toxicity."

Jan 1, 2011

By Joshua Hoffman, William Chad Wedding, Braden Lusk

The University of Kentucky employs an explosively driven shock tube in the course of experimentation. A good deal of the work completed relates to the verification of blast mitigation products and strategies. The work is dependent upon reliably reproducing specific pressure time histories called out by the test in question. The facilities are located in the workings of an underground limestone quarry in Georgetown Kentucky. As such, the temperature maintains fairly consistent 60°F (15.6°C), making it a comfortable work environment year round. Unfortunately, the relative humidity follows the prevailing weather conditions allowing a wide variation, especially between the winter and summer seasons. A study was undertaken to gauge the influence of relative humidity on shock wave generation, including the positive and negative phases of the wave.

Jan 1, 2011

By H. Mindivan

In the present study, the feasibility of recycling AA6061 Al alloy chips by a combination of ciyomilling, cold compaction and hot extrusion processes was investigated. Furthermore, the effect of Al powder addition to the recycled Al alloys chips on the mechanical properties was investigated. The characterization of recycled Al alloys was made by structural examination and mechanical tests (hardness, compression and dry sliding wear tests). The results indicated that by increasing wt. % of Al powder added to the recycled Al alloy chips the studied properties (the density, hardness, compressive strength and wear resistance) increased due to reduction of porosity in the recycled Al alloys.

Jan 1, 2011

By Ali Kahriman, Abdulkadir Karadogan, Alper Celtikci, Ahmet Varol, Ertugrul Kaya, Turgay Ozat

This paper presents analysis of environmental effects induced by cautious blasting during the construction of the Istanbul Subway 4 Levent - Ayazaga Darulsafaka Metro Tunnel Project carried out by the contractor, located at Northern Istanbul in Turkey. Within the scope of the study, for the prediction of the peak particle velocity and to determine the slope of the attenuation curves together with the maximum charge per delay for the S6-7-8 shafts of this tunnel route, ground vibration components were measured carefully by using five vibration monitors during the construction of the tunnels which required blasting. The particle velocities and frequency values of all blast events are evaluated according to the United States Bureau of Mines (USBM) and German DIN 4150 Norms in order to predict, and compare the influence grades to the neighboring buildings, and structures. Also, data pairs of scaled distance and peak particle velocity obtained from 107 records belong to 51 shots were analyzed statistically. Empirical relationships with correlation at the 95 % confidence interval were established for these tunnel excavations and suggested for the test sites in order to estimate particle velocity of the ground vibrations. As a result of the studies, some practical charts are created in order to minimize the psychological effects of the shots, and simplify the authorities of shots’ job. And last but not least, make sure that the shots will be done in a controlled way.

Jan 1, 2011

By Takashi Sasaoka

EGAT Mae Moh Lignite Mine in Thailand produces about 16 million tons of lignite annually from open-cut mining. The coal is used to generate 2,400 MW of electricity. In the near future, however, the coal must be extracted from underground at 400? 500 m (1,312?1,640 ft) deep from the surface. The problem is the thickness of the coal seams. There are two coal seams that are about 25 m (82 ft) thick with 20?25 m (66?82 ft) of interburden between them. Up to now, many mining systems for thick coal seams have been used and improved in the world. However, where the thickness of coal seams is beyond the limitation of the current mining technology and system, an applicable mining system has to be introduced, considering influencing factors such as caving and subsidence. In order to investigate thick seam mining systems and propose a new mining system in ultra-thick coal seams in Thailand, a joint research group was established by Japanese and Thai researchers and mining engineers in early2009. This paper describes underground mining systems for thick coal seams and proposes an innovative underground mining system for thick coal seam, ?eco-friendly underground mining system?, considering geological, geotechnical, and environmental conditions in this mine. This paper discusses its applicability to this mine by means of numerical analysis from the geotechnical point of view.

Jan 1, 2011

By A. L. Martikainen

In fluctuating airflow, continuous air velocity recording is the most reliable method of air velocity measurement. It allows for fast recognition of changes and the calculation of long-term averages. Also, it enables the mine operator to identify when the airflow has decreased to a point requiring action. Using ultrasonic anemometers provides an accurate option for continuous air velocity monitoring. This paper provides information about the effect of common obstructions in underground mining on air velocity readings. Stationary and moving obstructions are used to represent workers and equipment that would cause discrepancies in measured airflow. Also, it is important to know how large of a sample size is required to ensure reasonable accuracy of results. Statistical analysis is used to evaluate the required sample size. The sampling procedure is further studied by comparing two different sample rates. The results show that obstructions provide noticeable differences in air velocity measurements. Also, movement of obstructions can be recognized from changes in results. Surprisingly small sample sizes provide reliable air velocity information. Standard sample rates are found to be suitable for the underground environment.

Jan 1, 2011

By M. Abdellatif

Keywords: Pyrometallurgy, furnace, DC arc furnace, smelting, silicon The technical feasibility of silicon smelting in a DC arc furnace was investigated. A graphite-lined furnace was operated at power levels of 150 to 160 kW, and 40 to 60 V. The average feed rate during the silicon production period was about 30 kg/h. The recipe consisted of pre-mixed batches of 28% petroleum coke and 72% lumpy silica. The target furnace operating temperature was set at 1600°C and then raised to 1700°C. In total, about 1.6 tons of premixed feed materials was processed over 16 feeding?tapping operations. The feed was manually charged into the furnace in sub-batches of 10 to 40 kg at a time. The total batch mass was set at 90 kg during the initial part of the testwork, and increased to about 120 kg for the rest of the campaign.

Jan 1, 2011

By J. A. Botín

Identifying, quantifying and minimizing technical risks associated to investment decisions is a key challenge for the minerals industry decision takers and investors. However, risk analysis in most bankable mine feasibility studies are based on stochastic modelling of project NPV which, in most cases, fail to provide decision makers with a truly comprehensive analysis of risks associated to technical and management uncertainty and, as the result, are of little use for risk management and project optimization. This paper presents a value-chain risk management approach where project risk is evaluated for each step of the project lifecycle, from exploration to mine closure, and risk management is performed as part of a stepwise value added optimization process.

Jan 1, 2011

By S. Cotten

The regulations for current coal mine refuge alternative (RAs) require that there be sufficient life support to sustain survival of the maximum number of RA occupants for a minimum of 96 hours. This minimum duration assumes that rescuers can access the RA through the mine within four (4) days of the onset of the mine emergency. But what if mine rescue teams cannot reach the miners within the RA before the RA air supply is severely limited or exhausted? What could be done to extend the duration of the RA life support capability into the 97th hour and beyond? In addition, what might be done to enable more rapid rescue of the miners if they could not be reached through the mine in a timely manner? This paper describes a systems approach to address the potential need to extend the duration of RA life support beyond current design limits. New capabilities that need to be developed in advance of such a dire need include more reliable emergency communications, highly mobile and efficient drilling rigs, enhanced directional drilling techniques, and a standardized RA external life support interface along with RA internal design modifications to accommodate use of an external supply. The following sections describe the need, intent, and technology gaps associated with each of these capabilities. Government agencies and the mining industry should consider initiation of a program to investigate, design, and develop effective means of extending the current 96-hour time restriction on coal mine refuge alternative life support. The development process should begin with a focused study to refine the overall operational concept, investigate the current state-of-the art of critical technologies, identify specific technology development priorities, and make recommendations for a development program to provide in an organized, efficient, and timely manner a solution for extended refuge alternative life support and occupant rescue.

Jan 1, 2011

By Mim Li, Huimin Lu, Lisha Yang

"CuInS2 thin films solar cells have drawn much attention for their low-cost, stability and high conversion efficiency. The electrodeposition of Cu-In precursor films, as the first step in making CuinS2 solar cells electrochemically in the air-and water-stable ionic liquid based on choline chloride/urea eutectic mixture has been investigated at constant potential. Compared with aqueous electrolytes, the large electrochemical window as well as the high thermal stability of this ionic liquid allow the direct electrodeposition of Cu-In precursor films. Then the precursor films were sulfuretted in a tube furnace at different sulfurization temperatures to optimize the films properties. The films obtained were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS).IntroductionCuInS2 is one of the most prospective absorber materials for low cost thin film solar cells, with a high conversion efficiency that exceeds 32% in terms of theory and nearly 13% in laboratory level [1-2]. In addition to its long-term stability, CuinS2 has a band gap energy Eg ranging from 1.3 to 1.55 eV and an optimal optical absorption coefficient reaching 105cm-1 [3-4]. CuinS2 thin films have been prepared by several methods such as spray pyrolysis [5-6], r.f.sputtering [7], vacuum evaporation [8-9] and electrodeposition. Comparing with vacuum methods, electrodeposition has lots of advantages such as less energy consumption, preparation big area thin film, stable system and enabling cheaper films.The electrodeposition of most technologically important metals has been shown to be possible from a wide range of ionic liquids. These ionic liquids are currently applied in a wide variety area. It is reported that the cell efficiency of chalcopyrite absorber layer (CIS, CISeS, and CIGS) via an electrodeposition route in laboratory condition has reached 11.3% [10]. Copper and indium alloy film is regarded as important precursor for the production of compound semiconductors with sulfur. The electrodeposition of the alloy film from room temperature ionic liquid (RTIL) has not been widely investigated. Only few alloy films, such as ZnTe, CdTe, GaAs and AlSb have been electrodeposited."

Jan 1, 2011

By L. Andrews

Keywords: mineralogy, phase-chemical, chemical-looping combustion, XRD, SEM, EDS, QEMSCAN, PGM, slag, matte, ilmenite Mineralogy, traditionally associated with concentrator studies, is being increasingly applied to problems in pyrometallurgy. Such investigations commonly make use of a number of techniques, and the results are combined for a meaningful interpretation, which can lead to a successful solution. Mineralogical applications are described from pyrometallurgical operations. Examples are given of studies and investigations involving mineralogy in chemical-looping combustion, feed monitoring to platinum-smelting furnaces, and losses to slag in base metal and platinum smelting.

Jan 1, 2011

By M. Götze, P. Eysel

Over the last years, the importance of the assessment of environmental and social aspects as well as of issues of good governance has increased significantly in mining finance. For this, international standards as well as internal guidelines of the banks and other involved institutions have been established and continuously improved. Considering these standards and regulations, the banks can influence the sustainability of mining projects - and they have done so in the past -, mainly by implementing certain provisions and covenants in the loan documentation, binding the financing to the mining company’s adherence to the agreed sustainability standards. However, there are limits to the banks’ influence due to the competitive environment with other available means of financing. Nevertheless, the experience of the last years has shown that the standards and regulations bound to the financing by the banks help to lead the mining industry towards more sustainable projects.

Jan 1, 2011

By D. J. Gilbert

As a preventive action, the geotechnical department at the mine analyzed the original topography overlying a conveyor tunnel at the mine. Several dewatering drains were installed to intercept water collecting from an old lakebed. Subsequently, 20 steel arches were installed to provide additional support in an area of tunnel where original geological mapping indicated Type IV rock. This project was completed ontime with no loss to production. Construction schedules had to be developed to half hour precision, to accommodate the installation.

Jan 1, 2011

By R. Benito

This paper describes the development of a life-of-mine schedule (LOM) for one of the world's largest known sedimentary copper-cobalt districts located in the Katanga Province, Democratic Republic of Congo (DRC). A particular feature of the Tenke Fungurume LOM schedule is the considerable number of pits/phases for scheduling, each competing to provide the best ore available to a capacity-constrained process facility. This paper discusses the LOM scheduling objectives and constraints, data preprocessing steps such as ore binning, block aggregation and clustering analysis as a scheduling aid, the mine scheduling approach and results and conclusions. Mining Engineering, 2011, Vol. 63, No. 8, pp. 39-47. Official publication of the Society for Mining, Metallurgy and Exploration, Inc.

Jan 1, 2011

By Josef K. Alter

Crosshole Sonic Logging (CSL) of drilled shafts requires 1.5-in (38-mm) or 2-in (51-mm) I.D. sonic access tubes to be installed inside the steel reinforcement cage. The sonic access tubes do not contribute to the structural capacity of the drilled shaft. The proposed use of Ischebeck TITAN T73/56 CSL/Hollow Threaded Rebar for Cross Hole Sonic Logging Access Tubes Combined with Longitudinal Concrete Reinforcing in Drilled Shafts (patent pending) is discussed as an alternative method of construction and CSL probe access. The T73/56 hollow threaded rebar/sonic access tube performs as a high strength rebar while at the same time creating a 2.2-in (56-mm) I.D. sonic access tube. The deformed high strength hollow bar provides better adhesion to concrete thus reducing the problem of debonding associated with smooth PVC and steel pipe. A cost comparison using conventional rebar with added sonic access tubes is discussed. The use of T73/56 CSL/Hollow Threaded Rebar as a value engineering alternative can reduce both material and labor costs for drilled shaft construction and can provide an advantage where anchor bolt cages and longitudinal reinforcing create congestion.

Jan 1, 2011

By William Gleason

While a fleet of 100 t (110 st) haul trucks were busy removing overburden from the open pit mine in the distance, a host of dignitaries, including congressmen and California state representatives, gathered for Molycorp?s official groundbreaking ceremony at the Mountain Pass Mine on April 20. The mine, recognized as arguably one of the richest rare earths deposits in the world, is at the center of Molycorps? strategic ?Mine to Magnets? plan. It aims to secure America?s future supply of rare-earth-dependent technologies by developing a strong domestic rare earth industry. Molycorp identifies rare-earth-dependent technologies as those that cannot be produced without rare earth materials. The list of these technologies is long and growing. It encompasses everything from personal electronics and batteries for hybrid cars to permanent magnet generator wind turbines and national defense applications.

Jan 1, 2011

By K. Liddell

Current practice for the recovery of platinum group metals (PGM) from flotation concentrates is by energy-intensive smelting processes followed by separation and refining of the base and precious metals. Energy costs are rapidly increasing in South Africa and this trend is forecast to continue in future years. Moreover, the smelting operations are highly susceptible to deleterious constituents, particularly chromite; and the increasing tonnages of UG2 chromititic ore being mined results in an increasing chromite content of smelter feeds. Hence there is a substantial incentive to assess and implement alternative processes to smelting for the treatment of PGM concentrates. The Kell process is a patented hydrometallurgical alternative to smelting that is totally insensitive to the chromite content of the feed concentrate and comprises three commercially proven unit operations (pressure oxidation leaching of base metals and sulfur, roasting and chlorination of precious metals). The Kell process provides the opportunity for existing and new PGM producers to significantly reduce their energy consumption, and in particular their consumption of electricity, by removing the need to smelt PGM concentrates. Energy costs, greenhouse gas emissions and installed power requirements are also much reduced. Compared with smelting and refining these reductions are calculated as: ? Total energy consumption-50% reduction ? Electrical energy consumption-84% reduction ? Energy consumption costs-76% reduction ? C02 emissions-70% reduction ? Installed power requirement 92% reduction. The data obtained from simple laboratory batch amenability testing can be readily applied to the Simulus mass and energy balance simulation procedure to determine energy and reagent consumptions, equipment selection and process optimization. The applicability of Kell to treating low-grade 'dirty' concentrates with high UG2 content as well as to polymetallic concentrates containing base metals as the major payable metals with subordinate PGM means that these savings can also be expected when the process is used for treating a range of concentrate types and grades. Keywords PGM,UG2, Merensky, smelting, chromite, electricity, hydrometallurgy, Kell Process, Eskom.

Jan 1, 2011

By Allen Chung, John Twomey, Christopher J. Greet

"It is widely accepted that the type of grinding media has an impact on the grinding chemistry and subsequent flotation behaviour of the sulphide minerals being separated. There are countless laboratory investigations demonstrating that inert grinding media produces more oxidising pulp potentials, reduced levels of grinding media corrosion products and superior concentrate grades and valuable metal recoveries. However, taking these results to industrial scale has proven difficult.Work conducted at the Ernest Henry Mine, in north western Queensland, Australia, at laboratory and pilot plant scale clearly indicated that using a high chrome grinding media resulted in significant improvements in both copper and gold recoveries. However, advancing this work to plant trial represented considerable financial and technical risk to the mine.This paper provides details of the protocol developed and used during the high chrome grinding media plant trial. It describes the test regime employed to measure changes in pulp chemistry, and the statistical methodology utilised to interpret the results. The work also highlighted the need for close cooperation between the metallurgists on site and the researchers conducting the trial.To date, the trial has produced excellent results: indicating that the copper recovery has improved by about 2 percent. The successful application of high chrome grinding media to the Ernest Henry ore has increased metal value by $18.7 million USD per annum based on current spot price for copper.INTRODUCTIONTheoryThe application of electrochemically inert grinding media to mineral systems has been extensively studied (Table 1). Broadly, these studies indicate that most sulphide minerals are more noble than the grinding media used during comminution. Therefore, the sulphide minerals are cathodic with respect to the forged steel grinding media, and the following reactions apply:"

Jan 1, 2011

By Ambrose Buchanan, Rob Farnfield, Charles Adcock

Beginning on 7th September 1940 the City of London was subjected to 57 consecutive days of bombing in what became known as the ‘London Blitz’. To commemorate the 70th anniversary of this event a television series was commissioned that required the open detonation of World War 2 equivalent bombs close to purpose built structures constructed using period design and materials. The structures were built on a remote test facility in the North of England that is able to fire large quantities of explosive in the air.

Jan 1, 2011