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By Mariane Costalonga de Aguiar, Carlos Mauricio Fontes Vieira, Sergio Neves Monteiro

"This work evaluates the effect of incorporation of an ornamental rock waste into an industrial clayey body used for roofing tiles fabrication. Formulations with 0, 10, 20 and 30 wt.% of waste were prepared by replacing the sand in the industrial clayey body. The plasticity of the formulations was determined by the Atterberg limits. Specimens were fabricated by 18 MPa press-molding and then fired from 850, 950 and 1050°C. The specimens were tested to determine the water absorption, linear shrinkage and three points bending flexural strength. The results indicated that the waste improves the extrusion performance of the clayey body by decreasing its plasticity. The use of the waste was beneficial to the water absorption and mechanical strength of the fired clayey ceramic at 1050°C.IntroductionOrnamental rock is a natural resource available in the municipal area of Santo Antonio de Padua and located 150 km from the city of Campos dos Goytacazes, northe of state of Rio de Janeiro, Brazil. Intense industrial activity related to ornamental stones, especially gneisses, is traditionally occurring in the region. After mining, the flagstone is submitted to sawing to obtain blocks and then, after a manual operation, the final products are small flagstones [1,2]. During the sawing operation, a sludge composed of water and fine particles of rock is generated. A monthly production of 1000 tons of ornamental rock waste is estimated to be produced at Santo Antonio de Padua. The final disposal of this waste has brought serious environmental problems. Since most industries do not have an adequate sludge treatment, the waste is contaminating the soil and underground waters as well as obstructing rivers and lakes.Ceramic bodies industrially fabricated in the municipal area of Campos dos Goytacazes, 280 km from the city of Rio de Janeiro, are still empirically elaborated using a mixture of local clays. These clays are predominantly kaolinitic mineral, associated with high plasticity. Due to the excessive plasticity of the ceramic bodies, it is common to have dimensional defects in the final products after the drying and firing processes. Moreover, the kaolinitic structure and the presence of aluminum hydroxide confer a refractory behavior to the local clays. This impairs sintering during the firing operation. In the case of clay ceramics for civil construction, this results in greater porosity associated with elevated values of water absorption [3,4]. To avoid this problem, it is necessary to reformulate the ceramic body composition. The addition of both non-plastic materials to reduce plasticity and fluxes to condition the refractoriness is a possible alternative."

Jan 1, 2011

By K. Hiroto, H. Tamamoto, G. J. Kusuma

"Acid mine drainage (AMD) has become a serious environmental problem in the mining industry in the last decade. Many efforts have been made in an attempt to find a better method to manage this problem in a proper manner, both through prevention and mitigation. One of the methods to prevent AMD generation is a dry dump cover system that has been proposed to minimize oxidation of sulphide waste rock in dumping sites. The performance of this system depends on the physical and geochemical stability of a barrier layer to minimize water and oxygen influx. In the mining industry, this barrier layer is formed by using Inert/Non Acid Forming (NAF) waste rocks to cover Potentially Acid Forming (PAF) underneath. However, the availability of NAF waste rocks, due to the geological condition, mining sequence and capability of equipment, is limited in some mines. This paper will discuss the acid generation mechanism, application of a cover system and its problem being faced in an Indonesian coal mine, and describe a preliminary laboratory result of a multi layer cover system in an attempt to overcome this problem."

Jan 1, 2011

By Chris Castle

The Chatham Rise is a submarine topographic feature lying off the east coast of New Zealand between the South Island and the Chatham Islands and within New Zealand?s jurisdiction. The Chatham Rise hosts economically significant deposits of rock phosphate and other potentially valuable minerals. The deposits comprise nodules lying on, or just below the surface of the seabed in shallow waters. Rock phosphate is an essential ingredient of fertilizer and can be applied directly to pasture. There is a realistic opportunity the phosphate deposits could supply New Zealand?s agricultural requirements for an estimated 30-year period at current rates of consumption.

Jan 1, 2011

By C. Machio

This paper reports the results of a study to determine the effect of process control agent (PCA) on the characteristics of Ti-Mg powders during milling. It has been shown that a 2% increase in PCA content leads to up to a 40% increase in yield of the milled powder but reduces the kinetics of the mechanical alloying process. The introduction of 4% PCA decreases the mean powder particle size by up to 30%, whereas 6% PCA increases the mean particle size by up to 230%. The characteristics of the milled powders will be discussed in relation to the role of PCA in the milling process. Keywords Titanium?magnesium, mechanical alloying, PCA.

Jan 1, 2011

By Virginie Tilot

Recommendations have been drafted following an international multidisciplinary panel discussion organized at UNESCO/IOC by the Académie des Sciences d?Outre-Mer on 15 December 2010 conveyed, according to its mandate, to the French government and to an international pool of scientists and stakeholders. These take into consideration the relevant Provisions of the United Nations Convention on the Law of the Sea of 10 December 1982, the Rio ?Earth Summit? Convention of Biological Diversity of 5 June 1992 as well as the activities and recommendations implemented for the world?s oceans and seas, in particular by the International Seabed Authority (ISA) and the recent reports and scientific works (including those implemented by the ISA Kaplan, Ifremer, COI-Unesco). The recommendations integrate, for one of the ecosystems, the conclusions of the project of the conclusions of an IOC-UNESCO / Government of Flanders project (2004-2010) implemented by Dr. V. Tilot from 2004 to 2010, during which were published three volumes describing the referential state of the polymetallic nodule ecosystem and proposing options for the management and conservation of the nodule ecosystem in the Clarion Clipperton Fracture Zone, NE Pacific Ocean: http://unesdoc.unesco.org/images/0014/001495/149556f.pdf, http://unesdoc.unesco.org/images/0014/001495/149556e.pdf; http://unesdoc.unesco.org/images/0014/001495/149556e.pdf#223

Jan 1, 2011

A methodology has been developed and demonstrated to be effective in reclaiming surface-mined land for a forestry post-mining land use. The Forestry Reclamation Approach (FRA) has been applied, almost exclusively, to flat or gently rolling surfaces. One of the primary steps in the FRA is to loosely grade the top 1.22-m (4-ft) of soil or substitute root growth medium to avoid excessive compaction. Concern has been expressed by regulators and the public that loose grading on steep slopes could lead to slope failures, which is one of the issues that SMCRA sought to correct. A field investigation was conducted at a steep-slope contour operation in eastern Kentucky to test the applicability of FRA in this setting. Final grading was performed according to FRA standards. The surface consisted of two distinct substitute rooting media. One was unweathered gray sandstone and the other was a combination of gray sandstone, brown sandstone, and topsoil. A variety of native hardwoods was planted following the FRA guidelines. The slope was instrumented with 70 survey monuments to monitor for mass movement. The reclaimed spoil was also characterized using bulk density and penetrometer resistance methods. The characteristics of both spoils are similar to those observed on flat to rolling surfaces where the FRA has been used and, after one year, approximately 70% of the trees had survived. There has been no major mass movement of the slope and slope stability analyses indicate that the application of the FRA has little impact on the overall stability of the slope.

Jan 1, 2011

By S. L. George

The semi-solid metal casting process results in a unique solidification path. The microstructural features that were identified during the characterization of the as-cast microstructure, were used as evidence of the process history in order to determine the solidification path followed during the evolution of the microstructure. The morphology of the grains was characterized using SEM and the extent and distribution of the elemental segregation within the grain structure was analysed using EDS. Keywords Semi-solid casting, solidification path, segregation.

Jan 1, 2011

By R Yang, M Lownds

This paper reports studies showing the effects of delay scatter on the peak particle velocity (PPV) of blast vibration using a multiple seed wave (MSW) vibration model developed in recent years. The case studies also show the advantage of accurate delay timing on frequency control of blast vibration. The site parameters used in one of the studies are from a case in which the MSW model has been tested and confirmed to yield accurate predictions. This study uses an open pit blast design and a tunnel design in which blast vibrations using electronic detonators are compared with those from pyrotechnic detonators. Mean peak particle velocity (PPV) and the 97.5% upper bound PPV are compared. It is found that both these values increase significantly with the increase of the coefficient of variation of the site parameter. Using an open pit blast design, the modeling shows that electronic initiation shifts vibration energy to the expected frequency for a selected point of interest. However, for the same design of nominal initiation timing pyrotechnic detonators fail to shift vibration to the expected frequency due to its large scatter of timing.

Jan 1, 2011

By R. Lawrence

Mineral property valuations to be used for Canadian securities regulatory purposes must comply with CIMVal1. The technical basis for a CIMVal report is the same as that required for a technical report that complies with NI 43-1012. NI 43-101 describes the content to be covered in a technical report, while also covering other requirements, one of which is that the report should be based on a property visit. CIMVal is based on five tenets that the valuator must follow: ? Materiality. ? Independence. ? Transparency. ? Competence. ? Reasonableness. Upon its adoption by CIM Council in 2003, it was hoped that the new CIMVal code would be adopted without change by the several Canadian regulators.

Jan 1, 2011

By L. Hacini

The start-up is the most critical phase of the cell life, as an uncontrolled start-up could lead to early infiltrations, instabilities, and in some cases to the cell death. Lots of efforts are put to increase the lifespan of cells, as it has a major impact on both the operating costs and the environmental footprint of the aluminum industry. Obviously, a true size test on a cell is a resources- and time-consuming approach that could be used only to validate mature concepts. Moreover, numerical modelling is a low-cost and versatile tool capable to test a wide range of potential ideas and concepts. In the present article, a thermal electrical mechanical slice model is presented. This model describes the preheating and bath periods of a P155 aluminum cell start-up, as used at the Grande Baie smelter. The impact of sodium diffusion and expansion is also included in the model. This model will be useful to study different problematical issues such as the global behaviour of lining materials, shell and cradle deformations during start-up and several start-up scenarios. Such a model will also be able to answer some interrogations regarding early infiltrations and their impact on the lifespan of the electrolysis cell.

Jan 1, 2011

By Jorge A. S. Tenorio, Chuanwei Zhuo, Joner O. Alves, Yiannis A. Levendis

"The ever increasing number of automobiles and the consequential increase in consumption of tires have generated a pressing environmental issue, concerning the disposal of unserviceable tires. The worldwide disposed of waste tires is approximately 1 billion units per year and this amount is expected to increase by 2% each year. This work presents a microstructural characterization of nanomaterials synthesized in a catalyst system from the effluent of burning waste tire chips in a horizontal two-stage laminar-flow furnace. Controlled combustion of waste tire chips took place at temperatures of 900 or 1000 °C, and stainless steel meshes were used to synthesize the nanomaterials at 1000°C. Produced materials were analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The catalyst meshes were covered by materials with diameters of 20 to 200 nm and lengths of about 40 µm. They possessed structures similar to those of carbon nanotubes.IntroductionThe motor vehicles on the road have been increasing annually. World motor vehicle production in 2009 approached 62 million units. Consequently, the consumption of tires has also been on the rise; about 1.4 billion units were produced around the world in 2007 [l]. The disposal of scrap tires is a serious environmental problem. The worldwide disposed of waste tires is almost 1 billion units per year with an expected increase of around 2% each year. However, less than 7% of produced waste tires are recycled (excluding reuse, retreading or incineration). The waste rubber tires are a thermoset polymer, which cannot be reprocessed like thermoplastics polymers, therefore the recycling of this material requires special techniques that demand big investments [2, 3].A solution to the disposal of waste tires is the sequential pyrolysis/combustion process. Past research showed that waste tires are an attractive potential fuel due the high heating value (29-3 7 MJ/kg), which is comparable, or even higher to those of typical bituminous coals [ 4, 5]. Pyrolysis is a process wherein the material is thermally decomposed at elevated temperatures at the absence of an oxidizing gas. Combustion is characterized by the addition of the oxidizing gases during the process. Several studies indicate that the pyrolysis and combustion processes for the tires treatment have a great energy conversion potential [4, 5, 6]."

Jan 1, 2011

By T. R. Ellis

Minerals Appraisers/Valuers often find great difficulty or failure in attempting to employ the Sales Comparison Approach to the Market Value Appraisal of development and operating stage mineral properties. An important factor generally overlooked is a comparison of net operating income (NOI) margins on a per-unit-of-production basis between mineral properties, whether these be demonstrated or forecast margins. NOI margins can vary greatly between mines or quarries that are producing similar products. Ultimately, the expected NOI margin determines what a buyer is willing to pay for an income producing property. Common criticisms of the sales comparison approach by minerals appraisers are introduced. These are counterbalanced by raising some issues in the way the inputs for the Income Approach are usually derived by minerals appraisers, and by review of some conspicuous examples of the much too common misuse or abuse of the income approach in market value minerals appraisals. Example transaction analyses and sales comparison analyses are used to demonstrate the author?s methodology for adjusting units of resource in his transaction adjustment tables (see APPENDIX). The examples are used as the basis for discussion of ways to employ adjustments for operating economics and many other factors, while cautioning about the potential for double counting. The conclusions include a recommendation that minerals appraisers attempt to apply at least two of the three valuation approaches when appraising the market or fair value of development and operating stage mineral properties, the two being the sales comparison and income approaches.

Jan 1, 2011

By B. A. Osei

Research to evaluate possible metrics for predicting dredgeability of compact aggregates, by hydraulically actuated clamshell dredges, shows work done by the pistons as a viable metric. Analysis of field data shows that there is a low, positive, correlation between cycle time (CT) and work done. If this correlation exists, then CT has to be considered an independent variable affecting work done during dredgeability assessment. Further research is required to elucidate the relationship between CT and work done during dredging. The objective of this paper is to test the hypothesis that work done during dredging increases with increasing CT. Kinematics and dynamics of the hydraulic clamshell were modeled and implemented in Simulink® in MATLAB. The model was validated using field data. The model was then used to test the research hypothesis. The results show that work done increases with increasing CT. This work confirms that work done during dredging increases with increasing CT. This result indicates that though an operator can increase the CT to deal with difficult digging, inputting unduly high CTs results in higher energy consumption during dredging.

Jan 1, 2011

By D. Boshoff

The ability of an explosive to break rock is influenced considerably by the extent of confinement in the blasthole. It is believed that confinement is improved by the use of adequate stemming. The aim of this paper is to present the results of the first and second stages of developing a stemming performance testing rig for small diameter boreholes. The rig was used to compare and contrast the performance of different designs of products. The results showed that different stemming products have differences in terms of their functionality, which can have a major impact on the efficiency of rock breaking. Two test procedures were used, one through the exclusive use of compressed air and the second using a purpose-built high pressure test rig with small quantities of explosives. Both tests were used to identify and evaluate the ability of various stemming products to resist the escape of explosive gas through the collar of a blasthole. An investigation was done to determine the types of stemming products most commonly used in South African underground hard rock mines, and these products were used during the tests. The first stage of tests using compressed air only did not prove adequate to predict with certainty the pressure behaviour in the borehole of a particular product under high pressure conditions. The purpose-built high pressure test rig also did not prove to be a very effective tool to test stemming products under high pressure conditions. The test rig incorporated only the effect of gas pressure on the stemming product, and excluded the effect of the shock wave. This study therefore proved that to take into account only the gas pressure generated in the blasthole is not sufficient to effectively test stemming product performance.

Jan 1, 2011

By Lijun Liu, Yingwei Li, Jianhua Liu, Jinhui Peng

"As essential equipment in the metallurgical industry, current air heat exchangers cannot meet the requirements of high temperature heat transfer. In this paper, an energy efficient air heat exchanger, based on accumulation of the heat generated by microwave absorbing materials, is presented according to heat transfer theory and principles of the microwave field. A tubular shaped heat exchanger was designed and built up through temperature-rising curve, and experimental research of microwave high-temperature air heat exchangers was carried out. It was found from experiments that the tubular shaped heat exchanger fabricated using material B could be used for high temperature heat transfer system, and equilibrium temperatures could reach up to 457—485?.IntroductionHeating or cooling of air by heat exchangers is commonly practiced in a wide range of industries including construction, chemical, machinery, textile, printing, and dyeing [1-3]. Generally such heating or cooling of air is achieved in pipe heat exchangers. There are several drawbacks for such heat exchangers, namely, (i) the limitation of temperature to which the pipes can be heated, (ii) tendency to oxidize at high temperature, and (iii) poor strength of metallic pipes at high temperature. These limitations do not allow pipe heat exchangers to be operated at high temperatures [4-6].Microwave heating of inert solids, which are stable at high temperature, is a possible solution to achieve high temperature of the medium in air heat exchangers. It is well-known that microwave heating is an efficient, clean, safe, easy-to-control heating method. Microwave heating utilizes the dielectric and magnetic properties of a material. When microwaves penetrate and spread into the dielectric material, electrons, ions, etc move in the internal electromagnetic field, while the elasticity of inertia and friction impede these movements. This results in a significant thermal effect, increasing the surface temperature rapidly [7-8]. This paper studies mainly design and experimental research of microwave high-temperature air heat exchanger."

Jan 1, 2011

Clark volcano is a large volcanic center on the active arc front of the intraoceanic Kermadec arc. It is one of the two southern-most Kermadec arc volcanoes (the other being Whakatane volcano) that sits on oceanic crust before the transition to continental New Zealand, and is underlain by the 17-km-thick Hikurangi Plateau, which is presently subducting beneath the southern section of the Kermadec arc. Unusual K-rich basaltic lavas have been recovered from Clark (1.5 to 2.25 wt.% K2O), together with more typical basaltic-andesite, andesite and dacite rocks. The total volume of the Clark volcanic center is ~90 km3, calculated from the summit of the volcano down to the 2,500 m contour (which marks the inflection point of the volcano flanks with the surrounding seafloor) and comprises two separate edifices similar in size; the northern one having a volume of ~4.57 km3 and the southern one 4.43 km3. The volcano has a maximum relief of ~1,645 m from the 2,500 m contour to the summit of the shallower northern edifice shoaling to 855 m below sea level. The northern edifice is comprised of twin peaks each consisting of a constructional cone, with evidence of sector collapse having occurred between the cones. A more recent, smaller cone again has grown on the eastern flank between these summit cones. Massive, blocky lavas and coarse talus dominate the summits of the cones, with finer-grained volcaniclastic material and sediments a feature of the volcano flanks. The southern edifice is noticeably more dissected than the northern one, having a pronounced horst in the centre of the volcano bounded by 5-6 km-long faults. There is no obvious constructional cone atop the southern volcanic edifice.

Jan 1, 2011

By E. Latorre, T. S. Golosinski

ABSTRACT; his paper proposes new methodology to define the pit limits that yield the maximum net present value (NPV) for a deposit, under a given economic scenario and for a given discount rate. The method uses an algorithm that combines dynamic programming and heuristics. It was tested for evaluating deposits with different sizes and various grade distributions. For the discount rate of zero, the results confirm that the economic pit limits are the same as that defined using Lerchs Grossman method. However, when discount rates higher than zero are used, the pit limits differ, yielding a higher NPV.

Jan 1, 2011

By Masatsugu Morimitsu

This paper introduces new technology of oxygen evolution anodes which can be applied to produce copper, zinc, cobalt, and other metals by electrowinning. The anode consists of nano iridium oxide particles dispersed in amorphous tantalum oxide matrix as a catalytic layer formed on a titanium substrate. The anode can reduce oxygen evolution potential by 0.25 to 0.55 V compared to commercially available lead alloy anodes and can suppress unwanted side reactions such as manganese oxyhydroxide, lead oxide, cobalt oxyhydroxide which occur during oxygen evolution in the electrowinning solutions. This technology is effective for environmentally friendly electrowinning processes with low energy consumption and less anodic deposition.

Jan 1, 2011

By B. Anameric

Considerable effort has been directed towards understanding the carbothermic reduction mechanisms of self-reducing, fluxing dried green balls to produce pig iron nuggets. Given the geometry of the situation, some investigators believed that the shrinking core model was applicable. Hence, this study involved investigation of the applicability of the shrinking core model to pig iron nugget production. The experiments involved heat treatment of dried green balls utilizing either a laboratory-scale resistance box furnace or a gas-fired muffle furnace at various furnace temperatures and residence times. The products were analyzed for the following: (i) preferred reaction pattern, (ii) distribution of the metallized areas, (iii) % iron content variation in the pig iron nuggets from surface to center, (iv) carburization pattern and (v) physical and chemical properties of the pig iron nuggets. It was determined that the reduction of iron oxide occurred simultaneously throughout the sample and not beginning at the surface and propagating inward; thus the shrinking-core model was not applicable. Heat transfer and gas diffusion from surface to center were not the rate-limiting steps for reduction and carburization reactions.

Jan 1, 2011

By Tetsuo Yamazaki

Seafloor massive sulfides (SMS) in the western Pacific have received much attention as resources for gold, silver, copper, zinc, and lead (Lenoble, 2000). Since the end of the 1980s, SMS have been found in the back-arc basin and on oceanic island-arc areas. The typical representatives found are in the Okinawa Trough and on the Izu-Ogasawara Arc near Japan (Halbach et al., 1989; Iizasa et al., 1999), in the Lau Basin and the North Fiji Basin near Fiji (Fouquet et al., 1991; Bendel et al., 1993), and in the East Manus Basin near Papua New Guinea (PNG) (Kia and Lasark, 1999). The higher gold, silver, and copper contents in one of the areas increased the chance for profitable mining operation, which was considered by a private company (Malnic, 2001). The company gathered investment money and announced to start the commercial mining from 2010 (www.nautilusminerals.com). On the basis of geological information of the Sunrise Deposit of the Myojin Knoll on the Izu-Ogasawara Arc (Iizasa et al., 1999) and geotechnical characteristics of SMS (Yamazaki and Park, 2003), some preliminary economic validation analyses of the SMS mining in small production scale were reported by one of the authors (Yamazaki et al., 2003; Yamazaki and Park, 2005; Yamazaki, 2007). The results showed high profitability of the SMS mining.

Jan 1, 2011