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By Amy Nelson

In the electrolytic production of zinc, cobalt is removed from the zinc electrolyte by cementation with zinc dust prior to electrowinning. Although the thermodynamics for this reaction are favourable, kinetic barriers to cobalt reduction render the method almost useless in practice unless activators such as copper and antimony or arsenic are added. There is a large body of work studying the effect of these additives, yet the mechanism by which they act is still poorly understood. Even when the target conditions are met, zinc dust consumption is excessively high: satisfactory operation requires up to 300 times the stoichiometric amount of zinc dust. The objective of this work is three-fold: (1) to examine the effects of activators and elucidate the characteristics that make a good activator; (2) to identify new additives that could lead to a more efficient purification process; and (3) to test the new additives with synthetic and real electrolyte solutions. The present paper gives a status report on this project.

Jan 1, 1998

By J. Lu, D. B. Dreisinger, G. Houlachi

"Zinc metal is primarily produced by electrowinning from sulfate solution. Zinc electrowinning is very sensitive to impurities such as Co and Ni. These impurities have to be removed to produce high-quality zinc and maintain a high zinc current efficiency. Zinc dusts are used to remove these impurities by cementation. However cobalt cementation is extremely slow and it is typically activated by the addition of Cu and Sb. Even with the use of Cu-Sb activation, cobalt is still difficult to remove. The zinc dust used for cobalt cementation is negligible compared to that consumed for hydrogen evolution. In some plants up to 6-7% of electrolytic zinc is used for cementation. This is a great waste of energy. Cu-Sb activation is not well understood. The objective of this study was to further understand the Cu-Sb activation and then find a way to reduce hydrogen evolution and promote cobalt cementation. The investigation reveals how hydrogen evolution (or zinc dissolution) and cobalt cementation and re-dissolution change with temperature, zinc dust dosage, the concentrations of copper and antimony and time. In the Cu-Sb activation, copper is deposited on a zinc particle to produce a porous shell. The zinc particle as an anode dissolves while the shell as a cathode provides a place where cobalt cementation and hydrogen evolution occur and they are catalyzed by antimony. A certain level of antimony (around 0.1 mg/L) is a key to maintain the catalytic effect of the shell. At a higher antimony concentration, cobalt cementation is accelerated slightly while hydrogen evolution is increased greatly. When a zinc particle dissolves to a certain degree, cobalt loses its cathodic protection and starts to re-dissolve. The change in cobalt concentration is determined by the rates of cobalt cementation and re-dissolution. The operation conditions can be optimized to maximize the cobalt removal and minimize the zinc dust dosage.INTRODUCTIONMost of the world’s zinc metal is produced by electrowinning from sulfate media. Many impurities such as iron, copper, cobalt and nickel are co-extracted into solution with zinc. Iron, mercury, indium, lead and tin are removed by co-precipitation as hydroxides. Copper, nickel, cobalt, aluminum, arsenic and germanium are partially co-precipitated with iron while cadmium, magnesium and chloride remain in solution. Cobalt, copper, cadmium, nickel and etc. are subsequently removed by cementation with zinc dust to achieve an acceptable current efficiency and high purity metal product for the economical production of zinc. Zinc provides a strong thermodynamic driving force for the cobalt cementation:"

Jan 1, 2016

By Alejandro R. Alonso, Lizet Alvarado, Gretchen T. Lapidus

"Cobalt and lithium recovery from spent Li-ion secondary batteries has been increasingly studied in recent years due to the high value of both metals and the low proven reserves for lithium. The standard method employed until now has been the deactivation and crushing of the batteries, followed by leaching of the L1C0O2 spinel from the battery cathode using acid solutions, such as 1.5 to 2.0 M HC1 or H2SO4, in a temperature range from 120°C to 250°C. Once leached, the cobalt is separated by electrodeposition and the lithium by precipitation, using large amounts of carbonate to bring the solution to alkaline pH values. In the present work, citric-thiosulfate solutions are used for the spinel leach at room temperature, favoring a reductive environment at room temperature, which stabilizes the cobalt(II) as cobalt citrate and lithium(I) at pH 5, and recovers approximately 99% of both metals.IntroductionThe Li-ion batteries industry has become an important economic sector in recent years. This type of battery is the most promising system for energy storage, because of its high efficiency in charge-discharge cycles, and its adaptability to many configurations. The demand will probably increase because of the need for mobile energy sources in many types of devices ranging from cell phones, tablets, and laptops to medical, navigation and sophisticated communication equipment and even in automobiles.One major problem related to the use of these batteries is the method employed for recycling the components, mostly cobalt and lithium. Currently, there are two processes employed on an industrial scale: the Sony/Sumimoto process, used since 1990 [1] and the Toxco Process [2]. In the first case, incineration is used to open the batteries and at same time volatilize the organic solvents. After that, the metals (copper, iron and aluminum) are physically separated. The cobalt and lithium are recovered as oxides and then thermally treated in order to recycle them for new batteries manufacture."

Jan 1, 2012

By Alexander Malahoff

Accumulation of cobalt -rich ferromanganese crusts on Pacific seamounts located off-ridge in the Hawaiian EEZ, represents a complex process that involves geologic aging of the seamounts, geographic transportation- of the seamounts on the Pacific plate during the past 80 million years, and geochemical history of the oceans for that period. A comparative study of the building and erosion processes of the young Loihi Submarine Volcano, located south of the Island of Hawaii , and the 80 million year old Cross Seamount, located west of Hawaii , shows that both edifices show wide armchair-shaped talus chutes and intervening ridges of exposed dikes. The similarity between the observed mass wasting process on Loihi and Cross suggests that the slopes of submarine volcanoes are geologically unstable from the time of their origin on the seafloor through their entire geological history. The slopes of Cross are covered by coalesced ferromanganese crust covered talus, steep exposed dike faces, and crust covered dike ridges. A study of the stratigraphy of the crusts shows a range of thicknesses and number of unconformities present. The thickest crusts, up to 8 centimeters, are found preserved within the larger coalesced slabs along the shallower slopes of the talus chutes and along the crests of the ridges between water depths of 400 and 1800 meters. The platinum content was used in stratigraphic correlation between the crusts in the coalesced slabs and those collected from ridges with the PISCES V submersible. In the samples studied, the highest platinum content of 0.7 ppm

Jan 1, 1991

By S. A. Shuey

The present industrial practice used to separate aqueous cobalt from nickel is multistage solvent extraction processing. This paper describes a different but simpler treatment technology. The proposed technology has been applied to cobalt/nickel hydroxide intermediate solids produced from the treatment of Electrochemical Machining (ECM) waste sludge, The process consists of dissolving the cobalt/nickel hydroxides in basic cyanide solutions. Cobalt and nickel form aqueous .solution metal cyanide complexes. Nickel can be selectively precipitated from the solution as a nickellic hydroxide solid. Cobalt can be recovered from the leach solution by precipitation of a cobaltous/cobaltic cyanide double salt. The double salt product can then be subsequently treated to produce an appropriate cobalt product. The process chemistry, proposed fiowsheet and preliminary reagent costs are presented and discussed.

Jan 1, 1998

By Edwards A. B

Occasional, sporadic and small occurrences of lollingite in the Broken Hill lode have been described,(l) mostly in the garnet sandstone in the foot-wall and under-wall of the Broken Hill lode. The lollingite contains appreciable percentages of cobalt and nickel and is regarded as an early mineral in the development of the lode; and, with the incoming of the sulphides, it has suffered considerable replacement by arsenopyrite. During the conversion of iron arsenide into the iron sulpho-arsenide, ilie nickel and most of the cobalt are removed in solution and are inferred to reappear in niccolite and other minerals that have been recorded among the later minerals of the Broken Hill lode. As a result of observations of the officers of ilie Broken Hill South Ltd., an occurrence of cobaltite can now be recorded which has developed by an analogous type of replacement.Cobaltite has previously been recorded from the Australian Broken Hill Consols lode in the vicinity of the rich deposits of silver, though not in contact with them. Cobaltite has been found in the northern extremity of the No. 2 lens of the Broken Hill lode at the 1,480 feet level of the Broken Hill South...

Jan 1, 1944

The detailed work done by Stillwell and Edwards on the occurrence of cobaltite and safilorite-Iollingite at the South Mine, followed by its presentation as a paper to the Institute, calls for, a few notes on its occurrence elsewhere in the Broken Hill field. No massive cobaltite similar to that in the South Mine veinlet is known except from the Consols Mine (as mentioned in the paper). Fine grained cobaltite has, however, been found in low-grade ore from the North Mine. Microscopic grains occur in a mineralized green feldspar pegmatite. The feldspar has been replaced in part by graphite, and the cobaltite occurs in association with the graphite. In its hardness, pinkish-white colour, and resistance to the standard etchingqeagents it is similar to the South Mine cobaltite; it is etched by acid permanganate solution. An interesting feature of this occurrence is the way in- which some of the minerals (notably galena) have forced apart the graphite lamellae in crystallizing, forming lenses enclosed by the curved cleavage surlaces 0;[ the graphite.StillwelI and Edwards cite a note by G. Smitht for the statement that "cobaltite has been recorded from the Australian Broken Hill Consols Lode in the vicinity of the rich silver deposits, though not in contact with them."Smith, however, is here referring to the oxidized zone. Elsewhere in the same article he states "... a deposit of cobaltite in a very much altered condition was found. This was impregnated with silver, and assayed as high as 3,000 ounces," Of the cobaltite in the unoxidized zone, Smith simply states that it became rarer with depth.Cobaltite has also been recognized by Mr. H. F. Whitworth, M.SC., Curator of the Mining Museum, Sydney, in specimens from Burt's Copper Mine eight miles south of Broken Hill.

Jan 1, 1944

By Aldo Bendezú

En el Perú, el cobalto @>0.1% de concentración se da principalmente en sistemas hidrotermales, particularmente en yacimientos de tipo IOCG y en vetas altoandinas de Zn-Pb-(Ag)-Ni. El primer tipo se presenta en al menos dos segmentos del cinturón de yacimientos IOCG de la costa, entre Lima e Ica. El segundo ha sido documentado principalmente en la Cordillera Oriental, entre Huánuco y Puno. Se han identificado 29 sistemas de vetas y mantos significativos entre ambos tipos. En las vetas, estos ocupan porciones restringidas de 100-500 m de largo, 50-200 m de alto y 0.2-1.5 m de potencia, sugiriendo masas prospectivas del orden de 0.2-0.5 Mt por cada sistema.

May 10, 2023

By Daniel Rodríguez Hoyle

El presente texto señala una breve reseña histórica sobre el cobre, producción, exportación, consumo, reservas y su expansión mundial en el Perú durante los últimos cinco años.

Jan 1, 1968

By Ian D. Pirie

Presentation outline ?Project location ?Geology ?Resources and reserves ?Results of the FEED study ?Social and environmental considerations ?Project path forward

May 1, 2010

By Michael Valencia, Alonso Marchena, Fredy Arcos, Miguel Chumbe

Cobrepampa es un depósito de cobre ubicado en Acarí (Caravelí-Arequipa). La mineralización se emplaza en pórfidos dioríticos pertenecientes al intrusivo Cobrepampa (Superunidad Linga) y está constituida por bornita, calcosina, covelina y calcopirita y en la zona de oxidación cuprita, crisocola, malaquita y hematita. El magmatismo es calcoalcalino con alto K. El intrusivo Cobrepampa evoluciona por fraccionamiento y contaminación en una corteza más delgada que la superunidad Linga. Petromineralógicamente se tiene epidotización con diseminaciones de calcopirita, pirita y bornita, gangas de cuarzo y calcita con hematita acicular. Las inclusiones fluidas muestran temperaturas de homogenización de 165.5 - 266.43 °C y salinidad 3.5 - 16.8 % eq. peso NaCl de un mesotermal o epitermal, pero que por sus características geomineralógicas sería un mesotermal. Por tanto, Cobrepampa presenta más de un evento de mineralización: una con magnetita y actinolita, y otro mesotermal de vetas de cuarzo con sulfuros.

May 22, 2019

Cobriza can only be described as the Machu Picchu of the mining business. This relatively new mine of the Cerro de Pasco Corp. in Peru, subsidiary of The Cerro Corp., was put on stream in December 1967. The best way to get there is to go in the company's HelioCourier with pilot Paco Perez. The plane is mostly engine and the pilot is without nerves. The trip starts at an elevation of 12,000 ft at La Oroya and ends at the Cobriza air strip near the top of the Continental Divide at 14,200 ft. Perez says this is the highest air strip in the world. The flight is made at an altibude below many of the peaks and it is easy to pick out the Inca Trail which follows the ridge line of the top of the Andes. Inca ruins are also visible from the aircraft. The drainage pattern, with a surprising number of lakes and rivers, can be seen and so, too, can a great deal of structural geology and numerous agricultural settlements dotting the altiplano. Cobriza is in the monta[n]a on the east side of the Andes, which is characterized by tropical climate and vegetation, an abrupt change from the frosty mountain atmosphere. The mountainsides are precipitous and the bottoms of the steep valleys are channels for roaring rivers. Such is the setting of Cobriza, above the swift cataracts of the Mantaro, benched out precariously at about 8700 ft elevation. The mountains rise in majestic splendor and the sun comes up late and sets at 3: 30 on winter afternoons. One of the lowest of the Cerro de Pasco camps, it is the most remote.

Jan 11, 1969

By Jaime Tumialán

El presente artículo describe los trabajos subterráneos de la mina Cobriza, la mina más mecanizada del Perú, dado que es la primera en aplicar el minado sin rieles con equipo pesado montado sobre llantas neumáticas u orugas. La mina se encuentra localizada en la Oroya, Huancavelica. Las razones de su mecanización son: crecimiento de los costos, avance de la tecnología, la forma, magnitud y potencia del manto, así como la dureza y resistencia del mineral. Su método de minado es "Corte y Relleno altamente mecanizado con equipo pesado y tiene una productividad en subsuelo de 20Tn/h-g.

Nov 1, 1972

By J. P. Nowlan

"This paper is an attempt to outline the structural problems at the Cochenour Willans mine, in so far as their details have been tentatively worked out. It must be emphasized that there are considerable data that can be interpreted in more than one way, and that further work may modify or completely change some of the hypotheses presented herein. Certain features, however, are sufficiently constant to warrant reliance on them when searching for extensions of orebodies.As the individual ore shoots usually have relatively small dimensions, but are often very high grade, structural details are of more than usual significance in laying out a mining programme. An illustration of this is a small shoot recently located and mined as a result of studying a minor slip cutting off a part of high grade gold ore in No. 319 stope. The shoot, which is bounded on three sides by slips, and on the fourth by the original stoping, was roughly triangular in plan, 20 feet on the base, and 40 feet in length. The average width mined was 4.5 feet, but the gold obtained totalled over 1,800 oz.The property lies in Dome township, east of McKenzie island, and consists of an original group of thirteen claims acquired from the Cochenour Willans syndicate, plus one additional group of five claims obtained by purchase from the Kelson Red Lake Gold Mines, Limited, and one other claim that rounds out the southeast corner of the block.The claims of the original group were staked by W. M. Cochenour, Dan Willans, and Horace Young, during 1926 and 1927. The Cochenour Willans Syndicate was formed in 1928, and until incorporation of the present Company work was carried on at varying intervals by several different interests, including Ventures Limited, Hollinger Consolidated, who sank a shaft to open up the 150-foot level, and by the Syndicate itself. The first ore from the property was shipped to the Gold Eagle mill by the present Company in 1939, and amounted to 4,959 tons, from which 2,360 oz. gold was recovered. The first brick was poured in December, 1939, and production has been continuous since that date. To the end of June, 1946, gold having a value of $5,982,000 has been produced from 345,033 tons of ore treated."

Jan 1, 1954

By Chris L. Powell, Russell J. Denny

"The remotely located Cockatoo Island iron ore mine off the Kimberley coast in the northwest of Western Australia has been in operation since 1951. The mine was recently expanded up to about 50 m (165 ft) below sea level using staged construction to create a rockfill seawall around the open cut mining operation. Late in 2013, to allow expansion of subsea iron ore mining operations, Wagstaff Piling was engaged to install a seepage barrier through the rockfill seawall and into the underlying seabed sediments.Earlier stages of seawall construction had used a variety of different construction techniques with varied success, and the history of subsea mining on the island had been plagued with failures, including failures in the slope of the seawall itself, hanging wall failure underneath and inside the seawall, and footwall failures as the ore was mined leaving the rock face inclined at 55 degrees, parallel to the bedding. The current expansion, known as the Stage 4 expansion, was more tightly constrained by the pit geometry and available materials than previous seawall expansions that adopted clay core and sheet pile seepage barrier solutions. In Stage 4, an innovative seepage barrier solution using a grout curtain was selected to provide the necessary cutoff to allow access to highgrade ore, while protecting the mine from inundation by the sea.Seawall ConceptThe open cut subsea mining operation consisted of a 3 km (1.9 mi) long narrow pit along the south side of Cockatoo Island that extended to depths of about 50 m (165 ft) below sea level, and were exposed to the open sea on the south side of the pit. Massive tidal variations of more than 10.5 m (34.5 ft) required a seawall founded on the seabed, extending upwards to RL+13, to safely protect the pit from the high tide level rising to above RL+10."

Jan 1, 2017

By Chris L. Powell, Russell J. Denny

"The remotely located Cockatoo Island iron ore mine off the Kimberley coast in the northwest of Western Australia has been in operation since 1951. The mine was recently expanded up to about 50 m (165 ft) below sea level using staged construction to create a rockfill seawall around the open cut mining operation. Late in 2013, to allow expansion of subsea iron ore mining operations, Wagstaff Piling was engaged to install a seepage barrier through the rockfill seawall and into the underlying seabed sediments.Earlier stages of seawall construction had used a variety of different construction techniques with varied success, and the history of subsea mining on the island had been plagued with failures, including failures in the slope of the seawall itself, hanging wall failure underneath and inside the seawall, and footwall failures as the ore was mined leaving the rock face inclined at 55 degrees, parallel to the bedding. The current expansion, known as the Stage 4 expansion, was more tightly constrained by the pit geometry and available materials than previous seawall expansions that adopted clay core and sheet pile seepage barrier solutions. In Stage 4, an innovative seepage barrier solution using a grout curtain was selected to provide the necessary cutoff to allow access to high-grade ore, while protecting the mine from inundation by the sea.Seawall ConceptThe open cut subsea mining operation consisted of a 3 km (1.9 mi) long narrow pit along the south side of Cockatoo Island that extended to depths of about 50 m (165 ft) below sea level, and were exposed to the open sea on the south side of the pit. Massive tidal variations of more than 10.5 m (34.5 ft) required a seawall founded on the seabed, extending upwards to RL+13, to safely protect the pit from the high tide level rising to above RL+10."

Jan 1, 2017

By Aïda Espinola

Decontamination of synthetic solutions containing cadmium ions using coconut fibers in natura was investigated in laboratory scale. Cadmium ions, a serious pollutant of water ways, where it is detrimental to the environment, may be absorbed by fish and mollusk used as food, which will, eventually, poison humans; these ions are usually present in minero-metallurgical and electroplating industrial effluents. Usually employed for the aqueous effluents treatment are chemical precipitation, adsorption and electrolytic processes. Precipitation is not effective for cadmium removal, because of the high KpS of the cadmium hydroxide, which requires high pH; only sulfide would be efficient in cases of very small amounts. Some vegetal refuses have shown to be practical for absorption processes of several metallic ions. We have applied coconut (Cocos nucifera) shells, which are extremely abundant over most of the extensive Brazilian coast, in the removal of cadmium: it has been verified, in our laboratory, that the surface of the fiber of this coconut is rich in chemical compounds which are active scavengers for Cd2+. For the optimization of the process, hydrosoluble components existing on the surface of the fiber, which may be deleterious, were previously washed out by water, and variables, such as the pH and the proportion of mass of fiber to volume of solution, were adjusted. As much as 99% of the initial contaminant metallic ion has been eliminated, resulting a solution to be discarded which contains ca. 0.1 ppm; this attends to the maximum impurity legally admitted by the environmental control agency of Rio de Janeiro, FEEMA, for cadmium ions in aqueous effluents to be disposed in rivers and in the Guanabara Bay area.

Jan 1, 1998

By Jae-Ho. Lee

Mercury is a toxic contaminant encountered in the extraction of gold from mercury-containing ores. It is found in the leach solution of CIP circuits and in the cathodes of the electrolyte cells used to electrodeposit the gold. The research conducted has examined the potential for selective removal of mercury from synthetic Au-Hg-CN electrolytes containing only gold, only mercury, and both gold and mercury. Cyclic voltammograms were obtained for mercury- coated copper electrodes with these cyanide electrolytes. Exchange current densities were determined from the voltammograms in the low overpotential region. Laboratory scale batch- electrolysis at constant current was also conducted for the electrolytes containing only mercury and both mercury and gold, at 20 and 50°C and from which the kinetic behavior associated with the process was analyzed. The surface of cathode before and after electrolysis was also characterized and a copper mercury intermetallic (CyHg,) was identified. Gold codeposited with mercury during the later stages of electrolysis. The results of this work corroborate that the mercury-amalgam copper electrode offers a viable electrochemical technique for the selective removal of mercury, however a high-surface-area cathode-cell would have to be utilized to provide for the desired selectivity.

Jan 1, 1994

By J. L. Bray

IT is well known that iron markedly improves the physical properties and casting characteristics of aluminum bronzes. The use of 1 to 4 per cent iron as the principal modifying addition has become common practice in many foundries melting aluminum bronzes. Although the beneficial effects of iron are unquestioned, there is some uncertainty regarding the structural changes caused by it in the basic copper-alumi-num system. It is agreed that a new constituent appears in abundance when the iron content reaches 2 to 4 per cent. This constituent, which frequently occurs in shapes resembling clover leaves, is sometimes assumed to be an aluminum-iron intermetallic compound. If this were correct we might expect a change in the structural relationships of the matrix in the direction of decreased aluminum content. On the other hand, it has been reported that iron has a negligible effect in altering the fundamental relationships of copper-aluminum alloys1. Others2,3 have reported an additive coefficient. Apparently it will be necessary to know the equilibrium relationships between the phases of the copper-aluminum-iron alloy system to establish any such theory as fact. When this has been done it may very well be that a further revision in the structural relationships may be necessary to describe the changes to be expected in commercial cast alloys. It was with this latter problem before them that the authors attempted to

Jan 1, 1936

By P. Ashayer, J. Curran

Introduction Rockfalls occur when rocks or boulders detach from mountains or hills and tumble down. They can pose significant hazards to infrastructure such as highways, buildings, and mine open pits, and they sometimes result in personal injury or death. Prediction of rockfalls is a difficult task. Slopes that are at risk of rockfall have highly variable geometries. The location, mass, and shape of the rocks that might dislodge and fall are uncertain. Moreover, the materials that make up a slope can vary considerably from one section to another. Furthermore, the relevant material properties are usually not well known. Performing probabilistic simulations of rockfalls, combined with proper statistical analyses, has proven to be an effective and acceptable method for dealing with these difficulties [1, 2, 3]. The movements of a falling rock can be classified as freefall, bouncing, sliding, toppling, or rolling. The falling trajectory is controlled mainly by the geometry of the slope, the block shape, and the energy dissipated at each contact of the block with the slope. A rockfall model is evaluated based on its ability to efficiently predict the velocity, frequency, height of bounce, and run-out distance of falling rocks. With this information, the engineer can design remedial measures such as restraining nets and ditches. Most of the existing rockfall simulators are based on particle models that consider the falling rock as an infinitesimal particle with a mass, called the lumped mass or stereomechanical models [1, 2, 3, 4]. Other models involve hybrid methods relying on simplified assumptions. The most common hybrid methods are based on contact searching for the movement of a dimensionless object and incorporate some aspects of rigid body impact for bouncing [5, 6, 7]. There are also some rigid body models in the literature that employ simplified versions of rigid body models [8, 9]. This study applies a more sophisticated rigid body theory based on rigid body impact mechanics (RBIM), which was developed by Stronge [10, 11, 12]. The new theory captures all modes of rigid body movement. Due to the importance of the rock geometry, single impacts of ellipsoidal and prismatic rocks with rectangular cross sections are investigated. The effect of rock slenderness on rebound velocities and energies is also investigated for ellipsoidal rocks. The correspondence between the model parameters and the data from the rockfall literature data will be discussed.

Jan 1, 2007