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By McQuade CV, Riley SJ

Acid mine drainage is an unavoidable consequence of some coal mining operations. Typically runoff pH is below 3.5 and at these pH levels heavy metals are mobilised. Leachate from coal reject dumps may require collection and treatment to raise the pH and precipitate the metals before being discharged.A bi-product of coal mining operations at Clarence Colliery is coarse washery reject. At present the coarse reject is deposited above ground and rehabilitated. Adjacent to Clarence Colliery is the Kable's Transport Pty Ltd sand mining operation. It has been proposed that co-disposal of the rejects from both operations may produce a product whose leachate has near neutral pH.

Jan 1, 1998

By P. H. Williams, D. J. Morris

The co-disposal of coarse and fine coal wastes by combined pumping through a pipeline to subaerial deposition was pioneered in Australia in 1990 by Jeebropilly colliery in Queensland. Significant segregation of fines is found to occur in its co-disposal delta, leading to the formation of distinct mainly coarse upper and fine-dominated lower segments; the upper delta drains rapidly and is able to support traffic on its surface immediately after deposition. An existing theory of subaerial deposition, originally developed for mine tailings alone and later extended to trial co-disposal, is shown to apply also to the upper segment of the full-scale Jeebropilly delta

Jun 19, 1905

The concept and practices of co-extraction of coal and methane have emerged in recent years to improve coal mining safety and productivity, utilise methane resources, and reduce fugitive emissions in environments that involve multiple coal seams with low gas permeability. The system of co-extraction integrates two previously separate operations of coal extraction and methane drainage. The coal mining operation reduces the coal seam gas pressure and creates strata fractures that enhance gas migration and capture from mine workings and surrounding coal seams. An effective methane drainage operation produces a consistent and quality clean energy product and, at the same time, reduces the methane concentration in underground workings and the methane content and pressure in the adjacent coal seams. This is a significant benefit in preventing gas explosions and outbursts, and promotes a safer and more productive coal mining environment. In addition, the co-extraction with enhanced utilisation of coal mine methane directly leads to a reduction in greenhouse gas emissions. Presented in this paper are key results and outcomes of a major Asia Pacific Partnership project carried out from 2008?2012 by the Commonwealth Scientific and Industrial Research Organisation in collaboration with Huainan Mining Industry (Group) Co. Ltd., to develop and demonstrate advanced technologies at Pansan mine, Huainan, that promote the concept and practices of co-extraction of coal and methane. A comprehensive approach was adopted to assess fundamental strata and coal seam methane conditions during mining, and optimise mining sequences and coal mine methane capture systems. The project has not only demonstrated a practical approach and procedures of advanced co-extraction of coal and methane systems but also delivered significant benefits and outcomes in improved mining safety and efficiency, increased methane capture and utilisation, and reduced fugitive methane emissions at the Pansan mine. The total mine gas drained increased from 25.36 Mm3 in 2007 to 47.0 Mm3 in 2011, and the mine gas utilisation increased from 4.94 Mm3 in 2007 to 21.15 Mm3 in 2011. The improved methane capture resulted in reduced coal and gas outburst risks and methane concentration levels at the mine workings, provided a safe working environment for coal production, boosted the mining efficiency, and eliminated methane related incidents over the last few years at Pansan mine.

Aug 1, 2013

By L. Yuan, J. Qin, J. Xie, Q. D. Qu, Y. P. Liang

"This paper presents key outcomes of a major Asia-Pacific Partnership project between the Commonwealth Scientific and Industrial Research Organisation and Huainan Mining Industry Group Co. Ltd. to develop and demonstrate advanced technologies at Pansan mine, Huainan, China. A comprehensive approach assessed fundamental strata and coal seam methane conditions during mining and optimized mining sequences and coal mine methane capture systems. The project demonstrated a practical approach and procedures for advanced coal and methane co-extraction systems, improved mining safety and efficiency, increased methane capture and use, and reduced fugitive methane emissions.RÉSUMÉ Le présent article donne les principaux résultats d’un grand projet de partenariat Asie- Pacifique entre le CSIRO (Commonwealth Scientific and Industrial Research Organisation) [Organisation de recherche scientifique et industrielle du Commonwealth australien] et le Huainan Mining Industry Group Co. Ltd.; ce projet cherche à développer et à démontrer des technologies avancées à la mine Pansan, à Huainan, en Chine. Une perspective globale a évalué les conditions fondamentales des strates et du méthane dans les couches de charbon durant l’exploitation et a optimisé les séquences d’extraction et les systèmes de captage du méthane dans les mines de charbon. Le projet a permis de démontrer une approche pratique et des procédures pour des systèmes avancés d’extraction conjointe du charbon et du méthane, pour améliorer la sécurité et l’efficacité minières, accroître le captage et l’utilisation du méthane et réduire les émissions fugitives de méthane."

Jan 1, 2015

By C. J. Simensen, R. Østhus, H. J. Roven, K. G. Skorpen, H. Kalager

"This work encompasses co-extrusion of alloy Al4.5Mg at the core and rapidly solidified Al4.5Mg1Ag forming the surface layer. The goal is to produce a multi-material by co-extrusion having a relatively hard surface as compared to a softer core. At the same time, work hardening in both alloys is expected to be significant due to Mg in solid solution. Precipitation hardening at 160°C is studied by applying solution heat treatments at 560°C. The hardness increased from 80 to 130 VH in the surface material after 236 h. Surprisingly, the Al4.5Mg alloy also shows pronounced aging at this temperature, i.e. from 70 to 90 VH. The relatively high solution heat treatment temperature introduces grain growth in the core, but this is insignificant for the RS surface alloy. Blisters forms at the surface and cracks follows large portions of the interface. However, the tensile ductility is significant in all conditions due to very pronounced work hardening, i.e. for the as co-extruded, T6, under- and over-aged. The elongation at fracture ranges between 40–45% and the tensile strengths 240–275 MPa. The tensile properties increase linearly with the thickness of the RS alloy, i.e. following the rule of mixtures.INTRODUCTION Al-Mg alloys in 5xxx-series are classified as non-heat treatable wrought alloys (Polmear, StJohn, Nie, & Ma, 2017). The formation of the binary ß-Al8Mg5 does not give a substantial increase in the strength of the alloys (Mondolfo, 1976). When a third element like Ag, Cu or Zn are added, G.P.?zones are formed at low temperatures and intermediate, partial coherent phases are nucleated somewhat higher temperatures and finally a ternary, equilibrium phase is formed (Auld, 1968; Cousland & Tate, 1986; Mondolfo, 1976). Both the formation of G.P.?zones and intermediate phases increase the hardness and strength of the materials. An intermediate, hexagonal T´?phase is formed in Al-5 wt%Mg-1wt%Ag, and finally the equilibrium, cubic phase (Al,Ag)9Mg5 is nucleated (Cousland & Tate, 1986; Mondolfo, 1976)."

Jan 1, 2018

By K. Isaac, S. O. Bada

This research focuses on the co-firing of discard coal with refuse-derived fuel (RDF) to utilize this abundant resource in South Africa for energy generation and reduce the volume of waste disposed of at landfills. The potential of a coal with a high ash content (> 40%), which is a grade used in some power stations in South Africa, and its combustion compatibility with two different RDFs in terms of emission reductions has been established. Gaseous emissions and ash residues from the combustion and cocombustion of the coal, two different RDFs and coal/RDF blends of different proportion were analysed. One of the RDF samples contained mostly paper (PB) and the other mostly plastic (PL). Co-combustion ash from the discard coal and RDFs showed a decrease in chloride and alkali metal contents as the coal ratio in the blend increased. The slagging propensity of the co-fired blends was found to be very low, while the propensity for fouling decreased from high to medium for all the blends with < 75% RDF. Cocombustion of RDF with coal showed a decrease in SO2 emissions from 387 ppm (discard coal) to 50 ppm for the sample containing 25% coal discard plus 75% PL. A 15% PL to 85% coal blend also reduced NOx emissions from 145 ppm (100% PL) to 88 ppm. The lowest CO2 emission observed was 6000 ppm for the blend of 85% discard coal plus 15% PB. It was established that the most favourable fuel blend that can produce the lowest sulphur emissions if used for power generation is the 25% coal discard plus 75% PL sample.

Aug 2, 2022

By Zhang Jianliang, Zuo Haibin, Gao Bing, Wang Zhe

"As a result of the shortage of coking coal and the quality decrease of coke, it is important to know how to make better use of highly reactive cokes. The co-gasification behavior of highly and lowly reactive coke for blast furnace is investigated. The results show that: In the middle stage of reaction, the weight loss ratio of highly reactive coke reacted together with lowly reactive coke is higher than that of it reacted individually. However, the weight loss ratio of lowly reactive coke is lower. The weight loss ratio of highly and lowly reactive coke is almost the same as that of the weighted average. The scanning electron microscope analysis indicated that the reaction degree of surface and interior of lowly reactive coke is relatively uniform with the reaction time increased. And the reaction degree of surface of highly reactive coke is obviously higher than that of interior.IntroductionIn blast furnace iron making process, coke functions as heat supplier, reducing agent, carburizer and skeleton. With development of blast furnace iron making technology, the skeleton function of coke is becoming more and more important in requirements of large scale furnace and high pulverized coal injection. High reactivity coke is usually produced by cheap coal with bad quality, and is not good for blast furnace process. The reactivity of coke is mainly determined by the coals used, and the resource of good quality coking coal is limited and is non-renewable. In order to fulfill the need of blast furnace, a lot of research have been done to improve coal matching using new kinds of coal to enlarge resource, in which coking coal and fat coal are reduced, whereas low price coal with bad caking property are used to lower the cost, and this would inevitably increase the reactivity of coke [1-4] Blast furnace iron making would still be the main stream for a predicted future, and high reactivity coke would correspondingly be used more and more, so it has great importance to study how to use high reactivity coke in blast furnace."

Jan 1, 2013

By E. S. Schubert

Keywords: co-generation, furnace CO-gas cleaning, disintegrator scrubber, Theisen In a closed, electric, reduction furnace, no oxygen enters the furnace from the surrounding environment. The off-gases are thus not ?burnt? and therefore contain a considerable amount of CO and H2. Traditionally these gases have been captured and burnt in a flare stack. Recent developments have led operators of such furnaces to revise this strategy and to consider utilising these gases as a fuel for gas-fired generator sets to produce electricity, thus becoming more energy efficient. On 31 March 2010 the new emission standards, in accordance with the Air Quality Act, Act 39 of 2004, were promulgated. The minimum emission standards according to the act require that the particulate matter emissions from the primary fume-capture systems on closed furnaces for ?new plants? in ferroalloy and calcium carbide production not exceed 50 mg/Nm³ and 25 mg/Nm³, respectively. By implementing co-generation, the producer automatically complies with the new environmental emission standards for an off-gas. As much as 30% of the electrical power cost, which is set to double in the near future, can be saved by partly generating one?s own electrical power. In December 2010, the National Treasury published a discussion paper for public comment, one entitled ?Reducing greenhouse gas emissions: The carbon tax option?. Irrespective of how the tax is finally implemented, it will result in an increase of production costs in affected industries. This paper focuses on the characteristics of a furnace-off-gas cleaning system for closed ferroalloy smelters, characteristics that meet the requirements of both reducing solid-matter emissions and operating a safe and reliable gas plant.

Jan 1, 2011

By D Landriault, G W. Wilson, L Langetine and

Engineered soil covers are used for final closure options for both waste rock and tailings disposal facilities. Currently, cover construction requires excavation of appropriate cover material from a nearby site. If no suitable materials are available, the mine operation may have to ship appropriate materials long distances to the site before the construction of the cover can even begin. This has led to the proposal to engineer cover materials using existing waste materials from the mining operation. The paper presented here describes the results of a laboratory scale testing program to evaluate the potential for blending waste rock, smelter slag and tailings for the creation of a suitable cover material at a site in Canada. Tailings from the local mill, waste rock and slag were collected in the field and blended to create a material with an air entry value similar to the tailings and with physical strength similar to the waste rock. Testing indicated this mixed material could be blended at a consistency of a paste and was suitable for pumping. It can also be compacted to a high-density material. The preliminary results show that it may be possible to blend waste rock, slag and tailings into a material that can be utilised in the construction of a water retaining cover.

Jan 1, 2003

By K. Hardy

As part of Inco&apos;s $115 million Fluid Bed Roaster SO2 Abatement Project, a new weak acid treatment plant (WATP) was constructed to treat bleed solutions from the Copper Cliff Smelting Complex gas-cleaning circuits. The WATP produces an iron-arsenic co-precipitate, termed "basic ferric arsenate" (BFA), which requires disposal in an environmentally acceptable manner. Following analysis of many potential options, the short-listed disposal alternatives were: A) Co-disposal of the BFA?gypsum sludge with rock tailings, a portion of which would be used in mine backfill, with the remainder being sent to the tailings area, and B) Co-disposal of BFA?gypsum sludge with pyrrhotite tailings in the tailings area. Testwork showed that the addition of BFA?gypsum sludge to mine backfill samples increased the uniaxial compressive strength (UCS) of the backfill for most samples, especially those at lower binder content ratios. Extensive analysis was conducted on samples taken from the Copper Cliff tailings area, where BFA?gypsum sludge from Inco&apos;s Copper Refining Electrowinning Department has been co-deposited with pyrrhotite tailings since 1990. Pore water samples from these areas contained very low arsenic concentrations, indicating that the arsenic had remained stable in that environment. Ultimately, co-deposition with pyrrhotite tailings was chosen as the preferred option for the disposal of BFA?gypsum sludge from Inco&apos;s new WATP.

Jan 1, 2006

By C. Tokoro

Co-precipitation of dilute toxic anions with ferrihydrite is an important removal mechanism in wastewater treatment system. Although, numerous qualitative studies have been published on removal characteristic from wastewater of dilute anions by co-precipitation treatment, detail mechanism or quantitative characteristic is not well understood. This paper discussed the co-precipitation mechanism of As(V) and Cr(VI) with ferrihydrite by comparative experiments between co-precipitation and simple adsorption. In this study, co-precipitation experiments and simple adsorption ones were distinguished closely. In the former, precipitation of hydroxides and adsorption of anions develop simultaneously, but in the latter, anions adsorb onto prepared hydroxides. Although high affinity anions for hydroxides (e.g. As(V) for ferrihydrite) showed quantitative difference of removal ratio between co-precipitation experiments and simple adsorption ones, low affinity anions (e.g. Cr(VI) for ferrihydrite) showed quantitative agreement in spite of deferent forms of ferrihydrites between them, that is, amorphous ferrihydrite was formed in co-precipitation experiments, but goethite was formed in simple adsorption ones. In order to discuss the mechanism of co-precipitation phenomena, three experimental studies have been carried out: (i) adsorption isotherm measurement in the co-precipitation experiments of As(V) or Cr(VI) with ferrihydrite, (ii) zeta potential measurement of co-precipitated or simple ad-sorbed ferrihydrite with As(V) or Cr(VI), and (iii) XRD analysis of co-precipitated As(V) for ferrihydrite. All experimental results suggested the main mechanism in co-precipitation phenomena of As(V) was not only a surface complexation (simple adsorption) but also a surface precipitation.

Jan 1, 2014

By Mel Owen, Bob Tipman

"A number of studies have identified the presence of heavy minerals in the Athabasca oil sands. A 1996 Mineral Development Agreement study into the recovery of Co-Products identified low operating costs, a simple flowsheet and access to market as key drivers in advancing interest in a viable project.Commercial bitumen extraction processes recover 50% of the titanium heavy minerals and 85% of the zircon into froth containing 1 % of the feed solids. Froth treatment tailings grade is 11.5% Ti02 and 3.6% Zr02.Processing this high grade feed in a combination of flotation, roasting, screening, gravity concentration and magnetic separation, results in concentrates of rutile, leucoxene, ilmenite, zircon and rare earths of marketable quality.A combination of high grade feed and a simple process lead to operating costs among the lowest in the industry. Low cost heavy minerals and low energy costs indicate an intriguing potential for low cost pigment production in Alberta. The production of heavy minerals from oil sands remains one of the largest untapped resources in the Province of Alberta1.0 IntroductionThis paper describes the results of an investigation into the recovery of heavy minerals from tailings produced by the major oil sands plants. The study was carried out under a Canada-Alberta Mineral Development Agreement (Alberta Chamber of Resources 1996). The MDA Co-Products Study examined the potential for the economic recovery of heavy minerals from oil sands tailings."

Jan 1, 1998

By William Bourcier

Geothermal Brines are a significant potential source of valuable minerals and metals. These brines are water that is heated by the natural heat flow from the depths of the earth. Hotter brines, typically with temperatures greater than 120°C, are used to generate electricity. Lower temperature brines are directly used to supply thermal energy to applications such as agriculture, aquaculture and process/domestic heat. The geothermal waters have had intimate and lengthy contact with the layers of the earth?s crust that they flow through, resulting in dissolution of minerals and metals from the rocks, and solution into the hot water. These aqueous solutions can be processed to recover minerals and metals. Some potential products include silica, zinc and lithium, along with other materials. Recovery of minerals and metals from geothermal brines can be viewed as ?solution mining by nature?, followed by application of known or new hydrometallurgical techniques for isolation and purification. This paper discusses the opportunities, the processes, the challenges, the current status, the economics and the potential for recovery of minerals and metals from geothermal brines.

Jan 1, 2006

By L. S. Jen

Canadian copper, nickel, zinc, lead and molybdenum mines are characterized by the mining of ores from which more than one metal is recovered. During the 1980s, approximately 15% of the gold, 25% of the zinc, 30% of the copper, 55% of the molybdenum, 80% of the silver and 90% of the lead produced from Canadian mines were produced as co-products and by-products of base metal mining operations. This trend is not expected to change significantly in the near future. The presence of co-products and by-products affects the level of production and the level of revenue from base metal mines in several ways: (I) in general, production of one base metal cannot be expanded or cut back without affecting the amount of production of another metal;(2) the commercial success of certain base metal mining operations depends on the substantial bonus revenues from co-products and by-products; (3) the quality and economic viability of many ore deposits are significantly improved by the presence of co-products and by-products; and (4) while coproduction is critical to the survival of some mines, bonus revenue from by-products can also be life saving to others during economic downturns. For these reasons, deposits with significant co-product or by-product values are likely to continue to be significant targets for exploration and for acquisition.

Jan 1, 1992

By Lanre Oshinowo

Computational Fluid Dynamics (CFD) is used in conjunction with process modelling at HATCH to achieve a superior level of confidence in the process design of hydrometallurgical process plants. The use of these tools to evaluate designs through virtual prototyping reduces the risks associated with making design decisions. This paper highlights the development of a co-simulation strategy at Hatch for the seamless integration of process modeling software addressing different scales (process time and space): flowsheet level models and .equipment level models. With co-simulation, the process design engineers can improve design accuracy, troubleshoot and optimize performance and influence decisions impacting equipment operation by representing specific unit operations in the flowsheet model software with detailed CFD models. Specifically, this paper will focus on the co-simulation of a Ni/Co high-pressure acid leach (HPAL) process including heaters/heat exchangers and flash system, autoclave and quench/scrubber system. The knowledge developed can be transferable to other processes.

Jan 1, 2004

By S Paciornik

Computer-controlled microscopes with digital image acquisition and analysis led to the creation of the new field of digital microscopy. These techniques not only allow a certain degree of automation but have also brought new possibilities to microstructural characterisation. One of these new and promising possibilities is co-site microscopy, which links different kinds of information obtained from different microscopy techniques. The present work presents the development and implementation of a co-site microscopy methodology that combines images obtained by reflected light microscopy (RLM) and scanning electron microscopy (SEM). This methodology can improve the SEM analytical capacity by adding colour information from RLM. It involves the whole sequence, from image acquisition at the microscopes to the analysis of the phases using pattern recognition techniques. An automatic registration procedure for the two kinds of images was developed, allowing the adjustment of magnification, translation, rotation and pixel size, and the correction of local distortions. Thus, the images from RLM and SEM can be combined to build a multidimensional data set of each field, which can then be used in a pattern recognition approach to discriminate different phases. The methodology was tested with a copper ore sample, aiming at the discrimination of minerals that are not distinguishable with either RLM or SEM.

Jan 1, 2008

The high pressure acid leach process (HPAL) is being commercially used in four plants around the world to treat limonitic laterites. The two major operating costs of the HPAL process are the sulphuric acid and the energy required to heat the pulp to the desired temperature (>240°C). As an alternative to acid injection and steam heating, the in-situ generation of sulphuric acid and heat, produced during the high temperature pressure oxidation of sulphur-bearing materials blended with laterites, has been investigated at the laboratory scale. Various sources of sulphur have been examined, in particular, elemental sulphur, pyrrhotite and a Cu-Ni low-grade bulk concentrate. Under the proper blend ratios, all sulphur sources tested generated sufficient acid to result in equivalent nickel and cobalt dissolutions. A significant improvement to the process economics can result from the addition of sulphur sources containing valuable by-products, such as nickellcobalt andlor precious metals (gold and PGMs). This is especially true in the latter case, when the HPAL can be operated under Platsol conditions (i.e. with the addition of 5-10g/L of chloride), to dissolve the base metals and precious metals simultaneously in the autoclave. Various examples of the application of this concept are presented, together with a brief discussion of its implication on the autoclave design and the downstream processes to recover the values from the leach solutions. Keywords: limonite, co-treatment, acid consumption, sulphur, sulphur compounds, pressure acid leach (HPAL, PAL), Platsol process

Jan 1, 2004

By M. K. Gangal, E. D. Dainty, G. Kunchur

This paper presents a validation of C02 as a single surrogate measurement for other diesel-emitted pollutants in multi-diesel-machine operations typical of small underground mines. This means that the simple measurement of C02 alone can be used to estimate the concentrations of other components of diesel exhaust in the mine environment. The linear relationship of C02 concentration with other diesel-emitted pollutants was indicated by the results of simultaneous real-time monitoring of C02 with CO, NO, NO2, SO2, Respirable Combustible Dust (RCD), and Air Quality Index (AQI) in several small underground mines. The SO2 was not directly measured but calculated from the measured C02 concentration and diesel fuel analysis for carbon, hydrogen and sulphur. The measurements were made in the return air drift under various mining conditions involving a number of diesel LHDs and haulage trucks. The statistical analysis and mathematical representation of the several components of diesel pollutants with C02 are presented. Regression analysis shows that at the 1 percent level of significance there is a strong linear relationship of these diesel pollutants with C02. This relationship is discussed in detail, concluding that C02 measurement alone is a good indicator of overall mine air quality and can be used as a control parameter.

Jan 1, 1991

By Jim Sarvinis, Mark Berkley, David Clarry, Jason Berzansky

"Technologies developed to sequester CO2 or use CO2 for enhanced fossil fuel recovery are currently being utilized across the globe. Taxation regimes and CO2 credit trading are becoming drivers for a number of projects. Some mining companies have also identified ancillary opportunity to sequester CO2 in their by-products; recent work in the alumina industry is a prime example. In addition to process plant emissions, mining companies are becoming increasingly aware of their overall carbon footprint, including CO2 generated during the production of utility power. New power plant designs, in various stages of development, include CO2 separation and sequestration techniques. This paper summarizes the state-of-the-art for these technologies; including integrated gasification combined cycle (IGCC) power plants. A concept to use the gasification products as reductant in metallurgical processes is also described. The relevance of technology from power plant designs with post-combustion capture to the processing of off-gas generated in metallurgical facilities is also reviewed.IntroductionGlobalization and international economic growth have led to an increase in energy demand worldwide, and a corresponding increase in greenhouse gas (GHG) emissions. In 2005, 81% of global energy supply came from fossil fuels [1]; and while alternative energy technologies are emerging, it will require many decades to curb society’s fossil fuel dependence. Given the global concern of climate change and its scientific relationship with anthropogenic carbon dioxide (CO2), there is at present great interest in the development of techniques to reduce emissions of CO2. While most of these efforts are related to power generation and energy efficiency, the development of technologies for CO2 capture may offer opportunities in reducing emissions from industrial processes."

Jan 1, 2008

By Huayi Yin, Wang. Dihua, Wei Xiao, Xuhui Mao, Diyong Tang

"The world production of crude steel reached 1.55 billion tons in 2012,which generated ~2.5 billion tons of CO2. Electrochemical metallurgy especially through high temperature molten salt electrolysis with renewable electricity stands for a great opportunity for producing “green” metals. In recent years, electrolytic production of iron without emission of CO2 in different molten salt systems has been reported. A cost-affordable inert anode is the key to produce acceptable eco-friendly iron by the novel molten salt electrolysis processes. Based on the authors’ research, this paper will discuss iron production by molten salt electrolysis using a nickel alloy inert anode. On the other hand, the paper also covers a novel molten salt CO2 capture and electrochemical transformation (MSCC-ET) process, in which CO2 is effectively converted to value-added carbon and oxygen in a molten bath using a cost-affordable nonconsumable SnO2 anode.1. IntroductionEnergy and materials are cornerstones to support the development of human society. The traditional primary metal production, especially iron and steel, and electricity production are mainly based on the reactions between carbon (coal) and oxygen (represented by equations (1) and (2) respectively), which produce huge amount of CO2.MxOy + 0.5y C = x M + 0.5y CO2 (g) + Q1 ( 1 )C + O2 (g) = CO2 (g) + Q2 ( 2 )In 2012, the world production of crude steel reached 1.55 billion tons, of which 46.3 %, ~0.7165 billion tons were produced in China. Based on the average level of 1.7t CO2 emission per ton steel, more than 1 billion tons of CO2 generated from steel industry in China in the year. Besides the iron and steel industry, thermal power plant leads the CO2 emission in both USA and China. The total consumed electricity in China increased to 4959 billion kWh in 2012, ~70% of it was from coal fired power plant. The average CO2 emission for electricity production in the typical thermal power plant in China is around 0.78 kg kWh-1. It accounts for ~ 3.868 billion tons of CO2 emission from thermal power plant in 2012 in China."

Jan 1, 2014