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By Robin Perry, Claude Bazin

"Discrete transfer functions which use the grinding circuit feed tonnage to predict mass flowrates at reagent addition points in a flotation circuit were calibrated using a dynamic grinding/flotation circuit simulator. Predicted mass flow values are multiplied by reagent addition ratios to obtain actual reagent flow. The transfer functions are currently integrated into the distributed control system of Les Mines Selbaie.IntroductionThe development of adequate tools for the control of flotation processes is a continuous challenge. Since the early 1970s there have been numerous publications dealing with practical aspect of control of flotation processes. Most plants use a combination of feedback and feedforward controls to reduce the effect of the following flotation process disturbances (McKee, 1991):• changes in throughput;• changes in feed grade;• changes in particle floatability (size, liberation, surface oxidation ... ); and • deliberate changes of setpoint;Feedforward control manipulates variables such as reagent and/or air flow rate to attenuate the effect of disturbances such as changes of feed rate and mineral content. The feed forward strategy is driven by measurements of these disturbances. Feedback control is used to maintain process variables to targeted set-points of concentrate or tails grades. The feedback control action is driven by deviation from the set-point, caused by a deliberate change of set-point or disturbances.This paper proposes a method to improve feed forward control schemes by the addition of a simple model for solids transportation. The feedforward strategy considered in this paper is the ratio type, in which the manipulated variable is changed according to a predefmed ratio between this variable and the measured disturbance. A typical example is the ratio of the reagent addition to mass flow of ore.The paper reviews the state of the art in feed forward control strategy applied to flotation processes and describes the method used for predicting mass flow rates. The last section shows an application of the method in the Les Mines Selbaie flotation circuit."

Jan 1, 1994

By C. Bazin

"Discrete transfer functions which use the grinding circuit feed tonnage to predict mass flowrates at reagent addition points in the flotation circuit were calibrated using a dynamic grinding/flotation simulator. Predicted values are multiplied by g/t ratios to calibrate reagent flow. The transfer functions are currently integrated into the distributed control system at Les Mines Selbaie.INTRODUCTIONThe development of adequate tools for the control of flotation processes is a continuous challenge. Since the early 1970's there have been numerous publications dealing with practical applications of flotation process control. A review of that literature shows that basic feedback and feedforward controls are the two preferred strategies for flotation processes. Some advanced control schemes started to emerge (e.g. Zaragoza and Herbst, 1988). Feedforward and feedback aim at reducing the effect of the following flotation process disturbances (e.g. McKee, 1991):0 Changes in throughput;0 Changes in feed grade;0 Changes in particle floatability (size, liberation, surface oxidation ... );0 Deliberate changes of set-point;Feedforward strategy acts on manipulated variables, mainly reagent addition, to attenuate the effect of disturbances such as changes of feed rate and grade. The feedforward strategy is driven by measurements of disturbances. Feedback control acts to compensate unmeasured disturbances, such as ore floatability, and to bring process variables to targeted set-points of concentrate or tails grades. The feedback control action is driven by set-point error, caused by either a deliberate change of set-point or unaccounted disturbances.This paper proposes a way to improve feedforward control schemes by addition of a simple model of solids transportation. The feedforward strategy considered in this paper is of ratio type, i.e. the manipulated variable is changed according to a predefined ratio between this variable and the measured disturbances. A typical example is the ratioed reagent addition to mass flow of ore."

Jan 1, 1993

By C. M. G. Wortley

One of the major deliverables of the AMIRA P754 Project, which was sponsored by several major mining companies, was a code of practice and guidelines for metal accounting for the mining and metallurgical industry. These had the objective of improving the auditability and transparency of metal accounting from mine to product, thus assisting in good corporate governance. The overriding objective of mass measurement for metal accounting is to establish the mass of the particular material or component present at a specific time, or the mass flow of that component over a defined time period, to a defined accuracy suitable for metal balancing. As such, it is the first measurement in the chain that includes sampling, sample preparation and analysis, each of which introduces its own errors. Materials often contain moisture, the proportion of which must also be established in order to obtain the dry mass. They may also have to be measured as a volume or mass/mass flow of slurry, or in stockpiles or storage areas, in which case the relative density must be measured. Both the density and moisture measurement often introduce significant error. Whereas a great deal of effort has been directed at sampling, sample preparation and analysis to improve accuracy and establish the error, the same can seldom be said for the mass determination, including the moisture and density measurements. The possible major causes of error are highlighted and methods of reducing them discussed. Mass measurement can be classified into those measurements necessary for custody transfer and primary accounting of the input and output streams to a plant or operation, and measurements required for secondary accounting, or management control. The latter include intra company transfers and plant area performance, and those required for plant control only. This paper is concerned only with primary accounting measurements. The code and best practice state that the equipment should be certified (as sized) as is required for custody transfer. The most accurate and precise of the various possible methods is the static measurement of mass on a weighbridge, platform scale or a weigh bin. If static measurement is not possible, which is often the case for ore fed to a plant, possible alternatives are electromechanical conveyor belt weighers or in-motion weighing of rail trucks. In all cases the material must be adequately sampled to enable a representative moisture content to be determined to calculate the dry mass. Where material is flowing inside conduits, only certain types of the multiplicity of flow meters available may be used and, in the case of slurries, very few flow meters are suitable. As most flow meters measure volume or velocity, the density of the material must also be measured. The basic requirements in order to achieve satisfactory results for the mass, of the component of interest, are listed, as well as common problems and pitfalls encountered in practice. The measurement of the mass of stockpiles and in-plant stocks, often required for metal accounting, is often the largest source of error in metal balances. The reasons for this and methods for reducing and managing the effect are discussed.

Jan 1, 2009

The Estonia Mine, operated by Eesti Energia Kaevandused AS (EEK), the mining division of the Estonian Government's energy company, Eesti Energia AS, is a large room and pillar mine located in Eastern Estonia. It supplied approximately 4.9 Mt/a of oil shale in financial year ending 2010, which is used for electricity and shale oil generation. Due to the Estonian climate and the power station's need for a dry product, Estonia Mine has developed a planning system where short-term demands of the power stations dictate the schedule. Such an arrangement requires maximising flexibility and consequently the mine only operated for 199 days in 2010.The footprint plays a key role in achieving mass mining rates as the 12 km + 12 km lease area allows the mine to split into mining districts that act independently of each other and maximise the number of work areas available. Coupled with this, the geology of the mine is relatively homogenous over the mining lease, simplifying the mine design and production methods.During the last five years, EEK has commissioned a comprehensive conveyor network. Consequently, material handling only requires loaders to dump oil shale direct from the production face onto a chain conveyor that feeds the conveyor network that ultimately supplies the enrichment plant. Dewatering is also of critical importance, with 90 Mm3 of water discharged annually. EEK uses large trenches up to 3.5 m deep and 1.2 m wide to channel groundwater. Track mounted mechanical saws are used to cut slots in the floor, to control overbreak in blasting these trenches.EEK has introduced Salzgitter Machinenbau GB 280S auger drills that drill three 280 mm diameter holes simultaneously. This has improved void hole drilling times and reduced the drilling required for each face, reducing the overall production cycle time. Blasting activities have also been decoupled from other mining activities negating the need for firing times through the use of small independent firings, required to control vibrations.

Dec 6, 2010

By R. M. Caitlin

QUITE a number of years ago in looking for basic facts, it seemed obvious, in view of an unquestion-able supply of raw material and an extensive requirement probable in the near future, that the funda-mental requirement of any shale-oil industry was mass production 'by a continuous process. This decision greatly simplified matters, as it eliminated all considera-tion of externally-heated retorts, and all batch processes, which only utilize a part of the capacity of the interior space because, unless the ashes are removed as rapidly as formed, the space occupied by them is dead, instead of being occupied either by shale in active distillation or in drying out and heating up preparatory thereto. A second imperative and basic necessity soon appeared as a natural sequence, namely, the fixed carbon of the spent shale must be utilized to supply the heat for the eduction of the oil. PRODUCTION OF THE CRUDE As the production of the crude oil is the first and most important step in the utilization of oil-shale, being the only source from which the multitude of possible by-products can come, each by a special treatment of the crude oil, I will devote the time allotted to me to the subject of crude oil production-its cost expressed in terms of tons treated per man per shift. The costs of mining the shale and refining the crude shale oil vary with local conditions and are not specially influenced by the source of the crude. But the cost of distilling the shale in terms of tons per man shift seems to be the basis of any proper comparison of costs. After considerable experimenting, ranging from laboratory tests up to and including quantities of fifteen to twenty tons, it was evident that a plant might be made up of an indefinite number of units operating in concert. The economic size of the units, however, would .have to be determined by experiment. The general theory of our process contemplates a regulated combus-tion of the fixed carbon in the spent shale, in its incan-descent condition after all the oil has been driven out of it; and a transfer of the resultant heat to the mass of raw shale above.

Jan 1, 1927

By C. E. Schmidt

Condensate waters from the Bureau of Mines Synthane process for coal gasification have been investigated by mass spectrometric methods to determine the organic contaminants. Waters from the gasification of six coals were extracted with methylene chloride, yielding 0.6 to 2.4 weight-percent extractable material. Using high-resolution mass spectrometry (HRMS), combined gas chromatography-mass spectrometry (GC-MS), and low-voltage mass spectrometry, 60 to 80 percent of the extract was found to be phenolic. About 20 organic contaminants have been identified and are present in the condensate waters from each coal gasified. The relative distribution of contaminants in the condensate water was nearly the same for the six coals gasified under various conditions; phenolic compounds were the most abundant in all cases.

Jan 1, 1974

By V. L. Stolyarova

The high-temperature Knudsen effusion method was used to study partial pressures of vapour species, activities of components and the Gibbs free energies in the DyF3-Dy2O3 system at the temperature (1357±5) K. Partial pressures of vapour species were obtained by the ion current comparison method, with the DyF3 partial vapour pressure over pure DyF3 as a standard. The equilibrium constant of the gaseous reaction DyF3 + DyOF = Dy2OF4 is evaluated. Thermodynamic data obtained are in a agreement with the available phase diagram of the DyF3-Dy2O3 system. Results of the present study illustrate the negative deviations from the ideal behaviour in the system.

Jan 1, 1997

By Kumar M. Lyer

The channel reactor for ferrous and nonferrous processing has been modeled as a combination of ideal reactors. Cold model studies simulated the counter-current flow of slag and matte (or metal) with high-strength submerged gas injection. A composite model has been developed which describes the mass transfer between the two liquid phases, including the transfer of minor elements. The residence time for the matte droplets in the matte/slag emulsion is compared with the settling rates for the matte droplets in the slag to determine their relative importance in the mass transfer between matte and slag. The governing equations for mass transfer have been developed using correlations for the mass-transfer coefficients in the continuous and dispersed phases. An application of this scheme to a typical copper smelting system is presented.

Jan 1, 1993

By J. K. Brimacombe, F. D. Richardson

Studies have been made of interfacial turbulence occurring in reactions in which indium, zinc and cadmium, dissolved in amalgams, are oxidised into aqueous phases by ferric or mercurous ions. It has been found that this turbulence occurs when the concentrations of oxidising ions in the aqueous phase become sufficiently great. These concentrations are the same as those at which the mass-transfer coefficients in the aqueous phase increase sharply when both phases are stirred by gas bubbles rising through them. The effects of gas flow rate on the mass-transfer coefficients for zinc in mercury have been established, and the oxidation of pure mercury has been investigated. The relevance of the work to processes involving liquid metals is discussed

Dec 1, 1971

By E. S. Vargas, T. W. Chapman, Samuel W-S Tse

Models for interphase mass transfer rates in the solvent extraction of metals are developed for zinc and copper chlorides being extracted by trilsooctylamine and for copper extraction by LIX 64N from ammonia solution. The approach is to adopt a stagnant film model on which film thicknesses are known and to derive the interfacial metal fluxes for the case where all reversible reactions are fast and locally equilibrated. A growing drop mass transfer cell is used to measure extraction rates. It is found that for the cases studied the transfer rates are mass-transfer limited On the other hand, copper extraction by LIX from acidic solution exhibits slow reaction kinetics, and earlier kinetics models are confirmed. Interactions that cause varying selectivity in the simultaneous extraction of copper and zinc chlorides are demonstrated.

Jan 1, 1981

By E. Barsky

"Theoretical notions of mass transfer processes in cascade separation of bulk materials have not been adequately developed as yet (Barsky M.D. 1980). In this paper we have derived linear difference equation of the second order for a cascade with initial feeding top any stage proceeding from mass exchange regularities. The solution of these equations has allowed us to determine quantitative dependences of the material distribution over the cascade stages, which serve the basis of the method of predictive estimate of the process results. We have also examined the model of the material distribution coefficient formation at individual cascade stages.We have checked the adequacy of this model to experimental data. It is noteworthy that the obtained theoretical results are phenomenological, i.e. they can be applied to the processes of separation of different physical nature, e.g. of isotopes, liquid media, gases, etc.INTRODUCTIONRecently, the processes of cascade separation of bulk materials have found broad application in various industries. They ensure a high separation efficiency and high-quality composition of final products. Although specialized literature gives serious attention to cascade processes [1], their theory is not sufficiently developed yet. To achieve optimal organization of this process, we examine mass transfer in a cascade gravitational classifier with stages of identical design."

Jan 1, 2016

By K. H. Bech, S. T. Johansen

"The mass transfer at fluid-fluid interfaces due to turbulent agitation is investigated theoretically. In particular a theory is derived for interface stresses due to interface energy and surface renewal. This theory indicates that surface renewal may take place if the geometry is sufficiently large and if surface tension is sufficiently low.By using a model for a typical turbulent structure we compute the interface mass transfer for a stressless interface and a fully interface. Results for the general situation is not presently available. The computed results are used to derive analytical expressions for the mass transfer based on turbulent kinetic energy and free stream turbulent length scales.One important application of the theory is the mass transfer at the electrolyte side of the bath-metal interface in the Hall-Heroult process. For this process we show that mass transfer should be expected to be of the rigid surface type."

Jan 1, 1999

By G. S. Gupta

To predict the iron oxide concentration a mass transfer model has been developed for an Induction Smelting Process (ISP) in which self-fluxed composite pellets (made of iron ore, brown coal and lime) are melted in a single phase induction furnace in conjunction with top blown oxygen. Transient mass balance equation with complex boundary conditions has been worked out by adopting a relatively new approach known as the cell model approach. These equations have been solved numerically using finite difference technique to obtain the iron oxide concentration profile in the ISP. Numerical and experimental results obtained for iron oxide concentration show a reasonable agreement with each other.

Jan 1, 1991

By A. Kar

A mathematical model is presented for pure titaqium deposition from titanium tetrabromide on a stainless-steel (SS 304) substrate. Five three-dimensional, transient, and nonlinear partial differential equations are used to account for the diffusion of various species inside the deposition chamber and the thermal decomposition of titanium tetrabromide, titanium dibromide, and titanium monobromide at the surface of the substrate in order to determine the thickness of the titanium film deposited on the substrate. The effects of various process parameters on the deposition and shape of titanium films are examined, and under certain conditions, the deposited titanium films are found to have volcanic profiles.

Jan 1, 1992

By Ramani R. V

There are many important physical phenomena in mine ventilation which involve transient mass and heat transfer processes. These processes have been modeled using differential equations often solved with close form solution. Within the last two decades, many numerical schemes have been devised to solve these mass-transfer problems. Much of this effort has focused on variants of the finite element and finite difference methods. In this paper, the solution of mass transfer models in mine ventilation by finite difference technique is discussed. Specifically, the computational effort and the accuracy of the solution are presented.

Jan 1, 1988

By H R. C Pratt, G W. Stevens

Hydrodynamic and mass transfer performance are presented for a 72.5 mm diameter pulsed disc and doughnut column of the type used by Western Mining Corporation, Olympic Dam Operation, for the extraction of uranium from sulphate media using Alamine 336 as extractant. For the present purpose, 4.0 g/L sulphuric acid was used as solute. The mass transfer data were interpreted in terms of the diffusion model, thus accounting for continuous phase axial dispersion. The results indicated that an efficiency corresponding to approximately one transfer unit over the 1.0 m height of the column was obtained. This efficiency is comparable to that observed by Gottliebsen (1997) for a pulsed perforated plate column using 173 gm/L sulphuric acid.

Jan 1, 2000

By V. E. Ross

A model has been developed that describes the behavior of mineral particles and water in the cleaning zone of flotation columns. The possible detachment of particles from their sites of attachment at the bubble surfaces is related to the flux of bubble surface area with increasing distance from the interface between the collection and cleaning zones and the late at which floated particles are transported into the cleaning zone. The drainage velocities of floated and entrained particles are calculated from the drainage velocity of water and the properties of the particles. The effects of wash water and inhibited drainage in the froth are also explicitly accounted for.

Jan 1, 1988

By Thomas P. Kwiatkowski, John S. Anderson

The Massachusetts Bay Transportation Authority (MBTA) has undertaken an under-ground transit project to extend public transportation service from downtown Boston to the South Boston Piers area. This new system, known as the Transit way, will connect existing subway lines to this area which is comprised of approximately 300 acres, in light of the potential for 21 million square feet of development by 2010. This system includes construction of a concrete immersed tube tunnel crossing of Fort Point Channel. The crossing will be accomplished in the highly congested setting of down-town Boston and will be located just to the north of the famous Boston Tea Party ship exhibit and amid major Central Artery Construction activity. The most recent concrete tube constructed in the United States was in 1962. The Fort Point Channel Crossing will employ current design and construction methods commonly utilized in the Netherlands, Australia, Hong Kong and elsewhere. This paper will present the design philosophy, planning, and evaluation of alternative crossing methods which led to the selection of the concrete immersed tube tunnel and construction techniques envisioned for this particular application.

Jan 1, 1997

By David E. Thompson, Edward S. Plotkin

The Massachusetts Bay Transportation Authority (MBTA) Red Line Extension Northwest is nearing the final stages of construction. The 3. 1 mile extension of the Red Line from the existing Harvard Square Station in Cambridge, Massachusetts to Alewife Brook Parkway in Cambridge, includes a large, near surface, hard rock, rapid transit chamber at Porter Square in Cambridge (Figure 1).

Jan 1, 1983

By James M. Baylor

Ladies and geltlemen, it is indeed a privilege and a pleasure to be here in Denver with you. I want you to know too I'm not a stranger out here. Golden, Colorado is the headquarters of A. T. Massey Coal Company's Western Division, headed by Vice President, Gregory H. Hoyl. I also have a very close friend and fraternity brother who works and lives in Denver so I could talk on and on about this area and our western coal properties, but it's Massey's coal terminal business I'm to focus in on today, and that's a horse of a different color. So on to the subject of my address: MASSEY COAL TERMINAL INVOLVEMENT As I have stated on other occasions, A. T. Massey Coal Company, for better or for worse, is in the coal terminal business.

Jan 1, 1981