Search Documents

By D. Collins, J. Winfield, V. Gangrade, B. Slaker, S. Braganza

"Researchers at the National Institute for Occupational Safety and Health (NIOSH) are investigating the unique pillar stability issues associated with room-and-pillar mining in dipping underground stone mines. The objective of this paper is to study the post-blast impact in and around a pillar, using microseismic monitoring. To accomplish this, a microseismic monitoring system has been installed at a dipping underground stone mine in central Pennsylvania. The microseismic system is comprised of 18 uniaxial accelerometers; 12 sensors are installed in a single pillar and 6 sensors are installed in the surrounding area. More than 4,400 microseismic events have been located near the study pillar following the blasts. The number of triggers increased significantly following the blast, and the trigger rate in the first five minutes was 60 triggers per minute and three triggers per minute over the next three hours. The processing of high-quality triggers indicated a large number of low magnitude microseismic events near the blasting face. The event locations were identified more accurately by using a 3D-velocity model, with an average 9 m expected location accuracy for this array calculated using the system data. Seismicity was absent from the core of the pillar, but significant numbers of events were found following cutter roof along a crosscut as it was developed as well as in the location of a rib failure event. Additionally, the events were located in the roof, showing high number of microseismic events within 0–10 m of the roof line compared to 10–30 m above the roof line.INTRODUCTIONGround control stability is essential to any mining operation for ensuring mineworker safety and health and preventing catastrophic failures of underground structures. The National Institute for Occupational Safety and Health (NIOSH) has conducted research in stone pillar design and has established fundamental pillar design guidelines for the underground stone industry, which resulted in the development of the S-Pillar program (Esterhuizen et al., 2011; Esterhuizen and Murphy, 2018). However, the data that makes up the S-Pillar database consists of shallow depth, flat-lying, single-level mining operations. Therefore, to expand this dataset and to develop guidelines for challenging conditions such as dipping and multi-level mines, NIOSH is currently conducting detailed pillar response investigations at mines with these characteristics. The study is being conducted using multiple research approaches, including seismic modeling and tomography, numerical modeling (Sears et al., 2019), stress monitoring, and LiDAR-based laser scanning (Slaker, Murphy, and Winfield, 2019). This paper discusses the findings from the microseismic monitoring system installed at the Pleasant Gap Mine, a steeply dipping underground limestone mine in central Pennsylvania."

Jan 1, 2019

By J. Lindström, J. Hamuyuni, M. Lundström, J. Aromaa

"The rising demand for metals today, coupled with the scarcity of primary sources for raw materials threatens both technological advancements and industrial manufacturing. In order to meet the demand, metals and other resources trapped in waste streams, have to be harnessed. This philosophy supports circular economy, where metals and other resources are kept in a closed loop. The pickling acid recovery system of most stainless steel production is one such example where the dissolved metals such as iron, nickel and chromium are currently not completely recovered due to the limitations of the current technologies. The aim of this study was to assess the available metals recovery methods from extremely concentrated acids. The main aim is to simultaneously recover metals and keep sulphuric acid reusable in acid circulation process. From the available literature, the most promising methods were chosen for laboratory experiments. Based on experimental work, the results and observations of electrodeposition, solvent extraction, and freeze crystallization are provided. KEYWORDS Pickling acid, metal recovery, solvent extraction, cathodic polarization, Freeze crystallization. INTRODUCTION Pickling in stainless steel production is an essential surface treatment process (Regel-Rosocka, M. (2010); Agrawal and Sahu, 2009). It is applied for removing surface films such as oxides and chromium-depleted layers to improve the corrosion resistance and surface finish of steel (Regel-Rosocka, 2010). Whilst the process greatly improves the surface finish of the stainless steel, it generates large amount of used acid, containing dissolved metals including chromium, iron, and nickel (Agrawal and Sahu, 2009). Recovery of acid is common practice for most steel producing industries (Nyman and Koivunen, 1986). In this work, acid regeneration process is investigated so as to simultaneously reusing sulfuric acid and recovering the dissolved metals. Recovery of valuable metals even in very small amounts would also bring additional revenue to the steel production industry. At a time when metal production has also been challenged by lack of natural resources for raw materials, secondary sources for metals such as the acid pickling process therefore, have greater potential as supplements. From earlier studies, electrodeposition (Giovanardi and Orlando, 2011; Kuznetsov et al., 200; Rögener et al., 2012; Surviliene et al., 2006), solvent extraction (Alguacil and López 1996; Haghshenas et al., 2009; Kesieme et al., 2013) and freeze crystallization (Beyer et al.,2003; Hasan et al.,2017; Van der Ham et al., 1999) are some of the most established potential methods. Earlier studies have also shown that simultaneous recovery of acid and metals would require combination of different methods. This is primarily due to the nature of very stable metal containing complex compounds formed during pickling. These complexes must be broken down to free the metals for further recovery processes."

Jan 1, 2018

By Muhammad Azeem Raza, Muhammad Zaka Emad, Muhammad Usman Tahir, Saqib Ahmad Saki, Muhammad Usman Khan

Shotcrete is a key initial rock support component used in underground mining and civil projects. The strength of shotcrete plays a vital role in providing and deciding the support adequacy. The strength of shotcrete is evaluated by its uniaxial compressive strength (UCS) test that is usually conducted on extracted core samples. Shotcrete cores are commonly extracted from the test panels along the direction of its application; thus, its strength perpendicular to the direction of application is often neglected. The true bearing strength of shotcrete is thereby ignored despite the fact that higher stresses act normal to the direction of its application. Although the anisotropic behavior of shotcrete is well reported, no study has reported extensive testing of this scale and nature. This study reports extensive testing of shotcrete cores extracted from tunnels of a mega hydroelectric project in Pakistan. The study reports 7- and 28-days strength tests of shotcrete cores. The research also investigates the anisotropic behavior of steel fiber reinforced shotcrete and suggests that shotcrete exhibits higher strength perpendicular to the direction of its application.

Dec 26, 2022

By Deniz Akbay

The strength of rocks and soil is a crucial design parameter in engineering projects, and it can be determined through various test methods such as uniaxial compressive strength, tensile strength, and shear strength. The point load index test is a popular indirect test method for predicting the uniaxial compressive strength of rocks. However, the reliability of the point load index’s estimation of uniaxial compressive strength of rocks is questioned due to the wide range of coefficients that are used to predict uniaxial compressive strength of rocks using point load index values. Factors such as the shape and type of rock specimen, practitioner, and test apparatus used can affect the accuracy of the point load index test. This study investigated the effect of four different specimen shapes used in point load index test (diametral, axial, block, and irregular lump tests) in predicting the uniaxial compressive strength. The rock samples were tested using four test procedures which are called diametral, axial, block, and irregular lump tests. The results showed that the irregular lump test was the most accurate in predicting uniaxial compressive strength, with the highest correlation coefficients and lowest mean absolute percentage errors. The point load index test can be used as a reliable predictor of uniaxial compressive strength of rocks when the irregular lump test is preferred.

Oct 18, 2023

By Md. Z. Quadir, M. Ashraf, A. A. H. Ameri, J. P. Escobedo-Diaz

The quasi-static mechanical response of hot rolled lean duplex stainless steel 2101 (LDSS 2101) in rolling, transverse and normal directions under compression loading has been investigated for its perceived anisotropic behaviour. Microstructural characterization is performed by optical microscopy and Electron Back Scatter Diffraction (EBSD) to qualitatively define the influence of the texture by using Taylor factor and grain sizes, and phase boundaries by utilizing the modified Hall-Petch formula. It was observed that LDSS2101 does not show anisotropic behaviour in terms of the mechanical strength but it has a clear anisotropy in the lateral strains; the microstructural explanation of this response may result from the phase boundaries strengthening.

Mar 1, 2017

By D. Georgiou

Direct sulphuric acid leaching of nickeliferous limonites is the process of choice to recover nickel and cobalt from equatorially located lateritic ores. These ores are rich-in-iron (-45 wt%) existing in the form of goethite enriched with nickel. The merit of this process is due to its high nickel selectivity because of simultaneous iron separation and acid regeneration. Under acid leaching conditions (-250 to 270°C) iron follows an acid dissolution-hydrolytic precipitation path yielding a very low concentration level depending on temperature and acidity of the final leach liquor. The primary precipitation product of iron is hematite which also forms as a scale on reactor internals along with co-existing aluminum. In this paper, an overview of the behaviour of iron solid products under process conditions is made. The evolution of goethite to hematite transformation, as well as the role of iron in reactor scale production, are studied using SEM/EDX characterization techniques.

Jan 1, 1995

By R. Hewer

Transition metals have been widely used in medicine throughout history. The medicinal use of metals extends back to the earliest recorded history when the Chinese used gold as treatment for a variety of ailments. The ancient Egyptians used copper to sterilize water and mercury was reportedly used by Hippocrates in 400BC. Thereafter, numerous other metals have been used as treatment throughout the centuries. For example, zinc sulphate was used as an emetic in the 17th century and zinc oxide was used to treat epilepsy in the 18th century. This use of metals, and numerous other instances, which have been well described in Sneader 2008,1 make for interesting reading but largely occurred prior to the advent of rigorous scientific method. Therefore, although there are exemptions, most therapeutic applications of metals prior to the modern age lack scientific grounding and have been found to be mostly ineffective. Of more relevance are metal-based medicines approved by regulatory bodies (i.e. Food and Drug Administration; FDA) that are in current use as therapeutic drugs. There are presently a large number of metal-based drugs that are approved for use by the FDA ranging from over the counter medicines, such as bismuth subsalicylate for gastrointestinal problems, to prescription drugs such as lithium carbonate for the treatment of manic depression. The list of metal-based medicines approved by the FDA not only incorporates base metals but also includes precious metals. Platinum complexes have been found to be potently active against several different types of cancers while gold complexes have shown application as treatment for rheumatoid arthritis (RA). With the well-established foundation that exists for metal-based medicines, it is imperative to continue exploration into new therapeutic areas. The precious metals; gold, ruthenium and platinum, continue to attract scientific interest in the field of biomedicine and have been widely researched. Scientific studies conducted on gold complexes have demonstrated the potential of this metal for the treatment of HIV/AIDS, cancer and malaria. These diseases are also specific health concerns for developing nations; countries where disease has devastating impact. Within South Africa alone, an estimated 5.7 million people are infected with HIV/AIDS,2 approximately 7 000 new cases of malaria are reported annually, and it is projected that 1 in 4 persons will develop cancer. Continuous development of therapeutic drugs to combat these diseases is therefore apriority, and the exploration of gold-based compounds for this purpose is warranted.

Jan 1, 2009

By N. Hamlef

In this study, the effects of heat treatment on phase formation and surface morphology of the Cr-Pt coated system are investigated using X-ray diffraction and electron microscopy techniques. The CrPt andCr4Pt (Cr3Pt - A15 type) phases were formed after heat treatment of the coated samples. Heat treating at 1000°C renders a distinct island coating morphology that is non-continuous in nature. A diffusional model is proposed for this coated system with regards to the surface morphology formation after heat treatment.

Jan 1, 2014

By Tristan H. Jones

Rib-related accidents in underground coal mines continue to cause injuries and take lives at a rate of 1.3 fatalities per year for the last 17 years. Prevention of these accidents cannot simply be a matter of installing more rib support, though the eventual final solution will undoubtedly include that component. Ultimately, rib safety will be brought about through an understanding of the causes and mechanisms that cause rib fatalities, and by fine-tuning mining methods and procedures that are currently in place. This paper investigates the factors likely to be most influential in the occurrence of rib fatalities. A careful analysis has been conducted of the rib fatality reports documented by the Mine Safety and Health Administration between 1996 and 2013. The primary outcome is the determination of the relative impact of each type of rib fatality factor and a better understanding of the impact each factor has. Among the rib fatality factors considered, the influence of rib profileis considered for the first time. Mining height, rib stratigraphy, mining cycle, and the standing position of a miner next to a pillar are also considered. Questions are also raised about the current interpretation of rib fatalities due to mining depth, with the indication being that mines operating at the greatest depths may actually have the most respectable rib fatality record among all mining depths. Additionally, a new method of considering rib exposure is developed. Based on the results, recommendations are made for future work. By gaining a better understanding of how particular factors contribute to rib fatalities as opposed to rib failure or stability, it is hoped that future efforts can be more precisely directed towards the desired outcome of fatality reduction.

Jan 1, 2014

By Y. -L. Chiang

Paper written on project work carried out in partial fulfilment of BSc (Eng) (Chemical) The generation and control of manganese sulphide particle size distribution using various mixing configurations were investigated. Specifically, this paper discusses how varying mixing intensities on a macro and micro scale affect the resultant manganese sulphide particle size distribution (PSD) at a constant concentration. The mixing variations were achieved using various Y- and T-mixers as premixing devices into a jacketed, agitated vessel. The reagents used to generate the seeds were aqueous manganese sulphate and sodium sulphide solutions. The results showed that the absence of micromixing resulted in very poor control of the particle size distribution, the particle size and the number of particles produced. This was due to the fact that the macromixing time is much greater than the corresponding precipitation time, resulting in different mixing regions existing within the reactor. From the micromixing experiments, the T?mixer was found to be the most effective mixing device at lower concentrations due to the T-mixer providing a faster mixing time than the other mixing configurations, thereby effectively localizing the supersaturation and hence controlling the precipitation. The results obtained from the direct addition without the extension pipe (i.e. short mixing time) indicated a general increase in mean particle size and decrease in total particle number at reagent concentration of 0.007 mol.dm-3as compared to the corresponding micromixing experiments. The phenomenon may be due to incomplete crystallization at the immediate exit of the mixing device. Further experiments need to be conducted before any conclusions can be drawn about the precipitation mechanisms.

Jan 1, 2007

By David Hanson, Sean Warren, Chaparral Berry

"Coal bumps, also referred to as dynamic failure events or coal bursts (Lawson, Weakley, and Miller, 2016), continue to be a hazard in underground coal mines. While current design methods have significantly reduced the occurrence of coal bumps, they have not been completely eliminated. This paper investigates a correlation between coal compositional components, coal molecular structure, and probability of coal bumps in an effort to deepen understanding of coal behavior in an effort to reduce hazards in underground coal mines.Samples from the Penn State Office of Coal (PSOC) Department of Energy Coal Samples (DECS) were obtained for Fourier Transform Infrared Spectroscopy (FTIR) analysis using the KBr pellet method. Peaks indicative of the coal molecular structures were obtained using spectral integration software. These data, combined with published elemental data, were compared to historic bump occurrence in order to establish a possible correlation. Finally, results based on multivariate analysis of the elemental and FTIR data with bump status as the dependent variable suggest that elemental sulfur and molecular structure can be used as an indicator of bump susceptibility within the sample set considered.INTRODUCTIONThe study of coal requires consideration of multiple variables: percentages of organic and inorganic components, organic component origins, coal age, pore structure, cleat density, elemental composition, etc. Examining coal in situ increases the number of variables, such as coal depth, seam thickness, surrounding stratigraphy, and so forth. This collection of variables influences the subsequent behavior of coal simultaneously, and weighing their relative impact is a challenge for researchers. “A problem never exists in isolation; it is surrounded by other problems in space and time” (Ackoff, 1956). Having a substance such as coal that we know so much about, and yet so little, we have to ask what can be learned.An experimental study using Fourier Transform Infrared Spectroscopy (FTIR) was undertaken to determine if the chemical structure of coal contains information which may lead to a better understanding of triggers or attributes which may, in turn, lead to an increased probability of a dynamic failure event. While a full analysis of the factors driving dynamic failure are beyond the scope of this study, it is possible that a better understanding of the chemical structure of coal will lead to an increased knowledge of its inherent behavior, including its propensity to burst."

Jan 1, 2019

By M. Mathiba

High CO2 fluxes associated with reclaimed coal mine spoils pose an environmental hazard where such sites are used for building. CO2 concentrations in excess of 25% have been reported in homes constructed on or down gradient of such spoils. The objective of this study was to investigate the effect of a mitigation trench used at one mine site on CO2 fluxes across the trench using chamber?based trace gas measurement. LI8100 automated CO2 flux system was used to measure CO2 fluxes from 32 sample points located across a deep mitigation trench on June 8 and 9. The maximum recorded fluxes were 7.29 and 8.18 µmol/m2/s, with averages of 4.15 and 5.50 µmol/m2/s, up and down-dip respectively. These preliminary results show CO2 flux is higher up-hill than down-hill at 95% significant level. This work shows that flux measurement can be used to investigate CO2 migration on reclaimed mine land. Further work is necessary to allow geostatistical modeling of the spatial variability of CO2 fluxes over reclaimed coal mine spoils. Knowledge gained would assist mining practitioners and regulators in reclamation planning for envisaged post-mining land uses.

Jan 1, 2010

By P Moarefvand, M Osanloo

The anticipated economic life of the mine, which defines the rate of mine production, is dictated initially by the design capacity of the mill/concentrator and the production capacity of the mine relative to the grade and tonnage of ore that can be encompassed by the pit design. A small pit will result in smaller investment and cash flow; in contrast, a larger size of pit will increase capital investment and annual revenue. Since open pit mine design and long-term production sequencing are essentially based on three-dimensional block models, changes in block dimensions leads to different mine sizes, and therefore changes in the mine life. The physical characteristics of the deposit, such as reserve tonnage and ore grade, affect the expected future revenues from the mining project, and consequently they affect the life of the mine. Large blocks will increase the recoverable ore reserves and production rates and hence increase the mine life. This paper discusses the effects of the block dimension on the commercial ore reserve, grade-tonnage curve and its effect on the production rate, ultimate pit size, mining cost and consequently the mine life. The result shows that block height is the most effective parameter governing the economical life of the mine.

Sep 26, 2011

By A. Çelik

Wheel loaders are widely used in many sectors due to their mobility, operational flexibility, and low costs. The literature is mainly focused on improving the hydraulic, mechanical, and electronic subsystems of these machines in terms of efficiency or developing strategies for controlling these systems. In this study, the effects of the loader operator and different working conditions on the loading performance were investigated. The study was carried out at the Can Lignite Enterprise (CLI), which is a major coal producer in Turkey. In the study, which lasted approximately four months, a total of 808 measurements were performed to investigate seven different scenarios. The effect of a single parameter on loading performance was investigated in the first six scenarios. The results showed that the biggest impact on loading performance was caused by the operator's experience with 63.4%. On the other hand, the worst and most ideal working conditions determined from the first six scenarios were tested in the seventh scenario. It was tested as a script. The test results showed that the loading performance was 285.5% more effective under the most ideal operating conditions compared to the worst operating conditions. In addition, in the study, the loading performances of five loaders with four different capacities were examined in terms of energy efficiency and it was determined that the Kawasaki 115 work machine, which has a higher model and lower engine operating hours, was more advantageous. In the study, various suggestions were developed in parallel with the research results. The most prominent and easiest to implement of these suggestions is related to the selection of the loader operator.

Nov 27, 2024

By C. Chibwe, M. Tadie

Copper electrowinning models are useful for prediction of process performance, optimisation and improved understanding of complex phenomena such as current distribution without the expense of physical experiments. Recently, finite element models such as those generated in COMSOL Multiphysics have been developed for the electrowinning process. The predictive capacity of these models is improved by incorporating physical and chemical phenomena. Since physicochemical properties of electrolytes can have a significant effect on the quality of copper produced, this work was conducted to investigate the effect of such properties on electrodeposition at varying levels of copper, sulphuric acid concentration, iron concentration and temperature, in the presence of a smoothing agent. Tests were conducted at conditions similar to those for industrial copper electrowinning. Mathematical correlations were developed for the following properties; density, conductivity and diffusivity which were compared to existing models in literature and thereafter applied in a COMSOL generated model. The model predicts, current distribution at the cathode surface, deposit thickness (morphology), concentration of species within the cell and current efficiency. Current distribution output shows the impact of several phenomena on the deposit generated including the relationship between increasing copper concentration and current density and lack of influence of acid concentration on this property. Keywords: Electrowinning, physicochemical properties, electrolyte composition, modelling

Jan 1, 2020

By F. S. Hoseinian, D. Deglon, L. leal Filho, M. Safari, T. C. Souza Pinto

This paper investigates the effect of chemical and physical operational parameters on the reverse flotation of Timbopeba itabirite iron ore in a pilot-scale pneumatic flotation cell. Operational parameters include collector and depressant dosages, feed rate, superficial gas velocity and solids concentration. Results show that increasing collector dosage results in an increase in quartz recovery, particularly for the coarser quartz where recovery increases by nearly 30%. Increasing depressant dosage results in a decrease in both quartz recovery and hematite loss, for the coarser hematite particles. Increasing the feed rate has no effect on quartz recovery or hematite loss, suggesting that the pneumatic flotation cell is not residence time constrained. Increasing the superficial gas velocity results in an increase in quartz recovery to an optimum at a Jg of around 0.6 cm/s after which it decreases significantly, particularly for the coarser particles where recovery decreases by as much as 50%. Decreasing the solids concentration does not affect quartz recovery but results in significant decreases in hematite loss. Here, fine and coarse hematite loss decreases from around 25% to 12% and 10% to 2% respectively. Superficial gas velocity and solids concentration are operating parameters which have the largest effect on the flotation performance of the pneumatic flotation cell. Results suggest that this flotation cell should be operated at relatively low superficial gas velocities and solids concentrations. However, these are pilot-scale findings and would need to be tested at an industrial-scale where different operating conditions may be optimal. Keywords: Operational parameters, reverse froth flotation; entrainment; iron ore

Jan 1, 2020

By G. Orhan, C. Arslan

The possibility of producing metallic chromium from Cr2O3 via the aluminothermic route, with no external energy supply, was the subject of this laboratory-scale research. The experimental study focused on investigating the individual effects and quantitative optimization of the charge contents, i.e., the additions of CrO3, Al powder and CaO (or BaO). The highest chromium recovery of 98% was attained with the additions of 12% CrO3 and 1.2 times the stoichiometrically required amount of Al powder. The optimum CaO addition giving the highest chromium recovery was found when the CaO/Al weight ratio in the charge was equal to 0.3. When BaO was used, however, 95% Cr extraction efficiency was obtained at a BaO/Al weight ratio of 0.15.

Jan 1, 2000

By S. M. Bradshaw, C. Dorfling, F. Ngandu

"Selenium removal and platinum group metal (PGM) recovery from copper sulfate leach solutions form an integral part of platinum producers’ base metal refinery operations. Recent studies found that substantially higher PGM recoveries can be achieved if excess thiourea instead of sulfurous acid is used as precipitation reagent; however, the impact of the proposed process on downstream processes was unknown. The objective of the current study was therefore to investigate the effects that excess thiourea and residual selenium present in the rich copper sulfate electrolyte have on copper electrowinning. This was achieved by performing cyclic voltammetry tests using a platinum rotating disk as working electrode, a graphite auxiliary electrode and a saturated calomel reference electrode. A synthetic copper sulfate electrolyte containing 0.01 M Cu2+, 1 M H2SO4 and varying amounts of selenium (20 – 150 mg/L) and thiourea (10 mg/L and 100 – 300 % excess) was used. The results obtained have shown that both thiourea and selenium interact with the cupric ion cathodic reduction reaction. Thiourea polarized the working electrode and lowered the efficiency of the cupric reduction reaction. Tests on the solutions with high selenium concentration showed simultaneous reduction of copper and selenium, which led to copper selenide formation. Nodule formation on the deposit surface also became significant at higher selenium concentrations. Based on these results, it was concluded that precipitation of PGMs from the copper sulfate solution with excess thiourea is not feasible due to the detrimental effect on downstream electrowinning operations.INTRODUCTION During the high pressure oxidative leaching stage in a typical base metal refinery (BMR) circuit, selenium, tellurium and some platinum group metals (PGMs) are dissolved along with the desired copper ions. The impurities (selenium and tellurium) may pass to the copper electrowinning circuit where it can result in the formation of nodular copper electrodeposits or reduced current efficiency. The presence of PGMs in solution, on the other hand, increases the precious metal inventory and potential losses of the operation. Currently, sulfurous acid is widely used for selenium and tellurium precipitation from copper sulfate leach solutions. Sulfurous acid is capable of reducing cupric ions to cuprous ions; the generated cuprous ions then react with Se4+ and Se6+ to precipitate selenium as a copper selenide (Bello, Dorfling, 2014). Recent studies have, however, proposed the use of excess thiourea as a precipitating agent for the removal of selenium and tellurium; it has the advantage of improved PGM recovery in the Se/Te precipitation step (Lottering, Eksteen et al., 2012; Mulwanda, Dorfling, 2015)."

Jan 1, 2018

By D. R. Schmitt, Q. Jia, R. Kofman

"Tests were carried out on clear glass blocks containing borehole aligned with and at an angle to applied principal stress states in order to study the growth of drilling induced tensile fractures. The samples were illuminated such that photoelastic fringes could be video recorded during the measurements; this was useful in assessing states of stress and in determining fracture initiation. Axial drilling induced fractures were observed at the azimuths of the applied uniaxial stress as would be expected from the concentrated stresses. En echelon fractures were observed from the borehole deviated at 45° to the direction of the compression. These preliminary and currently qualitative results show that glass blocks serve as a useful test medium for studies of stress concentration and drilling induced fracture creation. INTRODUCTIONWith the increasing exploitation of unconventional oil/gas reservoirs using deviated drilling in recent years, the effects of the in-situ stress on the success of energy production have become more critical than ever before. Knowledge of the state of stress in the earth enables us to determine well trajectories, well locations, hydraulic fracturing design and production rates, but knowing the crustal stress is always challenging. Strictly, it can only be obtained to varying quantitative degrees by accessing the earth through drilling. Failure of the rock at the borehole wall produces borehole breakouts (e.g., Bell & Gough, 1979; Haimson & Herrick, 1986; Zoback et al., 1985) and drilling-induced tensile fractures (DITF) (e.g., Aadnoy, 1990; Aadnoy & Bell, 1998; Barton et al., 1997; Brudy & Zoback, 1999; Davatzes & Hickman, 2010; Peska & Zoback, 1995). Thus, it is important to understand the failure mechanism of the rock in the vicinity of the borehole. A number of closed-form expressions have been developed that allow the stress concentrations to be calculated in the vicinity of a borehole including Kirsch’s (1898) 2-D plane strain solution and 3D formulae for elastically isotropic (Hiramatsu and Oka, 1962) and anisotropic (Lekhnitskii, 1981; Amadei, 1983) continua. These solutions have been applied in numerous studies (e.g., Ong, 1994; Ong & Roegiers, 1996; Vahid & Ghassemi, 2011; Jia & Schmitt, 2014; Ito et al., 2001) to analyze the failure mechanisms of drilling-induced tensile fractures (DITF) on the borehole wall."

Jan 1, 2015

By X Zhang, B McFadzean, C T. O’Connor, S Pikinini

The Platreef in South Africa contains one of the world’s largest reserves of platinum group elements. One of the major platinum group minerals (PGM) components in this ore is sperrylite (PtAs₂), which has been found to be slow floating compared to the other PGMs. In a study aimed at determining the reasons for the poor floatability of sperrylite and to improve its recovery, tests were carried out to determine the interactions of the mineral with a range of standard and novel collectors. Microflotation tests were carried out to determine the hydrophobicity of the minerals before and after adsorption of collectors. In addition, experiments were carried out to determine the enthalpy and extent of collector adsorption on the minerals and to investigate electrochemical interactions between sperrylite and selected standard collectors. The results indicated that poor collector adsorption was the major cause for the poor floatability of sperrylite. Sperrylite had both poor natural (14.5 per cent) floatability and collector-induced flotation recoveries, the highest recovery of 26 per cent being observed using PNBX collector at pH 9. Moreover, the rest potential tests showed that the interaction of sperrylite with standard collectors such as xanthates was poor. The decrease in potential after the addition of the standard collectors ranged from 7.9 mV to 24.9 mV under alkaline conditions. Furthermore, sperrylite rest potentials remained unchanged with a change in pH from basic to acidic, indicating its resistance to surface alteration. Surface alteration of the minerals is key for the chemisorption of collectors to take place on the mineral surface. This was further emphasised by flotation recoveries at low pH, where only certain collectors responded positively to a decrease in pH and these were shown to have undergone a structural change. This work has highlighted the difficulties associated with sperrylite flotation and provides some direction for future research.

Aug 24, 2022