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By Richard R. Klimpel

The purpose of this paper is to summarize some of the author's experiences in applying population balance models to a variety of industrial grinding circuits. Over 26 separate industrial circuits have been studied in detail during the last 10 years, each unique in its equipment type and layout as well as in the material (s) being ground. The success of the population balance approach during these studies was variable. Fourteen of the circuits were shown to be very amenable to such an approach while the remainder had conditions present that sufficiently violated the standard population balance assumptions so that the analysis was of less than optimal utility. Some discussion of the importance of standard population balance assumptions will be given. It is increasingly becoming this author's opinion that the use of population balance models has its greatest utility in defining logically and cheaply (in contrast to actual physical testing), the relative limits and comparisons of different proposed circuit configurations and changes in equipment types and/or operating conditions. As far as specific quantitative predictions and actual optimization of existing plant performance, the results of applying the population balance approach have been often disappointing and need to be coupled at the plant level with other engineering quantification techniques in order to achieve desired improvements.

Jan 1, 1992

By H. Ziock, J. Ruby, A. A. Johnson

Power generation systems that promote energy security and environmental benefits are highly desired and pursued by a number of government and industry programs. Gasification of coal, other fossil fuels, or biomass has the technical promise of high efficiency and low or zero emission. Gasification for the purpose of electrical power generation has been researched, developed and demonstrated over the last 20 years, but for many reasons is not viewed as economically competitive. This paper describes a coal-based gasification technology well suited to mid and long-term goals of secure, environmentally clean energy. The technology should be adaptable for use with other carbon-based fuels including biomass and a full range of fossil fuels. The new zero emission gasification process is sponsored by ZECA Corporation, a continuation of the Zero Emission Coal Alliance (ZECA). ZECA has completed process design and engineering to assess the viability of a concept originated at Los Alamos National Laboratory, and the creation of a business plan to define paths for advancing the technology toward a near-term goal pilot plant. The zero emission carbon (ZEC) technology includes hydrogasification, the production of hydrogen and the carbonation of lime with CO2. For the power generation base case, the hydrogen is used in high temperature coal compatible fuel cells to produce electricity and the carbonate is calcined to produce a pure stream of CO2for sequestration. This paper provides the status of work with the ZEC technology and the availability of crucial equipment, materials and required testing. Discussions are presented for future actions to accelerate the technology assessment, testing and demonstration of a ZEC plant. Brief remarks are provided on complementary projects dealing withCO2separation and gasification costs.

Jan 1, 2004

By A. M. Marabini, G. Belardi, V. Alesse, E. Spaziani

The objective of this investigation was to verify the effectiveness of commercial and synthetic depressing agents in a complex oxidized zinc mineral flotation flowsheet using sodium sulfides and amine. The flotation tests were run on a finely-disseminated calamine ore grading 16.96% Zn and containing smithsonite, hemimorphite, cerussite, calcite, quartz and iron oxide, present essentially in colloidal form. The reagents used in the testing can be grouped into four classes: guar, starch, celluloses and acrylic polymers having various degrees of substitution and molecular weights. The depressants exhibiting the greatest selectivity towards the gangue (considered as a whole) are tripolyphosphate, polycarboxylic acids, methylcarboxylate guars and ethyl hydroxylic starch. In the rougher stage, the Zn recovery ranged from 70% to 80%, and the Zn grade ranged from 27% to 29%. In the Zn-Fe2O3 separation, the compounds ensuring the most efficient separation are the tripolyphosphate and the polycarboxylic acids. In the Zn-SiO2 separation, the compounds that exhibit the best separation efficiency are tripolyphosphate and guar of methylcarboxylic sodium salt. In the case of the Zn-Ca separation, methyl-carboxylic guar exerts the best depressing effect and does not adversely affect the Zn recovery. The separation provided by ethyl hydroxylic guar is also good, although not as good as the preceding reagent. Regarding the Zn-Al separation, the tripolyphosphate, the celluloses and the carboxylate guars are the best depressants. A hypothesis is advanced to interpret the depressing action of the most effective reagents.

Jan 1, 1995

By V. D. Ayurov, N. O. Kaledina

The coal mines monitoring should be based on the usage of simple and evident models, letting in the total unity to reflect a structure of organization of mine, system ability of its construction and specific character of its functioning. Such models are offered to create on the basis of extracted hierarchies of objects of mine. All objects of mine are broken on levels of technological hierarchy. For objects of each level of hierarchy there are made balanced models of entering and leaving material flows. Then these balanced models are coordinated among themselves by the help of the inter hierarchical relations. So the structured-qualitative characteristic of the object of monitoring, reflecting in a kind of the table structure of formation of material flows on mine, their intensity and measure of transformation is formed under transition from one level of hierarchy of mine to another. An example of real us- age of hierarchical balanced models on mine is given. The mathematical models of coal mine monitoring should reflect objective laws of their structural organization and functioning. Therefore under the constructing of mathematical models it is important such a way to reflect a structure of the mine organization, that in totality the models has been reproduction of system ability of its construction. The knowledge of the separate parties of functioning of mine, reflected in particular mathematical models, should "to be packed" in combined unity. Or else, they should be connected in system, convenient for recognition by the person. Considering the mine, the expert allocates multi-dimensionality of the objects of making its elements. He always has the knowledge of laws of development of mining work that is connected with pithy stratification of researched object. In dependence of sparial-temporary level of abstracting there are allocated the horizon, wing of a mine field, layer, panel, extracting face, longwall in coal mine. The human thinking on each of these levels operates with a set of concepts peculiar to him, characteristics, definitions.

Jan 1, 1996

By W. Blake, J. Mahaut, W. Hustrulid

Division II at Kamoto mine in Kolwezi, Zaire represents a transition zone between Divisions I and III where transverse and longitudinal cut-and-fill rooms were being mined. Because this transition zone had been geologically depicted as being badly faulted the mining in this division had been deferred to a future time. However, to increase production and to reduce mining costs by carrying out the mining of the 3 divisions simultaneously, it was decided to mine Division II. The mining research group of Gecamines was given the task of designing a mining geometry then testing this design in a full scale test. Based on an evaluation of the faulting and fracturing of the 2 parallel orebodies and on an extensive in situ testing program preliminary mathematical analyses were used to develop and evaluate room and pillar designs in the 35°-65° dipping bedded formations. Based on these analyses and the constraints of having to fit the design of Division II to grade into Divisions I and III in a logical manner, a mining geometry for Division II evolved. To test this design an instrumented room was excavated in the most critical area. The results of this full scale testing showed that the behavior of the roof and wall rocks were as had been predicted by finite element computer model studies which incorporated the material properties and results of the field testing. The room geometry design was both judged and observed to be stable, hence mining commenced.

Jan 1, 1977

By Gerald L. Finfinger, Michael A. Trevits

Since 1964, the US Bureau of Mines has been conducting a comprehensive program of research on the origin and control of coal bed gas. Several extensive databases have been developed during the work representing information from every major coal producing region in the United States. Gas content measurements have been made on 885 coal samples from 15 states representing 221 coal beds. Records indicate that the range of gas content varies from zero to over 640 ft3 per ton (20 cm3 per gm). During the conduct of the research program, several drilling and completion techniques have been developed or refined to divert and collect coal bed gas before it enters the mine environment. Such techniques include horizontal, cross-measure and vertical boreholes. Samples of gas collected from boreholes drilled under the program indicate that the primary gas constituent is methane which comprises 97 pct, the remaining hydrocarbons make up approximately 0.2 pct. Nitrogen and carbon dioxide account for the majority of the remaining gases at average concentrations of 1 pct each. Surveys have been made on the total daily gas emissions from underground coal mines. In fact, the most recent survey indicates that 180 mines had emissions in excess of 100 Mft3 per day (2.8 Mm3 per day). Furthermore, total mine emissions were in excess of 300 MMft3 per day (8493 Mm3 per day). An analysis of the data showed that there appears to be no relationship between in-place gas content and coal bed gas composition. Furthermore, no correlation was observed between in- place gas content and daily mine emissions. In a general sense, the higher the gas content the higher the relative gas emissions. Perhaps a more direct relationship would be observed if more complete emissions information (including gob gas borehole production) was available.

Jan 1, 1989

By Kenneth L. Clifford

We have heard a lot during the recession about the mining industry now competing in a world market for sales of such commodities as copper, lead, zinc, molybdenum, iron ore, and phosphate. If the US mining industry is to survive, do we not have to reduce direct operating costs to a minimum? How significant is labor cost compared to consumables, electricity, fuel, maintenance, materials, and transportation? Ore grade is ultimately the dominant factor; but can we offset its dominance by improving productivity? Is the US mining industry perhaps only 25-30% as productive as it might be? What prevents the industry from being more productive? Can we retrofit older plants to be more productive or does it take a new plant with the largest equipment available for each unit operation? Present Productivity A copper industry study a few years ago covering 13 US copper concentrators ranging from about 10-45 kt/d (11,000-50,000 stpd) showed that productivity did not vary with capacity above 18 kt/d (20,000 stpd). Operating productivity varied significantly, however, from about 180-635 t/d (200-700 stpd) per operating hourly worker in most units, but one operation had 900 kt/d (1,000 stpd). Concentrators with more than 545 t/d (600 stpd) per hourly worker were in the 23 kt/d (25,000 stpd) or more category. Maintenance productivity covered about the same range, but most concentrators were in the 270¬635 t/d (300-700 stpd) per hourly maintenance worker. Again, one company stood well above others by exceeding 1 kt/d (1,100 stpd). Total hourly productivity ranged from 125-280 t/d (140-310 stpd) per hourly worker for most concentrators. The company with the most productive operation, however, was above 455 t/d (500 stpd). Salaried worker productivity for most operations was in the 725 t/d to 1.2 kt/d (800-1,300 stpd) per salaried worker range. The best operation was 2.2 kt/d (2,400 stpd). The end result is, of course, tons per day per total personnel. Most operations fell in the 110-220 t/d (120-240 stpd) range with the best operation at 400 t/d (440 stpd). This is the productivity definition that is most directly related to unit costs. Many of these operations have made some productivity progress

Jan 11, 1983

By Y. J. Wang

Editor's Note: Y.J. Wang's paper appeared in the September Technical Papers section. There were some inadvertent editorial errors in it. So we are reprinting it here. Abstract - This paper examines the ventilation network problem from a view point of solving a system of B equations in B unknowns, where B is the number o f branches in the network. Based on Kirchhoff s current and voltage laws, the solution to the general ventilation network problem must satisfy B network equations. In this paper, the air quantities and control-device pressures are chosen as variables and are grouped into B dependent variables (unknowns) and B independent variables, resulting in a system of B equations in B unknowns. Based on whether their variables are dependent or independent, the network branches are classified into f our types: five d, non-fixed, p-fixed, and q fixed. The ventilation network problem may include all four types of branches. There are .some conditions under which the problem as defined in this manner does not have a unique solution. To have a unique solution, the Jocabian matrix of the equations m us! he nonsingular. It then follows that: • the number of branches with independent air quantities must be less than or equal to the number of chords with respect to a spanning tree; •the subnetwork of branches with independent air quantities must not contain any cutset; and •the suhnetwork of branches with dependent control-device pressures must not contain any cutset. These three conditions must be met regardless of the values for the variables. In addition to the problem formulation, a solution procedure applying the Newton (or Newton-Raphson) method is outlined and illustrated with an example problem.

Jan 1, 1991

By d&apos, L. R. Fletcher, Andrea. D. V., M. A. Peltier

The Bureau of Mines analyzed coal mine blasting accident data obtained from the Mine Safety and Health Administration (MSHA), U.S. Department of Labor. The data were examined to determine the causes, frequency, and severity of accidents in an effort to point out the most dangerous aspects of coal mine blasting. Accident data for the 14 years from 1971 through 1984 show that there has been a total of 43 fatal and 926 nonfatal blasting accident victims in surface and under- ground coal mining. This is an average of 3.1 fatal and 66.1 non- fatal injuries each year. Underground coal mining accounted for 60.5% of the fatal and 78.7% of the nonfatal accidents involving explosives and breaking agents in coal mining. In addition, since 1970 there have been 53 fatal and 20 nonfatal injuries that occurred when explosives were the ignition source for dust and/or methane explosions in underground mines. Abstracts from 297 accidents that occurred from 1978 through 1984 were also examined to determine accident causes. Most accidents occur during scheduled blasting, and failure of the blast area security system is the leading cause. Blast area security problems in surface mining are failure to clear the blast zone, failure of personnel to follow instructions, inadequate guarding, and failure to retreat to a safe location and/or take adequate cover. Other common causes in surface mining include premature blasts, excessive flyrock, and misfires. In addition to the above causes, accidents in underground coal mining can be due to rockfalls triggered by the blast, unexpected breakthroughs, fumes, and incidents associated with Airdox-type systems.

Jan 1, 1986

By L. A. Puchkov, Mesentsev. V. K., I. O. Temkin

The problem of increasing underground mine ventilation efficiency is still of top priority. The complication of geological conditions with the depth of underground mining processes and reinforcement of requirements to technological and ecological safety are extorting the necessity of solving this complex problem with using of new information technologies. There exist different approaches to the ventilation problem. One of them, which the authors adhere to, is based on the concept of monitoring (under special mining and geological conditions-automatic control) of mining atmosphere and operative re-distribution of underground mining air among consumer , in accordance with the criterion of optimality [ 1.3 1. ] The set of tasks which should be decided in the frame of con- crete ventilation system depends on the peculiarities of deposit, technological schemes and so on. Nevertheless, some ventilation tasks such as: defining of ventilation network parameters; finding of dependence between these parametrs; operative redistribution of air streems, could be interpreted as universal ones. Main aspects of practical solving of different ventilation problems and their classification were investigated and considered in detail before [I ,2 ]. Some years ago we have began our investigations to develope quite simple and effective methods for decision of ventilation tasks on the base of neural network technology. It is well known that ventilation net, formed by various mine workings, is the main component of underground mining ventilation system. In general, network air distribution may be described by some functional F(Q,R,H), where Q- is a vector of air consumptions; H- is a vector of depressions; R- is a vector of airdynamic resistences. (Q,R,H) - are the informative entities , characterising every branch of the net. There exist some fundamental tasks which should be decided during the process of control of mining ventilation: calculating of natural air distribution Q = Q,{R, H,}, or Q = Q2(R, Q?}, where H, - is the maximal depression of the ventilation net, Q, - is the air consumption in the ventilation shaft; identifying of airdynamic resistance for some branches on the base either of air-depression removal or operative monitoring: [ ]

Jan 1, 1996

By Kenneth S. Johnson

Oklahoma is a region of complex geology where a mobile belt of Paleozoic geosynclines and uplifts on the south abuts against the margin of the North American craton to the north. The state contains many classic areas where fundamental concepts of sedimentation, stratigraphy, structural geology, historical geology, mineral investigation, and petroleum exploration have been formulated through the years. In the southern Oklahoma mountain belts, there are exposed a great variety of igneous and sedimentary rock units seen at few other places in the Midcontinent area. Major geologic provinces of Oklahoma (Fig. 1) include: (1) the cratonic and relatively stable northern shelf areas, including the Ozark uplift; (2) the Ouachita geosyncline (now the Ouachita Mountain belt) and associated Arkoma basin in the southeast; and (3) the southern Oklahoma aulacogen (geosyncline), comprising the area of Anadarko, Ardmore, Marietta, and Hollis basins, as well as the Arbuckle and Wichita Mountain uplifts. The three principal fold belts, the Ouachitas, Arbuckles, and Wichitas, all originated from a series of Pennsylvanian orogenies (about 300 million years ago) in the two Paleozoic geosynclines.

Jan 1, 1999

By George Aul, Richard Ray

Short-hole horizontal degasification systems have been utilized in Island Creek's Virginia Division mines since 1986. These systems remove methane from the coal seam in advance of longwall mining. Without an in-seam methane drainage program, methane liberation rates from the longwall faces may exceed 0.47 cu m/s (1,000 cfrn), requiring 47 cu m/s (100,000 cfm) of air for adequate dilution capability. Optimization of the degas systems has enabled methane liberation levels and the associated ventilation requirements on the longwall faces to be reduced by 50 to 80 percent. Since the inception of the first degas system at the Virginia Pocahontas No. 6 Mine, Island Creek has developed an overall methane drainage program designed to maximize gas production and minimize ventilation requirements for methane dilution. Gas production from the degas systems is affected by four main design criteria: (1) hole location, (2) hole length and spacing, (3) collection system capacity, and (4) time available for drainage. Drilling equipment and materials for the gas collection system are selected to meet the necessary criteria while minimizing manpower requirements. Benefits gained from reducing methane liberation rates from the longwall faces are fourfold: (1) improved safety due to lower methane concentrations in the face area, (2) fewer production delays caused by excessive methane concentrations, (3) lower fan operating costs resulting from reduced air requirements, and (4) enhanced worker comfort resulting from lower air velocities and less dust generation.

Jan 1, 1991

At first glance the staid Joralemon background does not seem to equate with the life of adventure that irresistibly called me for over 70 years. But my ancestors had their adventures too. My father's family were Dutch Reformed Protestants who had energy or daring enough to come to America to escape the Catholic persecution that followed the Massacre of St. Bartholemew. The first Joralemon came from Friesland to New Amsterdam m 1636, just after Peter Stuyvesant. My father's mother's family, the Berdans, were French Huguenots who came to northern New Jersey only a little later to escape the Catholic domination in France. Some say that the first Berdan to come to America was given all the land between the Passaic and the Hacken-sack Rivers by King James. Whatever, the Berdan family settled there and was able to make a scanty living by farming and selling their produce in Manhattan. The spirit of adventure in my mother's family was just as tenuous. Gamaliel Beaman was pastor of a shipload of Puritans who came to Massachusetts in 1636. Gamaliel's descendents were peaceful farmers and some ministers in New England and later New York State. They had got all of the adventure out of their systems in the long and dangerous voyage across the Atlantic to escape religious persecution. The Joralemons and the Berdans married into families that had been in America almost as long as they had. On my father's side the Berdans, Doremus, DeGreys, Vanderbeeks, and Varicks showed by their names their Dutch or French Huguenot stock. The only one who achieved any fame was Peter Varick, who was George Washington's military secretary during the American Revolution. After this he was nine times mayor of New York and was one of the founders of Kings College, later Columbia University. He was responsible for one of my few ancestral claims to distinction. When the Marquis de Lafayette made a fare-

Jan 1, 1976

By Peter K. Achireko, Samuel Frimpong

Design and optimization of open pit limits are of paramount importance because they provide information for evaluating the economic potential of a mineral deposit and for developing short and long range mine plans. Many algorithms and their modifications have been used to design and optimize open pit limits. These algorithms have provided mine planning engineers with pertinent information in designing, optimizing and extracting ore reserves by open pit technology. However, they do not address the random field properties associated with the ore grades and reserves and commodity prices, and thus, fail to yield the truly optimized pit limits in any time horizon. In this paper, a new algorithm, MCSIMFNN, which overcomes these limitations is proposed and used to optimize open pit limits. The random field properties of the ore grade and reserves have been modelled using the modified conditional simulation based on the best linear unbiased estimation and local average subdivision techniques. Artificial neural networks are used to classify the blocks into classes based on their conditioned values. The error back propagation algorithm, in the neural networks, is used to optimize the pit limits by minimizing the desired and actual outputs error in a multi- layer perceptron under the pit wall slope constraints. The optimized pit value obtained by this algorithm has been compared to that from the Lerchs-Grossman's algorithm in a case study. The results are the same, but in random multivariable states, the MCSI MFNN algorithm is the most suitable for pit optimization. The method is also fast since it mimics the operation of the brain in the solution of the pit optimization problem.

Jan 1, 1996

By E. S. Erickson, R. L. Stone

Introduction Evidence from blast furnace operations has indicated that using pellets with a higher ISO low temperature reducibility, a lower SiO2 content, and better resistance to low temperature degradation results in considerable coke savings and improved furnace operation. Although these benefits could not be directly related to reducibility differences alone, we believed there was sufficient evidence of the advantages in improved pellet reducibility to warrant laboratory investigation of ways and means to effect such improvements. It is well known that pellet reducibility can be significantly altered by changes in the basicity and the amount of non-iron oxide constituents. Past work (Friel and Erickson, 1980, 1982; Saeki et al., 1977; Thanning, 1974) has shown that with increased MgO contents, and at optimum CaO/S1O2 ratios, significant improvement in low temperature reducibility can be attained. The improved properties of such fluxed pellets have reportedly led to increased blast furnace efficiency and productivity (Saeki et al., 1977; Ilmoni, 1975). Less well known, however, is exactly what factors control reducibility in acid pellets. Because of this gap in knowledge, studies were undertaken of the factors affecting reducibility in acid pellets and to estimate their relative significances in modifying reduction behavior. This paper describes that part of our work done to determine the effect of bentonite on reduction behavior. Our approach was to first examine the effect of bentonite's presence on as pure an iron oxide as possible (i.e., a magnetite "superconcentrate" containing about 0.2% SiO2) so as to eliminate any gangue-binder interaction. The next step was to look at bentonite effects on concentrates with only limited amounts of gangue (containing about 1% SiO2), but of two different types, simple and complex silicates. Last, we

Jan 1, 1988

By Kalle Hakalehto

Automation and mechanization in mining has no value of its own. It has to be measured in economic terms or in Increased safety or in the utilization of deposits which otherwise were unavailable. The mechanization and automation of workphases in the mining and rock construction process has led to the decrease of manual work. This has had a very essential importance in the countries where the labor is expensive or where there has been difficulties in the availability of labor. The work has become much more efficient. We would like to argue that the need of mechanization has been initiated mostly from the above mentioned reasons. The origin has seldom been the "process" approach or the real need or will to change the way mining is done. Through mechanization bigger unit sizes of machines and operations have become possible and better efficiency is achieved. This has led to new problems as well, but in most cases they have been solved so that better and more economic outcome than before has been the end result. The changes have thus been justified. It is perhaps feasible to state already at this stage that we see that the mechanization andautomation steps in the difficult conditions of mining have been remarkable. There is not a slightest underestimation of the achievements and importance of this development in our mind. Where we are to- day is the result of the experience, know-how and technological excellency of all the parties involved. The natural approach to automation has been through mechanization and automation of individual unit operations and machines. This has been the way as well in manufacturing industry as in mining. There may not have been any other way. The other presentations in this session tell us very clearly of the approach .which the machine manufacturers have taken. They have not done it alone but 'most of the initiatives have come from them. A good use of their present achievements gives many possibilities to increase the, efficiency in mining. We would, however, like to extend the view one step further to the future:

Jan 1, 1989

By Jesse L. . Jr. You

Tunnels in the granitic Climax stock at the Nevada Test Site were inspected for keyblock occurrence. Thirteen relatively large pyramidal keyblocks were located in about 230 m (750 it) of tunnel. Orientations, dimensions, joint roughness coefficients, and joint compressive strengths were measured for the faces of nine keyblocks. The measurements were used to back-analyze keyblock stability to check the validity of a numerical model for keyblock behavior. A newly developed three-dimensional numerical model correctly predicted whether or not each keyblock failed in six of eight cases. The two exceptions involved stress conditions and keyblock locations that clearly violated the assumptions that underlie the stability model. The observations also allowed the effect of tunnel orientation on keyblock occurrence to be evaluated. Of the thirteen observed keyblocks, nine large blocks were found in less than 30 m (100 ft) of the Piledriver drift (which runs N56E) while only four blocks of comparable size were observed in 200 m (656 ft) of the Spent Fuel Test--Climax drifts (N61W). The orientations of the keyblock faces were checked against known discontinuity set orientations; some of the faces correlated well with mean set orientations, whi.le other faces were fringe members of sets. Stereographic techniques were used to examine the frequency of keyblock occurrence and to determine the maximum keyblock size that could be encountered with a given combination of discontinuities. Keyblock occurrence was found to be affected by tunnel orientation in a predictable way; this can be used to guide or improve tunnel design practices.

Jan 1, 1986

By B. H. Gardner, S. Serata, D. Dickie

Since 1958, the Sifto Salt Division of Domtar, Inc., has operated the Goderich (Ontario) salt mine in Michigan basin bedded halite, with shafts located on Lake Huron's eastern bank. Initial mining utilized a conventional room and pi1lar pattern. However, roof deterioration developed. Incidence of progressive upward failure of saltback and over1yings ha1ey-do1omite layers intensified with entry aging. Studies were therefore initiated on new mining patterns utilizing the Serata Stress Control Method. Pursuant thereto, three test areas, indicated in the mine plan of Fig. 1, were designed and excavated. Full conversion to Stress Control mining was effected in January, 1983. This paper focusses on the instrumentation work in the third test area. Test Area 3 was designed to validate the excavation geometry of the new stress-controlled main entry system. The testing of that design was accomplished, in part, by comprehensive in situ stress, property, and deformation measurements on the performance of the model main entry section of Test Area 3. The paper describes: (1) the theoretical background of the SPDR/Stress Control Method; (2) specific problems and objectives addressed by the 1983 program of in situ measurements, (3) measurement results; and (4) conclusions drawn therefrom.

Jan 1, 1986

By L. B. Anderson, G. A. Carmody

We wish to comment on the paper by G.W. Heunisch (MINING ENGINEERING, January 1987), which raised several important points regarding treatment of acidic waste waters. This paper confirms, in part, tests carried out by Allyn Corp. Allyn is the manufacturer of the proprietary product Alka-Ment, one of the materials that Heunisch tested. The first point is the extreme sensitivity of the sedimentation rate on the nature of the treatment material used. This apparently results from differences in nucleation of the metal hydroxides, and is consistently higher for Alka-Ment. This decreased sludge volume is also observed when Alka-Ment is combined with flocculants, such as organic polymers (see Table 1). Our second point is to emphasize that Heunisch's work shows how dependent the sludge volume is on pH. It is common practice to overtreat AMD by raising pH to 9 or 10. This practice, in addition to being wasteful of material, actually decreases the density of the resulting sludge, probably by creating charged particles that do not readily coalesce. When treating with Alka-Ment, we recommend that the treatment be monitored by testing both pH and dissolved iron. For both tests, it is important to allow adequate time to elapse between treatment and measurement, so that dissolution of alkali, aerobic oxidation of iron, and precipitation of the metal hydroxides are nearly complete. Our tests have indicated that from 30 minutes to one hour is commonly required. Only in this way can a minimum pH be attained, with adequate treatment, denser sludge, and lower treatment rates achieved. Thirdly, Heunisch correctly recognizes that ASTM titration of Alka-Ment does not reflect the true treatment value available in a unit of Alka-Ment. Our work at Allyn indicates this is a most important consideration when evaluating various materials for the treatment of acidic waste waters. While we were unaware of Mr. Heunisch's work, we welcome comparisons between Alka-Ment and any competitive products readily available for field use. Allyn has hundreds of hours of laboratory and field data we are ready to share with interested parties treating acidic waste water.

Jan 1, 1988

By R. I. Yano

Analyses of trace elements in bulk ores and in chalcopyrite and other ore minerals from porphyry copper systems worldwide, including skarns and breccia pipes, reveal some key factors regarding byproduct critical elements. Petrographic and scanning electron microscope analyses combined with a laser ablation inductively coupled plasma mass spectrometry technique developed by the USGS on selected ores from the Mackay-Stanford Ore Deposits Collection suggest that selenium occurs as atomic substitutions in sulfides, particularly pyrrhotite (up to 430 ppm) and chalcopyrite (up to 300 ppm Se); tellurium occurs predominantly as less-than-five-micron-sized inclusions of bismuth-tellurium minerals in other ore minerals, particularly chalcopyrite; cobalt and nickel are locally enriched in pyrite (up to 7800 ppm Co and 9100 ppm Ni); gallium is locally enriched in magnetite (up to 83 ppm Ga); indium and silver are locally enriched in chalcopyrite (up to 890 ppm In and 770 ppm Ag); cadmium substitutes for zinc, particularly in sphalerite (up to 4100 ppm Cd). There is considerable variation, both between and within individual deposits, in both selenium and tellurium content in these copper ores, ranging from 0.6 to 148 ppm Se and 0.09 to 64 ppm Te. Indium tends to be high in copper ores that are also enriched in silver. At current prices, many of these elements are sufficiently enriched to warrant investigation into metallurgical recovery as byproducts of the major elements.

Feb 27, 2013