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By Shaning Yu, Yosry A. Attia

The purpose of this work was to investigate the feasibility of using column flotation as a floc separation technique. In this study, the ultrafine coal (minus 25 microns) slurries were cleaned by using the Integration of column flotation with selective flocculation. It was found that using column flotation as a floc separation technique during the "cleaning" stage, achieved much better results than that either using column flotation as a rougher separation technique for coal flocs, or using It directly to recover the ultrafine coal from the slurries without adding selective flocculant. Thus, the ultrafine coal slurries were first separated by selective flocculation process to reject a certain amount of the dispersed ultrafine ash minerals, and to aggregate the ultrafine coal particles as flocs. Thus, the entrainment of ultrafine ash minerals Into the coal floc-froth concentrate during flotation could be considerably reduced. Subsequently, the coal flocs were further "cleaned" by column flotation. The experimental results Indicated that this approach was technically feasible and particularly suitable for a slurry containing a large amount of ultrafine particles. The effect of flotation time, and collector dosage on column flotation of coal flocs were also Investigated and reported In this article.

Jan 1, 1988

By Misra M., P. Grimes, Chen. S.

The combustion of petroleum products produces emissions which contain oxides of nitrogen (NOx), hydrocarbons (HC), and particulate matter (PM) which have adverse health and environmental effects. In recent years there has been increasing interest in the use of water-fie1 emulsions as a substitute for conventional fuels. Emulsified fuels are emulsions of water in fuel, which are typically made of 10 to 20 percent of water mired with certain additives and fuel. Studies have shown that the emulsified diesel can significantly reduce the emissions of NO, PM and car- bon monoxide and increase the fuel efficiency. In order to produce a stable diesel emulsion, the development of an effective surfactant additive is critical. The stability of diesel emulsions is influenced by many factors, including size distribution of the droplets, the viscosity of the continuous phase, the physical properties of the interfacial film, and temperature. This paper describes a method to produce emulsified diesel and combustion results obtained from various tests. It has been found that the diesel emulsion made with this additive package was stable during the test, and the emissions were lower in NO, CO, and PM compared to the baseline diesel.

Jan 1, 2005

By R. Y. Wan, Corby G. Anderson, L. Ernest Krys, M. C. Fuerstenau

Since 1942, refractory precious metal concentrates at the Sunshine mine have been processed for antimony metal recovery using a novel leach-electrowin method. This is counter to most antimony production facilities where pyrometallurgical techniques are usually relied upon. The key step for removal of the antimony has been an ambient pressure alkaline sulfide leach. In 1990, a comprehensive laboratory study was undertaken to better understand this process. Factors studied included temperature, agitation, concentrate regrind, alkaline species concentrations, sulfur species concentrations and solids concentration. Details of these studies, as well as a brief description of Sunshine metallurgical processes, will be presented.

Jan 1, 1993

By Jean-François Bougard

It has already been said and written many times that the construction of tunnels in urban areas has proved more and more indispensable, if not vital. The subsequent development of tunnelling for 15 or 20 years has brought large and sometimes spectacular improvements in the fiel of execution methods. But, particularly in urban areas, the difficulties to be overcome have been and still remain very important. As a matter of fact, most of big cities, have been settled near rivers or lakes; therefore the geological nature of the subsoil is soft ground and the level of ground water is high. As a consequence, tunnelling is often faced with many well-known difficulties and dangers issued from decompression or loosening of the ground, sometimes accompanied by a lowering of the water table. This may compromise the safety of the excavation itself and of the workers, and also cause settlements which many severely damage nearby buildings or structures. This is the reason why it is always necessary to work out specially adapted methods and even to develop new ones. In most cases, each work is a particular one and has to be specifically studied since numerous data are to be taken into account, related not only to geology, cohesion and behaviour of the different layers concerned, ground water, the activity of it, but also to

Jan 1, 1979

By D. C. Seidel, W. K. Tolley

Supercritical water alters the structure of common sulfide minerals by partially removing sulfur from the mineral structure. This discovery has been applied to the treatment of pyritic gold ores to improve precious metal recovery without generating or utilizing environmentally sensitive products such as S02, chlorine, or cyanide. Pretreating pyrite concentrates in supercritical water under mildly oxidizing conditions provided by certain metal oxides or oxygen improved gold leaching using thiourea. The pretreatment differs from chlorination or roast pretreatments in that elemental sulfur rather than sulfuric acid is the major product. A pyritic ore containing 58 g/mt Au was pretreated with oxygenated supercritical water at 24 MPa and 400°C, then leached with 20 g/L thiourea. With pretreatment, gold recovery was 90%; by contrast, gold recovery was below 10% without pretreatment.

Jan 1, 1990

By M. Misra, I. A. H. Schneider

The flocculation of -38 pm calcite, hematite and kaolinite aqueous suspensions by the yeast Candida parapsilosis and products derived from rupture of the microorganism was studied. Flocculation of hematite suspensions by the microorganism and its derivatives readily takes place between pH 2.8 and 11.4. Maximum flocculation occurs at about pH 6.5. Flocculation of calcite suspensions by the microorganism and its derivatives readily takes place between pH 7.0 and 11.8. Maximum flocculation occurs at about pH 10.0. Flocculation of kaolinite suspensions was less than that for the other two minerals. However, a soluble fraction derived from the rupture of the organism functioned as a good flocculant for the mineral, albeit at an increased concentration, between pH 2.6 and 11.5. Maximum flocculation occurs between pH 6.8 and 7.2. An attempt is made to relate the behavior of the various systems to the surface characteristics of the minerals and the surface and chemical properties of microorganism and its derivatives. Experimentation used to evaluate the flocculation includes actual flocculation tests, microelectrophoresis measurements and scanning electron microscopy.

Jan 1, 1994

By Mohammad Irshad, Larry H. Heflin

INTRODUCTION The planned 166 kilometer (103 mile) Metro rapid rail transit system in Washington, D.C. is being designed and constructed by the Washington Metropolitan Area Transit Authority. At the present time, 112.6 kilometers (70 miles) of this system is in operation and contains 21 route-kilometers (13 miles) of rock tunneling, and 14.5 route-kilometers (9 miles) of soft ground tunneling. An additional 2.4 kilometers (1.5 miles) of single track tunnels in rock are planned and 6 additional contracts will consist of some 8 kilometers (5 miles) of twin tunnel, resulting in 16 additional linear kilometers (10 miles) of single track tunnel in soft ground. The Authority plans, upon its evaluation and the recommendation of the General Engineering Consultant, to include an alternative design incorporating the convergence confinement method of construction known as the New Austrian Tunneling Method (NATM), for Sections E-5, E-6e and E-8a of the E-Route. The Metro system is constructed in a variety of geological conditions and crosses the boundary of two major geographic provinces. Rock tunneling is to the west of this "fall-line" boundary, soft ground tunneling to the east. The soft ground tunneling portions of Metro construction lie in the coastal plain which consist of a

Jan 1, 1987

By S. K. Kawatra, S. J. Ripke

Iron ore pellets use bentonite clay as binder at dosages from 0.5to 1.0% (10 to 20 pounds per ton) of moist iron ore concentrate. Bentonite is typically shipped hundreds of miles from Wyoming to the Lake Superior iron ore district. It is therefore best to know how effective a bentonite will be before it is shipped and used to bind concentrate into pellets. Current tests of bentonite effectiveness include: plate water absorption, methylene blue uptake, free swell, exchangeable cations, and glycolated layer expansion. However, these tests have many disadvantages: First, they only measure the ability of a bentonite to expand, disperse, or absorb, not how well it will bond. Second, most of the tests require up to 20 hours to perform. Bentonite only has a few minutes to interact within the concentrate before it is indurated (sintered). These long-term tests may not reflect the true behavior of bentonite. Third, the tests are tedious and often results are inconsistent between different iron ore concentrates, labs, and technicians. Fourth, some of the testing equipment is difficult to procure. Fifth, procedures are often difficult to standardize. In this paper, the Binder Effectiveness Strength (BESt) test to evaluate binders for iron ore pellets is presented that: measures the ability of bentonite to bond, requires only about two hours to complete, is simple and reproducible, and utilizes readily available equipment that has been standardized for decades.

Jan 1, 2003

By R. Frenette, A. W. Mo, H. A. Hamza

Fine particles present major technical and economic problems to those who deal with solid/liquid separation processes. In the coal industry the problem is compounded by the large amounts of produced fines such as those present in Western Canadian coals. Flocculants in the form of high molecular weight water soluble polymers are commonly considered an effective solution for the enhancement of the separation process. These reagents are relatively expensive especially when considering a low-price commodity such as coal. Optimization of the use of these reagents is therefore an operational necessity. Six polymers were evaluated as to their effectiveness in flocculating a fine coal tailing. Results were compared with those for a reference flocculant, in-use at that time in the washery. It was shown that, in general, flocculants significantly improve the solid/liquid separation process. The ranking of the flocculants as to their effectiveness in settling and filtration indicated that the best flocculants for settling were not necessarily the most effective for filtration. Flocculants that showed the best filtration improvement were generally cationic and those best for settling were anionic.

Jan 1, 1988

By A. G. Journel

Few Earth Scientists realize fully the assumptions they are making, willing or not, when pooling into a same histogram data coming from different locations and considering such histogram as an estimate of a probabilistic distribution. First they need the hypothesis of stationarity in space; second the presence of spatial auto-correlations implies that data be unequally weighted according to their relative locations and the degree of spatial continuity of the underlying phenomenon. The novel technique of indicator kriging allows construction of local or global histogram which can be considered as unbiased estimators of precisely defined probabilistic distributions, full account being given to the underlying continuity. Such estimates of local distributions can be used in mine planning for estimation of local recoverable reserves.

Jan 1, 1982

By James E. Monsees, Richard J. Proctor

INTRODUCTION Los Angeles is one of the world's largest cities in area with a span of 70 km between its north and south limits. The population in the Los Angeles Basin exceeds 11 million people. Los Angeles is second only to New York City in density of U.S. urban population and it operates one of the largest city bus fleets in the world, 2,500 buses. After many years of planning and many consultants' reports, it is planned to initiate a 30 km (18.5 miles) starter line subway -- the "Wilshire Corridor" (Figure 1). Construction is to start in 1985. In several locations, subway routes ultimately will skirt or cross old oil fields, which may cause gassy tunneling. Of particular note are the La Brea Tar Pits, which overlie a part of the old Salt Lake oil field. Tunneling through tar sands for about 3 km will be unique for subway construction and will occur on the starter line. Experience with previous gassy tunnels in the greater Los Angeles area shows that tunnels can be completed safely if precautions are taken. Abundant ventilation is the main solution, although other precautions are discussed herein.

Jan 1, 1985

By Haydn H. Murray

The three major catalyst markets that utilize industrial minerals as raw materials are petroleum refining, chemical processing, and emission control. Because of economic, competitive, and regulatory pressures, catalyst producers are pushed to develop products with improved performance to meet changing environmental standards. Also, refiners are demanding new families of cracking catalysts that will crack residual fuels. In 1987, worldwide cracking catalyst sales amounted to $457 million (Occelli, 1988a). Recently enacted federal and state laws to improve air quality have prompted strong growth for environmental catalysts, which in 1989 accounted for more than a third of the $1.9 billion catalyst market in the United States (Farrauto, Heck, and Speronello, 1992). A catalyst is a material that promotes or enhances a chemical reaction but does not itself enter into the reaction. One of the more important mineral groups used as catalysts is clays. The first recorded use of clay as a catalyst was its use in the dehydration of alcohol (Bondt et al., 1797). Clay minerals that are used as catalysts are kaolinite, halloysite, smectite, palygorskite, and sepiolite. Minerals used as catalysts, catalyst supports, or as a raw material to make zeolites are kaolinite, halloysite, sodium montmorillonite, calcium montmorillonite, hectorite, palygorskite, sepiolite, talc, calcined kaolinite, gibbsite, chlorite, and titanium dioxide.

Jan 1, 1994

By Eddy J. Jacques

When the automatic control of a ventilation process is considered, and supervising expert systems need to be designed, an important problem to address is: what will be the optimal set points of the regulators that should meet a certain number of independently formulated requirements, distributed over a ventilation network? The set of these requirements, expressed in terms of air flow quantities or differential pressures in certain airways, need not be consistent. Their number is not limited by the number of available regulators, nor by their nature, i.e. passive or active. Moreover, they may be subject to upper or lower limit values. The method described here addresses this problem and tries to provide a tool that should allow to calculate the set points of all the regulators as a global and optimal solution with respect to this set of distributed requirements. The pure mathematical developments in this paper are kept as short as possible in order to allow more room for the description of a relevant example.

Jan 1, 1991

By Abou Saghafi

In order to investigate the design parameters of a future longwall in a thick coal seam a numerical model of gas emission from the goaf area was developed. A Longwall goaf was modelled as a collection of different size coal blocks. For each coal block the partial differential equation of gas flow was independently solved. In developing the flow equations, both pressure-driven and diffusion driven gas flow regimes were considered. The total gas emission rate was calculated by integrating the gas release from each individual coal block over the whole goaf area. The main output of the computer program are gas flowrate from goaf and residual content of caved coal in the goaf as a function of distance from the face. The model was applied to a longwall face driven in a thick seam where large volumes of coal in the roof were to be left behind the face. The gas contained in the coal was mainly CO, with a high desorption rate. Simulations were under- taken to quantify the effect of size of the caved coal on the flowrate from the goaf. The flow properties of coal, such as diffusivity, permeability and coal swelling due to gas adsorption, were directly measured on coal samples from the seam.

Jan 1, 1996

By Hajime Miki, Michael J. Nicol

Relatively simple techniques have been developed which enable the electrochemistry of sulfide minerals to be studied with particles varying in size from above 100 pm to less than 1 pm. Both oxidative and reductive processes have been studied wing the minerals pyrite, arsenopyrite and chalcopyrite. It has been shown that it is possible to completely oxidise or reduce the minerals during a single voltammetic sweep. The resulting voltammogram produces peaks which are characteristic of each mineral and can be used to qualitatively identify the minerals. In the case of chalcopyrite, it has been demonstrated that the charge involved in the anodic oxidation can be quantitatively related to the amount of copper dissolved. Quantitative information can be obtained using peak fitting techniques. Interesting differences in the behaviour of the minerals in sulfuric and hydrochloric acids have been observed, particularly in the case of pyrite for which a second major peak is obtained which has been attributed to the oxidation of elemental sulfur in the presence of chloride ions. The technique offers the possibility of providing mineralogical information of individual particles based on an electrochemical voltammetic finger print.

Jan 1, 2005

In conjunction with steady increases in production levels, longwall operators have applied greater quantities of ventilating air and spray water in an effort to control respirable dust and/or methane. Air velocities greater than 7.6 m/s (1,500 )fpm) have been measured on longwall faces. Operators have expressed concern over the potential entrainment of respirable dust at these high velocities. The greatest likelihood for entraining dust into the high-velocity airstream may occur as shields are advanced, allowing relatively dry particles to fall from the shield canopy directly into the airstream. Laboratory tests to simulate dust liberation during shield movement were conducted at the Pittsburgh Research Laboratory of NIOSH at velocities ranging from 2.0 to 8.2 m/s (400 to 1,600 fpm). Airborne dust samples were obtained with personal impactors to quantify the size distribution and concentration of the dust entrained at the various air velocities. Statistically significant increases in both total and respirable dust concentrations were measured as test air velocities were increased.

Jan 1, 2002

By O. Akinkugbe

The safe, productive exploitation of coal in multiple-seam situations requires specific design technology. At present, there are two general design approaches that the mining engineer can use to analyze the multiple-seam problem in question, either simple empirical relationships or complex numerical models. Often, the empirical approaches are too general for the specific problem and the numerical models require too much time and expertise for the practicing engineer. In this paper, a new program designed for quickly and easily calculating the stresses, strains, and safety factors associated with basic multiple-seam mining situations is presented. The program implements a simplified, two-dimensional boundary-element method in order to model the complex multiple-seam stress and displacement interactions. The program incorporates automatic coal and gob property generation to simplify the input, and inherently calculates pillar safety factors to enhance the output.

Jan 1, 2004

By Yuusaku Tominaga

A flexible expert system for a personal computer has been developed to take countermeasures for prevention of emergency in underground coal mines. The system makes a diagram to estimate maximum airflow rate of a specified branch such as coal face or advancing face, etc. under the conditions of opening regulators set in any two different branches, by computer simulation. The system approximates the ventilating condition underground by using both measured values and safety factor derived from the rules in the system. The probability of happening gas explosion, spontaneous combustion and mine fire underground is shown on a display and countermeasures in a data base in the system are selected according to a confidence factor. When it is recognized in the system that either safety factor or confidence factor of countermeasure has a small value, the system sends information relating to reasoning in the system to registered human experts by computer communi¬cation and facsimile. The replies in file transfer from the experts are stored in the system and reconsultations for estimation of underground condition are started automatically. As the replies in facsimile are shown on the display, user inputs new rules and, values for reconsultation. It is shown that the system is available to take better countermeasures as the condition' of a network in coal mine is changed by mining day by day.

Jan 1, 1992

By Richard R. Klimpel

This paper reviews some of the factors involved in selecting amine flotation reagents used to remove silica from ores. A comparison is made between the chemical reagent design approaches used to identify flotation reagents that are used to recover silica- and oxygen-containing minerals and the chemical reagents used to recover sulfide minerals. This introduction gives practitioners who are involved with oxide- and carbonate-type minerals and who may not be familiar with sulfide mineral flotation some ideas of the chemical reagent design challenges that exist with froth flotation on a broader scale and why oxide type mineral flotation reagents are what they are. This is followed by several sections that discuss various classes of available amines. The closing sections emphasize that the optimal choice of an amine collector depends not only on that amine's specific chemical characteristics and costs but also on the operating conditions, especially the flotation feed particle size distribution.

Jan 1, 1999

By Robert A. Jankowski, John J. McClelland, Charles Babbitt

The purpose of this study was to develop guidelines to enable mine operators to maximize longwall dust reductions, while optimizing the use of ventilating air and shearer water consumption. A recent investigation by Foster-Miller Incorporated, under a Bureau of Mines contract, quantified the effect of increased face airflow and shearer water supply on face dust concentrations. A 70 pct reduction in respirable dust levels was achieved at the shearer operator's position during tail-to-head cutting by an incremental increase in average face air velocity from 83.8 m/min (275 fpm) to 123.4 m/min (405 fpm), while holding shearer water consumption constant. A 60 pct reduction was achieved through an increase in shearer water pressure and flow from 9.1 kg/cm2 (130 psi) at 0.19 m3/min (50 gpm) to 19.7 kg/cm2 (280 psi) at 0.28 m3/min (75 gpm), holding airflow constant. The combined effects of increasing both parameters produced an 85 pct reduction. Optimal usage of ventilating air and shearer water consumption can be achieved by defining a "point of diminishing returns" above which further increases no longer reduce dust concentrations, proportionately .

Jan 1, 1987