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By J. E. Gebhardt, S. Chander

Significant advances have occurred in the use of electrochemical techniques for sulfide mineral flotation research. The techniques have been used singly or jointly with other characterization methods. When used in combination with other methods, the electrochemical methods provide a means to control the state of oxidation of the surface. Various analytical methods are employed for characterization. The methods that have been used include wetting, x-ray photoelectron and fourier transform infrared spectroscopies. The electrochemical methods include voltammetry and transient electrochemical techniques of galvanostatic polarization and AC impedance spectroscopy. The challenge for the future lies in the utilization of this knowledge in plant operations so as to increase the overall efficiency of flotation separations.

Jan 1, 1989

By Mulong Yu, Yosry A. Attia

Beneficiation of high magnesium Florida phosphates requires ultrafine grinding to liberate the dolomite (the main source of magnesium), and a separation process capable of dealing with ultrafine sizes such as selective flocculation. The objective of this study was to investigate the feasibility of separating dolomite from apatite ultrafines by selective flocculation. To achieve this objective, selective polymeric reagents to either dolomite or apatite must be first designed and synthesized. This challenging task was accomplished by carefully selecting complexing/chelating agents which are selective to either the Ca or Mg ionic sites on the minerals, and incorporating these reagents into the structure of long chain water soluble polymers to obtain either selective flocculants (with high molecular weight, MW, polymers), or selective dispersants (with low MW polymers) to either the dolomite or the apatite particles. Synthesis and testing of these polymers on individual and mixed mineral slurries, and on a sample of natural high magnesium phosphate ore, have been attempted and the results are described in the paper. The preliminary results showed encouraging signs for the feasibility of selective flocculation separation of dolomite from apatite.

Jan 1, 1993

By J. E. Gebhardt, D. W. Fuerstenau

The use of small quantities of polyacrylic acid (PAA) was found to significantly improve the flotation of fine-sized hematite particles at pH 4.1 and 0.001 M NaCl with sodium dodecykulfonate (SDS). Low polymer dosages before collector addition aid flotation by forming flocs of primary particles, but excess polymer results in low flotation yields due to surface saturation by the hydrophilic polymer. Contact angles, measured on a hematite disk, substantiate the hydrophilic nature of an adsorbed polymer film. Pre-adsorbed PAA reduces the amount of SDS adsorbed on the hematite particles, but the flotation of hematite flocs occurs, even at reduced amounts of adsorbed SDS, and is not depressed until PAA dosages in excess of the saturation value are used. Separation of a hematite-quartz mixture can be achieved by SDS flotation of PAA,-flocculated hematite. Maximum selectivity results with the addition of small quantities of PAA, while excess polymer is detrimental to the recovery of hematite. Consecutive flotation states on a single feed yield a higher grade hematite product at some expense to the overall recovery.

Jan 1, 1987

By Jose M. Milian, Raphael F. Matson

An intensive study was started in 1968 to determine the most economical process for winning nickel and cobalt from an extensive de- posit of complex, low grade nickel-cobalt ore (1.6% Ni, 0.10% CO) designated "the Greenvale ore." In 1974 the commercial plant at Yabulu, in Queensland, Australia, began processing the ore. In the interim, a great deal of laboratory and pilot-plant effort was applied to develop technical, process and commercial design data to demonstrate to potential financial backers and customers that a full-scale plant was feasible. The laboratory test work, pilot plant facilities and pro- gram are briefly reviewed in this paper.

Jan 1, 1979

By A. Peppas

Perlite is a naturally occurring siliceous rock, which can be expanded from four to twenty times its original volume when heated at a temperature close to its softening point. The expanded perlite is characterized by increased sound and thermal insulating properties. However, the conventionally expanded perlite products have high porosity and low mechanical properties that limit the range of their applications in the construction and chemical industry. The present work aims at the development of new closed porous microcellular material from perlite with enhanced mechanical and physical properties to be applied in new applications, like joint compounds, functional fillers for special paint types, special blasters and mortars, artificial marble. For the production of these new materials a vertical electrically heated furnace with six different heating zones and controlled gradient temperature profile was used. The effect of major process parameters, like temperature and air flow, on the quality of the produced materials was studied using Greek perlite from Milos Island. The quality of the new products was evaluated in terms of their bulk density, compression strength, water and oil absorption, surface area and pore volume. The experimental results show that the produced materials are characterised by improved mechanical and physical properties compared to the conventionally expanded perlite products.

Jan 1, 2006

By Steven H. Brown

Ore bodies which were once uneconomical to mine by conventional methods such as tunneling or open pits, have become attractive due to the development of nonconventional techniques, involving considerably less capital expenditure. Technologies such as uranium solution mining or in-situ leaching, have enabled commercial scale mining and milling of relatively small ore pockets of lower grade, and may make a significant contribution to overall U.S. uranium supplies during the next 20 years. Commercial size solution mining production facilities have operated since late 1975. Solution mining involves the pumping of ground water, fortified with oxidizing and complexing agents into an ore body, leaching and solubilizing the uranium in-situ, and then pumping the solutions to the surface where they are fed to a processing plant. Processing involves ion exchange, precipitation, calcining, and packaging operations. This paper presents an overview of the solution mining process and the health physics monitoring programs developed over the last four years at several production facilities as a result of the radiological character of these processes. Although many radiological aspects of the process are similar to that of conventional mills, conventional-type tailings as such are not generated. Some special monitoring considerations are presented which are required due to the manner in which radon gas is evolved in the process and the unique aspects of controlling solution flow patterns underground. An overview of the major aspects of the health physics compliance and monitoring programs that have been developed are discussed.

Jan 1, 1981

By Donald Ross-Watt

Mining project investment concerns the installation of mine capacity for the purpose of generating a stream of future economic benefits. In order to make this type of investment decision, the optimum specifications for the project must first be determined. Then, the economic justification of the investment tin be evaluated based on these specifications. Economic evaluation to guide mining project investment decisions is based on a proposed plan for mining the deposit over its operational life. If single point estimates are made of deposit characteristics and environmental parameters* as the basis for assessing a future stream of economic benefits associated with the investment, a future mining-plan can be optimally fitted to these estimates and, to the extent that such estimates are actually realized, this plan will retain optimality.

Jan 1, 1979

By E. Topuz, M. J. McPherson, I. M. Konduri

The research is carried out to investigate the flow mechanics and effectiveness of face ventilation using induction fans, as an effort to provide a more efficient alternative to conventional auxiliary duct or brattice ventilation systems. The induction effects and plume longevity of fluid jets are being studied with the help of a plexi-glass model, using water as the fluid medium and creating a system that is dynamically similar to the flow in mine headings. This scaled model represents a typical 1.5m x 6m x 25m heading connecting to a crosscut. Reynolds Number criteria are used to obtain dynamic similarity of the flow in the designed model to simulate real mining conditions. The role of various parameters such as nozzle position in three dimensions, airway roughness, nozzle geometry, and flow rate in the jet are studied. During the laboratory tests, flow visualization techniques, coupled with still and video photography, were employed to identify the flow patterns. The results indicate that in typical coal mine headings, jet fans can produce effective face ventilation for distance up to 30 meters.

Jan 1, 1995

By V. B. Achanti, A. W. Khair

This paper deals with the effects of various bit geometric parameters on the failure characteristics of rock material. Improving the rock-cutting efficiency of continuous mining machines has proven to be an interesting research topic during the last few decades. In the current study, an automated rotary rock-cutting simulator, duplicating a continuous miner, was used to study these parameters in the laboratory. The improvement of bit performance in terms of its life, cutting efficiency, dust production and energy consumption has drawn widespread attention. Research has demonstrated that optimizing bit parameters can result in efficient fragmentation of rock. Indiana limestone rock material was used in this study. The bit tip angle, bit tip size, bit spacing, depth of cut and cutting velocity of the rotary drum were varied to investigate the failure characteristics. The cutting pressure, penetrating pressure and the depth of cut were monitored on the simulator during the cutting process. Airborne dust and settled dust were measured for each experiment. Then, the specific airborne dust and specific energy were determined for each type of bit. Triaxial tests were carried out to correlate the failure angle of the rock in the static case to the dynamic cutting process failure. The physical and mechanical properties of the rock were also determined to assess their influence on the wear characteristics of each bit.

Jan 1, 2000

By Douglas W. Fuerstenau

This paper concern the specific adsorption of sulfate anions on nonmetallic minerals and its role in flotation. The specific surface affinity of sulfate ions in various systems has been observed in the results of electrokinetic measurements that show conditions under which sodium sulfate can reverse the sign of the zeta potential. The electrical double layer model provides a means for interpreting the results and for estimating the free energy of adsorption of sulfate ions. Because of their surface activity, sulfate ions not only can function as a depressant in the flotation of oxide minerals with physisorbed anionic collectors but also can function as an activator for flotation with physisorbed cationic collectors. Their role in depressing or enhancing the flotation of the sparingly-soluble mineral barite is also explained in terms of the double layer model.

Jan 1, 2005

By M. Alnot, J. A. Mielczarski, J. J. Ehrhardt, J. M. Cases

The flotation behavior of minerals depends on the balance between hydrophobic and hydrophilic species present at the surface of the minerals. The direct characterization of the interfacial products formed by the interaction of water and an aqueous solution of amyl xanthate with chalcopyrite, tetrahedrite and tennantite (the two former contain antimony and arsenic) were carried out by X-ray Photoelectron Spectroscopy (XPS) and infrared (IR) reflection spectroscopy. The experimental data collected from in-situ (IR ATR) and ex-situ (XPS, IR External Reflection) measurements have let us determine the types of the adsorption products and to propose mechanisms of interaction between the aqueous solution of surfactant and surface of the investigated minerals. It is shown that two major processes take place at the mineral interfaces: (i) the interaction with water and oxygen resulting in the formation of the oxidation products which are mainly hydrophilic (but also a hydrophobic product was found), and (ii) the adsorption of xanthate producing different types of hydrophobic surface products. The results obtained show differences in the composition of the outermost atomic layers of the investigated minerals which obviously will produce differences in the flotation behavior of these minerals. This work forms a good fundamental basis for a better separation between copper minerals containing arsenic and antimony, and chalcopyrite.

Jan 1, 1995

By H. Köse, C. Tatar, C. Helvaci, F. Simsir

The Çayirhan coal basin is located 124 km (77 miles) west of Ankara,Turkey. With approximately 520 Mt (570 million st) of lignite reserves, the Neogene Çayirhan basin is one of the important coal districts of the central Anatolia region. The Çoraklar formation consists of crossbedded sandstone, channel fill conglomerates, mudstones, carbonaceous shales and volcanoclastic pebblestones, which are fluvial in origin. The lower and upper lignite seams occur, respectively, in the lower and the uppermost parts of the Çoraklar formation. The lignite deposits are in the Çayirhan and Koyunagili portions of the Beypazari Neogene basin. The Çayirhan coalfield consists of lower and upper lignite seams. The lower lignite seam does not outcrop at the surface. Its lateral discontinuity and relatively low sulfur content, plus sedimentologic and stratigraphic features of the associated sediments, indicate a fluvial origin. Thus, the lateral spreading and geometry of the lower lignite deposits were controlled by the channel, flood plain and well drained marshes of a fluvial system. The mining method employed at Çayirhan is the fullymechanized, retreat, working longwall with caving system. Due to ventilation, haulage and tectonic conditions, panel lengths from 0.6 to 1.7km (0.4 to 1.1 miles) are chosen, and 220-m (720ft) face lengths are used. The annual coal production is 2.2 Mt (2.4 million st).

Jan 1, 1994

By R. R. Klimpel

This paper is a summary of the author's industrial experiences on the selection and optimization of flotation reagent schemes for the recovery of gold species. The trends given are a composite of data and experiences gained on 24 different gold ores from around the globe. The primary emphasis is on the benefits of matching the associated gold mineralogy to a reagent scheme most appropriate for that mineralogy. Two general categories are discussed: the flotation of free or native gold species and the flotation of gold associated with a variety of sulfide minerals. Important plant operating factors influencing each of these two categories are presented with supporting examples. Carefully matching reagent chemistry and appropriate operating conditions to any given gold-bearing ore will not only lower the total reagent cost but, more importantly, can lead to measurable increases in gold recovery.

Jan 1, 2000

By E. Sehner, G. Van Weert

Metal chloride pyrohydrolysis is a fifty year old technology, operating satisfactory in many plants around the world, mainly on ferrous chloride, The capabilities and costs of its two equipment options (spray roaster and fluid bed pyrohydrolysis) are well known. Why is the technology not more widely used in mineral processing, beyond the production of MgO and upgraded TiO2slag? After briefly reviewing chloride vs. sulphate process characteristics and existing plant operations, this paper will discuss pyrohydrolysis options for the mine developer using the processing of ilmenite, siliceous zinc oxides and oxidic nickel / cobalt ores as examples.

Jan 1, 2003

By K. Osseo-Asare

Metal recovery from solution, i.e., the formation of a solid product from a purified aqueous electrolyte solution, is increasingly becoming more than a simple matter of bulk precipitation. In many cases, operating conditions must be carefully manipulated to control the rate and yield of the precipitation/crystallization process, as well as the purity and physical characteristics of the solid product. A review is presented of the underlying physico-chemical processes, with emphasis on solution and interfacial chemistry. Opportunities for the integration of hydrometallurgical metal recovery and materials processing operations are discussed.

Jan 1, 1989

By G. E. Jones, G. K. Hoffman

Two Sun Juan Basin studies were completed through the USGS National Coal Availability program. The study areas are in the northwest Bisti field (Fruitland Formation) and in the eastern Standing Rock field (Menefee Formation). In the Bisti and Standing Rock areas, the original coal resource5 are estimated at 4.66 and 3.1 7 Gt (5.14 and 3.49 billion st), respectively. The Bisti coal resources are greatly reduced by the Bisti-De-Nu- Zin wilderness area, which contains an estimated 1.13 Gt (1.25 billion st) of coal. Technological restrictions remove 32.5% from Standing Rock's original resource. Available resources are 60%. 2.79 Gt (3.07 billion st), of the Bisti original resource and 65%, 2.07 Gt (2.28 billion st), of the original Standing Rock resource.

Jan 1, 2002

By F. Calizaya, I. Duckworth

An ore-pass is an underground conduit used to transfer ore from one level of a mine to another. This method of transportation depends on the elevation energy only; therefore, it has very low operating cost. However, two inherent problems may hamper this process: (1) hang-ups of interlocked pieces and (2) a sudden release of trapped air from the ore-pass (belching). These events can create unsafe conditions with the potential for catastrophic consequences. This paper presents a summary of CFD modeling studies that were formulated to investigate the pressure build-up and belching of dust and rock particles from long ore-passes. The models were calibrated against field data collected from an actual ore-pass system and used to predict the airflow-pressure distributions in the mine for various ore feed rates and ore-pass geometries. P.T. Freeport Indonesia’s Grasberg ore-pass system (240,000 tpd capacity) was used for this purpose. This system comprises of four active ore-passes, with each being more than 600 m in vertical length.

Jan 1, 2004

By Gerrit V. R. Goodman, Fred N. Kissell

The issue of miner safety in case of an underground mine fire has been extensively examined by both government and industry. These efforts have intensified in recent years following a number of fatal fires at underground coal mines. As a result, there is an increasing interest in the reliability of coal mine escapeways during a mine fire. This paper discusses the use of fault tree analysis for evaluating escapeway reliability. A fault tree is developed using standard logic formulations. It is later evaluated using commercially available software. The computer model uses Boolean reduction to obtain the minimal cut sets and minimal path sets of the tree. A brief analysis is also conducted to determine the occurrence probability of the TOP event. This study shows that fault tree analysis is a viable means of analyzing escapeway reliability. The cut and path sets reveal those event sequences leading to fatalities. Such information is useful in safety training and accident prevention. The probability of the TOP event shows the frequency of occurrence for fatalities in an underground mine fire. The usefulness of this value, however, is limited by the accuracy of the data for the initiating events. For mining events, the data is difficult to estimate precisely.

Jan 1, 1989

By James G. Donovan, Mario G. Karfakis

A large percentage of Southern Appalachian coal reserves are located in seams less than 36" thick. As thicker and currently more mineable deposits are exhausted, methods of underground thin-seam extraction must be developed. Past experience with highwall mining of thin-seam coal has indicated that recovery rates tend to be lower than in conventional operations. It is suspected that this will also apply to underground thin-seam mining, regardless of proposed technology or mining method. Backfilling is one alternative for thin-seam coal mining; although backfill has been used extensively in hard rock mining its use in coal mining has been limited. The ability of backfill to provide additional ground support may enhance coal recovery by allowing for the design of undersized pillars. Backfill is capable of providing additional ground support by restricting lateral deformation of surrounding coal pillars and roof. This additional support can result in significant increases in recovery from thin-seam coal deposits. However, the overall feasibility of backfill is dependent on the in situ behavior of the fill material, the properties of the fill, the effects of the filling method on the total mining operation, and the cost of filling per extra ton of coal recovered.

Jan 1, 2001

By J. E. Hoffman, S. P. Sandoval, T. J. Keefe, K. P. V. Lei, O&apos

The U.S. Bureau of Mines investigated the use of the Fe2+/Fe3+-SO2 (FFS) anode reaction in the copper leaching-solvent extraction-electrowinning circuit. The investigation revealed that six process variables, including anode type, Fe 21 concentration, current density, electrolyte temperature, degree of agitation, and manifold injection point were found to influence cell voltage and cell current efficiency. A 47% voltage reduction (0.8 versus 1.5 V) compared to conventional electrowinning with activated lead (ALE) anodes was achieved at a current density of 258 A/m2 (24 A/ft2) with an industrial electrolyte. Current efficiency was maintained above 90%, and S02 above the cell measured less than 1 ppm when activated carbon was used to assist the reduction of Fe" by S02 in the copper electrolyte. Solvent extraction tests showed that Alamine 336 is a stronger H2SO4 extractant than is needed to extract the excess acid produced by the FFS anode reaction.

Jan 1, 1993