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By R. T. Jones

Base metals and platinum group metals can be collected in metallic alloy form, via a wide variety of smelting processes. The recovery, or degree of collection, of the valuable metals is a function of the extent of reduction in the furnace, which, in turn, is indicated by the fraction of iron present in the feed materials that report to the alloy. An equation has been developed that relates the recovery of various metals (such as Ni, Co, Cr, and PGMs) to the recovery of Fe. This recovery equation (for each metal) is characterized by a single parameter (K?) that can either be empirically fitted to the data, or expressed in terms of the equilibrium constant and the ratios of the activity coefficients involved. Data from a number of varied DC arc furnace campaigns are presented to illustrate this behaviour.

Jan 1, 2009

By B. Z. Weiss, N. R. Comins, F. Blum

Some aspects of the mechanical behaviour of chromium-containing dual-phase 3CR12 steel were investigated as a function of the temperature and strain rate. The yield stress was found to depend on both the temperature and the strain rate, with no substantial differences between the longitudinal and the transverse directions. The strain-rate sensitivity decreased with increasing temperature. The yield stress could be presented as a function of a temperature-strain-rate parameter. Impact test results showed substantial differences between the energy absorption of the transverse and longitudinal specimens above the ductile-brittle transition temperature. Changes in energy absorption with temperature were gradual for specimens in both orientations, and the transition from ductile to brittle behaviour occurred between 373 and 173 K. Strain rates ahead of the tip of notches with different geometries were calculated and measured experimentally.

Jan 1, 1990

By R. M. Morris, G. A. Matthesius, M. J. Desai

Slow pyrolysis experiments were caried out on samples of coal from north em Natal having a volatile mater content ranging between 10 and 25 per cent by mass and a constant particle-size distribution. The tests were conducted at atmospheric pressure in a helium atmosphere, and ata heating rate of 10 KImin and a final temperature of 1220 K. The pyrolysis products were taken as coke and volatile mater (tar and eight other species), and tMir respective yields were measured. The experimental results were used in the modification of an existing mathematical model and in the derivation of new corelations for some of the parameters of the model, so that the volatile products of a coal can be predicted from ultimate and proximate analyses of the coal. The pyrolysis tests showed good agreement between the model predictions and the experimental results.

Jan 1, 1987

The 101 st Annual General Meeting of The South African Institute of Mining and Metallurgy was held in the Gold Room, Transvaal Automobile Club, 60 5th Street, Lower Houghton, Johannesburg on Wednesday, 12th August, 1998. Obituaries The President announced the death, during the year, of the following members: Honorary Life Fellows and Past Presidents H.E. Cross, D.G. Malan, P.W.J. van Rensburg Life Fellows J.B. Rolfes, W.C. Walmsley Fellows H.F. Boshoff, M.L.A. Fitzgerald, J. Humphriss Retired Fellows H.S. Botha, E.Collier, J.L. Curtis, A.H.H. Davison, D.I. Legge, B.D. McNeice, J.A. Northcott, D. de V. Oxford, S.S.K. Penney, P.C. Pirow, J. Pope, A.J. Rossouw, A.N. Shand, E.P. Smit, H.V. Solomon, S.G. Taussig

Jan 1, 1998

By R. Armstrong, C. Ware, P. Sudan, G. Whitmore

The northern KwaZulu-Natal (KZN) coastal dune cordon, South Africa, extends from north of Durban into Mozambique. The Quaternary dune cordon, which can be up to 2 km wide, comprises a series of stacked, unconsolidated dunes that in places attain a height of over 100 m. Mining of the dunes produces much of the world’s supply of ilmenite, rutile and zircon. This paper documents the age of zircon grains separated from dune units, identifies likely source rocks and presents an evolutionary history for the dune cordon. Between 30 and 60 detrital zircon grains from three distinct units from the northern KZN coastal dunes were analysed for U/Pb isotopic ages using the SHRIMP II at the Australian National University. The samples represent units from the base (ca. 250 ka; luminescence age1),middle (ca. 190 ka2) and upper (ca. 20 ka2) portions of the coastal dune cordon. Zircon grain ages identify three source populations: (1) a 1 000 to 1 200 Ma group correlated to the Natal Metamorphic Province, (2) a 500 to 650 Ma group representing a Pan-African belt, which may correlate to the Mozambique Belt and (3) a ca. 650 to 800 Ma group of unknown provenance. Surprisingly, the presently exposed basement, comprising the Kaapvaal Craton and Archaean volcano-sedimentary sequences, has not supplied a significant amount of zircon grains (< 5%).This suggests that unroofing of basement rocks in the region has only occurred during the last 20ka. In addition, the absence of zircon grains younger than 500 Ma indicates that the bulk of zirconis not reworked from the Karoo Supergroup cover succession, but may be sourced by reworking of the Natal Group sandstones.

Jan 1, 2003

1. Book review Economics of mineral exploration in Australia, by Brian W. Mackenzie and Michel L. Bilodeau. Australian Mineral Foundation (Private Bag 97, Glenside, South Australia 5065). 198pp. $A58. $A45 for students. Reviewer: D.G. Krige 2. Recent publications Combustion of coal liquid mixtures, by G.F. Morrison. London, lEA Coal Research, 1983, 52 pp. Hafnium: physico-chemical properties of its compounds and alloys. Vienna, International Atomic Energy Agency, 1981. 408 pp. 620 Austrian schillings. Canadian mines handbook 1984-85, edited by CD. Gardiner. Toronto, The Northern Miner, 1984. 500 pp. $24. Drilling equipment in Canadian mining and exploration- opportunities for the industry, by AJ. Jakubek. Toronto, Micromedia Limited (144 Front Street, Toronto M5J IG2, Canada), 1984. Research report 1984. Port Melbourne, Division Mineral Chemistry, Commonwealth Scientific and Industrial Research Organization, 1984. 190 pp. Surface engineering Wear is an unavoidable problem in virtually all products of the engineering industry, from the minute bearings of instruments to the cutting surfaces of earth-moving plant. Safety in mines About 50 papers will be presented at the 21st International Conference of Safety in Mines Research Institutes at Sydney from 21st to 25th October, 1985. Some 250 delegates from 30 nations are expected to attend. Professional development seminars March 18th-21st, 1985 Underground Blast-hole Mining May Ist-3rd, 1985 Mineral Processing of Gold Ores May 6th-10th, 1985 Mineral Comminution Systems May 13th-15th, 1985 Processing of Metallurgical Residues Analytical chemistry The Second Symposium on Analytical Chemistry in the Mining, Exploration and Processing of Materials is to be held in Pretoria from 15th to 19th April, 1985.

Jan 1, 1985

By P. Harris, N. Heywood

An existing 1 800 m long pipeline, which carried waste mica slurry from kaolin processing, is to be recommissioned. The mica solids throughput is to be substantially increased from 5.2 t/h up to a maximum of9.53 t/h, but with a typical throughput of around 7.5 t/h. Because of this throughput increase, it was unclear whether the existing 80 mm diameter pipe would be adequate. In addition, the pipe route is to be extended by 250 m to 2 050m, and its elevation at discharge to settling lagoons increased from 66.2 m to 80 m. The pipeline hydraulics of waste mica slurry were investigated for the 80 mm diameter pipe using the Saskatchewan Research Council?s (SRC) Two-Layer Flow Model, for the maximum mica solids throughput of 9.53t/h. The pipe operating velocity was compared with the predicted deposit velocity for several mica concentrations, ranging from 20% to 50% by weight. Estimates were made of the total differential pressure across the proposed2 050 m long pipeline, as well as the power imparted to the slurry by the pump, and the specific energy consumption (SEC). Two pipe diameters were assumed: 80 mm when no mica wall deposit is present, and 70 mm when there is a 5mm mica wall deposit. This parameter has a significant effect on the determination of the appropriate pipe operating conditions. For the pipe operating velocity to remain adequately above the deposit velocity (and therefore for the heterogeneous flow pattern to prevail in either horizontal or inclined pipe), it was concluded that if the newly commissioned pipeline contains no mica wall deposit, the pipe should initially be operated at a mica concentration of between 20% and 25% by weight, probably with a target mica concentration of about 23%. A 23% mica

Jan 1, 2007

By C. Lemire, A. Biscaro

Ferro-alloys are sold according to the size grading specifications of users. Fines are produced during crushing and the amount produced depends on the crushing process and the physical characteristics of the ferro-alloy. The market value of fines has declined. Market demand is very weak and in some extreme cases is nonexistent. An induction furnace melt process has been developed to solve this problem. The process feasibility has been demonstrated on a small scale with charges of approximately 2.5 kg. The piloting was carried out using a 100 kW furnace with a metal liquid capacity of 140 kg. The operating parameters were determined during the pilot process. The procedures were defined and the equipment required for melting fines produced at the client&apos;s site was sized. With the production of ingots, the client can now recover the full value of ferro-alloy fines.

Jan 1, 2004

By M. Abdellatif

Keywords: Pyrometallurgy, furnace, DC arc furnace, smelting, silicon The technical feasibility of silicon smelting in a DC arc furnace was investigated. A graphite-lined furnace was operated at power levels of 150 to 160 kW, and 40 to 60 V. The average feed rate during the silicon production period was about 30 kg/h. The recipe consisted of pre-mixed batches of 28% petroleum coke and 72% lumpy silica. The target furnace operating temperature was set at 1600°C and then raised to 1700°C. In total, about 1.6 tons of premixed feed materials was processed over 16 feeding?tapping operations. The feed was manually charged into the furnace in sub-batches of 10 to 40 kg at a time. The total batch mass was set at 90 kg during the initial part of the testwork, and increased to about 120 kg for the rest of the campaign.

Jan 1, 2011

By G. W. Healy

The smelting of calcium carbide has always been plagued by eruptions, too often with serious injury y or loss of life. To find their causes, the author calculated an internal energy balance using 1992 data for CaC2 and CaO, and older data for the remaining items. The heat content of the charge, and that of the hot gases formed at the reduction temperature, showed that only a fraction of its heat content can be supplied by these gases. Laboratory data on the electrical resistivity of fine mixtures of coke and non-conductive solids were extrapolated to a commercial carbide charge, and then used to calculate the heat produced by current flowing through the mix from the electrode surface to the hearth, which, under favourable conditions, sufficed to bring the charge to 1900 K and higher, at which temperatures reduction could take place.

Jan 1, 1995

Council and Standing Committees, 1975-1976 President: Dr R. E. Robinson. Vice-Presidents: Dr M. D. G. Salamon and P. A. von Wielligh. Honorary Treasurer: J. K. E. Douglas. Immediate Past President: Prof. R. P. Plewman. Members of Council: Dr M. G. Atmore, J. D. Austin, C. T. Fenton, J. A. Holmes, P. Holz, Dr P. R. Jochens, Prof. R. P. King, Dr D. G. Krige, Dr D. I. Legge, D. G. Malan, C. T. Shaw, D. A. Viljoen, R. A. von Maltitz, H. M. Wells. Chairman, Witbank-Middelburg Branch: E. J. Jackson. Chairman, Orange Free State Branch : G. J. C. Young. Past Presidents Serving on Council: R. J. Adamson, H. Britten, H. E. Cross, J. K. E. Douglas, R. C. J. Goode, Prof. D. D. Howat, Dr J. P. Hugo, D. M. Jamieson, D. G. Maxwell, Dr J. T. McIntyre, V. C. Robinson, P. W. J. van Rensburg. Seven Council meetings and five Executive Committee meetings were held during the year, and the standing and sub-committees held fifty-five meetings. Standing Committee Chairmen Membership, P. A. von Wielligh ; Technical Programme-Metallurgy, D. A. Viljoen; Technical Programme-Mining, D. G. Malan; Vacation School-Metallurgy, Dr P. R. Jochens ; Vacation School-Mining, H. M. Wells; Awards, Dr R. E. Robinson; Excursions, Dr D. I. Legge; Adjudicating, Dr R. E. Robinson; Constitution, Rules and Policy, Prof. R. P. Plowman; Mines and Works, C. T. Shaw; Education, Prof. R. P. Plewman; Foundry Colloquia, Prof. D. D. Howat. Representatives on Other Bodies Associated Scientific and Technical Societies: Members : Dr R. E. Robinson and Prof. R. P. Plewman. Alternates : P. A. von Wielligh and Dr M. D. G. Salamon. Federation of Societies of Professional Engineers: Members : J. K. E. Douglas and Prof. R. P. Plewman. Alternates: Dr R. E. Robinson and Dr M. D. G. Salamon. FSPE Technicians Committee: Member: D. M. Jamieson. FSPE Rationalziation Committee: Member: Dr M. D. G. Salamon. South African Council for Professional Engineers (Institute Nominees) Member : R. C. J. Goode. Alternate: G. H. Grange. South African National Committee on Tunnelling: Member : D. G. Malan. Alternate: Prof. R. P. Plewman. Engineers&apos; Liaison Committee (Pretoria) Member : Dr J. P. Hugo. Alternate : P. W. J. van Rensburg. Government Certificate of Competency Liaison Committee: Member: Prof. R. P. Plowman. Alternate: D. M. Jamieson. James Moir Memorial Lectures: Member : Prof. D. D. Howat. World Mining Congress-National Committee: Members : Dr M. D. G. Salamon, Prof. R. P. Plewman, and H. M. Wells. I.F.A.C. Symposium: Member: P. W. J. van Rensburg (Chairman-Organising Committee). Alternate : Dr J. P. Hugo. I. U.P.A.C. Symposium: Member: Dr P. R. Jochens. Membership Nine Fellows, twenty Members, six Associate Members, thirteen Graduates, nine Associates, twenty-nine Students, and ten Company Affiliates were elected during the year. One Fellow was elected to Honorary Life Fellowship, eight Members and one Graduate were transferred to Fellows, twelve Graduates and two Students were transferred to Members, three Students were transferred to Graduates, and one Student was transferred to the grade of Associate. Six Fellows, two Members, and two Associates were admitted to retired membership. Nine Fellows, fifteen Members, three Graduates, one Associate, two Students, and one Company Affiliate resigned. A statement of membership as at June 30th, 1976, and the end of the previous year is shown in the following tabulation. 30th June, - 30th June, 1975 1976 Honorary Life Fellows 16 - 17 Honorary Fellows 8 - 8 Life Fellows 171 - 171 Fellows 549 - 547 Members 523 - 517 Associate Members 15 - 21 Graduates 132 - 123 Associates 209 - 205 Students 173 - 179 Company Affiliates 71 - 80 1866 -1878 Obituaries Your Council records with deep regret the death during the year of the following members: P. A. Creewell, Life Fellow; A. S. Davis, J. S. Hay, P. 0. Lange, N.

Jan 10, 1976

Changes in reductant and energy inputs which are required to adjust the slag composition in anilmenite smelter to a higher or lower FeO content are calculated. The calculated changes are based on the assumption that solidification equilibrium with the freeze lining constrains the slag composition to follow a eutectic groove in the TiO2-FeO-TiO1.5phase diagram. Calculated equilibrium conditions along the eutectic groove are presented, and form the basis of the calculations. The inputs of energy and carbon need to deviate strongly from the steady-state values to adjust the slag composition. The inputs required at any given time depend on the desired rate of change of the slag composition, and the current slag composition. The steady-state relationship of a change in energy input of 5 kWh corresponding to a 1 kg change in carbon input does also hold for the changed inputs during transient changes in FeO content. Keywords: Ilmenite smelting, freeze lining, solidification, eutectic

Jan 1, 2003

By J. A. Bakken, T. Magnusson, G. Sævarsdottir

This paper describes measurements of current and voltage done on submerged arc furnaces. The aim is to focus on and attempt to separate from one another the electric arc current and the current bypassing the arc through the charge. Toward this goal two measurement campaigns on AC-arcs burning on coke beds are ac-counted for. The first was done on a 150 kVA pilot furnace at SINTEF in Trondheim Norway, and the second one was done on a 48 MVA industrial furnace run by Icelandic Alloys in Iceland. The measurements were compared to simulations employing an advanced MFD arc model. The main results are that a coke bed does not necessarily behave as a linear conductor. However the warmer chemically transformed part of an operating Si-metal or FeSi furnace probably exhibits linear behaviour and passes a considerable fraction of the phase current, perhaps on some operating conditions, as much as 50%.

Jan 1, 2007

By R. P. King

Held on the 22nd March 1972 at Kelvin House. Four papers were presented at this colloquium, which was attended by approximately 120 people. The first paper, &apos;Flotation Research Work at the N.I.M. research group, University of Natal on the modelling of a Flotation Process&apos; was presented by Dr R. P. King, the leader of the N.I.M. Research Group in the Department of Chemical Engineering at the University of Natal. A discussion panel, under the chairmanship of Dr R. E. Robinson with Mr M. Dawson (PMC), Mr E. Roux (FOSKOR), and Dr B. K. Loveday (NIM), discussed the potential application of the theoretical work on flotation modelling to industrial processes, and alternative approaches to providing a way of control of flotation plants. The second paper, &apos;Fundamental Studies of the Flotation Process the Work of the National Institute) for Metallurgy&apos;, was presented by Dr N. P. Finkelstein. The discussion panel for this paper was under the chairmanship of Professor D. D. Howat,and had as its members Mr H. P. Carlisle (JCI), Professor D. le Roux (University of Pretoria), and Mr E. Rudolph (Anglo American Research Laboratories). A lively discussion on this paper ensued, with several contributions from the floor. After lunch, Mr S. K. de Kok, Assistant Consulting Metallurgist, Anglo Vaal, presented a paper on &apos;The Flotation of Copper and Zinc Sulphide from Prieska Ore&apos;. The paper was discussed by a panel comprising Dr V. C. Lovell (NIM), Mr A. Gilbert (General Mining), and Dr D. Legge (Anglo Vaal), under the chairmanship of Dr L. Bushell. This discussion, in which many members of the audience participated, revolved around the difficulties associated with the production of copper and zinc concentrates and the lack of fundamental information on the behaviour of copper and zinc sulphides in flotation. The final presentati0n was a paper, &apos;The Recovery by Flotation of Cassiterite contained in Gravity Concentration Plant Tailings&apos;, presented by Mr E. B. Viljoen (Metallurgy Department, Goldfields South Africa Limited). The discussion, led by a panel consisting of Mr O. Tant (Goldfields Laboratories), Mr J. Levin (NIM), and Mr R. I. Shanks (NIM), under the chairmanship of Mr H. Cross (Goldfields South Africa Limited) referred particularly to the use of new reagents for the flotation of tin, with particular emphasis on the fundamental relationship between reagent composition and its ability to float this type of mineral.

Jan 4, 1972

The June General Meeting of the Institute was held in Kelvin House, Johannesburg, on 18th June, 1969, at 4.30 p.m. Mr J. K. E. Douglas (Vice-President) was in the Chair. There were also present fourteen Members, Messrs R. J. Adamson, F. P. Bath, D. M. Jamieson, D. G. Maxwell, Dr J. T. McIntyre, and Mr P. W. J. van Rensburg (Council Members), Messrs B. F. Berry, A. F. Lee, J. E. van Leeuwen, G. G. Nicolson, N. F. Peverett, Dr A. G. Raper, Messrs E. R. Rudolph and H. R. Reid. Five Associate Members, Messrs T. D. Brown, M. R. Fuller-Good, J. S. Freer, Dr P. R. Jochens and Mr D. A. Viljoen. One Graduate, Mr P. G. Mrkusic. Five Students, Messrs N. A. Barcza, J. A. Cruise, R. P. W. Henrard, D. I. Ossin and J. C. M. Wethmar. Nine Visitors, Messrs M. Badenhorst, N. J. Bovey, H. H. Herold, Dr H. J. S. Kriek, Messrs M. S. Rennie, B. B. Segal, S. Selmer-Olsen, O. A. W. Strydom and B. Yates. Secretary, Mr D. C. Visser. Total present: Thirty-six. MINUTES The Vice-President: "May we confirm the minutes of the Monthly General Meetings held on 24th March, 16th April and 21st May, 1969 as published in the Journal?" Agreed. MEMBERSHIP The Vice-President: "I have much pleasure in announcing that the names of the undermentioned candidates having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following grades: Members: Wilfred Desmond Morgan, Abraham Kriek. Associate Members: Rodger Neville Hampson, Robert Richard Booth Lodge. Graduates: Beverley Hugh Waiters, Gwynne Hugh Johnston. Students: Colin Edward Alvery, Peter Marthinus Haikes, Charles Aubrey Husband, John Nowell Randell, Frederick Johannes Jacobus Blaauw, Johannes Andries Breytenbach, Peter Vos, Frederik Hendrik Coetzee, Petrus Nicolaas Jacobus Smit, Patrick Alien Boardman, Robert Nelson Guest. "May I welcome the newly elected members to the Institute." (Applause.) ELECTION OF SCRUTINEERS FOR THE 1969-70 BALLOT FOR COUNCIL The Vice-President: "In terms of By-Law 9.4, I now call for nominations for scrutineers for the 1969-70 ballot for CounciL" P. W. J. van Rensborg: "I wish to nominate Messrs R. C. J. Goode, V. C. Robinson, J. K. E. Douglas, P. Lambooy, D. G. Maxwell, H. Britten and H. Simon as scrutineers."

By M. F. Dawson, S. B. Davis

SYNOPSIS This paper describes the size reduction of limestone smaller than 1 mm by attrition grinding, using quartz (1 to 3 mm) as the grinding medium in a laboratory rig. The ore and grinding medium were closely sized fractions, and the particle size of the grinding medium was at least three sizes larger than that of the ore. Batch tests showed that the size reduction of the feed followed two first-order rate processes: one for an apparently fast-breaking ore fraction, and a slower one for most of the ore (86 per cent). The production of fines (material smaller than 10 µm) followed a zero-order rate equation. Continuous runs showed that the process could be modelled as a perfectly mixed system provided that the discharge screen did not selectively retain coarser particles of ore. The ratio of medium to ore (both by mass and by volume) was found to have a significant effect, the most energy¬efficient grinding occurring at ratios between 1 and 2. The solids content of the slurry also had a significant effect, the greatest efficiency being obtained at 50 to 65 per cent solids (by mass). Within these energy-efficient ranges of medium-to-ore and solids content, the lower values resulted in maximum feed breakage and the higher values in maximum fines production. The most important factor in the breakage of feed was the difference in the particle size of the grinding medium and the ore; the amount of ore broken out of the feed size for a given energy input was found to increase linearly with the difference between the size of the grinding medium and that of the ore up to 2 mm. The production of fines increased similarly, but only up to a difference of about 1,2 mm, when it levelled off at about 5 kg/kW ? h. The mechanism proposed for attritioning is mainly the abrasion of 1 µm planes of limestone along the crystal axes, with some fracturing along existing lines of weakness. The energy consumption of nearly 200 kW ? h per ton of product smaller than 10 µm appears to be higher than that in other types of milling. It is concluded that the value of attrition milling lies in its selectivity; in this work, only the softer limestone and virtually none of the hard quartz grinding medium was comminuted.

Jan 1, 1989

By J. L. Havenga

South Africa produces about 400 Kt zircon (ZrSiO4) per annum. This represents about 30 percent of the global demand. However, very little is beneficiated locally and more than 95 percent is exported with little or no value addition. Zircon is a very inert material and needs to undergo high-temperature alkaline melting processes to produce valuable zirconium products. The conversion of zircon to plasma-dissociated zircon (PDZ) produces a chemically reactive species (ZrO2.SiO2) which consist of finely divided submicron monoclinic ZrO2 crystals dispersed in a SiO2 matrix. In this paper, an in-flight, non-transferred arc pilot plasma plant with a capacity of 100 kg/h and which consists of three 150 kW DC plasma torches, is described. The optimization of the plant, which includes the use of different zircon concentrates, the influence of particle size, feed rates, plasma gas, and energy utilization, is discussed.

Jan 1, 2012

By J. L. Havenga

South Africa produces about 400 Kt zircon (ZrSiO4) per annum. This represents about 30 percent of the global demand. However, very little is beneficiated locally and more than 95 percent is exported with little or no value addition. Zircon is a very inert material and needs to undergo high-temperature alkaline melting processes to produce valuable zirconium products. The conversion of zircon to plasma-dissociated zircon (PDZ) produces a chemically reactive species (ZrO2.SiO2) which consist of finely divided submicron monoclinic ZrO2 crystals dispersed in a SiO2 matrix. In this paper, an in-flight, non-transferred arc pilot plasma plant with a capacity of 100 kg/h and which consists of three 150 kW DC plasma torches, is described. The optimization of the plant, which includes the use of different zircon concentrates, the influence of particle size, feed rates, plasma gas, and energy utilization, is discussed.

Jan 1, 2012

Changes in reductant and energy inputs which are required to adjust the slag composition in an ilmenite smelter to a higher or lower FeO content are calculated. The calculated changes are based on the assumption that solidification equilibrium with the freeze lining constrains the slag composition to follow a eutectic groove in the TiO2-FeO-TiO1.5phase diagram. Calculated equilibrium conditions along the eutectic groove are presented, and form the basis of the calculations. The inputs of energy and carbon need to deviate strongly from the steady-state values to adjust the slag composition. The inputs required at any given time depend on the desired rate of change of the slag composition, and the current slag composition. The steady-state relationship of a change in energy input of 5 kWh corresponding to a 1 kg change in carbon input also holds for the changed inputs during transient changes in FeO content. Keywords: Ilmenite smelting, freeze lining, solidification, eutectic

Jan 1, 2003

By M. Abdellatif

The production of a 40% Al-Ti alloy was successfully proven at the lab scale, using pure TiO2, aluminium, and lime. These tests were conducted in an induction furnace maintained at 1600?16250C. The introduction of rutile into the feed recipe resulted in an alloy containing between 0.35 and 1.10% Zr, depending on rutile to TiO2 ratio. DC arc production of the alloy was largely accomplished at 40 and then 200kW scale. These tests evaluated various metallurgical and operational factors including target slag composition, Ti-content in the alloy, co-feeding versus sequential, furnace bath depth, and rutile as part of the Ti containing feedstock. Overall, an alloy containing 24?33% Ti was consistently produced with co-feeding of the reactants and with lower taphole tapping. When rutile was added, the zirconium analysis in the alloy remained below 0.2%. The main impurity elements were iron, silicon, carbon, nitrogen, and oxygen.

Jan 1, 2009