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By Stephen D. Hill

The Bureau of Mines devised and constructed a modified Knudsen effusion apparatus, permitting a constant measure of the weight of effusing vapor, to determine the equilibrium vapor pressure of metal halides at temperatures up to 1,200° K and over the pressure range 10-5 to 10-2 torr. The reliability of the apparatus was established by determining the vapor pressure of potassium chloride. After correcting for partial dimerization of the vapor, data obtained on solid KCl between 750° and 950° K can be expressed by the following equation:

Jan 1, 1966

By William J. Campbell

The possibility of chemical analysis by identification of characteristic X-ray spectral lines was first suggested by H. C. J. Moseley in 1913.3/ For a given spectral series it was found that the frequency of the characteristic radiation was proportional to the square of the atomic number of the excited atom. Siegbahn and his coworkers improved the instrumentation and accurately determined the wavelengths of the characteristic spectra for most of the elements .4/ In fluorescent X-ray spectroscopy, the characteristic X-rays of atoms are emitted or fluoresced upon absorption of primary or incident X-rays of shorter wave-lengths (higher energies). The K spectral lines are used for elements of atomic numbers 13 to about 63, and the L series for those above atomic number 50. Whether the K or L lines are used for elements 50-63 depends upon the type of instrumentation available. The laboratory at the Eastern Experiment Station of the Bureau of Mines, College Park, Md., uses the K lines up to atomic number 57 and the L lines for thong elements of higher atomic number.

Jan 1, 1955

By C. L. Karr

The U.S. Bureau of Mines is optimizing the design of an air-sparged hydrocyclone. This report summarizes the initial stage of the project-the prediction of collision efficiencies for use in a comprehensive air-sparged hydrocyclone model. The equations of motion are presented in nondimensional form and solved numerically for a small spherical particle passing around a larger bubble in an infinite fluid under the influence of a strong force field. Collision efficiencies are determined from the calculated particle trajectories for values of Stokes' number, K, between 0.01 and 100 and for values of the nondimensional force, W, between 0.0 and 100. These large values of K and Ware needed to model high-performance flotation devices like the air-sparged hydrocyclone; solutions for the required K and W values have not appeared in the literature prior to this study. Effects of changes in particle-to-bubble radius ratio are considered for both viscous and potential flows. The results help predict the improved recovery of fine particles when flotation is performed in a strong force field.

Jan 1, 1990

By James R. Welty

Heat content values were experimentally determined for yttrium metal between temperatures of 400° and 1,300° K and for iron pentacarbonyl between 301° and 380° K. The drop technique was used; that is, a sample of material sealed in a protective capsule was heated to 3 desired temperature in a furnace and then dropped into an ice calorimeter. A revised technique for determining heat content values from calorimetric data is described. Heat content and corresponding entropy-increment data above a reference temperature of 298.15° K are presented in tabular form. Equations for heat content and heat capacity as functions of temperature were derived for each substance. These equations are [Y (c): HT-H298.15 = 1.2041T 1 3.393 x 10-3T2- 0.4176 x 10' T"1 + 739.9 cal/mole Cp = 1.2041 + 6.786 x 10-3T + 0.4176 x 106-T-2 cal/deg mole Fe (CO) E, (1) : HT - H298.15 = 55.636T - 16,588 cal/mole Cp = 55.636 cal/deg mole]

Jan 1, 1963

By E. A. Loria

The Bureau of Mines analyzed the effects of oxygen, nitrogen, and carbon on the tensile properties of electrorefined vanadium in terms of the Petch equation. The effects of the different impurities and grain sizes on the yield and flow stress between 2730 and 770 K were studied. For specimens of like composition, the values of the Petch parameters 01 and ky obtained by two different methods, extrapolation and grain size, were nearly the same. For high-purity electrorefined vanadium, the 01 value at 2730 K was 10,300 psi (5,150 psi shear). The 01 values for this metal at 1950 and 2730 K were lower by factors of 3 to 4 than for three less pure samples of commercial vanadium metal of equivalent grain size. Nitrogen was more effective than oxygen in increasing 01' the increase being about twice as much for the same impurity level. Carbon produced a slight increase in 01 up to 0.024 percent and then a gradual decrease in 01 to 0.11 percent, the maximum carbon content studied. The corresponding ky values followed the same trend in regard to oxygen and nitrogen additions, whereas the addition of carbon produced no variations at either temperature. Dislocations in vanadium are anchored by carbon, oxygen, and nitrogen with increasing firmness in that order. The high purity of electrorefined vanadium was confirmed by low yield stress and high ductility throughout the low temperature range. The metal also exhibited profuse twinning with high ductility at 1230 and 770 K. The effective surface energy for fracture, y, was found to lie between 3.3 and 3.6 x 1()4 erg cm-2?

Jan 1, 1966

By Michael J. Sapko, Eric S. Weiss, Kenneth L. Cashdollar

A fundamental safety research area for the National Institute for Occupational Safety and Health (NIOSH) is to eliminate the occurrence of coal mine explosions or to mitigate their effects. One approach is to develop and evaluate new and innovative seal designs that provide increased explosion protection for mining personnel. The NIOSH Pittsburgh Research Laboratory (PRL) cooperated with HeiTech Corp. of Virginia, Barclay Mowlem Construction Ltd. of Queensland, Australia, and the Mine Safety and Health Administration (MSHA) in three separate research programs to evaluate the strength characteristics and air leakage resistance of numerous innovative seal designs and ventilation control structures for use in underground coal mines. For each phase of the program, various full-scale seals, stoppings, and an overcast design were constructed in PRL's Lake Lynn Experimental Mine near Fairchance, Fayette County, PA. The seals and stoppings were built in crosscuts and were subjected to explosions to evaluate their strengths. Four pumpable cementitious seal designs ranging in thickness from 610 to 915 mm (24 to 36 in) were evaluated in the first cost-reimbursable research program with HeiTech Corp. A simple wooden framework with brattice liner was used as a form to contain the cementitious slurry during the curing period. As the seal designs decreased in thickness, higher compressive strength cementitious grout was used. All four seals withstood an explosion pressure pulse of at least 138 kPa (20 psi) while maintaining acceptable air leakage resistance. In the second cost-reimbursable research program with Barclay Mowlem Construction Ltd. of Australia, several innovative seal and stopping designs and an overcast design were evaluated. Each of the seal designs and the overcast side and wing walls used one or more air-inflated vinyl bladder assemblies anchored to the mine roof and hitched into the ribs and floor. The air within these bladders was displaced with a high-strength cementitious grout. The overcast deck consisted of a 200-mm ('7.8-in) thick reinforced cementitious slab. This was the first time that an overcast structure had been explosion tested under full-scale conditions. All of the seals, stoppings, and overcast design passed the air leakage tests before being subjected to a series of explosions with static pressure pulses ranging from 14 to 475 kPa (2 tab 69 psi). Instrumentation measured seal and overcast wall displacement as a function of time. The 450-mm (1 7.7-in) thick seal in the 2.8-m(9-ft) high third crosscut withstood an explosion pressure of 170 kPa (25 psi), but failed during a later test, which generated a peak static pressure of 475 kPa (69 psi) at the seal location. A similar 450-mm-thick seal in the 2.1-m (7-ft) high second crosscut withstood three explosion tests, which generated peak static pressures of 195, 205, and 370 kPa (28, 30, and 54 psi) at the seal location. Next, the overcast design withstood four explosions, which generated static overpressures ranging from 16 to 47 kPa (2.3 to 6.8 psi). A third program at the request of MSHA evaluated the effectiveness of using pressurized grout bags (Packsetter bags) along the mine roof and ribs in lieu of floor and rib hitching for a standard-type solid- concrete-block seal. This program was initiated to address an urlusual geological mining condition encountered when building seals in entries where required rib hitching is not a viable option due to soft friable coal. Results showed that the use of these quick-setting grout-filled Packsetter bags pressurized internally to 300 kPa (44 psi) not only provides a seal that can withstand a 138-kPa static pressure explosion, but also provides a sealing option where rib hitching is not possible.

Jan 1, 2003

By Wilbur I. Duvall

Nineteen quarry blasts were instrumented with particle-velocity gages mounted in a uniform soil overburden, back of one face in a quarry in Iowa. Three components of particle velocity, radial, vertical, and transverse, were recorded at each of eight stations back of each blast. Distances from blast area to gage stations ranged from 150 to 3,000 feet. Eleven of the quarry blasts employed millisecond delays, and eight were instantaneous blasts. Charge weight per hole was 200 pounds, and the charge weight per delay interval, including the instantaneous blasts, ranged from 100 to 3,000 pounds. Analysis of the data from these tests shows that the particle velocity, V, produced at distance, D, by a quarry blast of charge per delay interval, W, can be represented by an equation of the form, V=KWb D-n, where b and n are exponents, and K is the intercept constant which is a measure of the level of vibration. The value of K for a millisecond-delayed blast employing one hole per delay interval is about 42 percent larger than the value of K for a single-hole blast. The value of K for a multiple-hole milli-second-delayed blast is about the same as that for an instantaneous blast when the charge per delay for the millisecond blast is equal to the total charge for the instanteneous blast. The vibration level from millisecond-delayed blasts employing one hole per delay is shown to be independent of the length of the delay interval and the number of delay intervals over the range of the variables tested: 9, 17, and 34 milliseconds and 3, 7, and 15 delays per blast.

Jan 1, 1963

By K. O. Bennington

[Thermodynamic properties of two amphibole asbestos minerals were determined by the Bureau of Mines. The enthalpies of formation were determined by the hydrofluoric acid solution calorimetry method. Heat capacity measurements were made with an adiabatic calorimeter over the range of 5 to 315 K. High-temperature enthalpies above 298 K were determined with a copper-block drop calorimeter to 852 K for amosite and to 902 K for crocidolite. Thermodynamic data determined for amosite of the composition Fe5+2.2766Mg1.5209 Fe+03.12Mn0.0825) Si7.9163Al0.0837022.0363)(OH)1.9637 are: S°298 = 168.8 ± 5 cal/deg-mole; ?Hf°298-15 (elements) = -2419.24 ± 2.95 kcal/mole; ?Hf298.15 (oxides) = -30.92 ± 2.47 kcal/mole; and ?Gf° -2260.1 kcal. Corresponding data found for s3 ,1s = crocidolite of the composition (Na1.9Ca0.1)(Fe2+.024Fe2.5 01Mg0.475) (Si7.9713024Fe+2 2.501Mg0.475) (Si7.971 Al0.029022.095) (OH)1.905 are: S2.98-15 - 161.1 ± 4 cal/deg-mole; ?Rf° 2 298.15 (elements) = -2433.56 ± 2.99 kcal/mole, 10298.1s (oxides) = -87.69 1.70 kcal/mole, and ?Gf°298.15 = -2269.8 kcal.] Calorimetric values from this investigation were combined with other data from the literature to calculate the Gibbs energies of formation and equilibrium constants of formation over the temperature range of the measurements. Tables of enthalpies of formation and Gibbs energies of formation are given as a function of temperature both from the elements and the constituent oxides.

Jan 1, 1978

By Mark Davis

As a follow-on to previous investigations, reduced treatment levels for the optimum fire retardant/preservative system were evaluated. An impregnation of 3.5 lbs/ft3 of Fyreprufe followed by 3.5 mils of Albi 107A plus an Albi 144 top coat provides adequate flammability and flame spread protection. However, there is a significant loss in compressive strength at this retention level, particularly parallel to the grain. A pilot-size pressure impregnation cell was installed for use in treating larger quantities of wood. Based on the optimum fire retardant/preservative treatment system - Fyreprufe/ACC impregnation followed by Albi 107A/144 intumescent paint - a model treatment pro¬cess was developed, capable of handling 3 million board feet per year. Associated annualized costs per thousand board feet (K bd. ft.) for treating 12" x 12" timber were calculated to be: Impregnation: $-63.00/K bd. ft. Coating: $112.00/K bd. ft. A literature search was conducted to identify materials and techniques suitable for a localized stench warning system for heated mine timbers. Based on this review, a number of stench warning concepts were developed. Those based on surface coating were given a preliminary laboratory evaluation.

Jan 1, 1982

By Philip Thompson

A part of the Bureau of Mines mission is to help improve the Nation's mineral posture by providing the technology for utilizing low-grade ores. In this regard, laboratory testing by the Bureau of Mines has shown that the removal of insoluble slimes using selective flocculation and flotation is a viable method for treating low-grade potash ores that have a high content of water-insoluble impurities. Results indicated that over 82 percent of the insoluble slimes could be removed from sylvinite ore containing 5 percent water insolubles and 13 percent K20 by using nonionic or cationic polyacrylamide flocculants and cationic, anionic, and/or nonionic collectors. Subsequent potash flotation recovered 87 percent of the potash in rougher concentrates containing 57 percent K2O. Sizing and cleaner flotation of the rougher concentrates upgraded the products to 60 percent K2O. Filtration of the water-leached insoluble-slimes flotation concentrates on a bed consisting of leached insoluble-slimes concentrate mixed with potash flotation tailings recovered 80 percent of the brine. Filtration rates using the mixed bed were nine times faster than filtration rates obtained when the insoluble-slimes flotation concentrates were filtered separately.

Jan 1, 1979

By J. I. Paige

As part of a continuing effort to develop technology that maximizes mineral and metal recovery from domestic resources, the Bureau of Mines investigated a method to totally utilize copper converter slags without recycling them back through the matte smelting furnace. The research was directed toward (1) recovering the contained copper in converting slags by producing a recyclable copper-iron matte, (2) carbothermically reducing the slags to recover the iron, and (3) producing slag wool from the depleted slags. This report deals with the reduction of three industrial converting slags, containing 2.0 to 7.3 wt-pct Cu, in an 800-kVA electric arc furnace to produce a recyclable copper-iron matte. The addition of sufficient iron pyrite to provide 29 to 113 pct of the stoichiometric sulfur (based on producing 40-pct-Cu matte) produced a recyclable matte (36 to 61 pct Cu) at an energy consumption of 520 to 700 kWh per ton of solid material charged. The expected energy saving for treating molten slag in an electric furnace (5-to 9-MVA range) is about 400 kWh per ton of molten slag treated.

Jan 1, 1982

By E. G. King

Low-temperature heat capacity determinations of the minerals goethite and pyrophyllite were made in the temperature range from 510 to 298° K. The entropies at 298.15° K were evaluated as 14.43 ±0.15 cal/deg mole for goethite and 56.6 ±0.5 cal/deg mole for pyrophyllite. The entropies of formation from the constituent oxides are -4.4 ±0.2 cal/deg mole for goethite and -12.3 ±0.6 cal/deg mole for pyrophyllite. The standard free energy of formation of goethite from its oxides is ?G°298.15 = 0.16 ±0.20 kcal/mole.

Jan 1, 1970

By A. R. Taylor

Using solution calorimetry, the following heats of reaction were determined: (1) NaCN(c) + 1/Cu20(c) + 129H20(l) ? CuCN(c) + NaOH?128.5H2O ?H = -13.44±0.10 kcal/mole, (2) HCN(2) + NaOH?128.5H20 ? NaCN(c) + 129.5H20(l) ? = -2.52±0.02 kcal/mole. From these reactions, the heats of formation for CuCN(c) and HCN(2) were calculated to be 22.7±0.4 kcal/mole and 24.9±0.4 kcal/mole, respectively. Reaction 2 was made to check the consistency of literature values for heats of formation of HCN and NaCN. Adiabatic calorimetric measurements between 10° and 400° K showed the entropy and heat capacity of CuCN(c) to be 21.51±0.06 eu and 14.58±0.04 cal/mole deg, respectively, at 298° K. A broad anomaly in the heat capacity was found in the temperature range 285°-320° K. The heat of transition associated with this anomaly was less than 1 cal/mole, the sensitivity of the measurements.

Jan 1, 1971

By R. K. Koch

The vapor pressures of liquid columbium and liquid hafnium were deter-mined by the Langmuir free evaporation method as a part of the Bureau of Mines program on the study of transition metals. An electron-beam furnace with a water-cooled copper crucible was used for melting. Temperature was measured with a two-color ratio pyrometer. Least-squares analyses of the vapor pres-sure data gave the following equations: [Logp (atm) = 5 .429 -31,310 T] for liquid columbium in the range 2,740° - 3,140° K, and [Log p (atm) = 5,690 28 T] for liquid zirconium in the range 2,500° -2,810° K. Third-law evaluations of each data set gave mean heats of sublimation (298.15° K) of 175.1±3.2 kcal/mole and 148.3±1.2 kcal/mole for columbium and hafnium, respectively. Second-law standard heats of sublimation determined from sigma plots and from sigma-prime plots agreed fairly well with the third-law values. The sigma-prime plots gave standard entropies of sublimation of 30.96±0.84 eu and 33.S6±0.44 eu for columbium and hafnium, respectively.

Jan 1, 1968

By J. W. Walkiewicz

One of the objectives of the Bureau of Mines is to develop substitution technology for scarce materials. In accordance with this goal, alloys containing lanthanum, cobalt, copper, and magnesium were investigated for fabrication of rare-earth-cobalt (RE-Co) permanent magnets. A complete substitution of lanthanum for samarium and a partial substitution of copper for cobalt was accomplished. Magnets of La-Co and La-Co-Cu-Mg alloys were fabricated by powder metallurgy techniques and evaluated. A maximum intrinsic coercivity of 23.2 kOe was obtained with a La-Co-Cu-Mg alloy. In comparison, maximum values of 9.3 kOe and 11.6 kOe were obtained with La-Co and La-Co-Cu alloys, respectively. The substitution of copper and magnesium for part of the cobalt resulted in a large increase of intrinsic coercivity, similar to the results of Bureau research with mischmetal-Co-Cu-Mg alloys. Unlike the mischmetal-Co-Cu-Mg magnets, the La-Co-Cu-Mg magnets showed signs of physical deterioration on exposure to air. The effects of fabrication parameters on the magnetic properties of the La-Co-Cu-Mg alloys were also determined.

Jan 1, 1982

By D. J. MacDonald

This U.S. Bureau of Mines report reviews published information on synthetic berlinite (AlP04) and suggests experimental conditions requisite for its production. Berlinite is a piezoelectric material with potential use as a substitute for quartz in the crystal oscillators, which are components of electronic and electroacoustic equipment. Information gathered here (mostly from published sources) includes historical background, physical properties, end-use applications, criteria of quality, and physio-chemical factors involved in berlinite crystal growth. It is concluded that growing large high-quality berlinite crystal would require high-purity starting materials in an autoclave equipped with a noncorrodible liner and operated with temperature control of ±O.OO5 ac over a range of 250 to 350 ac.

Jan 1, 1995

By Richard H. Singleton

Native asphalt was produced in 1980 by six companies in four States. Leading States were Texas and Utah. Output decreased 22% in 1980 to 1.25 million tons while value decreased 2% to $25.0 million. Bituminous limestone was produced by Whites Uvalde Mines and by Uvalde Rock Asphalt Co. in Uvalde County, Tex.; by Southern Stone Co. in Colbert, Ala.; and by Barton County Rock Asphalt Co. in Barton County, Mo. The product was used mainly in street and road repair. Gilsonite was produced by American Gilsonite Co. in Uinta County, Utah, and by Ziegler Chemical and Mineral Corp. in Weber County, Utah. This material was used for purposes other than road repair.

Jan 1, 1981

By William J. Campbell

This Bureau of Mines report describes a study conducted to determine the relationship of mineral habit to particle size and shape characteristics for prismatic, acicular, fibrous, and asbestiform varieties of tremolite. Particle measurements were made with the petrographic microscope at X 1,250 and the scanning electron microscope at magnifications up to X 10,000. All of the varieties of tremolite, upon Wiley milling, produced a significant percentage of particles that meet the Federal regulatory criteria for counting as asbestos fibers. However, only the asbestiform variety gave milled particles that fell into a size range of >10 µm in length and <0.5 µm in width; some medical scientists consider this range significant for production of adverse health effects.

Jan 1, 1979

By G. H. Keith

Electrowon tungsten powders were investigated with respect to consolidation, fabrication, and mechanical properties. Sheet, 0.03 inch thick, was produced and its tensile strength measured between 250° and 1,935° C. The large particle size of electrowon tungsten effectively precluded sintering to a density sufficient to allow hot working to sheet or bar. The powders were consolidated by die pressing to 70-percent density, sheathing in molybdenum, and high-energy-rate extruding to either round or sheet bar of 100-percent density. The material was then rolled conventionally to sheet. The mechanical properties of the sheet prepared from the electrowon powders compared favorably with those reported in the literature for sheet prepared from commercially produced hydrogen-reduced powder.

Jan 1, 1970

By Alla D. Mah

Heat content and entropy data at high temperatures were obtained for cuprous oxide (Cu2O) and cupric oxide (CuO). Experimental results and smooth values are reported. Equations are given for heat content increments and heat capacities above 2980 K. Low-temperature heat capacity data were obtained for cuprous oxide. Evaluation of the 2980 K entropy gave, S°298.15(Cu2O) = 22.08 ± 0.10 cal/deg mole. Heat of formation values were determined for cuprous and cupric oxides. The values are: AH°298.15(Cu2O) = -40,830 ± 300 cal/mole, and AH°298.15(CuO) = -37,230 ± 150 cal/mole.

Jan 1, 1967