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By E. J. HOFFMAN, J. c. W. FRAZER

The apparatus and methods described in the following pages were devised and used by the writers in connection with certain investiga- tions of the technologic branch of the United States Geological Sur- vey, especially those bearing on the improvement of furnace condi- tions and on efficiency in the use of fuel. The Bureau of Mines, which has charge of such analyses and tests of fuels as were formerly made by the technologic branch of the Sur- vey, is using the same apparatus and methods in connection with similar investigations that are being carried on at the testing plant of the bureau at Pittsburg, Pa. The furnace conditions prevailing both in small plants and in large industrial establishments in this country are frequently far from satisfactory. If such conditions are to be improved, they must be more thoroughly understood, and means must be found to insure complete combustion of the fuel, and yet to permit operation with such an excess of air as will result in the greatest efficiency. In this work the services of the chemist are indispensable. A very important problem is the determination of the small percentage of unburned combustible matter that escapes from the furnace in the flue gases. Under ordinary circumstances so little as 0.1 per cent of unburned combustible matter in a furnace gas is equivalent to about 1 per cent of the fuel used; and for the determination of such small percentages of gas more accurate and refined methods are required than have ordinarily been available heretofore. It is the purpose of this paper to describe some apparatus and methods which have proved satisfactory to those engaged in the chemical work of the investigations mentioned. While these methods and apparatus have been designed more particularly with regard to analysis of furnace gases, their use is by no means limited to that purpose. The reader will readily see their applicability to other uses in which the sampling and analysis of gases are involved.

Jan 1, 1911

By R. H. Nafziger

The Bureau of Mines evaluated 18 domestic titaniferous materials with widely varying compositions, mineralogy, and physical properties in electric-arc furnaces, Techniques were devised to recover both the titanium and iron values contained in these materials so that the reliance of the United States on foreign sources of higher grade ilmenites and rutile might be decreased. Most of the tested titaniferous materials responded well to lower grade or byproduct reductants, such as bituminous coals, charcoal, and coke breeze. Sufficient slag fluidity was realized by maintaining from 8 to 12 wt-pct iron in the slags; no contaminating fluidizers were required. Fluid slags containing up to 79, 70, and 54 wt-pct Ti02 were realized from east coast ilmenites, a rock ilmenite, and a titaniferous magnetite ore, respectively. A carbon-lined furnace shell is recommended for minimum slag contamination. Good results also were obtained during extended submerged-arc furnace tests.

Jan 1, 1980

By R. R. Schehl

The Bureau of Mines analyzed the structure of a high-grade metallurgical coke, carbonized at different temperatures in the range 500° to 1,000° C, through X-ray diffraction studies. Growth in the crystallite size with increasing coking temperature was calculated from profile analysis and compared with values obtained from the radial distribution function. The carbonization temperature appeared to have little influence upon the stack height, whereas the layer diameters more than doubled in size between 500° and 1,000° C. These results are comparable to those obtained from other studies of poorer quality cokes.

Jan 1, 1974

By R. W. Stahl

Gas accumulation and dust suspension are the major safety hazards in coal stockpiling and reclaiming operations. This report presents a schedule of safety precautions and plant design features devised by the Bureau of Mines to reduce danger from these and other sources.

Jan 1, 1965

By F. Garcia, J. Cervik

Recent advances in the commercial separation of gases using membranes have renewed interest in the possibility of applying this technology to the recovery of methane ( CH4 ) from mining operations . This Bureau of Mines report briefly reviews the history of the development of membranes for gas separation , the theory of how they work , and their application to the separation of methane from air and associated problems . However , methane -air mixtures are difficult to separate with membranes because the pertinent gas couples , 02 - N2 , 02 - CH4 , and N2 -CH4 , have poor separation characteristics , as indicated by their separation factors of about 3 or less . Even if these separation factors were substantially higher , there is doubt that methane could be recovered economically from the low concentrations in mine ventilation exhaust ( 2 vol pct or less ) . The exhaust pressures are not sufficient for adequate separation . The power cost of compressing the methane recovered . these mixtures would far exceed the value of New discoveries could make separation of gob hole methane - air mixtures practical . These mixtures have much higher concentrations of methane (from 30 to 100 vol pct ) ; however , for safety reasons , be limited to gob gas with 60 vol pct CH4 or more .

Jan 1, 1988

By J. D. Kalasky, Stephen Krickovic

A degasification experiment was conducted in a Pocahontas No. 3 coalbed mine in Virginia. It involved (1) drilling holes in the coalbed in the out- side headings of a set of five being developed in virgin area, and (2) conducting a methane emission rate study as mining progressed and additional holes were drilled. Degasification from all drill holes except the longest in each of the outside headings and the first three drilled (excluding the in-situ pressure hole), was erratic and inconsequential in methane emission rates. The two longest holes liberated 66 and 79 cfm of methane, which is significant for the coalbed, but such quantity lasted a relatively short time; the first three were uniform but low in methane emission.

Jan 1, 1972

By W. H. Oppelt

To provide a relatively structurally stable form of dried lump lignite, two North Dakota lignites from Mercer County were dried by the Fleissner process in an atmosphere of saturated steam at 200, 300, and 370 p.s.i.a. pressure, corresponding to steam temperatures of 382°, 417°, and 437° F., respectively. Two series of experiments were made at each test pressure with the individual lignites. In one series, the autoclave was preheated to the processing temperature before charging the lignite; in the other the lignite was charged into the autoclave at room temperature. In each case, heat losses were determined by blank tests of steam consumption over a similar operating cycle with the empty autoclave. The degree of moisture removal and net steam consumption were calculated from material balances. The amount of water removed as a liquid from the two North Dakota lignites during the heating and steaming periods was compared with results calculated from previously published data on drying Austrian lignite and Australian brown coal. These lignites, covering a wide geographical area, had original moisture contents ranging from 35 to 49 percent. The Austrian lignite and Australian brown coal are considered to be of Miocene Age, and the Dakota lignites belong to the Paleocene.

Jan 1, 1955

By M. M. Fine

The flotation work on samples from nine fluorspar properties in Crittenden and Livingston Counties, Ky., reported herewith was part of a wartime project that resulted in increasing the supply of metallurgical-grade fluorspar. The samples were tailings, dumps, and waste rock that had been rejected in previous milling operations. All were treated successfully by flotation to yield metallurgical-grade concentrates with recoveries ranging from 77.5 to 98.3 percent of the fluorite. After the laboratory testing, the results of which were available to the owners and operators of the properties, many of the tailing ponds and rock dumps were milled. The real value of this report, therefore, is to show the operators of gravity concentration plants the possibilities of re-treating waste products by flotation either at some future time or currently with the gravity

Jan 1, 1948

The question of earth models has repeatedly arisen in our work. An accurate representation of the seismic properties is required for three reasons: 1.To be able to determine from a set of received arrival times, the location of a seismic source in the earth, and secondly the degree of accuracy required in the model used for calculating source location from the set of arrival time differences. 2. To be able to determine the expected arrival times at an array of geophones produced in response to a hypothetical source in the earth. 3. To be able to estimate received signal strengths more accurately. The work reported here on earth models is based on information from sever- al consultants and from others who expressed an interest in the problem and supplied information to us. II. COAL MINE GEOLOGY On one of our earlier assignments for the Bureau of Mines, Earth Science Research Inc. of Cambridge, Massachusetts prepared for us a short description of the lithology to be expected at coal mine sites. This description follows, together with the ranges of compressional seismic velocities (Figure I*) associated with typical materials comprising the layered structure of a coal mine area. Coal is primarily associated with fresh water sediments including sandstones, shales, and clays, and occasionally may be metamorphased to varying degrees. In the Appalachian Basin the coal beds occur within cyclical sequences of non-marine shales, sands tones, conglomerates, limes tones, and clays. The beds range in thickness from a few inches to 60 feet, averaging between 2 feet and 10 feet. They have generally broad areal extent, occasionally up to 5,000 square miles, and have an overall tabular or lens-like shape. Within a particular lens, local changes in thickness are normal.

Jan 1, 1974

By L. L. Hirst

Liquid fuel oils possess certain advantages over solid fuels. Ease in handling, precision temperature control, and almost complete freedom from ash are among those considered when a liquid fuel is selected for use in industrial processing. In some instances these fuels are desirable because more heating units can e packed in a Given space where space is limited, as on snips. In other cases the' are chosen because of lower actual cost per British thermal unit absorbed, or for control of the flame to increase the capacity of furnaces, as in steel and refining.

Jan 1, 1948

By R. R. Sayers

The increasing use of hydrogen fluoride (annual consumption now exceeds 500,000 pounds (1)4/) directly and its occurrence as a byproduct of the utilization of fluorine compounds in the mineral industries, especially in metallurgical processes and in the refining of petroleum products, has aroused interest in its toxicity, and a brief review of the literature, with special reference to the hazard of poisoning in the mineral industries, seems to be opportune. Recently, residents in the vicinity of aluminum plants have been complaining of injury to livestock and vegetation as well as to their own health from the gases discharged into the air during operation of the plants, hydrofluoric acid gas apparently being the offender. The comparatively recent utilization of hydrofluoric acid in the alkylation process for the production of high-octane gasoline has raised the question of the hazard of poisoning in the petroleum Industry. In addition, the use of fluorine-containing refrigerants has extended the potential al exposure outside of industry (2).

Jan 1, 1945

Auger operations produced 14 million tons of coal in 1974, or approximately 5% of all surface mined coal. It was the most efficient of all coal mining methods, producing 40.0 tons per man-day. Exhibit 1.1 gives a breakdown of productivity of all coal mining methods. Exhibit 161 PRODUCTIVITY OF COAL MINING METHODS (Short tons per man-day) [Method - 1971 1972 1973 1974 Conventional 11.00 10.00 9.75 9.30 Continuous 13.00 12.50 12.25 11.90 Strip Mines 35.69 35.95 36.00 36.00 Auger Mines 39.00 43.00 45.33 40.00 ] Unlike other surface mining methods, augering produces clean coal, largely uncontaminated by foreign materials, other than those existing in the coal seam itself. However, compared to other methods, the coal recovery rate is relatively low. For example, a triple-headed auger in a 35-inch seam would recover approximately 50% of the coal in the seam as compared to a 90 to 95% recovery rate for strip mining and a 55 to 65% recovery rate for deep-mining. The low auger recovery rate is due to the circular cuts and pillars left in the seam.

Jan 1, 1975

By L. C. IlsLey

Through the cooperation of the Pennsylvania Department of Mines the writer obtained from State, records detailed information concerning coal-mine accidents occurring in Pennsylvania bituminous mines during 1939, particularly those nonfatal accidents in which the injured person lost 60 or more days? time from mark. The writer wishes to acknowledge assistance received from Pennsylvania State officials, especially Richard Maize, secretary of mines, and. Joseph J, Walsh, deputy secretary of mines; also to Thomas Dickinson,3/ of the Bureau of Mines, who rendered valuable assistance in assembling the data an the several tables.

Jan 1, 1941

By Thomas A. Morgan

The distribution of stress adjacent to each of 25 mine openings was determined by the borehole stress-relief method in the FMC Corp. Westvaco trona mine at Westvaco, Wyo. The purpose of the stress determinations was twofold: First, to study the effect on these distributions of various factors such as opening shape, stress level, and loading history; and second, to estimate the distribution of stresses adjacent to extensive high-extraction (85 to 100 percent) areas. Stress distributions in areas of low average stress correspond closely to the theoretical distributions based on elastic theory. However, in areas of high average stress, the stress distributions are of a type associated with plastic failure. The stresses adjacent to a mined-out area supported by remnant pillars were significantly higher than the stresses adjacent to another area in which the remnant pillars were removed.

Jan 1, 1965

By O. S. North

As recently as the late 1920's there Were few indications that a 15-million-dollar-a-year industry would ever grow out of the mineralogic curiosity vermiculite. Today, it is an important industrial commodity, used primarily as an insulating material and lightweight aggregate, but with a wide range of other applications. The quantity of crude vermiculite produced and used in the United States increased 14-fold in the 17 years between 1935 and 1951. The vermiculite minerals are of secondary origin, formed by hydrothermal alteration of an ultrabasic igneous rock, generally pyroxenite, or by alteration of phlogopite or biotite mica or possibly other similar minerals. According to different authorities, vermiculite may originate either by direct hydrothermel means, by the weathering of biotite or phlogopite, or by a combination of these two agencies. Vermiculites frequently occur at or near the contacts of an acid intrusive rock, especially a pegmatite dike, with a basic or ultrabasic country rock.

Jan 1, 1953

By James W. Townsend

[The Harrington-Hickory mine in the Star raining district, Beaver County, Utah, has produced approximately 20,000 tons of lead-zinc-silver ores since 1910. Production previous to 1910 is not known. The mine is owned by the New Majestic Mining Co. The property was rehabilitated and operated by James D. Williams under a 10-year lease with option to purchase from April 1943 to May 1949, Loans from the Reconstruction Finance Corporation in the aggregate of $41,000 wore used in construction of an access road, rehabilitation of the mine, and purchase of equipment for full-scale operation. The improved, all-weather access road extends from loading ramps on the Union Pacific Railroad at Milord to the urine storage bins 5 miles west o f town. The mine is serviced electrically by a. 5,000-volt line owned by Telluride Power Co. Mine transformers step the voltage down to 440/220/110 for surface and underground service.]

Jan 1, 1953

By Andrew Allan

[Research conducted by the Bureau of Mines hrinq the last 5 years on the uce of machines for 7!naer:rolmrl ?.eve loym~nt in pi.t,c hlng anthracite beds l~a~ provide? data ?howin? that ?:;panrt of thc roof an9 str?eg of thes? oTen - jnqs requires almst half of' the PRS? workin? time. The possibilitie~ of i!rinz a mvable,. te1.ee*co@. c tpr? 3f ?tee1 ~h-!.oltl at the face in~tetcrl of conventional wood a*ti~yorts w?r? si:~q~eteil by engineers engaqad on the~ work If ~uch a shi~l8 COLI.~,~. be ~sve~.~yad, it tnillil man that face workera w~uld be provi8ed with mulrnu.m prot?ct+on from falls of' roof and ribs mi! the en- tire ehift could he I~W? Lo ~lro,J.~:ce cocl. Fermanent tim3er coald be p'l.acnA behind the shielR independently of the 'face work as the face advanced.]

Jan 1, 1953

By C. J. Chindgren

A refractory-lined, garage-type automobile incinerator with a natural gas afterburner for air pollution control was cooperatively constructed and tested by the Bureau of Mines and the Wasatch Metal & Salvage Co. in Salt Lake City, Utah. The incinerator is capable of relatively smokeless burning of 32 to 60 cars per day, dependent on the degree to which the cars are stripped prior to incineration. Preliminary burning campaigns indicate the cost of incineration to be approximately $2.75 per car.

Jan 1, 1970

By Kenneth L. Rubow, Virgil A. Marple, Bruce K. Cantrell

"In a cooperative study by the University of Minnesota and the U.S. Bureau of Mines, diesel exhaust and mineral dust concentrations have been measured for aerosols generated in the laboratory and in five underground coal mines. Three mines utilized diesel-powered haulage equipment and two used all-electric equipment. Two source apportionment techniques have been applied to differentiate between the mineral dust and diesel exhaust aerosol concentrations measured. The first technique, using a micro-orifice, uniform deposit impactor (MOUDI) for size selective sampling, is based on modeling aerosol size and the premise that the diesel exhaust portion of the aerosol is predominantly submicron and the mineral dust portion is mostly greater that one micrometer in size. The second technique, Chemical Mass Balance (CMB) modeling, was used to referee the analysis of diesel exhaust and mineral dust aerosol concentrations from the size selective sampling results.The MOUDI size distribution data were modeled to obtain parameters describing the fine and course fractions of the sampled aerosol and to estimate the contributions to each mode from both mineral dust and diesel exhaust aerosol sources. The results showed the size distribution of the mixed aerosols exhibited two definite modes with the minimum between the modes occurring at 0.8 µm. Less than 5 pct of the coal mine diesel aerosol was found in the coarse size fraction. CMB analysis confirms the original premise for using aerosol size to separate diesel exhaust and mineral dust aerosol during sampling.Based on the results from the size selective sampling, a personal diesel aerosol sampler has been developed for measuring diesel aerosol mass concentrations. Th.is sampler uses an inertial impactor to size separate the respirable aerosol at 0.8 µm. All material less than 0.8 µm is collected on an after filter for subsequent gravimetric analysis."

Jan 1, 1990

By S. M. Shelton

Preliminary work in the investigation of electrolytic manganese, as reported J, showed promise for a practical procedure of continuous production. Laboratory work was continued in the direction of process simplification to determine an economically feasible procedure that mould require a minimum of expensive equipment for plant erection and a minimum of regent consumption for operation. Results furnished enough evidence to indicate that modifications of the process could be made leading to simplified procedure and with no sacrifice in operating efficiency. A supply of at least 200 pounds of the metal was desired for alloy research, and it was believed worth Mile to utilize available facilities in a search for difficulties, that were not encountered in the laboratory and that might arise in larger-scale operation. Consequently, an experimental pilot plant was erected. The plant was designed for a capacity of 15 rounds per day of metal and operated under simulated -plant practice.

Jan 1, 1938