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By Jennifer A. Slatnick

Chlorofluorocarbons (CFC's), once universally accepted as ideal compounds for use in cooling and refrigeration, in foam production, and in cleaning electronic components, are being phased out and eventually banned under extensive international agreements because the chlorine in CFC's is thought to deplete the Earth's ozone layer. The industry has responded with the introduction of alternatives in the form of hydrofluorocarbons (HFC's), which contain no chlorine, and with hydrochlorofluorocarbons (HCFC's), which fill an intermediate gap in the replacement of CFC's. As a result of the elimination of chlorine in the HFC's and the reduction of it in the HCFC's, these alternatives contain more fluorine than the CFC's do. Other nonfluorocarbon substitutes, known as not-in-kind alternatives, contain no fluorine at all. As a result, the fluorspar mining industry, which is the source of fluorine in fluorocarbons through intermediate hydrofluoric acid, is being affected. Concern for this impact has led the U.S. Bureau of Mines to employ its capabilities to analyze various scenarios in the evolution of CFC replacements and substitutes to determine their effect on fluorspar mining. This report utilizes a network flow model to examine the effects of proposed replacements for CFC's, in terms of fluorine content, on fluorspar operations worldwide and on hydrofluoric acid plants in North America and Europe.

Jan 1, 1994

By John D. Corrick

Three species of chemosynthetic iron- and sulfur-oxidizing autotrophic bacteria have been isolated from the leaching waters of copper mining areas. These species are: The sulfur-oxidizing Thiobacillus concretivorus, the iron-oxidizing Ferrobacillus ferrooxidans, and a sulfur- and iron-oxidizing bacterium closely resembling Thiobacillus ferrooxidans, INTRODUCTION Among several suggested new processes for treating marginal ores in the United States, none is more intriguing than the possibility of extracting metals from low-grade materials by the action of microorganisms One phase of a Federal Bureau of Mines investigation toward developing such a procedure was to isolate and identify specific chemosynthetic iron and sulfur. oxidizing autotrophic bacteria native to certain domestic copper deposits where leaching is practiced. The bacteria or microorganisms considered important to this investigation are those capable of producing solutions of ferric sulfate and sulfuric acid. Solutions of this type are excellent solvents for some copper minerals By establishing the presence of these bacteria at certain copper-leaching areas, strength would be given to a theory that microbial activity is partly responsible for the oxidation that takes place at these areas. Their presence also advances possibilities for controlled use of microbial action in metal extraction processes. Leathen4/ has demonstrated that one of the chemosynthetic iron-oxidizing bacteria, Ferrobacillus ferrooxidans, can oxidize 200 parts per million of ferrous iron to the ferric state in 3 days,

Jan 1, 1961

By H. M. Urban

This paper, one of a series being prepared for and published by the United States Bureau of Mines on methods and costs of mining at various mica mines in the United States, describes the methods now in use in the principal mica mines of the Southern Appalachian States. Those papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total costs might in some instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue.

Jan 1, 1932

By P. D. Lindahl

[A cost/benefit analysis was conducted by comparing the industry cost to protective structures on low-coal face equipment with the benefits paid for injuries/fatalities considered preventable by the use of these structures. Th industry costs were based on estimates by OEM's and rebuild shops for install protective structures on new and rebuilt face equipment. The accident benefit was based on evaluations performed by the USBM Accident Cost Indicator Model. Industry wide population data were developed on low-coal face equipment and injuries/ fatalities preventable with protective structures. The results of the analysis are to be used as a tool by USBM in determining the feasibility of continuing development of cab and canopy technology for low-coal equipment.]

Jan 1, 1983

The small-scale surface mining operation in northern regions is typically located in a remote, ungaged basin. With the recent increase in the economic potential of mining, the number of small operations is increasing. The year-to-year variability in precipitation in this region under study is of great concern to mine operators. Some years may yield only 5 to 6 inches of precipitation, while others may yield in excess of 15 inches. Such variability makes placer mining operations difficult to plan, since low water years may result in too little run-off for gravel washing and high water years may result in flooding of mining developments. There are no official streamfloaw records in many watersheds in the northern region containing placer mining claims. However, information from other streams permits calculation of an estimated discharge for a watershed under consideration using average flows per square mile of drainage. It is to be emphasized that these are average or expected figures in reality, one water year may be significantly wetter or drier than another. This high variability of annual precipitation is significant in relation to placer operations because of the large quantities of water required for this type of mining. Some operations can not operate in low water years. In the larger watersheds, operations may continue in low water years but at a slower pace because of longer water collecting times. The high variability of available run-off rakes placer mining in many parts of Alaska difficult to plan on a long range because of the unpredictability of water supplies.

Jan 1, 1985

By E. A. Ziemba

The modified in-situ process is one of the methods being considered for extracting oil from oil shale. One of the questions to be answered for this approach is the environmental consequence of underground retort abandonment. This report outlines a study which addresses the question in terms of a grouting solution. It covers the development of a spent shale ash based grout which will fulfill the environmental requirements in terms of strength, stability, and impermeability. In addition, it will allow the reinjection of up to 50 percent of material mined and surface retorted as part of this process.

Jan 1, 1982

By J. D. Noll, S. E. Mischler

Measurement and sampling of diesel particulate matter in mine air presents a challenge due to the complexity of the diesel aerosol. The results of a series of tests carried out by the National Institute for Occupation Safety and Health, Pittsburgh Research Laboratory, in an underground mine were used to evaluate several measurement methods that are currently used to characterize particulate matter emitted by diesel-powered equipment. This paper presents an overview of these techniques and examples of the results along with a discussion of the advantages and information gained by each technique. The measurement methods discussed include particle size measurements using a scanning mobility particle sizer, total particulate matter measurements using a tapered elemental oscillating microbalance, a size selective sampling method for workplace and personal exposure assessment and a size-selective high volume sampling method for carbon analysis.

By Wilbert J. Huff

For the past 9 years , the technical studies conducted by the Explosives Division of this Bureau have been summarized in a series of reports issued annually . The following account presents investigations undertaken from July 1 , 1943 , to June 30 , 1944. The work is detailed under a number of main headings corresponding to the organizational structure of the Division , the various activities being under the immediate direction of unit chiefs , who report directly to the author . Specific credit , however , is due to the individual unit leader and his assistants .

Jan 1, 1945

By W. S. Landers

This bulletin is a detailed study of low-temperature, entrained-bed carbonization of a Texas lignite. The lignite studied was from the Sandow strip mine and is representative of the Rockdale formation of the Wilcox formational group. Carbonization was conducted in a continuous entrained-bed reactor at several temperatures in the 8801 to 1,52°C F range, and at air-coal ratios it the 0 to 10.30 scf/lb range (moisture- and ash-free basis). Carbonization rates ranged from 97.1 to 410.0 lb/hr (as-received basis), At the higher air-to-coal ratios employed, all or most of the carbonization heat was provided by internal combustion with air in the reactor. At the lower air-to-coal ratios, parts of the heat for carbonization was supplied externally. It was demonstrated that the entrained-bed carbonization of lignite is a complex reaction and that several variables, of which carbonization temperature, air-to-lignite ratio, and the average size of lignite are important, act together to influence both the carbonization yields and the properties of the resultant products, Process variables established by pant tests were used to design the industrial scale carbonizer operated at Rockdale, Texas, by the Texas Power & Light Company as agents for the Aluminum Company of America. Properties of the carbonization product obtained from the industrial scale reactor were essentially the same as those obtained from the pilot plant reactor operated under the same conditions.

Jan 1, 1968

By A. J. Keast

This circular is one of a series dealing with the exploration, equipping, and development of mining properties, prepared and published by the United States Bureau of Mines in cooperation with various mining and exploration companies in the United States and Canada. This series of papers will supplement an earlier one which covered the methods and costs of mining and milling at a large number of producing mines. The present paper describes the exploration, equipping, and developing of a group of 18 claims remote from rail transportation, and the transport of equipment and heavy supplies for a distance of 120 miles by tractor over ice and winter roads, and of men and lighter supplies by airplane.

Jan 1, 1933

By H. R. Babitzke, H. Kato, R. E. Siemens, G. Asai

The purpose of this investigation was to develop a wide variety of columbium and tantalum alloys and to determine their suitability for use at elevated temperatures . Sixty - nine columbium and tantalum alloys were investigated . For this study , columbium was alloyed with two or more of the following : nium, tungsten , vanadium , titanium, and zirconium . Tantalum was alloyed with vanadium or hafnium, or hafnium and carbon . The fabricability was determined by an arbitrary procedure . Hardness measurements , elevated - temperature tensile properties , and oxidation- resistance studies were made . Of the alloys studied , Cb - 15 Hf - 5W, Cb - 15Hf - 5W- 10Ti , Cb - 15Hf - 10W- 10Ti , Cb - 10V - 5W, Ta - 30V , and Ta - 20 to 33Hf exhibited excellent high - temperature properties . These alloys were not only easy to fabricate , but they also had good oxidation resistance and excellent high- temperature strength .

Jan 1, 1964

By C. V. Brennan

This paper, describing the various mining methods and practices at Britannia mines, Britannia Beach, British Columbia, is one of a series covering mining practices, methods, and costs in the mining districts of the United States and Canada. The Britannia property has been operated continuously for 30 years, and in that time many diverse methods have been used in exploiting the various types of orebodies worked. Under normal conditions mining methods include surface gloryholes, shrinkage stoping, shrinkage with powder drifts for primary breaking, horizontal cut-and-fill, horizontal and inclined square-setting, and timbered and open rills, the three latter systems being combined with close filling. The Britannia method of mining, a large-scale retreating shrinkage system usually combined with powder drifts for primary breaking, has been developed and applied here very successfully. Each block of ground as developed is studied as a separate problem, and the mining method, or combination of methods best adapted to the work in hand is applied thereto. Operating at, capacity, the series of mines produces 7,000 tons of ore per day.

Jan 1, 1935

By Henry Kreisinger, J. F. Barkley

This book is one of a series of publications being issued by the Bureau of Mines for the purpose of disseminating information in regard to the methods by which the fuels in this' country may be used most efficiently. A knowledge of the temperature of the gases in boiler settings and in other commercial apparatus using heat tends to develop improved designs of apparatus and better methods of operation, thus reducing waste of fuel. The following pages present, for the benefit of those designing, operating, and testing such apparatus, information as to the accuracy of temperature measurements made under certain conditions and the corrections that can be safely applied.

Jan 1, 1918

By B. W. Gandrud

To say that the treatment and handling of the "fines" is the most difficult phase of coal preparation is probably an understatement of facts. It is the fine sizes from about 1/16-inch to 0 that are mainly responsible for the inescapable sludge and slurry problems at plants using wet methods of preparation. Sludge and slurry are a problem from the standpoints of both cleaning and dewatering. They cannot be cleaned satisfactorily by "gravity" methods, which are used so extensively on coarser Sizes, due to the fact that fine sizes, particularly from 65-mesh to 0, do not follow the same laws of settling as do the coarser sizes. Although fine sizes are cleaned more successfully on wet-wash tables than in jigs, even tables as usually operated in coal-preparation plants fail on sizes below 100-mesh. As to other phases of the, sludge and slurry problem, wet coal preparation plants are almost universally beset with troubles in connection with the recovery and dewatering of the fine sizes from about 14-or 20-mesh to 0. The sizes finer than 100-mesh further complicate the problems in a wet preparation plant by their tendency to stay in suspension and build up a troublesome load of solids in the circulating water. In order to prevent too much trouble from this source, it is, customary at most plants to bleed a fair-sized stream out of the circulating system continuously and replace it by addition of fresh make-up water. The slurry water withdrawn from the circuit is usually run to waste, in which case it carries with it a considerable amount of fine coal, thus increasing the "washer loss." Another evil results from wasted slurry water in that quite often it finds its way into creeks and larger streams, creating stream-pollution problems.

Jan 1, 1948

By Gregory J. Chekan

The U.S. Bureau of Mines is investigating longwall panel and gate road layouts to increase coal recovery and reduce multiple-seam interactive problems. This report presents design practices for longwall mining multiple seams to provide mine planners and operators with practical guidelines for designing productive longwall mines. Key aspects of mine design that control longwall interactions are examined, including sequencing of seams, design of gate road pillars, and orientation of gate roads and longwall panels. Theories that describe stress transfer between multiple scams and the mechanics of interaction are addressed in relation to geology. Common longwall designs were further investigated using a boundary element model, MULSIM/NL. The model provided insight into relative stress transfer and distribution that occurs between longwall operations in multiple seams. Findings from the model show that (1) a longwall panel should be mined from the gob to the solid coal of an overlying mine, because the stress concentrations are lower; the approach angle should be kept under 30°; and (2) when mining in descending order, superpositioning gate roads usually produces the worst stress condition. To prevent this, the overlying isolated gate roads should be positioned from the centerline toward the headgate side of the underlying panel.

Jan 1, 1993

By J. W. Paul

This circular is one of a series of reports on coal mining methods and cost s which are being prepared by the U. S. Bureau of Mines for the purpose of making available to those interested in the industry a knowledge of the mining methods employed in mines where mechanical and hand loading is practiced and the cost data on the several operations pertaining to the removal of coal from the working faces and its transportation to the tipple for loading into railroad cars. The methods employed are influenced by the natural local conditions with respect to the thickness and character of the coal beds and the overlying strata, the means employed for roof support and its control, and the disadvantages incident to the development of mines in thin coal beds.

Jan 1, 1929

By Laurel A. Powers

The Bureau of Mines process for recovering Ni and Co from low-grade domestic laterites uses a reduction roast followed by an ammonia, ammo-nium sulfate leach. This investigation examined the waste streams of the process for their potential environmental impact and focused on the laterite residue produced. The U.S. Environmental Protection Agency's extraction procedure (EP) toxicity tests and column leaching showed that leachable metal concentrations would be low enough so that the residue would not be considered a hazardous waste under present definitions. Under nonacid leaching conditions, about the same amount of metal was extracted from laterites as from their residues, and the leachates were similar to water samples from an undisturbed laterite deposit. Washing tests on the laterite residue showed that ammonia and ammonium sulfate concentrations were reduced according to equilibrium stage calculations, resulting in residues that would be acceptable for revegetation. With water washing only, the residue would not be considered a hazardous waste even though significant amounts of Ni and Co were absorbed from entrained leach solution onto the residue. Washing first with fresh leach solution and then with water prevented this absorption and thus improved the overall metal recovery.

Jan 1, 1983

By B. D. Nash

The Bureau of Mines continued its research into the recovery of fluorine by the phosphoric acid acidulation defluorination of phosphate rock concentrates. A small process development unit with a capacity of about 10 kilo-grams of charge per hour was operated, and concentrates from both Idaho and Florida were processed. Over 80 percent of the fluorine was evolved and recovered as a dilute fluosilicic acid solution. Phosphate extraction from the concentrates always exceeded 98 percent. The fluorine was converted to a synthetic fluorspar product (3CaFa?SiOa) suitable for use as a slag conditioner in electric furnace steelmaking operations.

Jan 1, 1977

By D. I. Bleiwas

Bureau of Mines personnel evaluated the potential availability of nickel from 151 deposits in 18 market economy countries and selected 126 for detailed analyses. An evaluation was made of tonnage-cost relationships indicating the quantity of nickel available at various total costs of production expressed in dollars per pound nickel, including a 15-pct rate of return on the invested capital. The 126 deposits studied contain approximately 73 million metric tons (t) of nickel. An estimated 52 million t is available from laterite deposits, of which less than 2 pct could be produced at $3.50/lb Ni, about equal to the average published price of nickel in 1981. Approximately 21 million t of nickel is available from sulfide deposits, of which about 10.0 million t can be produced at $3.50/lb. Sensitivity studies performed for both laterite deposits and sulfide deposits indicate that the total cost of nickel from laterites is most sensitive to increases in energy costs, and that sulfides are most sensitive to increases in labor costs; sulfides are also sensitive to changes in byproduct revenues. In 1983 the Nickel Mountain mine in Oregon was the only U.S. producer, though development continued on the Gasquet property in California. Of the total 5.1 million t of recoverable nickel in the United States, about 20 pct is available at or below $3.50/lb.

Jan 1, 1984

By J. W. Miller

This report deals with upgrading of the coal reserves of Raleigh County, VI. Va., to metallurgical standards. The data on samples herein correctly show the characteristics of the bed at the point where sampled and are used to indicate the general quality of the bed in the county. The principal results and conclusions are: 1. Raleigh County contains large reserves of high-quality, high-, medium-, and low-volatile coals. 2. The principal beds from which an increased amount of coal is expected to be mined in the future are: The Eagle, Powellton, No. 5 Block, Hernshaw, Fire Creek, and Pocahontas No.6.

Jan 1, 1954