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By G. M. Zhao

The gasification of lump coke with CO2 was studied in a fixed-bed reactor. The effective diffusivity of the gas was evaluated from measurements of the reactivity of the lump coke, produced by BHP Steel in New South Wales, and from kinetic parameters that were determined from the reactivity of fine grains. The grain model of effective diffusion in porous media was adopted to express the gasification rate of the lump coke and was found to fit the experimental data well. The relationship between reactivity and textural characteristics of the coke was examined

Jun 18, 1905

By S Durucan, A Korre

The application of simple methods of statistical analysis, coupled with geostatistical analysis and geographic information systems, can only summarise and give an outline of the spatial distribution of the parameters measured. Spatial analysis of the components or factors calculated, through principal component analysis or factor analysis, allows assessment of the geographical distribution of the dominant processes contributing to soil composition and/or contamination. Neither of these tools, however, distinguishes between the different sources of pollution. The application of canonical correlation to the data, driven by expert appraisal of the potential pollution sources, allows their quantitative and spatial assessment while GIS provides the environment in which to organise and present the results. The methodology is illustrated by its application to soil-contamination data from the Lavrio area in Greece, where silver-bearing orebodies have been mined for more than 25 centuries

Jun 21, 1905

By Boorder De, B. S. Panov, A. B. Westerhof, V. A. Korcemagin

Paper presented at the conference on Economic geology in Europe and beyond II, models for <mineral deposits> in sedimentary <basins>, held in Keyworth, UK, 13-14 April 1994. The Hg and Sb deposits of the Mediterranean and Circum-Pacific Belts are often found at elevated structural levels, suggesting that their preferential occurrence in young orogenic belts is not a fundamental metallogenic feature but merely reflects their chances of surviving post-orogenic peneplanation. In western Europe their emplacement appears often to be related to late orogenic extensional events accompanied by a notable increase in heat flow. Although Nikitovka and Almaden have quite different settings, both appear to be related to deep-reaching shears. Together with brittle fault zones at higher levels, these provided pathways for fluid phases that originated at least partially within the mantle. The Nikitovka deposits are located in the Donets segment of the 2 000 km Pripyat-Dniepr-Donets palaeorift in the East European Platform. Initiated in the mid-Devonian with a possible Precambrian precursor, its listric boundary faults displace the Moho from a depth of about 50 km north and south of the rift to 35 km along the axes of the Pripyat and Dniepr segments. The steep central anticline of the Donets segment, within which the main Hg-Sb district is located, is interpreted to be associated with a reactivated fault reaching into the upper mantle. The Almaden syncline, formed during the Variscan Orogeny, may be an older pull-apart basin or half-graben associated with the collapse of the Cadomian Orogenic Belt. It is situated on a major ENE-WSW-striking shear zone which may represent a Late Cadomian transfer zone reaching into the mantle

Apr 1, 1995

By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By Bakker J. de, P. A. Leest, W. L. Dalmijn, H. J. Glass

The test facility at the Delft University of Technology, in the Netherlands, was characterised. Advantages include the possibility of separating particles with high but different densities up to 9 g/cm3, the ease of adjustment to any required separation density and the absence of moving parts. Simultaneous separation of more than two types of particles is possible and the magnetic fluid is safe and convenient to use compared with other heavy liquids. Disadvantages include loss of magnetic fluid with outgoing particles (cost approx US $10/l) and degeneration of fluid due to bacterial activity, reaction with particles and with surroundings. Only non-magnetic materials can be separated, there is limited potential for scaling up and high investment is required on account of the cost of magnets. Future improvements in the design of the apparatus and the properties of the magnetic fluids can only enhance its attractiveness for commercial applications

Jun 18, 1905

By C. McCall, J. T. Knight, J. R. Ridley

Gold mineralisation in the gabbro sills is mainly stratabound to quartz- and Fe-rich, granophyric-textured units and is sited in undeformed, brittle quartz vein sets, which form pipe-like orebodies. Hydrothermal wallrock alteration consists of hornblende-plagioclase-calcite-quartz with minor biotite, garnet and chlorite and with arsenopyrite and pyrrhotite as the dominant sulphides. Geothermobarometric data suggest that gold was deposited at around 520 degrees C at 2.8-3.8 bar. Mineralisation is thought to have occurred during amphibolite-facies metamorphism. Fluid inclusion and isotope data indicate that gold mineralisation was the result of deposition from a low-salinity H2O-CO2-CH4 fluid of either metamorphic or magmatic origin. Although the Three Mile Hill deposit differs from others in the area in its wallrock-alteration assemblages, peak-metamorphic timing of gold deposition and distinct geochemical associations it forms a brittle stratabound ore body which suggests structural and gold-depositional mechanisms in common with those of the other gabbro-hosted gold deposits

Jun 18, 1905

By T. G. Carter, R. I. Miller

First, the influence of variation in the

Apr 1, 1995

By J. A. Hudson, D. L. Millar

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993 (original title: Rock engineering system performance monitoring using neural networks.) Synthetic and analytical approaches to objective-based design of rock engineering projects are discussed. Rock masses are considered as complex dynamic systems with components that concurrently interact with each other and their environment. The existence of a rock engineering system canon (i.e. a set of systems governing rules) is proposed. Its possible components are highlighted and an application is demonstrated using a "rock mass automaton" designed to simulate dynamic heat distribution in rock. In the example given, the canon implements the basic result from probability theory applied to the thermodynamics of solids. Rock engineering system performance is reduced to the mapping of the output of a rockmass to varying input (design) options, within the state space of the systems model. The Kohonen Self-Organising Map provides an extremely useful analytical tool to reduce the hyper-dimensionality of rock engineering system behaviour. Further, the hyper-dimensional state vector is mapped "quasiconformally" such that the neural map tends to spatially organise similar input state vectors, facilitating interpretation of rock engineering system behaviour (performance monitoring). Work is reported on the development and validation of the automation as a basis for an internal representation of the rock mass bahaviour. The results are reported of simulations compensating for the uncertainty of the exact mechanisms operating within the rock mass, using additive noise with the input state vector in the training stages of the self-organising map implementation. Initial work on adopting Grossberg's Adaptive Resonance Theory neural network architecture for classification of rock engineering systems behaviour is also presented

Apr 1, 1994

By R. O. Suominen, P. A. Taskinen, K. R. Lilius, A. T. Jokilaakso

Chalcopyrite concentrate was flash-oxidised in a laminar-flow furnace in oxygen-nitrogen atmospheres that ranged in composition from N2 to N2 + 50 vol% O2. Gas pre-heating temperatures were 500-1100 degrees C and four particle-size fractions were studied: 28-38, 38-44, 44-62 and 62-74 micrometres. The effect of the residence time of the particles on sulphur removal was studied in the range 0.1-0.35 s. Scanning-electron microscopy combined with energy-dispersive analysis and back-scattered electron analysis was used to determine the morphology and mineralogy of the reacted particles. Total desulphurisation was achieved under the most oxidising conditions. Particles were observed to undergo fragmentation during oxidation, the violence of this depending on the iron and sulphur contents and the original particle-size fraction. The melting and/or reaction stages of the particles under different conditions were studied in powder samples. Polished sections were examined to follow the development of porosity and the mineralogy of the particles. A model for the fragmentation process is described

Jul 1, 1991

By C. A. Jeffrey

The Dirtlow Rake vein deposit, which is up to 12 m thick, contains a range of paragenetically linked replacement mineralisation styles typical of many Mississippi Valley-type deposit environments. The main ore zone lies within the solution collapse breccia domes, the more southerly of which has recently been well exposed, allowing its relationship to the associated mineral-hosting structures to be studied. The domes were largely formed during early silicification, propagated by dissolution collapse and infilled by subsequent fluorite-barite mineralisation. The location of pipes and pervasive replacement was also controlled by early silicification. Structurally controlled bow tie shears were formed as a result of fluid access at fracture-bedding plane intersections. The nature and distribution of the mineralisation styles indicate that the degree of fluid access, residence time of solutions in contact with the wallrock and susceptibility of the limestone to silicification each played a major role in dictating mineralisation

Jun 19, 1905

By J. S. Mason

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Detailed paragenetic studies of the post-tectonic fracture-hosted vein mineralisation have demonstrated a complex paragenesis, reflecting a multi-phase combination of regional metallogenesis and tectonics through time. Previously published work regarding paragenesis and zoning was oversimplified. Two major epochs of mineralisation resulted in the emplacement of the A1 group of assemblages, from which lead, copper and silver were the main metals mined, and the A2 group, whose galena is only moderately argentiferous but which were major sources of lead and zinc. Tectonic and tentative isotopic evidence points to post-orogenic relaxation as the mechanism for development of the A1 assemblages in the early Devonian, whereas the A2 assemblages are believed to reflect Variscan extensional regimes and regional metallogenesis in the early Carboniferous and Permian

Jun 19, 1905

By G. E. Christidis, P. W. Scott

The deposits were formed from low-temperature alteration of pyroclastic rocks. Properties investigated include their cation exchange capacity, swelling capacity, pH, rheological properties, the green and dry compressive strengths, shatter index, wet tensile strength, compactability and permeability. It was found that deposits with abundant opal-CT have poor physical properties. The rheological and swelling properties were found to be influenced by the bentonite grade (smectite content) and the degree of disaggregation of the smectite quasi-crystals. The only deposits of high grade which had good foundry properties were those with no opal-CT. Hydrothermal alteration was detrimental to the physical and chemical properties of bentonites in that it decreased the smectite content and the pH and changed the smectite layer charge and the lattice dimensions

Jun 18, 1905

By L. B. Clarke

The optimal maintenance and control of the air flow and pressure distribution in a mine network are achieved by the correct positioning of the mine fans and regulators within the mine ventilation circuit. The principal considerations are the location of the main and underground fans or regulators and the attendant control of mine leakage. Air flow control is achieved by either passive or active regulation. Passive regulation adds resistance, usually in the form of a regulating door. Active regulation adds pressure sources in the form of underground booster fans. Ventilation engineers are increasingly turning to analytical tools to assist them in the design and operation of ventilation systems. The application of computer methods, formal optimisation methods and numerical solution methods is outlined

Jul 1, 1996

By P. Varona, L. Lorig, M. Board, E. Chacon

Geomechanical factors at the mine are important and will become even more relevant as the pit expands and deepens. To address these demands a team was assembled to collect geomechanical information and perform numerical analysis. The west wall is the largest and flattest of all the design sectors in the pit and rigorous studies were carried out on this wall. The wall behaviour is controlled mainly by a set of steeply dipping joints within the slope in the Fortuna Granodiorite and a weak zone, the Zona Plastica, that extends vertically near the pit bottom. These features lead to large toppling displacements in the upper portions of the wall. Two numerical models were used to reproduce the general features of failure observed in the wall. The modelling indicated that a toppling mode of failure results from shear on the steeply dipping joints. The toppling leads to slumping or landslides whereby the west wall flows slowly downslope as the Zona Plastica compresses

Apr 1, 1996

By Xiao Min You, D. R. Swonbourne

Smelting of Cu anode slimes involves the use of a slag to hold the oxidised Cu, but some Ag is also inevitably oxidised to the slag. The solubility of Ag in sodium silicate slags at 1 100 and 1 150 degrees C has now been determined over a very wide range of oxygen partial pressures. Silver was found to be present in the slags both as neutral atoms and as AgO(0.5). The activity coefficient for atomic Ag was a very strong function of slag composition and temperature, whereas that for AgO(0.5) was much less affected by slag composition and was almost independent of temperature over the limited range examined. The results reveal that the dissolved Ag cannot be fully recovered by reduction of the slag with very reducing gases

Jun 21, 1905

By P. E. J. Pitfield, S. D. G. Campbell

The regional shear zone runs along or near the southern margin of the Chinhoyi greenstone belt. It hosts four of the seven mines in the southern part of the belt with recorded production above 100 kg Au, including the top two current producers. Displacement occurred in the late Archaean, producing a shear zone with a trend ranging from northeast at Golden Kopje to east at Muriel. The orebodies at the two mines formed synchronously with the shearing and show strong but contrasting structural controls on mineralisation. The Golden Kopje orebodies plunge to the southwest, parallel to the intersection of curved foliation with discrete shear planes and sub-perpendicular to local stretching lineations. The Muriel orebodies plunge steeply west but parallel to local stretching lineations. The greatest fluid flow during mineralisation of the shear zone was along either the intersection of fabrics (Golden Kopje) or the extension direction (Muriel). There is no unique relation between the orebodies and the extension or shear direction. Where earlier mining has not established the directions of the oreshoots it is essential to understand the possible structurally controlled geometries of orebodies before planning a drilling programme to evaluate their potential

Apr 1, 1996

By H. R. Thorpe

A floating gold dredge operating in coarse alluvial gravels of the Grey River on the west coast of the South Island, New Zealand, generated high concentrations of clay and colloidal particles in the dredge pond, which entered the groundwater system. Sampling was carried out at depths down to 20 m and it was found that variation of the length of the flow path occurred because of the movement of the dredge towards the piezometers. The alluvial gravels, the suspended sediments, the groundwater system and the water chemistry were all studied. Sediment concentrations were found to be highly variable with depth, but the relative concentrations in the depth profile were generally consistent as the flow distance shortened. The sediments were extremely fine and travelled further through the gravels than predicted. Comparison of field results with the available theory of deep filtration in clean beds of porous media gives some basis for estimating the behaviour of fine sediments in other alluvial systems

Jun 19, 1905

By G. D. Schena, C Chiaruttini

The feasibility is demonstrated of reconstructing the volumetric distribution of liberated particles and middlings by use of a damped, weighted least-square regularisation method. This allows a precise mass balance to be obtained around a separation/concentration unit, permitting evaluation of the partition curve (Tromp curve) of the separator. Areal grade measurements are made on polished sections of feed, concentrate and tailings and a kernel-based inversion technique is then used to obtain the volumetric grade distribution of the three assemblages. A plain kernel (number of occurrences) and a weighted kernel (each occurrence counted with its area) are used for the solution. Testing of the method on computer-generated synthetic areal grade measurements indicates that it offers a valid alternative to the tedious conventional procedure of conducting experiments with heavy liquids

Jun 21, 1905

Carbon anode cells were studied by two-dimensional computer simulation to evaluate their suitability for alumina electrolysis at high superficial current densities. The most efficient anode arrangement was needed to overcome the electrochemical disadvantages of alumina's low solubility in chlorides. Cells with packed-bed anodes might provide practical superficial current densities greater than 0.67 A/cm2 when the granule size was less than 1 cm, but in the process of electrolysis the granules within the active zone would be consumed and become smaller, affecting alumina concentration transport. For zones of very small granules a concentration-dependent model should be considered; for more complete consideration a time-dependent model can be introduced to describe the variation of granule size and its influence on mass transfer and polarisation

Jun 19, 1905

By D. C. Goldring

Many high-grade iron ores are considered to result from the supergene enrichment of banded iron formations. The secondary processes may be related to either present-day or ancient erosion cycles and may reach a considerable depth. Other high-grade ores hosted by banded iron formations are regarded as either sedimentary or metamorphic in origin although often also subjected to the secondary processes. The evidence for this multiplicity of origins is reviewed with descriptions of selected deposits: Kedia d'Idjil and M'Haoudat in Mauritania, Bomi Hills and the Nimba Range in Liberia, the Itabira district in Minas Gerais, Brazil, and El Pao in eastern Venezuela. Emphasis is placed on the recognition of textures that show that some ores are tectonites, the precursor materials having undergone pervasive deformation accompanied by metamorphism. The question whether such ores are pre- or syntectonic is difficult to resolve, the evidence being inconclusive, but a diagenetic/early deformation origin is preferred. The possible range of origins has to be taken into account in exploration, particularly as regards the depth of drilling, and in the characterisation of ores for metallurgical use

Jul 1, 1991