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By Heribert F. Broicher, Arne Volland

The application of remote sensing techniques combined with fluorescence spectroscopy is realised in analytical devices called LIF Analysers. The analysis of laser-induced fluorescence facilitates non-destructive, non-contact, on-line and real-time rock identification and quality control of bulk solids in transport. LKAB of Sweden was the first company to test LIF Analysers in the Kiruna Mine for bulk sorting of run-of-mine ores depending on the phosphorus content. Other applications tested in Germany so far are quality control of limestone (iron and/or dolomite content) and rock identification in lignite mining. Of special interest also is rock identification in diamond mines for dilution control. The paper summarises the present state of the application of LIF Analysers.

Jan 1, 2003

New technology for on-line particle size analysis of mineral slurries has opened up new applications for particle size measurement. In some cases the particle size distribution of the final concentrate is an important quality issue. This paper discusses established on-line particle size analysis technologies and presents experiences on the use of a new technique employing laser diffraction in several minerals processing operations. The main innovations in the new instrument are a simple dilution system and multiple scattering correction algorithm, which allows wide solids content variations of diluted sample in the measurement cell. Representative sample for laser measurement is produced by a simple and reliable dilution system. The applications discussed are; Blaine number measurement of Fe concentrate before pelletizing, grinding of variable batches of ore and paste thickener control.

Jan 1, 2014

By Juan B. Yianatos

"After almost 100 years, since the first commercial application began in Australia, flotation has shown an extraordinary growth and nearly 2 billion tons of ore per year are presently treated by flotation processes. During this time flotation has promoted a wide scope of research activities ranging from fundamental chemistry and hydrodynamic studies to studies of industrial operations. In general, fundamental studies have been mainly related to ideal situations. In recent years, however, large efforts have been focusing on achieving a better insight into the actual sub-processes provided by the development of new and more sophisticated instrumentation. Since the massive incorporation of flotation columns, around 15 years ago, a renewed interest in flotation fundamental studies, process modelling and new cell designs have been observed worldwide. The key role of the froth has been recognized as an independent and sometimes rate limiting process step. Thus, separation of pulp and froth process stages seems the most appropriate in terms of process modelling, diagnostic, design and scale-up purposes.In relation to flotation equipment development, until the middle of the 1970’s, only the sub-aeration mechanical cells were dominant. Since the 1980’s, the use of pneumatic cells and forced air mechanical cells has emerged strongly. Also, in the last decade, flotation equipment has shown a dramatic increase in size, reaching values of 200m3 in unitary mechanical cells and more than 300m3 in columns. The general feeling, however, is that, despite the great advance observed in terms of process knowledge, the mechanisms and principles of industrial flotation cells design and scale-up are still not fully understood.Advances in process instrumentation and control now in use allow for more efficient operations, both in metallurgical performance and savings in operating costs."

Jan 1, 2003

By Juan B. Yianatos

"After almost 100 years, since the first commercial application began in Australia, flotation has shown an extraordinary growth and nearly 2 billion tons of ore per year are presently treated by flotation processes. During this time flotation has promoted a wide scope of research activities ranging from fundamental chemistry and hydrodynamic studies to studies of industrial operations. In general, fundamental studies have been mainly related to ideal situations. In recent years, however, large efforts have been focusing on achieving a better insight into the actual sub-processes provided by the development of new and more sophisticated instrumentation. Since the massive incorporation of flotation columns, around 15 years ago, a renewed interest in flotation fundamental studies, process modelling and new cell designs have been observed worldwide. The key role of the froth has been recognized as an independent and sometimes rate limiting process step. Thus, separation of pulp and froth process stages seems the most appropriate in terms of process modelling, diagnostic, design and scale-up purposes.In relation to flotation equipment development, until the middle of the 1970?s, only the sub-aeration mechanical cells were dominant. Since the 1980?s, the use of pneumatic cells and forced air mechanical cells has emerged strongly. Also, in the last decade, flotation equipment has shown a dramatic increase in size, reaching values of 200m3 in unitary mechanical cells and more than 300m3 in columns. The general feeling, however, is that, despite the great advance observed in terms of process knowledge, the mechanisms and principles of industrial flotation cells design and scale-up are still not fully understood.Advances in process instrumentation and control now in use allow for more efficient operations, both in metallurgical performance and savings in operating costs.INTRODUCTIONFlotation is a widely used process within the minerals processing industry, as well as being used for water treatment and de-inking of recycled paper. Froth flotation started in Australia at the beginning of the 20th century and since then flotation technology has made significant advances. Flotation was firstly applied to sulfide ores. The largest tonnages treated by flotation are copper and copper/molybdenum ores, handling about 50% of the total ore processed. Also significant are phosphate, iron ore and coal treatments. At present, Chile is the foremost copper producer in the world with around 35% of the world?s production. Figure 1(a) shows the evolution of copper production in Chile over the last decade. The total amount of fine copper produced in year 2001 was 4.7 million tons, from which 3.2 million tons was processed by flotation while 1.5 million tons went through LIX-SX-EW processes, which also showed significant development during the same period (Anon, 2001). The total flotation treatment of copper ores in Chile is about 325 million tons per year (Anon, 2002), so the world treatment of copper ore by flotation can be estimated at about 1 billion tons per year. Consequently a total of nearly 2 billion tons of ore per year is presently processed worldwide by flotation (Fuerstenau, 2001). In order to handle the higher tonnage of low-grade ore, a worldwide trend towards the development and use of larger flotation machines began in the 1960?s. Figure 1(b) shows that the trend became extremely marked from the beginning of the 1990?s, which is consistent with the strong increase in copper production during the same period."

Jan 1, 2003

By K. E. Waters, J. E. Nesset, F. Rosenblum, R. Langlois, J. A. Finch

"Some sulphide mineral mixtures when exposed to air and a warm and humid environment can exhibit a self-generating temperature rise, referred to as self-heating or spontaneous heating. The observed self-heating derives from the oxidation reactions of the active sulphides. In previous publications by the authors, it was proposed that the self-heating of sulphides proceed in three distinct stages; namely, Stage A, Stage B and Stage C. In Stage A (<100OC) the sulphides, in the presence of moisture are oxidized, generating heat through a series of sequential reactions and forming elemental sulphur as one of the products. In Stage B (>100OC) the elemental sulphur produced in Stage A is further oxidized to generate additional heat and SO2. Stage C (>~380OC), sometimes referred to as thermal runaway or roasting, is not addressed in this paper. This communication focuses on the type and role of elemental sulphur found in Stages A and B, and the sequence of reactions that is occurring in Stage A. The sequence is divided into two phases, the first based on galvanic interaction between the sulphide minerals that generates an acidic environment but little heat, and the second involving the production of H2S which rapidly oxidizes to produce heat and elemental sulphur. To date, data suggest that the primary oxidation product formed in Stage A is the stable orthorhombic a-S8 form of elemental sulphur. Above 96OC the a-S8 transforms to a monoclinic ß-S8 structure which is less stable and will readily oxidize to generate heat and SO2. Above 159OC a proportion of the ß-S8 sulphur will transition to a polymeric Sµ form of sulphur which can readily volatilize. INTRODUCTION Some particulate and granular materials, when exposed to appropriate atmospheric and physical conditions, can exhibit a self-induced temperature rise resulting from accumulated heat due to internal exothermic oxidation reactions. This phenomenon is commonly referred to as self-heating or spontaneous heating. Under favorable physical and environmental conditions, these reactions can elevate the temperature of a given material from ambient to the point of auto-ignition. Self-heating behaviour should not be equated to pyrophoric behaviour which describes a group of materials (e.g. certain finely powdered metals) that will ignite spontaneously in air below 55OC. There are numerous materials such as coals, hay, forestry wood products, food products to name a few that can exhibit self-heating behaviour. This publication continues the focus of the authors on the self-heating of sulphide mineral mixtures. Many of the metals of commercial use found in nature are in the form of these sulphides which must be mined, crushed, ground and concentrated prior to smelting or hydrometallurgical processing in order to produce primary metal. The issues of sulphide self-heating therefore pertain to the mining and processing of metals."

Jan 1, 2018

By J. Ma

Vanadium ore is widely distributed in black rock series (Fan, Zhang and Ye, 2004) in many provinces of China, which accounts for 87% (Zuo, Peng and Dugang, 2001) of vanadium reserves in China. In Cambrian black rock series in south Qinling Mountain, there are large or medium-sized sedimentary deposits such as Zhongcun vanadium deposit, Yinhua vanadium deposit, Qianjiaping vanadium deposit, Xiajiadian gold-vanadium deposit and Lengshuigou vanadium deposit. The vanadium is distributed in other minerals mainly in the form of isomorphic replacement. These types of ore are characterized by no independent vanadium mineral, low grade and vast reserves. Now in China the vanadium extraction technology is backward with low utilization rate of resources. The difficulties of vanadium extraction from black rock series are that the enrichment by means of mechanical beneficiation is difficult; the cost of direct chemical extraction is high and the emission of waste gas from pyrogenic process does not conform to environmental protection standard. Therefore the study of vanadium occurrence, the improvement & optimization of vanadium extraction technology and the realization of pollution-free and low-cost extraction of vanadium from black rock series are of great and realistic importance for environment-friendly exploitation & utilization of vanadium resource in China. The study is based on carbon content in ore of Cambrian black rock series in south Qinling Mountain. Two kinds of ore are selected. Vanadium ore with low carbon content (TC<1%) is taken as Sample 1 while vanadium ore with high carbon content (TC>10%) as Sample 2. Based on analysis of ore?s lithologic features and vanadium?s occurrence, a vanadium extraction technological process characterized by selective grinding, low cost and no pollution is proposed.

Jan 1, 2014

By V. A. Chanturiya

The results study the minerals oxidation were obtained by us during the methods of microscopic, FT-IR spectroscopic, XRD and chemical analyses of sulphides in tailings of copper-nickel wastes in Kola peninsula. Sulphide minerals begin to oxidize already at the stage of stockpiling and initial stages of storing. The proportion of non-ferrous metals and magnesium oxide increases with time, calcium partially precipitating in the form of gypsum. Comparison of heavy metal contents in pore solutions in cur-rent and stale copper-nickel ore concentration tailings has revealed a significant difference in practically all the parameters. The lower metal contents in current tailing pore solutions (by 5~30 times) are probably due to the presence of float reagent residues blocking oxidation. Much lower concentrations of magnesium and calcium can be accounted for by the difference in kinetics: the rate of sulphide oxidation at this stage is much higher than that of solution interaction with non-metallic minerals as the result of which the solid phase ? solution equilibrium is not achieved. It is generally believed worldwide that it the mining wastes with acidic pore solutions that pose the greatest hazard for the environment. Our findings suggest that although the solution pH in all the samples is higher than 7.8, the contain heavy metal concentrations by far exceeding permissible values. The direct determination of the total and silicate Ni contents in the tailings from current production and in storage tailings has shown that both sulphide and silicate Ni forms occur in tailings. However, the role of silicate Ni is much larger in the storage tailings. The average silicate Ni content accounts for 10% of the bulk Ni content in the current tailings and it increases to 40% in the storage tailings. Thus, the storage tailings are marked not only by sulphide oxidation and the removal of water-soluble sulfates, but also by the interaction of sulfates with the silicate matrix. Although complete equilibrium is not achieved even within 30 yr under polar-region conditions, the major part of the Ni in fine-grained fractions passes into silicate form. The probability of Ni transition to the silicate form directly correlates with the dispersion of the material and the amount of chemically reactive serpentine and hydrochlorite. The migration of Ni as sulfates and its precipitation by chemically active silicates distorts the distribution of this component in the coarse- and fine-grained fractions that are typical of tailings from the current production of copper-nickel ores. On the one hand, the variation of the mode of Ni occurrence in storage tailings lowers the value of technogenic raw materials as a source of this metal.

Jan 1, 2014

By R. D. van der Weijden, W. F. C. van Wageningen

"Copper(II) can be recovered or removed from acidic copper sulfate solutions as cuprite or metallic copper powder by reduction with carbohydrates (van der Weijden et al., 2001, 2002). In order to make this process suitable for a commercial scale pipe reactor, process conditions and reactor configuration need to guarantee proper throughput of the dilute suspension. This is where crystal engineering also comes into view. Copper powder characteristics, such as size and shape of particles, influence the tendency to adhere to reactor walls and to agglomerate, which in turn influence the throughput. Furthermore, separation, drying, packaging and product quality, are dependent on the powder characteristics.In this paper the effect of both chemical and physical parameters on the shape and size of particles were systematically studied in a number of autoclave experiments. These parameters include mixing, Cu(II) concentration, pH, temperature, seeding, use of additives and reactor materials. Additionally, Monte Carlo simulations of copper growth inside a Kenics static mixer were made. Results show that the use of additives, and the use of static mixers influence particle characteristics the most."

Jan 1, 2003

By K. W. Stöckelhuber, A. Wenger, H. J. Schulze

"An important elementary step of the flotation process is the forming, drainage and rupture of a thin intervening liquid film between bubble and mineral particle.After the encounter of the bubble with the solid surface a wetting film is formed. The initial thinning of this film is driven by the capillary pressure inside the bubble. When the film has reached a certain thickness rupture can take place.There are two possible mechanisms describing this process:-, Growing fluctuation waves (spinodal dewetting) on fluid interfaces under the influence of any kind of attractive forces (electrostatic, van der Waals). -, Nucleation inside the film.Metastable wetting films on negatively charged, hydrophobic glass surfaces (gaseous phase methylated), or on hydrophilic, positively charged glass surfaces (with Al3+ ions), have been analysed by means of the kinetics of film thinning according to the Reynolds law. These experiments demonstrate that both mechanisms can be responsible for the rupture of a thin wetting film. In the case of hydrophobic surfaces the nucleation mechanism is preferred; in the case of opposite charged silica surface the capillary waves mechanism due to an attractive electrostatic double layer force between silica and air bubble takes place.Hereby the existence of a long range hydrophobic force. on a hydrophobic surface can be excluded. The apparent interaction can be explained by the presence of gas nuclei formed on heterogeneous surface sites. The results provide deeper insight into the mechanisms of wetting film stability, adhesion process in flotation and droplet coalescence."

Jan 1, 2003

By Evvie Chockalingam

Acid mine drainage (AMD) is a perennial problem particularly in abandoned mines, occurring due to the oxidation of sulphidic mine wastes. AMD is usually characterized by high concentration of dissolved metal ions, sulphate and low pH. The efficacies of substrates such as rice husk and the bark of Eucalyptus tereticornis (Sm.) are assessed for the removal of metal ions such as iron, zinc and copper from acid mine water obtained from an abandoned copper mine. Over 99 % of Fe, 98 % of Zn and 95 % of Cu removal could be achieved from acid mine water, with a concomitant increase in the pH value by three units using rice husk as an adsorbent. With respect to tree bark as an adsor-bent, about 96 % of Fe, 75 % of Zn and 92 % of Cu could be removed from the acid mine water with an attendant increase in the pH value by two units. The free energy of adsorption of the metal ions onto rice husk and tree bark is found to be negative in both the cases, while the adsorption process is endothermic in the case of rice husk and exothermic for tree bark. The adsorption process is found to adhere to the Lagergren pseudo-first order rate equation. The reduction of sulphate con-centration in the acid mine water is achieved using a typical sulphate reducing bacteria namely De-sulfotomaculum nigrificans. Desorption experiments indicate that about 88 % of Zn, 87% of Cu and over 77 % of Fe could be recovered from rice husk and over 70 % of Fe, 82 % of Zn and 77 % of Cu could be desorbed from the metal loaded tree bark using 5 M HCl. The possible mechanisms of metal ion and sulphate removal from acid mine water using rice husk and tree bark are discussed.

Jan 1, 2014

By Patricio Berrios, David Barriga, Peter Amelunxen, Gerson Sandoval, Roger Amelunxen

Laboratory test equipment and methods have undergone relatively little change since their introduction in the 1950’s. The Denver sub-A cell is still by far the most commonly used laboratory batch cell, but bottom-driven and instrumented cells are beginning to appear. Test procedures have also changed little over the past 60 years, and most engineers continue to rely on empirical models for predicted plant scale performance from laboratory scale tests. This approach is problematic, because changes in the froth phase characteristics in the lab hamper the reliability and reproducibility of the empirical extrapolation to plant scale. In a previous work, the authors reported on the impact of froth recovery at the laboratory cell, showing that variability in the froth recovery can lead to significant error in the modeled kinetic rate constant unless it is properly accounted for in the scale-up model. In this work, we review the role of hydraulic entrainment in the lab cell, and how variability in particle specific gravity, shape factor, and froth residence time can impact the entrainment recovery.

Jan 1, 2014

By W. S. Eu

Reduction of weathered mineral ores can initiate phase transformation which can affect either their activation or deactivation, subsequently influencing the extent of extraction of desired metals in a leaching reagent. The reduction of ilmenite ores for one occurs as a series of parallel, solid state reactions which at present has no known mechanisms, although the evidence of their effects is abundant. Understanding these reactions may well be the key to uncovering the mechanism of ilmenite activation, hence enabling precise control of its reaction process to maximize yield of TiO2 extraction. However, documenting the solid state reactions in the reduction of ilmenite is challenging due to the ore complexity, the number of simultaneous reactions and the difficulty of capturing critical intermediate reactions and phase transformations during processing. The phase transformations of ilmenite minerals reduced at temperatures up to 850°C were investigated in this study. Mineral transformations were studied in-situ using synchrotron radiation based X-ray powder diffraction with temperature resolved tests. The effect of the extent of reduction and specific mineral transformations were verified by leaching reduced ore with sulphuric acid. The re-sults suggest that transformation of major mineral phases occurs within of specific window of operation and thermal treatment appears to influence the extent of activation and leachability of ilmenite minerals.

Jan 1, 2014

By Ming’an Wei, Chuanyao Sun, Zhenguo Song, Zengwen Dou, Yangge Zhu

"The effects of pH value and dissolved oxygen(DO) in the pulp to the Eh and flotation recovery of pyrite were investigated using potential online detection system. The effects of DO on the Eh and flotation recovery were tested which DO changed from 0.5mg/L to 19.5mg/L in six different pH buffer flotation systems (pH: 4.00, 5.62, 6.86, 9.18, 10.01 and 10.96 respectively). Results of potential detected online demonstrated that the pyrite electrode has nearly the same response to potential as with platinum electrode for the FeS2-xanthate-H2O flotation system under the study conditions. Pulp potential and recovery of pyrite were remarkably influenced by pH, both of them decreased with the increasing of pH and, especially, sharp decreased after pH above 9. As the concentration of DO was increased, the Eh was also increased in all the six different buffer solution, while the flotation recovery was decreased. And the amplitude of variation for Eh was not obvious in acidic and neutral solutions, but on the contrary, the change for flotation recovery was remarkable in neutral and alkaline conditions. This may indicate that the flotation of pyrite will be deteriorated in alkaline and high DO concentration conditions."

Jan 1, 2014

By Kazutoshi Haga, Ryo Kawarabuki, Atsushi Shibayama, Masato Kosugi, Masanobu Kawata, Refilwe S. Magwaneng, Kohei Mitsuhashi, Altansukh Batnasan

"The recovery of copper and iron from carbonaceous sulfide ore is of economic and environmental interest despite its processing difficulty. Hydrometallurgical methods can be used to concentrate sulfide metals of these hard-to treat ores in a simple and eco-friendly manner. In this study, high pressure acid leaching process was comprehensively studied to dissolve metals from an ore with organic carbon and carbonaceous gangue material using autoclave equipment. The sample used for the experiment was reduced to an average particle size of 75 µm after undergoing flotation to reduce carbonaceous gangue minerals. A comparative study on two leaching reagents of sulfuric acid and iron sulfate and their dosage was used to observe dissolution of copper and iron. Other parameters of temperature (90-170 0C), solid-liquid ratio (1:10, 1:5, 1:3 and 1:1) were investigated through kinetic studies to access the influence of organic carbon and carbonaceous material on recovery of copper and iron. Materials balancing analysis was used to evaluate the efficiency of metal dissolution. The effects of parameters on leaching rate and concentration was demonstrated. Results obtained from the experiment indicated low concentrations of copper and iron in pregnant leached solutions, which was attributed to acid consumption by organic carbon and carbonaceous material in feed. However, the high efficiency rates of 92.4% and 86.3 % for copper and iron respectively in sulfuric acid can be concluded that leaching of concentrates of carbonaceous ore is possible provided system control on type of acid, pH and temperature. The purpose of this research is important in understanding mechanism involved in dissolution of copper and iron in concentrates of carbonaceous ore and marks an improvement in leaching of highly contaminated ores."

Jan 1, 2018

By Yagmur Sirinyurt, Ayhan Ali Sirkeci, Gülay Bulut, Mustafa Özer, Tuncer Acar

"The basic requirement of glass industry for the silica sand is at least 99% SiO2 content. On the other hand, coloring impurities such as Fe and Ti, must be removed. Flotation is the most widely used method for the purification of silica sands from impurities. In this study experimental studies were carried out to reduce Fe content of Mersin (Turkey) district silica sands by flotation. Silica sand sample with a d80 particle size of 1.85 mm was reduced below 0.5 mm in size. Then the size fraction -0.5 +0.106 mm was subjected to flotation tests. In flotation tests, sulfonate-type R801-R825, fatty acid based DER NA 7 (Produced by a Turkish company) and HA110-HA150 a blend of various chemicals produced by Mersin Cam-Is Mining Company (producer of glass raw materials) were used as collectors. Flotation tests showed that sulfonate type R801-R825 collectors provided much better results in acidic medium (pH: 3). The optimum pH value for DER NA, HA150 and HA110 collectors was found to be 7. It was observed that the addition of collector at once caused an increase in the amount of floated product that resulted in a loss of silica to the tailings. In the case of multistage addition of the collector much better selectivity was achieved. As a result of flotation tests conducted under best conditions, a concentrate assaying 0.046% Fe was obtained with a weight percentage of 93.4 when DER NA 7 was used as a collector. In the case of R801-R825 a concentrate was produced with 0.058% Fe content with a yield of 98.4%. On the use of HA150-HA110 the concentrate was produced with 96% weight recovery and 0.052% Fe content."

Jan 1, 2014

By Gülay Bulut, Ünzile Yenial

"Water composition has a significant effect on flotation. A better understand the role of water composition in flotation is very important for process quality and performance. Based on source of process water, the concentrations of the dissolved ions, hardness, contaminants and residual composition of reagents can varied in the process water. The various water resources employed during lead and zinc flotation caused activation, depression or selectivity effects on minerals due to the presence of different ions in solution. Metal ions in these water resources were adsorbed on the ore, whilst ions associated with gangue minerals were released into the flotation pulp.This paper includes a research for the effect of different water compositions on lead and zinc sulphide flotation. Experiments were carried out five types of water such as tap water, recycling water, tailing dam water, underground mine water and sea water. The ore sample was obtained from Esan Balikesir-Balya mine. The mineralogical study of ore sample shows that it contains mainly galena, sphalerite, pyrite, hematite, quartz, diopside, epidote, calcite, and chlorite. It is found that recycling water and tailing dam water has a positive effect on recovery of lead and zinc minerals and detrimental effect on content of both minerals. This result may explain with remaining reagents in these waters. Underground mine water and tap water gave nearly the same recoveries of zinc. Sea water affects the recovery lead and zinc negatively."

Jan 1, 2014

By de Vaux. Deryck, Natalie J. Shackleton, Vratislav Malysiak Cyril T. O. Connor

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. This investigation aimed at reducing surface passivation of pentlandite and inadvertent activation of pyroxene, thereby improving ultimate valuable mineral recovery and selectivity. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion.The addition of diethylenetriamine (DETA) reduces the copper concentration on both minerals, predominantly on the pyroxene surfaces and polyphosphate further enhances the selectivity at pH 6.The microflotation and batch flotation data obtained has shown a significant improvement in the ultimate flotation response of valuable mineral recovery and concentrate grade compared to the standard reagent regime, while the continuous flotation results significantly improved the selectivity, however, at a similar ultimate recovery."

Jan 1, 2003

By P. M. Solozhenkin

On the territory Sakha (Yakutia) are located largest in Russian Federation reserves of antimony ores, Sarylakhsk and Sentochansk deposits, amaunt 10% of world stocks of antimony. A processing gold antimony ores Sarylakhsk deposit is carried out on gravitation-flotation circuit to receive gold gravitation concentrate and gold-antimony flotation concentrate with the contents of antimony over 60%. The gold-bearing concentrate is treated on place hydrometallurgicaly to a high-standard product, accepted by gold bank cash department. At the ore dressing plant reached the highest recovery in world in a concentrate of antimony 90%~91.6%, and gold 85.7%~86.0% as a result of scientific research works. Studied the mechanism of interaction cations of metals Pb2+, Cu2+, Cd2+, Hg2+, Ag+ with a surface antimonite presented on the basis of modern physical-chemical methods: nuclear quadrupol resonance, x-ray electron spectroscopy, electron spin resonance. The industrial tests of sodium dimethyldithiocarbate were carried out which confirmed high recovery of Sb and As. The leaching Sb2S3 by bacteria Desulfovibro desulfuricans and transformation antimonite in antimony trioxide by Tiobacillus Ferrooxidans improved following cyanidation . The extraction of antimony in a solution 96.0%~98.0% under optimal conditions. The common total extraction in the appropriate commodity products for gold reached 98%, for Sb 96.5%. At a combination of bioprocessing and cyanidation 85.5% of extraction Au was achieved. The new solvents for antimonite were found. Now by the Close Joint-Stock Co ?Sarylach-Antimony? industrial plant is constructed for processing Au-Sb concentrates to receive antimony trioxide and gold from various antimony deposits of Sakha (Yakutia).

Jan 1, 2014

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

By Silvia França, Hudson Couto

"In this paper, an alternative beneficiation process was developed to recover nickel minerals from low-grade weathered ores. The studied sample, 0.3% Ni grade, is essentially composed of nickel sulfides (pyrrhotite and pentlandite); magnetite and silicates (mostly talc and amphibolites) are the primary gangue minerals. The particle size distribution was controlled using a grinding operation to avoid producing an excess of fine particles by overgrinding. The sample underwent a grinding step for the fine degree of liberation. The slimes (-20 ?m) were removed via two desliming stages in hydrocyclones (diameters of 1.5" and 2"); the ground material, which was classified in a range of (-150+20) ?m, was processed by column flotation in three different stages: rougher flotation for magnesium silicates, rougher flotation for sulfides, and cleaner flotation for sulfides, using pilot flotation columns (2" and 6" in diameter and 20 ft high). The goal of using the preliminary magnesium silicate flotation step was to remove hydrophobic minerals (mostly talc) that would float naturally with the sulfides, which would decrease the Ni grade in the concentrate, as well as to reduce the MgO content because this compound is considered harmful in metallurgical processes when a grade greater than 9% is used. The final concentrate obtained in the cleaner flotation step reached up to 2% Ni and 7.0% MgO. The global and flotation recoveries in the process were approximately 30% and 60%, respectively, due to the losses of Ni during the desliming process. Despite this low global recovery, the adopted beneficiation process can be considered an interesting alternative to produce nickel concentrate from tailings or waste materials."

Jan 1, 2014