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By Fathi Habashi

"Hydrochloric acid (HCl), although more expensive than sulfuric, find uses as a leaching agent in reactions involving iron oxide. The reason for this substitution was the discovery that oxyhydrolysis of ferrous chloride by which HCl can be recycled economically. This avoided the pollution of the environment by ferrous sulfate. It was found further that the rate of leaching of sulfides is faster when HCl is used as compared with sulfuric apparently due to the formation of aqueous chlorine. In case of refractory gold ores, HCl leaching under pressure avoids the use of cyanide solution since gold chloride is produced which can be recovered by standard methods. Hydrochloric acid find also uses in the leaching of scheelite and apatite but its use in leaching clay and anorthosite is questionable.INTRODUCTION Sulfuric acid is the cheapest acid and is used as a leaching agent in many hydrometallurgical processes. However, hydrochloric acid (HCl), although more expensive since it is prepared by reaction of sulfuric with sodium chloride, has replaced sulfuric acid in many reactions involving iron oxide. It replaced sulfuric acid for the first time in 1960s in pickling of steel because of pollution problems (Habashi, 2000). Ferrous chloride produced in pickling can be economically decomposed to ferric oxide and HCl according to:2FeCl2 + 2H2O + 1/2O2 ? Fe2O3 + 4HCl (1)which also shows that the acid can be regenerated but ferrous sulfate cannot be economically decomposed to recover sulfuric acid for recycle. Since then, HCl has been used in many leaching processes. Hydrochloric acid is a corrosive acid and is usually handled in rubber-lined equipment. REGENERATION OF HYDROCHLORIC ACID Regeneration of HCl is conducted in fluidized bed or in spray roaster Fluidized bed oxyhydrolysis In a fluidized bed, ferrous chloride solution is introduced onto a bed of hot ferric oxide where heating is provided by the hot fluidizing combustion gases (Figure 1). The solution is fed on top of the bed of oxides. The liquid feed wets the outer layer of the hot oxide particles and is quickly evaporated to form a layer of new solid oxide on top of the existing oxide, thereby producing dense homogeneous particles."

Jan 1, 2017

By A. D. Yell

"Recovery of water is always a major factor in the Beneficiation process. As Preparation Plants become larger the recovery of water for reuse, is a critical cost consideration. Tema Isenmann Inc in conjunction with our sister Company Multotec Manufacturing, has over the years, developed numerous different Screen Panels, Sieve Bends and Static Screens for dewatering. This paper will focus on a new innovation, the TeePee™ Panel which has double the open area of conventional Screen Panels. This results in efficient dewatering (reduced filter cake moistures) which allows for the use of smaller Vibrating Screens or increased capacity on existing Vibrating Screens. A major factor in the efficiency of any Screen Panel, including TeePee™ Panels, is the performance of the Vibrating Screen. If the Vibrating Screen does not have the required gravitational force or screen area to drain it will not dewater efficiently. Therefore a holistic approach has to be taken where the Vibrating Screen needs to operate at an optimal level, in conjunction with the correct Screen Panels, to achieve efficient dewatering. Key performance areas for Vibrating Screens are therefore detailed in this paper with an emphasis on important dewatering criteria. Case studies of different dewatering applications are included, where the use of TeePee™ Panels, has shown a marked improvement over conventional flat Screen Panels in reduction of filter cake moisture content.INTRODUCTION Dewatering can be done in a number of different ways and is largely dependent on the ore type, the particle size distribution and to what extent one needs to dewater will determine the method used. There are a number of different dewatering methods that can be used for particles above 200 micron, including Screen Bowl Centrifuges, Filter Presses, Static Screens, Static Sieve Bends and Vibrating Screens. This paper will focus primarily on Vibrating Dewatering Screens showing improved drainage and a reduction in the filter cake moisture content. KEY PERFORMANCE CRITERIAL FOR VIBRATING DEWATERING SCREENS For clarification the critical key performance criteria for Vibrating Dewatering Screens are set out in this paper. Dewatering Screens Vibrating Dewatering Screens are normally linear motion, either horizontal or inclined at 5 to 7° upwards with a vertical or back sloped plate at 45° to the rest of the screen deck. The back plate will often have screen panels in them to increase the dewatering capability, as shown in Figure 2 below."

Jan 1, 2017

By A. Taylor, E. Thorn Corthay, J. Farrell, L. A. Westfall, S. Borchardt

Mining and metallurgical industries need to minimize their greenhouse gas (GHG) emissions; Hatch specializes in conducting mining and metallurgical energy management assessments and optimizing productivity. Projects executed have demonstrated that there is a wealth of energy management, waste reduction, and process efficiency improvements that require no or low capital investment. Typical energy cost savings are on the order of 5% to 12%, with similar reductions in GHG emissions. Hatch generates Marginal Abatement Cost Curves to optimize the implementation pathway, maximizing carbon abatement and minimizing cost. The findings of a practical case study from Cameco are presented.

Jan 1, 2010

By R. Simon, A. Khosravi

"Tensile strength of rock samples is measured by direct and indirect tensile tests in accordance with standard guidelines. Due to the difficulties in performing direct tensile test, the indirect tensile (Brazilian) test is conventionally carried out to obtain the ultimate tensile strength. A limited number of studies have been conducted to investigate the role of sample size (length to diameter ratio = L/D) in the stress distribution of the Brazilian test using numerical and analytical methods. These investigations showed that the tensile stress distribution along the loading diameter is not uniform. They also indicated that the difference between the tensile stress at the middle part and at the sides of the sample with higher L/D ratio is greater than that in the other samples.The objective of this study is to show the effect of tensile stress distribution on the fracture surface created by the Brazilian test from a morphological point of view on the samples with different L/D ratio. Hence, a series of fracture surfaces created using the Brazilian tests on the rock samples with L/D of 0.5, 0.75, 1, 1.25 and 1.5 were investigated.In this study, all fracture surfaces were scanned by a 3D laser profilommeter. A number of roughness profiles parallel and perpendicular to loading axis have been selected from the samples with different L/D ratio and spacing of 1 mm. The results show that the roughness of the profiles perpendicular to the loading axis increases with an increase of L/D ratio, while the roughness of the profiles parallel to the loading axis decreases. Furthermore, some roughness profiles parallel to the loading axis were chosen and divided into three segments. The results revealed that the segment in adjacent to the upper loading platen possesses higher roughness than the other segments."

Jan 1, 2015

By H. M. Lima, L. A. Gomiero, C. A. de Morais

ABSTRACT The Caetité-Brazil uranium facility produces approximately 400 tonnes U3O8 per year from an ore averaging 0.29% U3O8. The process steps are ore crushing, heap leaching with sulphuric acid, uranium separation and purification by solvent extraction (SX) with a tertiary amine, followed by stripping with a sodium chloride solution, precipitation as ammonium diuranate (ADU), and product drying. A change in the milling process is being evaluated to increase production and uranium recovery. Heap leaching will be replaced by conventional agitated tank leaching of the –590 µm ground ore slurry in a sulphuric acid medium. Replacement of the stripping reagent is also being considered.

Jan 1, 2012

By B. Hart, D. J. Miller, J. T. Francis, M. C. Biesinger, Smart. R. St. C.

Diagnosis of the surface chemical factors playing a part in flotation separation of a valuable sulfide phase requires measurement of the hydrophobic and hydrophilic species that are statistically different between the concentrate and tail streams. Time of flight secondary ion mass spectrometry (ToF-SIMS) can be used to identify sufficient particles of a specific mineral phase for reliable statistics determining a mean value for each species with 95% confidence intervals (1). Using the region of interest (ROI) facility in the Tof-SIMS software, a mass spectrum from each particle, at 1-2 monolayer sensitivity, is recorded and stored. This analysis is reported for a chalcopyrite / pyrite / sphalerite mineral mixture conditioned at pH 9 for 20 minutes in order to study transfer of copper from chalcopyrite via solution to the other two mineral surfaces since this mechanism can be responsible for their inadvertent flotation in copper recovery. Analysis from mineral selection based on specific ToF-SIMS signals (eg. Pb, Zn, Cu, Fe, Fe/Cu) indicated no statistical difference in the copper intensities on pyrite and sphalerite after this conditioning. Principal component analysis (PCA) of the ToF-SIMS imaging data identifies combinations of factors strongly correlated (positively or negatively) in images or spectra from mass spectra recorded at each of 256x256 pixels in a selected area of particles. PCA is a better method of selecting minerals due to multi-variable recognition. It has clearly separated a statistical difference in copper intensities between the sphalerite and pyrite phases. The method has been extended to samples from an operating plant again with excellent phase recognition and diagnostic surface chemistry.

Jan 1, 2004

By Emmanuel Henry

Hanging wall deformation monitoring at the Kiruna Mine is a major concern for Luossavaara- Kiirunavaara AB (LKAB) since underground production is deepening towards the Kiruna Town. In the quest for more effective monitoring techniques, LKAB decided to evaluate satellite-borne Synthetic Aperture Radar (SAR) interferometry?s ability to monitor ground subsidence by generating continuous deformation maps from satellite radar images. While adopted by other geoscience-related industries, SAR interferometry is still relatively untested in the Mining industry. This paper describes how subsidence is actually monitored on the Kiruna Mine?s hanging wall and gives an insight on SAR interferometry?s principle. The encouraging results are discussed as well as the technique?s benefits (continuous deformation mapping, low cost, fast, etc) and limitations (sensitivity to snow and vegetation cover).

May 1, 2003

By G. V. Poropat

Roughness of a discontinuity may be an important factor influencing shear strength of the discontinuity. Traditionally, determining the roughness of a discontinuity surface and providing a numerical measure of the roughness has required considerable effort or specialised equipment. The development of new 3D imaging tools that are easy to use has provided effective fast and accurate means of creating 3D surface models from which roughness measurements can be readily obtained. These new techniques are versatile enabling a user to measure roughness along any desired profile and at any resolution up to the limit of the spatial subtense of a measurement on the discontinuity surface. This paper primarily reviews extensions to the use of 3D imaging that enable the measurement of roughness. Additionally we provide some examples of the measurements and examine some of the issues associated with extracting measures from the spatial data that will support estimation of shear strength.

May 1, 2009

By C. J. Havard, G. C. Taylor, D. G. Cook, N. C. Ollerenshaw, D. K. Norris

"The area encompassed by this report is the eastern and northern Cordillera, shown on the composite map accompanying these background papers. It extends from the 49th pm•allel to the Arctic Ocean and from the Rocky Mountain and Tintina trenches to the Interior Plains. The Mackenzie delta is included in the discussions because of the implications of the bedrock geology of the Arctic Plateau and Coastal Plain on the hydrocarbon and mineral potential beneath it.The eastern and northern Cordillera forms the back-bone of the Western Canada sedimentary basin and from it most of the principles of orogenesis and epeirogenesis relating to the understanding of the structural, depositional and fossil record of the basin have been derived. It may be divided roughly into two parts, reflecting basic differences not only in structural style but also in mineral potential. The more easterly and younger rocks generally contain hydro-carbons, coal and non-metallic minerals; the more westerly and older rocks contain metallic and industrial minerals."

Jan 1, 1970

By M. du Plessis, G. More O’Ferrall, A. Hartzenberg

"Lonmin Platinum has experienced several cases of large-scale hangingwall instabilities during the extraction of the Upper Group 2 Chromitite Layer (UG2) at a number of the Marikana operations along the Western Limb of the Bushveld Complex. These instabilities were all attributed to the presence and interaction of prominent geological features and highlighted that assumptions made in the design of the stable pillars and stable span were potentially overly simplistic in these areas. Investigations into the various case studies over the past ten years have resulted in the identification and classification of the rock mass characteristics of the geological structures causing the instabilities.In order to get a better understanding of these instabilities, it is important to understand the structural geology in general, and the sequence of events that led to the formation of the Bushveld Complex in particular. The tectonics involved in the formation of the various layers around the economic mineralized layers has been investigated, and the influence of these tectonic events on the stability of the UG2 stopes hypothesized.Following this investigation, the behaviour of the various layers in the hangingwall of the UG2 is better understood. This paper presents a description of the ground conditions being experienced in the underground stoping environment, the possible source of the associated structures and the resultant behavioural mechanism of these structures causing the rock mass instabilities."

Jan 1, 2015

By J. Drenda

The model for methane removal from the workings directly behind an advancing longwall as presented in this paper may be used for U-ventilated cross or length-wise systems of longwall advance, starting from the boundaries of the extraction field. In mines with high methane concentrations, Uventilated longwall extraction from the boundary of the extraction field produces a methane risk. The risk is manifested by a higher methane concentration at the end of the longwall, upper gate and incline. The methane in increasing concentrations, which is emitted mainly from the workings with caved areas, appears towards the end of the longwall and in the upper gate. The graphical model of the longwall provided includes both the workspace of the longwall and the caved area. Based upon a model of the rock distribution in the cave, a ventilation model comprising two standard air splits and large number of crosswise air splits has been constructed. Simulations indicate that if the shearer is not present in the longwall, the air distribution in the caved area is symmetrical. The presence of the shearer, both at the bottom and the top of the longwall, causes an asymmetrical air distribution in the cave, that is the asymmetrical flows in the goaf and longwall workspace and in the inflows and outflow between those regions. This phenomenon causes an increase in methane concentration at the end of the wall and at the upper gate. The methane removal method proposed for workings with a caved area directly behind the advancing U-ventilated longwall, starting from the boundary of the field, consists of the removal of methane-air mixtures from the caved area with the boom pipes. These booms may be of several meters long and may be extended if necessary. The insertion of the boom pipes into the cave towards the end of the longwall and connecting them with the general methane removal system creates negative pressure causing a change in the depression field, which is the aerodynamic potential field in the goaf area around the ends of the boom pipes. This will promote the extraction of the methane-air mixture from voids and the goaf cracks, and the area from which methane is being extracted may extend to the side of the cave. This is a positive phenomenon, which could result in the methane flow from the goaf into the airflow in the longwall workspace decreasing or even stopping. A reduction in the methane flow into the longwall workspace with extractions booms will be advantageous for the production continuity. Based on the floor load model for the rocks in the cave and the methane-removal boom load model, the value of the force required to move the boom behind the advancing wall has been calculated. Strength calculations for the pipe were performed using a finite elements method. The analysis results, as well as the comparison of the pipe material effort to the strength parameters of steel, which can serve as piping material (for the assumed load conditions), lead to a belief that the proposed boom construction satisfies the strength requirements.

Aug 1, 2013

"This contribution is concerned with adaptive processing decisions, where the process parameters are optimally adapted to the varying properties of the material input stream. Our starting point is the geometallurgical paradigm that the varying properties of the input stream are considered known e.g. from a geometallurgical model of the mined ore body, and optimal processing parameters are computed from them, by finding the parameter seaming optimal in a computer simulation.This approach however has to work with a lot of uncertainties: The prediction of the geometallurgical ore parameters can only be done with some geostatistical uncertainty. The parameters themselves are only proxies for true ore properties. Model prediction can differ relevantly from actual process results, due to model simplifications. Due to these uncertainties the computed processing choices can turn out to be inferior to simple non-adaptive processing. In this contribution we focus on the uncertainty of the ore properties and analyse this effect systematically, by modelling this uncertainty effect mathematically and in computer simulations. The most important findings are:(a) Processing choices not taking into account the uncertainty sometimes even perform worse than simple non-adaptive processing, for the sole reason of ignoring the uncertainty effect.(b) Ore properties, not adequately reflected in the ore description, might require different approaches, in which the observed processing behaviour feeds back into process control.(c) Bayesian decision theory allows computing optimal processing choices combining the information from the mine (geostatistical predictions) and from the process feedback. These choices give much more robust choices and do not suffer from the drawbacks described for the simple approach we started from.These new approaches can substantially improve the performance of adaptive processing in existing plants."

Jan 1, 2016

By A. L. Mackie

Mine water from base metal mines is generally characterized as having high concentrations of heavy metals and low pH, resulting in the need for treatment prior to discharge to receiving waters. In this study, two high-rate clarification processes were evaluated at bench-scale: the high density sludge (HDS) process and sand-ballasted flocculation. High-rate clarification processes generate larger, denser flocs which settle more quickly than those formed in conventional flocculation processes. The HDS process uses recirculated sludge in order to seed floc formation, whereas ballasted flocculation uses microsand. Both of these high-rate processes require the addition of quicklime or hydrated lime to increase pH and allow for the formation of insoluble metal hydroxides, which can then be removed in the clarification stage. Previous research has shown that cement kiln dust (CKD) can effectively replace quicklime in conventional sedimentation processes for metals and acidity reduction to meet discharge guidelines (Mackie & Walsh 2012). CKD is an alkaline by-product of cement manufacture that has fine particle sizes and varying free lime concentrations depending on the manufacturing process. The lower solubility (i.e., free lime content) of CKD requires larger doses of material to be added to reach treatment pH targets for metals precipitation. The purpose of this study was to evaluate the treatment efficacy of high-rate clarification processes for mine water treatment, compared with conventional sedimentation, at bench-scale with conventional (i.e., lime) and novel (i.e., CKD) pH adjustment additives. Results of the study showed that all treatment processes (i.e., HDS, ballasted flocculation, and conventional sedimentation) were able to reduce target metal concentrations to well below Canadian guidelines (i.e., total zinc and total nickel < 0.5 mg/L, total copper < 0.3 mg/L) using either CKD or lime. Additionally, mine water samples treated with CKD generated lower sludge volumes than those treated with lime (i.e., 50 versus 100 mL for conventional sedimentation and 100 versus 200 mL for HDS) even with increased concentrations of solids introduced during treatment. This is most likely due to slower neutralization rates when using CKD, due to its lower solubility, as well as finer particle size. The sand-ballasted flocculation process was able to reduce final turbidity in CKD-treated samples while the HDS process did not when compared to conventional sedimentation, making the ballasted flocculation process preferable for reducing final solids concentrations in CKD-treated mine water.

Aug 1, 2013

By J. Y. Kim

This paper presents a novel action recognition method for observing human workers using interactions between actions and related objects on an internal construction site. This method can be used to measure work rates for labour productivity monitoring. This monitoring is critical because the performance of a construction project is significantly impacted by labour productivity. However, construction sites are generally crowded with a large number of workers and objects. Such congestion disrupts the accurate, automatic recognition of construction workers? actions. This congestion is one reason that existing automatic action recognition studies of construction areas mainly focus on workers? actions themselves. However, the crowded conditions mean that sites could offer a great deal of clues that could be used for automatic action recognition. According to psychological studies, interactions clearly take place between human actions and related objects, such as between hammering and a hammer. Humans use these interactions to recognize actions or objects more accurately. On the construction site, workers, materials, tools, and equipment are carefully planned out ahead of actual construction. The categories of workers and objects are pre-defined and, as noted, specific interactions define relations between worker actions and objects. In this paper, the interactions are limited to human workers and their hand-held objects. Action recognition results can be combined with hand-held object information to improve recognition accuracy. With the limited interactions, experiments in this paper show a significant improvement in action recognition. This paper describes the utilization of these interactions to improve construction action recognition accuracy based on human skeleton data and 2D color video from Microsoft KINECT sensor.

Aug 1, 2013

By Gerald Blackmore

This paper discusses the present state and future trends within the coal industry, and then goes into the reasoning behind these planned trends. Such factors as marketing, costs, new mining techniques and machinery, and manpower and human resources are considered. Finally, the author refers to the effect that these trends will have on the coal industry of Cape Breton.

Jan 1, 1968

By G. Zárate, G. Tapia

Anglo American Chile has been doing copper concentrate leaching studies at the laboratory and small pilot plant scale since 1992. Among the processes evaluated are bacterial leaching and pressure leaching using Mantos Blancos, Salobo Project and Quellaveco Project concentrates. Late in the nineties, it was decided to focus the research on pressure leaching, either medium or total pressure oxidation. Preliminary scouting tests were run with Mantos Blancos concentrate samples during 2000, which were repeated during 2003 together with samples of Los Bronces and El Soldado concentrates, in order to define the most suitable concentrate for running a pilot plant campaign at AARL, which was carried out in two campaigns, a first one from November 2003 through January 2004 and a second one during April 2004. Mantos Blancos was the selected concentrate and the laboratory and pilot plant results are discussed in this paper together with some preliminary economic estimates.

Jan 1, 2004

In the last five years, new iron ore pellet plants have been built with significantly reduced air pollution levels compared to the older generation of plants. European and American pollution controls are more stringent that in China and Brazil. The recent American plants have successfully employed circulating fluidized beds for sulfur control, baghouses for particulate control, activated carbon injection for mercury and a new design of specialized low-NOx burners.

Jan 1, 2015

By M. Somppi, Z. Yamak

"Gold producers invest significant effort in mining, processing, and creating an intermediate gold doré product. Nonetheless, equal effort should be extended to the final handling and processing of the doré bar, and managing the high-purity gold produced at the fine-gold toll refiner. This detailed attention to bullion handling and refining provides rigor and confidence that the mine site is achieving, through fair and controlled methodology, the most appropriate value for the final product. With the above in mind, the following study explores the importance of preparing a set of site best-practices for bullion handling and specifically, detailing the peculiarities of sampling methodologies and the impact on assays.INTRODUCTION Gold and silver handling practices are common place at mine sites and refineries. The practices include but are not limited to smelting, ingot casting, weighing practices, and secure transportation. Proper handling and processing of the bullion material ensures that the mine site is achieving the true value of the final product. Various handling aspects can critically impact the perceived value of the bullion. A few of these particulars include weight tracking, scale recertification and calibration, refining and melting practices, melt temperature measurement, sampling, pouring, bar cleaning, furnace technology and crucible selection, and assaying. Nevertheless, this report discusses and focuses on the importance of proper sampling and molten-metal temperature measurement and their potential impact on the final doré bar value. Refining or re-melting operations achieve a proper measure of the precious metal content of its bullion when the sample accurately represents the whole bar. At first this task appears seemly straightforward, however, taking a representative sample can be challenging and is also one of the most important tasks for valuing gold during the settlement stage at the precious metal refinery. Various bullion sampling methodologies exist; including: dip sampling, granulation, drilling, cutting, and vacuum pin sampling. The Royal Canadian Mint (2009) indicated in their technical review of refinery operations that pin sampling is one of the best methods for cases where representative sampling and accuracy are required, e.g. to determine the payable metal content. Pin sampling consists of inserting a sealed glass vacuum tube (Figure 1) into the molten metal; when the molten metal contacts a purposely-designed weak portion of the glass, the seal breaks and the metal is suctioned into the hollow centre (Figure 2)."

Jan 1, 2018

By N. Shi, T. G. Joseph

ABSTRACTA series of algorithms were developed to perform geometric and kinematic analyses of cable shovel dipper-ground interactions for a given set of mining face conditions. The routines examine and analyze (a) the position of the dipper in relation to the shovel; (b) the dipper in relation to the face conditions; (c) the dipper position in relation to possible interference or collision with crawler tracks during digging cycles; and (d) kinematic and geometric considerations with respect to any point on the dip-per as it conducts a duty cycle. In all cases, field measurement verifcation provided good agreement(within 4% variance).

Jan 1, 2011

By W. E. Hale

An area of about 7,000 square miles within the eastern part of the Grenville Sub-province is underlain chiefly by granitic gneisses. There are, however, some exposures of mafic rocks which warrant further investigation, and some attractive structures, particularly basins, which deserve additional economic consideration. T HIS paper describes in a very general fashion the economic and geological features of an area of about 7,000 square miles on the north shore of the Gulf of St. Lawrence in the eastern part of the Grenville Sub-province (Figure 1). The scarcity of published geological data on this part of the Cana-dian Shield (DePuyjalon, 1899 and Longley, 1944) justifies the presentation of these tentative results. It should be appreciated, however, that the information which follows was acquired in a rapid reconnaissance designed specifically to out-line what might be interpreted as favourable geological environments for the occurrence of economic minerals, rather than to produce an authoritative analysis of the geological history of the region.

Jan 1, 1962