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By M. Kucharski

The model of the Outokumpu direct-to-copper process deals with a steady-state process the parameters of which do not depend on time. To give a prediction for the process outcome, "a modified black box" method, which ignores most of the chemical reactions in the furnace, was used. This method takes input and output parameters into consideration. The presented model describes the Outokumpu direct-to blister process in the form of the set of linear equations which give mass and enthalpy balances as well as the distribution of elements between blister copper and slag. However, only major substances where quantities in the feed charge exceed a certain level (for example 0.5 kg/ lMg of smelted concentrate) are taken into consideration. Minor elements are distributed among slag and metal phases in a different way. Some of the equations are derived from distribution coefficients. The value of distribution coefficients can be calculated from plant production data.

Jan 1, 2007

By O. S. Perry, G. H. Charlewood, K. Griffin, S Ogryzlo, H. Hopkins, G. MacIntosh

"The gold mines of Kirkland Lake are in Teck township, Timiskaming district, Ontario, latitude 48°9'N. and longitude 80°3'W., at an elevation of 1,038 feet above sea-level.There are seven contiguous producing mines in a length of 3;1/2 miles along the general east-west strike of the deposits. The seven mines are, in order from west to east, Macassa, Kirkland Lake, Teck-Hughes, Lake Shore, Wright-Hargreaves, Sylvanite, and Toburn.The first discovery of gold in the zone was made by W. H. Wright in 1911 on the east claim of the Wright-Hargreaves property, and the following year the Tough brothers and H. Oakes found gold in what is now the No. 1 vein_ at the Toburn. Production began at the Toburn in 1915, followed by Teck-Hughes in 1917, Lake Shore in 1918, Kirkland Lake Gold in 1919, Wright-Hargreaves in 1921, Sylvanite in 1927, and Macassa in 1933.To the end of 1946, 31,938,350 tons of ore had been milled at the Kirkland Lake mines, from which 16,132,700 oz. gold, having a value of $498,517,600, were recovered. The bullion varies from mine to mine between 800 and 900 fine, the average for all the mines being 853. The average fineness of the native gold is 941.The workings of some of the mines are more than 6,000 feet deep and sinking to depths below 7,000 feet is now in progress.GENERAL GEOLOGYThe regional structural geology of the area in which the mines of Kirkland Lake occur is described in a preceding paper in this volume by J. E. Thomson."

Jan 1, 1954

Microseismic (MS) methods offer one of the few ways to monitor a 3D volume of rock and essentially see into the rockmass and the regions of real time rock fracture. This is a critical component when considering workplace safety as well as the economic viability of a mining operation. New Gold Inc. New Afton Mine, an intermediate copper-gold mining company located 350km northeast of Vancouver in the south-central interior of British Columbia, Canada, has recently installed a MS system to help understand the block caving process in space and time. For a block cave mining operation is it important to utilize the MS events to map out the seismogenic zone related to the regions of stress concentration and fracturing mechanisms which lead to caving. The geological setting within the local array is complex, consisting of several distinct lithologies with unique material properties that each affect the microseismic signal differently. The block cave consists of a muck filled void, also affecting the seismic waveform path. This paper compares the use of a single velocity model to a variable velocity model which accounts for the differing lithologies and cave. The variable velocity method determined 3D raypaths for all source to receiver possibilities through five irregular shaped geological domains and the estimated cave. For calibration blast data, the variable velocity model is found to successfully decrease the error for event location from an average of 38m to 20m (47% improvement), and its importance to location accuracy is expected to increase as the cave develops in size.

Aug 1, 2013

By A. H. Onur

Spontaneous combustion of coal is a significant hazard in underground coal mines. It causes serious problems for miners for many years after the fact. It threatens workers? lives and causes economic losses for companies. It disrupts coal production and makes it necessary to abandon the main drift where the spontaneous combustion occurred. Coal fires have to be prevented before they occur; otherwise they are very hard to control. Precautions thus have to be taken in potentially risky areas. For coal to spontaneously combust, it needs 3 elements: fuel, oxygen and heat. If one of them is missing, the fire cannot occur. The best way to prevent spontaneous combustion is to prevent contact between coal and air. Coating of the coal surface with an air-proof lining material would be a practical and useful solution to prevent spontaneous combustion of coal. In the scope of this study, a lining material for coating the coal surface was designed at laboratory conditions. Lining material to be used for preventing coal fires should be airproof, cheap, sufficiently strong, have low rebound, be water- and heat-resistant, and easily obtained and applied. It should also be safe for human health when in contact with mine ventilation. By considering these obligations, 3 kinds of gypsum (plaster, satin plaster, molding plaster), as well as lime, cement and fly ash and different mixtures of these materials were applied in laboratory conditions to form a lining material. Samples of lining material were subjected to uniaxial compressive strength tests to determine their behavior against roof loads. Although there is no need to carry any roof load, the lining material has to be sufficiently strong to stay in place on the applied surface. If the lining material is broken, coal and oxygen can react again. Air permeability and curing time of the mixtures were also tested in laboratory conditions. Then the tested mixtures were applied on a wall with a pump to test the applicability of mixtures. After all tests were performed in laboratory, the most suitable mixture was determined as the optimal lining material to prevent coal fires.

Aug 1, 2013

By D. J. Lloyd

"Bending is involved in the forming of many sheet parts and it is important to understand the phenomena involved. In this paper the basic equations describing bending on a global scale are compared with strain measurements of bent sheet. The development of strain on a local, microstructural scale is also investigated, as is the general aspects of plasticity and the failure process. It is shown that the global equations can be used to estimate the strains involved and the local strains can be attributed to various aspects of the plasticity. The bendability can be related to the fracture strain of the sheet and the ability of a sheet alloy to accommodate the necessary bending to form the part can be assessed.INTRODUCTION The ability of a sheet alloy to undergo bending without failure is an important capability in the forming of many parts and it is useful to be able to assess the bendability of an alloy during its development. The basic mechanics of bending were developed in the 1950s (Lubhan & Sachs, 1950; Hoffman & Sachs, 1953). When a sheet is bent the upper bend surface is in tension, the lower surface in compression and at some point within the sheet there is a plane of zero strain which is referred to as the neutral axis. For sheet exhibiting limited plasticity the neutral axis is static and occurs at the mid-point of the sheet thickness but for sheet exhibiting extensive plasticity the neutral axis progresses deeper in to the sheet as bending progresses. This results in two expressions for the maximum strain at the upper bend surface depending on the motion of the neutral axis. For Al alloys such as AA6111, AA6016 and the like extensive plasticity occurs and the neutral axis is expected to move during bending. However, very few studies have examined how the neutral axis motion and the strains develop, compared with the mechanics analysis. Geist and Parker (1984) used hardness measurements to investigate neutral axis motion but these experiments did not have the resolution necessary to compare the results with experiment but did indicate neutral axis motion. To understand the nature of plasticity and failure during bending it is important to know the extent of neutral axis motion, the scale of strain gradients developed through the sheet and the maximum strains occurring at the bend surface, finally comparing experimental results with the theoretical predictions. The influence of microstructure on the evolution of strain and failure can then be considered in the context of these parameters. Recently, bending in some automotive Al alloys has been reported mainly from the microstructural perspective (Lloyd, 2000, Lloyd et al., 2002, Mattei et al., 2013) and FEM studies have also investigated the development of plasticity under bending, demonstrating the tendency for strain localization (Becker, 1992, Shi et al., 2014)."

Jan 1, 2018

By R. Hendricks

"IT IS a pleasure for me to appear before yon today and to have this opportunity of reviewing with you recent developments in the world lead and zinc industry. To provide essential background material, I propose reviewing the period from 1950 to the present, a period which has undoubtedly been the most hectic in the long history of the industry.In capsule form, the pattern for this period is one of repeating cycles of boom and recession, of failure through research to develop adequately new markets and new uses for lead and zinc, of surplus production and growing inventories, of price instability, and lastly, of an abdication in some sections of the industry of responsibility for control of its own destiny by turning to governments for support in time of stress. This is not a pretty picture but, as the 1950 decade ends, there are signs of a new maturity and of a growing determination on the part of the industry to put its own house in order.The difficulty suffered by the world's lead and zinc industry in the current decade originated with the support extended to it in 1950 by the U.S. Government at the time of the Korean conflict. Recalling the shortage of base metals in World War II and fearing that the Korean conflict might develop into World War III, the U.S. Government in 1950 adopted a policy to encourage the production of lead and zinc, both domestically and abroad by means of development loans and long-term floor priced purclu.se contracts."

Jan 1, 1960

By Jaeheon Lee, Junmo Ahn, Doyun Shin

"Many alternative leaching systems including bacterial leaching have been introduced to avoid passivation on the surface of chalcopyrite and to increase the leaching efficiency of copper from chalcopyrite. Recently, glycine, one of the simplest amino acids, has been emerging as an efficient and environmental-friendly lixiviant to recover copper. In the present study, an alkaline glycine–peroxide lixiviant system was used to leach copper from chalcopyrite concentrate and the leaching mechanisms were also investigated by a suite of kinetic studies under different conditions. The chalcopyrite concentrate contains 28.8% copper with 30.8% sulfide sulfur. The effect of concentration of glycine and hydrogen peroxide of the leaching solution was investigated. Glycine concentration was varied from 0.5 to 1.0 M and the hydrogen peroxide concentration was changed between 3 to 5%. Leaching time and pulp density were also varied. Hydrogen peroxide is an oxidant of the system and the leaching efficiency with periodic additions of the peroxide was also studied. A mineralogical study was performed using XRD and SEM. To investigate the surface of the residue materials, XPS was used to see if any passivating layer was formed during the leaching. Detailed results from mineralogical, chemical, and metallurgical studies will be presented and discussed.INTRODUCTION The greatest global resource of copper is low-grade chalcopyrite and heap bioleaching may be the only economic option for its processing. However, formation of a passivating layer on the surface of chalcopyrite slows down the oxidation reaction and reduces the efficiency of the process."

Jan 1, 2017

By Walter F. Atkins

Fair market value, in the legal sense , is the price which a prudent and knowledgeable buyer and a prudent and knowledgeable seller, acting without constraint or compulsion , will agree upon to exchange an asset. In the ordinary commercial or engineering usage, the term may imply simply the market value or a reasonable and equitable price. The engineer evaluator who is called upon to express an opinion about the fair market value of an asset may be able to base his estimate on the sale price of similar assets or on the market values of stock. Frequently such indicators of value are not available and the evaluator must devise other means of appraisal. Mineral resource properties may be thought of as having value by virtue of the existing or potential ability to produce at a profit. Conventional procedures permit the computation of the present value of future revenues having due regard for the time value of money and the risks attendant upon the realization of the venture. Such computations have gained wide acceptance as a basis for the estimation of fair market value.

Jan 1, 1977

By M. Mirnezami, J. A. Finch, S. Uddin

A fast, reliable and practical way of measuring zeta potential using sedimentation potential method is proposed. A cell was designed along with the instrument control software to determine the required variables simultaneously i.e. sedimentation potential, specific conductivity, volume fraction of solid as well as pH. High purity alumina and silica powders were used as test samples. Measured zeta potential using the proposed technique was comparable with the results by electrophoresis.

Jan 1, 2009

By Q. Li

"The precursor of In2O3 was prepared by hydrolysis precipitation/hydrothermal method using In(NO3)3 solution as the feed material and ammonium hydroxide as the neutralizing agent. The crystallinity, morphology and particle size of the products were characterized by SEM, XRD, BET and LPSA. The results showed that the hydrolysis product consists of an aggregate of cubic In(OH)3 particles with a short rod morphology. In the hydrothermal process, the structure, morphology and size of the particles changes through the mechanisms of Ostwald ripening and phase transition, respectively. When the hydrothermal temperature was less than 280 ?, the Ostwald ripening process took place, which changed the morphology of the particles from short rods to cuboids through dissolution-recrystallization. When the hydrothermal temperature was higher than 280 ?, the processes of Ostwald ripening and phase transition took place successively. Firstly, the morphology of the particles changed from short rods to cuboids through Ostwald ripening, and then, the phase transition from cubic In(OH)3 to orthorhombic InOOH occurred and the morphology of the particles changed from cuboids to polyhedron. INTRODUCTIONDue to its excellent electrical conductivity and optical transparency, indium tin oxide (ITO) film has been wildly used in flat-panel display, solar cell, antistatic coating and EMI shielding (Medvedovski et al., 2008). Indium oxide powder is one of the fundamental materials for preparing ITO film. Along with the development of ITO targets of both high density and large size, high quality indium oxide powders, such as single phase, nano-size, spherical morphology and mono-disperse, have been in high demand (Nakashima and Kumahara, 2002; Betz et al., 2006; Kim et al., 2007). The main preparation methods for indium tin oxide or indium oxide powders include chemical precipitation (Nam et al., 2001; Xu and Yu, 2007), melt atomizing-combustion (Chen et al., 2000) and spray pyrolysis (Ogi et al., 2009). Among them, chemical precipitation has been preferred, since it is simple, easy to control and suitable for industrial scale-up. In chemical precipitation method, indium oxide powders were prepared through the following steps: firstly, indium hydrate precursor was precipitated from an indium salt solution by neutralization using an alkali, such as ammonia; and then, indium oxide (In2O3) powders can be obtained from the precursor through calcination (Li et al., 2006), or solvothermal method (Lee and Choi, 2005), or hydrothermal processing/roasting (Xu et al., 2005; Chen and Li, 2007), respectively. However, the indium oxide powders obtained by direct roasting are polycrystalline, dispersable with a wide size distribution (Liao, 2006). The disadvantages of the solvothermal method are high cost, complicated after-treatment processes, as well as bad performances of the powders (Udawatte and Yanagisawa, 2000). Therefore, among three methods of obtaining indium oxide from the hydrolysis precursor, the hydrothermal process/roasting method is the most feasible to synthesize high quality In2O3 powder with uniform crystallinity and size (Kim et al., 2002; Zhu et al., 2004; Xu et al., 2005; Xu et al., 2005; Chen and Li, 2007; Seetha et al., 2009). However, current research on hydrothermal process-roasting method has been limited to the synthesis of a certain ITO or In2O3 powders under specific conditions. A systematic study on the phase transition, as well as the change of the morphology and size of the particles in the hydrothermal process is still missing. In this paper, the effects of hydrothermal processing on the mineralogy, morphology and size of products were investigated. The results showed that the evolution of crystal structure, morphology and size in the hydrothermal process was affected through the mechanisms of Ostwald ripening and phase transition successively. These results are novel and have guidance for improving the hydrothermal process for In2O3"

Jan 1, 2012

By G. Roy, D. R. Lentz, A. O. Wills

"Abstract - Diamond-drill hole DDH-B357, located 1.5 km north of the Brunswick No. 6 Zn-Pb- Cu-Ag volcanic-sediment-hosted massive sulfide (VSHMS) deposit, intersects three exhalative horizons within variably altered felsic volcanic rocks of the Nepisiguit Falls and Flat Landing Brook formations. These three petrographically indistinguishable iron formation intervals (Fe2O3T = 21.4 wt.%) likely represent cogenetic hydrothermal sedimentary units because they display a common geochemical signature: Fe2O3T = 42.9 ± 10.5 wt.%, MnO = 5.4 ± 3.1 wt.%, elevated base metal values (Zn+Pb = 1999 ± 1091 ppm), strong enrichment in additional exhalative components (CaO = 5.3 ± 3.9 wt.%; P2O5 = 1.43 ± 1.00 wt.%), oxidized signature (Fe/Mn = 10 ± 6), as well as a common immobile element signature (Zr/TiO2 = 0.025 ± 0.007) representative of a pelagic source. The calc-alkaline to transitional host volcanic rocks can be discriminated by Zr/TiO2, and to a lesser extent by Th/Nb: Nepisiguit Falls Formation: Zr/TiO2 = 0.053 ± 0.004, Th/Nb = 1.08 ± 0.37; Flat Landing Brook Formation: Zr/TiO2 = 0.107 ± 0.043, Th/Nb = 0.86 ± 0.17. A symmetrical repetition of the footwall-iron formation-hanging wall stratigraphic sequence is observed in DDH-B357, with distinct felsic volcanic rock domains separated by the three iron formations. This is best explained by parasitic F2 folds on the west flank of the south-plunging Brunswick antiform, similar to the fold closures known to host massive sulfide accumulations in the Brunswick No. 6 and No. 12 mines. Iron formation geochemistry and felsic volcanic rock chemostratigraphy from drill core sampling can provide an effective mineral exploration tool for the structurally complex rocks of the Bathurst Mining Camp. Sommaire - Le forage au diamant DDH-B357, situé à 1.5 km au nord du gisement de Sulfures Massifs à Encaissant Volcanique et Sédimentaire (SMEVS) de Zn-Pb-Cu-Ag Brunswick No. 6 recoupe trois horizons exhalatifs au sein des roches volcaniques felsiques diversement altérées des formations de Nepisiguit Falls et de Flat Landing Brook. Ces trois intervalles de formation de fer, impossibles à distinguer pétrographiquement les uns des autres, représentent vraisemblablement des unités sédimentaires hydrothermales cogénétiques sur la base de leur signature géochimique commune: Fe2O3T = 42.9 ± 10.5 % poids, MnO = 5.4 ± 3.1 % poids, des teneurs élevées en métaux usuels (Zn+Pb = 1999 ± 1091 ppm), un fort enrichissement en composantes exhalatives additionnelles (CaO = 5.3 ± 3.9 % poids; P2O5 = 1.43 ± 1.00 % poids), une signature oxydée (Fe/ Mn = 10 ± 6), ainsi qu’une signature d’éléments immobiles communs (Zr/TiO2 = 0.025 ± 0.007) indicative d’une source pélagique. Les roches volcaniques encaissantes calco-alcalines à transitionnelles peuvent êtres reconnues par leur rapport Zr/TiO2, et à un moindre degré par leur rapport Th/Nb: Formation de Nepisiguit Falls: Zr/TiO2 = 0.053 ± 0.004, Th/Nb = 1.08 ± 0.37; Formation de Flat Landing Brook: Zr/TiO2 = 0.107 ± 0.043, Th/Nb = 0.86 ± 0.17. Une répétition symétrique de la séquence stratigraphique Mur-Formation de Fer-Toit a été observée dans le forage DDH-B357, avec des domaines distincts constitués de roches volcaniques felsiques séparés par les trois formations de fer. La meilleure explication est que le flanc ouest de l’anticlinal Brunswick à plongée sud est affecté par des plis parasites F2, similaires aux zones de charnière contenant les sulfures massifs des mines Brunswick No. 6 et No. 12. La géochimie des formations de fer et la chimiostratigraphie des roches volcaniques felsiques en forage peuvent fournir un outil d’exploration minérale efficace dans les roches structuralement complexes du Camp Minier de Bathurst."

Jan 1, 2006

By B. A. Strathdee

An arsenical ore containing both pyrite and arsenopyrite was heated to a temperature at which decomposition and distillation took place. The condensate consisted of metallic arsenic and arsenic disulphide, although the analysis of the ore showed that volatile arsenic and sulphur were present in proportion to produce a condensate of arsenic trisulphide and sulphur. Distillation tests on the mineral arsenopyrite also produced a condensate of metallic arsenic and arsenic disulphide. This arsenic sulphide gave a distinct x-ray diffraction pattern which was not listed in the A.S.T.M. data file. This same sulphide can be produced by heating a mixture of arsenic and sulphur in vacuo. Its chemical analysis corresponds to As2S2. The dissociation pressures of arsenopyrite and the vapour pressures of arsenic disulphide and arsenic metal were measured, using a quartz "spoon" gauge. The dissociation pressures of arsenopyrite were compared with the published data for the dissociation pressures of pyrite to account

Jan 1, 1961

By Robert D. McKellar, Luke Frawley, Okrasa. Richard

"The resource industries in Canada are facing increasing global competition and stringent environmental regulations. This has made it essential for companies to lower operating costs wherever possible. Electrical energy rep-resents one variable cost that may be better managed and utilized, providing the user with lower operating costs, improved productivity and better yields.The utility industry is also facing changes in the way it must do business. Utilities in North America are facing the prospect of deregulation that will eliminate the monopoly they have traditionally held. This will force them to strive for lower operating costs, to maintain a competitive position and to improve customer ser-vice so as to maintain their customer base.Ontario Hydro has been working with industry for several years. Many opportunities for cost savings have been identified involving energy efficiency, process improvements and the use of new electro technologies. One useful service that the utility can offer industry is to increase the awareness of potential opportunities suited to their operations. This paper will provide an overview of some of the projects that have been implemented and those that are presently being evaluated. An electronic data-base of electro technology applications that is under development will also be described."

Jan 1, 1996

By V. Bonilla-Sierra, M. Elmouttie, L. Scholtès, F. V. Donzé

In the presence of joint sets sub-parallel to a slope face, the stability of the rock mass is controlled by the shear strength of the joints. On one hand, if the joints are persistent their shear strength can be assessed according to Mohr-Coulomb criterion, assuming appropriate values for the cohesion and the friction angle on the joint surface. On the other hand, if the joints are non-persistent with their continuity being interrupted by the presence of rock bridges, their shear strength will increase considerably. In this latter case, the contribution of the rock bridges to the shear strength of the joint has to be accounted for in order to better assess the stability of the rock mass. A numerical analysis of the progressive failure of a rock slope involving a non-persistent joint has been set up based upon simulations performed using a Discrete Element Method (DEM) algorithm specifically enhanced for the modeling of jointed rock masses. Pre-existing discontinuities are explicitly accounted for in the model by using a modified contact logic that ensures an explicit and constitutive mechanical behavior of the joint planes. In addition, rock bridges can be spatially distributed along these joint planes following a prescribed probabilistic technique. Jennings’ formulation (Jennings, 1970) is considered as one of the first rock slope analysis that evaluates the shear resistance to sliding as a weighted combination of the shear resistance of the intact rock and the joint planes. The validity of this formulation is discussed in the present study. Contrary to the Jennings’ formulation, we show that tensile failure is an important mechanism, particularly as the dip angle of the sliding plane increases.

Jan 1, 2015

By W. T. Sampson

Introduction The Kirkland Lake (Ontario) property of Wright-Hargreaves Mines, Limited, - consists of four claims. The two main shear zones or 'breaks' of the Kirkland Lake camp extend through three of these claims, for a distance of approximately 3,500 feet. These claims are on the northeast side of the original lake. The water in this section of the lake has now been replaced with mill tailings. The degree of success of any completed undertaking, especially in the mining industry, reflects the personnel involved. I state with pleasure that the successful deepening of No. 5 winze from 6,400 feet to 7,272 feet was largely due to the co-operation and skilled workmanship of Shaft Captain J. Myelde and his efficient 'leaders'. This winze was sunk at a time when it was most difficult to obtain experienced shaftmen, with the result that the crews did not wholly consist of experienced men (although their desire to learn shaft sinking soon gave good results). This condition added greatly to the responsibilities and duties of those in charge, whose first consideration was for the safety of those engaged in the work, and I take great pride in recording that the entire sinking programme was completed without a lost-time accident. Location of Winze Due to the information obtained through deep diamond-drill holes collared below the 6,000-foot level being of sufficient importance to warrant further exploration, it was decided to deepen the existing No. 5 winze rather than sink another winze. This decision meant that the sinking must be co-ordinated with and proceed simultaneously with operations in the winze, where mining was being carried on between the 3,900-foot and 5,100-foot horizons, inclusive.

Jan 1, 1948

By R. S. Boorman, H. G. Ansell

"Poor separation of lead from a copper concentrate of a major base metal producer was thought to have resulted from copper (0.2-0.4%) in the galena which caused it to float with chalcopyrite. No inclusions of copper mineral were detected which could account for the flotation of galena. The tendency for copper-bearing galena to float with chalcopyrite was confirmed by Hallimond-tube experiments in which the floatability of copper-doped synthetic galena (0.1-0.4% Cu) was approximately four times as high as copper-free galena. The difference in the cell edge (5.9338 ± 0.0003 A, Cudoped galena; 5.9361 ± 0.0002 A, Cu-free galena) indicated that the copper was lattice-bound and did not occur as submicroscopic mineral inclusions."

Jan 1, 1973

By E. Shum, V. G. Papangelakis

"Attempts to reduce the energy requirements of water recovery in the process industries have resulted in the development of techniques to freeze and purify aqueous solutions that take advantage of local climatic conditions. Natural freezing is a technique by which aqueous solution is exposed to freezing air temperatures, resulting in the production of a layer of ice on the surface. As the ice layer tends to exclude solute, a concentrated solution is formed. However, due to dendritic ice growth along the advancing growth front, small quantities of solution are trapped within the ice, decreasing the purity of the water recovered. The ice produced can then be allowed to thaw in order to recover the water using low grade plant heat. As the more concentrated parts of the ice melt first, a purer ice remains. In this study, 0.5 molal magnesium sulfate solution was frozen under simulated natural freezing conditions at temperatures between –1 and –6°C. The ice produced was thawed at either room temperature or 50°C. Up to 40% of the water was recovered with a separation efficiency of above 95% when thawing at room temperature.INTRODUCTION Advances in refrigeration technology have made low-temperature separation processes increasingly appealing to an energy-conscious society. The latent heat of freezing of water is about seven times smaller than the latent heat of evaporation providing freezing with a strong thermodynamic advantage over the traditional evaporation-based processes. The result is the development of a wide variety of processes that fall under the term Freeze Concentration (FC), which describes a variety of techniques in which an aqueous solution is concentrated by the creation and subsequent removal of ice (Williams et al., 2015).FC processes exploit the freezing behaviour of aqueous solutions as dictated by their respective water-salt phase diagram. When, for example, a solution of magnesium sulfate is cooled to a temperature below its freezing point but above its eutectic temperature of –4.1?C (Figure 1) then, if the concentration of MgSO4 is less than the eutectic concentration (about 1.7 m), ice will form until the solution concentration reaches its equilibrium concentration at the given temperature on its phase diagram. If the concentration is greater than the eutectic concentration, MgSO4 solid will precipitate until the concentration reaches equilibrium. It is for this reason that ice can be selectively produced in FC processes (Randall & Nathoo, 2015)."

Jan 1, 2017

By G. Gauvin

Life span of aluminum smelting electrolysis cells can reach up to 3000 days. During this period, cathode blocks go under various physical and chemical changes that could result in an increase of electrical resistivity. The increase may be due to carbon migration from the cast iron to the steel bars, gap evolution between the cathode block and the cast iron, cathode cracking, etc. This paper focuses however only on the collector steel bar electrical resistivity evolution. To reveal the main phenomena responsible for the electrical resistivity increase, chemical analysis, metallographic and electrical resistivity tests were conducted on two steels bars picked from two Hall-Héroult cells after autopsies. Cathode voltage drop and temperature were measured using electrically insulated internal probes and thermocouples on 16 samples from each steel bar. Electrical resistivity can reach up to 1.21µO-m for a steel bar aged 2505 days compare to 0.142µO-m for steel AISI 1008 at room temperature.

Jan 1, 2011

By Kevin Azocar, Jim Hazzard

"Slope stability analysis is performed most commonly using limit equilibrium calculations or numerical models assuming a two-dimensional slice through an infinitely long slope surface. In areas such as open pit mining, where most slope surfaces are not planar, the importance of curvature becomes important due to the economic gains associated with creating a steeper slope. With advances in computing capabilities within the last decade, three-dimensional slope analysis can be performed within reasonable time frames. Some work has been done on the potential importance of curvature on slope stability, mainly assuming homogenous materials with a circular shear-failure mechanism. However, many open pit mines are excavated in jointed rock mass where a completely different set of failure mechanisms can be seen. Depending on the geometry and radius of the pit, the curved geometry may influence the factor of safety and failure behaviour compared to a two-dimensional slice.A series of numerical analyses were performed to investigate the effect of curvature on jointed rock slope stability compared to an equivalent two-dimensional slope analysis. By using discrete element method models, the influence of joint planes and interaction between distinct blocks can be seen. With a three-dimensional model, the effect of curvature can be combined with multiple joint sets at any orientation, which cannot be seen in a single slice. Numerous three-dimensional models are created, along with an equivalent unit-thick slice. The effect of curvature on a variety of different types of failure mechanisms is observed, and graphical relationships are created to quantify the difference between the three-dimensional factor of safety and the two-dimensional factor of safety based on the degree of curvature."

Jan 1, 2015

By Takanori Kokubo, Kenta Suzuki, Tomohiro Sasaki, Toshiya Anami

"Previous work has shown that the strengthening Al-Mn alloys with copper leads to the formation of an undesirable reduction in recrystallized grain size. In this study the mechanisms of strengthening and recrystallization behavior in a continuously cast automotive heat exchanger fin stockof Al-1.1wt%Mn-0.5wt%Fe-0.3wt%Si with a0.3wt%Cu addition were investigated. Metallurgical analysis revealed that the Cu strengthening was dominated by the formation of dispersoid particles, while solid solution strengthening decreased with the Cu additions. This result is attributed to the decrease in the amount of Mn solid solution. The post brazing recrystallized grain size was reduced compared to that not containing Cu. It is postulated that the Cu addition leads to a decrease in the amount of Mn in solid solution which leads to a finer grain size. This effect is attributed to Mn in the aluminum matrix inhibiting boundary migration but allowing other grains to grow during heat treatment. The results are rationalized based on particle stimulated nucleation (PSN), wherein dispersoid particles are more likely to become active recrystallization nuclei during the heat treatment. The increase in the number of active dispersoid particles with Cu addition is correlated to the recrystallized grain structure.INTRODUCTIONImprovements in properties such as strength, braze ability and corrosion resistance in thermal fin stock alloys are all means to gain improved efficiency in heat exchangers particularly in automotive applications. While Al-Mn alloys dominate automotive heat exchanger fin stock alloy, even small chemical compositional changes can profoundly influence these properties (Kawaharaet al., 2004; Yoshino et al., 2009). The microstructure (particularly the grain size and shape) also plays a key role in determining the product performance and hence the thermo-mechanical processing (TMP) must also be considered. The casting method (typically conventional direct chill, DC, or continuous casting) significantly influences the properties in no small part due to the very different TMP routes that are used. Continuous casting is generally favored for fin stock applications as its higher cooling rate (which can be 2 to 3 orders of magnitude higher than DC casting) leads to finer as-solidified intermetallic particles and an increase in super-saturated solid solution elements (such as Mn)that are known to improve fin stock performance such as strength, braze ability(Okiet al., 2008)."

Jan 1, 2018