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By M. Laframboise, M. Buarzaiga

High-pressure acid leaching (HPAL) of nickel laterites has received considerable attention in recent years. High paymetals extraction, good selectivity, and advances in pressure hydrometallurgical technology are some of the reasons for this interest. Falconbridge Limited (Sudbury. Ontario) investigated the HPAL process using both fresh water and seawater for ore processing. The use of seawater resulted in a chloride concentration of 7.8 g/L in the autoclave feed. A test program was developed to study the effect of process water and leach temperature on the leaching behaviour of different ore compositions from the Koniambo deposit in New Caledonia. The work showed that salinity has a major effect on autoclave chemistry. This paper explores the results.

Jan 1, 2004

By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By J. Coffin, R. Multani, C. Deredin

Glencore’s Strathcona Mill has recently evaluated a pyrrhotite depressant combination of diethylenetriamine (DETA) and sodium metabisulfite (SMBS) to improve its overall plant pyrrhotite- pentlandite (Po-Pn) selectivity, with the aim of producing a higher quality nickel concentrate. In a previous paper, key findings from a comprehensive lab-scale program (completed at the XPS Centre) were summarized where, of the depressants tested, DETA/SMBS combination was found to be the most effective in improving the Po-Pn selectivity. The present paper describes the metallurgical program recently completed at Strathcona Mill; DETA/SMBS evaluation on select plant “grab” samples as well as the major results of three DETA/SMBS plant trials conducted on several plant ore feeds (long-term testing). Interestingly, it was found that there was variable success in using DETA/SMBS depressants on the different plant ore feeds; DETA/SMBS (dosage: 25/50 g/t milled feed) on lower Cu feeds demonstrated a ~2% Ni recovery increase at the same Ni grade. On the other hand, higher Cu feeds demonstrated virtually no benefit from DETA/SMBS at the same plant dosage, suggesting that higher DETA/SMBS dosage (at specific locations) than that tested is required to overcome the increased Cu-DETA complexation for these particular feeds. Glencore Nickel – Sudbury Integrated Nickel Operations owns and operates Strathcona Mill which has been processing Ni-Cu ores from the Sudbury Basin since 1968. The valuable sulfides are pentlandite (Pn) – (Ni,Fe)9S8 and chalcopyrite (Cp) – CuFeS2, majority of the sulfide gangue is pyrrhotite (Po) – Fe(1-x)S [0 < x ≤ 0.125] which is present in two forms: hexagonal Po (Fe9S10) and monoclinic Po (Fe7S8) (Multani & Waters, 2017; Lawson et al., 2014). Currently Strathcona Mill processes ore mined from two primary sources from the Sudbury area and produces two concentrate streams: (1) nickel-copper concentrate that is sent to the Sudbury Smelter; and (2) copper concentrate that is shipped to the Fonderie Horne (Glencore Copper, Rouyn-Noranda).

Jan 1, 2019

By K. Parameswaran, A. Veek, A. Fernandez, P. Safe

ASARCO LLC (Asarco) Hayden Copper smelter, in Hayden, Arizona, has operated continuously (except for minor labor and economic curtailments) since 1912. The current plant configuration comprises INCO flash smelting, Peirce Smith (P-S) converting and fire refining/anode casting. In order to comply with the U.S. Environmental Protection Agency (EPA) 1-hour National Ambient Air Quality Standards (NAAQS) for sulfur dioxide promulgated in June 2010, the Hayden smelter had to increase overall sulfur fixation from approximately 95 % to 99+ %, requiring a retrofit of the existing converter department and upgrade of associated emissions controls systems. The Converter Retrofit Project (CRP) involved replacing the five existing 13’ diameter Peirce-Smith converters (2 blowing, 2 hot standby) with three new 15’ diameter Peirce- Smith converters (1 blowing, 1 hot standby) to allow for more effective process gas capture using the existing acid plant contact section. Significant upgrades were made to the acid plant wet gas cleaning section and converter primary gas handling system to improve capture performance, reliability, and sludge handling. In addition, a new tertiary gas capture system was installed to further minimize fugitive emissions from the converter aisle. The existing furnace tapping ventilation ESP was replaced with a new baghouse to enable at least 50% SO2 removal using high-surface-area dry lime injection, which was also implemented on the existing converter secondary gas baghouse system. The first two converters and all gas handling system improvements were started up in April 2018, and the third converter was brought online in November 2018. This paper presents the regulatory context; genesis and rationale for CRP; detailed description of the project; challenges during commissioning; system improvements implemented, and design considerations made, and systems performance and process optimization achieved since startup.

Jan 1, 2019

By Julián M. Ortiz

Uncertainty quantification of a spatially distributed variable at any scale can be handled through geostatistical simulation. Large computation time, storage, and post-processing of the realizations are required to obtain a final assessment of block uncertainty. Multi-Gaussian kriging is a flexible alternative to simulation. The idea is to compute the conditional distribution of uncertainty after normal score transformation of the original samples. Under the multi-Gaussian assumption, all marginal and conditional distributions are Gaussian, hence fully defined by their mean and variance. The parameters of the conditional distributions are obtained by simple kriging and can be back-transformed to the original units of the variable of interest. An estimate and any summary of uncertainty can be easily retrieved. The main disadvantage of performing multi-Gaussian kriging is that change of support is not straightforward, that is, calculating uncertainty of block grades. We propose a methodology to overcome this limitation by considering a matrix simulation to generate multiple probability fields. Each probability field is used to draw spatially correlated point values from the point-support conditional distributions, and multiple realizations of the average can be obtained. This permits the calculation of the average over the block and its uncertainty. These blocks may correspond to selective mining units or to volumes from longer production periods relevant for engineering decisions. They can even be disjoint blocks, such as when several faces are mined at the same time. POSTMG, a Fortran program to perform these calculations, is described and a case study is provided.

May 1, 2004

By Jan E. Nesset, Antonio DiFeo, James A. Finch, Jose Hernandez-Aguilar, Cesar O. Gomez

"The gas dispersion measurement sensors and methodology developed by the mineral processing group at McGill University have to-date been employed at a number of plants in Canada, Australia, the U.S., South Africa and South America. In some cases the measurements have been directly linked with metallurgical performance while in others the gas dispersion surveys on their own have proved very useful in understanding the behaviour of the flotation cells. In addition to reviewing the current state of the gas dispersion measurement technology, the paper will present a series of case studies from the various plants and will show how this technology brings a remarkable new level of understanding to flotation behaviour. The influence of the bubble size distribution on recovery and grade are emphasized in the paper.INTRODUCTIONBackgroundThe advent of new sensors to characterize gas dispersion parameters in flotation cells is a development that is long overdue. While the chemistry of flotation has been studied since the early 1900’s, it is only now that the significance of bubble size distribution, gas rate and gas holdup can be meaningfully measured in-plant with robust and precise sensors. Early researchers, like T.A. Rickard (1916) recognized the importance of understanding the role of air and bubbles in flotation when he wrote in 1916 “we know that the key to the flotation process is to be found not in the oil, the acid, or the apparatus, but in the bubbles. The man who understands the mystery of a soap bubble has mastered the chief mystery of flotation”. In his 1999 review paper on The Froth Flotation Century D.W. Fuerstenau laments the fact that due to their “inert nature”, bubbles have never received their due attention from researchers who tended to focus on the chemical, physical, surface and colloidal aspects, rather than the physics of the process. It is perhaps fitting that now, 100 years after the inception of industrial flotation practice at Broken Hill, Australia, researchers and industry have turned their attention toward the importance of truly understanding the role of bubbles in flotation."

Jan 1, 2005

By Fidelis T. Suorineni

Rockbursts are a major hazard in deep hard rock underground mining and tunneling. To date a significant number of rockbursts still defy conventional explanations. A review of rockburst case histories in the literature has shown that pillars and tabular excavations under shear loading are prone to rockbursting in situations where they are least expected under conventional knowledge of rockburst causes. Despite the evidence of the effects of shear loading on underground infrastructure, and the frequency of their occurrence, little is known about how this loading mechanism causes such large magnitude events and extensive damage. In this paper analytical and numerical modeling are used to understand the behaviour of pillars and tabular excavations under shear loading. The numerical modelling results show that pillars under shear loading are less confined than their equivalents in loaded in pure compression in the same geologic environment, and are therefore more brittle and weak. For tabular excavations under shear loading, the behaviour depends on whether such excavations are continuous, co-planar or offset with rock bridges. Analytical results based on slit theory show releasable potential energy in tabular excavations increases nonlinearly with excavation half-span. The study results are important for the safe and economic extraction of orebodies under shear loading.

May 1, 2011

By M. B. Kime, A. T. Kaniki

"Grinding tests were conducted on an oxidized copper-cobalt ore using a pear-shaped ball mill. Twelve mono-sized ore fractions were prepared and wet ground batchwise. The mill was run for 0.5 to 30 min intervals. The shortest interval provided data more closely related to the breakage function (B) because less secondary breakage was hypothesized. Some selection function (S) and B parameters were determined. Remaining parameters were estimated using a population balance model simulator. To evaluate the kinetics model, an unsized ore sample was also milled. Predicted and measured particle size distributions (PSDs) agreed well, suggesting that S and B parameters can be used for continuous operation mass balances.RÉSUMÉ Des essais de broyage ont été menés sur un minerai oxydé de cuivre-cobalt à l’aide d’un broyeur à boulets piriforme. Douze fractions de minerai de dimension unique ont été préparés et broyés en voie humide en lots. Le broyeur était mis en route à des intervalles de 0,5 à 30 minutes. L’intervalle le plus court fournissait des données plus étroitement liées à la fonction d’abattage (B) car d’après l’hypothèse avancée, le besoin d’abattage secondaire était moindre. Certains paramètres de la fonction de sélection (S) et de B ont été déterminés ; les paramètres restants ont été estimés à l’aide d’un simulateur de modèle d’équilibre de population. Pour évaluer le modèle de cinétique, un échantillon de minerai non calibré a également été broyé. Les compositions granulométriques (PSD, de l’anglais particle size distributions) prévues et mesurées correspondaient bien, ce qui laisse penser que l’on peut se servir des paramètres S et B dans le cadre d’équilibrages massiques en fonctionnement continu. INTRODUCTIONSize reduction of solids is a very energy intensive and highly inefficient process. It consumes approximately 5% of the electricity produced worldwide (Rhodes, 1998), and more than 50% of the total energy used in mineral processing plants (Walkiewicz, Lindroth, & Clark, 1996). An increase in grinding efficiency can therefore result in significant reductions in operating costs. This often amounts to determining the optimal design configurations for milling an ore sample in a laboratory mill under standard conditions. Prior to optimizing the milling stage, the requirements for downstream processing in terms of particle size distribution (PSD) need to be understood because low liberation and overgrinding will lead to future problems. Once this is done, it is also important to clearly understand the breakage properties of the ore. The kinetics of size reduction in tumbling mills are often determined using two probabilistic functions: selection and breakage (Austin & Luckie, 1972). Knowledge of the selection and breakage functions also enables the prediction of the PSD for a given ore sample."

Jan 1, 2017

By Q. Zhang

The necessary capability of the gravity transportation pipeline system for cemented coal gangue backfilling at the Suncun Coal Mine, China, is about 74.4 m3?h-1 according to mining production and working times in the mine. It is estimated that the working velocity and maximum pipe length-backfill depth ratio of the backfill system are 3.82m?s-1 and 5.4, respectively and that the probable backfill capability of the system is 110.18m3?h-1. Results of hydraulic calculations for the backfill transportation system show that the designed backfill system is reliable in flowability and sufficient for backfill capability needs.

May 1, 2007

By Peter Radziszewski

"Comminition process costs, which typically represent an important contribution to mining operating costs, can themselves be divided roughly between energy and liner /charge wear. As such, developing the ability of predicting mill wear will allow a more accurate estimation of wear costs and therefore their control. In this paper and based on the possibility of estimating energy dissipated in impact and abrasion by using a discrete element charge motion model for mill charge motion simulation, media wear will be investigated principally as a function of three wear mechanisms : impact, abrasion and corrosion. Experimental results will be used to identify a total media wear model. Model results will be compared with real mill data from three operating Australian mines. These preliminary results show for the cases tested that the overall average error, as compared with the observed cases, is 0 % with a standard deviation of 66.1 %. Results from the Bond abrasion index tests, for the same cases investigated, give an overall error of 73 % and a standard deviation of 192.5 %. Further work is in progress to improve test procedure, validity and confidence.INTRODUCTIONComminition process costs, which typically represent an important contribution to mining operating costs, can themselves be divided roughly between energy and line / charge wear. In Greenfield situations where the estimation of operating costs is critical in determining project feasibility, the level of confidence in such estimates becomes quite important. With regards to media wear, the Bond abrasion test currently serves as the standard media wear prediction device. However, as shown [l, 21 test results once compared with actual wear rates can vary greatly. Figure 1 shows test results as compared with 15 cases. Average error over this data is 73 % with a standard deviation of 192.5 %. As such, developing the ability of more accurately predicting mill wear will allow greater confidence in wear cost estimation and therefore their control."

Jan 1, 2001

By Julian Wills

The Candrill was developed with Soredem as a one-operator rockdrill for Canadian narrow vein mining. It provides the benefits of increased drilling rates, lower noise and vibration, mass reduction of 20% and system cost saving. The Candrill is to be commercialised at the end of 2001 together with a stoper drill through Parts Headquarters, Novatek&apos;s Canadian agent. The Candrill or pneumatic drills may be further exploited using a simple mechanised drilling system to further reduce operator labour, improve drilling speeds by up to 50% and to enhance drilling accuracy. Novatek&apos;s drilling system for simple mechanisation in gold and platinum mines is integrated with roof supports, can operate in stope widths as low as 800 mm and has resulted in labour savings of 50%, improved advances per blast of 20 to 50% and improved operator safety and ergonomics.

Oct 1, 2001

By J. E. Nesset

Significant progress has been made over the past few years on characterizing and understanding the hydrodynamic properties of frothers and collectors and their effect on flotation performance. This new understanding of the relationship between chemistry and hydrodynamics has dramatic implications for how flotation circuits should be controlled and optimized. Previous work has shown that choosing a frother of the right &apos;strength&apos; is critical to the optimization process, and the work and discussion presented here serve to strengthen the argument. In addition, we know that collector chemistry may also influence hydrodynamic properties and needs to be taken into consideration. To achieve the desired outcome, the overall system of reagents and operating parameters must be considered. This paper describes and discusses some of the findings from recent research on frother and collector chemistry effects (on hydrodynamics), and how this knowledge can be used to improve flotation performance. Examples from plant experience are discussed.

Jan 1, 2009

By Steve Lalancette

Centre Jardin Lac Pelletier (CJLP) has been a leading actor in the revitalisation of closed mining sites in northern Québec for over 20 years. Over that period, CJLP developed a cost-efficient technique that transforms sterile mining residue into a substrate able to support a resilient ecosystem. Using a unique mix of organic matter, fertilisers and selected plant species, this technique rapidly builds a microorganic fauna and a layer of humus that will sustain the creation of vegetation coverage. The coverage is composed of over 13 different plant species, each having a unique role in the development of a resilient ecosystem, from soil stabilisation to nitrogen fixing. Considerably less expensive than traditional methods using civil engineering techniques, it does not require the use of heavy machinery or the spread of topsoil. This technique has been successfully used to restore over 20 sites in Québec such as Joutel, Yvan Vézina and Louvicourt. It is a proven technique that has passed the test of actual implementation. The presentation will review the biological, production and economic aspects of the technique through the revitalisation of the Joutel site.

May 1, 2011

By Thom Sedun

No sector of the mining industry is more closely tied to local communities than aggregates. Noise, dust, traffic, visuals aesthetics and environmental impacts all fall under the purview of neighbours, local governments and nongovernment organizations. It is no surprise that aggregate operations may not be welcome neighbors in many communities. In British Columbia (BC), the regulatory environment for aggregate operations includes a local component of municipal bylaws and land use-planning in addition to the usual suite of federal and provincial statutes that apply to its sister mining sectors. Additionally, under common law aggregate extraction is not considered to be a land use subject to land use zoning, and some aggregate processing activities can be regulated by zoning. Often traversing multiple local government jurisdictions, aggregate producers find themselves negotiating not only local traffic, but also a mosaic of regulatory environments. There is an opportunity in this present situation to facilitate the application of current technology and practices in the mitigation of many community and environmental concerns associated with aggregate operations. Moving a bulk commodity is a volume-based business, and operators often don?t have time for matters that don?t directly or obviously affect the bottom line. Regulatory agencies often play multiple and complex roles with respect to their industry, not the least of which is the fiduciary role. Balancing how and when to assist an industry is often a difficult decision. For the aggregate industry in BC, the Ministry of Energy and Mines saw an opportunity to assist not only aggregate operators, but also regulatory agencies, local governments, and the general public. Through investing in the Aggregate Operators Best Management Practices Handbook (handbook) project, the Ministry of Energy and Mines (MEM) believes that it will realize a return of upheld community values, enhanced environmental protection, improved regulatory compliance, reduce disputes and a stronger provincial aggregate industry. It is the intent to publish the handbook electronically through the MEM website later this year.

May 1, 2002

By Michael R. Brown

A facilities success or failure of doing well during a regulatory inspection is typically measured by the number and type of citations that result, and financial liability resulting from those citations. The success of a facility during an inspection depends on several factors including, the preparation prior to an inspection, behavior and activities during and inspection, and finally, action taken following the inspection. This paper contains suggestions for improving inspection results and establishing an attitude of compliance at manufacturing and mining facilities.

May 1, 2002

By Ross Nairn

"Tulawaka Mine is a joint venture between Pangea Minerals Limited 70% (a wholly-owned subsidiary of Barrick Gold Corporation) and Northern Mining 30%. Tulawaka Mine is located in North West of Tanzania in the Lake Victoria Goldfields. Tulawaka Mine is scheduled to process 360,000 tonnes per year at an average 11.5 g/t head grade over a 4 year mine life.The Tulawaka Process Plant uses single stage crushing, single stage SAG milling, gravity, intensive leach of gravity concentrates, CIL, Zadra desorption and cyanide detoxification to process the ore. Gold recovery exceeds (or is expected to) 95%.The Process Plant was designed and constructed under the supervision of Ausenco Engineering of Australia. Site works commenced in January 2004, Process Plant construction commenced in July 2004 and the first ore was presented to the Process Plant 26th February 2005. The first gold was poured on 15th March 2005. All construction contractors were demobilized from site 7th April 2005. Major achievements have been 3.4 million hrs LTI free during construction and operation to date, training of the Tanzanian workforce at Bulyanhulu Mine prior to commissioning, a succession plan to replace expatriate personnel with Tanzanian staff and significant over performance of the Process Plant against design.INTRODUCTIONTulawaka Mine is situated approximately 160 km south west of Mwanza in the western Lake Victoria Goldfields District of north western Tanzania. The property is held under a joint venture between Pangea Goldfields Inc (70%), a wholly owned subsidiary of Barrick Gold Corporation, and Explorations Minieres Du Nord Ltée (30%). A location map showing the position of the operation in Tanzania is shown in Figure 1.Mine site staff at Tulawaka comprises a combination of Tanzanian and Expatriate personnel. All Pangea personnel live on site and commute to their place of residence for their R&R on a 9 weeks on 4 weeks off roster."

Jan 1, 2006

By B. Roy

The Somita plant processes low sulphide gold ore in Burkina Faso with a CIL process. After experiencing recurrent low gold recoveries, Somita undertook an investigation on the source of the problem. COREM conducted a mineralogical study on different pit samples. A series of tests was also conducted on a composite sample from the plant which shows a content of 3.4 g/t in gold and 0.48 % in graphite. A reference test in laboratory resulted in a recovery of gold of 75%, similar to plant recoveries for the evaluated ore. In these tests, even if cyanide is not deficient, it was diverted mainly into iron cyanide complex, copper cyanide complexes and by graphite adsorption. Causes of low recovery were also identified and quantified. Solutions to increase gold recovery were suggested such as increasing gold dissolution kinetics by O2 or by lead nitrate addition, change in activated carbon addition point location to the 1st cyanidation tank and finer grinding to increase liberation. Increase in the pH could also contribute to reduce cyanidation consumption. Following these recommendations, Somita changed carbon addition from tank 2 to tank 1 in the CIL circuit. This change led to an increase of more than 5% in gold recovery. A system for the addition of lead nitrate is also under implementation at the plant and benefit will be evaluated in 2013. Finally, pit management for cyanidation will be done based on mineralogy instead of gold content in the future.

Jan 1, 2014

By S. A. H Tyrrell, R. Rotzinger

"Taseko Mines Limited recommenced operation of the Gibraltar copper-molybdenum mine in 2004 and embarked on series of development projects to modernize the mine and increase throughput capacity. The Gibraltar Development Plan 3 (GDP3) project included a second stand-alone copper-molybdenum concentrator, a stand-alone molybdenum separation plant and associated services. Ausenco was contracted to commence the detailed design in 2Q2011, commissioning commenced in 4Q2012 and first ore was processed in 1Q2013. This paper discusses the design, implementation and commissioning of the GDP3 Concentrator.INTRODUCTION The Gibraltar Mine (Gibraltar) property is located in the Cariboo Region of south central British Columbia, approximately 360 kilometers northeast of Vancouver. The site is accessed via an 18 kilometer paved road from the town of McLeese Lake, which is located on the province’s main north-south highway between the cities of Williams Lake and Quesnel. Gibraltar was originally developed by Placer Development and commenced production in 1972. Gibraltar was acquired, while on care and maintenance, by Taseko Mines Limited (Taseko) in 1999 during a period of unusually low metal prices. Taseko recommenced operations at Gibraltar in 2004, and embarked on series of development projects to modernize the mine and increase throughput capacity. The 1972 Gibraltar process flowsheet incorporated two-stage crushing followed by rod and ball milling and flotation. In 2008 Gibraltar completed their first development stage that included the installation of a SAG mill, converting the existing rod mills to ball mills and adding additional flotation capacity. Gibraltar continued development with the installation of an in-pit primary crusher, expansion of the bulk regrind circuit, expansion of the cleaner flotation circuit, replacement of the tailings pumping system and replacement of the concentrate filters and dryer."

Jan 1, 2014

By K. Morin

"Silver and gold leaching by cyanidation is a well-known process used around the world. This reaction is often accompanied by the leaching of other species throughtout the cyanidation circuit that causes the diversion of cyanide towards non valuable by-products (SCN-, Cu(CN)x, Fe(CN)x, etc.). One of the detrimental impacts of the formation of these by-products is the precipitation of silver-cyanide complexes that occurs when cyanide concentration is too low. Without any extra-addition of free cyanide, the precipitated silver is lost and cannot be recovered causing an important economic loss. To overcome silver precipitation, cyanidation circuits are often operated at higher cyanide concentrations. Recently, COREM’s research team has been working on a technology to measure and control silver precipitation during the cyanidation process. Moreover, a methodology has been elaborated in order to evaluate threshold cyanide level which corresponds to the cyanide concentration at which silver starts to precipitate. This technology has been tested on site on a real cyanidation circuit at Agnico Eagle’s LaRonde mine."

Jan 1, 2014

By John Frostiak, Lloyd Buckingham, Kenneth G. Thomas, Luis Wilson

"The El Indio roasting facility associated with El Indio Mine in Central Chile has operated since 1981. It is a facility developed to remove arsenic and antimony from gold bearing enargite/pyrite flotation concentrates.The three installed roasters are Nichols Herreschoff units each with 14 hearths and measuring 4.85 metres diameter. Hearths are rabbled by central shaft driven rabble arms. Product is progressively heated to 750°C under neutral to reducing atmospheric conditions to drive off labile sulphur, arsenic and antimony.Ancillary equipment includes skip hoist feed arrangements, water cooled screw conveyors for transporting and cooling calcine, gas cyclones, post combustion chambers, heat exchangers, electrostatic precipitators, bag houses, gas scrubbers and packaging facilities .Operating practices, history, mineralogy and results are reviewed. The improvements to arsenic and antimony extraction, ambiental conditions and environmental achievements are discussed.INTRODUCTIONHistoryThe El Indio property lies in the El Indio belt, a copper, gold and silver area approximately 175 km long by 10 km wide. The property is located in the Andes Mountains of the central part of Chile at latitude 30"" South and 160 km from the sea-side city of La Serena. Plant location is at 3850 meters above sea level.The property currently consists of two underground mines feeding the El Indio plant and an open pit feeding the newer Tambo leach plant. The property has been controlled by a succession of owners (St. Joe Minerals, Fluor, Bond Gold International and Lac Minerals Ltd.) before acquisition by Barrick Gold Corporation in 1994."

Jan 1, 1999