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By J. -P. Tshibangu, M. Ramos da Silva, F. Descamps, C. Schroeder, J. -C. Verbrugge

"The mechanical behaviour of rock materials is largely influenced by the stress state and pore pressure; this needs to be considered in many applications, such as petroleum engineering, tunnelling or stability of underground excavations.Conventional triaxial tests (d2 = d 3) are generally used to assess the influence of confining and pore pressure. In this work, those tests are performed on a porous rock named Sorcy limestone, along with more advanced stress paths like triaxial extension (d 2 = d 1) and purely deviatoric tests with independent pore pressure control. Those tests are combined to a true triaxial study on the dry rock in order to investigate the effect of true triaxial stresses and, hence, build three-dimensional limiting envelopes accounting for the influence of pore pressure.Three-dimensional limiting envelopes of dry Sorcy limestone are built in meridian and octahedral planes. The shape of the octahedral sections changes with the mean stress from triangular to hexagonal and then quasi circular. At even higher mean stresses, the evolution continues towards a triangle with apexes oriented in the direction of triaxial extension stress states. In meridian sections, the deviatoric stress first increases with the mean stress. The transition between this deviatoric mechanism and the cap surface occurs at different mean pressures depending on the Lode angle.Terzaghi’s effective stress is found to govern the yield and plastic behaviour of saturated Sorcy limestone. Triaxial tests show that the limiting envelope does not depend on the loading path (conventional compression and purely deviatoric stress paths). In triaxial extension, the brittle-ductile transition is observed for a higher mean pressure than in triaxial compression, as previously found for true triaxial tests on the dry rock.Finally, it is shown that upon appropriate normalisation, the dry and saturated yield envelopes come very close one to each other. This suggests that only the size of the yield envelope changes between dry and saturated state (pore pressure = 5 MPa); its shape does not seem to evolve."

Jan 1, 2015

By M. C. Villeneuve, P. A. Siratovich

We present an integrated analysis of laboratory-based thermally induced fracturing and results of numerical models to give insight to the role of thermal shock fracture on geothermal reservoir rocks. Thermal stimulation is a reservoir permeability enhancement technique applied to commercial geothermal reservoir rocks to enhance fluid injection capabilities for spent power plant working fluids. The process is well known to enhance permeability but the thermodynamic and physical constraints of the process are less certain. In an attempt to constrain the interaction and the ideal conditions that lead to permeability enhancement, experimental procedures were carried out to mimic the conditions that a reservoir rock would experience during a thermal stimulation using temperature differentials ranging from 50-300°C. Samples underwent such thermal gradients under controlled laboratory conditions and were characterized for the changes to permeability, porosity, ultrasonic velocities, dynamic elastic moduli and petrological changes. The thermal stimulation was simulated in a FLAC2D thermal numerical model to investigate the nature of the thermally induced changes in the sample. The development of this model also allows us to investigate the relationship between geological characteristics and the ability to thermally stimulate any type of rock. The results indicate that numerical thermal shocking experiments are corroborated by laboratory-based results. The implication of this study is that the refined numerical models present an insight to the conditions and constraints under which thermal stimulation can prove to enhance permeability that could not be gained through purely laboratory-based studies.

Jan 1, 2015

By V. Nudo, R. del Villar, A. R. Laplante

"Fine iron ore recovery from the tails of Les Mines Quebec Cartier was investigated using Reichert trays and spirals. The effect of feed rate, density and splitter setting on the performance of rougher, cleaner and recleaner stages of a 2DS tray assembly was determined using 2- and 3- factorial experimental designs. The tray concentrate, assaying 27% Fe, was further upgraded by spiral to yield a concentrate assaying 55% Fe. Further laboratory scale testing showed this material to be easily upgraded to 65-66% Fe with high Fe recoveries.This paper presents the metallurgical results of the three tray stages. The model used to predict the performance of a full recovery circuit is then described. Simulation results are presented and their reliability assessed. Finally, an economic evaluation of the proposed scavenging circuit is summarized.INTRODUCTIONThe Mount Wright plant (UWP), located near Fermont, Quebec, processes daily 130,000-150,000 tonnes of iron ore assaying between 27 and 33% Fe, to upgrade it with three stages of 44.5 cm pitch GEC spirals to 66% Fe, while rejecting approximately 80,000 tonnes assaying between 6 and 11% Fe (1-3). Heavy liquid separation (at 3. 3 g/mL) of the plus 37 µm fraction (+400 mesh) of the tails reveals that a significant fraction of the iron is in the sink product, below 150 pm (100 mesh), as shown in Table 1. Also shown is the iron grade of the sink and float fractions. The high grade of the fine sink indicates that hematite ls well liberated below 105 µm (150 mesh), as previous studies have shown (4,5). The iron grade of the floats is very low in the fine size range, but increases with increasing size above 105 pm, because of incomplete liberation. Overall, two thirds of the plus 37 µm iron ls in the sink product, which constitutes less than 10% of the total tail."

Jan 1, 1987

By Roy O. Ifill, W. Charle Cooper, Alan H. Clark

"Queen’s UniversityIn representative, run-of-mine samples from the Panel and New Quirke mines of the Elliot Lake uranium district, Ontario, brannerite, ametamict uranous titanate, occurs in microscopic grain-aggregates which display wide variations, both in textural habit and in the relative proportions of brannerite, titania polymorphs and/or “uraniferous titania”. As is widely documented, much of the brannerite occurs as trellis-like arrays of laths and needles pseudomorphing rutile oranatase. In some cases, the laths and needles are cemented by coffinite. Brannerite, with an average composition of (U0.629Th0.039Ca0.20)(Ti2.199Fe0.13)O69contains =3 wt% Th and is distinctly Ti-rich relative to the ideal composition, UTi2O6. Much of the Si reporting consistently in electron microprobe analyses (between 1 wt%and 5 wt%) is tentatively attributed to contamination by the quartz-sericite matrix, and a minor proportion is attributed to the presence of coffinite intergrowths. “Uraniferous titania” (average par-tial composition by weight: 10.8% U, 0.3% Th,32.9% Ti) is considered to represent an intermediate stage in the conversion of titania to brannerite.The leaching behaviour of brannerite in its different modes of occurrence was studied qualitatively by the rotating-disc (polished section) method in H2SO4and HCl solutions at 25° to70°C. Redox potential was not measured. The progress of the dissolution of the individual brannerite crystallites and grain-aggregates was monitored by optical and scanning electron microscopes. Regardless of its morphology and texture (laths or needles, reticulate or blocky),brannerite is not readily leachable. Regardless of the process conditions, the rate-controlling step appears to be the initial leach-pit formation. These pits expand radially through the aggregate as leaching proceeds. This dissolution mode is independent of the relative amounts of brannerite and titania, i.e. the type of grain-aggregate. Secondary coffinite intergrowths are readily leachable and enhance the overall leaching kinetics of brannerite by accelerating leach-pit formation. These data provide, for the first time, information on the controls on the leaching of the uraniferous phases which dominate the lower-grade ores in the Elliot Lake district."

Jan 1, 1996

By K. MacMaster

"This paper deals with the history, development, present and future of the Employee Assistance Programs in place at the Inco Ltd. operations in Thompson, Manitoba. It should be noted that, although many similar programs exist in various industries and jurisdictions, these programs had to be fine-tuned to meet the needs of Inco employees, having in mind the helping professional resources available in Thompson and its geographic location. IntroductionIn the late 70s, many Canadian industries and the Canadian Labour Congress and their affiliates commenced discussions on the value of the Employee Assistance Program (E .A.P.) philosophy to both management and labour.In the contract signed between Inco Ltd., Manitoba Division and Local 6166, U.S.W .A. in 1981, a commitment was made to establish a joint E.A.P. for the hourly workforce in Thompson, Manitoba. With this background and sequence of events in mind, it is appropriate to explain the methodology and the steps that were taken for the implementation of the hourly program. Development of Hourly ProgramIt was agreed by the company and the union that the committee to develop the program should consist of equal numbers from both sides: three active union members plus an advisor representing the Union and three supervisory personnel plus an advisor representing the Company; in addition, a person familiar with E.A.P.s from the Alcoholism Foundation of Manitoba was to act as a facilitator. The Union appointed a social worker who was working as a counsellor for union members as their advisor , and the company appointed a staff employee who had worked voluntarily in the field of alcohol and drug abuse for many years. The makeup of the committee was extremely important in order to give credibility to the entire process. The makeup of the committee is shown in Table 1.The facilitator selected from the Alcoholism Foundation of Manitoba was well known in the community and highly respected in his profession."

Jan 1, 1989

"Sedimented hydrothermal precipitates of silica, now fine-grained quartz, are described from a Pb-Zn-bearing vein system. Their discrimination from the wall-accreted fine-grained quartz that is common in the shallow parts of epithermal systems is discussed. Local fine-grained (<0.3 mm) quartz accumulations occur in a suite of veins with otherwise normal drusiform and crustified infills. This sediment may fill the vein above chokes in steep segments (axial plugs), or form continuous layers within the footwall material where the vein is inclined at low to moderate angles. Pads of fine-grained sediment are deposited on the upwards-facing surfaces of wall-rock clasts and of drusiform crystals growing from the vein walls. The asymmetry of these deposits differentiates them from the more common symmetrical, crustified walllining deposits of fine-grained quartz and opaline silica, and requires a gravity-controlled, sedimentary depositional mechanism.Thin section examination shows that much of the fine-grained quartz is present as elongate prisms. The prism habit was present soon after deposition, but it is not possible to identify unequivocally the original sedimented grains. Sedimentation of vein- and wall-rock-derived detritus is also recognized. Deposition of the fine-grained sediment accompanies normal in situ drusiform growth of quartz and other vein minerals. The mammilated and spherulitic textures associated with accretion of amorphous quartz are entirely absent from the Tyndrum veins with sedimented materials. The literature on modern hydrothermal waters and physical chemistry of silica precipitation shows that precipitates of silica suspended in hydrothermal fluids are amorphous and derived from colloidal silica. It is argued that much of the suspended silica was present as quartz at the time of deposition or was converted from amorphous silica almost immediately after deposition.Hydrothermal sediments and their distribution potentially provide information on flow directions and velocity in veins. Plugs of sediment obstruct vertical flow and lead to local flows with large horizontal components. It is shown that sedimentation features occur in other deposits and can involve other minerals. If the features seen here can be scaled up to the size of major veins, they may result in up and downdip variations in mineral assemblages and abundances, which may affect grade."

Jan 1, 2007

By Peter J. Franklin

"Short-term mine planning of open pits is an activity that has historically been carried out by hand. Typically, the use of computers has played little part in this type of mine planning. This paper describes the objectives and the procedures involved in short-term mine planning, comments on the type of computer systems available, and describes in detail a computer-aided short-term planning and scheduling system known as STEPS.IntroductionThe mine planning department of any o pen-pit mining operation performs a wide variety of different tasks. However, their primary concern is the preparation of detailed long-and short-term mine plans. These mine plan s will define the long-term operating strategies and definitive everyday working plan s for the ongoing development of the open pit.In this day and age, when operating costs have spiralled upwards due to inflation , and product revenues have decreased due to depressed economies and poor markets, it is vitally important for all aspects of the mining operation, including mine planning, to be efficient and cost effective.There are numerous options available for planning engineers when generating a mine plan. A cost effective mine plan must investigate all these options and select the optimum. When using manual planning techniques, it is often impossible to evaluate all the available options. To do this, and to produce an optimum mine plan, a computer is required.This paper discusses mine planning, with emphasis toward the short-term plan and comments on how the processes may be computerized. It also describes in detail, a computer software system called STEPS, which has been designed as an interactive graphics, computer-aided short -term mine planning and scheduling tool."

Jan 1, 1985

By H. Matsuoka, M. Kawata, K. Mitsuhashi, C. Tokoro, T. Kato

Copper sulfide minerals such as chalcocite, bornite, and chalcopyrite exhibit high floatability, thus they can be recovered as a froth product by adding only a collector in flotation process. However, when their surface is oxidized, the floatability decreases and the simple addition of collectors is no longer effective. In this case, flotation activators are required to improve the floatability. Sodium hydrosulfide (NaHS) acts as an activator for chalcocite and bornite by re-sulfurizing their oxidized surface portions. Nevertheless, the flotation conditions still require optimization in order to achieve a satisfactory recovery of copper minerals. This work addresses the study of the effect of pH and NaHS dosage on the flotation of a complex Chilean copper ore containing chalcocite, bornite, and chalcopyrite. Flotation experiments were conducted using a Denver-type flotation cell and by investigating the effect of two NaHS dosages (50, 100 g/t) and three pH values (8, 9, 10). Following this process, the surface interaction between the minerals and NaHS were analyzed using zeta potential measurements. INTRODUCTION In recent years in the mining area of metal resources, the complexity of ores and the fineness of grind required to liberate minerals have become serious problems. When ores are complex, several valuable minerals may interact with each other and reactions may become more complicated compared with an ore containing only one valuable mineral. Therefore, more processing steps may be required than for a simple ore. When the valuable minerals exist as fine grains, it is difficult to liberate them and more grinding time is required. Furthermore, the probability of collision of fine particles with bubbles in the flotation process declines and it takes much time to recover them. Flotation is one of the most applied methods to separate valuable minerals from unwanted ones using the difference of hydrophobicity (or hydrophilicity). In the flotation method, the air is fed to a cell filled with the pulp of the mineral of interest and agitation is implemented to introduce air and generate bubbles. The hydrophobic particles attach themselves to the bubbles and float along with the bubbles while the hydrophilic particles remain in the pulp. Copper sulfide minerals such as chalcocite (Cu2S), bornite (Cu5FeS4), chalcopyrite (CuFeS2) are widely known abundant copper resources. Generally, flotation is used to recover and concentrate these minerals. Copper sulfide minerals usually have high floatability. However when their surfaces are oxidized, their floatability becomes lower. When the sulfide surfaces are oxidized, activators are added before flotation to modify the surface property of the Copper sulfide minerals so that they can be floated. Sodium hydrosulfide, NaHS, is known as one of the activators. Zhao (2018) reported that NaHS is often used as a sulfurizer for oxidized sulfide minerals (Becker (2014), Clark (2000), Newell (2006), and Newell (2007)). In earlier work, the authors performed flotation tests on a sample of Chilean copper ore which contained chalcocite, bornite, and chalcopyrite using a Denver-type flotation apparatus. The sample was ground to P80 70 µm with a rod mill and ball mill. In these tests, the following conditions were used: natural pH (about pH 8.5), flotation time of 45 min, 60 g/t AP3477 (sodium diisobutyl dithiophosphate) as collector, and MIBC (methyl isobutyl carbinol) at appropriate dosage as frother. NaHS was applied at the dosage of 0, 67, and 120 g/t, respectively at the conditioning. The concentrates were collected at 6, 18, 30, and 45 min. The weights of the concentrates and tailing were measured and they were assayed for copper by ICP-AES (Optima 5300 DV, PerkinElmer Inc.). The flotation recoveries of the copper minerals were calculated from the results of MLA (mineral liberation analyser) (MLA 650, FEI) measurements.

Jan 1, 2019

By Tony Lipiec, Ian Orford

"A key part of plant design is the selection of the design tonnage which is the hourly tonnage target that the equipment selection is based on. Its selection is critical for ensuring that the nominal tonnage which is critical to the financial performance of the project will be met. With deposits being developed at lower grades, higher tonnages and a higher degree of hardness variability, it is essential to ensure that the design process selects the comminution equipment which will be able to deal with the impact of this ore quality variation.Ore hardness and its variance are key factors to be taken into consideration for the selection of the design tonnage. It is well accepted that for the nominal or name plate tonnage to be consistently achieved, it is necessary to base the design tonnage on a hardness value greater than the average ore hardness of the deposit to be mined. The question is how much greater should this design value be to ensure that the nominal tonnage is met to the satisfaction of the project financial model. Standard industry practice is to set the design tonnage by:1. Select an ore hardness percentile that is greater than the average ore hardness to be the basis of the nominal tonnage. Typically either the 75th or 80th percentile value from the data set will be selected.2. Selection of a design factor to multiply by for determining the design tonnage, i.e. the design tonnage = tonnage (based on the average ore hardness) multiplied by design factor.This paper discusses the selection of the design ore hardness through the use of modelling or the use of a design factor. It further shows the impact of ore hardness variance on the capacity of the process and its ability to meet the nominal tonnage. Insight is provided as to what ore hardness percentile value should be selected balancing the shortfalls of tonnage for ores harder than the design value versus the above target production achieved for ores softer than the design ore hardness."

Jan 1, 2016

By K. Adham, T. Buchholz

"Significant capacity increases to meet new production demands can often be fulfilled through debottlenecking of an existing production facility, rather than the more expensive option of building new plants and facing new environmental and infrastructure challenges. To achieve that goal, it is important to model and calculate the existing ultimate capacity of each processing plant area, and that of each key equipment sector within the plant areas. This paper describes a methodology of how process modeling tools can be used to simulate the processing steps, how to estimate their existing and ultimate capacities, and how to determine the sweet-spots (minimum cost points) for a plant expansion – leading to a road map of the subsequent debottlenecking project implementation.The debottlenecking technique is presented through a generic work-flow narrative which can be applied to different mineral processing studies, starting with establishment of heat-and-mass balances, drawing a bottleneck diagram, brainstorming capacity increase options, and preparing a cost-capacity curve. Hatch has successfully applied this technique to a number of plant capacity studies, with great benefits to our industrial clients.INTRODUCTIONWith the softening of the metals and minerals prices, and the escalated costs of building new processing plants, it is now economically more viable to improve and debottleneck the existing facilities, rather than build new ones. However, spending new money on old plants requires careful considerations, in order to identify the most economically advantageous incremental steps of improvement and the best potential returns on investment. Process modeling, hand in hand with plant measurements, can identify the best scenarios to balance the three aspects of plant capacity (nameplate, utilization and yield), both at the global and the individual system and subsystem levels."

Jan 1, 2016

By F. Habashi

"Extractive metallurgy was divided into the three sectors pyro-, hydro-, and electrometallurgy in 1959 when Professor Joseph Newton at the Idaho School of Mines in Moscow mentioned this in his book Extractive Metallurgy. Pioneer hydrometallurgists who built this discipline can be traced to the alchemists in the ninth century. It is now a mature subject of great importance in which pressure plays a vital role. Short biographies of some hydrometallurgists and the processes they invented are briefly outlined.INTRODUCTIONHydrometallurgy is the use of aqueous solutions to recover metals from ores. It is a relatively new discipline when compared with pyrometallurgy the use of fire to melt ores and recover metals which was practiced in ancient times. Hydrometallurgy can be traced to the time of alchemists whose concern was the transmutation of base metals into gold. Although alchemists did not succeed in their venture yet they described many reagents that are useful today. For example, they prepared sulfuric acid by distillation of iron vitriol, muriatic acid by distillation of sulfuric acid with salt, and nitric acid by reaction of sulfuric acid by reaction of sulfuric acid with salpeter. Jabir Ibn Hayyan the Muslim alchemist who lived in the ninth century (Figure 1) described aqua regia a mixture of nitric and hydrochloric acid that can dissolve gold although either acid has no action on gold. THE MIDDLE AGESIn the Middle Ages, it was reported that copper was recovered at Rio Tinto in Spain by allowing copper-containing pyrite to be exposed in piles to the action of air and rain. Copper sulfate solution obtained was treated with pieces of iron to precipitate metallic copper—a process that was called cementation. Georgius Agricola (1494–1555) (Figure 2) a medical doctor in Saxony who used to visit mines and smelters to examine miners and metal workers, described in his book De Re Metallica the parting of gold, i.e., separating of silver from gold by acids."

Jan 1, 2016

By Yan Germain, Université Laval, Bernard Dallaire, Jocelyn Bouchard, Peter Radziszewski, Gilles LeBlanc, Michelle Levesque, Nicolas Tremblay

"The comminution process is estimated to be only 1% efficient, resulting in waste energy dissipated as heat, noise, and vibration. Energy recovery from grinding circuits has not been implemented mainly because recovering heat from the surface of the grinding mill or from mill slurry can impede operation, increase maintenance requirements, and prolong plant shutdown time (and production). However, currently very little information is available in the public domain regarding the amount of waste energy and that potentially recoverable in the grinding circuit of a mineral processing plant. Availability of such information could drive innovation and improve decision-making regarding opportunities for waste energy recovery. The Canadian Mining Innovation Council (CMIC) has initiated a study with CanmetMINING and mining industry partners to develop a model to map the energy flows in grinding circuits and to quantify the potential for energy recovery. The paper outlines the underlying fundamentals and data requirements for use in the model and then focuses on quantifying the energy recovery potential of the semi-autogenous grinding and ball mill circuits at the Agnico Eagle Goldex Division. Results show that most of the electrical energy (over 75%) is used to heat the slurry, leaving only a relatively small amount of it to achieve mechanical work (~9%). INTRODUCTIONCanmetMINING commissioned a study in 2013 to better understand the barriers for adoption of new technologies in the mining industry (MNP, 2013). The conclusions highlighted the importance of enhancing industry/regulator engagement and communication to raise awareness and improve the industry’s comfort level with new technologies.In November 2014, the Green Mining Innovation Advisory Committee (GMIAC) held a workshop to explore the possibility of accelerating the uptake of green mining technologies by bringing together key stakeholders among the mining value chain to address industry priorities. Participants included representatives from mining companies and associations, academia, provincial governments and federal departments and organizations. Two key priority areas emerged at the workshop: i) energy saving, and ii) water management."

Jan 1, 2016

By L. Nastac, Y. Xuan

"The metal-matrix-nano-composite (MMNCs) in this research work consists of an A356 alloy matrix reinforced with 1.0 wt. % SiC 50 nm diameter nanoparticles that can be dispersed within the molten alloy matrix via ultrasonic stirring technology (UST) and induction melting and stirring processing. The necessary ultrasonic parameters to achieve the essential cavitation for adequate degassing and refining of the A356 alloy as well as the optimum fluid flow characteristics for uniform dispersion of the nanoparticles into the A356 alloy matrix have been investigated in this study by using computational fluid dynamics (CFD) modeling with a magneto-hydro-dynamics (MHD) model and an UST cavitation model.The MHD model accounts for turbulent fluid flow, heat transfer and solidification, electromagnetic field as well as the complex interactions between the solidifying alloy and nanoparticles by using ANSYS Maxwell and ANSYS Fluent Dense Discrete Phase Model (DDPM) and a particle engulfment and pushing (PEP) model.INTRODUCTIONAluminum matrix nanocomposites can offer outstanding properties, including low density, high specific strength, high specific stiffness, excellent wear resistance and controllable expansion coefficient, which make them attractive for numerous applications in aerospace, automobile, and military industries field (Bozic, 2010, De Cicco, 2009, Elshalakany, 2014, Goh, 2006, Jia, 2013 and 2015, Liu, 2014, Reihani, 2006, and Su, 2010).As shown in literatures (Aki, 1999 and Mussert, 2002), it is highly advantageous to use nano-sized ceramic particles to produce metal matrix nano-composites (MMNCs) since similar ductility and higher strength with the metal matrix can be achieved. Currently, there are several fabrication methods of MMNCs, including mechanical alloying with high energy milling (Chen, 1997) , ball milling (Filho, 2003), nano-sintering (Groza, 1999), spray deposition, electrical plating, sol-gel synthesis, laser deposition, etc. The mixing of nano-sized ceramic particles is normally lengthy, expensive, and energy consuming.Ultrasonic Stirring Technology (UST) has been extensively used in purifying, degassing, and refinement of metallic melt (Jian, 2005, Khalifa, 2008, Eskin, 2002, Xu, 2004, and Meek, 2006) mainly because introducing the ultrasonic energy into a liquid will induce nonlinear effects such as cavitation and acoustic streaming. SiC nanoparticles are widely used as reinforcement particles due to their relatively good thermal and chemical stability. Ultrasonic vibration can improve the wettability between the reinforced nanoparticles and the metal matrix (Lan, 2004, Cao, 2008, and Yan, 2011), which will assist to distribute the nanoparticles more uniformly into the metal matrix. Ultrasonic cavitation in liquids causes high speed liquid jets of up to 1000 km/h. Such jets press liquid at high pressure between the particles and separate them from each other (Hielscher, 2005)."

Jan 1, 2016

By Peter Clevenstine

Minnesota Iron Ore Trifecta 1. World Demand 2. Industry Consolidation 3. Competitive Advantages

May 1, 2011

By P. I. Laforest, M. S. Moats

"Antimony in smelted copper anodes has been shown to cause problems in electrorefining including brittleness of starter sheets. In order to improve deposit properties, a study was conducted examining the effect of anode chemistry on cathode ductility and electrolyte chemistry. Two industrial anodes with different molar ratios of As/(Sb+Bi) were used in laboratory electrorefining experiments with commercial electrolyte, and the addition of commercial glue and Avitone. The ductility of 21-hr copper deposits was evaluated by a 180° bend test. X-ray diffraction (XRD) and metallography were performed on unbent specimens to characterize the deposit structure. Increasing the anode As/(Sb+Bi) molar ratio from 0.54 to 3.8 resulted in an increase, on average, from four to eight bends to failure in cathode material produced. Significantly lower concentration of antimony (V) in the electrolyte was detected when operating with the higher molar ratio anode. The presence of (111) and (200) planes was noted in cathode material produced from the higher molar ratio anode suggesting that mixed growth character could be responsible for the observed increase in bend test results. The ductility of the starter sheet materials was improved by a higher anode molar ratio.INTRODUCTIONThe presence of antimony in copper electrorefining electrolyte has been reported to cause problems in cathode production (Hiskey, 2012; Peng, Zheng & Chen, 2012; Wang, Chen, Zhou-Lan & Lian-Sheng, 2006; Wang, Chen, Zhou-Lan, Wang, Xiao & Zhang, 2010; Wang, Chen, Zhou-Lan, Wang, Xiao & Tang, 2011; Wesstrom, 2014). To better understand the impact of antimony, laboratory scale electrorefining experiments were conducted using industrial inputs (anodes, cathodes and electrolyte). The influences of anode chemistry on the valences of antimony and arsenic in the electrolyte were monitored and correlated to physical cathode characteristics, such as a bend test to failure and crystallographic orientation.Commercially, starter sheets are produced by electrorefining impure cast copper anodes onto titanium blanks. The starter sheets are then hung in an electrorefining or electrowinning cell using loops of bent starter sheet material. These loops, in the absence of sufficient ductility, fail resulting in cathodes falling into the electrolysis cells. It is thought that the reduction in ductility can be related to anode composition; in particular, the molar ratio of arsenic to antimony plus bismuth As/(Sb+Bi). It has been stated that maintaining this ratio above 2:1 results in numerous improvements to electrorefining operations (Baltazar, Claessens & Thiriar, 1987; Kamath, Mitra, Radhakrishnan & Shetty, 2003; Krusmark, Young & Faro, 1995; Noguchi, Itoh & Nakamura, 1995; Wenzl, 2008)."

Jan 1, 2016

By Bhawani Singh, Mahendra Singh, N. K. C Samadhiya

"Inherently anisotropic rocks occur in abundance at many rock engineering project sites in Himalayan region. These rocks pose difficulty in analysis and design due to their direction dependent strength behaviour. Moreover the strength varies in a non-linear manner with confining pressure. Mohr- Coulomb strength criterion is widely used by geotechnical engineers for defining strength of rocks subjected to given confining pressure. However, the conventional Mohr-Coulomb (MC) criterion suffers from the limitation that the strength is treated to be linearly dependent on confining pressure. In the present article, the MC criterion has been modified by incorporating non-linear term while retaining the original parameters c and ?. The non-linearity with confining stress level has been imbibed through critical state concept (Barton, 1976). The criterion has been applied to a triaxial test data base comprising of more than 1140 triaxial tests conducted world-wide on anisotropic rocks. Statistical evaluation of the goodness of fit of the proposed criterion to the data-base has been carried out. Further the predictive capabilities have been evaluated by determining the error in estimation of triaxial strength if only few triaxial test data are available for determining the criterion parameters. The data base has also been back-analysed to assess the critical confining pressure for anisotropic rocks. Statistically the critical confining pressure, for the present criterion, may be taken nearly equal to 1.25?cmax, where ?cmax is the maximum value of the UCS out of all orientations of planes of anisotropy. It is concluded that reasonably good estimates of the anisotropic strength are possible through the proposed criterion.INTRODUCTIONMany rocks encountered in Himalayan region like shale, slate, schist and phyllite are inherently anisotropic and exhibit direction dependency in their strength behaviour. In addition, the strength of the rock also depends on the confining pressure and, the strength response is non-linear especially when the confining pressure may vary over large range. Conventionally, Mohr-Coulomb criterion is the most widely used criterion for rocks. However, the limitation of this criterion in its present form is that the strength is treated to be linearly dependent on the confining pressure. The present study attempts to address the following two main objectives: i) Include nonlinear response in the Mohr-Coulomb criterion while retaining parameters c and In their original form; and ii) consider anisotropic response of the rock for a given confining pressure. A nonlinear strength criterion, which uses shear strength parameters c and as per Mohr-Coulomb criterion, has been suggested based on critical state concept for rocks."

Jan 1, 2015

By J. E. Hawley

"IntroductionA STUDY of the trace elements in the ash •of coals from nine seams in the Sydney coalfield, Nova Scotia, was undertaken at the suggestion of Dr. W. A. Bell, Geological Survey of Canada, as a part of a larger study of these and other Nova Scotia coals being made by the Geological Survey and the Nova Scotia Department of Mines under the direction of Dr. P. A. Hacquebard.The main purpose of this investigation has been to •determine if a knowledge of the trace element distribution might be of assistance in the recognition of individual seams, the distinction of which is not always easy or positive in folded and faulted strata by ordinary stratigraphic and structural means.The study has been so conducted as to afford information on the variation of trace elements in individual petrographic intervals or divisions in each of the seams examined, intervals determined by Dr. Hacquebard on the basis of their banded ingredients, vitrain, clarain, durain, fusain, etc, as observed under the microscope in polished sections. The results, as well, indicate the trace element composition of the coals of the area as a whole, and quantitative data for fifteen elements are given, along with concentrations of thirteen other elements, stated in terms of intensity ratios. Data on distribution of germanium, though considered here along with other elements, are dealt with elsewhere*."

Jan 1, 1955

Reaction between xanthate ions in solution and oxidized compounds present on the surface of galena to form lead xanthate is considered to be a side reaction not contributing to flotation, although accounting for some consumption of reagent. The direct reaction of lead sulphide with xanthate and oxygen to form lead xanthate is the most significant to flotation. Coadsorntion of dixanthogen is also involved. Previous work has shown lead recovery in lead rougher flotation to be a function of m [H+] where: m = concentration of xanthate in solution rHl = hydrogen ion concentration. A plausible explanation for this relationship is suggest-ed. Likewise, the experimental findings that the amount of xanthate adsorbed under certain conditions is a function of m&apos;[H+] are explained in terms of reaction between xanthate ions and soluble basic lead salts such as PbO.PbS04? It is also shown that m[H+] should have a constant value in lead cleaners operating at a higher pH than the roughers. This conclusion is confirmed by plant data, and the value of the constant agrees well with the calculated value. The finding is useful in mill control.

Jan 1, 1965

By Henrik Saxén, Mikko Helle

The operation of hot stoves used for preheating the blast in the ironmaking blast furnace has a strong effect on the consumption of reductants, economic performance of and CO2 emissions from the steelmaking site. Generally, it is recommended to maintain as high blast temperature as possible, because this minimizes the rate of reductants in the blast furnace. The blast temperature is affected in a complex way by the time periods of heating and cooling of the stoves, and by the amount of gas combusted in the stoves. Furthermore, as the hot stoves show degraded performance with age, it is a non-trivial task to select optimal operation parameters for the stoves. The paper addresses this computationally by applying a one-dimensional heat-transfer model of the hot stoves for optimization of the performance of the system. The complexity and strong coupling of the decision variables is demonstrated by numerical examples, where the blast temperature is maximized under different constraints.

Jan 1, 2015

By R. H. McMillan

A classification of important uranium deposits which utilizes both genetic and descriptive criteria is presented. The dual aspect is useful because, while the non-genetic nomenclature for the different deposit types is amenable to various interpretations, the critical characteristics of each deposit type can be analyzed to clarify various genetic points. Although the classification is intended primarily for Canadian uranium deposits, most of the important deposit types known elsewhere can be accommodated.

Jan 1, 1978