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By G. J. Desroches

"In order to improve zinc plant productivity, areas of low efficiency were identified. As a result, solution purification was improved, additional dust precipitator capacity was made available and a new zinc casting plant was installed. The effects of these and other changes are discussed and the expenditure and benefits reviewed. HistoryThe operation of the Flin Flon metallurgical complex including an electrolytic zinc plant commenced in October 1930. The design of the zinc plant was based on that of the Commonwealth Mining and Smelting Company at Trail, British Columbia, the Anaconda Great Falls Montana Plant and the Electrolytic Zinc Company plant at Risdon, Tasmania.The plant began with a design capacity of 60 tons per day and currently produces 255 tons per day. Since plant start-up, approximately 3.5 million ton s of zinc metal have been produced, most of it exceeding special high-grade specifications.IntroductionThe facility incorporates the basic process steps of roasting, leaching, purification, electrowinning and casting. Figure I details the flowsheet. During the late 1970s, management recognized that in order for the zinc plant to continue operating, it was necessary to introduce cost-effective practices.Study groups, consisting of design engineers and operations personnel, were formed to investigate the details of plant revisions.The objectives were to improve productivity by reducing manual labour, reducing energy usage, increasing zinc recovery, increasing metal output and reducing costs.This paper details the changes made during the period 1979to 1986 and shows how these changes have affected the productivity and economics of the zinc plant operation."

Jan 1, 1988

By Donald Roberts

"Parameters f or design and development of an emergency hoist system (Fig. I) were submitted to Timberland Equipment Limited of Woodstock, Ontario by the Potash Corporation of Saskatchewan Mining Limited.The unit is the first of its kind in Canada. Not only does it comply with the province of Saskatchewan's mining regulations, but has the added advantage of being completely mobile and self-contained.As well as being useful in the mining industry, the mobile hoist unit could be used in other emergency situations such as rescuing people trapped in wells.JustificationRevisions to the Mines Regulations under Section 13 of the Occupational Health and Safety Act, 1977, of the Province of Saskatchewan stipulate as follows:"" Section 410 .04(4) The Mine Employer shall make adequate provision at every mine where any worker is hoisted in a shaft not equipped with a manway to enable an y such worker trapped in a conveyance in the shaft to be rescued . "" It was not possible to equip the shafts at PCS Mining' s Divisions with "" manways"" and therefore an alternative was required.BackgroundThe Potash Corporation of Saskatchewan Mining Limited, a subsidiary of the Potash Corporation of Saskatchewan, operates four potash mines. Of these, three, Cory, Rocanville and Lanigan Divisions are wholly owned while the fourth, Allan Division, is 40% owned by Kidd Creek Mines Ltd., but managed by PCS Mining. The four underground operations all have a service and production shaft.From 1979 to 1981 the PCS Mining Division, along with Central Canada Potash, were developing an idea to use the existing ground-mounted timberland hoist at Lanigan as an emergency hoist. This hoist was used in the past for rope-up work at both Rocanville and Lanigan and other potash mine s. The Department of Labour at this time had concerns about the time it would take to load, t ran sport and re-install the hoist on a foundation when needed for an emergency. Weight and size made this particular unit very cumbersome for transporting.In addition, the speed at which this hoist operates is too slow for rescue work. When the Department of Labour expressed concern that this unit would be unsuitable for these rea sons, a search for a suitable unit was initiated.The project responsibility for procuring an emergency hoist for the Potash Corporation of Saskatchewan Mining Limited was assigned to the author, a shaft/ hoist specialist a t PCS Mining."

Jan 1, 1986

By F. Urekar, R. B. Pankhurst

"Air spaces and air gaps in an explosives column are known to allow greater distribution and cushioning of explosive energy from the rock mass. This energy distribution is enhanced if the explosives ' gases can be confined in the borehole for as long as possible by plugging and stemming above the air space.Power Plug is an inflatable plug which can seal a borehole at any point to separate the stemming from an air gap and explosive toe load.IntroductionThis paper will discussion-going work by C-I -L Inc. and operators of two open pit mines to study the results of using Power Plugs:I. Pit wall stability - the authors have found the Power Plug effective for wall control blasting in open pit mines.2. Selective mining of coal seams - the authors work shows the Power Plug allows mining selective coal seams by predrilling underseam waste wedges.Pit Wall StabilityWall stability in an open pit mine is essential for safety. Good wall stability can be achieved with wall control blasting techniques which cushion the effect s of the explosives charge by decoupling the charges from the borehole wall. The usual method of decoupling a charge in a large-diameter rotary borehole is to load the explosives in tubes (Fig .I) . We now believe the air deck system is effective in sea ling a borehole above the explosive charge to create an air deck within the borehole which will cushion the blast.In a linear decoupled charge, an air annulus surrounds the explosives charge and cushions the effects of detonation genera ted gases on the pit wall. In an air deck, i.e. with the hole plugged at the collar, the gases genera ted by an explosive toe load are sealed in the empty borehole column. After a period of time, these trapped gases produce radial cracking between holes along the entire length of the borehole.It is common practice to employ de coupled explosive charge columns in the borehole to limit blast damage to surrounding rock. The exact mechanism of energy transfer in such blasts, however, is not well understood. Interruption of the continuous explosive column in a borehole by means of stemming, or air decks, may also be viewed as another form of decoupled blast. Decoupling of the explosive charge from the borehole wall affects both explosive energy release and explosion pressure developed in the borehole."

Jan 1, 1988

By Yve Fourmanoit

"This paper discusses the exploitation of shallow underground deposits in a very altered geological environment. The methods, their adaptation to local conditions, their evolution, dilution control and recovery of mineral reserves will all be dealt with.The recovery of the B zone crown pillar under 40 m of till that was originally saturated with water, is of particular interest.Future underground development and production start-up of the A-2 zone, organization of mining operations, mechanical services, group incentives and safety practices will also be given.IntroductionThe underground deposit of B zone is not very deep. A 300 m shaft provides access to the mine. In addition , exploitation sublevels are developed every 20 m and are linked by a service ramp. The overburden located on top of the deposit is 40 m thick and is composed of a very dense till.A detailed work plan was initiated to permit mining under the overburden. To do so, it was imperative that efficient methods be developed. At a time when an accident at the Belmoral Mine shook the mining world , it was a task to convince provincial authorities that it was safe.While B zone was being mined , development began in the A-2 zone deposit which has recently been put into production (Figs. 1 and 2).The intention of this paper is to provide an outline of the mining method s and their particular aspects. To do so, some of the mine services are described and a brief outline of the under ground department is provided."

Jan 1, 1990

By P. Hanniala, S. Harkki, B. Andersson

"The Outokumpu Flash Smelting Process was put into commercial operation in 1949. The original process was based on the use of preheated air. The adoption of oxygen enrichment of the flash smelting process air in 1971 was a crucial improvement, especially for smelter capacity. Oxygen use according to the Outokumpu method means selection of the most suitable oxygen content for the process air on the basis of the concentrate composition, capacity and matte grade. The furnace is not bound to only one fixed degree of process air oxygen enrichment; the oxygen content may vary from 21% to 100%.The degree of oxygen enrichment and the matte grade are the most important process parameters in reducing the operating costs of the whole system, including smelting, converting and acid production. Raising the matte grade allows more efficient use of the reaction heat in the smelting stage. Sulphur is recovered in a high-strength, constant-flow gas stream. The blowing time in the converters is reduced considerably.Oxygen enrichment and high matte grade improve the energy efficiency of the plant complex as long as the surplus heat from the system is not wasted. When the operating costs and investment expenditure of the total plant complex are taken into account, a reasonably high degree of oxygen enrichment (35-80°/0) is the best alternative in practice. Existing operating smelters have achieved single-stream thoughputs of over one million t/yr of concentrates.HistoryLocal capital and operating costs as well as lower energy consumption per unit of metal produced are now the crucial factors in determining the choice of process. In the late I940s, the same reasons prompted Outokumpu to develop the original flash smelting process in Finland. Between 1900 and 1940, very few technical changes in pyrometallurgical copper production took place. However, the commercial use of the flash smelting technique began a new era in metal extraction from sulphide concentrates. The characteristic feature of the method is that the concentrate is smelted in suspension: this offers the most favourable conditions for heat and mass transfer, and thus high reaction velocities. Outokumpu was the first to exploit the known advantages of flash smelting in a commercial installation at Harjavalta in 1949."

Jan 1, 1982

By Ali M. Ghazi, Ronald J. Goble, Lowell S. Whiteside

"Geerite (Cu1.6S) is a rhombohedral copper sulphide which occurs naturally in epitactic replacement of sphalerite; cell dimensions closely approximate those of the host sphalerite.Geerite-type structures can be produced by leaching digenite (Cu1.8S) in ferric sulphate solutions. X -ray diffract ion and electron microprobe studies indicate that eight metastable geeritetype structures can be produced, depending upon the concentration of f erric sulphate solution used and the duration of the each. Although compositions cluster on or near values observed for natural phases, optical properties indicate that we are dealing with polymorphs of these phases. Leaching of chalcocite (CU2Sj in dilute f erric sulphate solutions produces similar results. In contrast, leaching of chalcocite in more concentrated solutions seems to produce true analogues of natural minerals.During froth flotation, sphalerite is activated with a monolayer of floatable copper sulphide with the composition, CuS, of the mineral covellite. However, covellite is not significantly more floatable than sphalerite, and has an incompatible structure because of the presence of covalently-bonded atoms of sulphur. Leaching ofdigenite was used to produce a polymorph of covellite with a geerite-type structure, compatible with that of sphalerite. This polymorph has a flotational behaviour similar to copper-activated sphalerite, suggesting that the monolayer has a geerite-type CuS structure. IntroductionIn an ideal close-packed sulphide structure the distance between sulphur layers, D, is equal to 2R 2/3, where R is the radius of the sulphur atoms. In sulphides with covalently-bonded sulphur layers, such as covellite (Fig. I), D will be an average of the number of covalentl y-bonded and close-packed sulphur layers, weighted as to the relative number of each type of layer. Both D and R are spacings which are readily identifiable structurally and on X-ray diffraction patterns. Goblel has shown that for copper-iron sulphides with metal-to-sulphur ratios between 0 and 2 and copper-to-total metal ratio s between 113 and I there are strong correlations between composition and measured D and R distances (Fig. 2). D can be represented by a single empirical equation relating interlayer spacing to composition; R must be represented by three equations relating the radius of sulphur atoms to composition. One of these equations (R, in Fig. 2) represents ideal close-packed behaviour, the other two represent sulphur radii greater than (R1) or less than (Rh) the ideal."

Jan 1, 1988

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May 1, 2006

By J. M. Goris

"Researchers at the U.S. Bureau of Mines are conducting research on cable-type ground supports to assess their material and support properties and to provide design criteria for implementing cable supports as a workable roof control system under various underground mining conditions. Much of this work involves laboratory assessment of the material and support properties of cable supports using both conventional and birdcage steel cables. Included in this assessment are single and double cables, effects of changes in embedment length on support strengths, water-cement ratios, use of breather tubes, and pumpability and water-bleeding properties of grouts.IntroductionSince cable supports were introduced in the early 1970s, considerable research has been conducted in laboratories and at mine sites to understand their behaviour. The U.S. Bureau of Mines began a laboratory evaluation project in 1985 at the Spokane Research Center (SRC) to study the behaviour of cables supports under uniaxial loads so that the effects of various cable support components, such as grout and breather tubes, could be identified. Other objectives were to compare the behaviour of various types of cables and grouts and to collect meaningful data for numerical analyses. Pull tests were conducted to determine how cables supports reacted under uniaxial loads and how they failed when ultimate loads were exceeded. Such data are essential for the development of numerical models for analyzing rock mass behaviour when the rock is supported with cables.Test ProgramBecause each cable support can be composed of either single or double cables as well as a breather tube, pull tests were designed to include a variety of samples containing these components. A series of samples containing a single conventional cable, a neat cement grout having a water-cement ratio of 0.45, and no chemical additives was selected as a standard (Table I). Then one component in the system, such as the presence of a breather tube, was changed, and results of tests compared to results obtained for the standard samples to determine what influence that component might have on the behaviour of the support system. If significant changes in test data occurred, they could be attributed to that one component. To control the quality of the samples, the physical condition of the cables and tubes were monitored closely, and compressive and tensile strengths as well as flow properties were determined for the grout used in each test series."

Jan 1, 1991

By Y. Prevost, D. Verhelst

"A computer-assisted process control system for the Noranda Process Reactor Wa5 installed at the Home smelter in 1991. Operating as an advisory tool for the furnace operators, and using a flexible oxygen balance as the basic building block of the computer program, the new control system has helped to reduce the variability in the grade of the matte produced by 50% . The smelter is currently operating at a 72% copper matte, with a standard deviation of between 1.0 and 1.3, while treating a wide range of concentrates, secondary materials and scrap. Enhanced process control has allowed for longer reactor campaigns, and improved stability of the converting operation.This paper reviews the feed classification and blending practice used at the smelter, outlines the strategy of the new computer control system, and summarizes the benefits realized since the implementation of the system in early 1990.IntroductionUntil 1989 the Noranda Home smelter operated as a multi furnace smelter, at one time having three hot-charge reverberatory furnaces, and finally operating with one wet-charge reverberatory furnace and one Noranda Process Reactor. In 1989 the final reverberatory furnace was closed and the Reactor became the sole smelting vessel, treating around 750 000 tonnes of concentrate, secondary materials, and scrap per year. At the time of the start-up of theNoranda Reactor in 1973, the vessel was capable of treating 750tonnes per day of a heterogeneous mixture of copper concentrates, fluxes and secondary materials to produce copper in one operation. Through process improvements, and the introduction of additional oxygen in 1982(pannell and Mackey, 1988), the daily tonnage increased to 1800 tonnes by 1988. The operation had also been changed to produce a high-grade matte instead of copper. Figure1 illustrates the main features of the reactor, a cylindrical vessel which is charged at one end and tapped at the other. The matteis subsequently processed through Peirce-Smith converters and anode furnaces before being cast into copper anodes. Figure 2 outlines the progressive increase in the furnace smelting capacity. Over this period the percentage of secondary materials, and scrap feeds also increased to approximately 110 000 tonnes per year, or 15% of the total new feed input (Bedard et al., 1991). Now operating wholly as a custom feed operation, the Home smelter can treat over 2200tonnes per day of new metal-bearing material."

Jan 1, 1993

By Joo Hyun Park, Hyun-Sik Park

"Gold is one of the most valuable and precious metals. But, the extraction efficiency of gold from natural resources is very low and labor-intensive due to very low concentration of gold, i.e.,1–5 ppm, which means that gold extraction processes produce extensive amounts of tailings. The gold content in printed circuit boards (PCB) from waste mobile phones is about 100 to 400 ppm, which is enormously greater than the concentration found in natural ores. Consequently, processes for recycling waste PCB and gold mine tailings become of increasing importance to maintain a sustainable society. As processing these waste materials by pyrometallurgical methods has become more economically attractive, understanding the thermodynamic behavior of gold in smelting slags under oxidizing and reducing conditions has become increasingly important. Therefore, in this study, the effects of slag chemistry, oxygen potential and temperature on gold solubility in smelting slags are discussed. From the results presented, the predominant species of gold is strongly dependent on the basicity of slag. Furthermore, more basic slags showed higher solubility of gold at a given oxygen partial pressure, and more oxidizing atmospheres enhanced the dissolution of gold to the molten slag phase. As a consequence, careful control of the slag composition during pyro-processing of gold-containing waste materials is required to maximize gold recovery. INTRODUCTIONGold has good physicochemical properties. Thus, it plays an increasingly important role in industrial applications. For example, over 300 tons of gold are used annually in electronic components (Hageluken &Corti, 2010).However, 75% of all gold ever produced has been extracted since 1910 and gold reserves in the world are becoming rapidly depleted (Louis & Pluchery, 2012).The cost of gold production and its price in the market have increased rapidly during last 20 years as shown in Figure 1, and interest in the recycling of gold-containing materials has naturally increased.The wastes from electronic equipment (e-wastes) contain large amounts of precious metals compared to their own respective ores, and therefore such wastes may be considered as a secondary source of valuable metals. For instance, the concentration of gold in natural ore is commonly 0.5–15 g/ton-ore (0.5–15 ppm), while its concentration in electronic circuit boards is over 10 times higher, typically being about 150 ppm in expansion cards and over 10,000 ppm in central processing units(Barbieri et al., 2010).Also, gold mine tailings are discharged after the flotation process as slurry form then stored near the operating plants (approx. 100 ton per day in one Korean gold mine). Gold mine tailings contain gold at about 1–2 g/ton. This is the reason why Au-containing materials such as e-wastes and mining wastes are highly important sources of gold (Yamasue et al., 2009)."

Jan 1, 2017

By M. M. Holgate

"Porosity neutron deflection scales can be derived more easily by cumulative correlation than by the conventional method of plotting corresponding points on a graph. The micro-log can be used as a porosity datum for the neutron log by transforming the permeability cut-off it shows to a porosity cut-off by a permeability-porosity function obtained from core analysis. Porosity footage values calculated in this manner from the neutron log are within 20 per cent of core analysis values."

Jan 1, 1960

By A. Romero

"Most underground mines require heating or cooling systems to meet health and safety standards in the working areas. In regions where daily or seasonal fluctuations of environmental conditions exist, these systems tend to be over-sized and operate at low average load factors, which increase both investment and operating costs. One possible approach to reduce the temperature variations of the fresh air supplied to the mine, and so reducing the investment in large heating or cooling systems, is to use rock as a thermal regenerator or thermal storage system. Packed rock beds act as thermal inertial units, damping the atmospheric temperature oscillations to provide a more constant fresh air temperature. However, although regenerators exist in some mines, and packed bed rocks have been studied in detail in solar thermal power applications, there is a lack of tools to design new and sufficiently large storage systems of this kind. This work fills the existing gap by presenting a methodology to design and evaluate the impact on the ventilation systems of these regenerators. The method is validated using existing rock bed systems found in the literature and illustrates possible designs for small and large size regenerators in both hot and cold climates.1 INTRODUCTION “ It is quite amazing how often answers to extremely complicated problems can be obtained in this way, by using greatly simplified models of the real situation for the purpose of calculation.” Whiller, A. in private communication to J. S. Stachulak (1989). Motivation Most underground mines located in regions with extreme climatic conditions require the thermal pre-treatment of the fresh ventilation airflows, whether for heating or cooling. Heating commonly is needed in sites with sub-zero temperatures and is usually effected by direct or indirect burning of natural gas or propane. Alternatively, cooling is required in areas with hot temperatures, or in mines with high underground thermal loads where the fresh air at ambient temperature cannot provide enough refrigeration. Thus, when the ambient air conditions cannot provide by itself enough thermal power to ensure safe underground working conditions, a heating or cooling plant is required, which involves a considerable equipment and operation cost."

Jan 1, 2019

By M. W. Grabinsky, B. D. Thompson

ABSTRACT: Use of cemented paste backfill (CPB) offers economic and environmental advantages over other backfill methods. However, many operations have limited knowledge of how their CPB behaves in situ. Therefore, to avoid over-pressuring containment barricades, backfilling strategies necessarily tend to be conservative. In situ monitoring at Barrick Gold Corporation’s Williams Mine and Inmet Mining Corporation’s Cayeli Mine has been conducted and factors controlling barricade pressures are demonstrated, including rise rates, binder content, stope geometry, and tailings properties. The application of barricade pressure monitoring on a stope-by-stope basis can increase backfilling efficiency and, thus, reduce stope cycle times, while maintaining optimal safety.

Jan 1, 2011

Red Chris Project Project Status ? Tahltan, Iskut First Nations MOU ? Bankable Feasibility Study ? BC Environmental Assessment Certificate ? CEAA (Federal Environmental) ? EPCM contracts LOI?s ? US$110 million Project Debt Financing(credit approval pending) ? 1st5 years concentrate production sold ? 99,150 m of drilling in 371 holes First Nations Participation Agreement ?Advanced stage negotiations

May 1, 2006

By M. Yao, D. Thibodeau

"Selective mining, such as post pillar cut and fill, is used in large, flat, irregularly shaped ore bodies where ground stability is to be maintained. This selective mining is used to open the stope to the full lateral extent of the ore body in order to minimize the dilution and maximise the recovery. For increased mining depth, design of the post pillar becomes more challenging since those pillars will eventually fail as mining progresses upwards. The post pillar should be designed such that failure does not occur at the early mining stage, such as at the first cut. After mining progresses upwards, the post pillars are expected to fail but be confined by backfill. In order to maximise ore recovery, both drift width and post pillar size must be designed adequately with a consideration of all geomechanic parameters. This paper will describe the process used to design post-pillar cut and fill for one of the ore bodies in Vale’s Copper Cliff Mine using a combination of both empirical deterministic and numerical modelling techniques. By utilizing both empirical deterministic and numerical modelling techniques drift width and post pillar size can be effectively designed. Current post pillar cut and fill design in the existing Vale operations are used to validate the design for Copper Cliff Mine. INTRODUCTIONCopper Cliff Mine is located within the Copper Cliff Offset in the limits of City of Greater Sudbury, Ontario, Canada, as shown in Figure 1. The Copper Cliff Offset extends about eight kilometres south from the Sudbury Igneous Complex into the footwall rocks. Until 2008, the current Copper Cliff Mine was operated as two separate mines i.e. North Mine and South Mine. However, as part of restructuring of Vale Ontario Operations, the North and South Mines were merged in 2009 to form the “Copper Cliff Mine”."

Jan 1, 2015

By D. A. Beck

The load-deformation response of discontinuous rock under static and dynamic loading conditions has been simulated using Explicit Finite Element models. The intent of the analysis was to investigate the effects of specimen size and confining stress on strength, dilation and comminution. The simulations allow the development of homogenised constitutive material properties for discontinuous rock masses using laboratory scale measurements and representative Discrete Fracture Networks (DFNs). A procedure for this is presented which includes a comparison of measured seismic response in a mine to the Dissipated Plastic Energy (DPE) that is released in the simulated rock masses. The models also show how confinement and scale affect the stress-strain and DPE response of the simulated rock specimens, reproducing a number of known rock phenomena that are often poorly captured in geotechnical modelling. A case study is presented showing a satisfactory match between the model-derived, homogenised material properties and values achieved by calibration of a mine-scale model where many thousands of seismic, displacement and damage measurements were available.

May 1, 2009

By Fred A. Curtis, Kathryn E. Moore

"The past 14 years have brought an increased awareness of environmental problems. Surface mining for mineral aggregates has been one o f the issues which ha s sparked fierce controversy and debate. Various level s of government, industry, and the public have engaged in an unending battle for adequate planning, regulation, and rehabilitation of pits and quarries. Agreement has seldom been reached and, as a result, few standards, guidelines or policies have been established, or enforced province-wide.Surface mining ca uses a number of environmental problems including noise, dust, water table disturbances, aesthetic degradation, increased traffic, and health and safety hazards. These problems are particularly serious in urbanizing area s, where people are exposed to the mining operations. Associated with the operational phase of surface mining are the issues generated by the multiplicity of abandoned pits and quarries which dot the countryside. These large, gaping, often dangerous waterfilled holes are a blight o n the landscape, and represent a misuse of land.The environmental problems connected with pit s and quarries are compounded by the fact that accessible reserves of mineral aggregates are being lost through the process o f urbanization. In addition, restrictive zoning at the municipal level is restricting access to even more aggregate rich land. This results in the paradox that the very urbanizing process which creates the demand for aggregates is rapidly reducing the available supply. These problems have stimulated the Ontario Ministry of Natural Resources to call for a province-wide program of inventory, assessment and planning for the protection o f high-quality reserves in Official Plans. These proposals have met with strong opposition from municipal leaders, who are jealously protecting their autonomy.Environmental management education is a prerequisite for all parties involved in pit and quarry planning, regulation or rehabilitation. To this end the following bibliography of selected articles with attention given to the Ontario experience, should provide helpful information on these topics."

Jan 1, 1985

By Marcio Luis S. Godoy

The Salobo Project will be the first Vale operation to use an HPGR mill to process copper-gold ore. The mine is located in Para state, southeast of the Amazon region in Brazil. The circuit was designed to treat 12 million metric tons per year of finely disseminated sulphide ore with high hardness. The comminution circuit comprises a gyratory primary crusher, secondary crushing utilizing two cone crushers, two 2 x 1.5 m HPGR operating in closed configuration with 6 mm screens, followed by two 26 x 40 ft ball mills. The concentration circuit consists of two rougher flotation stages using mechanical cells, regrinding with vertical mills, three cleaner stages with columns and one cleaner scavenger stage in mechanical cells. The concentrate is dewatered, filtered and transported by trucks and train to the port, to be exported. The circuit was designed on the basis of data obtained from a comprehensive laboratory and pilot plant campaign. The ore variability was assessed through simulation using data from a drilling core characterization program. The start-up of the industrial plant is planned for 2011. This paper describes the main aspects of circuit design, as well as information related to the beginning of the project construction.

May 1, 2010

By D. B. Dreisinger, M. Rasouli

"Developing technology to address the environmental hazards associated with selenium in mine-impacted waters has been a serious challenge. Ion exchange (IX) has been identified as a potential treatment technology. This paper begins with a review on selenium adsorption with commercially-available basic anionic exchangers (BAS). It then looks at the use of resins for selenium removal via modification with the addition of -O, -N, or -S-containing chelating ligands and chelating polymeric ion exchangers pre-loaded with immobilized metal cations. The synthesis of chelating exchangers requires a final product with a highly stable metal in the ligand-metal complex. The nature, oxidation state, size, and affinity of the metal for the target oxyanions and the size, degree of protonation and space configuration of the oxyanion are among critical factors affecting the oxyanion uptake. There is a limited number of studies on the critical parameters affecting the selenium affinity for chelating exchangers. Such a study could fill in the gaps of our understanding of selenium-metal-chelating ligand interactions and assist in developing a new ion exchanger. In addition to commercial IX resins, layered double hydroxide materials (LDH) have received attention for oxyanion removal from waste water. The adsorption capacity of the LDHs are affected by the crystallinity of LDH, the nature of metal components, the ratio of metals, charge and type of anion, and the space between the layers. In particular, the Friedel phase (FP), a member of the LDH family, showed high adsorption capacity for selenate removal from synthetic solution. A study is currently underway at the University of British Columbia to investigate the effect of different synthesis methods and aging on the suitability of FP for selenium removal from mine waste water."

Jan 1, 2017

By L. Rao, P. Carabin

"Advances in thermal plasma torches have resulted in this technology becoming a commercially viable solution for chemical and metallurgical processes. The main advantages of plasma are its ability to control process chemistry and to build small footprint reactors due to its high energy density and reactivity of the free radicals that are produced. This paper focuses on thermal plasmas produced by DC torches and their applications for waste treatment, production of high purity metals, and nanomaterials. Both transferred and non-transferred torches have been used as either a source of heat or as a reagent in various industrial processes. INTRODUCTIONPlasma technology has become an ideal solution for many industrial chemical, metallurgical and mechanical processes (Venkataramani, 2002). Thermal plasma powered systems are typical used for their unique characteristics such as high energy densities, high temperatures, small installation sizes, rapid startup and shutdown features, controlled process chemistry and use of electrical energy as a heating source resulting in decoupling the heat source from the oxygen flow rate (Heberlein et al., 2007). Depending on the nature of the main plasma forming gas used, thermal plasma systems offer a high temperature heating source coupled with a highly reactive plasma plume rich in free radicals and ions which promote otherwise hard to drive chemical reactions, as well as high heat transfer rates.Industrial plasmas can be broadly classified as thermal plasmas and non thermal plasmas. Thermal plasmas are atmospheric pressure plasmas characterized by local thermodynamic equilibrium (Boulos et al., 1994). Thermal plasmas are typically established between any two current conducting electrodes separated by an insulator. A plasma forming gas is blown between the two conducting electrodes resulting in a high temperature plasma plume. A plasma torch generates and maintains an electrically conducting gas column between the two electrodes; a cathode (negative electrode) and an anode (positive electrode) (Camacho, 1988). If both electrodes are housed in a single housing, resulting in an arc enclosed inside the plasma torch, then such plasma generating torches are termed as non-transferred (NT) plasma torches, whereas, if the second electrode is external to the torch, creating an arc transferred between the cathode and the working piece, then such plasma torches are termed as transferred (T) plasma torches. Depending on the source of the electricity which can be either direct current (DC), alternating current (AC) at main network frequency or at radio frequency (RF), the plasma torches are classified as DC, AC or RF plasma torches (Venkataramani, 2002)."

Jan 1, 2012