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By D. Gorc, T. M. Fraser, Z. T. Nikic, R. Pesalj

"Mount Polley is an alkalic porphyry copper-gold deposit of Lower Jurassic age within the Quesnel terrane in south-central British Columbia. The silica-saturated Mount Polley intmsive complex is assumed to be coeval with volcanic rocks of similar composition in the Nicola Group in which it was emplaced. Other intmsions and some of the volcanic rocks in the Mount Polley area are silicaundersaturated and contain feldspathoids.The Mount Polley deposit is characterized by multiple intrusions that vary from diorite to crowded plagioclase porphyry to monzonite. Intmsion breccias are associated with some of the intmsive phases. Abundant hydrothermal breccias occur on the margins and above plagioclase porphyry intmsions. These breccias provide the main host for mineralization and are associated with the highest concentrations of copper and gold. The breccias are subdivided into four distinct types based on the dominant hydrothermal mineral in the matrix. Actinolite breccia is developed in an elongate zone within the core of the Central zone and grades laterally and vertically into biotite breccia to the southeast. Magnetite breccia is irregularly distributed and is relatively sparse throughout the deposit and albite breccia is dominant in the West zone. Pervasive and vein-related alteration correlates with the breccia types. The core of the hydrothermal system at Mount Polley is subdivided into three zones: actinolite, biotite and K-feldspar-albite. The margins of the core zone are overprinted by a discontinuous zone of calc-silicate minerals. This intermediate zone passes outward into propylitic alteration. Mineralization is most prominent within hydrothermal breccias and is generally present as disseminations, blebs within the matrix and abundant veins. Mineralization is associated with a chalcopyrite-magnetite-bornite assemblage in the core of the deposit passing out into magnetite-pyrite-chalcopyrite. Relatively constant copper to gold ratios suggest that both metals were precipitated under similar conditions.Hydrothermal breccias are genetically related to the emplacement of the crowded plagioclase porphyry melt. Crystallization of the melt was probably accompanied by volatile/aqueous exsolution, forming a water saturated carapace. Decompression of the chamber in response to magma withdrawal, fracture propagation and possible fault movement allowed hydrothermal brecciation to occur at the apex and margins of the intmsion. Alteration and mineralization appears to have been controlled by fluids migrating away from the plagioclase porphyry."

Jan 1, 1995

By Steve Custer, Chris Bennett, Patrick Garretson, Glenn Dobby, Jacques McMullen

"Barrick Gold is in the process of expanding one of its grinding circuits at the Goldstrike property as a response to both increasing ore hardness and increased ore sensitivity to finer grinding as it relates to gold recovery. The plant currently operates with two parallel grinding lines, each with a SAG mill, a pebble crusher, and a ball milling arrangement. As part of determining what additional equipment was to be required, a CEET evaluation program was conducted (CEET is an acronym for Comminution Economic Evaluation Tool). The work included: Development of a hardness ‘model’ for the ore body, as described by SAG Power Index and Bond Work Index;Site benchmarking surveys to fine tune the SAG and ball mill calibrations within CEET;Conducting CEET studies to examine the process options;Comparing CEET results to standard grinding circuit design techniques.The recommendation of the study, presently being implemented, is the installation of an additional ball mill on one of the two grinding lines. This paper reviews the sizing techniques applied, providing a CEET case study for circuit performance analysis and circuit design. OVERVIEW OF COMMINUTION AT GOLDSTRIKEOre feeding the autoclaves at Goldstrike are first processed through two parallel grinding lines. Both lines use SAG mills with cone crushing of pebbles followed by ball milling. A summary of the key circuit parameters is provided in Table 1. Line 1 primarily processes underground Meikle ore, although when no Meikle ore is available, it processes open pit Betze ore. Line 2 processes Betze ore exclusively. The Mill Line 1 P80 objective for Meikle ore is 74 microns. According to the recovery optimization analysis, a P80 of 90 microns was recommended for Betze ore. The potential however exists to perform co-mingling of both ore types and feed the higher grade Betze ore to Line 1, in which case the P80 of 74 microns would be retained."

Jan 1, 2001

By P. Radziszewski

Industrial practice in mineral processing shows that an important problem in understanding and monitoring in-mill parameters is due to the lack of fundamental knowledge and appropriate sensors. With the development and growing use of DEM charge motion simulators for mill optimisation and design, it is possible to describe the fundamentals of grinding mill behaviour, in improving the understanding of internal grinding mill dynamics and in developing solutions to industrial practice. The main challenge to bringing this DEM technology to the mill operator however was the need for substantial computing power and time. However, what about a simplified DEM charge motion model running in real-time? What about the use of sensor technologies to correct any possible drift in simulator prediction? Could such a technological system be used to predict mill performance and eventually be used for mill control and optimisation? Some of these questions are answered with the development of an "on-line" DEM charge motion simulator package (SAGTools?) along with that of a number of sensor technologies (liner wear, acoustic, instrumented ball) that can contribute to simulator precision. With the objective of bringing this modelling and sensor technology into the concentrator control room to assist operators, this paper aims to describe the main elements of this emerging and developing technology and discuss how it can lead to online mill performance prediction and eventual control.

Jan 1, 2007

By J. A. Finch

Samples of feed and product from a closed grinding circuit treating a heterogeneous lead-zinc ore were taken. The feed was subjected to laboratory batch grinding in a rod and ball mill with the objective of simulating the closed-circuit size distribution. It was concluded that the batch rod mill can closely simulate this product if only the over-all size is considered, but mineral-by-mineral large differences occur. If, as is suspected, the mineral sizes are the important factor in flotation, the differences could lead to problems in interpreting flotation results. An example of mineral recovery as a function of size is described to illustrate the potential problems.

Jan 1, 1979

By X. Cao, J. J. Jonas, Wanjara. P., J. Gholipour, E. Dalgaard

The linear friction welding (LFW) behaviour of near-ß titanium alloy Ti-5Al-5V-5Mo-3Cr (Ti- 5553) was investigated. Microhardness measurements were performed in order to evaluate the mechanical properties of the welded material. The linear friction welded (LFWed) Ti-5553 was examined with optical microscopy and scanning electron microscopy (SEM) to evaluate the microstructure’s response to the thermomechanical conditions. Characterization of the welds included analysis of the microstructural features of the weld region and thermomechanically affected zone (TMAZ) in relation to the parent material.

Jan 1, 2010

By R. W. Brigstocke

History The birth of the mining industry of Canada took place about 1670. According to Salone (Salone E., La Colonisation de la Nouvelle France, page 205) the first discovery of ore in the country was made by an iron-master, Monsieur de la Potardiere, near Trois Rivieres, Quebec. Under French rule some prospecting was done; but at this time no one seemed to consider the working of mines practicable. It was not until the time that Begon became Intendant, when the Marquis of Vaudreuil was Governor, that mining was attempted. Begon was a patron of industrial arts and did his best to promote home manufactures. The mining industry was developed under his regime and discoveries of copper and lead ores were made in 1730. About this time the St. Maurice Forges were erected to treat bog-iron ore, and they were in operation for many years. Prior to 1747, iron pans to the value of £21,000 were manufactured, together with bar-iron and plough-shares. About 1769, that is, ten years after the conquest by Wolfe, stoves and other articles, and, later, potash kettles, appeared. What is still more interesting to us-or was, at least, to General Wolfe-is that cannon balls made at the St. Maurice Forges delayed his operations. A map dated 1744, a copy of which appears in the report of the Ontario Bureau of Mines for 1913 (Vol. XIX), indicates the extensiveness of the wanderings of the French and also shows the location of the lead mine on the east shore of Lake Timiskaming. Bog-iron ore was turned into metal, with charcoal for fuel, at Norman-dale, Norfolk county, Ontario, in 1813, and at Clementsport, Nova Scotia, in 1825. In a volume published in 1672, reference is made to the occurrence of coal on the Atlantic seaboard, and in 1677 Monsieur Duchesneau, the Intendant, levied a royalty of twenty sous per ton on all coal taken from Cape Breton.

Jan 1, 1932

By J. -F. Blais, M. -O. Simonnot, P. Charbonnier, J. Mocellin, Université de Lorraine INRA, G. Mercier

"Huge amounts of air pollution scrubber sludge have been generated during ferromanganese production using blast furnace. These residues have been historically deposited in ponds near steel making plants. They are very rich in zinc, manganese and lead (5 to 40 %) and also contain aluminum and iron. Considering the market value of these metals, brownfield sites can now be used as secondary resources. These ponds also have to be cleaned up to meet the environmental regulations.We have developed a hydrometallurgical process to recover Zn, Mn and Pb in order to produce valuable compounds of Mn and Zn and recover the final Pb residue by pyrometallurgy. The Zn and Mn compounds need to be pure enough to be economically valuable. Batch laboratory tests were carried out to determine suitable selective leaching conditions. The investigated operating conditions were acid concentration, pulp density and temperature. Optimal conditions to maximize zinc extraction (100 %) and manganese extraction (95.9 %) were found using sulfuric acid and sodium metabisulfide. The final residue contained 14.8 to 23.8 % of Pb. Then, Zn was recovered in the form of ZnO or ZnS by precipitation and Zn metal by electrowinning, while Mn was recovered as MnCO3 with a fairly acceptable concentration of impurities.INTRODUCTIONFerromanganese has been produced by pyrometallurgy in much of Western Europe for centuries. Use of wet scrubber to remove pollutant and dust particles from gas stream was common for most of these operations. Those residues contain high concentration of Zn, Mn and Pb. They have been left to decant in settling ponds installed close to the steel production plants. They now constitute heavily contaminated artificial soils. Those sludges are so contaminated with Zn, Mn and Pb that they can be used for metal production. Currently, no method is available to decontaminate these residues and recover Zn, Mn and Pb. Therefore, an approach considering these brownfield sites as secondary resource is in development. Doing so would achieve two goals, decontaminate the site and produce metals.. (Huot, Faure, Biache, Lorgeoux, Simonnot, & Morel, 2014a; Huot, Simonnot, Marion, Yvon, De Donato, & Morel, 2012; Huot, Simonnot, Watteau, Marion, Yvon, De Donato, & Morel, 2014b)."

Jan 1, 2016

By L. Henry Smith, David C. Arthur

"The Williams Mine is Canada’s largest gold producer, with annual production of 450 000ounces from 2 300 000 tonnes of ore. Highly mechanized and automated underground mining practices are employed in order to achieve and maintain high levels of productivity and minimize costs.The mine ventilation system is modified to include a new vent raise and variable pitchvane-axial fan. This addition allows several fan installations underground to be decommissioned. A substantial net savings in installed horse power is achieved.Heating costs associated with under-ground ventilation air are a significant portion of mine operating costs. Air heating costs are substantially reduced by recovering heat from upcast exhaust air, minewater and compressor cooling circuits. This waste heat is used to supplement propane fired air heating systems for underground ventilation air. An additional benefit is the availability of a heat sink for summer cooling of the compressors.System design, energy savings data and payback calculations are presented."

Jan 1, 1996

By J. A. Bos, Z. Dai, P. Quinn, A. Lee

A flowsheet is being developed for processing Thompson ultramafic low-grade nickel ores. This type of ore is characterized by high content of serpentinized magnesium silicates which generate slimes during comminution. Flotation of this type of ore proves difficult due to problems associated with the slimes. The flowsheet, based on extensive laboratory and miniplant flotation tests, consists of two key components: desliming by hydrocyclones prior to flotation and using soda ash for pH control in flotation. Satisfactory metallurgical results have consistently been achieved in laboratory full circuit simulation and miniplant tests.

Jan 1, 2009

By N. Depountis, Th. Rondoyanni, N. Sabtakakis, K. Kavoura, G. Tsiambaos

"Some typical landslide phenomena in Western Greece, in terms of the geological composition and structure of the affected materials, induced by heavy rainfalls are thoroughly studied and analyzed. The studied cases involved composite landslides on Flysch and Neogene weak rock materials that constitute the most critical landslide prone geological formations in Greece. The studied cases named Platanos, Platanitis and Karya include representative landslide sites as regards to the geological composition and structure of the displaced formations. Thus: (a) flysch formation includes different lithological units as shales, marls, siltstones, sandstones and conglomerates and is closely related to the Alpine orogenesis, suffering intense past tectonic movements and (b) the Plio-Pleistocene sediments include clayey marls, marlstones and siltstones. The investigated landslides , affecting mainly transportation routes, are closely related to heavy rainfalls induced by extreme meteorological events and are controlled by active fault tectonics. Long term movement monitoring using borehole inclinometers and surface benchmarks showed that landslides control was effective only when the proper stabilization measures were taken.INTRODUCTIONLandslides represent a major threat to human life, property, infrastructure and natural environment in most regions of the world. They are recognized by the scientific and politic authorities as having a major socio-economic impact and they represent a significant hazard for the population and the properties in particular locations. Landslide hazard expressed as the probability of occurrence within a reference time period and is a function of the spatial and temporal probability (Varnes, 1984; Guzzetti et al. 1999; Lee and Jones, 2004). The spatial probability of landslide initiation (susceptibility) is mainly related to static causal factors (slope inclination, material properties, etc.), while temporal probability is mainly related to dynamic causal factors such as rain input, increased groundwater levels and drainage, earthquakes, etc. (Van Westen et al. 2005)."

Jan 1, 2015

By P. G. Claridge, R. A. Tenbergen

"Pipe Open Pit ore is delivered by rail to the Thompson Mill at a rate of 34,000 tons per week. Ore is milled at a rate of 220 tons per hour.Characteristics of the serpentinised peridotite host rock are such that significant deviations from hitherto experienced milling practice became a necessity because of coagulation of the gangue upon cominution.Extensive development work was done in the grinding and classification circuits to better understand the ore characteristics and optimize operating parameters and the use of available equipment. This work ultimately resulted in the change from 30 to 20-inch diameter cyclones.Coagulation of the ore slurry and the characterstics of the sulfide minerals necessitated an ""unconventional approach"" in processing as compared with the beneficiation of Thompson Mine ore.Recent changes in ore characteristics led to testing of antistatic agents to reduce tailing losses."

Jan 1, 1975

By E. W. J. Thornton

During the past six or seven years extensive research has been performed on ore samples procured at the Bruns1,vick Tin Mines which is located in the south-west corner of New Brunswi.ck. This property was originally staked by Mount Pleasant Mines and they did considerable metallurgical and geological work on a small copper, zinc and tin deposit. In 1969, the property was obtained by the Sullivan Mining Group and after much geological and diamond drilling work, an entirely separate ore body \Vas located two miles south of the previous workings. The major economic metals in this ore zone are tungsten, bismuth and molybdenite, but many other metals exist as well. As the ore contains a host of different mineral species, it can be seen that considerable time WRS required to develop a practical flow sheet.

Jan 1, 1977

By M. M. K. McCrank

"PRACTICAL SAMPLING TECHNIQUESIt is important to achieve reliability when sampling heterogeneous materials where there is a difference in composition, and non random distribution of the constituent particles. Throughout the design, construction and installation of sampling systems it must be borne in mind that the sampling point must be capable of:-allowing each particle in the stream an equal opportunity to be sampled.-accepting and collecting as large a volume or mass of material as necessary to satisfy the requirements of particle counting statistics.-establishing a sampling plan so that the sample is representative of the whole to a defined standard of accuracy.Design ConsiderationsFactors that may influence the design of the sample point include:-the mass, or volume flow rate of the material being sampled-the size and shape of the material or flowing stream-the physical condition of the material being sampled (i.e. temperature, wetness, size consist, density).-the chemical composition of the material being sampled -the location of the sample point and the space available for installation, extraction, reduction where necessary, secondary sampling, and return of the sample rejects downstream.-whether the process to be sampled is in an existing plant or one yet to be designed and built.-ease of access for servicing and maintaining the equipment.-whether the sampled material must be collected continuously or intermittently.-whether an existing sampling method is likely to be adequate or whether a new technique has to be developed."

Jan 1, 1989

By A. Vien, B. C. Flintoff, R. P. Edwards

"This paper provides a critical review of the development and application of advanced controls in mineral processing at the industrial level. These algorithms can be sub-divided into four broad categories: Kalman filter, self-tuning, extended horizon, and knowledge based or expert systems. Applications from each category are described outlining the benefits derived, the relative advantages of that particular controller, and potential limitations of the controller which may inhibit their more widespread application. The paper will conclude with a description of control algorithms which are currently in the rudimentary design stage, but may hold tremendous potential for mineral processing control systems in the next decade. INTRODUCTIONThe Canadian mining industry has a large installed milling base and many plants are run with manual or low level automatic process control. The competitive pressures imposed by the market will not allow these operations to ignore the significant increase in efficiency that can be achieved through the effective application of advanced process control. These improvements will come in the form of better quality, higher productivity and reduced costs.There have been quite a number of reports of successful applications of advanced control in mineral processing applications. As this trend continues, and more of the work is documented, the technology will be more effectively transferred to process and control engineers. It is the authors' opinion that the most difficult problems facing process control are not really technical in nature. Rather, they lie more in process control education. This extends from management, through engineering to the operators.The purpose of this paper is to provide a tutorial type overview of some of the more frequently encountered advanced control algorithms. The assumption is that the reader has a superficial knowledge of this technology. In the discussions which follow, several techniques are explored within the framework of simple process examples. Industrial examples are cited for each and an evaluation of the expected longer term potential is given."

Jan 1, 1992

By D. M. Doyle

"In this paper I will summarized the Falconbridge Nickel Mines1) energy costs and consumption data by fuel, process, cost centre and estimate our future costs and consumption patterns 2) detail the distribution of electrical energy 3) distribution of other forms of energy 4) describe present and planned energy conservation schemes; and 5) discuss economic justification and responsibility.There is sufficient material in this presentation to warrant several technical papers, however we felt that an overview of all our data and endeavors on the subject, would be most beneficial to those companies formulating energy conservation plans. The data briefly referred to in this slide presentation can be found in the technical paper.Over a five year period, total energy costs will vary between $63 and $94 MM depending on the future rate of energy cost escalation. An unrealistic 32% reduction in energy consumption is required to hold our own in the years ahead whereas an attainable 10°;, reduction in energy consumption would save $9 MM over this five year period.Total energy consumption, tonnage of ore delivered to plants and their ration BTU’s per ton of ore, are graphed for the years 1973 through 1976 and forecasted for the 1980’s. In 1974 we along with other member companies of the Mining Association, determined our purchased energy per ton consumption rate and set, as our goal, a 20% reduction by 1980. The dotted lines calculated from the energy audit, based on 1976 data shows there is a potential for a 10% increase in energy per ton. This could result from a lower than forecasted mining rate and operation of the new roasting, electric furnace and acid recovery facilities installed for environmental considerations at designed capacity."

Jan 1, 1978

By L. W. Hamel

"Two 35 foot diameter enviro clear thickeners were tested in series as CCD units from June until October, 1978. Up to shutdown in July, we ran with automatic bed level control via the level probes and underflow pinch valves. Despite extensive efforts, we were unable to eliminate the surges created between the units by the opening and closing of the pinch valves. Early in July, the best rake speed and gap setting were determined. After shutdown, the enviro clears were run by manually controlling the pinch valves. These efforts were successful.A few mechanical problems were encountered while operating the thickeners. New units should incorporate more support for the drive coupling and a rubber feed seal. A few modifications of the instrumentation control scheme will be required before the units can be fully automated. A less sophisticated automatic flocculant addition system will accomplish the desired results. Control of the underflow withdrawal via the pinch valve should be investigated further. Our best results were obtained by keeping the feed volume to the No. 1 enviro clear constant. Surges were controlled by opening or closing both underflow valves proportionately.Capacity of the enviro clears is dependent of many variables. The ore treated during the test program was much finer than that reported on in R & D Project Report 76-02. Conditions were never steady enough to determine best flocculant dosage or addition point(s). The lowest soluble losses were obtained at very high wash rates. The underflow densities drop but the soluble losses also drop. Regression equations were developed in order to assess the effect of the various parameters. Within the range studied, these equations will predict the performance of enviro clear thickeners as CCD units on Elliot Lake ores. Our results show that the enviro clear thickeners are a viable alternative to the conventional CCD thickener."

Jan 1, 1979

By M. Leroux, P. Lacombe, S. R. Rao, J. Y. Kim, J. A. Finch, G. Labonté, N. Macminn, M. Ounpuu

"Laboratory investigations on two complex ores, the A1 zone ore from Les Mines Selbaie and the Lyon Lake ore from Mattabi Mines Ltd. (Division of Noranda Minerals), have been carried out to determine some of the main variables in collectorless flotation. In particular, the effect of pulp potential (controlled by gas composition), conditioning time, pH and grinding media have been studied.Chalcopyrite showed the greatest response to collectorless flotation among the four major sulphide minerals present, followed by galena. Flotation of sphalerite was variable from minimal to important depending on the mineralogy and the pre-treatment performed. Appreciable silver recovery was achieved collectorlessly for the Lyon Lake ore while it could not be achieved for the A1 zone ore of Les Mines Selbaie. It appears that the difference between the two ores is related to silver's predominance as tetrahydrite in the Lyon Lake ore while it is as argentite and native silver in the A1 zone ore.The response of the ores to collectorless flotation is strongly dependent on the pulp potential, Ep, and pH. Using different gas compositions and different conditioning times it was found that collectorless flotation occurs when Ep is +195 to +295 mv (vs SHE). The actual on-set potential for collectorless flotation is dependent on the ore. A too high potential or prolonged oxidation leads to a decrease in selectivity. Some other factors were examined, notably the effect of pH and the type of grinding media on the selectivity achieved in the laboratory.Preliminary results from a plant trial at Mattabi Mines Ltd. confirmed that collectorless flotation occurs and that it is preferential for chalcopyrite and to a lesser extent galena. Collectorless flotation was not attempted at Les Mines Selbaie. However, examination of the distribution of collector between the different addition points in the copper circuit suggests that it may be present."

Jan 1, 1990

By P. N. Calder, D. B. Apel, S. D. Butt

Mine-wide (MW) microseismic systems use widely spaced transducers to determine the source location and parameters of stronger microseismic events, while high frequency (HF) systems use fewer transducers to monitor local areas for the weaker events that can precede stronger events. Previous monitoring at the Creighton Mine indicated that an HF transducer located 120 m away from an active stope recorded two types of activity in response to production blasting: the first occurring at the same time as the production blasts and associated with the passage of the direct seismic waves from the blast through the local area, and the second occurring several hours later and associated with the arrival of a slower moving stress change through the rock mass (which was identified by the mine’s MW system). Interpretations of locally increased stress levels, based on analysis of the recorded HF events, correlated with the nearby occurrence of two strong seismic events. These results were applied to a similar monitoring trail at the Kidd Creek Mine where the transient stress changes induced by several development blasts were monitored. It was observed that increases in HF activity corresponded with the occurrence of MW events near the transducer location, and that fewer HF events were recorded the longer this occurred after the blast. Local geological features appeared to influence the number and occurrence of both HF and MW events.

Jan 1, 2000

By Lang Tao, Jun Wang, Wei Xiao, Wenqing Qin, Pan Cao, Guanzhou Qiu, Key Lab of Biohydrometallurgy of Ministry of Education, Central South University

"The effect of metal cations on the rutile flotation using styryl phosphoric acid (SPA) as the collector was investigated by micro-flotation test, bench scale flotation test, zeta-potential measurements and adsorption measurements. The micro-flotation results indicated that Fe (?) and Al (?) ions in low concentrations had obvious activation on the rutile flotation, and Pb (?) ions in low concentrations had smaller activation of rutile, but Fe (?), Al (?), Pb (?), Ca (?) and Mg (?) have strong inhibition of rutile flotation in high concentrations. The bench scale flotation results indicated ethylene diamine tetraacetic acid (EDTA), boracic acid, and sodium hexametaphospate can decrease the metal ions concentrations, and increase the recovery of rutile flotation. Adsorption measurements and zeta-potential measurements revealed that Fe (?), Al (?) and Pb (?) ions were adsorbed on the rutile surface, and had interaction with SPA. But when these ions concentration were over the largest adsorption capacity, residual metal ions could occur chemical reaction with SPA.INTRODUCTIONRutile is one of the favored minerals for production of titanium dioxide white pigment, primarily through the chloride manufacturing process (Stanaway 1994; Hou et al., 2013) However, the majority of rutile ores belong to refractory ores, while flotation is one of the most efficient methods to separate fine rutile from gangue (Dolbear et al., 1937). With the flotation development, many effective collectors were successfully applied in the oxide ore. Many reviews have indicated that organic phosphonic acid collectors showed good selectivity on oxide ores such as ilmenite and rutile (Bulatovic & Wyslouzil 1999; Liu & Peng 1999).It is inevitable that many types of metal cations are present in ore pulp. These metal cations significantly influence the flotation of minerals. Liu et al. (2015) showed that Ca2+ and Mg2+ could improve the floatability of spodumene at pH 12.5 and 10.0, respectively. The authors proposed that Ca2+ and Mg2+ ions readily form hydroxy complexes (CaOH(l) and MgOH(l)) and precipitates as (Ca(OH)2 and Mg(OH)2) in strongly alkaline solutions. Fan and Rowson (2000) investigated the effect of Pb(NO3)2 addition as an activator on ilmenite flotation and showed that it could improve ilmenite floatability. The addition of Pb(NO3)2 resulted in an increase of ilmenite zeta potential in both weakly alkaline and acidic aqueous solutions. Mehdilo, Irannajad, and Rezai (2015) studied three kinds of ilmenite of different origins and discovered that both Mg and V had a negative correlation with ilmenite flotation, while the Mn content seemed to correlate positively with flotation efficiency. A number of studies have also showed that Fe3+ can improve the floatability of ilmenite (Fan et al., 2009; Nuri, Mehdilo, & Irannajad, 2014)."

Jan 1, 2016

By Maciej Wrobel, Joerg Hammerschmidt, Dana Nurgaliyeva, Alexandros Charitos, Jochen Guentner

"Smelting of copper concentrates in the flash smelter generates a flue dust stream that contains a substantial amount of copper and accumulates more than half of the arsenic input to the smelter. In view of its high copper content flue dust recirculation to the flash smelter is common practice. Globally traded copper concentrates are affected by ever increasing arsenic contents and cause an increasing circulating arsenic load in flash smelter operation. Control of the arsenic level in the smelter slag becomes a challenge. This interaction of arsenic loaded copper feedstock, need for flue dust recirculation and slag quality control call for possibilities to reduce the arsenic load of the recirculated flue dust stream.The technology of partial roasting is known from pre-treatment of copper concentrates before smelting, and gold concentrates before cyanide leaching, to remove the harmful element arsenic. The partial roasting technology can be adapted for use in the purification of the flue dust. A major challenge for flue dust treatment is its extremely fine particle size compared to usual concentrates. For this reason Outotec developed a new process, which allows handling of such fine flue dust. This process solution provides an efficient possibility to reduce the arsenic burden in copper smelter operations.The suggested process aims at reducing the arsenic load to the smelter by treating the flue dust prior to recirculation to the smelter. The presented results are based on test work in the Outotec R&D-centre in Frankfurt. It is possible to remove 80-85% of the contained arsenic and to collect it in an arsenic trioxide residue with a concentration above 90%. The final off gas contains SO2 from decomposition of sulphates that are contained in the flue dust. The off gas stream is relatively small. We assume that it is possible to combine the off gas stream with other smelter process gas streams and to treat it in an existing sulphuric acid plant. Coal is used as fuel and as reductant to reduce pentavalent arsenate to trivalent arsenite. Arsenite can be kept in gas form at temperatures above 450°C. This permits separation of a calcine stream with arsenic levels of 0.2 – 0.3%, which is recirculated to the furnace.Outotec has a wide range of roasting testing facilities from lab-scale to pilot-scale. Outotec has both capability to modify and adapt technology to specific ore or concentrate requirements, but also the necessary infrastructure in its research centers in Frankfurt and Pori to do appropriate validation tests in lab and pilot scale size plants."

Jan 1, 2016