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By G. Granata, C. Tokoro, T. Kato

"The goal of this study was to evaluate the effectiveness of mechanochemical activation by planetary milling as method to enhance the recovery of cerium from rare earth ores. For this purpose, a weathered ore was first ground by planetary milling and then leached by sulfuric acid. The influence of planetary milling was investigated by assisting the experiments with X-ray absorption fine structure (XAFS) in cerium LIII-edge and inductively coupled plasma spectrometry to measure the concentration of cerium dissolved by leaching. Results showed that, by increasing the grinding time, although the particle size of the specimen increased due to agglomeration, the recovery of cerium significantly increased. This finding clearly indicated that a smaller particle size actually hinders the recovery of cerium. In particular, XAFS analysis revealed that the longer the grinding time, the more tetravalent cerium could be converted into trivalent cerium and such conversion, also called mechanochemical reaction was beneficial to the recovery of cerium. Based on the obtained results, it was confirmed that approximately 70% of cerium could be recovered by mechanochemically activated leaching of rare earth ores.INTRODUCTION Rare earth elements (REEs) are a group of 17 chemically similar metallic elements comprising lanthanides, scandium and yttrium. Since REEs have various unique physical and/or chemical properties, they have become essential materials for advanced application (Adachi, 2015). REEs used in industry are usually supplied as rare earth minerals. In the last decades, flotation, gravity separation, magnetic separation and leaching have been widely applied to recovery of REEs from rare earth minerals like monazite (Archana, Rekha, Manis, Jitendra, & Jin, 2015). Among these operations, leaching has been widely studied in the recent years to improve the state of the art (Archana, Rekha, Manis, Jitendra, & Jin, 2015; Xiao, Feng, Huang, Huang, Chen, Liu, Wang, & Long, 2016; Farzaneh, Fereshteh, & Ahmad, 2017). Aiming to enhance recovery of REEs from rare earth minerals, a possible advancement of leaching technology could be the mechanochemically activation of the ore by high-intensity milling (Alorro, 2016). In the mechanochemical activation, an improvement of the leaching performances can be achieved through high-intensity milling operations which result into a dramatic decrease of the mineral particle size with a consequent improvement of the physical kinetics of leaching. Furthermore, the high mechanical energy provided to the sample during milling can determine the rupture of the crystal structure of the mineral, thereby transforming it into a more leachable form."

Jan 1, 2017

By Davis. B. R.

There are a number of hydrogen storage systems proposed for automotive applications. However, all of the current suggestions fall short of the DOE targets for storage density and volumetric density. The DOE has suggested that only through radically new ideas will a practical solution to hydrogen storage for automotive applications be realized. This paper provides some background in chemical hydrogen storage and discusses roadblocks to the implementation of some proposed technologies.

Jan 1, 2005

By H. Hao

This paper outlines the development of a 2-D axisymmetric mathematical model to predict the evolution of temperature during the Direct Chill (DC) casting of AZ31 magnesium billets. Model predictions of temperature have been compared to measurements made on an industrial DC casting machine at Timminco Ltd, in Haley, Ontario. These measurements have been used to fine-tune the thermal boundary conditions employed in the mathematical model, The model, which is based on the commercial finite-element code ABAQUS, has been developed as part of a strategic project aimed at improving the DC casting process for light metals through a reduction in casting related defects and increased productivity.

Jan 1, 2004

By G. T. Lapidus, R. Zárate-Gutiérrez

Selective leaching of lead from a Pb-Ag-Zn concentrate with hydrogen peroxide in citrate solutions was studied at room temperature. Leaching tests were performed, varying the H2O2 concentration and the solid-liquid ratio, holding the solution pH constant at 7, and the citrate concentration at 1 M. Lead extractions of 100 % were achieved with 4 and 5 times the stoichiometric quantity needed to form elemental sulfur, with only a small amount of metal impurities dissolved (Ag, Zn and Fe). The lead solubility limit at those conditions was found to be ~21 g L-1. X-ray diffraction analyses of the leach residues were free of galena (PbS), while other metal sulfides, such as sphalerite (ZnS), chalcopyrite (CuFeS2) and pyrite (FeS2), were basically unaffected.

Jan 1, 2014

By F. Awotwe-Appiah, P. Koshy, A. Y. Fosu, J. Dankwah, J. R. Dankwah

Ghana currently exports its bauxite raw without any value addition. Gradual depletion of high grade bauxite (with high alumina content) and the emergence of low grade bauxite (with high iron oxide content) calls for novel and inexpensive ways to recover alumina from these low grade ores. Bauxite users have indicated their willingness to pay 10% to 50% higher for a corresponding reduction in impurities by a similar amount. This project therefore investigates the carbothermal upgrading of the Ghana Awaso bauxite using waste polypropylene as reductant in a locally designed gas-fired furnace. Composite pellets of low grade bauxite sample (assaying 45% Al2O3) containing pulverised waste polypropylene were formed, oven dried, placed in fireclay crucible and fired for 30 minutes. The magnetic fraction after reduction was separated by a Low Intensity Magnet and weighed. It was observed that up to 97% of the iron oxides (occurring as hematite and goethite) could be separated into the magnetic fraction as magnetite leaving a nonmagnetic fraction with over 98% Al2O3 as opposed to the 45% Al2O3 in the as-received bauxite sample. This research direction provides yet another simple but effective way for simultaneously upgrading low grade bauxite and recycling waste polypropylene, whilst at the same time decreasing the amount of waste material generated as red mud after the Bayer process.

Jan 1, 2015

By J. Cui, Z. Meng, W. Zhao

"The decomposition of rare earth concentrates containing bastnasite and monazite by alkali solutions has been investigated. A slurry of the rare earth concentrate and the alkali solutions was calcined at different temperatures. The impacts of calcination temperature on the decomposition of rare earth minerals, the oxidation of cerium, the deportment of fluorine and phosphorous, and the adaptability of the method to the different grades of rare earth concentrate were all studied. A possible technique for comprehensive recovery is proposed in which the chemical elements such as rare earth, fluorine, phosphorus, calcium, iron and thorium could be recycled or recovered. INTRODUCTIONThe liquid alkali decomposition method is an important technique for the decomposition of mixed rare earth concentrates. The technique is relatively clean compared with the sulfuric acid roasting method. However, its operation is intermittent rather than continuous. The two-step solid-liquid reaction and the subsequent water washing make it not very suitable for mass production and application. An important reason for the disadvantage is that an additional process of ""calcium removal by acid leaching"" is needed for the technique. The content of calcium in Baotou rare earth concentrates is usually 6-12%. The requirement of the current technique is that the content of calcium should be reduced to about 0.2% after the calcium removal process. Otherwise, the decomposition and leaching of rare earth will be affected. Therefore, calcium removal by acid leaching is a necessity before the alkali decomposition process is carried out. Research on different alkali decomposition techniques has been conducted with prior calcium removal by acid leaching (Xu, 1995; Yu, 1993; Han, Li, Chang, Liu & Xu, 1985). There have been some investigations of direct decomposition of the bastnasite (Feng, Pan & Li, 1998; Zhao, Zhang, Yang & Liu, 2002)and monazite (Sun, Li, Li, Su, Zhao & Liu, 1998; Zhou, 2005) by alkali-liquid, however, all studies were carried out in solid-liquid reaction system, and continuous calcination studies have not been reported.This paper investigates the process of direct decomposition of Baotou rare earth concentrates by continuous calcination with concentrated alkali. Using the rotary tubular electric furnace, the mixture of rare earth concentrate and concentrated alkali solution were decomposed continuously. Satisfactory decomposition results were achieved. A method for clean processing and comprehensive resource recovery from Baotou rare earth concentrates is proposed."

Jan 1, 2012

By T. M. Ahmed

Sherritt International Corporation experienced corrosion failures with the 316L stainless steel tubing in a high-pressure still condenser employed for ammonia recovery. A detailed failure analysis was conducted on the condenser tubing to determine the mode and the root cause of the failure. The analysis included both optical and scanning electron microscopy (SEM) of the inner and outer surfaces of the tube as well as characterization of the corrosion products using energy-dispersive X-ray spectroscopy (EDX). Results revealed that the corrosion attack was confined to the first ?100 mm of the tubing at the inlet where the tube was connected to the top tubesheet. The tube suffered both external stress-corrosion cracking (SCC) and crevice corrosion from the shell side (water side), and wall thinning of the inner surface (the tube side) due to erosion corrosion. It was evident that failure of one of the tubes occurred due to SCC that penetrated the whole wall thickness and resulted in a leak failure. Some prevention measures are proposed to avoid this type of corrosion attack in the future.

Jan 1, 2005

By F. R. Archibald

Introduction It is the purpose of this paper to review the subject of roasting as preparation of refractory gold ores and concentrates for cyanidation, with particular reference to operations at the mill of Beattie Gold Mines (Que.), Ltd., Duparquet, Quebec. Two earlier papers relating to the Beattie roasting operations are cited as background to the ? present discussion, and more general reference is made to other publications relating? to geology and metallurgy at Beattie. The Beattie roasting plant was built in 1937 as an addition to the existing flotation and cyanidation plant to permit complete processing of the ore at the mine property. Previously, the flotation concentrate had been cyanided, yielding 70 per cent of the gold values, followed by re-flotation of a concentrate from the cyanide residue. This re-floated residue was shipped to a smelter for recovery of gold values unavailable from direct cyanidation. The roasting plant itself is of interest through application in its design of multiple-hearth roasters and a Cottrell plant for separate recovery of dust and arsenic. In the laboratory and plant studies that accompanied development of the plant into a dependable and efficient working unit have been found principles and ideas applicable to other roasting 'problems. Before enlarging on these aspects relating particularly to the Beattie problems and plant, brief consideration is given to roasting in general.

Jan 1, 1949

By Tad S. Golosinski

The paper describes Online Master of Engineering Program at the University of Missouri-Rolla and discusses the experience gained during the first three years of its offering. This innovative educational program is designed primarily for mature students with an engineering or science background who want to acquire or upgrade their knowledge of mining engineering. Students can specialize in several different areas of mining, such as surface mining, underground mining, mine environment and the like. All courses constituting the program are taken online, through the Internet, without the need to attend the UMR campus in person.

May 1, 2004

Vale Inco?s Coleman Mine 153 Orebody is a narrow vein deposit with a dip that varies from 30 to 70 degrees. It has a strike length of 1200-feet and the current mining extends from the 4250 level to 5100 level. The primary mining method is mechanized cut-and-fill although drift-and-fill is also used in wider sections of the ore zone. The ore body is divided into six main mining horizons with an average of three mining blocks on each cut. There are some interesting rock mechanics challenges related to mining upward from the 4550 level and these challenges are increasing as the mining front progresses toward the 4400 level. The mining of the 4550 block is currently at cut 13 whereby the crown pillar thickness is approximately 60-feet. Significant factors including increased stress levels in the crown pillar, the change in the orebody dip at this level and a recently indentified geological structure in the footwall, have all combined to introduce seismic activity in the footwall of 4550 level. Closer studies revealed a consistent trend of seismicity that was further examined with core logging and Acoustic TeleViewer technology. The data from these assessment tools disclosed a geological structure that is influencing the mining environment. This paper reviews the seismic analysis for the 4550 level mining zone and the subsequent procedures used to locate the new geological structure. The paper also discusses the key mining practices used to successfully mine cut 13 of 4550 level and briefly reviews the studies that are underway to up-date the mine design for continued extraction of high-grade ore in a safe and productive manner.

May 1, 2009

By Ronald C. Schimmel

In 2006, the Corus IJmuiden pellet plant produced approximately 4.6 mln tonnes of pellets. Corus IJmuiden is about to increase its pig iron production to 6.4 mln tonne HM per annum. The burden of the Corus IJmuiden blast furnaces consists of approximately 50% high basicity sinter and 50% acid pellets, both produced in-house. To enable an increased iron production, the capacity of the pellet plant needs to be raised to 5.0 mln tonne per annum. The capacity is increased by modifications to the plant layout, which were implemented during the 2006 cold maintenance stop. In addition, the composition of the ore blends is optimised to gain productivity.

May 1, 2007

By Y. Feng

Perovskite structured oxide 15% Y-doped BaCeO3 (BCY15) has been evaluated for use as proton conducting electrolyte in SOFC with propane as the fuel and Pt as both electrodes. Under the fuel cell conditions, BCY15 exhibited high proton conductivity and good cell performances. Propylene was detected as product at the anode outlet, and the product distribution suggests that propane dehydrogenation underwent competition with cracking to lighter hydrocarbons. Stability during cell performance tests showed that there was no obvious degradation for BCY15 electrolyte during operation of C3H8-O2 fuel cell.

Jan 1, 2005

By D. S. Evans

Major Project Blues Over the last two decades, almost every major project has suffered significant cost overruns, significant schedule delays, and/or poor quality work. Exceptions are rare and most projects that tout being ?On Time and Under Budget? have re-cast schedules, significantly modified scope or revised base estimates. The problem isn?t new. In the late 1980?s the Rand Corporation published a study showing that 80% of all major projects had significant cost and schedule overruns. The problem is not restricted to the Canadian environment, or to a specific industry. It is a global problem.

May 1, 2013

By J. Stumper

The control of the distribution and movement of liquid water is crucial for increased reliability and durability of PEM fuel cells: whereas the proton exchange membrane requires a minimum amount of liquid water for optimum operation, water excess in the GDL will impede reactant gas access to the catalyst layer thereby reducing performance. In order to understand the relationships between water management on one hand and fuel cell performance and durability on the other, Ballard has been developing a number of minimally invasive techniques that can throw light on the role of liquid water for both cell performance and durability. This paper introduces a novel measurement method that can provide information about the amount and distribution of liquid water under operation. It is shown how the MEA Resistance and Electrode Diffusivity (MRED) method can be used to determine i) the amount of liquid water in the fuel cell, ii) the pure ohmic cell resistance and iii) the O2 -diffusivity of the cathode. Furthermore, through a combination of the MRED method with current mapping it is possible to determine spatially resolved MEA resistance profiles.

Jan 1, 2005

1.Assessment of methane content in coal. Given a naturally low methane content in 11 Coal Seam and the fact that the areas of the 11 Seam adjacent to the tunnelway were degassing for a very, very long time due to previous development and mining, it is conservatively estimated that the remaining in -situ methane is less than 0.5m3/tonne. 2. Continuous miner cutting rate based on the past practice. The best loading rate recorded at the past operations of Smoky River Coal was 45 seconds for a 8 tonnes shuttle car. Using these records, the maximum peak loading rate potential at the face is calculated at 0.178 tonnes per one second or 10.67 tonnes per one minute. 3. Methane release at the face. ?The actual face methane liberation, conservatively assumed at 40% of the total in situ content: 0.20 m3/tonne ?The peak cutting rate: 0.178 t/sec ?The maximum (peak) face methane release: 0.20*0.178 = 0.036 m3/sec

May 1, 2003

By L. Bratek, K. Jaworek, M. Czaplicka

Methods for arsenic compound removal from aqueous solutions include processes such as: coagulation, adsorption, membrane techniques, electrochemical and biotechnology techniques. Advanced oxidation using both UV radiation and strong oxidizing agents such as ozone and hydrogen peroxide may also decompose these compounds. It is known that effluents from metallurgical processes contain inorganic arsenic compounds in addition to the organic compounds such as: dimethylarsinic acid and phenylarsonic acid. This paper presents the conditions that lead to the formation of deposits containing mainly arsenic, such as pH, the wavelength of the radiation and the type of oxidant, for this type of effluent.

Jan 1, 2014

By W. R. Lindsay

Considerable attention has of late been given to the blasting of large amounts of ore in one operation, on account of the saving in labour and explosives and consequent low cost per ton, and also on account of the additional safety to employees. The blast here described, at the Hidden Creek mine. at Anyox, B.C., is not necessarily unique either in size or methods employed, but some interesting p10blems were encountered and the solutions of these may be of interest to others engaged in similar work. The ore consisted mainly of old scope-bottoms and sill pillars, although there also were some braces and parts of vertical pillars included. Some of the stope-bottoms were overlain by caved waste, and one of the problems was to break them in such a manner that the maximum amount of ore could be recovered without serious dilution with waste. The ore blocks, designated as the 385 silt and the 7 A-103 blocks, were under preparation for blasting for over a year, as conditions permitted. This work consisted in drilling long machine drill holes, varying in length from 14 to 20 feet. These holes were drilled with the Numa detachable bit, made locally, starting at 2~-inch diameter and bottoming at 2 inches for the longest length. The long hole drilling was used in the thinner sections of the area. For the stronger, thicker portions, powder drifts (3 ft. by 4 ft. in section) were driven for the powder charges. Reference to the plan and sections (Figures 2 co 8 inclusive) show the relative location of these, as well as the long drilling. The amount of explosives used in the powder drift charges averaged 0.25 pounds per ton of estimated burden, varying from 0.2 to 0.3 pounds per ton.

Jan 1, 1934

By K. Sakai, M. Miyaue, T. Aoki, T. Tani, S. Tanaka, N. Kudo

In the planning stage of a tunnel, due to limited available technology in the geological survey and the financial restriction, tunnel supports are often designed from unsatisfactory information, and the tunnel construction is started. Therefore, "observational construction" is carried out in the construction stage, in which the design is rationally verified and modified by observations/measurements. Moreover, the ground conditions ahead of a tunnel face must be predicted for efficient and safe tunnel construction. The authors have examined effective prediction methods to the ground conditions ahead of a tunnel face under construction of a mountain tunnel (Aoki et al., 2010) in view of the established method (Schubert et al., 1995). Though the prediction method of Schubert et al. requires the displacement in the direction of tunnel axis, it is difficult to obtain its accurate data by the electro-optical distance meter. Then, we have proposed a method that uses tilt sensors installed at the tunnel crown near the face to obtain the slight tilting information. To measure inclination of the tunnel crown, this inclinometer was originally developed as a daily management measurement, such that the geological condition and its possible change behind the face could be detected early, and a steady advance and construction safety could be ensured. This paper describes the method of forward prediction mechanism and advantages of this proposed method. It then presents the typical results of a field demonstration test at a tunnel under construction. Lastly, the predictable range from the stratum boundary at which ground stiffness changes are discussed based on the results of three-dimensional numerical analysis.

Jan 1, 2015

By Mary A. Wells, Amir Hadadzadeh, Mark A. Whitney, Stephen F. Corbin

In an effort to produce less expensive titanium sheet via roll compaction, the room temperature compaction behavior of titanium sponge granules (99.9% pure, Alfa Aesar) was studied under uniaxial die compaction. The titanium sponge granules were irregularly shaped, with a high degree of porosity, having a maximum particle size of 3mm. Manual die compaction was conducted using a Carver hand press, in a hardened tool steel die with 12.61 mm inner diameter. Uniaxial die compaction in a hardened tool steel die with 9.50 mm inner diameter was also performed using a Gleeble® 3500 thermal-mechanical simulation testing system which allowed for controlled deformation rates. Compaction behavior of the titanium sponge was studied using well-established compaction equations (Heckel, Panelli-Filho and Ge), and it was observed that compaction rate influences the room temperature compaction behavior of this material. The Heckel analysis of the titanium sponge showed that the behavior of the material could be analyzed in two compaction pressure regimes. In the low pressure regime (<100 MPa) the granules exhibited high compressibility, while; in the high pressure regime (>100 MPa) lower compressibility of the titanium sponge was observed.

Jan 1, 2015

By H. Utsunomiya, J. Su, K. S. Tamimi, S. Yue, M. Sanjari, L. Kestens, A. S. Kabir, R. Petrov

The recrystallization and texture evolution of AZ31 sheets obtained through two stages was investigated at different stages of post-rolling annealing. The specimens were rolled at the temperature of 100? and at a fast speed of 1000m/min and low speed of 15m/min with a reduction of 30% in one pass. The results show thatAZ31B sheets rolled at 15 m/min and 100 °C has fractured for reductions of more than 30% per pass. However, by increasing the rolling speed to 1000 m/min the rollability was improved significantly and the material can be rolled to reductions of more than 70% per pass. The high speed and heavily deformed materials are fully recrystallized even at 100 °C.

Jan 1, 2015