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By J. Gurland

THE microstructure of sintered carbides consists of particles of metal carbides, such as WC and TiC, embedded in a metallic binder which is usually a cobalt—or nickel-rich solid solution. One of the important factors influencing the strength of the alloys is the degree of dispersion of the carbide particles in the binder matrix. While it is generally accepted

Jan 1, 1960

By Arthur Zentner

THE essentials of the electrolytic zinc process, as now used in commercial plants, date back to work done by Letrange in 1881. He used sulfuric acid to leach roasted sulfide and ,oxide ores, purified his solution very much as we do now, and electrolyzed the purified zinc sulfate solution. Ten years later Hoepfner developed a process using chloride solutions, and built three plants. One in England operated until 1924 in one of the works now merged in the Imperial Chemical , Industries, Ltd. Ashcroft built a plant in 1898 in the Broken Hill district of Australia. He used both chloride and sulfate solutions.. While his work failed, the aid his published results have been to later workers has made him an outstanding contributor to the de- velopment of the electrolytic zinc process. A good deal of work was done in the following years, aiming to electrolyze zinc chloride solutions and fused zinc chloride. Quite a bit of work on sulfate solutions was also done in the last years before the war. With the outbreak of the war, metal demand and rise in metal prices provided the stimulus which resulted in the remarkably rapid commercial development of electrolytic zinc. In this last period of development, all the work brought to commercial fruition has been with sulfate solutions. The high-density process, or the Tainton process, is used, as you know, in the Sullivan electrolytic zinc plant at Kellogg, Idaho, and will be used in the Evans- Wallower plant now being built at East St. Louis. The low-density process is used by the other plants now operating in the United States and other countries. There are now in operation and under construction four electrolytic zinc plants in the United States, two in Canada, two in Italy and one each in Australia, Rhodesia, Poland, Norway and Germany.

Jan 1, 1929

By Donald H. McLaughlin, John H. Moses

IN the latitude of Lima, the broad uplifted block that forms the Andes is made up of a complex sequence of folded and faulted sediments and volcanics, broken by large and small bodies of granitic rocks and porphyries with which the principal mineral deposits are closely associated in both time and space. The intrusives are a final episode in the geologic history as revealed by the consolidated rocks, for after their emplacement and after the formation of the primary ore deposits in and about them the record is simply one of long continued erosion and uplift.

Jan 1, 1945

By Philip J. Shenon

IN 1947 the mining industry strove desperately to regain operating normalcy. During the first part of the year the industry in this country was plagued with labor shortages, strikes, and portal-to-portal lawsuits. Then followed the uncertainty of Government policy with respect to subsidies and tariffs; and the long and bitter controversy as to whether we are a nation of mineral "haves" or "have-nots." As the year progressed the labor supply impoved somewhat and the Taft-Hartley law brought partial relief to strike-troubled industry. The uncertainty with respect to tariffs was partly answered by President Truman on April 29 when he announced the suspension of the 4¢ import duty on copper until March 31, 1949, and later, near the close of the year, by the announcement of the tariff agreement signed by the United Nations at Geneva. By this agreement tariff rates are to be adjusted downward, or "bound" at their present levels, for three years, on commodities amounting to some 60 per cent of United States trade. Effective Jan. 1, 1948 the rate of duty will be substantially reduced on ores, concentrates, or metals of zinc, aluminum, copper, manganese, tungsten, iron, steel, barytes, nickel, cadmium, and antimony.

Jan 1, 1948

Adolph Greiner, Seraing, Belgium:—I have nothing special to add to Professor Hubert's paper except to say that there are some little things that it would be well to have corrected when the paper comes to be published. In dealing with the thermal efficiency of the engine, you will find that the 29.84 per cent. was a very high one. Professor Hubert has forgotten those engines built under the Cockerill type, but he has referred to them in Appendix 11. At our works at Cockerill we have built 63 engines, giving 63,000 h.p., and the other companies who have received licenses have built 113 engines, making 103,000 h.p., and aggregating 176 engines and 166,000 h.p. Eight years ago I had the pleasure of giving to the Institute the results obtained up to that time. Since then a good many engines have been constructed. In 1898 I thought a blast-furnace producing 100 tons of pig iron would allow 3,000 h.p. Professor Witz and Professor Hubert show that with the same production of pig the new engines take 3,800 h.p. out of the gas. At present at Cockerill we make 700 to 800 tons of pig iron per day, and we hope to have 26,000 h.p. in a few years. At present we have only half of that in gas-engines, but we hope to have in five or six years all the gas out of these furnaces to the number of 25,000 or 26,000 h.p. Tom WEstGarth, Middlesbrough, England :—My contribution is not a paper in the ordinary sense of the word, because I am sure you will agree with me that what I have written is only supplementary to the other two papers. The notes are schedules of the larger-size gas-engines built by British engine-makers, of 500 h.p. and upwards. If you look at the schedules you will find that in England gas-engines have become quite ordinary motors for a good many purposes. It was at first thought that gas-engines were troublesome, and ill-

Jan 1, 1907

By Clark A. Sumner, D. Arthur Burnham

A process for recovery of greater than 99% of the copper contained in acid leach solutions by sulfide precipitation using hydrogen sulfide as a hydrometallurgical reagent has been developed. The process incorporates the concept of hydrogen sulfide addition to recycled copper sulfide solids in a turbulent flow area where further precipitation or agglomeration occurs to increase the effective particle size of the copper sulfide precipitate. Because the recycled solids provide a larger number of particles upon which momentary excesses of hydrogen sulfide are absorbed, oversulfidization of the product is prevented. Copper sulfide precipitates produced in this manner in a laboratory test reactor showed greatly improved physical characteristics compared to copper sulfide precipitates obtained by conventional direct precipitation in which H2S is bubbled directly into acid leach liquor. Copper sulfide precipitates were evaluated and compared by use of filtration tests and settling rate studies. Electron microscopic examination of the solids confirmed the presence of larger particles in reactor-precipitated copper sulfide. Flotation was examined as an alternative to filtration for recovery of CuS precipitates and was found to achieve complete CuS removal without addition of collector or frothing reagents in a period of 2 min. In the same test reactor, a rapidly floatable CuS precipitate was also formed by mixing H2S with acid liquors used to leach crushed copper oxide-copper sulfide ore (LPF process). In the presence of gangue from the crushed ore, flotation of both natural and reactor-produced copper sulfides resulted in recovery of better than 90% of the copper contained in the crushed ore.

Jan 1, 1974

All the Technical PUBlications and Preprints published in 1932 are available at Institute headquarters. They are also on file in public, university and technical libraries and, when so indicated in the list, may be found in the Transactions. Copies of the Technical Publications have been mailed to those members of the Institute who are registered in the different classes: A-Metal Mining; B-Milling and Concentration; C-Iron and Steel Division; D-Nonferrous Metallurgy; E-Insti-tute of Metals Division; F-Coal Division; G-Petroleum Division; H-Nonmetallic Minerals; I-Mining Geology; K-Mining Administration; L-Geophysical Prospecting. Other members may obtain copies by writing to the Secretary. Copies of Preprints may also be obtained from the Secretary's office. Additional copies are sold at the rate of 1 cent per page; minimum charge, 25 cents. Nonmembers may purchase the papers at the prices mentioned. Metal Mining Technical Publi- Title Author Meeting Trans. cation Volume No. and Page* 484-A.45 Propeller Type Mine Fan at Moose A. S. Richardson New York 102, 88. 95 F.52 Shaft. Butte. Montana (13) Feb.. 1932 487-A.46 Progress in the Improvement of Max H. Barber New York. Methods and Equipment at Feb., 1932 Open-pit Iron Mines on the Lake Superior Iron Ranges (9) Pre. Sand Filling through Pipes and Lucien Eaton New York, 102, 33, 41 Boreholes (9) Feb., 1932 Milling And Concentration 445-B.37 Soap Flotation of the Nomulfides Will H. Coghill New York. H.19 (18) J. Bruce Clemmer Feb., 1932 461-B.38 Principles of Flotation—An Experi- I. W. Wark New York. mental Study of the Effect of A. B. Cox Feb.. 1932 Xanthates on Contact Angles at Mineral Surfaces (48) Iron and Steel Division 447-C.81 Electrochemical Potentials of Nitri- Shun-ichi Satoh New York, fied Steels (31) Feb.. 1932 450-C.82 Reaistanoe of Iron-aluminum Alloya N. 9. Ziegler New York. 100, 267. 670 E.143 to Oxidation at High Tempera- Feb., 1932 tures (8) 451-C.83 Pressure Welding of Low-carbon C. H. Austin New York. Steela with Theoretical Con- W. S. Jeffries Feb.. 1932 siderations on the Mechanism of Such Welding (42) 453-C.84 Inclusions—Tbeir Effect, Solubility C.E.Sims New York, 100, 154, 176 and Control in Cast Steel (24) 0. A. Lillieqvist Feb., 1932

Jan 1, 1932

By Edward Keller

ALTHOUGH the subject matter contained in this paper is presented under a new title, its writing was induced by the work of S. Skowronski and K. W. McComas.1 A discussion of the latter is here combined with the presentation of new and independent data. The physical constants quoted by the authors of that paper, such as melting and boiling points, as also the chemical reactions of the substances involved, are so well established that the numerous confirmatory experiments and their application to metallurgical conditions leave little or no room for criticisms. On the contrary, they will greatly aid to dispel any lingering skepticism as to possible considerable losses of copper accruing when the metal is melted in the presence of its own and, probably, other chlorides and when no provision is made for the recovery of volatile products. Exception may be taken, to some degree, to that part of the work under the caption Melting Drillings of Copper Mixed With Sodium Chloride. These experiments should have been extended in order to make the implied reactions clear and the results convincing. The latter are stated to be, "that when sodium chloride is present above certain minimum quantity relative to copper some of it is found to volatilize in the melt while another part reacts with the metallic copper to produce the volatile cuprous chloride, and that When smaller quantities of sodium chloride are present the reaction is complete and all chlorine is found to have volatilized as cuprous chloride." Metallic copper and sodium chloride are mentioned as the sole reagents in this chemical process, acting, according to the authors, in a neutral atmosphere of carbon dioxide. The chemist, quite naturally, will inquire into the formula according to which that reaction takes place and find that it would present itself as follows: 2Cu + 2NaC1 = 2Na + Cu2Cl2 It would appear that the truth of this formula will be challenged and a more rational explanation of the reaction sought. Apparently, carbon dioxide is neutral relative to metallic copper in its molten state; whether it remains neutral in the presence of sodium chloride is quite another question. Does it not at that high temperature become an oxidizer and do not the conditions of the reaction change to those expressed in the following formula? 2Cu + 2NaCl + 2002 = Na2CO3 + CO + Cu2Cl2

Jan 9, 1919

By J. Kittl, D. Arias

THE decomposition on cooling of the high-temperature ß bcc phases in copper- or silver-based binary systems usually takes place by a martensitic. massive, bainitic, or pearlitic reaction depending upon the particular conditions of each system. The AgAl system is one of these systems in which a massive or a martensitic transformation can occur upon cooling from the 3 phase field. Recently Hawbolt and Brown1 observed both massive and martensitic transformation products in a 22.7 at. pct A1 alloy. In the present work the massive and the martensitic transformations were investigated in a number of alloys for the composition range between 23.2 and 27.9 at. pct Al. The alloys were prepared using high-purity silver, 99.999 pct, supplied by ASARCO and aluminum, 99.999 pct, supplied by ALCOA. The metals were melted using a graphite or a sintered alumina crucible which was sealed in quartz tubes under an argon atmosphere. The alloys Were remelted to reduce segregation and homogenized in the 13 phase field for 24 hr. The weight of the alloys after homo-genization compared with the initial weight indicating the alloy composition to be within k0.1 pct of the in- tended composition. Chemical analysis of several samples confirmed the estimated alloy composition. All metallographic observations were performed on samples electropolished with ac current using a 10 pct solution of KCN and a stainless-steel electrode. The samples were cut into -1-mm-thick slices, polished, heat-treated in the ß phase field, and quenched in air, ice water, or iced brine. Some heat treatments consisted of a 2-min anneal carried out in air to allow maximum quenching speeds. Other samples were heat-treated in a vacuum of 10"4 torr and quenched using a helium blast in a quenching apparatus described elsewhere.&apos; In both cases, no appreciable losses of silver or aluminum were noted at the sample surface by sectioning and electropolishing. Table I summarizes the microstructure resulting from the various quenching treatments. The composition of the alloys investigated is also indicated on the equilibrium diagram in Fig. 1. The <, hcp phase, typical of a massive ß — cm, transformation, was observed in all alloys. A minimum temperature of 450°C was estimated for this transformation based on preliminary cooling experiments. the results being included in Fig. 1. In these

Jan 1, 1970

By R. O. Harma

Introduction Wet autogenous grinding is utilized in three iron ore concentrating plants operated by the Cleveland-Cliffs Iron Company (CCI). This paper will trace some of the development in converting from the use of metal grinding mill liners to the use of rubber and will update the current performance of rubber liners in these applications. The Cleveland-Cliffs Iron Company is a natural resources firm with major interests in iron ore mining and processing and oil and gas contract drilling. The company also has interests in oil shale, uranium, forest products, and Great Lakes shipping. The three operations discussed in this paper are the Empire and Tilden Mines on the Marquette Iron Range in Michigan&apos;s Upper Peninsula and the Sherman Mine in northern Ontario, Canada. The Empire Iron Mining Partnership is managed by The Cleveland-Cliffs Iron Company and is owned by Inland Steel, McLouth Steel, The Cleveland-Cliffs Iron Company, and International Harvester. The Tilden Iron Mining Partnership is also managed by The Cleveland-Cliffs Iron Company and is owned by Algoma Steel Corporation, Ltd., Jones & Laughlin Steel Corporation, The Cleveland-Cliffs Iron Company, Steel Company of Canada, Wheeling-Pittsburgh, and Sharon Steel Corporation. The Sherman Mine is a joint venture managed by Cliffs of Canada, Ltd. and owned by Dominion Foundries and Steel Company, Ltd. and Tetapaga Mining Company, a wholly owned subsidiary of The Cleveland-Cliffs Iron Company. The concentrators at all three mines utilize two stage autogenous grinding. Empire and Sherman process magnetic iron ores (Table 1) and utilize magnetic, hydraulic, and flotation concentration methods. Tilden processes an oxidized iron ore (martite, goethite, and hematite) and utilizes a selective-flocculation desliming and flotation concentration flowsheet. Final grind particle sizes are 90% -325M (43k) at Sherman, 90% -500M (25,u ) at Empire and 85% -500M (25 µ) at Tilden. Developmental History The success of using rubber mill linings in Scandinavia led to the first rubber mill lining used by CCI. It was installed in a conventional primary ball mill at Republic Mine in 1964 as reported by Lindroos (1970). This was followed by additional rubber liners for both primary and regrind ball mills. Generally these rubber linings provided about twice the service life as compared to the Type I Ni-hard liners previously used. Grinding efficiency of rubber was found to

Jan 1, 1982

By E. T. Turkdogan, P. Grieveson

STAFF: Editor, Gerhard Derge Acting Editor, Paul G. Shewmon Carnegie lnstitute of Technology Sc hen ley Park Pittsburgh 13, Pa. Editorial Assistant, M. A. Redmerski Production Editor, Otto T. Johnson THE METALLURGICAL SOCIETY: Karl L. Fetters, President; J.S. Smart, Jr., Past-President; R. C. Cole, Vice President; R. L. Hennebach, Treasurer; R. W. Shearman, Secretary. PUBLICATIONS COMMITTEE OF THE METALLURGICAL SOCIETY: W. 0. Phil-brook, Chairman; H. L. Bishop, R. C. Cole, J. N. Hobstetter, W. A. Krivsky, E. R. Morgan, F. C. Langenberg, R. E. Lund, Paul Queneau, L. L. Seigle, R. L. Smith, and T. &apos;4. Wainwright. Review and selection of manuscripts is under the supervision of the following Publications Committes: Extractive Metallurgy Division: R. E. Lund, Chatrmon; M. E. Wodsworth, Vice Chairman; D. H. Baker, Jr., G. M. Bell, R. E. Groce, W. A. Krivsky, R. A. Lewls, Charles O&apos;Neill, A. W. Schlechten, R. E. Shinkoskey, and W. W. Stephens. Iron and Steel Division: T. V. Wainright, Choirman; H. L. Bishop, R. E. Boni, T. E. Dancy, C. W. Murphy, Johonnes M. Uys, J. B. Wagstaff, and R. G. Ward. lnstitute of Metols Division: J. N. Hobstetter, Chairman; P. A. Beck, J. J. Becker, G. F. Bolling, J. O. Brittain, J. 8. Clark, R. S. Davis, A. E. Dwight, R. W. Fountain, L. R. Girifalco, J. C. Gurland, H. S. Kclish, E. L. Harmon, J. J. Heger, A. A. Hendrickson, L. Himmel, J. P. Hirth, H. H. Johnson, Jr., R. R. Nosh, T. N. Rhodin, R. H. Richman, H. C. Rogers, W. Rostoker, C. Sherby, C. W. Spencer, L. Slifkin, J. K. Stanley, R. Steinitz, H. C. Stumpf, and R. Swolin. Published bimonthly by the American Institute of Mining, Metallurgical, and Petroleum Engineers, Inc., 345 East 47th Street, New York 17. N. Y. Telephone PLaza 2-6800. Subscription $30 per year for non-AIME members in United States and North, South, and Central America; $32, foreign; $7.50 for AlME members. Single copies, $6.00, single copies foreign, $6.50. The AlME is not responsible for any statement made or opinion expressed in its publications ... Copyright 1962 by the American lnstitute of Mining, Metollurgical. and Petroleum Engineers. Inc. . . . Registered cable address, AlME New York . . . Indexed in Engineering Index, lndustriol Arts Index, and Chemical Abstracts . . . Second class postage paid at New York, N. Y., and Ann Arbor, Mich. Volume 224, Number 6.

Jan 1, 1962

By Lester Guttman

THE connection between short-range order and thermodynamic activities in binary solid solutions has been pointed out by Birchenall1 who calculated approximate values of the energy of interaction of Zn and Cu and of the degree of short-range order in alpha-brass at one composition and two temperatures. The purpose of this note is to call attention to a somewhat more accurate theory than that used by Birchenall and to extend the calculations to a wider range of temperatures and compositions as a means of testing its applicability. This is an example of the well-known general method of comparing measured thermo-dynamic functions of a system with those calculated from a microscopic model by means of statistical mechanics. In this case, mathematical approximations must be used which make difficult any decision about the validity of the model. Birchenall&apos;s statistical method resembles closely that called by Fowler and Guggenheim2 the "quasi-chemical" method which has been shown to lead in certain cases to results identical with those obtained by the method of Bethe.3 The quasi-chemical method has been extended by Takagi4 to give general formulae for the free energy of binary solid solutions based on several lattices at all compositions and temperatures. Specifically, he treats the four systems typified by: I. ß-brass; 2. a- brass; 3. AuCu3; 4. AuCu. When the temperature is so high that no long-range order exists, these formulae reduce to the same form for all lattice types, namely: [ ] Here the symbols have the following meanings: [F-Helmholtz free energy E-energy S-entropy k-the gas constant per molecule z-coordination number, (e.g. 12 in. a-brass). N-total number of atoms c-atomic fraction of A] VAA, VBB, VAB-energy per bond of the corresponding bonds log means log, throughout The superscript 0 denotes the thermo- dynamic function in the standard state, which has been chosen to be pure A or B with the same crystal structure as the solid solution. The quantity x is the ratio of the number of A-A bonds to the total number and for minimum F satisfies the equilibrium condition [ ] The free energy may also be written in terms of µA and µB, the chemical potentials or partial free energies per atom:

Jan 1, 1948

By William J. Gillich, Gerald L. Moss

PREVIOUS studies of the shock loading of randomly oriented polycrystalline aggregates have firmly established that, after rather short load duration, hydrostatic compression closely approximates the shocked state.&apos; However, McQueen deduced from pressure measurements with good time resolution that, during shock loading, metals begin to undergo a stress relaxation at the yield stress. He suggested that the relaxation is due to plastic deformation accompanying the change from a one-dimensional compression to a three-dimensional, hydrostatic, compression.&apos; Stress relaxation may occur faster as stress is increased above the yield stress, but the existence of unidirectionally compressed states for finite times suggests that the concept of a unidirectionally distorted lattice should furnish considerable insight into the mechanical behavior of materials subjected to shock loading. Here, a crystallographic analysis is presented for the hypothetical situation where atom motion may be considered as unidirectional which, as indicated above, is a useful extension of the macroscopic concept of shock loading to the microscopic domain. Only motion caused by the com-pressive forces is treated; i.e., lattice vibrations upon which this motion is superimposed, as discussed by Fitzgerald, are ignored.3 The purpose of the analysis to be presented is to develop a description for single crystals of the lattice rotations that occur for idealized uniaxial strain deformation. The usefulness of such an analysis in realistic deformation is to give a method of specification of those properties of an initially distorted lattice which would affect the subsequent deformation. Non-axial complications that arise experimentally, such as off-axis rarefaction waves, must be treated in proper context. Consider the material element shown in Fig. 1 and let the compression be uniform at all regions of the element. Then, any interior point of the element is displaced in proportion to its distance from the base of the element. Accordingly, if the top of a unit element is displaced by an amount, (-K), with respect to the base, a point P(X, Y) will be displaced by (-KY). Crystal planes are, therefore, rotated by the compression. Analysis of this rotation may be accomplished from the geometry shown in Fig. 1 where the line OP is the edge of the plane {hkl} and N is its normal. The orientation of the crystal plane with respect to the shock direction is specified by the angle, before deformation. After deformation the edge of plane {hkl}

Jan 1, 1969

By S. Stutz

Three years ago, at the Philadelphia meeting, in February, 1881, the author had the pleasure of presenting to the Institute a paper on coal-washing machinery.* Since that time many new machines, with important improvements and labor-saving apparatus, have been introduced, the construction and description of which may be of interest to some of the members of the Institute. By referring to the above-mentioned paper, and more especially to Plate IV., representing a vertical section of a coal-washer, it will be noticed that the bottom of the plunger-box B is made level or horizontal, and supports a spring-buffer F for the purpose of limiting the down-stroke of the plunger P and receiving the impacts of the latter. Althongh the construction of the box, in view of these impacts, received from the start the proper attention (the bottom of the chamber 3 being made of three thicknesses of 3-inch planks, resting on 6-inch sqnare columns), yet, through careless working of the machinery, without the necessary water in the box, it proved in several instances not strong enough, and had to be changed. To prevent such interruptions in future, it became necessary to devise some means for relieving the machine from the impacts of the plunger altogether. This has been accomplished by the arrangement shown upon Plate I. of this paper, representing a new waesher; and not only has the difficulty been overcome, but also sorne other advantages have been obtained, as will be seen further on. The compartments +, A&apos; of the separator-box have been set upon heavy cast-iron brackets B, leaving sufficient space below the bottom for the buffer F and the sediment-valve K. By means of the plunger-rod 6 passing through the stuffing-box s to the outside, and provided at its lower end with a shoe a, the impacts of the plunger are now transmitted from the buffer F directly to the foundation. At the same time a better guide for the plunger P in its up and down movement has been obtained. The plunger of the former machine had only the guide I and the yoke Y, whereas the new machine has an additional guide in the stuffing-box s, thus preventing wear and friction of the plunger against the lining of the box. Further-

Jan 1, 1884

By R. B. Russell

The expansion coefficients of hexagonal (a) zirconium have been calculated from the lattice expansionparameters of both coefficientsofhexagonallow and high hafnium alloys in the range 0° to 600°C. It is found parametersofboththat the coefficients are straight-line functions of the temperature and that the effect of hafnium is to depress the mean coefficients by about 1 pct at room thattemperature and 9 pct at 600°C. The cubic (ß) form was stabilized so that its coefficient could be determined from 400&apos; to 900°C. COEFFICIENTS of thermal expansion for hexagonal-close-packed (a) zirconium were determined up to 600°C (1112°F), without any interference from the effects of preferred orientation, by measurement of the lattice parameters obtained from a symmetrical back-reflection focusing X-ray camera. This paper combines the results for a 1.2 atomic pct hafnium alloy from an earlier report&apos; with those for hafnium-free zirconium. The problem confronting the investigator is essentially that of getting sharp, high-angle diffraction lines which represent the material at a known constanl. temperature and chemical composition. In order to do this, it was necessary to use the proper X-ray emission wave length (Co K was chosen) and to have a fine-grained metal whose atomic spacings would be free from effects of cold work (the specimen was annealed) and to prevent a changing composition owing to gas absorption during the heating of the metal to temperature (the sample was heated in a vacuum). A summary of the effect of temperature on properties is listed in Table I which gives data for ordinary zirconium, as well as new values for the low hafnium metal. The coefficients of the linear thermal expansion that have been reported are given in Table 11. The discrepancies shown may be explained perhaps by the effect of preferred orientation, and McGeary and Lustman2 have done this successfully for sheet metal. The differences in texture cannot explain all the differences in expansion coefficient shown in Table II. liesults by the author agree most closely with those of Kroll.3 Chemical analysis of the high hafnium metal pre- viously reported1 showed that it was 98.22 atomic pct (97.40 wt pct) pure. The low hafnium metal was dehydrogenated Westinghouse crystal bar, designated SMZ-137A. Its analysis was as given in Table 111 (chemical analyses 5377, 5431, and 5432).

Jan 1, 1955

By William L. Fink, Kent R. Van Horn

Zinc is one of the effective elements introduced to enhance the strength of aluminum. This strengthening is principally attributable to the high solid solubility of zinc in aluminum and the pronounced variation of solubility with temperature. Consequently an accurate determination of the solid solubility curve is desirable. The solid solubility relations have been studied by numerous investigators. Shepherd1 first established the existence of a solid solution region at the aluminum end of the diagram (-v phase) by specific volume and microscopic determinations. Bauer and Voge12 published a constitutional diagram which showed the limits of solid solubility as determined by thermal and microscopic methods. Hanson and Gayler3 presented the aluminum-zinc diagram which is now most generally accepted (Fig. 1). Chill-cast samples were given thermal treatments designed to obtain equilibrium conditions, quenched, and microscopically examined. The solubility was placed between 15 to 20 per cent at 60" C., 20 to 22 per cent at 140" C. and 36 to 38 per cent at 270" C. Sander and Meissner decidedly modified the limits of the -y phase field of Hanson and Gayler&apos;s diagram by using similar methods on chill-cast specimens annealed for a shorter period of time. Tanabe,s utilizing dynamic hard-ness, electrical conductivity and dilatometric measurements of specimens at temperature, obtained values comparable to Hanson and Gayler&apos;s at room temperature, but appreciably lower at higher temperatures. Nishimura6 concluded from age-hardening results of aluminum-zinc alloy chill castings, which had been quenched from 400" to 500" C., that the solubility of zinc in aluminum at room temperature is less than 5 * Metallurgical Division, Aluminum Research Laboratories. 1 E. S. Shepherd: Aluminum-Zinc Alloys, Jnl, phys. Chem. (1905) 9, 504. 2 0. Bauer and 0. Vogel: Aluminum-Zinc Alloys, Int. Jn1. Melallog. (1916) 8, 101. 3 D. Hanson and M. V. L. Gayler: A Further Study of the Alloys of Aluminum and Zinc. Jnl. Inst. Met. (1922) 27, 267. 4 W. Sander and K. L. Meissner: ZII~ Kenntnis der Konstitution der Aluminium-Zinklegierungen. Ztsch. f. Metallkunde (1922) 14, 385. 4 T. Tanabe: Studies in the Aluminum-Zinc System, Jnl. Inst. Met. (1924) 32, 415 6 H. Nishimura: On the Age-Hardening of Aluminum-Rich Al-Zn Alloys. Mem. Kyoto Imp. Univ. (1924) 3, 133.

Jan 1, 1932

US 4,141,854-Method of resolving water-in-oil emulsions from the organic solvent extraction of uranium from an aqueous ore leach solution The emulsion is treated at optimum temperature with a water-soluble acrylamide copolymer which contains 5-50% by weight of a lower alkyl substituted tertiary aminoethyl methacrylate or quaternary ammonium salts thereof The emulsion is broken, enabling recovery and reuse of the organic portion of the emulsion A M Pavilcius and M A Latko, assigned to Nalco Chemical Co Feb. 27, 1979 3 pp (252-301 1W) Filed: 12-14-77 (860,542). US 4,142,952-In the recovery of copper from an ore leach solution, the solution is contacted with a water-immiscible organic solvent containing 5 to 20 g/L of o-hydroxyaryloxime and 2 to 20 times the weight of the o-hydroxyaryloxime of nonylphenol The loaded solvent phase is separated from the aqueous phase and stripped with sulfuric acid Copper is recovered rapidly and in high yield from aqueous solutions containing high copper concentrations R F Dalton, as¬signed to Imperial Chemical Industries Ltd Mar 6, 1979 6 pp (204-106) Filed 1-3-77 (756,067). Priority: United King¬dom, 1-30-76 (3788/76), 6-15-76 (24722/76), and 10-21-76 (43711/76). Same- British 1,549,615, dated Aug. 1, 1979 US 4,148,631-In the recovery of nickel and cobalt from a mixed sulfate ore leach solution, both metals are extracted by means of a cationic extractant, the loaded extractant treated with an aqueous chloride or thiocyanate solution to back extract the cobalt, and the cobalt then recovered by solvent extraction or ion exchange with an anionic extractant Recovery is effected in a relatively few extraction steps. F Babjak, V A Ettel, and K. R Dymock, assigned to Interna¬tional Nickel Co , Inc, Apr. 10, 1979 6 pp (75-101 BE) Filed¬7-27-78 (928,401). Priority- Canada, 12-28-77 (293,967) US 4,148,813-An improved extractant for use in the recov¬ery of nickel and cobalt from an ore leach solution comprises a water immiscible organic solvent system containing solubilized mercaptide ions, e g , dodecanethiol. Cobalt and nickel mercaptides solvated in the organic phase are easily stripped in the presence of carbon monoxide and an aqueous alkaline solution A. S. Rappas and J. P. Pemsler, assigned to Ken¬necott Copp

Jan 1, 1980

The following is a report of the papers submitted to the Papers &apos;and Publications Committee during 1928: The Committee held nine regular meetings during the year 1928. During that period there were presented to the Institute 214 papers which were acted upon as follows: Accepted as Technical Pub1ications............................ 85 Declined for publication...................................... 16 Action pending, Dec. 31...................................... 25 Manuscripts held for annual volumes, Dec. 31................... 7 Withdrawn temporarily...................................... 1 Accepted as Preprints........................................ 20 Printed for first time in volumes.............................. 35 Published in Mining and Metallurgy........................ 12 Papers in Technical Publication No. 156 (Coal Classification) and not accounted for elsewhere in this table..................... 10 Mimeographed only*................................... 3 Total.................................................. 214 * A considerable number of papers were mimeographed for the annual meeting. Of the 85 papers accepted as Technical Publications 8 were reprinted in the Transactions, 7 in Proceedings of the Institute of Metals Division (1928), 7 in Iron and Steel Technology in 1928, 13 in Geophysical Prospecting, and 50 were in Technical Publication form on Dec. 31. Of the 20 papers accepted as Preprints 1 was reprinted in the Transactions, 13 in Petroleum Development and Technology in 1927, 2 in Geophysical Prospecting, and 4 were in Preprint form on Dec. 31. Of the 35 papers printed for the first time in the various volumes 8 were included in the Transactions, 2 in Proceedings of the Institute of Metals Division (1928), 1 in Iron and Steel Technology in 1928, and 24 in Petroleum Development and Technology in 1927. Of the 12 papers accepted for Mining and Metallurgy 1 was, accepted for Geophysical Prospecting and 1 for the Transactions. There were published in 1928 113 Technical Publications containing a total of 1928 pages, as against 88 in 1927, totaling 1528 pages. The Technical Publications published in 1928 were classified as follows: Group A, Metal Mining, 17 papers (361 pages); B, Milling and Concentration, 4 papers (39 pages); C, Iron and Steel, 15 papers (256 pages); D, Non-ferrous Metallurgy, 13 papers (191 pages); E, Institute of Metals, 36 papers (588 pages); F, Coal and Coke, 15 papers (392 pages); G, Petroleum and Gas, 10 papers (246 pages); H, Non-metallic Minerals, 3 papers (33 pages); I, Mining Geology, 18 papers (356 pages); K, Mining Administration, etc., 3 papers (47 pages); L, Geophysical Prospecting, 21 papers (430 pages).

Jan 1, 1929

The following is a list of members who died in 1928. It is compiled from reports to the Secretary&apos;s office. Biographical sketches published in Mining and Metallurgy are indicated in the last two columns. Issue Containing Year or Date or Biography Election Name Death 1928 Page 1914 Adams. David T.................... July 22 October 471 1905 Aguilera. Pedro................... May 3 October 469 1902 Althouse, H. W.................... NOV. 3 December 559 1920 Averill: C. C...................... July 9 October 471 1915 Baldwin, C. Kemble............... Aug. 9 October 471 1926 Barquist, Walter C............... NOV. 14 June 298 Barron,* Clarence Walker......... Oct. 2 November 511 1917 Beasley, Fred E.................... Aug. 31 October 471 1901 Belden, S. B....................... May 15 July 333 1927 Binney, Edwin, Jr.................. Dec. 29 February 96 1915 Bonsall, James Malcolm............ Feb. 12 June 284 1917 Boyle, John....................... July 12 December 561 1913 BradEn, Eugene B............. Jan. 29 March 157 1889 Bulkley, Frank.................... Mar. 25 May 240 1896 Callaghan, J. T., Jr............... Apr. 1 1892 Chalmers, George.................. Feb. 4 April 197 1898 Clark, Josiah H.................. May 7 July 333 1887 Copeland, F. K............. Nov. 10 December 561 1915 Cunningham, B. L11............... Dec. 6 August 294 1888 Dana, R. T........................ Aug. 20 December 559 1907 Dennis, Clifford G............... Dec. 28 March 1 1920 DeVenny, Thomas................ Feb. 13 April 197 1882 d&apos;Invillier-, Edward V........... Jan. 4 March 157 1884 Duncan, M. M..................... Dec. 17 February 96 1924 Dyrssen, WaldemaR ............... Aug. 4 October 471 1906 Edmondson. H. W................ Dec. 21 February 1884 Emmerton, F. A.................. Oct. 9 June 298 1911 Eu, S. H............................ July 20 February 1917 Farrand, Ira W.................... Sept. 6 October 469 1900 Fell, E. Nelson...........•......... Mar. 25 May 231 1918 Fenton, Clarence M.............. October Junet 298 1908 Ferraris, Erminio................. Sept. 22 June 298 1914 Galloway. A. D. R............... December April 215 1924 Grant, A. W., Jr................... .4pr. 5 June 285 1917 Grant, Clifford G............... Jan. 26 January? 37 1918 Grant, Frank E.............. Jan. 14 September 417 1921 Gunderoth, C. J.................. Feb. 15 1897 Harms, Ernest..................... Aug. 12 November 512 1891 Hartrick, J. S..................... Feb. 9 June 285 1925 Hochschild, Berthold.............. Jan. 24 April 197 1917 Hutton, L. W...................... NOV. 3 January 37 1894 Jenning", S. J...................... NOV. 17 December 560 1925 Jones, J. Ravenscroft............... Jan. 29 March 157 1880 Jones, J. T......................... May 4 June 284

Jan 1, 1929

Discussion of the paper of J. K. FURST, presented at the Pittsburgh meeting, October, 1914, and printed in" Bulletin No. 94, October, 1914, pp. 2493 to 2514. W..McA. JOHNSON, New York, N. Y.-On discussing this paper I am open to the criticism of "bringing coals to Newcastle," as I, a zinc man, am bringing new ideas on steel to Pittsburgh. But still the view of an outsider can be valuable to the insider. Any multistage process, where each apparatus operates on its particular part of the work at a high efficiency, constitutes an advance in the state of art. But in multiplicity there can be complication and ensuing loss and inefficiency. The duplex steel process is not the pronounced success which was predicted for it by its adherents, for several of such plants have reverted to plain open-hearth methods. If we regard broadly refining processes, such as the Bessemer, open-hearth, puddling, copper refining, lead cupelling, nickel refining, we find that in general refining processes are intermittent and &apos;concentration processes are continuous. (This generalization I believe to be original with me; it was communicated to Dr. E. F. Roeber, editor, and appeared as an editorial in Metallurgical and Chemical Engineering, March, 1905.) Where we desire primarily quality in a metallurgical operation we must put a batch of metal in the furnace, work on it until we get it to the required purity, test it, and take it out; whereas, if we desire primarily quantity we shove ore into a furnace and smelt it as fast as possible, allowing conditions to make a non-uniform product provided only we get tonnage. From general commercial principles, I believe that the weak point of the duplex process is that the operation is not a money maker unless the plant is kept at. 90 to 95 per cent. of its rated capacity, or unless the Bessemerizing is done so often that it is practically continuous. For in some manner the operation should be made continuous and the control on the tonnage should be commercially flexible. The commercial rigidity of having to control purity exactly increases operating costs without a corresponding gain. Conversely, the chief reason for failure of "steel from ore direct" is that it makes a final operation continuous, which should be naturally intermittent.

Jan 4, 1915